CN113825417A

CN113825417A - Stable package for aerosol-generating articles

Info

Publication number: CN113825417A
Application number: CN202080035424.5A
Authority: CN
Inventors: T·乔伊柯斯
Original assignee: Philip Morris Products SA
Current assignee: Philip Morris Products SA
Priority date: 2019-06-10
Filing date: 2020-06-08
Publication date: 2021-12-21
Also published as: BR112021022735A2; US20220240564A1; JP2022536459A; AU2020292699A1; CA3136898A1; IL288697A; EP3979846A1; WO2020250111A1; ZA202107200B; KR20220017902A; MX2021015084A

Abstract

A wrapper for use in a smoking article is provided. The package has low penetration of grease or visual spotting and can be used with aerosol-generating substrates. An aerosol-generating article (10) comprises an aerosol-generating substrate (12) comprising nicotine and a gel composition. The wrapper is disposed around and in contact with the aerosol-generating substrate. The package comprises a paper layer (50) comprising a surface treatment such that the paper has a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002.

Description

Stable package for aerosol-generating articles

The present disclosure relates to a wrapper for use in a smoking article, wherein the wrapper has low lipid penetration or visual spotting and can be used with an aerosol-generating substrate.

Aerosol-generating articles in which an aerosol-generating substrate, such as a tobacco-containing substrate, is heated rather than combusted are known in the art. Typically, in such heated aerosol-generating articles, an aerosol is generated by transferring heat from a heat source to a physically separate aerosol-generating substrate or material, which may be positioned in contact with, inside, around or downstream of the heat source. During use of the aerosol-generating article, volatile compounds are released from the aerosol-generating substrate by heat transfer from the heat source and entrained in air drawn through the aerosol-generating article. As the released compound cools, the compound condenses to form an aerosol.

The paper used to wrap the aerosol-generating substrate may absorb the aerosol former, water and other liquid compounds found in the mainstream smoke or aerosol passing through the aerosol-generating article or moisture surrounding the paper. The absorbed liquid may contaminate or weaken the paper and adversely affect the appearance and structural integrity of the aerosol-generating article. Heated aerosol-generating articles are particularly prone to becoming wet and damaged due to the high aerosol former levels in the aerosol-generating substrate of these heated aerosol-generating articles. When the aerosol component is absorbed by the package, the heated aerosol-generating article will swell particularly easily, resulting in difficulty in removal from the heating device. Heated aerosol-generating articles are particularly susceptible to breakage when they are received closely and then removed from the heating device.

It is desirable to provide a visually and mechanically stable wrapped aerosol-generating substrate, particularly for aerosol-generating articles containing high levels of liquid or aerosol former.

It would be desirable to provide an aerosol-generating article comprising a wrapper which does not swell by absorbing water or compounds contained in the aerosol-generating substrate.

It is desirable to provide an aerosol-generating article comprising a package that provides a grease barrier to grease compounds contained in the aerosol-generating substrate.

It is also desirable that the package does not affect the taste of the aerosol generated by the aerosol-generating article.

It is also desirable that the package does not easily burn when the heating element is accessed.

It may be an object of the present invention to at least partially address one or more of the above-mentioned desired technical benefits.

According to the present disclosure, there is provided an aerosol-generating article comprising an aerosol-generating substrate and a wrapper disposed around the aerosol-generating substrate, wherein the aerosol-generating substrate comprises nicotine. The package comprises a paper layer having a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002.

According to the present disclosure, there is provided an aerosol-generating article comprising an aerosol-generating substrate and a wrapper disposed around and in contact with the aerosol-generating substrate, wherein the aerosol-generating substrate comprises nicotine and a gel composition. The package comprises a paper layer comprising a surface treatment such that the paper has a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002.

According to the present disclosure, there is provided an aerosol-generating article. The aerosol-generating article may comprise an aerosol-generating substrate. The aerosol-generating substrate may comprise a wrapper. The wrapper may be disposed around the aerosol-generating substrate. The package comprises a paper layer having a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002.

Preferably, the paper layer has a negative result on at least five of the kit oil samples of method Tappi559cm-02 classical method 2002. Preferably, the paper layer has a negative result for at least eight of the kit oil samples of method Tappi559cm-02 classical method 2002. Preferably, the paper layer has a negative result for all ten kit oil samples of method Tappi559cm-02 classical method 2002.

Preferably, the paper layer has a thickness per square meter grammage in the range of about 1.0 micron/gsm to about 1.2 microns/gsm. The paper layer may have a thickness of less than about 50 microns, or less than about 40 microns. The wrapper includes a paper layer having a grammage in the range of about 25gsm to about 45gsm, or about 35gsm to about 40 gsm. Preferably, the paper layer has a grammage in the range of about 25gsm to about 45gsm and a thickness in the range of about 35 microns to about 50 microns.

Preferably, the paper layer has a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002 and has a water contact angle of at least 30 degrees. The paper layer may have a water contact angle of at least about 40 degrees, or at least about 45 degrees.

Preferably, the package comprises a paper layer having a CD/MD elongation at break ratio of about 2.5 or less and having a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002. The paper layer may have a negative result on at least five of the kit oil samples of method Tappi559cm-02 classical method 2002, or on all ten of the kit oil samples.

Preferably, the package comprises two paper layers, wherein a first paper layer has a negative result for at least one kit oil sample of method Tappi559cm-02 classical method 2002 and a second paper layer has a negative result for at least one kit oil sample of method Tappi559cm-02 classical method 2002. The package may have a total thickness of less than about 80 microns.

Preferably, the wrapper comprises PVOH (polyvinyl alcohol) or silicon. The paper layer may comprise a surface treatment comprising PVOH or silicon. The addition of PVOH (polyvinyl alcohol) or silicon can improve the grease barrier properties of the package.

The term "silicon" refers to siloxane. The silicon or siloxane preferably comprises polydimethylsiloxane.

Preferably, the aerosol-generating substrate may comprise homogenized tobacco material. The tobacco homogenized tobacco material may comprise a tobacco material, from about 1% to about 5% binder, and from about 5% to about 30% aerosol former, on a dry weight basis.

Preferably, the aerosol-generating substrate may comprise a gel composition. The gel composition may comprise a majority (by weight) of glycerol. The gel composition may comprise xanthan gum.

Preferably, the aerosol-generating substrate may comprise a metal inductive heating element. The metal induction heating element may comprise a plurality of metal induction heating elements. The metal induction heating element may comprise a metal induction heating ring element.

The package may be formed from a single paper layer. The package may be formed from two paper layers. The package may be formed from more than two paper layers.

Preferably, the wrapper covers at least 20%, at least 50%, at least 80%, at least 90%, at least 95%, at least 99% or preferably about the full length (entire length) of the aerosol-generating substrate. The wrapper preferably covers the entire aerosol-generating substrate and does not extend beyond the aerosol-generating substrate.

When the package has two or more paper layers, the first paper layer may have the unique properties described herein and the second paper layer may be considered a conventional paper layer. The second paper layer may preferably be arranged above the first paper layer. Alternatively, the first paper layer may be disposed over the second paper layer. Preferably, the first paper layer having the unique properties described herein is in contact with the aerosol-forming substrate.

