CN113831063B - Light quartz stone plate and preparation method thereof - Google Patents
Light quartz stone plate and preparation method thereof Download PDFInfo
- Publication number
- CN113831063B CN113831063B CN202111363159.6A CN202111363159A CN113831063B CN 113831063 B CN113831063 B CN 113831063B CN 202111363159 A CN202111363159 A CN 202111363159A CN 113831063 B CN113831063 B CN 113831063B
- Authority
- CN
- China
- Prior art keywords
- percent
- powder
- quartz
- raw materials
- glass fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a light quartz stone plate and a preparation method thereof, and relates to the technical field of plate processing. The light quartz stone plate is prepared from quartz powder with the particle size of 1-5 mu m, fly ash microspheres, unsaturated polyester resin, glass fiber powder, nano graphene powder, an accelerator, a curing agent and a coupling agent. The quartz powder consumption in the raw material composition is as low as 55-60%, a certain amount of low-density fly ash microspheres are added, and the auxiliary agent components are adjusted, so that the quartz stone plate keeps higher compactness, and the volume density is reduced to 2.0-2.1g/cm 3 The quartz stone plate with high hardness, high temperature resistance, wear resistance and light weight is obtained.
Description
Technical Field
The invention belongs to the technical field of quartz stone plate processing, and particularly relates to a light quartz stone plate and a preparation method thereof.
Background
The quartz stone slab is a novel stone material of artificial marble which is processed by more than 90 percent of quartz crystal combined resin and other auxiliary agents. The quartz stone plate has the advantages of high hardness, no radiation, zero pollution, high temperature resistance, wear resistance and the like. The quartz stone plate has excellent compactness and high quartz occupation ratio, so the current most light quartz stone plate with excellent performance has the density of 2.37-2.5 g/cm 3 The market demand for light weight cannot be achieved.
At present, the preparation of light quartz stone plates is a hot direction of attention of researchers in the industry, for example, in patent CN201410634878.0, a light artificial quartz stone and a preparation method thereof are disclosed, which is processed into a low-density quartz stone plate by using quartz powder with two particle size specifications, unsaturated polyester resin, silane coupling agent, expandable beads and curing agent. The analysis shows that the quartz proportion in the plate is up to more than 70%, although a small amount of expandable microspheres are added into the raw material composition, the specific gravity of the plate is still high, and the test and detection result verifies that the density of the quartz stone plate is 2.8-3.0 g/cm 3 Left and right.
In patent CN201910651671.7, a high-density quartz stone and a preparation method thereof are disclosed, wherein the quartz stone plate is a double-layer composite plate, that is, the quartz stone plate is composed of a quartz stone layer and a composite material layer (light material layer) wrapped inside the quartz stone layer. As can be seen from the patent document, the density of the quartz stone prepared by the invention is still kept at 2.5g/cm 3 Therefore, the density of the high-quality quartz stone plate is further reduced, the technical difficulty is high, the composite quartz stone plate also has the problem of poor use stability, and phenomena such as fault and cracking are easy to occur.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a light quartz stone plate, wherein the quartz powder (with the particle diameter of 1-5 mu m) is used in an amount of 55-60%, and the quartz stone plate keeps higher compactness by adding a certain amount of low-density fly ash microspheres and adjusting auxiliary agent components, and simultaneously the density is reduced to 2.0-2.1g/cm 3 The quartz stone plate with high hardness, high temperature resistance, wear resistance and light weight is obtained.
The quartz stone plate comprises the following raw materials:
55 to 60 percent of quartz powder with the grain diameter of 1 to 5 mu m,
15 to 20 percent of fly ash microspheres,
10 to 20 percent of unsaturated polyester resin,
1 to 5 percent of glass fiber powder,
1-5% of nano graphene powder,
0.1 to 2 percent of accelerant,
1 to 5 percent of curing agent,
1 to 5 percent of coupling agent,
the sum of the mass percentages of the raw materials is 100 percent;
the bulk density of the fly ash microspheres is 0.6-0.7g/cm 3 。
Preferably, the promoter in the raw material is cobalt naphthenate; the curing agent is methyl ethyl ketone peroxide; the coupling agent is a silane coupling agent.
The main components of the fly ash microspheres used in the present invention are shown in table 1.
TABLE 1
| Chemical composition | SiO 2 | CaO | MgO | Al 2 O 3 | Fe 2 O3 | Na 2 O | K 2 O | SO 3 |
| Percent by mass (%) | 56.5 | 4.8 | 1.3 | 26.5 | 5.3 | 1.4 | 3.28 | 0.65 |
The length-diameter ratio of the glass fiber powder adopted by the invention is 5:1, and the particle size of the glass fiber powder is 300-400 meshes.
The grain size of the nano graphene adopted by the invention is 50-100 nanometers.
In one embodiment, the light quartz stone plate is composed of the following raw materials in percentage by mass:
55 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
In one embodiment, the light quartz stone plate is composed of the following raw materials in percentage by mass:
55 percent of quartz powder with the grain diameter of 1-5 mu m,
20 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
In one embodiment, the light quartz stone plate is composed of the following raw materials in percentage by mass:
60 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3 percent of coupling agent,
the sum of the mass percentages of the raw materials is 100 percent.
