CN102079898B - Digital jet ink and preparation method and application thereof - Google Patents
Digital jet ink and preparation method and application thereof Download PDFInfo
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- CN102079898B CN102079898B CN 201010599145 CN201010599145A CN102079898B CN 102079898 B CN102079898 B CN 102079898B CN 201010599145 CN201010599145 CN 201010599145 CN 201010599145 A CN201010599145 A CN 201010599145A CN 102079898 B CN102079898 B CN 102079898B
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Abstract
The invention discloses digital jet ink and a preparation method and application thereof. The digital jet ink mainly comprises the following components (in percentage by weight): 0.3 to 5.0 percent of color materials, 3 to 25 percent of diglycol, 2 to 20 percent of ethanol, 1 to 10 percent of dimethyl formamide, 0.2 to 5.0 percent of N-methyl-2-pyrrolidone, 0.01 to 0.3 percent of bactericide, 0.1to 3.0 percent of PH value regulator, 0.1 to 3.0 percent of surfactant and 60 to 90 percent of water. The digital jet ink can be used for the spray printing of embroidery patterns, is particularly suitable for the spray printing of cross-stitch patterns for cotton, hemp, chemical fiber fabrics, ensures accurate color reproduction and smooth ink jet, and can be washed away without leaving any trace by being soaked in water.
Description
Technical field
The present invention relates to a kind of ink and its production and use, particularly a kind of digital ink-jet cross embroidery ink and its production and use.
Background technology
For a long time, embroidering and cutting the field, need a large amount of line and pattern; And after embroidering or cutting end, need again original bottoming pattern is removed, time-consuming; Especially embroider, it is to draw coordinate at cloth that tradition is embroidered, during embroidery, the embroidery art shining coordinate is arranged pattern at the above-mentioned corresponding coordinate of cloth, choose simultaneously corresponding multi-color cord, embroidered a width of cloth figure, tend to allow embroidery art's dim eyesight, time-consuming this defective is more outstanding.
For a long time, traditional ink-jet printing ink is pursued the washing fastness of color always, still ink is not applied at present in advance the pattern spray printing can flush away on medium not be had the ink for ink-jet print of trace.
Summary of the invention
The object of the invention is to provide a kind of digital jet ink; Another object of the present invention is to provide the preparation method of this digital jet ink; The 3rd purpose of the present invention is to provide the new purposes of this digital jet ink on cotton, fiber crops, chemical fibre.
The present invention seeks to be achieved through the following technical solutions:
Option A:
A kind of digital jet ink mainly comprises following component (in weight ratio):
Look material: 0.3～5.0, glycol ether: 3～25, ethanol: 2～20, water: 60～90.
Described digital jet ink preferably includes following component (in weight ratio):
Look material: 1.0～3.0, glycol ether: 5～15, ethanol: 2～12, water: 65～80.
Described digital jet ink preferably includes following component (in weight ratio):
Look material: 2.5, glycol ether: 12, ethanol: 10, water: 67.9;
Look material: 2, glycol ether: 13, ethanol: 10, water: 67.9;
Look material: 2.5, glycol ether: 7, ethanol: 2, water: 77.9;
Look material: 2.4, glycol ether: 7, ethanol: 2, water: 78;
Look material: 1.2, glycol ether: 12, ethanol: 3, water: 78;
Look material: 2.8, glycol ether: 6, ethanol: 12, water: 66;
Perhaps look material: 2.0, glycol ether: 10, ethanol: 7, water: 73.
