CN113908666A - Chlorinated paraffin environment-friendly production system - Google Patents
Chlorinated paraffin environment-friendly production system Download PDFInfo
- Publication number
- CN113908666A CN113908666A CN202111185809.2A CN202111185809A CN113908666A CN 113908666 A CN113908666 A CN 113908666A CN 202111185809 A CN202111185809 A CN 202111185809A CN 113908666 A CN113908666 A CN 113908666A
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- Prior art keywords
- tail gas
- fixedly connected
- electric energy
- chlorinated paraffin
- heat
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- 239000012188 paraffin wax Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 91
- 238000010521 absorption reaction Methods 0.000 claims abstract description 44
- 239000000843 powder Substances 0.000 claims abstract description 40
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 31
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000012544 monitoring process Methods 0.000 claims abstract description 29
- 239000002184 metal Substances 0.000 claims abstract description 25
- 239000000498 cooling water Substances 0.000 claims abstract description 19
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims abstract description 19
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 239000012528 membrane Substances 0.000 claims abstract description 18
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 15
- 239000003513 alkali Substances 0.000 claims abstract description 12
- 238000001514 detection method Methods 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 230000017525 heat dissipation Effects 0.000 claims description 25
- 238000009413 insulation Methods 0.000 claims description 21
- 238000007872 degassing Methods 0.000 claims description 12
- 230000007613 environmental effect Effects 0.000 claims description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 230000007246 mechanism Effects 0.000 claims description 8
- 239000010959 steel Substances 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 7
- 239000011553 magnetic fluid Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 5
- 239000002657 fibrous material Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 5
- 229910001285 shape-memory alloy Inorganic materials 0.000 claims description 5
- 230000008602 contraction Effects 0.000 claims description 2
- 238000002955 isolation Methods 0.000 claims 2
- 230000002146 bilateral effect Effects 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 16
- 239000000460 chlorine Substances 0.000 abstract description 16
- 229910052801 chlorine Inorganic materials 0.000 abstract description 16
- 239000000428 dust Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 7
- 230000003068 static effect Effects 0.000 abstract description 7
- 230000005611 electricity Effects 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 230000009102 absorption Effects 0.000 description 32
- 238000001179 sorption measurement Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000003921 oil Substances 0.000 description 7
- 230000002159 abnormal effect Effects 0.000 description 5
- 230000005389 magnetism Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 229920000431 shape-memory polymer Polymers 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 240000007643 Phytolacca americana Species 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 230000009103 reabsorption Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000003446 memory effect Effects 0.000 description 2
- 230000006386 memory function Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- -1 hoses Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/30—Controlling by gas-analysis apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/017—Combinations of electrostatic separation with other processes, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/202—Single element halogens
- B01D2257/2025—Chlorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
The invention discloses an environment-friendly chlorinated paraffin production system, which belongs to the field of chlorinated paraffin production and realizes the full absorption of hydrogen chloride, chlorine and free chlorine by a tail gas absorption system, a tail gas treatment system and an oil spraying absorption system, an online PH detection and alarm system and a tail gas monitoring system monitor the alkali liquor consumption and tail gas emission in tail gas treatment, and the environment-friendly online electric energy monitoring system can monitor the running condition of environment-friendly equipment in real time by matching with an electric energy control electric box, and in the working process of the electric energy control electric box, a heat pipe conducts heat generated by the heat pipe to the inside of the electric energy control electric box, so that cooling water absorbs heat and cools down and is gasified into vapor to flow upwards, ammonium chloride powder is decomposed by heating, the absorbed heat is cooled down, a memory metal rope is matched with a cooling block to drive a swing plate to swing up and down, the flow of hot air is accelerated, and an elastic membrane drives collision balls to rub and collide with each other, generates static electricity to cooperate with the superfine fiber to adsorb dust.
Description
Technical Field
The invention relates to the field of chlorinated paraffin production, and particularly relates to an environment-friendly chlorinated paraffin production system.
Background
The chlorinated paraffin is an organic substance, a chlorinated derivative of paraffin, has the advantages of low volatility, flame retardance, good electrical insulation, low price and the like, can be used as a flame retardant and a polyvinyl chloride auxiliary plasticizer, is widely used for producing products such as cable materials, floor materials, hoses, artificial leather, rubber and the like, is applied to additives such as polyurethane waterproof coatings, polyurethane plastic tracks, lubricating oil and the like, and needs to absorb tail gas generated in the production process of the chlorinated paraffin so as to avoid influencing the environment.
