CN113832743A - High-temperature disperse dye ink - Google Patents
High-temperature disperse dye ink Download PDFInfo
- Publication number
- CN113832743A CN113832743A CN202111351761.8A CN202111351761A CN113832743A CN 113832743 A CN113832743 A CN 113832743A CN 202111351761 A CN202111351761 A CN 202111351761A CN 113832743 A CN113832743 A CN 113832743A
- Authority
- CN
- China
- Prior art keywords
- disperse dye
- temperature disperse
- percent
- high temperature
- boiling point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000986 disperse dye Substances 0.000 title claims abstract description 51
- 239000002904 solvent Substances 0.000 claims abstract description 56
- 238000009835 boiling Methods 0.000 claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 230000000149 penetrating effect Effects 0.000 claims abstract description 9
- 238000007639 printing Methods 0.000 claims description 28
- 239000004094 surface-active agent Substances 0.000 claims description 19
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 10
- 230000003115 biocidal effect Effects 0.000 claims description 10
- 239000003139 biocide Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 239000003899 bactericide agent Substances 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- -1 acetylene glycol Chemical compound 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000001045 blue dye Substances 0.000 claims description 4
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 claims description 4
- 239000001044 red dye Substances 0.000 claims description 4
- 239000001043 yellow dye Substances 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 3
- 229940093476 ethylene glycol Drugs 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 3
- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 235000013772 propylene glycol Nutrition 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000013508 migration Methods 0.000 abstract description 11
- 230000005012 migration Effects 0.000 abstract description 11
- 230000014759 maintenance of location Effects 0.000 abstract description 7
- 239000000976 ink Substances 0.000 description 68
- 239000000203 mixture Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 239000002357 osmotic agent Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- 230000002070 germicidal effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000213951 Salmonella enterica subsp. enterica serovar Austin Species 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- OXLITIGRBOEDEZ-UHFFFAOYSA-N 1,5-diamino-4,8-dihydroxy-2-(4-hydroxyphenyl)anthracene-9,10-dione Chemical compound C=1C(O)=C2C(=O)C=3C(N)=CC=C(O)C=3C(=O)C2=C(N)C=1C1=CC=C(O)C=C1 OXLITIGRBOEDEZ-UHFFFAOYSA-N 0.000 description 1
- MUERWWKQVXXPML-UHFFFAOYSA-N 3-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound ClC1=CC([N+](=O)[O-])=CC(Cl)=C1N=NC1=CC=C(N(CCC#N)CCC#N)C=C1 MUERWWKQVXXPML-UHFFFAOYSA-N 0.000 description 1
- ZCMWRFQVYXHUQN-UHFFFAOYSA-N 4,11-diamino-1-imino-2-(3-methoxypropyl)naphtho[2,3-f]isoindole-3,5,10-trione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(C(N(CCCOC)C1=N)=O)C1=C2N ZCMWRFQVYXHUQN-UHFFFAOYSA-N 0.000 description 1
- YMCIVAPEOZDEGH-UHFFFAOYSA-N 5-chloro-2,3-dihydro-1h-indole Chemical compound ClC1=CC=C2NCCC2=C1 YMCIVAPEOZDEGH-UHFFFAOYSA-N 0.000 description 1
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- XREZMAAQVYVESP-UHFFFAOYSA-N acetyloxymethyl 2-[n-[2-(acetyloxymethoxy)-2-oxoethyl]-2-[2-[2-[bis[2-(acetyloxymethoxy)-2-oxoethyl]amino]-4-fluorophenoxy]ethoxy]-5-fluoroanilino]acetate Chemical compound CC(=O)OCOC(=O)CN(CC(=O)OCOC(C)=O)C1=CC(F)=CC=C1OCCOC1=CC=C(F)C=C1N(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O XREZMAAQVYVESP-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LEGWLJGBFZBZSC-UHFFFAOYSA-N n-[2-[(2,6-dicyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(C#N)C=C([N+]([O-])=O)C=C1C#N LEGWLJGBFZBZSC-UHFFFAOYSA-N 0.000 description 1
- IGUCIQQRHZUQKG-UHFFFAOYSA-N n-[2-[(2-bromo-6-cyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]propanamide Chemical compound CCC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(Br)C=C([N+]([O-])=O)C=C1C#N IGUCIQQRHZUQKG-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
- D06P1/928—Solvents other than hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The application relates to high-temperature disperse dye ink which comprises the following components in parts by weight: 20 to 50 percent of disperse dye, 10 to 30 percent of high boiling point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low boiling point solvent with the boiling point lower than 200 ℃, 0.05 to 5 percent of penetrating agent and the balance of water. The application provides high-temperature disperse dye ink, adopts reasonable ink formula, has excellent moisture retention and fluency, can improve the stability of printed products, and is not easy to generate color migration at high temperature.
