CN113789134A - Antiskid wear-resistant flame-retardant adhesive tape and preparation method thereof - Google Patents
Antiskid wear-resistant flame-retardant adhesive tape and preparation method thereof Download PDFInfo
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- CN113789134A CN113789134A CN202111138603.4A CN202111138603A CN113789134A CN 113789134 A CN113789134 A CN 113789134A CN 202111138603 A CN202111138603 A CN 202111138603A CN 113789134 A CN113789134 A CN 113789134A
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- flame
- retardant
- wear
- resistant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 154
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 143
- 239000002390 adhesive tape Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000010410 layer Substances 0.000 claims abstract description 92
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- 239000002245 particle Substances 0.000 claims abstract description 38
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 22
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 21
- 239000000853 adhesive Substances 0.000 claims abstract description 21
- 230000001070 adhesive effect Effects 0.000 claims abstract description 21
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 16
- 239000007822 coupling agent Substances 0.000 claims abstract description 16
- 239000002105 nanoparticle Substances 0.000 claims abstract description 16
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- JSHBAWMNSZLGGH-UHFFFAOYSA-N C(C=C)(=O)O.[P] Chemical compound C(C=C)(=O)O.[P] JSHBAWMNSZLGGH-UHFFFAOYSA-N 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 5
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 239000002250 absorbent Substances 0.000 claims description 5
- 230000002745 absorbent Effects 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000003242 anti bacterial agent Substances 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 5
- 239000004611 light stabiliser Substances 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 239000011265 semifinished product Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 4
- 238000005299 abrasion Methods 0.000 claims description 4
- FNAKEOXYWBWIRT-UHFFFAOYSA-N 2,3-dibromophenol Chemical compound OC1=CC=CC(Br)=C1Br FNAKEOXYWBWIRT-UHFFFAOYSA-N 0.000 claims description 3
- QWVCIORZLNBIIC-UHFFFAOYSA-N 2,3-dibromopropan-1-ol Chemical compound OCC(Br)CBr QWVCIORZLNBIIC-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 claims description 3
- LADVLFVCTCHOAI-UHFFFAOYSA-N isocyanic acid;toluene Chemical compound N=C=O.CC1=CC=CC=C1 LADVLFVCTCHOAI-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229920006267 polyester film Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 230000001046 anti-mould Effects 0.000 abstract description 3
- 239000002546 antimould Substances 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 241001391944 Commicarpus scandens Species 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention provides an antiskid wear-resistant flame-retardant adhesive tape and a preparation method thereof, wherein the antiskid wear-resistant flame-retardant adhesive tape comprises a surface flame-retardant wear-resistant antiskid layer, a flame-retardant pressure-sensitive adhesive layer, a flame-retardant base material and a release layer; the surface flame-retardant wear-resistant anti-slip layer comprises a flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive, silicon carbide nanoparticles, metal aluminum particles, wear-resistant particles, a flame retardant, a curing agent, an initiator, a coupling agent, an anti-aging agent and an anti-mildew agent. In order to improve the wear resistance, the wear-resistant particles are added to improve the wear resistance of the anti-skid wear-resistant flame-retardant adhesive tape, and in order to ensure that the wear resistance has a better effect, the diameter of the wear-resistant particles is selected between 200 and 300 mu m; in order to improve the anti-skid performance, silicon carbide nano particles and metal aluminum particles are added to improve the friction coefficient; the anti-skid rubber has the advantages of improving the anti-skid performance, better wear resistance, certain anti-mould performance and weather resistance, better flame retardant performance, good tensile anti-tear performance, difficult fracture, easy attachment and easy stripping after use.
Description
Technical Field
The invention belongs to the technical field of adhesive tapes, relates to an adhesive tape, and particularly relates to an anti-skid wear-resistant flame-retardant adhesive tape with good anti-skid performance, good wear resistance and good flame retardance and a preparation method thereof.