When the package has two or more paper layers, the first paper layer may have the unique properties described herein and the second paper layer may also have the unique properties described herein. All of the paper layers forming the package may have the unique properties described herein. In particular, one or both paper layers forming the package may comprise PVOH (polyvinyl alcohol) or silicon. One or both paper layers forming the package may comprise a surface treatment comprising PVOH or silicon. Advantageously, a smoking article or aerosol-generating article comprising the paper wrapper described herein can reduce the wetting and absorption of water, humectant or grease in the smoke or aerosol passing through the smoking article or aerosol-generating article. Thus, even when high levels of humectant are included in the aerosol-generating substrate, visible contamination and physical weakening of the smoking article or the wrapper portion of the aerosol-generating article may be reduced.

Paper packaging having a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002 shows reduced paper swelling. Preferably, paper packaging that has a negative result on at least five of the kit oil samples of method Tappi559cm-02 classical method 2002 exhibits reduced paper swelling. Preferably, paper packaging that has a negative result on all ten kit oil samples of method Tappi559cm-02 classical method 2002 exhibits reduced paper swelling.

Advantageously, an aerosol-generating article comprising a package as described herein may reduce wetting, absorption of water, aerosol former or grease in the smoke or aerosol passing through the aerosol-generating article. Thus, swelling, visible contamination and physical weakening of the wrapper portion of the aerosol-generating article may be reduced even when high aerosol-former levels are included in the aerosol-generating substrate.

Advantageously, the aerosol-generating article provides a visually and mechanically stable encapsulated aerosol-generating substrate that will avoid swelling. This is particularly applicable to heated, rather than combustion, aerosol-generating articles that may be inserted into a heating device. The aerosol-generating article package may resist combustion if proximate to the heating element, and so the inductive heating element may be incorporated throughout the aerosol-generating substrate.

The term "aerosol-generating article" is used herein to refer to an article in which an aerosol-generating substrate is heated to generate and deliver an inhalable aerosol to a consumer. As used herein, the term "aerosol-generating substrate" refers to a substrate capable of releasing volatile compounds upon heating to generate an aerosol.

A conventional cigarette will light when a user applies a flame to one end of the cigarette and draws air through the other end. The localized heat provided by the flame and the oxygen in the air drawn through the cigarette causes the end of the cigarette to be lit and the resulting combustion produces breathable smoke. In contrast, in heated aerosol-generating articles, aerosols are generated by heating a flavour-generating substrate, such as tobacco. Known heated aerosol-generating articles include, for example, electrically heated aerosol-generating articles and aerosol-generating articles in which an aerosol is generated by heat transfer from a combustible fuel element or heat source to a physically separate aerosol-forming substrate. For example, aerosol-generating articles according to the present disclosure find particular application in aerosol-generating systems comprising electrically heated aerosol-generating devices having an internal heater blade adapted for insertion into a rod of aerosol-generating substrate. Aerosol-generating articles of this type are described in the prior art, for example in EP 0822670.

As used herein, the term "aerosol-generating device" refers to a device comprising a heater element which interacts with an aerosol-generating substrate of an aerosol-generating article to generate an aerosol.

As used herein, the term "aerosol-generating system" refers to the combination of an aerosol-generating device and an aerosol-generating article.

The term "aerosol-generating substrate" refers to a substance capable of generating or releasing an aerosol. The aerosol-generating substrate may be a solid, a paste, a gel, a slurry, a liquid, or may comprise any combination of solid, paste, gel, slurry and liquid compounds. Preferably, the aerosol-generating substrate is a solid or gel composition. The aerosol-generating substrate may preferably comprise nicotine.

The aerosol-generating article may comprise an aerosol-generating substrate and a mouthpiece. The mouthpiece may comprise a filter. The tipping wrapper may join the filter to the aerosol-generating substrate.

The aerosol-generating substrate may be a solid composition. The composition may comprise a plant-based material. The aerosol-generating substrate may comprise tobacco, and preferably the tobacco contains volatile tobacco flavour compounds which are released from the aerosol-generating substrate when heated. The aerosol-generating substrate may comprise a homogenized tobacco material, an aerosol former and a binder.

Nicotine may be present in the aerosol-generating substrate in a range of about 0.5 to about 10 wt% nicotine, or about 0.5 to about 5 wt% nicotine. Preferably, the aerosol-generating substrate may comprise from about 1 to about 3 wt% nicotine, or from about 1.5 to about 2.5 wt% nicotine, or about 2 wt% nicotine.

The aerosol-generating substrate may comprise a flavourant. The plant material provides a flavourant which may impart a flavour to the taste of an aerosol generated by the aerosol-generating article. Flavorants are any natural or artificial compound that affects the organoleptic qualities of the aerosol. Non-limiting examples of sources of flavorants include mints such as peppermint and spearmint, coffee, tea, cinnamon, clove, cocoa, vanilla, eucalyptus, geranium, agave, and juniper; and combinations thereof.

The aerosol-generating substrate may comprise an essential oil. Essential oils can provide flavorants that can impart a flavor to the taste of an aerosol generated by an aerosol-generating article. Suitable essential oils include, but are not limited to, eugenol, peppermint oil, and spearmint oil. The preferred essential oil is eugenol. The essential oil may be present in the aerosol-generating substrate in an amount of at least about 0.1 wt%, or at least about 0.5 wt%, or at least about 1 wt%. The essential oil may be present in the aerosol-generating substrate in a range from about 0.1 wt% to about 10 wt%, or from about 0.1 wt% to about 5 wt%, or from about 0.5 wt% to about 2 wt%.

The aerosol-generating substrate may comprise a gel composition. The term "gel" means a solid at room temperature. By "solid" in this context is meant that the gel is of a stable size and shape and does not flow. Room temperature in this context means 25 degrees celsius. A gel may be defined as a substantially dilute crosslinked system that does not exhibit flow at steady state. Gels may be predominantly liquids by weight, but they behave like solids due to the three-dimensional cross-linked network in liquids. It is the cross-linking within the fluid that gives the gel its structure (hardness). Thus, a gel may be a dispersion of liquid molecules in a solid, wherein the liquid particles are dispersed in a solid medium.

The gel composition may comprise a gelling agent that forms a solid medium, an aerosol former such as glycerin dispersed in the solid medium, and nicotine dispersed in the glycerin. The composition forms a stable gel phase. The gel composition may comprise at least two gelling agents forming a solid medium, glycerol dispersed in the solid medium and nicotine dispersed in the glycerol. The composition forms a stable gel phase. The gel composition may comprise a viscosity enhancing agent and a gelling agent that forms a solid medium, glycerin dispersed in the solid medium, and nicotine dispersed in the glycerin. The composition forms a stable gel phase. A gel composition can include nicotine, an aerosol former, a viscosity enhancing agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent. The gel composition may also comprise divalent cations.

The term "viscosifier" refers to a compound that increases viscosity without causing gel formation when added uniformly in an amount of 0.3 wt% to a mixture of 50 wt% water/50 wt% glycerol at 25 ℃, which mixture retains or retains fluid. Preferably, the tackifier means 0.1s when added uniformly in an amount of 0.3 wt.% to a mixture of 50 wt.% water/50 wt.% glycerin at 25 ℃^-1At a shear rate of (a) that increases the viscosity to at least 50cP, preferably at least 200cP, preferably at least 500cP, preferably at least 1000cP, without causing a gel to form, said mixture retaining or retaining the fluid. Preferably, the tackifier means 0.1s when added uniformly in an amount of 0.3 wt.% to a mixture of 50 wt.% water/50 wt.% glycerin at 25 ℃^-1At a shear rate of (a) that increases the viscosity to a value at least 2 times, or at least 5 times, or at least 10 times, or at least 100 times higher than before the addition without causing gel formation, the mixture retaining or retaining the fluid.

