CN113789132A - Noctilucent easy-to-clean adhesive tape and preparation method thereof - Google Patents
Noctilucent easy-to-clean adhesive tape and preparation method thereof Download PDFInfo
- Publication number
- CN113789132A CN113789132A CN202111148502.5A CN202111148502A CN113789132A CN 113789132 A CN113789132 A CN 113789132A CN 202111148502 A CN202111148502 A CN 202111148502A CN 113789132 A CN113789132 A CN 113789132A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive tape
- agent
- weight
- easy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002390 adhesive tape Substances 0.000 title claims abstract description 61
- 230000003670 easy-to-clean Effects 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000010410 layer Substances 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 35
- 239000006260 foam Substances 0.000 claims abstract description 23
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 21
- 239000010703 silicon Substances 0.000 claims abstract description 21
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- 238000004140 cleaning Methods 0.000 claims abstract description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003063 flame retardant Substances 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 230000001954 sterilising effect Effects 0.000 claims abstract description 9
- 239000002216 antistatic agent Substances 0.000 claims abstract description 8
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 230000002335 preservative effect Effects 0.000 claims abstract description 8
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000002105 nanoparticle Substances 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims description 35
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 16
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- 239000006255 coating slurry Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 229920002545 silicone oil Polymers 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 7
- 238000013329 compounding Methods 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- ROHUXHMNZLHBSF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCC(CN=C=O)CC1 ROHUXHMNZLHBSF-UHFFFAOYSA-N 0.000 claims description 5
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 claims description 5
- LGNQGTFARHLQFB-UHFFFAOYSA-N 1-dodecyl-2-phenoxybenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1 LGNQGTFARHLQFB-UHFFFAOYSA-N 0.000 claims description 5
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 5
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 5
- JSHBAWMNSZLGGH-UHFFFAOYSA-N C(C=C)(=O)O.[P] Chemical compound C(C=C)(=O)O.[P] JSHBAWMNSZLGGH-UHFFFAOYSA-N 0.000 claims description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- PTIXVVCRANICNC-UHFFFAOYSA-N butane-1,1-diol;hexanedioic acid Chemical compound CCCC(O)O.OC(=O)CCCCC(O)=O PTIXVVCRANICNC-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 229910000449 hafnium oxide Inorganic materials 0.000 claims description 5
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 4
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000001632 sodium acetate Substances 0.000 claims description 4
- 235000017281 sodium acetate Nutrition 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- IFPMZBBHBZQTOV-UHFFFAOYSA-N 1,3,5-trinitro-2-(2,4,6-trinitrophenyl)-4-[2,4,6-trinitro-3-(2,4,6-trinitrophenyl)phenyl]benzene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(C=2C(=C(C=3C(=CC(=CC=3[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)C(=CC=2[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)=C1[N+]([O-])=O IFPMZBBHBZQTOV-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 238000005299 abrasion Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 241001391944 Commicarpus scandens Species 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 6
- -1 alcohol ester Chemical class 0.000 description 4
- FNAKEOXYWBWIRT-UHFFFAOYSA-N 2,3-dibromophenol Chemical compound OC1=CC=CC(Br)=C1Br FNAKEOXYWBWIRT-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- LADVLFVCTCHOAI-UHFFFAOYSA-N isocyanic acid;toluene Chemical compound N=C=O.CC1=CC=CC=C1 LADVLFVCTCHOAI-UHFFFAOYSA-N 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/50—Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2427/00—Presence of halogenated polymer
- C09J2427/006—Presence of halogenated polymer in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a noctilucent easy-to-clean adhesive tape and a preparation method thereof, the noctilucent easy-to-clean adhesive tape comprises a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises: the paint comprises water-based organic silicon modified polyacrylic resin miniemulsion, water-based fluororesin emulsion, pigment, nano oxide particles, nano-particle noctilucent powder, an anti-settling agent, an antistatic agent, a dispersing agent, a defoaming agent, a sterilization preservative, a pH regulator, a film forming agent, a thickening agent and deionized water. The adhesive tape provided by the invention has the advantages that the abrasion resistance is ensured, the easy cleaning performance is obviously improved, the adhesive tape has a noctilucent function, the adhesive tape can play a role in warning and reminding in a dark environment, the practicability of the adhesive tape is improved, the adhesive tape also has good flame retardant performance and antistatic performance, the tensile and tear resistance is good, the adhesive tape is not easy to break and easy to attach, the adhesive tape is easy to peel off after being used, the wide and long-length production can be realized greatly, and the large-area construction is convenient.