Background
The adhesive tape is one of fixing and shielding tools commonly used in daily life and work, can be divided into a high-temperature adhesive tape, a double-sided adhesive tape, an anti-slip adhesive tape, a special adhesive tape, a pressure-sensitive adhesive tape, a die-cutting adhesive tape and the like according to the efficacy, and is suitable for different places and fields according to different efficacies.
The anti-slip adhesive tape is used very frequently in life, needs to be used in many places, has a very considerable protective effect and is protected, many places and instruments can be used more safely, and the places which can be used comprise kindergartens, schools, swimming pools, old homes, stations, subway train platforms, docks, hotels, convention houses, kitchens, toilets, playgrounds, fitness and entertainment rooms, elevator entrances, pedestrian slopes, goods yards, working areas, decks and other places; the available apparatus includes slide board, scooter, running machine, body building device, lathe, pedal of printing machine, passage and step in bus; places where it may be used include a recreation tour, a ship, a trailer, a truck, an airplane hanging ladder, a large or small power plant.
The current general antiskid wear-resistant adhesive tape has several main problems: in the above-mentioned use environment, the flame retardant property and wear resistance of the adhesive tape are very important. Meanwhile, the existing adhesive tapes are mostly made of pure polyvinyl chloride adhesive tapes, so that the anti-skid effect is poor.
Disclosure of Invention
The invention aims to solve the defects of single performance and poor antiskid effect of the existing antiskid adhesive tape, and provides an antiskid wear-resistant flame-retardant adhesive tape with good antiskid performance, good wear resistance and good flame retardance.
The invention also aims to provide a preparation method of the anti-skid wear-resistant flame-retardant adhesive tape.
In order to achieve the purpose, the invention adopts the following technical scheme:
the anti-slip wear-resistant flame-retardant adhesive tape comprises a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer, a base material and a release layer; the surface flame-retardant wear-resistant anti-slip layer comprises the following components in parts by weight: 60-87 parts of flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blended adhesive, 15-27 parts of silicon carbide nanoparticles, 5-10 parts of metal aluminum particles, 5-10 parts of wear-resistant particles, 3-8 parts of flame retardant, 2-6 parts of curing agent, 1-5 parts of initiator, 0.1-2 parts of coupling agent, 0.1-2 parts of anti-aging agent and 0.1-2 parts of anti-mildew agent.
In the technical scheme, the outer surface of the anti-skid wear-resistant flame-retardant adhesive tape is a surface flame-retardant wear-resistant anti-skid layer, in order to improve the wear resistance, wear-resistant particles are added to improve the wear resistance of the adhesive tape, and in order to ensure that the wear resistance has a better effect, the diameter of the wear-resistant particles is selected to be between 200 μm and 300 μm;
meanwhile, the flame retardant property, the processing property and the bonding property of the surface layer are improved by adding acrylic ester, and the breakage easiness of the phenolic resin is changed by adding rubber;
in order to improve the anti-skid performance, the silicon carbide nanoparticles and the metal aluminum particles are added to improve the friction coefficient, and in order to prevent the surface of the adhesive tape from being too uneven, the silicon carbide nanoparticles are selected to improve the anti-skid performance and enable the surface of the adhesive tape to have certain flatness and flame retardant performance.
As a preferable scheme of the invention, the flame-retardant pressure-sensitive adhesive layer comprises the following components in parts by weight: 10-17 parts of phosphorus acrylic acid monomer, 42-57 parts of butyl acrylate, 8-14 parts of methyl methacrylate, 2-6 parts of acrylic acid, 4-10 parts of allyl alcohol, 0.1-0.5 part of nitric acid, 3-8 parts of melamine, 3-8 parts of curing agent and 2-4 parts of initiator.
In a preferred embodiment of the present invention, the substrate includes one of a polyimide film, a flame-retardant polyester film, a flame-retardant PP, a flame-retardant PE or a flame-retardant PVC.
As a preferable scheme of the invention, the release layer comprises the following components in parts by weight: 0.5-3 parts of non-silicone oil release agent, 0.05-0.3 part of cross-linking agent, 0.02-0.2 part of adhesive force additive, 0.05-0.2 part of release force regulator and 96.3-99.38 parts of solvent.