The viscosity values reported herein can be measured using a Brookfield RVT viscometer at 25 ℃ rotating a disk RV #2 spindle at 6 revolutions per minute (rpm).

The term "gelling agent" refers to a compound that when uniformly added to a mixture of 50 wt.% water/50 wt.% glycerin in an amount of about 0.3 wt.% forms a solid medium or carrier matrix that results in a gel. Gelling agents include, but are not limited to, hydrogen bond crosslinking gelling agents and ionic crosslinking gelling agents.

The term "hydrogen-bonding crosslinking gelling agent" refers to a gelling agent that forms non-covalent crosslinks or physical crosslinks via hydrogen bonding. Hydrogen bonding is an electrostatic dipole-dipole attraction type between molecules, rather than a covalent bond with a hydrogen atom. It results from the attractive force between a hydrogen atom covalently bonded to an electronegative atom such as N, O or a F atom and another electronegative atom.

The term "ionically crosslinking gelling agent" refers to a gelling agent that forms non-covalent crosslinks or physical crosslinks through ionic bonds. Ionic crosslinking involves the association of polymer chains by non-covalent interactions. Crosslinked networks are formed when multivalent molecules of opposite charge are electrostatically attracted to each other to form a crosslinked polymer network.

The gel composition comprises an aerosol former. Ideally, the aerosol former is substantially resistant to thermal degradation at the operating temperature of the associated aerosol-generating device. Suitable aerosol-forming agents include, but are not limited to: polyhydric alcohols such as triethylene glycol, 1, 3-butanediol, and glycerin; esters of polyhydric alcohols, such as monoacetin, diacetin, or triacetin; and aliphatic esters of mono-, di-or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate. The polyol or mixture thereof may be one or more of triethylene glycol, 1, 3-butanediol, glycerol (glycerol or propane-1, 2, 3-triol) or polyethylene glycol. The aerosol former is preferably glycerol.

The gel composition may comprise a majority of an aerosol former such as glycerol. The gel composition may comprise a mixture of water and glycerol, wherein the glycerol forms the majority (by weight) of the gel composition. The glycerin may form at least about 50% by weight of the gel composition. The glycerin may form at least about 60 wt%, or about 65 wt%, or about 70 wt% of the gel composition. The glycerin may form from about 70% to about 80% by weight of the gel composition. The glycerin may form from about 70% to about 75% by weight of the gel composition.

The gel composition preferably contains no or a small amount of water. When the gel composition does not contain water or contains a small amount of water, the gel composition may contain higher levels of other compounds such as aerosol former, gelling agent, viscosity increasing agent and nicotine. Moreover, gel compositions that do not contain water or that contain a small amount of water are more easily vaporized and require less energy to vaporize. Aerosols formed from gel compositions that do not contain water or that contain a small amount of water may be perceived by the user as less hot. Preferably, the gel composition comprises less than about 40 wt%, preferably less than about 30 wt%, preferably less than about 25 wt% water. The gel composition may comprise less than about 20 wt% or less than about 15 wt% or less than about 10 wt% or less than about 5 wt% water. The gel composition may preferably comprise some water. When the gel composition contains some water, the gel composition is more stable. Preferably, the gel composition comprises at least about 1 wt.%, or at least about 2 wt.%, or at least about 5 wt.% water. Preferably, the gel composition comprises at least about 10% or at least about 15% by weight water. Preferably, the gel composition comprises water in the range of about 15% to about 25% by weight.

The gel composition may comprise gelling agents that are hydrogen-bond crosslinking gelling agents and ionic crosslinking gelling agents. The gel composition may also include a tackifier. The gelling agent may form a solid medium in which the aerosol former may be dispersed. The gelling agent may form a solid medium in which the aerosol former and water may be dispersed. The viscosifying agent in combination with the hydrogen-bond crosslinking gelling agent and the ionic crosslinking gelling agent appears to unexpectedly support the solid medium and maintain the gel composition even when the gel composition comprises a high glycerol level.

The gel composition may comprise a gelling agent in the range of about 0.4 wt% to about 10 wt%. Preferably, the composition may comprise a gelling agent in the range of about 0.5 wt% to about 8 wt%. Preferably, the composition may comprise a gelling agent in the range of about 1% to about 6% by weight. Preferably, the composition may comprise a gelling agent in the range of about 2 wt% to about 4 wt%. Preferably, the composition may comprise a gelling agent in the range of about 2% to about 3% by weight.

The gel composition may include a tackifier in a range from about 0.2 wt% to about 5 wt%. Preferably, the tackifier is in the range of about 0.5 wt% to about 3 wt%. Preferably, the tackifier is in the range of about 0.5 wt% to about 2 wt%. Preferably, the tackifier is in the range of about 1 wt% to about 2 wt%.

The gel composition may comprise a viscosifying agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent present in the gel composition in a total amount of about 1 wt% to about 8 wt%. Preferably, the gel composition may comprise a viscosifying agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent present in the gel composition in a total amount of about 2 wt.% to about 6 wt.%. Preferably, the gel composition may comprise a viscosity increasing agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent present in the gel composition in a total amount of about 3 wt.% to about 5 wt.%.

The gel composition may comprise a viscosifying agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent each independently present in the gel composition in a range from about 0.3 wt% to about 3 wt%. Preferably, the gel composition may comprise a viscosifying agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent each independently present in the gel composition in a range from about 0.5 wt% to about 2 wt%. Preferably, the gel composition may comprise a viscosifying agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent each independently present in the gel composition in a range from about 1 wt% to about 2 wt%.

The viscosifying agent may comprise one or more of xanthan gum, carboxymethyl cellulose, microcrystalline cellulose, methyl cellulose, gum arabic, guar gum, lambda carrageenan, or starch. The viscosifying agent may preferably comprise xanthan gum.

The gel composition may comprise a viscosity increasing agent such as xanthan gum in a range from about 0.2 wt% to about 5 wt%. Preferably, the xanthan gum can range from about 0.5 wt% to about 3 wt%. Preferably, the xanthan gum can range from about 0.5 wt% to about 2 wt%. Preferably, the xanthan gum can range from about 1% to about 2% by weight.

The hydrogen-bonding cross-linking gelling agent may comprise one or more of galactomannan, gelatin, agarose or konjac gum or agar. The hydrogen-bond crosslinking gelling agent may preferably comprise agar.

The gel composition may comprise a hydrogen-bonding crosslinking gelling agent such as agar in the range of about 0.3 wt% to about 5 wt%. Preferably, the composition may comprise a hydrogen-bonding crosslinking gelling agent in the range of about 0.5 wt% to about 3 wt%. Preferably, the composition may comprise a hydrogen-bonding crosslinking gelling agent in the range of about 1 wt% to about 2 wt%.

The ionically cross-linking gelling agent may comprise a low acyl gellan gum, pectin, kappa carrageenan, iota carrageenan, or alginate. The ionic crosslinking gelling agent may preferably comprise a low acyl gellan gum.

The gel composition may comprise an ionically cross-linked gelling agent such as a low acyl gellan gum in a range from about 0.3 wt% to about 5 wt%. Preferably, the composition may comprise an ionically cross-linked gelling agent in the range of about 0.5 wt.% to about 3 wt.%. Preferably, the composition may comprise an ionically crosslinked gelling agent in the range of about 1 wt.% to about 2 wt.%.

The gel composition may further comprise a divalent cation. Preferably, the divalent cations may include calcium ions, such as calcium lactate in solution. For example, divalent cations (e.g., calcium ions) can aid in gel formation of compositions comprising gelling agents, such as ionically crosslinked gelling agents. The ionic effect may aid in gel formation. The divalent cation may be present in the gel composition in the range of about 0.1 to about 1 weight percent, or about 0.5 weight percent.

