CN109160769A - A kind of diamond plate and preparation method thereof with quartz performance - Google Patents
A kind of diamond plate and preparation method thereof with quartz performance Download PDFInfo
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- CN109160769A CN109160769A CN201811255153.5A CN201811255153A CN109160769A CN 109160769 A CN109160769 A CN 109160769A CN 201811255153 A CN201811255153 A CN 201811255153A CN 109160769 A CN109160769 A CN 109160769A
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- mesh
- white glass
- diamond plate
- preparation
- calcium carbonate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
- C04B2201/52—High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a kind of diamond plate and preparation method thereof with quartz performance.It is by mass percentage 100% meter, the raw material for preparing of the diamond plate with quartz performance includes: 90 mesh calcium carbonate sand 33-47%, modified calcium carbonate powder 35-47%, the glass 25-26% of various mesh numbers, unsaturated polyester resin 6-6.7%, pigment 0.2-0.26%, coupling agent 0.06-0.08%, curing agent 0.06-0.08% and promotor 0.006-0.008%.The Mohs' hardness of hilllock stone of conventional prior preparation is about 3 or so, and the hardness of quartzite slate is 7 or so, and the hardness of product of the invention is 5 or so and cost is relatively low.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of diamond plate with quartz performance and its
Preparation method.
Background technique
Hilllock stone is also known as artificial stone, compound stone, agglomerated stone, engineered stone.Hilllock stone is main former with natural marble particle, mountain flour
Material also can add the materials such as mosaic, shell, glass as interspersing, using organic resin as cementing agent, be stirred under vacuum,
Square stock is made in high pressure concussion, using processes manufactured Boards such as room temperature curing (curing time was at 7 days or more), sawing, polishing, polishings
Material.Compared with quartzite slate, the hardness and strength of hilllock stone are slightly worse, therefore in client need to have material hardness and intensity higher
It is required that when be not just very applicable.
Quartzite slate refer to by 90% or more quartz crystal plus resin and other microelements it is artificial synthesized one
Kind Novel stone, hardness and strength are all higher, but its main material is quartz, so cost is very high, is unfavorable for market
It promotes.
Summary of the invention
To solve the shortcomings and deficiencies of the prior art, the primary purpose of the present invention is that providing a kind of with quartz
The preparation method of the diamond plate of performance.
Another object of the present invention is to provide a kind of as made from above-mentioned preparation method with the Buddha's warrior attendant of quartz performance
Stone slab.
The object of the invention is achieved through the following technical solutions:
A kind of preparation method of the diamond plate with quartz performance, comprising the following steps:
(1) by mass percentage for 100% meter, weigh 90 mesh calcium carbonate sand 33-47%, modified calcium carbonate powder 35-47%,
The glass 25-26% of various mesh numbers, unsaturated polyester resin 6-6.7%, pigment 0.2-0.26%, coupling agent 0.06-0.08%,
Curing agent 0.06-0.08% and promotor 0.006-0.008%；
(2) glass of modified calcium carbonate powder, 90 mesh calcium carbonate sand, various mesh numbers is first proportionally added into blender, then
Pigment is added, adds unsaturated polyester resin, promotor, curing agent and coupling agent；Above-mentioned all materials are put into stirring
High-speed stirred after machine, wherein the frequency of high-speed stirred is 65Hz, the time is 15-18 minutes, and stirring while vacuumizes, vacuum
Degree reaches 0.096Mpa or more, and after the completion of stirring then cloth is suppressed, compacting puts vacuum in 10-15 minutes or so to mold
Mold is taken out, spontaneous curing, simultaneously sanding and polishing obtains the diamond plate with quartz performance to blank.
Preferably, the glass of the various mesh numbers includes the white glass of 30-50 mesh, the white glass of 16-30 mesh, 8-16 purpose
One of white glass of white glass and 6-8 mesh is a variety of.
Preferably, in step (1), it is by mass percentage 100% meter, weighs raw material: 90 mesh carbonic acid according to following proportion
Calcium sand 33.343%, modified calcium carbonate powder 35.31%, the white glass 6% of 16-30 mesh, the white glass 8% of 8-16 mesh, 6-8 purpose
White glass 11%, unsaturated polyester resin 6%, pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor
0.007%.
