CN113860337A - 硫酸法锂盐生产的尾气综合处理工艺方法 - Google Patents
硫酸法锂盐生产的尾气综合处理工艺方法 Download PDFInfo
- Publication number
- CN113860337A CN113860337A CN202111198547.3A CN202111198547A CN113860337A CN 113860337 A CN113860337 A CN 113860337A CN 202111198547 A CN202111198547 A CN 202111198547A CN 113860337 A CN113860337 A CN 113860337A
- Authority
- CN
- China
- Prior art keywords
- tail gas
- roasting
- gas generated
- sulfuric acid
- acidification
- Prior art date
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- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 77
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910003002 lithium salt Inorganic materials 0.000 title claims abstract description 20
- 159000000002 lithium salts Chemical class 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 230000020477 pH reduction Effects 0.000 claims abstract description 40
- 238000002485 combustion reaction Methods 0.000 claims abstract description 8
- 239000000428 dust Substances 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 10
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- 239000012141 concentrate Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 230000009466 transformation Effects 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 74
- 239000000463 material Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 10
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 238000005201 scrubbing Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 238000000227 grinding Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/06—Sulfates; Sulfites
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D13/00—Apparatus for preheating charges; Arrangements for preheating charges
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/004—Systems for reclaiming waste heat
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
监测项目 | 监测值(三次监测均值)/(mg/m<sup>3</sup>) | 标准限值mg/m<sup>3</sup> |
颗粒物 | 5.8 | 30 |
二氧化硫 | 28 | 100 |
氮氧化物 | 86 | 200 |
监测项目 | 监测值(三次监测均值)/(mg/m<sup>3</sup>) | 标准限值mg/m<sup>3</sup> |
颗粒物 | 10.8 | 30 |
二氧化硫 | 32 | 100 |
氮氧化物 | 103 | 200 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111198547.3A CN113860337B (zh) | 2021-10-14 | 2021-10-14 | 硫酸法锂盐生产的尾气综合处理工艺方法 |
Applications Claiming Priority (1)
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CN202111198547.3A CN113860337B (zh) | 2021-10-14 | 2021-10-14 | 硫酸法锂盐生产的尾气综合处理工艺方法 |
Publications (2)
Publication Number | Publication Date |
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CN113860337A true CN113860337A (zh) | 2021-12-31 |
CN113860337B CN113860337B (zh) | 2023-06-27 |
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CN202111198547.3A Active CN113860337B (zh) | 2021-10-14 | 2021-10-14 | 硫酸法锂盐生产的尾气综合处理工艺方法 |
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CN (1) | CN113860337B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115282759A (zh) * | 2022-07-28 | 2022-11-04 | 中国恩菲工程技术有限公司 | 酸化焙烧烟气处理方法及系统 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1246235A (fr) * | 1958-08-11 | 1960-11-18 | Le Ministere Des Mines | Procédé cyclique pour récupérer des sels de lithium |
CN102874850A (zh) * | 2012-10-25 | 2013-01-16 | 西安三瑞实业有限公司 | 一种用外热式回转炉进行锂矿石酸化焙烧系统及焙烧方法 |
CN106011457A (zh) * | 2016-07-15 | 2016-10-12 | 甘肃酒钢集团宏兴钢铁股份有限公司 | 一种难选铁矿石粉磁化焙烧系统及工艺 |
CN106966411A (zh) * | 2017-04-20 | 2017-07-21 | 中国恩菲工程技术有限公司 | 处理锂辉石的方法 |
CN111664716A (zh) * | 2020-04-10 | 2020-09-15 | 安徽迪诺环保新材料科技有限公司 | 一种硫酸法钛白生产煅烧尾气余热利用的方法 |
CN112325312A (zh) * | 2020-10-21 | 2021-02-05 | 昆明理工大学 | 碳酸盐矿热解减排co工业尾气中酸性有害气体的方法及装置 |
CN113028827A (zh) * | 2021-04-29 | 2021-06-25 | 洛阳申特工程技术有限公司 | 一种锂辉石煅烧转化装置的操作方法 |
-
2021
- 2021-10-14 CN CN202111198547.3A patent/CN113860337B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1246235A (fr) * | 1958-08-11 | 1960-11-18 | Le Ministere Des Mines | Procédé cyclique pour récupérer des sels de lithium |
CN102874850A (zh) * | 2012-10-25 | 2013-01-16 | 西安三瑞实业有限公司 | 一种用外热式回转炉进行锂矿石酸化焙烧系统及焙烧方法 |
CN106011457A (zh) * | 2016-07-15 | 2016-10-12 | 甘肃酒钢集团宏兴钢铁股份有限公司 | 一种难选铁矿石粉磁化焙烧系统及工艺 |
CN106966411A (zh) * | 2017-04-20 | 2017-07-21 | 中国恩菲工程技术有限公司 | 处理锂辉石的方法 |
CN111664716A (zh) * | 2020-04-10 | 2020-09-15 | 安徽迪诺环保新材料科技有限公司 | 一种硫酸法钛白生产煅烧尾气余热利用的方法 |
CN112325312A (zh) * | 2020-10-21 | 2021-02-05 | 昆明理工大学 | 碳酸盐矿热解减排co工业尾气中酸性有害气体的方法及装置 |
CN113028827A (zh) * | 2021-04-29 | 2021-06-25 | 洛阳申特工程技术有限公司 | 一种锂辉石煅烧转化装置的操作方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115282759A (zh) * | 2022-07-28 | 2022-11-04 | 中国恩菲工程技术有限公司 | 酸化焙烧烟气处理方法及系统 |
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CB03 | Change of inventor or designer information |
Inventor after: Du Mingze Inventor after: Zhang Bingyuan Inventor after: Fan Yonglan Inventor after: Tu Mingjiang Inventor after: Li Longjun Inventor after: Wang Rong Inventor after: Zhao Jin Inventor after: Liang Shan Inventor before: Du Mingze Inventor before: Zhang Bingyuan Inventor before: Tu Mingjiang Inventor before: Li Longjun Inventor before: Wang Rong Inventor before: Zhao Jin Inventor before: Liang Shan |
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