As a preferable scheme of the invention, the wear-resistant particles are composed of silicon dioxide, zirconium oxide and aluminum oxide in a mass ratio of 2-3:1: 3-5.
As a preferred embodiment of the invention, the flame retardant comprises one or more mixtures of dibromophenol, tetrabromophthalic anhydride or 2, 3-dibromopropanol.
As a preferred embodiment of the present invention, the curing agent includes toluene isocyanate or diphenylmethane diisocyanate; the coupling agent comprises a silane coupling agent KH-570, KH-560 or KH-550; the anti-aging agent comprises the following components in a mass ratio of 1: 1, the hindered amine light stabilizer and the ultraviolet absorbent, and the anti-mildew agent is a silver hydroxyapatite antibacterial agent.
As a preferable scheme of the invention, the thickness of the surface flame-retardant wear-resistant anti-slip layer is 200-800 μm, the thickness of the flame-retardant pressure-sensitive adhesive layer is 30-100 μm, the thickness of the base material is 25-250 μm, and the thickness of the release layer is 0.1-50 μm.
The invention provides a preparation method of the antiskid wear-resistant flame-retardant adhesive tape, which comprises the following steps:
1) preparing a base material, and preparing slurry of a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer and a release layer according to a formula;
2) coating a primer on the surface of the substrate, and compounding the release layer obtained in the step 1);
3) coating the flame-retardant pressure-sensitive layer obtained in the step 1) on the base material obtained in the step 2);
4) coating the surface flame-retardant wear-resistant anti-slip layer obtained in the step 1) on the other surface of the base material obtained in the step 3) to obtain a semi-finished adhesive tape product;
5) curing and rolling the semi-finished product of the adhesive tape obtained in the step 4) to obtain the anti-skid wear-resistant flame-retardant adhesive tape.
As a preferable scheme of the invention, in the step 1), the preparation method of the surface flame-retardant wear-resistant anti-slip layer comprises the following steps: adding the modified phenolic resin into methyl isobutyl ketone, adding the flame-retardant acrylate and the nitrile rubber, mixing and dispersing at 90-120 ℃ for 5-10min, and filtering to obtain the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive; adding silicon carbide nano particles, metal aluminum particles and wear-resistant particles into the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive, uniformly mixing, adding a flame retardant, a curing agent, a coupling agent, an anti-aging agent and an anti-mildew agent, uniformly mixing, and standing.
Compared with the prior art, the invention has the following beneficial effects:
1) the adhesive tape disclosed by the invention has the advantages that the anti-skid performance is improved, the wear resistance is better, and the adhesive tape has certain anti-mould performance and weather resistance;
2) the adhesive tape also has better flame retardant property;
3) the adhesive tape has good tensile tear resistance, is not easy to break, is easy to attach, is easy to peel after being used, can realize large-width and large-length production, and is convenient to construct in a large area;
4) the adhesive tape has wide application range, and can be applied to the fields of emergency channels of high-rise buildings, frozen warehouses, schools, hospitals, fire signs, ship applications, underground operations and the like.
Drawings
FIG. 1 is a schematic of the present invention.
In the figure, 1, a surface flame-retardant wear-resistant anti-slip layer; 2. a substrate; 3. a flame-retardant pressure-sensitive adhesive layer; 4. and a release layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The raw materials and the method used in the invention are all available, if not specified.