Description
Technical Field
The present application relates to the field of printing technology, and in particular, to high temperature disperse dye inks.
Background
At present, the industry begins to change from extensive type to fine management, more manufacturers concentrate on the research and development of printing ink and equipment, and develop a digital textile printing technology with low pollution, low energy consumption, high precision and personalized customization. With continuous innovation of industrial piezoelectric type spray heads, eight-head and sixteen-head high-temperature disperse dye high-speed digital printing machines are continuously developed in the market, and direct-injection printing becomes a development trend.
However, in long-distance transportation of the current printing, the printing is in a high environment and room temperature for a long time, the cloth or the ready-made clothes are easy to be stained, secondary color migration occurs, the loss of finished fabrics is caused, the permeability of the ink is low, and the stability and the durability are still to be improved.
Disclosure of Invention
In view of this, the application provides high-temperature disperse dye ink, adopts reasonable ink formula, has excellent moisture retention and fluency, can improve the stability of printed products, and is not easy to cause color migration at high temperature.
In a first aspect, an embodiment of the present application provides a high temperature disperse dye ink, which includes the following components in parts by weight: 20 to 50 percent of high-temperature disperse dye, 10 to 30 percent of high-boiling-point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low-boiling-point solvent with the boiling point lower than 200 ℃, 0.05 to 5 percent of penetrating agent and the balance of water.
In one possible embodiment, the high temperature disperse dye ink comprises the following components in parts by weight: 20 to 50 percent of high-temperature disperse dye, 10 to 30 percent of high-boiling-point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low-boiling-point solvent with the boiling point lower than 200 ℃, 0.5 to 3 percent of penetrating agent, 0.05 to 5 percent of surfactant, 0.2 to 0.4 percent of bactericide and the balance of water.
In one possible embodiment, the high temperature disperse dye includes at least one of a high temperature disperse blue dye, a high temperature disperse red dye, and a high temperature disperse yellow dye.
In one possible embodiment, the high boiling point solvent includes at least one of glycerol, triethylene glycol, diethylene glycol, 1,5 pentanediol, ethylene glycol, and 1,2 propanediol.
In one possible embodiment, the low boiling point solvent includes at least one of n-propanol, isopropanol, and ethanol.
In one possible embodiment, the weight ratio of the high boiling point solvent to the low boiling point solvent is 1: (1-4).
In one possible embodiment, the biocide comprises at least one of the U.S. Dow biocide BIOBAN BIT-10, the U.S. Dow biocide BIOBAN BIT-20, the U.S. Austin biocide PROXEL GXL, and the U.S. Austin biocide PROXEL CMG.
In one possible embodiment, the surfactant includes at least one of an acetylene glycol-based surfactant and a silicone-based surfactant.
In one possible embodiment, the acetylenic diol surfactant includes at least one of SURFYNOL 104E, SURFYNOL 420, SURFYNOL 465; the silicone surfactant comprises at least one of DYNOL 960, DYNOL 980, BYK-346, BYK-348, and EFKA-3580.
In one possible embodiment, the osmotic agent includes at least one of the group consisting of the Pulsatil WT 100 and the osmotic agent T-50.
The application also provides an application of the high-temperature disperse dye ink in digital printing.
Has the advantages that:
the application provides an ink adds penetrant, high boiling point solvent and low boiling point solvent in the ink system, can improve the high temperature resistance of whole high temperature disperse dye ink for high temperature disperse dye ink has excellent moisture retention, smoothness nature, is difficult to block up and beats printer head, and the high temperature is difficult for taking place the color migration. Moreover, the application medium range of the ink is wide, the permeability is good after printing, the yarn turning and the white exposure are not easy, and the stability of a printed product can be improved.
Detailed Description
While the following is a preferred embodiment of the embodiments of the present application, it should be noted that those skilled in the art can make various improvements and modifications without departing from the principle of the embodiments of the present application, and such improvements and modifications are also considered to be within the scope of the embodiments of the present application.