In the chlorinated paraffin tail gas treatment process, in order to guarantee the safe operation of tail gas treatment equipment, need monitor it, avoid the emergence of abnormal conditions, but the monitoring facilities radiating effect among the prior art is poor, and the heat is difficult for distributing away fast, causes the influence to its work easily, makes it take place to damage, influences the use, reduces monitoring effect.
Disclosure of Invention
1. Technical problem to be solved
Aiming at the problems in the prior art, the invention aims to provide an environment-friendly chlorinated paraffin production system which can fully absorb hydrogen chloride, chlorine and free chlorine through a tail gas absorption system, a tail gas treatment system and an oil spraying absorption system, an online PH detection and alarm system and a tail gas monitoring system can monitor alkali liquor consumption and tail gas emission in tail gas treatment, the environment-friendly online electric energy monitoring system can monitor the running condition of environment-friendly equipment in real time by matching with an electric energy control electric box, in the working process of the electric energy control electric box, a heat pipe conducts heat generated by the electric energy control electric box to the interior of the electric energy control electric box, cooling water absorbs heat and cools down and is gasified into water vapor to flow upwards, ammonium chloride powder is decomposed by heating, the heat is absorbed to cool down, a memory metal rope is matched with a cooling block to drive a swing plate to swing upwards and downwards, and the flow of hot air is accelerated, and the elastic membrane drives the collision small balls to mutually rub and collide to generate static electricity to match with the superfine fibers to adsorb dust.
2. Technical scheme
In order to solve the above problems, the present invention adopts the following technical solutions.
An environment-friendly chlorinated paraffin production system comprises a tail gas tertiary absorption system, wherein a four-stage packed tower is arranged in the tail gas tertiary absorption system, a degassing kettle is arranged in the tail gas tertiary absorption system, a tail gas main pipe is arranged in the tail gas tertiary absorption system, a glass steel pipe is arranged in the tail gas tertiary absorption system, the glass steel pipe is respectively communicated with the degassing kettle and the tail gas main pipe, a tail gas alkali tower is arranged in the tail gas tertiary absorption system, the tail gas tertiary absorption system is in signal connection with a tail gas treatment system, the tail gas treatment system is in signal connection with an oil spraying absorption system, the tail gas treatment system is in signal connection with an online PH detection and alarm system, the outer end of the online PH detection and alarm system is in signal connection with an environment-friendly online electric energy monitoring system, the outer end of the environment-friendly online electric energy monitoring system is in signal connection with the tail gas online monitoring system, the outer end of the degassing kettle is connected with a safety instrument system through a signal, a tank area is arranged on the right side of the tail gas tertiary absorption system, a hydrochloric acid tank area volatile hydrogen chloride reabsorption system is arranged in the tank area, free chlorine can be fully absorbed through the tail gas tertiary absorption system, the hydrogen chloride can be fully absorbed by the four-stage packed tower, hydrogen chloride and chlorine can be fully absorbed through the degassing kettle, a tail gas main pipe and a glass steel pipe in cooperation with a tail gas alkali tower, the free chlorine, the hydrogen chloride and other gases can be fully absorbed by the tail gas treatment system in cooperation with an oil spray absorption system, the possibility of residual unabsorbed gases is reduced, the alkali liquor consumption condition in the tail gas treatment process can be realized through the online PH detection and alarm system, the alkali liquor can be timely replaced by alarming on-site operators, the tail gas excessive discharge caused by untimely replacement is avoided, and the tail gas emission condition can be monitored by the online monitoring system, if abnormal, in time report, the online electric energy monitored control system of environmental protection can real time monitoring environmental protection equipment operational aspect, if abnormal, in time report, and safety instrument system can real time monitoring response device running state, and when the parameter surpassed the specification, the valve can in time be closed, avoids chlorine to leak, and the volatile hydrogen chloride resorption system in hydrochloric acid tank field can absorb the volatile hydrogen chloride in the tank field, avoids causing the influence to the environment, improves the feature of environmental protection.