Example 1
Referring to fig. 1, the embodiment provides an anti-slip wear-resistant flame-retardant adhesive tape, which sequentially comprises a surface flame-retardant wear-resistant anti-slip layer 1, a substrate 2, a flame-retardant pressure-sensitive adhesive layer 3, and a release layer 4;
the surface flame-retardant wear-resistant anti-slip layer comprises the following components in parts by weight: 60 parts of flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blended adhesive, 15 parts of silicon carbide nanoparticles, 5 parts of metal aluminum particles, 5 parts of wear-resistant particles, 3 parts of flame retardant, 2 parts of curing agent, 1 part of initiator, 0.1 part of coupling agent, 0.1 part of anti-aging agent and 0.1 part of anti-mildew agent;
the flame-retardant pressure-sensitive adhesive layer comprises the following components in parts by weight: 10 parts of phosphorus acrylic acid monomer, 42 parts of butyl acrylate, 8 parts of methyl methacrylate, 2 parts of acrylic acid, 4 parts of allyl alcohol, 0.1 part of nitric acid, 3 parts of melamine, 3 parts of curing agent and 2 parts of initiator.
The substrate is a polyimide film.
The release layer comprises the following components in parts by weight: 0.5 part of non-silicone oil release agent, 0.05 part of cross-linking agent, 0.02 part of adhesive force additive, 0.05 part of release force regulator and 96.3 parts of solvent.
The wear-resistant particles consist of silicon dioxide, zirconium oxide and aluminum oxide in a mass ratio of 2:1: 3.
The flame retardant is dibromophenol.
The curing agent is toluene isocyanate; the coupling agent is a silane coupling agent KH-570; the anti-aging agent is prepared from the following components in a mass ratio of 1: 1, the hindered amine light stabilizer and the ultraviolet absorbent, and the anti-mildew agent is a silver hydroxyapatite antibacterial agent.
The thickness of the surface flame-retardant wear-resistant anti-slip layer is 200-800 mu m, the thickness of the flame-retardant pressure-sensitive adhesive layer is 30-100 mu m, the thickness of the base material is 25-250 mu m, and the thickness of the release layer is 0.1-50 mu m.
The preparation method comprises the following steps:
1) preparing a base material, and preparing slurry of a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer and a release layer according to a formula; the preparation method of the surface flame-retardant wear-resistant anti-skid layer comprises the following steps: adding the modified phenolic resin into methyl isobutyl ketone, adding the flame-retardant acrylate and the nitrile rubber, mixing and dispersing at 90-120 ℃ for 5-10min, and filtering to obtain the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive; adding silicon carbide nano particles, metal aluminum particles and wear-resistant particles into the modified phenolic-nitrile rubber adhesive, uniformly mixing, adding a flame retardant, a curing agent, an initiator, a coupling agent, an anti-aging agent and an anti-mildew agent, uniformly mixing, and standing;
2) coating a primer on the surface of the substrate, and compounding the release layer obtained in the step 1);
3) coating the flame-retardant pressure-sensitive layer obtained in the step 1) on the base material obtained in the step 2);
4) coating the surface flame-retardant wear-resistant anti-slip layer obtained in the step 1) on the base material obtained in the step 3) to obtain a semi-finished adhesive tape product;
5) curing and rolling the semi-finished product of the adhesive tape obtained in the step 4) to obtain the anti-skid wear-resistant flame-retardant adhesive tape.
Example 2
Referring to fig. 1, the embodiment provides an anti-slip wear-resistant flame-retardant adhesive tape, which sequentially comprises a surface flame-retardant wear-resistant anti-slip layer 1, a substrate 2, a flame-retardant pressure-sensitive adhesive layer 3, and a release layer 4;
the surface flame-retardant wear-resistant anti-slip layer comprises the following components in parts by weight: 75 parts of modified phenolic-nitrile rubber adhesive, 22 parts of silicon carbide nanoparticles, 8 parts of metal aluminum particles, 7 parts of wear-resistant particles, 5 parts of flame retardant, 3 parts of curing agent, 4 parts of initiator, 1.2 parts of coupling agent, 1.5 parts of anti-aging agent and 1.8 parts of anti-mildew agent;
the flame-retardant pressure-sensitive adhesive layer comprises the following components in parts by weight: 15 parts of phosphorus acrylic acid monomer, 47 parts of butyl acrylate, 10 parts of methyl methacrylate, 3 parts of acrylic acid, 10 parts of allyl alcohol, 0.5 part of nitric acid, 8 parts of melamine, 8 parts of curing agent and 4 parts of initiator.