Description
Technical Field
The invention belongs to the technical field of adhesive tapes, relates to an adhesive tape, and particularly relates to a noctilucent easy-to-clean adhesive tape with good wear resistance, good elasticity and a noctilucent function and a preparation method thereof.
Background
With the development of economy and the advancement of science and technology, China has become a processing and producing factory and a consuming nation of the world adhesive industry. The adhesive tape can be divided into: high-temperature adhesive tapes, double-sided adhesive tapes, insulating adhesive tapes, special adhesive tapes, pressure-sensitive adhesive tapes and die-cutting adhesive tapes are widely applied to the industries of electronics, communication, packaging, construction, papermaking, woodworking, aerospace, automobiles, textile, metallurgy, mechanical manufacturing, medical treatment and the like according to different effects, and the adhesive industry becomes the most active important industry in the chemical industry in China. The existing adhesive tape is generally composed of a base material and an adhesive, two or more unconnected objects are connected together through adhesion, and the existing adhesive tape has the defects of insufficient wear resistance, poor elasticity and difficult cleaning in the use environment.
Disclosure of Invention
The invention aims to solve the problems of insufficient wear resistance, poor elasticity and difficult cleaning of the existing adhesive tape, and provides a noctilucent easy-to-clean adhesive tape which has good wear resistance and elasticity and has a noctilucent function.
The invention also aims to provide a preparation method of the noctilucent easy-cleaning adhesive tape.
In order to achieve the purpose, the invention adopts the following technical scheme:
the noctilucent easy-cleaning adhesive tape comprises a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises the following components in parts by weight: 100-200 parts of water-based organic silicon modified polyacrylic resin miniemulsion, 50-100 parts of water-based fluororesin emulsion, 200-400 parts of pigment, 10-100 parts of nano oxide particles, 10-100 parts of nano particle noctilucent powder, 2-5 parts of anti-settling agent, 10-12 parts of antistatic agent, 1-4 parts of dispersing agent, 1-3 parts of defoaming agent, 0.1-1 part of sterilizing preservative, 0.5-2 parts of pH regulator, 10-15 parts of film forming agent, 1-4 parts of thickening agent and 60-200 parts of deionized water.
In the technical scheme of the invention, the fluorosilicone emulsion with low surface energy is used as the main material of the surface layer to realize easy cleaning performance, the nano oxide particles are added to be dispersed in the surface layer to improve the wear resistance of the surface layer, a certain amount of antistatic agent and sterilization preservative are added to improve the antistatic performance and sterilization and corrosion resistance of the adhesive tape, and the nano particle noctilucent powder is added to have better noctilucent effect, long noctilucent afterglow time which can reach more than ten hours and practicability, so that the adhesive tape has noctilucent effect.
As a preferable embodiment of the present invention, the preparation method of the aqueous silicone modified polyacrylic resin miniemulsion comprises: the water-based organic silicon modified polyacrylic resin miniemulsion is prepared by taking 10-15 parts by weight of methyl methacrylate and 15-25 parts by weight of n-butyl acrylate as acrylate comonomers, taking 1-5 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 10-15 parts by weight of methyl triethoxy silane as functional organic silicon monomers and adopting a miniemulsion polymerization method.
According to the technical scheme, Methyl Methacrylate (MMA) and n-Butyl Acrylate (BA) are used as acrylate comonomers, 3- (methacryloyloxy) propyl trimethoxy silane (MEMO) and methyl triethoxy silane (MTMS) are used as functional organosilicon monomers, and an organosilicon modified polyacrylate miniemulsion is prepared by adopting a miniemulsion polymerization method. The applicability of the methyltriethoxysilane can be improved by adjusting the hydrolysis emulsification time, the particle size and the distribution of the monomer miniemulsion are effectively reduced, the standing stability of the monomer miniemulsion is improved, and the particle size is reduced more, the particle size distribution is narrower and the stability is higher along with the increase of the siloxane content.
In a preferred embodiment of the present invention, the aqueous fluororesin emulsion is prepared by a method comprising: 20-30 parts by weight of 1H,1H, 7H-dodecafluoro-1-heptyloxy sodium acetate is used as an emulsifier, and binary or ternary copolymerization is carried out on 45-65 parts by weight of vinylidene fluoride and 10-20 parts by weight of chlorotrifluoroethylene or 10-20 parts by weight of vinyl ether monomers to obtain the aqueous fluororesin emulsion.