Further, an electric energy management and control electric box is arranged in the environment-friendly online electric energy monitoring system, a heat dissipation frame is fixedly connected to the upper end of the electric energy management and control electric box, a plurality of heat conduction pipes which are uniformly distributed are fixedly connected between the electric energy management and control electric box and the heat dissipation frame, cooling water is filled in the heat conduction pipes, an opening is drilled at one end, close to the electric energy management and control electric box, of each heat conduction pipe, an elastic membrane is fixedly connected between the inner walls of the openings, a connecting ball is fixedly connected to one end, far away from the electric energy management and control electric box, of each elastic membrane, a poking rod is arranged at the inner bottom end of each heat conduction pipe and is located in the cooling water, a connecting rope is fixedly connected between each poking rod and the connecting ball, ammonium chloride powder is filled in the heat dissipation frame, a poking mechanism is arranged in the heat dissipation frame, and released heat is transmitted to the inside of the electric energy management and control electric box through the heat conduction pipes to enable the cooling water to be absorbed, and the cooling water is heated and is vaporized, form vapor and upwards flow, cooperation gas thermal expansion drives the elastic membrane and takes place the motion, the elastic membrane drives the poker rod through connecting the rope and takes place the motion, make the cooling water take place to flow, accelerate its absorption to the heat, the ammonium chloride powder of heat dissipation frame is heated the decomposition under the assistance of the mechanism of dialling scattered simultaneously and produces hydrogen chloride gas and chlorine, and absorb the heat, reduce the temperature, and vapor upwards flows to the top in the heat-conducting pipe, absorb the heat along with the desorption of ammonium chloride powder, make heat pipe upper end department temperature reduce, make vapor recondenstion become the drop of water again, drip, realize cyclic utilization, absorb the heat of electric energy management and control electronic box release, reduce its temperature.
Further, the poking and scattering mechanism comprises a deformation memory balloon, the outer end of the deformation memory balloon is fixedly connected with the inner wall of the heat dissipation frame, a magnetic ball is fixedly connected inside the deformation memory balloon, magnetic insulation powder is filled inside the deformation memory balloon, two L-shaped rods which are symmetrical left and right are fixedly connected between the inner walls of the heat dissipation frame, a sliding ring is sleeved at the outer end of each L-shaped rod and is slidably connected with the L-shaped rod, an elastic rope is fixedly connected between the sliding ring and the L-shaped rods, magnetic fluid is filled inside the sliding ring, two straight plates which are symmetrical up and down are fixedly connected at the outer end of the sliding ring, two poking screen meshes which are symmetrical left and right are fixedly connected at one ends, far away from each other, of the two straight plates, the deformation memory balloon is heated and expanded along with the upward flow of hot air to drive the magnetic insulation powder to diffuse, and the magnetic ball cancels the magnetic shielding state, attract the magnetic current body to approach to it, drive the slip ring and slide to the magnetic ball direction, drive and stir the motion of screen cloth, realize stirring the dispersion to ammonium chloride powder, improve reaction efficiency.
Furthermore, the inner bottom end of the electric energy control electric box is fixedly connected with two elastic ball bags which are bilaterally symmetrical, the cooling blocks are fixedly connected inside the elastic ball bags, the heat insulation powder is filled inside the elastic ball bags, a memory metal rope is fixedly connected between the upper end of the elastic ball bags and the lower end of the heat dissipation frame, one end of the heat conduction pipe, which is far away from the electric energy control electric box, is rotatably connected with a plurality of swing plates which are uniformly distributed, the memory metal rope is fixedly connected with the swing plates, the memory metal rope is heated to contract along with the conduction of heat, the swing plates are pulled to move upwards, the elastic ball bags are deformed, the heat insulation powder is diffused, the cooling blocks cannot be effectively isolated, the cold air emitted by the cooling blocks overflows, and the memory metal rope is cooled after contacting the cold air, returns to the initial state and drives the swing plates to move downwards, thereby realizing driving the swing plate to move up and down, quickening the flow of hot air and improving the heat dissipation effect.
Further, the one end fixedly connected with that the elastic membrane is close to the electric energy management and control electronic box adsorbs the cover, the inside that adsorbs the cover is equipped with a plurality of evenly distributed's collision bobble, adsorb the superfine fiber that the cover is close to a plurality of evenly distributed of one end fixedly connected with of electric energy management and control electronic box, the motion of elastic membrane drives the collision bobble in adsorbing the cover and takes place the motion, and mutual collision friction produces static, is stained with because of the high temperature through electrostatic adsorption ability and adsorbs the clearance to be stained with the dust of attaching on electric energy management and control electronic box surface, makes it be stained with and attach at superfine fiber, reinforcing dust removal effect.
Furthermore, the shape memory balloon is made of a shape memory polymer material, the initial state of the shape memory balloon is a contraction state, the shape memory balloon made of the shape memory polymer material has a one-way memory effect, and is deformed and expanded after the temperature rises and is restored to the initial state after the temperature falls.