The substrate is a flame-retardant polyester film.
The release layer comprises the following components in parts by weight: 3 parts of non-silicone oil release agent, 0.2 part of cross-linking agent, 0.15 part of adhesive force additive, 0.17 part of release force regulator and 97.66 parts of solvent.
The wear-resistant particles consist of silicon dioxide, zirconium oxide and aluminum oxide in a mass ratio of 2.4:1: 4.
The flame retardant is tetrabromo phthalic anhydride.
The curing agent is diphenylmethane diisocyanate; the coupling agent is KH-550; the anti-aging agent is prepared from the following components in a mass ratio of 1: 1, the hindered amine light stabilizer and the ultraviolet absorbent, and the anti-mildew agent is a silver hydroxyapatite antibacterial agent.
The thickness of the surface flame-retardant wear-resistant anti-slip layer is 200-800 mu m, the thickness of the flame-retardant pressure-sensitive adhesive layer is 30-100 mu m, the thickness of the base material is 25-250 mu m, and the thickness of the release layer is 0.1-50 mu m.
The preparation method comprises the following steps:
1) preparing a base material, and preparing slurry of a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer and a release layer according to a formula; the preparation method of the surface flame-retardant wear-resistant anti-skid layer comprises the following steps: adding the modified phenolic resin into methyl isobutyl ketone, adding the flame-retardant acrylate and the nitrile rubber, mixing and dispersing at 90-120 ℃ for 5-10min, and filtering to obtain the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive; adding silicon carbide nano particles, metal aluminum particles and wear-resistant particles into the modified phenolic-nitrile rubber adhesive, uniformly mixing, adding a flame retardant, a curing agent, an initiator, a coupling agent, an anti-aging agent and an anti-mildew agent, uniformly mixing, and standing;
2) coating a primer on the surface of the substrate, and compounding the release layer obtained in the step 1);
3) coating the flame-retardant pressure-sensitive layer obtained in the step 1) on the base material obtained in the step 2);
4) coating the surface flame-retardant wear-resistant anti-slip layer obtained in the step 1) on the base material obtained in the step 3) to obtain a semi-finished adhesive tape product;
5) curing and rolling the semi-finished product of the adhesive tape obtained in the step 4) to obtain the anti-skid wear-resistant flame-retardant adhesive tape.
Example 3
Referring to fig. 1, the embodiment provides an anti-slip wear-resistant flame-retardant adhesive tape, which sequentially comprises a surface flame-retardant wear-resistant anti-slip layer 1, a substrate 2, a flame-retardant pressure-sensitive adhesive layer 3, and a release layer 4;
the surface flame-retardant wear-resistant anti-slip layer comprises the following components in parts by weight: 87 parts of modified phenolic-nitrile rubber adhesive, 27 parts of silicon carbide nanoparticles, 10 parts of metal aluminum particles, 10 parts of wear-resistant particles, 8 parts of flame retardant, 6 parts of curing agent, 5 parts of initiator, 2 parts of coupling agent, 2 parts of anti-aging agent and 2 parts of anti-mildew agent;
the flame-retardant pressure-sensitive adhesive layer comprises the following components in parts by weight: 17 parts of phosphorus acrylic acid monomer, 57 parts of butyl acrylate, 14 parts of methyl methacrylate, 6 parts of acrylic acid, 8 parts of allyl alcohol, 0.3 part of nitric acid, 5 parts of melamine, 5 parts of curing agent and 3 parts of initiator.
The substrate is flame retardant PE.
The release layer comprises the following components in parts by weight: 2.7 parts of non-silicone oil release agent, 0.3 part of cross-linking agent, 0.2 part of adhesive force additive, 0.2 part of release force regulator and 99.38 parts of solvent.
The wear-resistant particles consist of silicon dioxide, zirconium oxide and aluminum oxide in a mass ratio of 3:1: 5.
The flame retardant is 2, 3-dibromopropanol.