The gel composition may also comprise an acid. The acid may comprise a carboxylic acid. The carboxylic acid may comprise a ketone group. Preferably, the carboxylic acid may comprise a ketone group having less than about 10 carbon atoms, or less than about 6 carbon atoms, or less than about 4 carbon atoms, such as levulinic acid or lactic acid. Preferably, the carboxylic acid has three carbon atoms (e.g., lactic acid). Lactic acid surprisingly improves the stability of the gel composition even over similar carboxylic acids. The carboxylic acid may aid in gel formation. The carboxylic acid reduces the variation in nicotine concentration within the gel composition during storage.

The gel composition may comprise carboxylic acids such as lactic acid in the range of about 0.1 wt% to about 5 wt%. Preferably, the carboxylic acid may range from about 0.5 wt% to about 3 wt%. Preferably, the carboxylic acid may range from about 0.5 wt% to about 2 wt%. Preferably, the carboxylic acid may range from about 1 wt% to about 2 wt%.

Nicotine is contained in the gel composition. The nicotine may be added to the composition in the form of the free base or in the form of a salt. The gel composition can comprise from about 0.5% to about 10% by weight nicotine, or from about 0.5% to about 5% by weight nicotine. Preferably, the gel composition may comprise from about 1% to about 3% by weight nicotine, or from about 1.5% to about 2.5% by weight nicotine, or about 2% by weight nicotine. The nicotine component of the gel formulation may be the most volatile component of the gel formulation. In some aspects, water may be the most volatile component of the gel formulation, and the nicotine component of the gel formulation may be the second most volatile component of the gel formulation.

The aerosol-generating system may comprise: a heat source; an aerosol-generating substrate; at least one air inlet downstream of the aerosol-generating substrate; and an airflow path extending between the at least one air inlet and the mouth end of the article. The heat source is preferably upstream of the aerosol-generating substrate. The heat source may be integral with the aerosol-generating device and the combustible aerosol-generating article may be releasably received within the aerosol-generating device.

The heat source may be a combustible heat source, a chemical heat source, an electrical heat source, a heat sink, or any combination thereof. The heat source may be an electrical heat source, preferably shaped in the form of a blade, which may be inserted into the aerosol-generating substrate. Alternatively, the heat source may be configured to surround the aerosol-generating substrate and may therefore be in the form of a hollow cylinder, or any other such suitable form. Alternatively, the heat source is a combustible heat source. As used herein, a combustible heat source is a heat source that burns on itself during use to generate heat, unlike a cigarette, cigar or cigarillo, and does not involve burning an aerosol-generating substrate. The combustible heat sources may comprise carbon and an ignition aid such as a metal peroxide, superoxide or nitrate, wherein the metal is an alkali or alkaline earth metal.

The aerosol-generating substrate may comprise an inductive heating element or susceptor or a plurality of inductive heating elements or susceptors. The induction heating element or susceptor heats in the presence of an alternating or fluctuating electromagnetic field. When heated by induction heating, the fluctuating electromagnetic field is transmitted by the aerosol-generating article to an induction heating element or susceptor, such that the susceptor or induction heating element converts the fluctuating field into thermal energy, thereby heating the aerosol-generating substrate.

The inductive heating element or susceptor may be formed from any material that can be inductively heated to a temperature sufficient to generate an aerosol from an aerosol-generating substrate. The induction heating element or susceptor may comprise a metal or carbon. Preferred induction heating elements or susceptors may comprise ferromagnetic materials, such as ferritic iron, or ferromagnetic steel or stainless steel. The induction heating element or susceptor may comprise aluminum. The induction heating element or susceptor may be formed of 400 series stainless steel, such as grade 410, or grade 420, or grade 430 stainless 20 steel. Different materials will dissipate different amounts of energy when placed within an electromagnetic field having similar frequency and field strength values. Preferably, the induction heating element or susceptor is heated to a temperature in excess of 250 degrees celsius. Preferably, however, the induction heating element or susceptor is heated to less than 350 degrees celsius to prevent combustion of material in contact with the susceptor.

The inductive heating element or susceptor may be located in the vicinity of the wrapper of the aerosol-generating substrate, as the wrapper described herein advantageously resists combustion.

The term "mouthpiece" is used herein to denote the part of an aerosol-generating article that is designed to be in contact with the mouth of a consumer. The mouthpiece may be a portion of the aerosol-generating article that may comprise a filter, or in some cases, the mouthpiece may be defined by the extent of the tipping wrapper. In other instances, the mouthpiece may be defined as a portion of the aerosol-generating article that extends about 40mm from the mouth end of the aerosol-generating article or about 30mm from the mouth end of the aerosol-generating article.

The terms "upstream" and "downstream" refer to the relative positions of elements of the aerosol-generating article with respect to the direction of the aerosol as it is drawn from the aerosol-generating substrate and through the mouthpiece.

The terms "wrapper" or "paper wrapper" are interchangeable and refer to one or more layers of wrapping material wrapped around an aerosol-generating substrate to contain the aerosol-generating substrate or to hold the shape of an aerosol-generating article and formed from paper. The wrapper will reduce spotting on the outer surface of the aerosol-generating article. Preferably, the wrapper contacts the aerosol-generating substrate.

The term "hydrophobic" refers to a surface that exhibits water repellency properties. One useful method of determining this is to measure the water contact angle. The "water contact angle" is the angle conventionally measured through a liquid where the liquid/vapor interface meets the surface of a solid. It quantifies the wettability of a liquid to a solid surface by young's equation. Hydrophobicity or water contact angle can be determined by using TAPPI T558 test method, with results presented as interfacial contact angle and reported in degrees, which can range from near zero degrees to near 180 degrees.

Grease penetration is reported according to test method Tappi559cm-02 classical method 2002. This test method determines the oil permeability of paper or packaging. The test method measures the level of penetration by dropping a mixture of castor oil and solvent onto it. These mixtures were a set of 10 kits, prepared from castor oil, n-heptane and toluene, as described in the table below. The total volume of one kit was 10 ml.

The sample was placed on a dark surface with the test side up. Starting from kit 1, a 25. mu.l drop was deposited onto the paper with a micropipette fixed at a height of 13mm above the sample. After 15 seconds, the excess was cleaned and the paper surface was immediately visually inspected to check for the appearance of dark spots. The paper was then removed to carefully check for any drops on the dark surface. The results are reported below:

if the paper shows spots only on the surface, the test is positive for this kit and the result is "visible transmission".

If the dark surface shows spots, the test is positive for the kit and the result is "breakthrough".

If there are no spots, the result is negative for this kit.

The test is repeated with the next kit until the result is "breakthrough" or the last test kit (kit 10) is reached. When a suitable test kit has been identified, at least three measurements must be taken to verify a "positive" spot.

The present disclosure relates to a package for use in an aerosol-generating article, wherein the package comprises a paper layer having low grease penetration or grease spotting and is usable with an aerosol-generating substrate. According to the present disclosure, there is provided an aerosol-generating article comprising an aerosol-generating substrate and a wrapper disposed around the aerosol-generating substrate, wherein the aerosol-generating substrate comprises nicotine. The package comprises a paper layer having a low permeability to grease and having a negative result on at least one of the kit oil samples of method Tappi559cm-02 classical method 2002, preferably on at least five of the kit oil samples of method Tappi559cm-02 classical method 2002, and preferably on all ten of the kit oil samples of method Tappi559cm-02 classical method 2002.