Further, the magnetism insulation powder is made of Fe-Ni alloy materials, the content of Ni in the magnetism insulation powder is 80%, and the magnetism influence of the magnetic balls can be shielded in a dense state by using the magnetism insulation powder made of the Fe-Ni alloy materials.
Further, the heat insulation powder is made of a heat insulation cotton material, the memory metal rope is made of a shape memory alloy material, the initial state of the memory metal rope is a stretching state, the heat insulation powder made of the heat insulation cotton material can isolate the magnetic influence of the cooling block in a dense state, the shape memory alloy has a memory function, the memory metal rope deforms and contracts along with the rise of temperature, and the memory metal rope returns to the initial extension state along with the reduction of temperature.
Further, the collision bobble adopts the chemical fiber material to make, the inside of collision bobble is hollow setting, can produce static when the collision friction each other through using the collision bobble that adopts the chemical fiber material to make, adsorbs the dust, and through setting up the collision bobble to hollow, can effectual reduction its weight, makes its easy motion take place.
3. Advantageous effects
Compared with the prior art, the invention has the advantages that:
this scheme realizes fully absorbing hydrogen chloride and chlorine and free chlorine through tail gas absorption system and tail gas processing system and oil spray absorption system, and on-line PH detects and alarm system and tail gas monitoring system monitors alkali liquor consumption and exhaust emissions in handling tail gas, and the online electric energy monitored control system of environmental protection cooperation electric energy management and control electronic box can real time monitoring environmental protection equipment behavior, and in electric energy management and control electronic box working process, the heat pipe conducts its heat of production inside to, make the cooling water heat absorption cooling and gasify vapor upwards flow, the decomposition is heated to the ammonium chloride powder simultaneously, the absorbed heat cools down, and memory metal rope cooperation cooling block drives the wobble plate luffing motion, accelerate the flow of hot-air, and the elastic film drives collision bobble looks mutual friction collision, produce the superfine fibre of electrostatic fit and adsorb the dust.
Drawings
FIG. 1 is a flow chart of an environment-friendly production system for chlorinated paraffin according to the invention;
FIG. 2 is a schematic view of an overall structure of the electric power management and control box according to the present invention;
FIG. 3 is a schematic cross-sectional view of a heat pipe according to the present invention;
FIG. 4 is a schematic cross-sectional view of the shape-changing memory balloon according to the present invention;
FIG. 5 is a schematic sectional view of a slip ring according to the present invention;
FIG. 6 is a schematic perspective view of a toggle screen according to the present invention;
fig. 7 is a schematic sectional view of the adsorption sleeve of the present invention.
The reference numbers in the figures illustrate:
1. a tail gas tertiary absorption system; 101. a four-stage packed tower; 102. degassing the kettle; 103. a tail gas main pipe; 104. a glass reinforced plastic pipe; 105. a tail gas caustic tower; 2. a tail gas treatment system; 3. an oil spray absorption system; 4. an online pH detection and alarm system; 5. an exhaust gas on-line monitoring system; 6. an environment-friendly online electric energy monitoring system; 601. an electric energy control box; 602. a heat dissipation frame; 603. a heat conducting pipe; 604. an elastic film; 605. a connecting ball; 606. connecting ropes; 607. a poke rod; 608. a shape-changing memory balloon; 609. a magnetic ball; 6010. an L-shaped rod; 6011. a slip ring; 6012. a magnetic fluid; 6013. shifting the screen; 6014. an elastic cord; 6015. a straight plate; 6016. an adsorption sleeve; 6017. bumping the small ball; 6018. superfine fibers; 6019. a memory metal cord; 6020. an elastic balloon; 6021. cooling the block; 6022. a swing plate; 7. a tank area; 8. a hydrogen chloride reabsorption system volatilized from a hydrochloric acid tank field; 9. a safety instrumented system.