The curing agent is diphenylmethane diisocyanate; the coupling agent is KH-560; the anti-aging agent comprises the following components in a mass ratio of 1: 1, the hindered amine light stabilizer and the ultraviolet absorbent, and the anti-mildew agent is a silver hydroxyapatite antibacterial agent.
The thickness of the surface flame-retardant wear-resistant anti-slip layer is 200-800 mu m, the thickness of the flame-retardant pressure-sensitive adhesive layer is 30-100 mu m, the thickness of the base material is 25-250 mu m, and the thickness of the release layer is 0.1-50 mu m.
The preparation method comprises the following steps:
1) preparing a base material, and preparing slurry of a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer and a release layer according to a formula; the preparation method of the surface flame-retardant wear-resistant anti-skid layer comprises the following steps: adding the modified phenolic resin into methyl isobutyl ketone, adding the flame-retardant acrylate and the nitrile rubber, mixing and dispersing at 90-120 ℃ for 5-10min, and filtering to obtain the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive; adding silicon carbide nano particles, metal aluminum particles and wear-resistant particles into the modified phenolic-nitrile rubber adhesive, uniformly mixing, adding a flame retardant, a curing agent, an initiator, a coupling agent, an anti-aging agent and an anti-mildew agent, uniformly mixing, and standing;
2) coating a primer on the surface of the substrate, and compounding the release layer obtained in the step 1);
3) coating the flame-retardant pressure-sensitive layer obtained in the step 1) on the base material obtained in the step 2);
4) coating the surface flame-retardant wear-resistant anti-slip layer obtained in the step 1) on the base material obtained in the step 3) to obtain a semi-finished adhesive tape product;
5) curing and rolling the semi-finished product of the adhesive tape obtained in the step 4) to obtain the anti-skid wear-resistant flame-retardant adhesive tape.
Comparative example 1, the same as example 1, no surface flame retardant, abrasion resistant, and anti-slip layer was used.
Comparative example 2, the same as example 2, no wear resistant particles were added to the surface flame retardant wear resistant non-slip layer.
Comparative example 2, the same as example 3, silicon carbide nanoparticles and metallic aluminum particles were not added to the surface flame-retardant wear-resistant anti-slip layer.
The product properties are shown in Table 1, Table 2 and Table 3.
TABLE 1 product Property 1
TABLE 2 product Properties 2
As can be seen from tables 1 and 2, the outer surface of the anti-skid wear-resistant flame-retardant adhesive tape is a surface flame-retardant wear-resistant anti-skid layer, in order to improve the wear resistance, the wear-resistant particles are added to improve the wear resistance of the adhesive tape, and in order to ensure that the wear resistance has a better effect, the diameter of the wear-resistant particles is selected to be between 200 and 300 μm; in order to improve the anti-skid performance, silicon carbide nano particles and metal aluminum particles are added to improve the friction coefficient; the adhesive tape disclosed by the invention has the advantages of improved antiskid performance, better wear resistance, certain anti-mould performance and weather resistance, better flame retardance, good tensile tear resistance, difficulty in breaking, easiness in laminating and easiness in stripping after use.
Claims (10)
1. The anti-slip wear-resistant flame-retardant adhesive tape is characterized by comprising a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer, a base material and a release layer; the surface flame-retardant wear-resistant anti-slip layer comprises the following components in parts by weight: 60-87 parts of flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blended adhesive, 15-27 parts of silicon carbide nanoparticles, 5-10 parts of metal aluminum particles, 5-10 parts of wear-resistant particles, 3-8 parts of flame retardant, 2-6 parts of curing agent, 0.1-2 parts of coupling agent, 0.1-2 parts of anti-aging agent and 0.1-2 parts of anti-mildew agent.
2. The anti-slip wear-resistant flame-retardant adhesive tape according to claim 1, wherein the flame-retardant acrylate pressure-sensitive adhesive layer comprises the following components in parts by weight: 10-17 parts of phosphorus acrylic acid monomer, 42-57 parts of butyl acrylate, 8-14 parts of methyl methacrylate, 2-6 parts of acrylic acid, 4-10 parts of allyl alcohol, 0.1-0.5 part of nitric acid, 3-8 parts of melamine, 3-8 parts of curing agent and 2-4 parts of initiator.