Preferably, in step (1), it is by mass percentage 100% meter, weighs raw material: 90 mesh carbonic acid according to following proportion
Calcium sand 33.343%, modified calcium carbonate powder 35.31%, the white glass 10% of 16-30 mesh, the white glass 7% of 8-16 mesh, 6-8 mesh
White glass 8%, unsaturated polyester resin 6%, pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor
0.007%.
It closes door in whipping process of the present invention to vacuumize, vacuum degree will at least reach under conditions of 0.096Mpa just can be with
Cloth is expected in mold, then is pressed, and otherwise might have bubble on plate.
The present invention also provides a kind of as made from above-mentioned preparation method with the diamond plate of quartz performance.
Compared with prior art, the present invention has the following advantages and beneficial effects:
The present invention is mainly to provide a kind of a kind of product between hilllock stone and quartzite slate performance, than hilllock stone hardness
It is good many with intensity, it is close with the hardness and strength of quartzite slate, it is able to satisfy the requirement of most of occasion, but cost is remote
Lower than quartzite slate.Key point of the invention is by calcium carbonate material in conjunction with glass phase, and material obtained has both two kinds of hilllocks
The advantage of stone and quartz fills up the blank of plate currently on the market.The Mohs' hardness of the hilllock stone of conventional prior preparation is big
About 3 or so, the hardness of quartzite slate is 7 or so, and the hardness of product of the invention is 5 or so and cost is relatively low.
Detailed description of the invention
Fig. 1 is the diamond plate photo prepared by embodiment 1 with quartz performance.
Specific embodiment
Below with reference to embodiment and attached drawing, the present invention is described in further detail, but embodiments of the present invention are unlimited
In this.
Unsaturated polyester resin of the present invention is that the unsaturation of the p-phenyl of Putian Yu Cheng Chemical Co., Ltd. production is poly-
Ester resin (model YC-818), 90 mesh calcium carbonate sand are purchased from Lianzhou City Qiang Yi mineral products Co., Ltd.Modified calcium carbonate powder is Lianzhou City
312 powder (400 mesh of average grain diameter or so) of Qiang Yi mineral products Co., Ltd of city production, hybrid pigment are produced each by the happy company of Bayer
Titanium dioxide (model 706) composition of kind iron pigment and Du Pont's production.Curing agent (methyl ethyl ketone peroxide) and promotor are (different pungent
Sour cobalt) it is the dedicated auxiliary agent curing agent of hilllock stone and promotor that Guangzhou Li Heng curing agent Science and Technology Ltd. produces.Coupling agent
The silane coupling agent (model KH570) of Hangzhou boiling point Chemical Co., Ltd. production.The white glass of various mesh numbers is purchased from Yunfu grace beauty
Artificial stone business department.
Embodiment 1
A kind of preparation method of the diamond plate with quartz performance, comprising the following steps:
(1) it is by mass percentage 100% meter, weighs 90 mesh calcium carbonate sand 33.343%, modified calcium carbonate powder
35.31%, white glass 11%, the unsaturated polyester resin of the white glass 6% of 16-30 mesh, the white glass 8% of 8-16 mesh, 6-8 mesh
6%, hybrid pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor 0.007%.
(2) unsaturated polyester resin is added in coupling agent and promotor to be stirred 10 minutes or more, it is spare；It will first be modified
Paris white, 90 mesh calcium carbonate sand, the white glass of 16-30 mesh, the white glass of 8-16 mesh, 6-8 mesh white glass weigh up in proportion
Weight passes through Belt Conveying to blender from feed bin, and hybrid pigment is thrown into and is stirred in blender 5 minutes, is then added unsaturated
The mixture and curing agent of polyester resin, coupling agent and promotor；By high speed after above-mentioned all material investment blenders
Stirring, wherein the frequency of high-speed stirred is 65Hz, the time is 22 minutes, and stirring while vacuumizes, and vacuum degree reaches
0.096Mpa or more, cloth to mold, is then suppressed, and compacting puts vacuum in 11 minutes or so and takes out mold, and seven days natural
Blank and sanding and polishing obtain the diamond plate with quartz performance after solidification.
Fig. 1 is the diamond plate photo prepared by embodiment 1 with quartz performance, somewhat transparent sense in picture
The particle of feel is exactly white glass because the hardness of glass is more much higher than calcium carbonate, diamond main performance embody just and these glass
The material of glass is related.