In a first aspect, the present application provides a high temperature disperse dye ink, comprising the following components by weight: 20 to 50 percent of high-temperature disperse dye, 10 to 30 percent of high-boiling-point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low-boiling-point solvent with the boiling point lower than 200 ℃, 0.05 to 5 percent of penetrating agent and the balance of water.
The application provides a high temperature disperse dye ink adds penetrant, high boiling point solvent and low boiling point solvent in the ink system, can improve the high temperature resistance of whole dye ink for dye ink has excellent moisture retention, smoothness nature, is difficult to block up and beats printer head, and the high temperature is difficult for taking place the color migration. Moreover, the application medium range of the ink is wide, the permeability is good after printing, the yarn turning and the white exposure are not easy, and the stability of a printed product can be improved.
The disperse dye comprises at least one of high-temperature disperse blue dye, high-temperature disperse red dye and high-temperature disperse yellow dye. The disperse dye can be suspended in an ink system better, so that the system is uniform and does not precipitate.
Wherein, the high-temperature disperse blue dye: disperse blue 60, disperse blue 73, disperse blue 79, disperse blue 87, disperse blue 115, disperse blue 165, disperse blue 183, disperse blue 354 and disperse blue 366.
High temperature disperse red dye: at least one of dispersed red 33, dispersed red 54, dispersed red 74, dispersed red 92, dispersed red 152, dispersed red 153, dispersed red 167, dispersed red 177, dispersed red 179, and dispersed red 343.
High-temperature disperse yellow dye: at least one of disperse yellow 30, disperse yellow 44, disperse yellow 73, disperse yellow 114, disperse yellow 118, disperse yellow 119, disperse yellow 134, disperse yellow 163, and disperse yellow 211.
Further, the weight ratio of the high temperature disperse dye in the high temperature disperse dye ink may be specifically 20%, 22%, 25%, 28%, 30%, 32%, 35%, 40%, 45%, 50%, or the like, but is not limited to the enumerated values, and other values not enumerated within the numerical range are also applicable.
Optionally, the high boiling point solvent comprises at least one of glycerol, triethylene glycol, diethylene glycol, 1,5 pentanediol, ethylene glycol, 1,2 propanediol. It is understood that the high boiling point solvent may be obtained by mixing one or more high boiling point solvents, and the ratio of the high boiling point solvents is not limited as long as the total weight ratio of the high boiling point ink in the high temperature disperse dye ink system is controlled. The weight ratio of the high-boiling solvent in the high-temperature disperse dye ink may be, for example, 10%, 12%, 15%, 17%, 19%, 20%, 25%, 28%, or 30%, but is not limited to the above-mentioned values, and other values not shown in the above-mentioned range are also applicable.
The boiling point of the solvent is a boiling point at normal pressure.
Optionally, the low boiling point solvent comprises at least one of n-propanol, isopropanol, ethanol. It is understood that the low-boiling point solvent can be obtained by mixing one or more low-boiling point solvents, and the ratio of the low-boiling point solvents is not limited as long as the total weight ratio of the low-boiling point ink in the high-temperature disperse dye ink system is controlled. The weight ratio of the low-boiling solvent in the high-temperature disperse dye ink may be specifically 5%, 5.5%, 6%, 7%, 8%, 9%, 10%, or the like, but is not limited to the recited values, and other values not recited in the numerical range are also applicable.
Optionally, the weight ratio of the high boiling point solvent to the low boiling point solvent is 1: (1 to 4) specifically include 1:1, 1:1.5, 1:1.8, 1:2, 1:2.5, 1:3, 1:3.5, 1:4, etc., but the numerical values are not limited to the enumerated values, and other numerical values not enumerated within the numerical range are also applicable.
Optionally, the osmotic agent comprises at least one of Pulsatil WT 100 and osmotic agent T-50. The weight ratio of the penetrant in the high-temperature disperse dye ink may be specifically 0.05%, 0.08%, 0.09%, 0.1%, 0.2%, 0.45%, 0.5%, 1%, 2%, 3%, 4%, or 5%, but is not limited to the recited values, and other values not recited in the above range are also applicable. The Pulsatil WT 100 comprises isooctanol polyoxyethylene polyoxypropylene ether, and the osmotic agent T-50 comprises diisooctyl maleate sulfonate. Preferably, the weight ratio of the penetrating agent in the high-temperature disperse dye ink is 0.5-3%, and the penetrating agent is penetrating agent T-50.