The paper layer may have a thickness per gram per square meter in a range from about 0.8 microns/gsm to about 1.2 microns/gsm. The paper layer may have a thickness per gram per square meter in a range from about 1.0 micron/gsm to about 1.2 microns/gsm. The paper layer may have a thickness of about 1.0 micron/gsm per square meter grammage. The paper layer may have a thickness of about 0.9 microns/gsm per square meter grammage. The paper layer may have a thickness of about 1.0 micron/gsm per square meter grammage. The paper layer may have a thickness of about 1.1 microns/gsm per square meter grammage. The paper layer may have a thickness of about 1.2 microns/gsm per square meter grammage.

The paper layer may have a thickness of less than about 50 microns, or less than about 40 microns. The paper layer may have a thickness in a range of about 10 microns to about 50 microns. The paper layer may have a thickness in a range of about 20 microns to about 50 microns. The paper layer may have a thickness in a range of about 30 microns to about 50 microns. The paper layer may have a thickness in a range of about 35 microns to about 50 microns. The paper layer may have a thickness in a range of about 35 microns to about 40 microns. The paper layer may have a thickness in a range of about 40 microns to about 50 microns.

The paper layer may have a grammage in the range of about 25gsm to about 45 gsm. The paper layer may have a grammage in the range of about 30gsm to about 45 gsm. The paper layer may have a grammage in the range of about 35gsm to about 45 gsm. The paper layer may have a grammage in the range of about 35gsm to about 40 gsm.

In one embodiment, paper has a negative result for all ten kit oil samples of method Tappi559cm-02 classical method 2002.

In one embodiment, paper has a negative result for all ten kit oil samples of method Tappi559cm-02 classical method 2002. The paper layer has a grammage of about 35gsm to about 40gsm and a thickness of about 35 microns to about 45 microns.

In one embodiment, paper has a negative result for all ten kit oil samples of method Tappi559cm-02 classical method 2002. The paper layer has a grammage of about 35gsm to about 40gsm and a thickness of about 35 microns to about 45 microns. The paper layer has a water contact angle of about 35 degrees to about 50 degrees.

Preferably, the paper layer comprises PVOH (polyvinyl alcohol) or silicon. In one embodiment, the paper layer comprises PVOH (polyvinyl alcohol). PVOH can be applied to paper layers as a surface coating. The PVOH may be provided on an outer surface of a paper layer of the aerosol-generating article. The PVOH may be disposed on an outer surface of a paper layer of the aerosol-generating article and form a layer. The PVOH may be provided on the inner surface of a paper layer of the aerosol-generating article. The PVOH may be disposed on an inner surface of a paper layer of the aerosol-generating article and form a layer. The PVOH may be provided on both the inner and outer surfaces of a paper layer of the aerosol-generating article. The PVOH may be disposed on the inner and outer surfaces of a paper layer of the aerosol-generating article and form a layer.

The paper layer may comprise a surface treatment comprising PVOH or silicon. The paper layer may comprise a surface treatment comprising PVOH. The paper layer may comprise a surface treatment comprising silicon. The surface treatment may be applied to the outer surface of the paper layer. The surface treatment may be applied to the inner surface of the paper layer. The surface treatment may be applied to both the outer and inner surfaces of the paper layer. The addition of PVOH or silicon may improve the grease barrier properties of the paper layer.

The aerosol-generating substrate may comprise a gel composition. The gel composition may comprise a majority of an aerosol former such as glycerol. The gel composition may comprise nicotine, at least about 50 wt% glycerin or at least 70 wt% glycerin, at least about 0.2 wt% hydrogen bond crosslinking gelling agent, at least about 0.2 wt% ionic crosslinking gelling agent, and at least about 0.2 wt% viscosity enhancing agent. The gel composition may comprise xanthan gum.

The aerosol-generating substrate may comprise a homogenized tobacco material. The tobacco homogenized tobacco material may comprise a tobacco material, from about 1% to about 5% binder, and from about 5% to about 30% aerosol former, on a dry weight basis.

The aerosol-generating substrate may comprise a metallic inductive heating element. The metal induction heating element may comprise a plurality of metal induction heating elements. The metal induction heating element may comprise a metal induction heating ring element.

The packages described herein are expected to reduce and prevent the formation of consumer visible spots on aerosol-generating articles. It has been observed that spots can occur on aerosol-generating articles after storage in a moist environment or during consumption. Spotting may be caused by the absorption of water or aerosol former (including any suspended or dissolved colored material) into the cellulosic fibrous web making up the wrapper. Without being bound by any theory, the water or aerosol former interacts with the cellulose fibers of the paper and changes the texture of the fibers, resulting in local changes in the optical properties of the package, such as brightness, color and opacity, as well as mechanical properties, such as tensile strength, permeability.

The packages described herein are expected to reduce and prevent swelling of the aerosol-generating article. Reducing or preventing swelling of the aerosol-generating article will improve the usability of the aerosol-generating article to securely insert and remove the aerosol-generating article into and from a heating device without damaging the aerosol-generating article.

The wrapper is a portion of the aerosol-generating article which is disposed around the aerosol-generating substrate to help retain the cylindrical form of the aerosol-generating article. The package may contain the aerosol-generating substrate over at least about 50% of the length of a rod (plug) of aerosol-generating substrate. Preferably, the wrapper contains the aerosol-generating substrate over at least about 90% of the length of the rod of aerosol-generating substrate. More preferably, the wrapper contains the aerosol-generating substrate over at least about 100% of the length of the rod of aerosol-generating substrate.

The package may exhibit a range of permeability, including impermeability. The permeability of the cigarette paper is determined using international standard test method ISO 2965:2009 and results are presented in cubic centimeters per minute per square centimeter and are referred to as "CORESTA units". The permeability of the wrapper described herein can range from about 1 to about 10CORESTA units, from about 5 to about 20CORESTA units, or from about 1 to about 5CORESTA units.

The wrapper may be formed from any cellulosic material such as paper, wood, textiles, natural fibers, and man-made fibers. Preferably, the package does not contain a filler such as calcium carbonate. Preferably, the wrapper is formed from at least 90% by weight cellulosic material. Preferably, the wrapper is formed from at least 95% by weight cellulosic material.

The paper layer may be formed from any cellulosic material, such as paper, wood, textiles, natural fibers, and man-made fibers. Preferably, the paper layer does not contain fillers such as calcium carbonate. Preferably, the paper layer is formed from at least 90 wt% of cellulosic material. Preferably, the paper layer is formed from at least 95 wt% of cellulosic material.

The surface of the paper layer may have a water contact angle of at least about 30 degrees, at least about 35 degrees, at least about 40 degrees, or at least about 45 degrees. Hydrophobicity or water contact angle is determined by using the TAPPI T558 test, and results are presented in terms of interfacial contact angle and reported in degrees, which can range from near zero degrees to near 180 degrees.

The paper layer may have a negative result (no visible spots) on at least one of the kit oil samples of method Tappi559cm-02 classical method 2002. The paper layer may have a negative result on at least five of the kit oil samples of method Tappi559cm-02 classical method 2002, or on all ten of the kit oil samples.

The package may comprise two paper layers, wherein a first layer has a negative result for at least one kit oil sample of method Tappi559cm-02 classical method 2002 and a second paper has a negative result for at least one kit oil sample of method Tappi559cm-02 classical method 2002. The package has a total thickness of less than about 80 microns.