Described digital jet ink look material is matching stain, pigment or heat sublimation dyestuff;
Described digital jet ink look material preferred acidic dyestuff; More preferably salt-free, without the divalent ion matching stain;
Described matching stain is the very responsive acid material of nonmetal complexing alkali resistance, includes but not limited to one or more in yellow dyes, magenta dye, cyan dye and/or the black dyes; Described yellow dyes kind includes but not limited to C.I. turmeric yellow 7, C.I. turmeric yellow 17, C.I. acid yellow 23 or C.I. turmeric yellow 73; Magenta dye includes but not limited to C.I. azogeramine, C.I. acid red 18, C.I. Xylene Red 52, C.I. Xylene Red 73, C.I. Xylene Red 82, C.I. acid red 87 or C.I. Acid Red 249; Cyan dye includes but not limited to C.I. acid blue 9, C.I. acid blue 90, C.I. acid blue 93, C.I. Blue VRS 04, C.I. acid blue 225 or C.I. acid blue 254; The black dyes kind includes but not limited to C.I. acid black 2, C.I. acid black 172, C.I. Acid Black 1 94; Described black dyes kind also can be three look complex compositions of above-mentioned yellow dyes kind, magenta dye kind, cyan dye kind.
Described matching stain, most preferably C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 are perhaps by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52, perhaps with the dyestuff of the close character of above-mentioned dyestuff; C.I. acid yellow 23, the C.I. Xylene Red 52 composite composite weight ratios of black are the C.I. acid blue 9: C.I. acid yellow 23: C.I. Xylene Red 52=0.5-1.5: 1-0.5: 0.5-1; Composite weight ratio is preferably the C.I. acid blue 9: the C.I. acid yellow 23: C.I. Xylene Red 52=0.5: 1.3: 0.7 or 1: 0.8: 0.8.
C.I. number being international standard number, is the C.I. acid blue 9 such as C.I.ACIDE BLUE 9.
Option b:
A kind of digital jet ink mainly comprises following component (in weight ratio):
Look material: 0.3～5.0, glycol ether: 3～25, ethanol: 2～20, dimethyl formamide: 1～10, METHYLPYRROLIDONE: 0.2～5.0, water: 60～90.
Described digital jet ink preferably mainly comprise following component (in weight ratio):
Look material: 1.0～3.0, glycol ether: 5～15, ethanol: 2～12, dimethyl formamide: 1～5, METHYLPYRROLIDONE: 1.2～2.5, water: 65～80.
A kind of digital jet ink preferably mainly comprise following component (in weight ratio):
Look material: 2.5, glycol ether: 12, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, water: 67.9;
Look material: 2, glycol ether: 13, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, water: 67.9;
Look material: 2.5, glycol ether: 7, ethanol: 2, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, water: 77.9;
Look material: 2.4, glycol ether: 7, ethanol: 2, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, water: 78;
Look material: 1.2, glycol ether: 12, ethanol: 3, dimethyl formamide: 4.5, METHYLPYRROLIDONE: 1.5, water: 78;
Look material: 2.8, glycol ether: 6, ethanol: 12, dimethyl formamide: 1.2, METHYLPYRROLIDONE: 2.4, water: 66;
Perhaps look material: 2.0, glycol ether: 10, ethanol: 7, dimethyl formamide: 2.5, METHYLPYRROLIDONE: 1.4, water: 73.
Described digital jet ink, look material are matching stain, pigment or heat sublimation dyestuff;
Described digital jet ink, look material preferred acidic dyestuff; More preferably salt-free, without the divalent ion matching stain;
Described matching stain for the very responsive acid material of nonmetal complexing alkali resistance, includes but not limited to one or more in yellow dyes, magenta dye, cyan dye and/or the black dyes; Described yellow dyes kind includes but not limited to C.I. turmeric yellow 7, C.I. turmeric yellow 17, C.I. acid yellow 23 or C.I. turmeric yellow 73; Magenta dye includes but not limited to C.I. azogeramine, C.I. acid red 18, C.I. Xylene Red 52, C.I. Xylene Red 73, C.I. Xylene Red 82, C.I. acid red 87 or C.I. Acid Red 249; Cyan dye includes but not limited to C.I. acid blue 9, C.I. acid blue 90, C.I. acid blue 93, C.I. Blue VRS 04, C.I. acid blue 225 or C.I. acid blue 254; The black dyes kind includes but not limited to C.I. acid black 2, C.I. acid black 172, C.I. Acid Black 1 94; Described black dyes kind also can be three look complex compositions of above-mentioned yellow dyes kind, magenta dye kind, cyan dye kind.