Further, the high-temperature disperse dye ink also comprises the following components in percentage by weight: 0.05-5% of surfactant and 0.2-0.4% of bactericide.
The surfactant includes at least one of an acetylene glycol surfactant and a silicone surfactant. The acetylenic diol surfactant comprises at least one of SURFYNOL 104E, SURFYNOL 420, SURFYNOL 440, and SURFYNOL 465, and the silicone surfactant comprises DYNOL 960 and DYNOL 980; at least one of BYK-346, BYK-348 and EFKA-3580. The addition of the surfactant can reduce the surface tension of the ink, so that the ink has excellent printing fluency on printing equipment.
The inventor finds through experiments that the surfactant is preferably a combination of SURFYNOL 465 and BYK-346, so that the ink has the most excellent moisture retention and fluency, and is not easy to block a printing head.
The weight ratio of the surfactant in the high-temperature disperse dye ink may be specifically 0.05%, 0.08%, 0.09%, 0.1%, 0.2%, 0.45%, 0.5%, 1%, 2%, 3%, 4%, or 5%, but is not limited to the enumerated values, and other values not enumerated within the numerical range are also applicable.
The bactericide comprises at least one of American Dow bactericide BIOBAN BIT-10, American Dow bactericide BIOBAN BIT-20, American Aocon bactericide PROXEL GXL and American Aocon bactericide PROXEL CMG. In a particular embodiment, the germicide may be PROXEL GXL. In other embodiments, the germicide may be other types of germicides, and is not limited herein.
The weight ratio of the bactericide in the high-temperature disperse dye ink may be specifically 0.2%, 0.25%, 0.28%, 0.32%, 0.38%, 0.4%, or the like, but is not limited to the enumerated values, and other values not enumerated within the numerical range are also applicable.
In this embodiment, the balance of the water may be at least one of tap water, deionized water, and distilled water, and preferably, the water is deionized water, so that impurities in the slurry can be reduced, and the influence on other components in the ink can also be reduced.
In a second aspect, the present application provides the use of a high temperature disperse dye ink in digital printing.
In some embodiments, the application medium may be polyester cloth, blankets, shoe material, chiffon, sportswear, curtains, or the like. The printing permeability is good, the migration performance is excellent, secondary color migration cannot occur during container transportation and color development batching, yarn turning and white exposure are not easy to occur, the loss of finished fabric cannot be caused, and the stability of a printed finished product can be improved. In addition, the high-temperature disperse dye ink has excellent fluency and compatibility, so that the service life of the printing nozzle can be further prolonged compared with other inks.
The examples of the present application are further illustrated below in various examples. The present embodiments are not limited to the following specific examples. The present invention can be modified as appropriate within the scope of protection.
It should be noted that the percentages of the components mentioned above and below in the present application are mass percentages, and all the percentages are percentages of the components in the total mass of the pigment ink except for those specifically mentioned.
1. Preparation of high-temperature disperse dye ink
As shown in Table 1 below, examples 1-4 and comparative examples 1-4 comprised black, blue, red, yellow inks formulated according to the mass percent compositions shown in Table 1 below. The specific formulation is shown in table 1:
TABLE 1
The "/" in the above table indicates no addition.
2. Performance testing
The high temperature disperse dye inks prepared in the above table 1 were respectively subjected to performance tests, and the corresponding test results are shown in the following tables 2 and 3:
TABLE 2 summary of the test results of the examples
TABLE 3 summary of comparative test results
As can be seen from the above table 2 and table 3, in the examples 1-4, the high boiling point solvent and the low boiling point solvent are added to the ink formulations of different colors, and the inks of the examples 1-4 not only have good moisture retention, but also can effectively improve the printing smoothness of the inks; under the coordination of penetrant, no secondary migration exists in the pressing test, and the phenomenon of printing head blockage can not occur after the test is standby for 7 days. And the stability of the ink after printing is good, and the bad phenomena of yarn turning and white exposure can not occur when the ink is printed on textile fabrics.
The ink formula of the comparative example 1 is not added with a penetrant, the ink permeability of the comparative example 1 is reduced, and compared with the ink formula of the examples 1-4, the defects of yarn turning and white exposure appear when the ink is printed on textiles.
In the ink formulation of comparative example 2, the solvent is not added with the low boiling point solvent, but is composed of the high boiling point solvent, and since the drying speed of the high boiling point solvent is reduced in the printing process, the heater power needs to be increased, although the ink formulation has no secondary migration phenomenon after printing and good stability, the ink formulation affects the fluency and the standby performance.