In one embodiment, the light quartz stone plate is composed of the following raw materials in percentage by mass:
60 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
2 percent of glass fiber powder,
3 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3 percent of coupling agent,
the sum of the mass percentages of the raw materials is 100 percent.
The invention also provides a preparation method of the light quartz stone plate, which comprises the following steps:
(1) weighing raw materials according to a proportion and mechanically stirring uniformly;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the material distribution is finished, carrying out vibration pressing molding under a vacuum condition;
(4) curing the pressed blank at the temperature of 60-110 ℃;
(5) and polishing the plate obtained after curing.
Preferably, the pressure of the press forming in step (3) of the present invention is 50-100t, and the vibration frequency is 30-55 Hz.
Preferably, the curing time in step (4) of the present invention is 30-50 min.
Preferably, the polishing manner in step (5) of the present invention is water grinding polishing.
Compared with the prior art, the invention has the following beneficial effects:
the light quartz stone plate prepared by the invention has higher hardness, wear resistance and high temperature resistance, and the density of the quartz stone plate is as low as 2.0-2.1g/cm 3 Decrease ofThe specific gravity of the plate is increased, and the requirement of the market on the light quartz stone plate is met.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples, wherein the particle size of the quartz powder used in the following examples is 3 μm.
Example 1
The preparation method of the light quartz stone plate comprises the following steps:
(1) weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
55 percent of quartz powder,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3% of a silane coupling agent;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 55 Hz;
(4) curing the pressed and formed blank at the temperature of 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
Example 2
The preparation method of the light quartz stone plate comprises the following steps:
(1) weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
55 percent of quartz powder,
20 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3% of a silane coupling agent;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 50 Hz;
(4) curing the pressed and formed blank at the temperature of 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
Example 3
The preparation method of the light quartz stone plate comprises the following steps:
(1) weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
60 percent of quartz powder,
15 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3 percent of silane coupling agent
(2) Sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) After the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 50 Hz;
(4) curing the pressed blank at 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
Example 4
The preparation method of the light quartz stone plate comprises the following steps:
(1) weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
60 percent of quartz powder,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
2 percent of glass fiber powder,
3 percent of nano graphene powder,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3 percent of silane coupling agent
(2) Sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 50 Hz;
(4) curing the pressed and formed blank at the temperature of 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
Comparative example 1
The preparation method of the light quartz stone plate comprises the following steps:
(1) Weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
55 percent of quartz powder,
25 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3% of a silane coupling agent;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 55 Hz;
(4) curing the pressed and formed blank at the temperature of 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
Comparative example 2
The preparation method of the light quartz stone plate comprises the following steps:
(1) weighing the following raw materials in percentage by mass, and mechanically stirring and uniformly mixing;
55 percent of quartz powder,
40 percent of unsaturated polyester resin,
0.5 percent of accelerant (cobalt naphthenate),
1.5 percent of curing agent (methyl ethyl ketone peroxide),
3% of a silane coupling agent;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) After the cloth is distributed, carrying out vibration pressing molding under a vacuum condition, wherein the pressure of the pressing molding is 100t, and the vibration frequency is 55 Hz;
(4) curing the pressed and formed blank at the temperature of 80 ℃ for 30 min;
(5) and carrying out water grinding and polishing treatment on the plate obtained after curing.
The quartz stone plates prepared in examples 1 to 4 and comparative examples 1 to 2 were tested (the specification of the plate is 305cm × 76cm × 1.2cm), the specific test method refers to GB/T17657-1999 and JCT908-2013 standard in GB/T1.1-2009, and the test results are shown in table 2.
TABLE 2
It should be noted that the above-mentioned embodiments are merely examples of the present invention, and it is obvious that the present invention is not limited to the above-mentioned embodiments, and other modifications are possible. All modifications directly or indirectly derivable by a person skilled in the art from the present disclosure are to be considered within the scope of the present invention.
Claims (5)
1. The light quartz stone plate is characterized by comprising the following raw materials in percentage by mass:
55 to 60 percent of quartz powder with the grain diameter of 1 to 5 mu m,
15 to 20 percent of fly ash microspheres,
10 to 20 percent of unsaturated polyester resin,
1 to 5 percent of glass fiber powder,
1-5% of nano graphene powder,
0.1 to 2 percent of accelerant,
1 to 5 percent of curing agent,
1 to 5 percent of coupling agent,
the sum of the mass percentages of the raw materials is 100 percent;
the bulk density of the fly ash microspheres is 0.6-0.7g/cm 3 ；
The accelerant is cobalt naphthenate; the curing agent is methyl ethyl ketone peroxide; the coupling agent is a silane coupling agent;
the length-diameter ratio of the glass fiber powder is 5:1, and the particle size of the glass fiber powder is 300-400 meshes;
the particle size of the nano graphene is 50-100 nanometers;
the preparation method of the light quartz stone plate is characterized by comprising the following steps of:
(1) weighing raw materials according to a proportion and mechanically stirring uniformly;
(2) sending the uniformly stirred raw materials into a scattering machine for scattering treatment, and then sending the scattered materials into a distributing machine for distribution;
(3) after the material distribution is finished, carrying out vibration pressing molding under a vacuum condition;
(4) curing the pressed blank at the temperature of 60-110 ℃;
(5) polishing the plate obtained after curing;
the pressure of the compression molding in the step (3) is 50-100t, and the vibration frequency is 30-55 Hz;
the curing time in the step (4) is 30-50 min;
and (5) polishing by using a water mill.