Described matching stain, most preferably C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 are perhaps by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52, perhaps with the dyestuff of the close character of above-mentioned dyestuff; C.I. acid yellow 23, the C.I. Xylene Red 52 composite composite weight ratios of black are the C.I. acid blue 9: C.I. acid yellow 23: C.I. Xylene Red 52=0.5-1.5: 1-0.5: 0.5-1; Composite weight ratio is preferably the C.I. acid blue 9: the C.I. acid yellow 23: C.I. Xylene Red 52=0.5: 1.3: 0.7 or 1: 0.8: 0.8.
Scheme C:
A kind of digital jet ink mainly comprises following component (in weight ratio):
Look material: 0.3～5.0, glycol ether: 3～25, ethanol: 2～20, dimethyl formamide: 1～10, METHYLPYRROLIDONE: 0.2～5.0, sterilant: 0.01～0.3, pH value conditioning agent: 0.1～3.0, tensio-active agent: 0.1～3.0, water: 60～90.
Described digital jet ink preferably mainly comprise following component (in weight ratio):
Look material: 1.0～3.0, glycol ether: 5～15, ethanol: 2～12, dimethyl formamide: 1～5, METHYLPYRROLIDONE: 1.2～2.5, sterilant: 0.05～0.2, pH value conditioning agent 0.5～2.0, tensio-active agent 0.5～2.0, water: 65～80.
Described digital jet ink preferably mainly comprise following component (in weight ratio):
Look material: 2.5, glycol ether: 12, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, sterilant: 0.1, pH value conditioning agent: 1.5, tensio-active agent: 1.0, water: 67.9;
Look material: 2, glycol ether: 13, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, sterilant: 0.1, pH value conditioning agent: 1.5, tensio-active agent: 0.5, water: 67.9;
Look material: 2.5, glycol ether: 7, ethanol: 2, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, sterilant: 0.1, pH value conditioning agent: 1.5, tensio-active agent: 1.0, water: 77.9;
Look material: 2.4, glycol ether: 7, ethanol: 2, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, sterilant: 0.1, pH value conditioning agent: 1.5, tensio-active agent: 1.0, water: 78;
Look material: 1.2, glycol ether: 12, ethanol: 3, dimethyl formamide: 4.5, METHYLPYRROLIDONE: 1.5, sterilant: 0.2, pH value conditioning agent: 0.6, tensio-active agent: 2.0, water: 78;
Look material: 2.8, glycol ether: 6, ethanol: 12, dimethyl formamide: 1.2, METHYLPYRROLIDONE: 2.4, sterilant: 0.05, pH value conditioning agent: 2.0, tensio-active agent: 0.6, water: 66;
Perhaps look material: 2.0, glycol ether: 10, ethanol: 7, dimethyl formamide: 2.5, METHYLPYRROLIDONE: 1.4, sterilant: 0.1, pH value conditioning agent: 1.0, tensio-active agent: 1.0, water: 73.
Described digital jet ink, look material are matching stain, pigment or heat sublimation dyestuff;
Described digital jet ink, look material preferred acidic dyestuff; More preferably salt-free, without the divalent ion matching stain;
Described matching stain for the very responsive acid material of nonmetal complexing alkali resistance, includes but not limited to one or more in yellow dyes, magenta dye, cyan dye and/or the black dyes; Described yellow dyes kind includes but not limited to C.I. turmeric yellow 7, C.I. turmeric yellow 17, C.I. acid yellow 23 or C.I. turmeric yellow 73; Magenta dye includes but not limited to C.I. azogeramine, C.I. acid red 18, C.I. Xylene Red 52, C.I. Xylene Red 73, C.I. Xylene Red 82, C.I. acid red 87 or C.I. Acid Red 249; Cyan dye includes but not limited to C.I. acid blue 9, C.I. acid blue 90, C.I. acid blue 93, C.I. Blue VRS 04, C.I. acid blue 225 or C.I. acid blue 254; The black dyes kind includes but not limited to C.I. acid black 2, C.I. acid black 172, C.I. Acid Black 1 94; Described black dyes kind also can be three look complex compositions of above-mentioned yellow dyes kind, magenta dye kind, cyan dye kind.