The package may comprise two paper layers, wherein a first layer contacts the aerosol-forming substrate and a second layer covers the first layer. The first layer may comprise PVOH (polyvinyl alcohol) or silicon or a surface treatment comprising PVOH or silicon. The second layer may comprise PVOH (polyvinyl alcohol) or silicon or a surface treatment comprising PVOH or silicon. Both the first and second layers may comprise PVOH (polyvinyl alcohol) or silicon or a surface treatment comprising PVOH or silicon. Only the first layer may comprise PVOH (polyvinyl alcohol) or silicon or a surface treatment comprising PVOH or silicon. Only the second layer may comprise PVOH (polyvinyl alcohol) or silicon or a surface treatment comprising PVOH or silicon

An aerosol-generating article comprises an aerosol-generating substrate which may comprise a charge of tobacco surrounded by a wrapper as described herein. The aerosol-generating substrate may comprise any suitable type or types of tobacco material or tobacco substitute in any suitable form. The aerosol-generating substrate may comprise fire-tube flue-cured tobacco, burley tobacco, maryland tobacco, oriental tobacco, specialty tobacco, homogenized or reconstituted tobacco, or any combination thereof. The aerosol-generating substrate may be provided in the form of: tobacco cut filler, tobacco lamina, treated tobacco material such as volumetrically expanded or puffed tobacco, treated tobacco stems such as cut-rolled stem or puffed stem, homogenized tobacco, reconstituted tobacco, cast leaf tobacco, or blends thereof, and the like. The term "tobacco cut filler" is used herein to indicate a tobacco material that is predominantly formed from the lamina portion of tobacco leaf. The term "tobacco cut filler" is used herein to indicate a single species of Nicotiana (Nicotiana) as well as two or more species of Nicotiana that form a blend of tobacco cut fillers.

As used herein, the term "homogenized tobacco" refers to a material formed by agglomerating particulate tobacco. Homogenized tobacco may include reconstituted tobacco or cast leaf tobacco or a mixture of both. The term "reconstituted tobacco" refers to paper-like materials that can be made from tobacco by-products such as tobacco dust, tobacco stems, or mixtures of the foregoing. Reconstituted tobacco can be made by extracting soluble chemicals from tobacco by-products, processing the remaining tobacco fiber into a sheet, and then reapplying the extracted material to the sheet in concentrated form. The term "cast leaf tobacco" is used herein to refer to the product resulting from processes well known in the art, which are based on casting a slurry comprising ground tobacco particles and a binder (e.g., guar gum) onto a support surface, such as a belt conveyor, drying the slurry, and removing the dried sheet from the support surface. Exemplary methods for producing these types of aerosol-generating substrates are described in US 5,724,998, US 5,584,306, US 4,341,228, US 5,584,306 and US 6,216,706. The homogenized tobacco may be formed into a sheet that is rolled, convoluted, folded or otherwise compressed, and then wrapped to form a rod. For example, sheets of homogenized tobacco material for use in the present invention may be crimped using a crimping unit of the type described in CH-a-691156, which comprises a pair of rotatable crimping rollers. However, it is to be understood that the sheet of homogenized tobacco material used in the present invention may be textured using other suitable machines and processes that deform or perforate the sheet of homogenized tobacco material.

Aerosol-generating substrates used in aerosol-generating articles typically contain higher levels of aerosol former than combustion smoking articles such as cigarettes. Humectants may also be referred to as "aerosol formers". Aerosol-former is used to describe any suitable known compound or mixture of compounds which will, in use, promote the formation of an aerosol and which is substantially resistant to thermal degradation at the operating temperature of the aerosol-generating substrate. Suitable aerosol-forming agents are known in the art and include, but are not limited to: polyhydric alcohols such as propylene glycol, triethylene glycol, 1, 3-butanediol, and glycerin; esters of polyhydric alcohols, such as monoacetin, diacetin, or triacetin; and aliphatic esters of mono-, di-or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate. Preferred aerosol formers are polyols or mixtures thereof, such as propylene glycol, triethylene glycol, 1, 3-butylene glycol, most preferably glycerol or glycerine. The aerosol-generating substrate may comprise a single aerosol former. Alternatively, the aerosol-generating substrate may comprise a combination of two or more aerosol-forming agents.

The aerosol-generating substrate may have a high aerosol former level. As used herein, a high aerosol former level refers to an aerosol former content of greater than about 10 wt.%, or preferably greater than about 15 wt.%, or more preferably greater than about 20 wt.%. The aerosol-generating substrate may also have an aerosol former content of between about 10 wt% to about 30 wt%, about 15 wt% to about 30 wt%, or about 20 wt% to about 30 wt%. The aerosol-generating substrate may also have a glycerin content of between about 10 wt% to about 30 wt%, about 15 wt% to about 30 wt%, or about 20 wt% to about 30 wt%.

The aerosol-generating substrate may comprise at least about 1 wt%, or at least about 2 wt%, or at least about 5 wt%, or at least about 7 wt%, or at least about 10 wt%, or at least about 12 wt%, or at least about 15 wt%, or at least about 18 wt% of the aerosol former. The aerosol-generating substrate may comprise aerosol former in the range of about 1 to about 20 wt%, or about 5 to about 20 wt%, or about 10 to about 20 wt%.

The aerosol-generating substrate may comprise at least about 1 wt%, or at least about 2 wt%, or at least about 5 wt%, or at least about 7 wt%, or at least about 10 wt%, or at least about 12 wt%, or at least about 15 wt%, or at least about 18 wt% of glycerin. The aerosol-generating substrate may comprise glycerol in the range of about 1 to about 20 wt.%, or about 5 to about 20 wt.%, or about 10 to about 20 wt.%.

The aerosol-generating substrate in gel form may have a majority of the aerosol former, preferably glycerol. The gel composition may comprise a gelling agent that forms a solid medium, an aerosol former such as glycerin dispersed in the solid medium, and nicotine dispersed in the glycerin. The composition forms a stable gel phase. The gel composition may comprise at least two gelling agents forming a solid medium, glycerol dispersed in the solid medium and nicotine dispersed in the glycerol. The composition forms a stable gel phase. The gel composition may comprise a viscosity enhancing agent and a gelling agent that forms a solid medium, glycerin dispersed in the solid medium, and nicotine dispersed in the glycerin. The composition forms a stable gel phase. A gel composition can include nicotine, an aerosol former, a viscosity enhancing agent, a hydrogen-bond crosslinking gelling agent, and an ionic crosslinking gelling agent. The gel composition may also comprise divalent cations.

The wrapper described herein is disposed around the aerosol-generating substrate. The package reduces the absorption of aerosol-former compounds and water onto the package as air is drawn through the heated aerosol-generating article.

Preferably, the aerosol-generating article may be substantially cylindrical. This enables the aerosol to flow smoothly. The aerosol-generating article may have an outer diameter of, for example, between 4 mm and 15 mm, between 5 mm and 10 mm, or between 6 mm and 8 mm. The aerosol-generating article may have a length of, for example, between 10 mm and 60 mm, between 15 mm and 50 mm, or between 20 mm and 45 mm.

The resistance of the aerosol-generating article to draw (RTD) will vary with the length and size of the passageway, the size of the aperture, the size of the narrowest cross-sectional area of the internal passageway, and the material used, etc. The RTD of the aerosol-generating article may be between 50 mm water (mm H2O) and 140 mm water (mm H2O), between 60 mm water (mm H2O) and 120 mm water (mm H2O), or between 80 mm water (mm H2O) and 100 mm water (mm H2O). The RTD of the article refers to the static pressure difference between the one or more apertures of the article and the mouth end of the article when traversed by the internal longitudinal passageway at steady state conditions where the volumetric flow rate at the mouth end is 17.5 milliliters per second. The RTD of the test specimens can be measured using the method set forth in ISO standard 6565: 2002.