In the ink formula of the comparative example 3, the solvent is not added with the high-boiling-point solvent, and is composed of the low-boiling-point solvent, and the low-boiling-point solvent is easy to volatilize in the using process, so that the printing smoothness of the ink is reduced, and the phenomenon of blockage of the printing head can occur after the ink is standby for 30 minutes, so that the ink is inconvenient to use.
In the ink formulation of comparative example 4, the ratio of the solvent low-boiling point solvent to the solvent high-boiling point solvent is 1:8, and since the amount of the low-boiling point solvent is low and the amount of the solvent high-boiling point solvent is high, the drying speed is reduced in the printing process, the heater power needs to be increased, and although the ink formulation has no secondary migration phenomenon after printing and is good in stability, the ink formulation is easy to dry, and the printing effect and the standby performance are affected.
The application provides a high temperature disperse dye ink, through improving the formula system, add penetrant and high boiling point solvent, low boiling point solvent in the ink, can improve the high temperature resistance of whole dye ink for dye ink has excellent moisture retention, smoothness nature, is difficult to block up and beats printer head, and the high temperature is difficult for taking place the color migration. Moreover, the application medium range of the ink is wide, the permeability is good after printing, the yarn turning and the white exposure are not easy, and the stability of a printed product can be improved.
Although the present application has been described with reference to preferred embodiments, it is not intended to limit the scope of the claims, and many possible variations and modifications may be made by one skilled in the art without departing from the spirit of the application.
Claims (10)
1. The high-temperature disperse dye ink is characterized by comprising the following components in parts by weight: 20 to 50 percent of high-temperature disperse dye, 10 to 30 percent of high-boiling-point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low-boiling-point solvent with the boiling point lower than 200 ℃, 0.05 to 5 percent of penetrating agent and the balance of water.
2. The high temperature disperse dye ink according to claim 1, wherein the high temperature disperse dye ink comprises the following components in parts by weight: 20 to 50 percent of high-temperature disperse dye, 10 to 30 percent of high-boiling-point solvent with the boiling point higher than or equal to 200 ℃,5 to 10 percent of low-boiling-point solvent with the boiling point lower than 200 ℃, 0.5 to 3 percent of penetrating agent, 0.05 to 5 percent of surfactant, 0.2 to 0.4 percent of bactericide and the balance of water.
3. The high temperature disperse dye ink according to claim 1 or 2, wherein the high temperature disperse dye comprises at least one of a high temperature disperse blue dye, a high temperature disperse red dye, and a high temperature disperse yellow dye.
4. The high temperature disperse dye ink according to claim 1 or 2, wherein the high boiling point solvent comprises at least one of glycerol, triethylene glycol, diethylene glycol, 1,5 pentanediol, ethylene glycol, 1,2 propanediol.
5. The high temperature disperse dye ink according to claim 1 or 2, wherein the low boiling point solvent comprises at least one of n-propanol, isopropanol, and ethanol.
6. The high temperature disperse dye ink according to claim 1 or 2, wherein the weight ratio of the high boiling point solvent to the low boiling point solvent is 1: (1-4).
7. The high temperature disperse dye ink of claim 2, wherein the biocide comprises at least one of the U.S. dow biocide BIOBAN BIT-10, the U.S. dow biocide BIOBAN BIT-20, the U.S. ao Lin biocide PROXEL GXL, and the U.S. ao Lin biocide PROXEL CMG.
8. The high temperature disperse dye ink according to claim 2, wherein the surfactant comprises at least one of an acetylene glycol surfactant and a silicone surfactant.
9. A high temperature disperse dye ink according to claim 1 or 2, wherein the penetrant comprises at least one of the group consisting of a spear lucamul WT 100 and a penetrant T-50.