Described matching stain, most preferably C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 are perhaps by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52, perhaps with the dyestuff of the close character of above-mentioned dyestuff; C.I. acid yellow 23, the C.I. Xylene Red 52 composite composite weight ratios of black are the C.I. acid blue 9: C.I. acid yellow 23: C.I. Xylene Red 52=0.5-1.5: 1-0.5: 0.5-1; Composite weight ratio is preferably the C.I. acid blue 9: the C.I. acid yellow 23: C.I. Xylene Red 52=0.5: 1.3: 0.7 or 1: 0.8: 0.8.
Described sterilant includes but not limited to KATHON LXE, the KATHON LEX of Rhom and Hass, at least a among the Proxel GXL of ArchChemicals company, Proxel LV, the Proxel XL2; Preferred Proxel GXL.
Described pH adjusting agent includes but not limited to one or more in thanomin, diethanolamine, trolamine, the ammoniacal liquor; Preferred alcohol amine.
Described tensio-active agent includes but not limited to one or more in TW-100, OP-10, NP-10, NP-15 or the silicane tensio-active agent of FSO-100 or FSN-100, Surfynol 465 or Surfynol 604,4430, polyethenoxy ether class.The preferred Surfynol 465 of tensio-active agent.
Digital jet ink viscosity 3～8cP of the present invention, surface tension 25～35mN/m, pH value 7.5～9.5.
The invention provides a kind of preparation method of digital jet ink, it is for subsequent use to comprise the steps: that the look material is added an amount of melt into 10% mill base of water in advance; All the other components among option A, option b or the scheme C are imported mix and blend in the still at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend, negative pressure stirs; Filter by micron membranes, get ink.
The invention provides a kind of preparation method of digital jet ink, preferably include following steps: it is for subsequent use that the look material is added an amount of melt into 10% mill base of water in advance; All the other components among option A, option b or the scheme C are imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; Order is by 1 micron, and 0.5 micron, 0.22 micron membranes filters, and gets ink.
Digital jet ink of the present invention can be used for the spray printing of embroidered pattern, is particularly suited for the spray printing of cross embroidery pattern, is particularly suited for the spray printing of cotton, fiber crops, chemical fiber fabric cross embroidery pattern.
Digital jet ink of the present invention is applied in advance the pattern spray printing on medium, according pattern with media processes after, and water is with the pattern flush away of spray printing on medium.No matter digital jet ink of the present invention and traditional ink-jet printing ink are wide cut machine or tabletop machine relatively, fast still machine at a slow speed of machine, heat foamable machine or Medium-voltage Motor, can both guarantee that color rendition is accurate, ink-jet is smooth, and being soaked in water just can leave no trace by flush away.Digital jet ink of the present invention is printed on the cloth, and rate of drying is fast, prints smoothness, does not get damp, and pattern is sharp keen; Be placed under the sun and be exposed to the sun, namely faded in three days; In the holding chamber, lucifuge is placed in 1 year colour-fast; Sample is issued the embroidery art, and the embroidery art can according to the pattern color distribution, embroider rear pattern and still can keep original color.Behind digital jet ink of the present invention, embroidery art's embroidery speed and original velocity ratio, fast 3 times.Digital jet ink of the present invention removes with cold wash easily, and 40 degree left and right sides Warm Wash are except faster.Dyestuff of the present invention does not need to grind, and production cost is low, and it is low the plug probability to occur, and is minimum to the damage of China ink head.The present invention under freezing conditions, steady quality is without separating out; The present invention is composite with dimethyl formamide and METHYLPYRROLIDONE, finds that Output rusults can broken needle; The output image sharpness is high.
Experimental example 1: the different dyes test of fading
Material: dye sample, glycol ether, ethanol, Proxel GXL, thanomin, 465, dimethyl formamide, METHYLPYRROLIDONE, water; Silk, Mao Yumian, fiber crops, chemical fiber fabric.