All scientific and technical terms used herein have the meanings commonly used in the art unless otherwise indicated. The definitions provided herein are to facilitate understanding of certain terms used frequently herein.

As used in this specification and the appended claims, the singular forms "a", "an", and "the" encompass embodiments having plural referents, unless the content clearly dictates otherwise.

As used in this specification and the appended claims, the term "or" is generally employed in its sense including "and/or" unless the content clearly dictates otherwise.

As used herein, "having," including, "" comprising, "and the like are used in their open sense and generally mean" including, but not limited to. It is understood that "consisting essentially of … …", "consisting of … …", and the like are included in the "comprising" and the like.

The words "preferred" and "preferably" refer to embodiments of the invention that may provide certain benefits under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, recitation of one or more preferred embodiments does not imply that other embodiments are not useful, and is not intended to exclude other embodiments from the scope of the disclosure, including the claims.

Figure 1 is a schematic cross-sectional view of an aerosol-generating article.

Figure 2 is a schematic cross-sectional view of another aerosol-generating article.

Figure 3 is a schematic cross-sectional view of another aerosol-generating article.

Figure 4 is a schematic cross-sectional view of another aerosol-generating article.

Figures 5 and 6 are schematic cross-sectional views of aerosol-generating systems.

The aerosol-generating article depicted in fig. 1-4 illustrates one or more embodiments of the aerosol-generating article or components of the aerosol-generating article described above. The schematic drawings are not necessarily to scale and are presented for purposes of illustration and not limitation. The figures depict one or more aspects described in the present disclosure. However, it should be understood that other aspects not depicted in the drawings fall within the scope and spirit of the present disclosure.

The aerosol-generating article 10 of figure 1 illustrates an aerosol-generating substrate 12 comprising a tobacco rod, a hollow cellulose acetate tube 14, a polylactic acid filter segment 16 and a mouthpiece segment 18 formed from a cellulose acetate material. Each of these four elements is wrapped with a paper layer. In particular, the aerosol-generating substrate 12 is wrapped with a first paper layer 50 as described herein. The four elements are arranged in end-to-end, longitudinally aligned fashion.

The aerosol-generating substrate 12, the hollow cellulose acetate tube 14, the polylactic acid filter segment 16 are joined together and surrounded by a second paper layer 20 to form an intermediate article. The mouthpiece section 18 is joined to the intermediate article with tipping paper 25 to form the aerosol-generating article 10. The first paper layer 50 and the second paper layer 20 can cooperate to form a package as described herein.

The aerosol-generating article 10 has a mouth end 22 and an upstream distal end 24 at the end of the article opposite the mouth end 22. The aerosol-generating article 10 shown in figure 1 is particularly suitable for use with an electrically operated aerosol-generating device comprising a heater for heating an aerosol-generating substrate 12.

The aerosol-generating article 100 of fig. 2 comprises four elements arranged in coaxial alignment: a high Resistance To Draw (RTD) tip rod 600 at the distal end 103, a first paper layer 500 surrounding the aerosol-generating substrate 124, a fluid guide 400, and a mouthpiece 170 at the proximal end 101. These four elements are arranged in sequence and are surrounded by a second paper layer 110 to form the aerosol-generating article 100. The aerosol-generating article 100 has a proximal or mouth end 101 and a distal end 103 located at an end of the aerosol-generating article 100 opposite the proximal end 101. First paper layer 500 and second paper layer 110 cooperate to form a package as described herein.

The aerosol-generating article 100 of figure 3 illustrates a cross-sectional view of one example of an aerosol-generating article 100, which article is suitable for induction heating and for heating with a blade-like heating element.

The aerosol-generating article 100 comprises, in order from proximal end to distal end, a mouthpiece 170 at the proximal end 101, a fluid guide 400, a cavity 700, a first paper layer 500 surrounding the aerosol-generating substrate 124, and a terminal rod 600. In this example, the aerosol-generating substrate 124 comprises a gel and a susceptor (not shown). The susceptor in this example is a single strip of aluminium centrally located along the longitudinal axis of the aerosol-generating substrate 124. When the distal end 103 of the aerosol-generating article 100 is inserted into the aerosol-generating device 200 (see fig. 6), the portion of the aerosol-generating article 100 is positioned adjacent to the inductive heating element 230 (see fig. 5) of the aerosol-generating device 200 (see fig. 6). When a negative pressure is applied at the proximal end 101 of the aerosol-generating article 100, the electromagnetic radiation generated by the inductive heating element 230 will be absorbed by the susceptor and contribute to heating the aerosol-generating substrate 124 in the first paper layer 500, thereby contributing to the release of material from the aerosol-generating substrate 124, e.g. nicotine entrained in the delivered aerosol. A fluid, e.g. air, enters the outer longitudinal passage 831 via holes (not shown) to be transferred to the cavity 700 and then to the aerosol-generating substrate 124, where it mixes with the aerosol-generating substrate 124 and entrains nicotine before returning to the cavity, and then via the inner longitudinal passage (not shown) of the fluid guide 400 before exiting at the proximal end 101.

In this example, the first paper layer 500 is wrapped around the aerosol-generating substrate 124 and the first paper layer 500 is wrapped by the second paper layer 110. First paper layer 500 and second paper layer 110 form a package as described herein. The aerosol-generating substrate 124 may comprise a gel composition.

The aerosol-generating article 100 illustrated in fig. 2 and 3 may be used with an aerosol-generating device 200 as illustrated in fig. 5 and 6.

The aerosol-generating article 10 of figure 4 illustrates an aerosol-generating substrate 12, a hollow cellulose acetate tube 14, a hollow tubular segment 16 and a mouthpiece segment 18. The aerosol-generating substrate 12 is wrapped with a first paper layer 50 as described herein. The four elements are arranged in end-to-end, longitudinally aligned, and are wrapped by a second paper layer 20 to form the aerosol-generating article 10. The first paper layer 50 and the second paper layer 20 can cooperate to form a package as described herein.

The aerosol-generating article 10 has a mouth end 22 and an upstream distal end 24 at the end of the article opposite the mouth end 22. The aerosol-generating article 10 shown in figure 4 is particularly suitable for use with an electrically operated aerosol-generating device comprising a heater for heating an aerosol-generating substrate 12.

The aerosol-generating substrate 12 has a length of about 12 mm and a diameter of about 7 mm. The aerosol-generating substrate 12 is cylindrically shaped and has a substantially circular cross-section. The aerosol-generating substrate 12 comprises a gathered sheet of homogenised tobacco material. The sheet of homogenized tobacco material contained 10% by weight of glycerin on a dry weight basis. The hollow cellulose acetate tube 14 has a length of about 8 millimeters and a thickness of about 1 millimeter. The tobacco plug segment 18 comprises a filter segment of 8 denier per filament cellulose acetate tow and has a length of about 7 millimeters.

The hollow tubular section 14 is provided as a cylindrical tube having a length of about 18 millimeters and the thickness of the tube wall is about 100 micrometers. The aerosol-generating article 10 comprises a ventilation zone 26 provided at about 5 mm from the upstream end of the mouthpiece segment 18. Thus, the ventilation zone 26 is about 12 mm from the downstream end of the aerosol-generating article and about 13mm from the upstream end of the hollow tubular section. Thus, the ventilation zone 26 is about 21 mm from the downstream end of the aerosol-generating substrate 12.

Fig. 5-6 show examples of aerosol-generating articles 100 and aerosol-generating devices 200. The aerosol-generating article 100 has a proximal or mouth end 101 and a distal end 103. In fig. 5, the distal end 103 of the aerosol-generating article 100 is received in the container 220 of the aerosol-generating device 200. The aerosol-generating device 200 comprises a housing 210 defining a container 220 configured to receive the aerosol-generating article 100. The aerosol-generating device 200 further comprises a heating element 230 forming a cavity 235 configured to receive the aerosol-generating article 100, preferably by an interference fit. The heating element 230 may comprise a resistive heating element. In addition, the apparatus 200 includes a power supply 240 and control electronics 250 that cooperate to control the heating of the heating element 230.

The heating element 230 may heat the distal end 103 of the aerosol-generating article 100. In this example, the aerosol-generating substrate 124 comprises a gel comprising nicotine. Heating of the aerosol-generating article 100 causes the aerosol-generating substrate 124 to generate a nicotine-containing aerosol that can be transferred out of the aerosol-generating article 100 at the proximal end 101. The aerosol-generating device 200 comprises a housing 210. Fig. 5-6 do not show the exact heating mechanism.

In some examples, the heating mechanism may be by conduction heating, wherein heat is transferred from the heating element 230 of the aerosol-generating device 200 to the aerosol-generating article 100. This may easily occur when the aerosol-generating article 100 is positioned in the container 220 and the distal end 103 of the aerosol-generating device 200 (which is preferably the end at which the aerosol-generating substrate 124 is located) and thus the aerosol-generating article 100 is in contact with the heating element 230 of the aerosol-generating device 200. In a specific example, the heating element comprises a heating blade protruding from the aerosol-generating device 200 and adapted to penetrate into the aerosol-generating article 100 to be in direct contact with the aerosol-generating substrate 124.

In this example, the heating mechanism is by induction, wherein the heating element emits wireless electromagnetic radiation that is absorbed by the tubular element when the aerosol-generating article 100 is positioned in the container 220 of the aerosol-generating device 200.

Once the aerosol-generating article 100 is releasably received in the aerosol-generating device 200 and on the heating element 230, the aerosol-generating device 200 is actuated to heat the aerosol-generating substrate 124 to a temperature of about 375 degrees celsius. As a user draws on the mouth end 101 of the aerosol-generating article 100, volatile compounds emitted from the aerosol-generating substrate 124 are drawn downstream through the aerosol-generating article 100 and condense to form an aerosol, which is drawn through the mouthpiece 101 of the aerosol-generating article 100 into the user's mouth. The

packages

500, 110 repel the aerosol former and moisture from the aerosol reducing contamination and weakening of the

packages

500, 110.

The

first paper layer

50, 500 has a negative result on at least one of the kit oil samples of the method Tappi559cm-02 classical method 2002. Preferably, the

first paper layer

50, 500 has a negative result on at least five of the kit oil samples of the method Tappi559cm-02 classical method 2002. Preferably, paper layers 50, 500 have a negative result for all ten kit oil samples of method Tappi559cm-02 classical method 2002.

Preferably, the

first paper layer

50, 500 has a thickness per gram per square meter of weight of about 1.2 microns/gsm or less and a water contact angle of at least about 30 degrees. The

first paper layer

50, 500 may have a thickness of less than about 50 microns, or less than about 40 microns. The

first paper layer

50, 500 may have a grammage of about 25gsm to about 45gsm, or about 35gsm to about 40 gsm.

Preferably, the

first paper layer

50, 500 has a water contact angle of at least about 30 degrees and a CD/MD elongation at break ratio of about 2.5 or less. The

first paper layer

50, 500 may have a CD/MD elongation-to-break ratio of about 2.2 or less, or about 2 or less.

Preferably, the

first paper layer

50, 500 has a CD/MD elongation at break ratio of about 2.5 or less and has a negative result on at least one kit oil sample of method Tappi559cm-02 classical method 2002. The

first paper layer

50, 500 may have a negative result on at least five of the kit oil samples of the method Tappi559cm-02 classical method 2002, or on all ten of the kit oil samples.

Preferably, the package comprises a

first paper layer

50, 500 and a

second paper layer

20, 110, wherein the

first paper layer

50, 500 has a negative result for at least one of the kit oil samples of method Tappi559cm-02 classical method 2002, or for at least five of the kit oil samples of method Tappi559cm-02 classical method 2002, or for all ten of the kit oil samples of method Tappi559cm-02 classical method 2002.

Preferably, the package comprises a

first paper layer

50, 500 and a

second paper layer

20, 110, wherein the

first paper layer

50, 500 has a negative result for at least one kit oil sample of method Tappi559cm-02 classical method 2002, and the package may have a total thickness of less than about 80 microns.

Preferably, the

first paper layer

50, 500 comprises PVOH (polyvinyl alcohol) or silicon. The

first paper layer

50, 500 may comprise a surface treatment comprising PVOH or silicon. The addition of PVOH (polyvinyl alcohol) or silicon can improve the grease barrier properties of the package.

Preferably, the

second paper layer

20, 110 comprises PVOH (polyvinyl alcohol) or silicon. The

second paper layer

20, 110 may comprise a surface treatment comprising PVOH or silicon. The addition of PVOH (polyvinyl alcohol) or silicon can improve the grease barrier properties of the package.

The above exemplary embodiments are not limiting. Other embodiments consistent with the above exemplary embodiments will be apparent to those skilled in the art.

Claims

1. An aerosol-generating article comprising:

an aerosol-generating substrate comprising nicotine and a gel composition; and

a wrapper disposed around and in contact with the aerosol-generating substrate, the wrapper comprising a paper layer comprising a surface treatment such that the paper has a negative result on at least one kit oil sample of process Tappi559cm-02 classical process 2002.

2. An aerosol-generating article according to claim 1, wherein the paper layer has a negative result on at least 5 kit oil samples of method Tappi559cm-02 classical method 2002.

3. An aerosol-generating article according to any preceding claim, wherein the paper layer has a negative result for all 10 kit oil samples of method Tappi559cm-02 classical method 2002.

4. An aerosol-generating article according to any preceding claim, wherein the paper layer has a caliper of 25g/m²To 45g/m²Grammage in the range of 35 microns to 50 microns and a thickness in the range of 35 microns to 50 microns.

5. An aerosol-generating article according to any preceding claim, wherein the paper layer comprises PVOH or silicon.

6. An aerosol-generating article according to any preceding claim, wherein the paper layer comprises a surface treatment comprising PVOH or silicon.

7. An aerosol-generating article according to any preceding claim, wherein the paper layer comprises PVOH.

8. An aerosol-generating article according to any preceding claim, wherein the paper layer comprises silicon.

9. An aerosol-generating article according to claim 1, wherein the gel composition comprises a majority of glycerol.

10. An aerosol-generating article according to claim 9, wherein the gel composition comprises xanthan gum.

11. An aerosol-generating article according to any preceding claim, wherein the aerosol-generating substrate comprises homogenized tobacco material.

12. An aerosol-generating article according to claim 11, wherein the tobacco homogenized tobacco material comprises tobacco material, from 1% to 5% binder and from 5% to 30% aerosol former by dry weight.

13. An aerosol-generating article according to any preceding claim, wherein the aerosol-generating substrate comprises a metallic inductive heating element.

14. An aerosol-generating article according to any preceding claim, wherein the aerosol-generating substrate comprises a plurality of metallic inductive heating elements.