In a preferred embodiment of the present invention, the nano-oxide particles are a mixture of hafnium oxide, silicon oxide, zirconium oxide and titanium oxide in a mass ratio of 2-4:1:1-3: 1-5.
As a preferable scheme of the invention, the film forming agent comprises a mixture of alcohol ester twelve and isopropanol in a mass ratio of 1: 3-5.
As a preferable scheme of the invention, the release layer comprises the following components in parts by weight: 0.5-3 parts of non-silicone oil release agent, 0.05-0.3 part of cross-linking agent, 0.02-0.2 part of adhesive force additive, 0.05-0.2 part of release force regulator and 96.3-99.38 parts of solvent.
As a preferable scheme of the invention, the pressure-sensitive adhesive layer comprises the following components in parts by weight: 10-17 parts of phosphorus acrylic acid monomer, 42-57 parts of butyl acrylate, 8-14 parts of methyl methacrylate, 2-6 parts of acrylic acid, 4-10 parts of allyl alcohol, 0.1-0.5 part of nitric acid, 3-8 parts of melamine, 3-8 parts of curing agent and 2-4 parts of initiator.
As a preferred embodiment of the present invention, the primer layer comprises the following components in parts by weight: 20-40 parts of acrylic acid, 10-20 parts of methyl acrylate, 10-20 parts of ethyl acrylate, 10-20 parts of 2-ethylhexyl acrylate, 10-20 parts of methyl methacrylate, 20-40 parts of butyl acrylate, 5-10 parts of dimethylolpropionic acid, 5-8 parts of triethylamine, 3-5 parts of a silane coupling agent, 3-5 parts of a sealing agent, 5-15 parts of dodecyl diphenyl ether disulfonic acid, 3-5 parts of a tackifier, 3-5 parts of aqueous silicone oil and 400 parts of 200-ion water.
As a preferable scheme of the invention, the elastic foam layer comprises the following components in parts by weight: 10-30 parts of polytetramethylene ether glycol, 30-45 parts of propylene oxide-ethylene oxide copolyether triol, 25-35 parts of polyethylene glycol butanediol adipate, 16-30 parts of 1, 4-bis (isocyanatomethyl) cyclohexane, 5-12 parts of diethylene glycol, 0.5-2 parts of HDI trimer, 0.05-1 part of catalyst, 0.2-1 part of foaming agent and 0.1-2 parts of flame retardant.
In the technical scheme, the elastic foam layer takes polyether polyol (N-220, 330N) and Hexamethylene Diisocyanate (HDI) as main raw materials and diethylene glycol (DEG) as a micromolecular chain extender to synthesize an-OH-terminated PU (polyurethane) prepolymer; then adding a proper amount of HDI tripolymer, catalyst, foaming agent and flame retardant, preparing the PU foam PSA under a certain temperature condition, and coating the PU foam PSA on the surface of the substrate to form an elastic foam layer.
The invention also provides a preparation method of the noctilucent easy-cleaning adhesive tape, which comprises the following steps:
1) preparing surface coating slurry, elastic foam layer slurry, bottom coating slurry, pressure-sensitive adhesive layer slurry and release layer slurry according to a formula, and preparing a base film;
2) coating the base coat slurry obtained in the step 1) on the surface of the base film, drying, coating the elastic foam layer slurry obtained in the step 1), and compounding the surface coating slurry obtained in the step 1) to obtain a semi-finished base film;
3) coating the pressure-sensitive adhesive layer slurry obtained in the step 1) on the surface of the semi-finished base film obtained in the step 2), compounding the release layer slurry, and curing to obtain the noctilucent easy-to-clean adhesive tape.
Compared with the prior art, the invention has the following beneficial effects:
1) the adhesive tape has the advantages that the abrasion resistance is guaranteed, the cleaning performance is obviously improved, the adhesive tape has the noctilucent function, the adhesive tape can give a warning prompt in a dark environment, and the practicability of the adhesive tape is improved;
2) the adhesive tape also has better flame retardant property and antistatic property;
3) the adhesive tape has good tensile tear resistance, is not easy to break, is easy to attach, is easy to peel after being used, can realize large-width and large-length production, and is convenient to construct in a large area;
4) the adhesive tape has wide application range, and can be applied to the fields of emergency channels of high-rise buildings, frozen warehouses, schools, hospitals, fire signs, ship applications, underground operations and the like.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The raw materials and the method used in the invention are all available, if not specified.