Embodiment 2
A kind of preparation method of the diamond plate with quartz performance, comprising the following steps:
(1) it is by mass percentage 100% meter, weighs 90 mesh calcium carbonate sand 33.343%, modified calcium carbonate powder
35.31%, white glass 8%, the unsaturated polyester resin of the white glass 10% of 16-30 mesh, the white glass 7% of 8-16 mesh, 6-8 mesh
6%, hybrid pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor 0.007%.
(2) unsaturated polyester resin is added in coupling agent and promotor to be stirred 10 minutes or more, it is spare；It will first be modified
Paris white, 90 mesh calcium carbonate sand, the white glass of 16-30 mesh, the white glass of 8-16 mesh, 6-8 mesh white glass weigh up in proportion
Weight passes through Belt Conveying to blender from feed bin, and hybrid pigment is thrown into and is stirred in blender 5 minutes, is then added unsaturated
The mixture and curing agent of polyester resin, coupling agent and promotor；By high speed after above-mentioned all material investment blenders
Stirring, wherein the frequency of high-speed stirred is 65Hz, the time is 22 minutes, and stirring while vacuumizes, and vacuum degree reaches
0.096Mpa or more, cloth to mold, is then suppressed, and compacting puts vacuum in 11 minutes or so and takes out mold, and seven days natural
Blank and sanding and polishing obtain the diamond plate with quartz performance after solidification.
Embodiment 3
(1) it is by mass percentage 100% meter, weighs 90 mesh calcium carbonate sand 47%, modified calcium carbonate powder 46.012%, no
6.7% hybrid pigment 0.2% of saturated polyester resin, curing agent 0.08% and promotor 0.008%；
(2) promotor addition unsaturated polyester resin is stirred 10 minutes or more, it is spare；First by modified calcium carbonate
Powder, 90 mesh calcium carbonate sand, weigh up in proportion weight from feed bin by Belt Conveying to blender, hybrid pigment is thrown into blender
In stir 5 minutes, the mixture and curing agent of unsaturated polyester resin and promotor is then added；By above-mentioned all materials
High-speed stirred after blender is put into, wherein the frequency of high-speed stirred is 65Hz, the time is 22 minutes, is taken out while stirring true
Sky, vacuum degree reach 0.096Mpa or more, then cloth to mold is suppressed, and compacting puts vacuum for mold in 11 minutes or so
It takes out, simultaneously sanding and polishing obtains a kind of artificial slabstone to blank after spontaneous curing in 7 days.
Above three embodiments, the data mainly changed are glass types and weight, from embodiment 1 to the 6-8 of embodiment 2
The weight of mesh white glass gradually decreases, and the white glass weight of 16-30 mesh is increasing, and the total weight of white glass is not change, this
The plate that sample is worked it out, the plate surface more than 16-30 mesh white glass weight seem that density is higher.The effect of hardness is also more
It is good.Changing from embodiment 2 to embodiment 3 maximum is exactly that white glass is not added in embodiment 3, because white glass is not added, resin
Amount increase, increased costs, hardness and other effects is also worst.As it can be seen that the glass of same quality, small glass is more, covers
Lid rate is bigger, comparatively the range of hardness also it is big a bit.
Plate product obtained above is cut into the plate that length is 300mm, width 150mm, high 20mm, does properties survey
Examination.Dry compressive strength is surveyed with computer on-screen formula universal hydraulic testing machine.Test result is as follows shown in table:
| Detection project | Unit | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Density | g/cm3 | 2.55 | 2.56 | 2.58 |
| Dry compressive strength | MPa | 180 | 185 | 170 |
| Mohs' hardness | 4.3 | 4.5 | 4 |
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (7)
1. a kind of preparation method of the diamond plate with quartz performance, which comprises the following steps:
(1) it is by mass percentage 100% meter, weighs 90 mesh calcium carbonate sand 33-47%, modified calcium carbonate powder 35-47%, various
The glass 25-26% of mesh number, unsaturated polyester resin 6-6.7%, pigment 0.2-0.26%, coupling agent 0.06-0.08%, solidification
Agent 0.06-0.08% and promotor 0.006-0.008%；
(2) glass of modified calcium carbonate powder, 90 mesh calcium carbonate sand, various mesh numbers is first proportionally added into blender, be then added
Pigment adds unsaturated polyester resin, promotor, curing agent and coupling agent；It is high later that all materials are put into blender
Speed stirring, stirring while, vacuumize, and after the completion of stirring then cloth is suppressed to mold, suppress put after a period of time it is true
Sky takes out mold, spontaneous curing, and simultaneously sanding and polishing obtains the diamond plate with quartz performance to blank.