Method: (1) glycol ether 12g, ethanol: 10g, sterilant: Proxel GXL 0.1g, pH adjusting agent: thanomin: 0.5g, tensio-active agent: 465:0.6g, scale remover: dimethyl formamide 3g, METHYLPYRROLIDONE: 2g, add water to total amount 97.5g mix and blend 0.5 hour, obtain mixed solution;
(2) matching stain sample 2.5g joins in the mixed solution that (1) obtain, and negative pressure stirred 5 hours, and then successively by 1 micron, 0.5 micron, 0.2 micrometer nylon filter membrane is namely directly printed the ink-jet dye ink of cross embroidery pattern; Ink viscosity 3～the 8cP for preparing, surface tension 25～35mN/m, pH value 7.5～9.5;
(3) with ink droplet in cloth cover, not dried, dry up, place with blower under one day, the situation in a week, January, steeped in the water of differing temps 5 minutes, different water temp situations are: water temp is that 20 degree, 30 when spending, 40 degree, 40 degree add washing powder.
Result: such as following table 1
Table 1
Conclusion: C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 or by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52, no matter the time how long, after cloth is sprayed ink, after cotton, numb, terylene cleans, do not stay the color vestige; And its allochromatic colour material all leaves vestige.
Experimental example 2: anti-dyestuff is separated out freezing test
Material: dyestuff: C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 or by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52; Composite weight ratio is: the C.I. acid blue 9: 0.5 weight part, C.I. acid yellow 23: 1.3 weight parts, C.I. Xylene Red 52:0.7 weight part.
Solvent auxiliary agent mixed solution: glycol ether, ethanol, METHYLPYRROLIDONE, dimethyl formamide, thanomin, GXL, 465, water.
Method: (1) four look dyestuff gets respectively 1,2,2.5,3g;
(2) glycol ether 12g, ethanol: 10g, METHYLPYRROLIDONE: 2g, dimethyl formamide: 3g, thanomin: 1.5g, GXL:0.1g, 465:0.5g, water: 68ml, be made into solvent auxiliary agent mixed solution, respectively with (1) in the dyestuff compatibility of all kinds of Different Weight part, make ink;
(3) with join in (2) ink fill with in clear bottles, be put in-15 the degree refrigerators in 24 hours.
Result: see the following form 2
Table 2
The result shows, only the C.I. acid yellow 23 is when weight part surpasses 3% in the ink component, and dyestuff is separated out, and hence one can see that, and ink is stable when dyestuff weight part of all kinds is equal to or less than 2.5%, without separating out.
Experimental example 3: scale remover is tested the impact of ink-jet stability:
Material: C.I. acid yellow 23, C.I. Xylene Red 52, C.I. acid blue 9; Glycol ether, ethanol, Proxel GXL, thanomin, 465, N-methyl-2 pyrrolidone, dimethyl formamide, butyrolactone, 2-Pyrrolidone, pure water; 914mm fabric width pp paper.
Equipment: one of military rattan 900C ink-jetting printer.
Method: covering under the safe rip environment, make the original driving of rattan 900C of useing force; Paper arranges: common paper; Picture size arranges: 5 meters x0.914 rice; Picture: four looks are deceived 0.8 meter x5 rice, and other four looks are respectively: 0.026x5 rice; Stepping: two-way 2pass; Gamma value: 2; The test of output previous crops spray orifice is checked without beginning output behind the inclined to one side pin of broken needle, does the spray orifice test after the output, checks the inclined to one side pin of needle break, and have: it is poor to be recorded as, nothing: be recorded as.