Detailed Description
The drawings in the embodiments of the invention will be combined; the technical scheme in the embodiment of the invention is clearly and completely described; obviously; the described embodiments are only some of the embodiments of the invention; but not all embodiments, are based on the embodiments of the invention; all other embodiments obtained by a person skilled in the art without making any inventive step; all fall within the scope of protection of the present invention.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "top/bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "sleeved/connected," "connected," and the like are to be construed broadly, e.g., "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example (b):
referring to fig. 1, an environment-friendly chlorinated paraffin production system comprises a tertiary tail gas absorption system 1, a four-stage packed tower 101 is arranged in the tertiary tail gas absorption system 1, a degassing kettle 102 is arranged in the tertiary tail gas absorption system 1, a tail gas header pipe 103 is arranged in the tertiary tail gas absorption system 1, a glass steel pipe 104 is arranged in the tertiary tail gas absorption system 1, the glass steel pipe 104 is respectively communicated with the degassing kettle 102 and the tail gas header pipe 103, a tail gas alkali tower 105 is arranged in the tertiary tail gas absorption system 1, the tertiary tail gas absorption system 1 is in signal connection with a tail gas treatment system 2, the tail gas treatment system 2 is in signal connection with an oil spray absorption system 3, the tail gas treatment system 2 is in signal connection with an online PH detection and alarm system 4, an environment-friendly online electric energy monitoring system 6 is in signal connection with the outer end of the online PH detection and alarm system 4, an outer end signal of the environment-friendly online electric energy monitoring system 6 is in connection with an tail gas online monitoring system 5, the outer end of the degassing kettle 102 is connected with a safety instrument system 9 through a signal, the right side of the tail gas tertiary absorption system 1 is provided with a tank area 7, a hydrochloric acid tank area volatile hydrogen chloride reabsorption system 8 is arranged in the tank area 7, the free chlorine can be fully absorbed through the tail gas tertiary absorption system 1, the hydrogen chloride can be fully absorbed by the four-stage packed tower 101, the hydrogen chloride and chlorine can be fully absorbed through the degassing kettle 102, a tail gas main pipe 103 and a glass steel pipe 104 in cooperation with a tail gas alkali tower 105, the tail gas treatment system 2 can fully absorb the gases such as the free chlorine and the hydrogen chloride in cooperation with an oil spraying absorption system 3, the possibility of residual and unabsorbed gases is reduced, the alkali liquor consumption condition in the tail gas treatment process can be realized through the online PH detection and alarm system 4, the alarm is carried out to remind field operators to replace the alkali liquor in time, and the excessive discharge of the tail gas caused by the untimely replacement is avoided, the tail gas online monitoring system 5 can realize monitoring the tail gas emission condition, if abnormal, the on-line electric energy monitoring system 6 of environmental protection can real-time monitoring environmental protection equipment operation condition, if abnormal, the on-line electric energy monitoring system can timely report, and the safety instrument system 9 can real-time monitoring reaction equipment running state, when the parameter surpasses the specification, can in time close the valve, avoid chlorine leakage, the volatile hydrogen chloride resorption system 8 of hydrochloric acid tank field can absorb the volatile hydrogen chloride in the tank field 7, avoid causing the influence to the environment, and the environmental protection performance is improved.
Referring to fig. 2-6, an electric energy control box 601 is disposed in an environment-friendly online electric energy monitoring system 6, a heat dissipation frame 602 is fixedly connected to an upper end of the electric energy control box 601, a plurality of heat conduction pipes 603 are fixedly connected between the electric energy control box 601 and the heat dissipation frame 602, cooling water is filled in the heat conduction pipes 603, a through hole is drilled at one end of the heat conduction pipes 603 close to the electric energy control box 601, an elastic membrane 604 is fixedly connected between inner walls of the through hole, a connection ball 605 is fixedly connected to one end of the elastic membrane 604 away from the electric energy control box 601, a poking rod 607 is disposed at an inner bottom end of the heat conduction pipes 603, a connection rope 606 is fixedly connected between the poking rod 607 and the connection ball 605, ammonium chloride powder is filled in the heat dissipation frame 602, a poking mechanism is disposed in the heat dissipation frame 602, and during operation of the electric energy control box 601, released heat is transferred to the interior of the heat conduction pipes 603 to absorb the cooling water, the cooling water is vaporized by heating, water vapor flows upwards, the elastic membrane 604 is driven to move by matching with the gas heated expansion, the elastic membrane 604 drives the poke rod 607 to move through the connecting rope 606, the cooling water flows, the heat absorption of the cooling water is accelerated, meanwhile, the ammonium chloride powder of the heat dissipation frame 602 is heated and decomposed under the assistance of the poke mechanism to generate hydrogen chloride gas and chlorine gas, the heat is absorbed, the temperature is reduced, the water vapor flows upwards to the top end in the heat conduction pipe 603, the heat is absorbed along with the decomposition of the ammonium chloride powder, the temperature of the upper end of the heat conduction pipe 603 is reduced, the water vapor is condensed into water drops again, the cyclic utilization is realized, the heat released by the electric energy control electric box 601 is absorbed, and the temperature of the electric energy control electric box is reduced.