10. Use of a high temperature disperse dye ink according to any one of claims 1 to 9 in digital printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111351761.8A CN113832743A (en) | 2021-11-16 | 2021-11-16 | High-temperature disperse dye ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111351761.8A CN113832743A (en) | 2021-11-16 | 2021-11-16 | High-temperature disperse dye ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113832743A true CN113832743A (en) | 2021-12-24 |
Family
ID=78971237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111351761.8A Pending CN113832743A (en) | 2021-11-16 | 2021-11-16 | High-temperature disperse dye ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113832743A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115323810A (en) * | 2022-08-26 | 2022-11-11 | 珠海天威新材料股份有限公司 | Fabric printing pretreatment liquid and fabric printing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106087477A (en) * | 2016-06-20 | 2016-11-09 | 常州大学 | A kind of textile inkjet printing reactive dye ink and preparation method thereof |
| CN107254784A (en) * | 2017-07-03 | 2017-10-17 | 上海安诺其数码科技有限公司 | A kind of high temperature direct-injection dispersible ink and preparation method thereof |
| CN109810560A (en) * | 2019-01-16 | 2019-05-28 | 深圳市墨库图文技术有限公司 | A kind of ink-jet ink and preparation method thereof suitable for photo printing |
| CN111235909A (en) * | 2020-03-13 | 2020-06-05 | 珠海纳思达企业管理有限公司 | Thermal sublimation ink and preparation method and application thereof |
-
2021
- 2021-11-16 CN CN202111351761.8A patent/CN113832743A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106087477A (en) * | 2016-06-20 | 2016-11-09 | 常州大学 | A kind of textile inkjet printing reactive dye ink and preparation method thereof |
| CN107254784A (en) * | 2017-07-03 | 2017-10-17 | 上海安诺其数码科技有限公司 | A kind of high temperature direct-injection dispersible ink and preparation method thereof |
| CN109810560A (en) * | 2019-01-16 | 2019-05-28 | 深圳市墨库图文技术有限公司 | A kind of ink-jet ink and preparation method thereof suitable for photo printing |
| CN111235909A (en) * | 2020-03-13 | 2020-06-05 | 珠海纳思达企业管理有限公司 | Thermal sublimation ink and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张伟等: "喷墨印花墨水及其发展" * |
| 胡木升: "灯芯绒圆网印花坑底露白疵病的分析及防止" * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115323810A (en) * | 2022-08-26 | 2022-11-11 | 珠海天威新材料股份有限公司 | Fabric printing pretreatment liquid and fabric printing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI661009B (en) | Disperse dye mixtures, their preparation and use | |
| CN108624125B (en) | Environment-friendly water-based bi-component nylon screen printing ink and use method thereof | |
| WO2014129323A1 (en) | Ink for ink jet printing and staining method | |
| JP6665286B2 (en) | Fiber-based aqueous transfer ink for ink jet printer and fiber transfer paper for applying the same | |
| CN111087852A (en) | Ink-jet printing ink containing disperse dye and reactive dye and application thereof | |
| JP5851417B2 (en) | Disperse dye and method for dyeing hydrophobic fiber material using the same | |
| CN110373043A (en) | It is a kind of blue to black disperse dye composition and dye preparations | |
| JP4617914B2 (en) | Red disperse dye composition and application to hydrophobic fiber materials | |
| CN113832743A (en) | High-temperature disperse dye ink | |
| KR100555336B1 (en) | Ink for inkjet recording | |
| JP2009108151A (en) | Disperse dye composition and dyeing/printing method | |
| JP5955224B2 (en) | Disperse dye and method for dyeing hydrophobic fiber material using the same | |
| CN111235909B (en) | Thermal sublimation ink and preparation method and application thereof | |
| CN109853256A (en) | A kind of nylon fabric thermal transfer ink and preparation method thereof | |
| CN108727900A (en) | A kind of storage stability and the good disperse dye ink and preparation method of redispersibility | |
| JPS60229969A (en) | Ink for jet printing | |
| CN102079898B (en) | Digital jet ink and preparation method and application thereof | |
| TW202112977A (en) | Colored dispersion, recording medium, and method for printing hydrophobic fibers | |
| CN113914116B (en) | High-temperature direct-injection disperse dye ink and preparation method and application thereof | |
| CN115573177B (en) | High-temperature direct-injection antibacterial ink, digital printing direct-injection process and printing product | |
| CN112695547B (en) | Reactive dye ink suitable for high-speed ink-jet printing and preparation method thereof | |
| JP2006219616A (en) | Disperse dye composition and its application to hydrophobic fiber material | |
| JP7479342B2 (en) | Dye dispersion and method for printing hydrophobic fibers | |
| JP2018150410A (en) | Ink composition for inkjet printing and printing method of hydrophobic fiber | |
| JP2018150399A (en) | Ink composition for inkjet printing and printing method of hydrophobic fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211224 |
|
| RJ01 | Rejection of invention patent application after publication |