Ink samples forms:
C.I. acid yellow 23 2.5g, glycol ether 12g, ethanol: 10g, sterilant: Proxel GXL0.1g, pH adjusting agent: thanomin: 0.5g, tensio-active agent: 465:0.6g, scale remover: 4.5-5g, water: surplus, total amount are 100g;
C.I. Xylene Red 52 2.5g,, glycol ether 12g, ethanol: 10g, sterilant: Proxel GXL0.1g, pH adjusting agent: thanomin: 0.5g, tensio-active agent: 465:0.6g, scale remover: 4.5-5g, water: surplus, total amount are 100g;
C.I. acid blue 9 2.5g, glycol ether 12g, ethanol: 10g, sterilant: Proxel GXL0.1g, pH adjusting agent: thanomin: 0.5g, tensio-active agent: 465:0.6g, scale remover: 4.5-5g, water: surplus, total amount are 100g;
C.I. acid yellow 23: C.I. Xylene Red 52: C.I. acid blue 9=4.5: 2.3: 1.4 mixed black 2.5g, glycol ether 12g, ethanol: 10g, sterilant: Proxel GXL 0.1g, pH adjusting agent: thanomin: 0.5g, tensio-active agent: 465:0.6g, scale remover: 4.5-5g, water: surplus, total amount are 100g;
Preparation method: each component mix and blend 1 hour, negative pressure stirred 2 hours, then successively by 1 micron, 0.5 micron, 0.2 micrometer nylon filter membrane, namely directly printed ink viscosity 3～8cP that the ink-jet dye ink of cross embroidery pattern is prepared, surface tension 25～35mN/m, pH value 7.5～9.5;
Above ink all is fit to heat foamable and piezoelectric inkjet printer and spray drawing machine monochrome and colour print and air brushing.
The result: 3-5 sees the following form
Table 3
Table 4
Table 5
Conclusion: dimethyl formamide and METHYLPYRROLIDONE are composite, and examination with computer, the clean degree of black head surface be than singly adding the METHYLPYRROLIDONE height, and Output rusults can broken needle; Favourable to image sharpness output.
Following embodiment all can realize the effect of above-mentioned experimental example.
Embodiment 1
Components total 100g (by weight): C.I. acid blue 9: 2.5%, glycol ether: 12%, ethanol: 10%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid blue 9; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 2
Components total 100g (by weight): C.I. acid yellow 23: 2.5%, glycol ether: 12%, ethanol: 10%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid yellow 23; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 3
Components total 100g (by weight): C.I. Xylene Red 52:2.5%, glycol ether: 12%, ethanol: 10%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance for C.I. Xylene Red 52; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 4
Components total 100g (by weight): by C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52 composite black (composite weight ratio is: the C.I. acid blue 9: 0.5 weight part, C.I. acid yellow 23: 1.3 weight parts, 52: 0.7 weight parts of C.I. Xylene Red) 2.5, glycol ether: 12%, ethanol: 10%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: will be by C.I. acid blue 9, C.I. acid yellow 23, melt into 10% mill base is for subsequent use in advance for C.I. Xylene Red 52 composite black; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 5
Components total 100g (by weight): C.I. acid yellow 23: 2%, glycol ether: 13%, ethanol: 10%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:0.5%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid yellow 23; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 6
Components total 100g (by weight): C.I. Xylene Red 52:2.5%, ethylene glycol: 3%, glycol ether: 7%, ethanol: 2%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance with C.I. Xylene Red 52; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 7
Components total 100g (by weight): C.I. acid blue 9: 2.4%, ethylene glycol: 3%, glycol ether: 7%, ethanol: 2%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid blue 9; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 8
Components total 100g (by weight): C.I. acid blue 9: 0.5%, C.I. Xylene Red 52:0.7%, C.I. acid yellow 23: 1.3%, ethylene glycol: 3%, glycol ether: 7%, ethanol: 2%, METHYLPYRROLIDONE: 2%, dimethyl formamide: 3%, thanomin: 1.5%, GXL:0.1%, 465:1%, water: surplus;
Method for making: with the C.I. acid blue 9: 0.5%, C.I. Xylene Red 52:0.7%, C.I. acid yellow 23: 1.3%, melt into 10% mill base is for subsequent use in advance; With all the other components, imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 9
Components total 100g (by weight): C.I. acid blue 9: 2.5, glycol ether: 12, ethanol: 10, water: 67.9;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid blue 9; With all the other components, add conventional auxiliary material, import at normal temperatures mix and blend in the still, get mixed solution; Mill base is added mixed solution, mix and blend, negative pressure stirs; Filter by micron membranes, get ink.