2. The lightweight quartz stone slab as recited in claim 1, comprising the following raw materials in mass percent:
55 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
3. The lightweight quartzite sheet material as claimed in claim 1, comprising the following raw materials in mass percent:
55 percent of quartz powder with the grain diameter of 1-5 mu m,
20 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
4. The lightweight quartzite sheet material as claimed in claim 1, comprising the following raw materials in mass percent:
60 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
10 percent of unsaturated polyester resin,
5 percent of glass fiber powder,
5 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
5. The lightweight quartzite sheet material as claimed in claim 1, comprising the following raw materials in mass percent:
60 percent of quartz powder with the grain diameter of 1-5 mu m,
15 percent of fly ash microspheres,
15 percent of unsaturated polyester resin,
2 percent of glass fiber powder,
3 percent of nano graphene powder,
0.5 percent of accelerant,
1.5 percent of curing agent,
3% of coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111363159.6A CN113831063B (en) | 2021-11-17 | 2021-11-17 | Light quartz stone plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111363159.6A CN113831063B (en) | 2021-11-17 | 2021-11-17 | Light quartz stone plate and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113831063A CN113831063A (en) | 2021-12-24 |
| CN113831063B true CN113831063B (en) | 2022-07-29 |
Family
ID=78971459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111363159.6A Active CN113831063B (en) | 2021-11-17 | 2021-11-17 | Light quartz stone plate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113831063B (en) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833265B (en) * | 2014-01-23 | 2015-08-05 | 黄捷 | High-strength artificial quartz stone plate and preparation method thereof |
| KR101809196B1 (en) * | 2017-01-20 | 2017-12-14 | 윤석수 | Base Materials and Their Manufacturing Method Using Composite Material |
| CN107244876A (en) * | 2017-07-29 | 2017-10-13 | 南通戈雅石业有限公司 | A kind of building panel |
| CN107804993A (en) * | 2017-10-31 | 2018-03-16 | 佛山市欧泊石业有限公司 | A kind of novel artificial quartzite plate and preparation method thereof |
| CN111548052B (en) * | 2020-05-06 | 2021-05-04 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
-
2021
- 2021-11-17 CN CN202111363159.6A patent/CN113831063B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN113831063A (en) | 2021-12-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3766693A1 (en) | Inorganic fiber toughened inorganic composite artificial stone panel and preparation method thereof | |
| CN102229189B (en) | Square stock type artificial quartzite plate and manufacturing method thereof | |
| CN103833265A (en) | High-strength man-made quartz plate and preparation method thereof | |
| CN108393792B (en) | Active filler pore-forming agent, resin grinding tool containing pore-forming agent and manufacturing method of resin grinding tool | |
| CN102241491A (en) | Fireproof artificial quartz stone and production process thereof | |
| CN112608051B (en) | Method for preparing cement-based composite material by utilizing surface-modified silica fume-graphene oxide mixture | |
| US10906836B1 (en) | Composite plate and preparation method thereof | |
| CN101941816A (en) | Pretreatment recycling method of waste powder from polishing of artificial stone | |
| CN113831063B (en) | Light quartz stone plate and preparation method thereof | |
| CN103193436A (en) | Veneer with shielding performance | |
| CN102751066B (en) | A kind of magnetic material bad Product recycling recycling technique | |
| CN108751805B (en) | Artificial glass stone | |
| CN115677294B (en) | Light high-strength concrete and preparation method thereof | |
| WO2021012308A1 (en) | Organic fiber toughened inorganic composite artificial stone panel and preparation method therefor | |
| CN107954603B (en) | Matte glaze for glass surface and preparation process of glass mosaic | |
| CN113121143A (en) | Nano-micron composite concrete powder early strength agent and preparation method thereof | |
| CN111348862A (en) | Artificial stone and preparation method thereof | |
| CN113896459B (en) | Ultrathin quartz stone plate and preparation method thereof | |
| CN103981757B (en) | A kind of complex loop pressure strengthening agent and preparation method thereof | |
| CN113462196A (en) | Preparation method of narrow-distribution superfine silicon powder | |
| CN105295839B (en) | It is a kind of using ceramic polished waste material as resin-matrix friction material of filler and preparation method thereof | |
| CN111533488B (en) | Artificial stone plate and preparation method thereof | |
| CN108975679B (en) | Preparation method of silica powder for TFT-LCD glass substrate | |
| CN112897936A (en) | Artificial quartz stone line board and preparation method thereof | |
| CN109160769A (en) | A kind of diamond plate and preparation method thereof with quartz performance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |