CN113816398B - 安德卢梭法中氨比例的变化 - Google Patents
安德卢梭法中氨比例的变化 Download PDFInfo
- Publication number
- CN113816398B CN113816398B CN202111323245.4A CN202111323245A CN113816398B CN 113816398 B CN113816398 B CN 113816398B CN 202111323245 A CN202111323245 A CN 202111323245A CN 113816398 B CN113816398 B CN 113816398B
- Authority
- CN
- China
- Prior art keywords
- ammonia
- methane
- cost
- reactor
- hcn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 642
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 320
- 238000000034 method Methods 0.000 title claims abstract description 139
- 230000008569 process Effects 0.000 title claims description 92
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 610
- 238000004519 manufacturing process Methods 0.000 claims abstract description 83
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims description 316
- 238000006243 chemical reaction Methods 0.000 claims description 90
- 239000003054 catalyst Substances 0.000 claims description 36
- 239000012535 impurity Substances 0.000 claims description 20
- 238000011084 recovery Methods 0.000 claims description 14
- 229910052697 platinum Inorganic materials 0.000 claims description 13
- 230000007423 decrease Effects 0.000 claims description 8
- 239000010948 rhodium Substances 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 6
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910000629 Rh alloy Inorganic materials 0.000 claims description 3
- 230000003442 weekly effect Effects 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 116
- 239000001301 oxygen Substances 0.000 description 116
- 229910052760 oxygen Inorganic materials 0.000 description 116
- 239000000047 product Substances 0.000 description 40
- 239000007789 gas Substances 0.000 description 26
- 239000003345 natural gas Substances 0.000 description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 23
- 239000000376 reactant Substances 0.000 description 22
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 18
- 238000006189 Andrussov oxidation reaction Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- 239000006227 byproduct Substances 0.000 description 9
- 239000002699 waste material Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 150000002825 nitriles Chemical class 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- 229910018967 Pt—Rh Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 201000007197 atypical autism Diseases 0.000 description 2
- 208000029560 autism spectrum disease Diseases 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 historically Chemical compound 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 2
- 238000001407 pulse-discharge detection Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000001668 ameliorated effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229960002163 hydrogen peroxide Drugs 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111323245.4A CN113816398B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261738727P | 2012-12-18 | 2012-12-18 | |
US61/738,727 | 2012-12-18 | ||
CN202111323245.4A CN113816398B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
CN201310680761.1A CN103864106B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201310680761.1A Division CN103864106B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113816398A CN113816398A (zh) | 2021-12-21 |
CN113816398B true CN113816398B (zh) | 2023-11-10 |
Family
ID=49885453
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111323245.4A Active CN113816398B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
CN201310680761.1A Active CN103864106B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310680761.1A Active CN103864106B (zh) | 2012-12-18 | 2013-12-12 | 安德卢梭法中氨比例的变化 |
Country Status (4)
Country | Link |
---|---|
CN (2) | CN113816398B (fr) |
HK (1) | HK1198997A1 (fr) |
TW (1) | TW201425229A (fr) |
WO (1) | WO2014099565A1 (fr) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2746843A (en) * | 1951-11-06 | 1956-05-22 | Distillers Co Yeast Ltd | Manufacture of hydrogen cyanide |
US3370919A (en) * | 1965-02-23 | 1968-02-27 | Monsanto Co | Production of hydrogen cyanide |
US4107278A (en) * | 1976-08-16 | 1978-08-15 | E. I. Du Pont De Nemours And Company | Process for making HCN |
US4128622A (en) * | 1976-08-27 | 1978-12-05 | E. I. Du Pont De Nemours And Company | Process for producing hydrogen cyanide |
US5817286A (en) * | 1997-07-25 | 1998-10-06 | Thermatrix Inc. | Processes for the synthesis of hydrogen cyanide |
WO2000020333A1 (fr) * | 1998-10-08 | 2000-04-13 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede ameliore de production d'acide cyanique |
CN101269824A (zh) * | 2007-03-23 | 2008-09-24 | 赢创罗姆有限责任公司 | 氰化氢(hcn)的制备方法 |
CN101687658A (zh) * | 2007-05-14 | 2010-03-31 | 因温斯特技术公司 | 高效反应器和方法 |
CN101977844A (zh) * | 2008-03-20 | 2011-02-16 | 阿肯马法国公司 | 改善的用于制备氢氰酸的方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1934838A (en) | 1930-04-14 | 1933-11-14 | Ig Farbenindustrie Ag | Production of hydrocyanic acid |
DE549055C (de) | 1930-04-15 | 1932-04-22 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Cyanwasserstoff |
DE69613581T2 (de) * | 1995-09-01 | 2002-04-25 | Ineos Acrylics Uk Ltd | Verfahren und vorrichtung zur herstellung von cyanwasserstoff |
DE10034194A1 (de) * | 2000-07-13 | 2003-09-11 | Roehm Gmbh | Verfahren zur Herstellung von Cyanwasserstoff |
DE10309209A1 (de) * | 2003-02-28 | 2004-09-09 | Degussa Ag | Verfahren zur Herstellung von Cyanwasserstoff nach dem BMA-Verfahren und Katalysator zu seiner Durchführung |
DE102007034715A1 (de) * | 2007-07-23 | 2009-01-29 | Evonik Röhm Gmbh | Reaktor zur Herstellung von Cyanwasserstoff nach dem Andrussow-Verfahren |
-
2013
- 2013-12-12 CN CN202111323245.4A patent/CN113816398B/zh active Active
- 2013-12-12 WO PCT/US2013/074526 patent/WO2014099565A1/fr active Application Filing
- 2013-12-12 CN CN201310680761.1A patent/CN103864106B/zh active Active
- 2013-12-12 TW TW102145767A patent/TW201425229A/zh unknown
-
2014
- 2014-12-12 HK HK14112512.8A patent/HK1198997A1/xx unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2746843A (en) * | 1951-11-06 | 1956-05-22 | Distillers Co Yeast Ltd | Manufacture of hydrogen cyanide |
US3370919A (en) * | 1965-02-23 | 1968-02-27 | Monsanto Co | Production of hydrogen cyanide |
US4107278A (en) * | 1976-08-16 | 1978-08-15 | E. I. Du Pont De Nemours And Company | Process for making HCN |
US4128622A (en) * | 1976-08-27 | 1978-12-05 | E. I. Du Pont De Nemours And Company | Process for producing hydrogen cyanide |
US5817286A (en) * | 1997-07-25 | 1998-10-06 | Thermatrix Inc. | Processes for the synthesis of hydrogen cyanide |
TW512132B (en) * | 1997-07-25 | 2002-12-01 | Thermatrix Inc | Processes for the synthesis of hydrogen cyanide |
WO2000020333A1 (fr) * | 1998-10-08 | 2000-04-13 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede ameliore de production d'acide cyanique |
CN101269824A (zh) * | 2007-03-23 | 2008-09-24 | 赢创罗姆有限责任公司 | 氰化氢(hcn)的制备方法 |
CN101687658A (zh) * | 2007-05-14 | 2010-03-31 | 因温斯特技术公司 | 高效反应器和方法 |
CN101977844A (zh) * | 2008-03-20 | 2011-02-16 | 阿肯马法国公司 | 改善的用于制备氢氰酸的方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103864106A (zh) | 2014-06-18 |
CN103864106B (zh) | 2021-11-26 |
CN113816398A (zh) | 2021-12-21 |
WO2014099565A1 (fr) | 2014-06-26 |
TW201425229A (zh) | 2014-07-01 |
HK1198997A1 (en) | 2015-06-19 |
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