Embodiment 10
Components total 100g (by weight): C.I. acid yellow 23: 2.0, glycol ether: 10, ethanol: 7, water: 73;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid yellow 23; All the other components are imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 11
Components total 100g (by weight): C.I. Xylene Red 52:2.5, glycol ether: 12, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, sterilant: 0.1, pH value conditioning agent 1.5, tensio-active agent 1.0, water 67.9;
Method for making: melt into 10% mill base is for subsequent use in advance with C.I. Xylene Red 52; All the other components are imported mix and blend in the still at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend, negative pressure stirs; Filter by micron membranes, get ink.
Embodiment 12
Components total 100g (by weight): by the composite black (composite weight ratio is: the C.I. acid blue 9: 0.5 weight part, C.I. acid yellow 23: 1.3 weight parts, 52: 0.7 weight parts of C.I. Xylene Red) of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52: 2.0, glycol ether: 10, ethanol: 7, dimethyl formamide: 2.5, METHYLPYRROLIDONE: 1.4, water 73;
Method for making: will be by C.I. acid blue 9, C.I. acid yellow 23, melt into 10% mill base is for subsequent use in advance for C.I. Xylene Red 52 composite black; All the other components are imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Embodiment 13
Components total 100g (by weight): C.I. acid blue 9: 2.5, glycol ether: 12, ethanol: 10, dimethyl formamide: 3, METHYLPYRROLIDONE: 2, Proxel LV:0.1, ammoniacal liquor: 1.5, Triton: TW-1001.0, water: 67.9;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid blue 9; All the other components are imported mix and blend in the still at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend, negative pressure stirs; Filter by micron membranes, get ink.
Embodiment 14
Components total 100g (by weight): C.I. acid yellow 23: 2.0, glycol ether: 10, ethanol: 7, dimethyl formamide: 2.5, METHYLPYRROLIDONE: 1.4, KATHON LXE:0.1, trolamine: 1.0, polyethenoxy ether class OP-10:1.0, water: 73;
Method for making: melt into 10% mill base is for subsequent use in advance with the C.I. acid yellow 23; All the other components are imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; By 1 micron, 0.5 micron, the filtration of 0.22 micron membranes get ink.
Claims (8)
1. digital jet ink is characterized in that mainly being made by following component in weight ratio:
Look material 0.3-5.0, glycol ether 3-25, ethanol 2-20, dimethyl formamide 1-10, METHYLPYRROLIDONE 0.2-5.0, water 60-90; Described look material is the C.I. acid blue 9, be no more than 3% C.I. acid yellow 23 and C.I. Xylene Red 52 any one, perhaps by the composite black of C.I. acid blue 9, C.I. acid yellow 23, C.I. Xylene Red 52, composite weight ratio is C.I. acid blue 9 C.I. acid yellow 23 C.I. Xylene Red 52=0.5-1.5: 1-0.5: 0.5-1.
2. digital jet ink as claimed in claim 1 is characterized in that being made by following component in weight ratio:
Look material 0.3-5.0, glycol ether 3-25, ethanol 2-20, dimethyl formamide 1-10, METHYLPYRROLIDONE 0.2-5.0, sterilant 0.01-0.3, pH value conditioning agent 0.1-3.0, tensio-active agent 0.1-3.0, water 60-90.
3. digital jet ink as claimed in claim 2 is characterized in that being made by following component in weight ratio:
Look material 1.0-3.0, glycol ether 5-15, ethanol 2-12, dimethyl formamide 1-5, METHYLPYRROLIDONE 1.2-2.5, sterilant 0.05-0.2, pH value conditioning agent 0.5-2.0, tensio-active agent 0.5-2.0, water 65-80.