Referring to fig. 5-6, the poking and scattering mechanism includes a shape-changing memory balloon 608, an outer end of the shape-changing memory balloon 608 is fixedly connected with an inner wall of the heat-dissipating frame 602, a magnetic ball 609 is fixedly connected inside the shape-changing memory balloon 608, the inside of the shape-changing memory balloon 608 is filled with magnetic-isolating powder, two L-shaped rods 6010 that are symmetrical left and right are fixedly connected between inner walls of the heat-dissipating frame 602, a sliding ring 6011 is sleeved on an outer end of the L-shaped rod 6010, the sliding ring 6011 is slidably connected with the L-shaped rods 6010, an elastic rope 6014 is fixedly connected between the sliding ring 6011 and the L-shaped rods 6010, a magnetic fluid 6012 is filled inside the sliding ring 6011, two straight plates 6015 that are symmetrical up and down are fixedly connected to an outer end of the sliding ring 6011, two left and right symmetrical poking screens 6013 are fixedly connected to an end of the two straight plates 6015 that are far away from each other, the deformation-changing memory balloon 608 is heated and expanded to drive the magnetic-isolating powder to be diffused as hot air flows upwards, the magnetic ball 609 cancels the magnetic shielding state, attracts the magnetic fluid 6012 to approach the magnetic ball 609, drives the sliding ring 6011 to slide towards the direction of the magnetic ball 609, and drives the stirring screen 6013 to move, so that the ammonium chloride powder is stirred and dispersed, and the reaction efficiency is improved.
Referring to fig. 2-3, two bilaterally symmetrical elastic balloons 6020 are fixedly connected to the inner bottom end of the electric power control box 601, a cooling block 6021 is fixedly connected to the inside of the elastic balloon 6020, heat insulation powder is filled in the elastic balloon 6020, a memory metal rope 6019 is fixedly connected between the upper end of the elastic balloon 6020 and the lower end of the heat dissipation frame 602, a plurality of swing plates 6022 are uniformly distributed and rotatably connected to one end of the heat pipe 603 away from the electric power control box 601, the memory metal rope 6019 is fixedly connected to the swing plates 6022, the memory metal rope 6019 is heated to contract with the conduction of heat, the swing plates 6022 are pulled to move upwards to deform the elastic balloon 6020, the heat insulation powder is diffused, the cooling block 6021 cannot be effectively isolated, the cooling air emitted from the cooling block 6021 overflows, and the temperature of the memory metal rope 6019 is reduced to return to its initial state after contacting the cooling air, the oscillating plate 6022 is driven to move downwards, so that the oscillating plate 6022 is driven to move up and down, the flow of hot air is accelerated, and the heat dissipation effect is improved.
Referring to fig. 2 and 7, an adsorption sleeve 6016 is fixedly connected to one end of the elastic membrane 604 close to the electric energy control box 601, a plurality of collision beads 6017 are uniformly distributed inside the adsorption sleeve 6016, a plurality of ultrafine fibers 6018 are uniformly distributed and fixedly connected to one end of the adsorption sleeve 6016 close to the electric energy control box 601, the collision beads 6017 inside the adsorption sleeve 6016 are driven by the movement of the elastic membrane 604 to move, and collide with each other to generate static electricity, so that dust adhered to the surface of the electric energy control box 601 due to high temperature is adsorbed and cleaned by the electrostatic adsorption capacity, and is adhered to the ultrafine fibers 6018, thereby enhancing the dust removal effect.
Referring to fig. 4, the shape-memory balloon 608 is made of a shape-memory polymer material, the initial state of the shape-memory balloon 608 is a contracted state, the shape-memory balloon 608 made of the shape-memory polymer material has a one-way memory effect, deforms and expands after the temperature rises, and returns to its initial state after the temperature drops, the magnetism-insulating powder is made of a Fe-Ni alloy material, the content of Ni in the magnetism-insulating powder is 80%, and the magnetism of the magnetic ball 609 can be shielded in a dense state by using the magnetism-insulating powder made of the Fe-Ni alloy material.