3. The anti-slip, abrasion resistant and flame retardant adhesive tape according to claim 1, wherein said substrate comprises one of polyimide film, flame retardant polyester film, flame retardant PP, flame retardant PE or flame retardant PVC.
4. The anti-slip wear-resistant flame-retardant adhesive tape as claimed in claim 1, wherein the release layer comprises the following components in parts by weight: 0.5-3 parts of non-silicone oil release agent, 0.05-0.3 part of cross-linking agent, 0.02-0.2 part of adhesive force additive, 0.05-0.2 part of release force regulator and 96.3-99.38 parts of solvent.
5. The anti-slip wear-resistant flame-retardant adhesive tape according to any one of claims 1 to 4, wherein the wear-resistant particles comprise silica, zirconia and alumina in a mass ratio of 2 to 3:1:3 to 5.
6. The anti-slip, abrasion resistant and flame retardant tape of claim 5 wherein the flame retardant comprises one or more mixtures of dibromophenol, tetrabromophthalic anhydride or 2, 3-dibromopropanol.
7. The anti-slip, abrasion-resistant and flame-retardant adhesive tape according to claim 5, wherein the curing agent comprises toluene isocyanate or diphenylmethane diisocyanate; the coupling agent comprises a silane coupling agent KH-570, KH-560 or KH-550; the anti-aging agent comprises the following components in a mass ratio of 1: 1, the hindered amine light stabilizer and the ultraviolet absorbent, and the anti-mildew agent is a silver hydroxyapatite antibacterial agent.
8. The anti-slip wear-resistant flame-retardant adhesive tape as claimed in claim 5, wherein the thickness of the surface flame-retardant wear-resistant anti-slip layer is 200-800 μm, the thickness of the flame-retardant pressure-sensitive adhesive layer is 30-100 μm, the thickness of the substrate is 25-250 μm, and the thickness of the release layer is 0.1-50 μm.
9. A method for preparing the anti-slip wear-resistant flame-retardant adhesive tape according to any one of claims 1 to 8, wherein the method comprises the following steps:
1) preparing a base material, and preparing slurry of a surface flame-retardant wear-resistant anti-slip layer, a flame-retardant pressure-sensitive adhesive layer and a release layer according to a formula;
2) coating a primer on the surface of the substrate, and compounding the release layer obtained in the step 1);
3) coating the flame-retardant pressure-sensitive layer obtained in the step 1) on the base material obtained in the step 2);
4) coating the surface flame-retardant wear-resistant anti-slip layer obtained in the step 1) on the other surface of the base material obtained in the step 3) to obtain a semi-finished adhesive tape product;
5) curing and rolling the semi-finished product of the adhesive tape obtained in the step 4) to obtain the anti-skid wear-resistant flame-retardant adhesive tape.
10. The preparation method of the anti-slip wear-resistant flame-retardant adhesive tape according to claim 9, wherein in the step 1), the preparation method of the surface flame-retardant wear-resistant anti-slip layer comprises the following steps: adding the modified phenolic resin into methyl isobutyl ketone, adding the flame-retardant acrylate and the nitrile rubber, mixing and dispersing at 90-120 ℃ for 5-10min, and filtering to obtain the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive; adding silicon carbide nano particles, metal aluminum particles and wear-resistant particles into the flame-retardant modified phenolic-flame-retardant acrylate-nitrile rubber ternary blending adhesive, uniformly mixing, adding a flame retardant, a curing agent, a coupling agent, an anti-aging agent and an anti-mildew agent, uniformly mixing, and standing.
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| CN115340828A (en) * | 2022-07-04 | 2022-11-15 | 江西昊泽光学膜科技有限公司 | Lithium ion battery termination adhesive tape with corrosion resistance |
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Application publication date: 20211214 |