2. a kind of preparation method of diamond plate with quartz performance according to claim 1, which is characterized in that
The glass of the various mesh numbers includes the white glass of 30-50 mesh, the white glass of 16-30 mesh, the white glass of 8-16 mesh and 6-8 purpose
One of white glass is a variety of.
3. a kind of preparation method of diamond plate with quartz performance according to claim 2, which is characterized in that
It is by mass percentage 100% meter, weigh raw material according to following proportion: 90 mesh calcium carbonate sand 33.343% change in step (1)
Property Paris white 35.31%, the white glass 6% of 16-30 mesh, the white glass 8% of 8-16 mesh, the white glass 11% of 6-8 mesh, insatiable hunger
With polyester resin 6%, pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor 0.007%.
4. a kind of preparation method of diamond plate with quartz performance according to claim 2, which is characterized in that
It is by mass percentage 100% meter, weigh raw material according to following proportion: 90 mesh calcium carbonate sand 33.343% change in step (1)
Property Paris white 35.31%, the white glass 10% of 16-30 mesh, the white glass 7% of 8-16 mesh, the white glass 8% of 6-8 mesh, insatiable hunger
With polyester resin 6%, pigment 0.2%, coupling agent 0.07%, curing agent 0.07%, promotor 0.007%.
5. a kind of preparation method of diamond plate with quartz performance according to any one of claims 1 to 4,
It is characterized in that, the frequency of the high-speed stirred is 65Hz, the time is 15-18 minutes, and stirring while vacuumizes, and vacuum degree reaches
0.096Mpa or more.
6. a kind of preparation method of diamond plate with quartz performance according to any one of claims 1 to 4,
It is characterized in that, the time of the compacting is 10-15 minutes.
7. with the diamond plate of quartz performance as made from any one of the claim 1-6 preparation method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811255153.5A CN109160769A (en) | 2018-10-26 | 2018-10-26 | A kind of diamond plate and preparation method thereof with quartz performance |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811255153.5A CN109160769A (en) | 2018-10-26 | 2018-10-26 | A kind of diamond plate and preparation method thereof with quartz performance |
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| Publication Number | Publication Date |
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| CN109160769A true CN109160769A (en) | 2019-01-08 |
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ID=64875220
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| CN201811255153.5A Pending CN109160769A (en) | 2018-10-26 | 2018-10-26 | A kind of diamond plate and preparation method thereof with quartz performance |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436823A (en) * | 2019-07-08 | 2019-11-12 | 广东意新家居有限责任公司 | A kind of composite board and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1834935A1 (en) * | 2006-03-16 | 2007-09-19 | QUARELLA S.p.A. | Wall and floor tiles and slabs consisting of agglomerated stone with photocatalytic properties |
| CN104446143A (en) * | 2014-11-19 | 2015-03-25 | 广西利升石业有限公司 | Preparation method of artificial stone from colored glass particles |
| CN106866084A (en) * | 2016-12-28 | 2017-06-20 | 广西利升石业有限公司 | A kind of large scale inorganic type artificial stone and preparation method thereof |
-
2018
- 2018-10-26 CN CN201811255153.5A patent/CN109160769A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1834935A1 (en) * | 2006-03-16 | 2007-09-19 | QUARELLA S.p.A. | Wall and floor tiles and slabs consisting of agglomerated stone with photocatalytic properties |
| CN104446143A (en) * | 2014-11-19 | 2015-03-25 | 广西利升石业有限公司 | Preparation method of artificial stone from colored glass particles |
| CN106866084A (en) * | 2016-12-28 | 2017-06-20 | 广西利升石业有限公司 | A kind of large scale inorganic type artificial stone and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436823A (en) * | 2019-07-08 | 2019-11-12 | 广东意新家居有限责任公司 | A kind of composite board and preparation method thereof |
| CN110436823B (en) * | 2019-07-08 | 2021-07-30 | 广东意新家居有限责任公司 | Composite board and preparation method thereof |
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Application publication date: 20190108 |