Referring to fig. 3 and 7, the thermal insulation powder is made of thermal insulation cotton, the memory metal rope 6019 is made of shape memory alloy, the initial state of the memory metal rope 6019 is a stretched state, the magnetic influence of the cooling block 6021 can be isolated in a dense state by using the thermal insulation powder made of the thermal insulation cotton, the shape memory alloy has a memory function, the memory metal rope 6019 deforms and contracts with the increase of temperature, and returns to its initial extended state with the decrease of temperature, the collision small balls 6017 are made of chemical fiber material, the collision small balls 6017 are hollow, static electricity can be generated during mutual collision and friction by using the collision small balls 6017 made of the chemical fiber material, dust is adsorbed, and the weight of the collision small balls 6017 can be effectively reduced by setting the collision small balls 6017 to be hollow, so that the collision small balls 6017 are easy to move.
In the invention, when a relevant technician uses the device, firstly, in the working process of the electric energy control electric box 601, released heat is transmitted to the interior of the electric energy control electric box 603 through the heat pipe to absorb cooling water, the cooling water is heated and vaporized to form water vapor which flows upwards, the elastic membrane 604 is driven to move by matching with the thermal expansion of gas, the elastic membrane 604 drives the shifting rod 607 to move through the connecting rope 606 to flow the cooling water so as to accelerate the absorption of the cooling water on heat, the deformation memory balloon 608 is heated and expanded along with the upward flow of hot air to drive the magnetism-insulating powder to diffuse, the magnetic ball 609 cancels the magnetic shielding state to attract the magnetic fluid 6012 to approach the sliding ring 6011 to slide towards the magnetic ball 609 to drive the shifting screen 6013 to move, so as to realize the shifting dispersion of ammonium chloride powder, accelerate the reaction of the ammonium chloride powder, decompose the hydrogen gas by heating to generate chlorine and chlorine gas, and absorb heat, the temperature is reduced, the water vapor flows upwards to the top end in the heat pipe 603, the heat is absorbed along with the decomposition of the ammonium chloride powder, the temperature at the upper end of the heat pipe 603 is reduced, the water vapor is condensed into water drops again and drops down, the cyclic utilization is realized, the heat released by the electric energy control electric box 601 is absorbed, the temperature is reduced, along with the conduction of the heat, the memory metal rope 6019 is heated to contract, the swinging plate 6022 is pulled to move upwards, the elastic ball 6020 is deformed, the heat insulation powder is diffused, the cooling block 6021 cannot be effectively isolated, the cold air diffused by the cooling block 6021 overflows, the temperature of the memory metal rope 6019 is reduced after contacting the cold air, the initial state is recovered, the swinging plate 6022 is driven to move downwards, the swinging plate 6022 is driven to move upwards and downwards, the flow of the hot air is accelerated, the heat dissipation effect is improved, and the movement of the elastic membrane 604 drives the collision small ball 6017 in the adsorption sleeve 6016 to move, the mutual collision friction produces static electricity, adsorbs the clearance to the dust because of high temperature is stained with on electric energy management and control electronic box 601 surface through electrostatic adsorption ability, makes it be stained with and attaches at superfine fibre 6018, reinforcing dust removal effect.
The above; but are merely preferred embodiments of the invention; the scope of the invention is not limited thereto; any person skilled in the art is within the technical scope of the present disclosure; the technical scheme and the improved concept of the invention are equally replaced or changed; are intended to be covered by the scope of the present invention.
Claims (9)
1. The utility model provides a chlorinated paraffin environmental protection production system, includes tertiary absorption system of tail gas (1), its characterized in that: a four-stage packed tower (101) is arranged in the tail gas tertiary absorption system (1), a degassing kettle (102) is arranged in the tail gas tertiary absorption system (1), a tail gas main pipe (103) is arranged in the tail gas tertiary absorption system (1), a glass steel pipe (104) is arranged in the tail gas tertiary absorption system (1), the glass steel pipe (104) is respectively communicated with the degassing kettle (102) and the tail gas main pipe (103), a tail gas alkali tower (105) is arranged in the tail gas tertiary absorption system (1), the tail gas tertiary absorption system (1) is in signal connection with a tail gas treatment system (2), an oil spraying absorption system (3) is in signal connection with the tail gas treatment system (2), an online PH detection and alarm system (4) is in signal connection with the tail gas treatment system (2), and an environmental protection online electric energy monitoring system (6) is in signal connection with the outer end of the online PH detection and alarm system (4), the outer end signal connection of online electric energy monitored control system of environmental protection (6) has tail gas on-line monitored control system (5), the outer end signal connection of degasification cauldron (102) has safety instrument system (9), the right side of the tertiary absorption system of tail gas (1) is equipped with tank field (7), be equipped with hydrochloric acid tank field volatile hydrogen chloride resorption system (8) in tank field (7).