4. digital jet ink as claimed in claim 3 is characterized in that being made by following component in weight ratio:
Look material 2.5, glycol ether 12, ethanol 10, dimethyl formamide 3, METHYLPYRROLIDONE 2, sterilant 0.1, pH value conditioning agent 1.5, tensio-active agent 1.0, water 67.9; Or
Look material 2, glycol ether 13, ethanol 10, dimethyl formamide 3, METHYLPYRROLIDONE 2, sterilant 0.1, pH value conditioning agent 1.5, tensio-active agent 0.5, water 67.9; Or
Look material 2.5, glycol ether 7, ethanol 2, dimethyl formamide 3, METHYLPYRROLIDONE 2, sterilant 0.1, pH value conditioning agent 1.5, tensio-active agent 1.0, water 77.9; Or
Look material 2.4, glycol ether 7, ethanol 2, dimethyl formamide 3, METHYLPYRROLIDONE 2, sterilant 0.1, pH value conditioning agent 1.5, tensio-active agent 1.0, water 78; Or
Look material 1.2, glycol ether 12, ethanol 3, dimethyl formamide 4.5, METHYLPYRROLIDONE 1.5, sterilant 0.2, pH value conditioning agent 0.6, tensio-active agent 2.0, water 78; Or
Look material 2.8, glycol ether 6, ethanol 12, dimethyl formamide 1.2, METHYLPYRROLIDONE 2.4, sterilant 0.05, pH value conditioning agent 2.0, tensio-active agent 0.6, water 66; Or
Perhaps look material 2.0, glycol ether 10, ethanol 7, dimethyl formamide 2.5, METHYLPYRROLIDONE 1.4, sterilant 0.1, pH value conditioning agent 1.0, tensio-active agent 1.0, water 73.
5. such as the arbitrary described digital jet ink of claim 2-4, it is characterized in that wherein said tensio-active agent is Surfynol 465.
6. digital jet ink as claimed in claim 5 is characterized in that wherein said sterilant is ProxelGXL; Described pH adjusting agent is thanomin.
7. the preparation method of digital jet ink as claimed in claim 6 is characterized in that the method is that the look material is added an amount of melt into 10% mill base of water is for subsequent use; All the other components are imported in the still mix and blend 0.5 hour at normal temperatures, get mixed solution; Mill base is added mixed solution, mix and blend 1.5 hours, negative pressure stirred 5 hours; Order is by 1 micron, and 0.5 micron, 0.22 micron membranes filters, and gets ink.
8. such as the application of the arbitrary described digital jet ink of claim 1-4 in cotton, fiber crops or chemical fiber fabric spray printing.
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| CN107880648A (en) * | 2017-12-07 | 2018-04-06 | 珠海华彩打印耗材有限公司 | A kind of waterborne digital printing dye sublimation ink-jet ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246883A (en) * | 1997-02-14 | 2000-03-08 | 宾尼及史密斯公司 | Washable colouring composition |
| CN1400256A (en) * | 2001-08-01 | 2003-03-05 | 伊斯曼柯达公司 | Dye mixture for jetted ink and its printing method |
| CN1803945A (en) * | 2005-12-29 | 2006-07-19 | 大连思创信息材料有限公司 | Black pigment ink for ink-jet printer and method for preparing the same |
| CN101899786A (en) * | 2010-08-18 | 2010-12-01 | 郑州鸿盛数码科技股份有限公司 | Textile inkjet printing acid dye ink and production method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246883A (en) * | 1997-02-14 | 2000-03-08 | 宾尼及史密斯公司 | Washable colouring composition |
| CN1400256A (en) * | 2001-08-01 | 2003-03-05 | 伊斯曼柯达公司 | Dye mixture for jetted ink and its printing method |
| CN1803945A (en) * | 2005-12-29 | 2006-07-19 | 大连思创信息材料有限公司 | Black pigment ink for ink-jet printer and method for preparing the same |
| CN101899786A (en) * | 2010-08-18 | 2010-12-01 | 郑州鸿盛数码科技股份有限公司 | Textile inkjet printing acid dye ink and production method thereof |
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