2. The environmental-friendly chlorinated paraffin production system according to claim 1, characterized in that: an electric energy control electric box (601) is arranged in the environment-friendly online electric energy monitoring system (6), a heat dissipation frame (602) is fixedly connected to the upper end of the electric energy control electric box (601), a plurality of heat conduction pipes (603) which are uniformly distributed are fixedly connected between the electric energy control electric box (601) and the heat dissipation frame (602), cooling water is filled in the heat conduction pipes (603), a through hole is formed in one end, close to the electric energy control electric box (601), of each heat conduction pipe (603), an elastic film (604) is fixedly connected between the inner walls of the through holes, a connecting ball (605) is fixedly connected to one end, far away from the electric energy control electric box (601), of each elastic film (604), a poking rod (607) is arranged at the inner bottom end of each heat conduction pipe (603), the poking rod (607) is located in the cooling water, and a connecting rope (606) is fixedly connected between each poking rod (607) and the connecting ball (605), the interior of heat dissipation frame (602) is filled with ammonium chloride powder, the inside of heat dissipation frame (602) is equipped with dials scattered mechanism.
3. The environmental-friendly chlorinated paraffin production system according to claim 2, characterized in that: the poking and scattering mechanism comprises a deformation memory balloon (608), the outer end of the deformation memory balloon (608) is fixedly connected with the inner wall of the heat dissipation frame (602), the inside of the shape-changing memory balloon (608) is fixedly connected with a magnetic ball (609), the inside of the shape-changing memory balloon (608) is filled with nonmagnetic powder, two L-shaped rods (6010) which are symmetrical left and right are fixedly connected between the inner walls of the heat dissipation frame (602), a sliding ring (6011) is sleeved at the outer end of each L-shaped rod (6010), and the sliding ring (6011) is connected with the L-shaped rod (6010) in a sliding way, an elastic rope (6014) is fixedly connected between the sliding ring (6011) and the L-shaped rod (6010), the magnetic fluid (6012) is filled in the sliding ring (6011), the outer end of the sliding ring (6011) is fixedly connected with two vertical symmetric straight plates (6015), and one ends, far away from each other, of the two straight plates (6015) are fixedly connected with two bilateral symmetric shifting screens (6013).
4. The environmental-friendly chlorinated paraffin production system according to claim 2, characterized in that: the inner bottom end of the electric energy control box (601) is fixedly connected with two bilaterally symmetrical elastic balloons (6020), the cooling block (6021) is fixedly connected to the inside of the elastic balloons (6020), heat insulation powder is filled in the elastic balloons (6020), a memory metal rope (6019) is fixedly connected between the upper end of the elastic balloons (6020) and the lower end of the heat dissipation frame (602), one end, far away from the electric energy control box (601), of the heat conduction pipe (603) is rotatably connected with a plurality of uniformly distributed swing plates (6022), and the memory metal rope (6019) is fixedly connected with the swing plates (6022).
5. The environmental-friendly chlorinated paraffin production system according to claim 2, characterized in that: one end fixedly connected with of elasticity membrane (604) near electric energy management and control electronic box (601) adsorbs cover (6016), the inside of adsorbing cover (6016) is equipped with a plurality of evenly distributed's collision bobble (6017), adsorb cover (6016) and be close to electric energy management and control electronic box (601) one end fixedly connected with a plurality of evenly distributed's superfine fiber (6018).
6. The environmental-friendly chlorinated paraffin production system according to claim 3, characterized in that: the shape-changing memory balloon (608) is made of shape-changing memory polymer materials, and the initial state of the shape-changing memory balloon (608) is a contraction state.
7. The environmental-friendly chlorinated paraffin production system according to claim 3, characterized in that: the magnetic isolation powder is made of Fe-Ni alloy materials, and the content of Ni in the magnetic isolation powder is 80%.
8. The environmental-friendly chlorinated paraffin production system according to claim 4, wherein: the heat insulation powder is made of a heat insulation cotton material, the memory metal rope (6019) is made of a shape memory alloy material, and the initial state of the memory metal rope (6019) is a stretching state.
9. The environmental-friendly chlorinated paraffin production system according to claim 5, wherein: the collision small ball (6017) is made of chemical fiber materials, and the collision small ball (6017) is arranged in a hollow mode.
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