The anti-settling agent, the antistatic agent, the dispersing agent, the defoaming agent, the sterilization preservative, the pH regulator and the thickening agent used in the invention are all auxiliary agents commonly used in the industry, and are not described herein again.
The pigment used in the invention comprises one or a combination of more of rutile, titanium dioxide, aluminum tripolyphosphate, zinc phosphate, iron oxide red, carbon black, lemon chrome yellow, superfine talcum powder, light calcium carbonate, superfine barium sulfate or superfine mica powder. It is used for providing various colors including black, middle gray, date red, orange, blue, black and yellow, red and white, transparent, reflective, luminous and the like, and can also be used for fixing colors and printing patterns according to the requirements of customers.
Example 1
The embodiment provides a luminous easy-to-clean adhesive tape, which comprises a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises the following components in parts by weight: 100 parts of water-based organic silicon modified polyacrylic resin miniemulsion, 50 parts of water-based fluororesin emulsion, 200 parts of pigment (the pigment is 100 parts of rutile, 50 parts of carbon black and 50 parts of lemon chrome yellow), 10 parts of nano oxide particles, 10 parts of nano particle noctilucent powder, 2 parts of anti-settling agent, 10 parts of antistatic agent, 1 part of dispersing agent, 1 part of defoaming agent, 0.1 part of sterilization preservative, 0.5 part of pH regulator, 10 parts of film forming agent, 1 part of thickening agent and 60 parts of deionized water; the preparation method of the water-based organic silicon modified polyacrylic resin miniemulsion comprises the following steps: the water-based organic silicon modified polyacrylic resin miniemulsion is prepared by taking 10 parts by weight of methyl methacrylate and 15 parts by weight of n-butyl acrylate as acrylate comonomers, taking 5 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 15 parts by weight of methyltriethoxy silane as functional organic silicon monomers and adopting a miniemulsion polymerization method (the miniemulsion polymerization method is the prior art and is not described any more).
The preparation method of the water-based fluororesin emulsion comprises the following steps: the water-based organic silicon modified polyacrylic resin miniemulsion is prepared by taking 10 parts by weight of methyl methacrylate and 15 parts by weight of n-butyl acrylate as acrylate comonomers, taking 5 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 15 parts by weight of methyltriethoxy silane as functional organic silicon monomers and adopting a miniemulsion polymerization method (the miniemulsion polymerization method is the prior art and is not described any more).
The nano oxide particles are a mixture of hafnium oxide, silicon oxide, zirconium oxide and titanium oxide in a mass ratio of 2:1:1: 1.
The film forming agent is a mixture of alcohol ester twelve and isopropanol in a mass ratio of 1: 3.
The release layer comprises the following components in parts by weight: 0.5 part of non-silicone oil release agent, 0.05 part of cross-linking agent, 0.02 part of adhesive force additive, 0.05 part of release force regulator and 96.3 parts of solvent; wherein the non-silicone oil release agent is K1000, the cross-linking agent is benzoyl peroxide, the adhesion additive is a titanic acid coupling agent, the release force regulator is straight-chain alkane, and the solvent is butanone.
The pressure-sensitive adhesive layer comprises the following components in parts by weight: 10 parts of phosphorus acrylic acid monomer, 42 parts of butyl acrylate, 8 parts of methyl methacrylate, 2 parts of acrylic acid, 4 parts of allyl alcohol, 0.1 part of nitric acid, 3 parts of melamine, 3 parts of curing agent toluene isocyanate and 2 parts of initiator ammonium persulfate.
The base coat comprises the following components in parts by weight: 40 parts of acrylic acid, 20 parts of methyl acrylate, 20 parts of ethyl acrylate, 20 parts of 2-ethylhexyl acrylate, 20 parts of methyl methacrylate, 40 parts of butyl acrylate, 10 parts of dimethylolpropionic acid, 8 parts of triethylamine, 5 parts of a silane coupling agent, 5 parts of a sealing agent, 15 parts of dodecyl diphenyl ether disulfonic acid, 5 parts of a tackifier, 5 parts of aqueous silicone oil and 400 parts of deionized water.
The elastic foam layer comprises the following components in parts by weight: 10 parts of polytetramethylene ether glycol, 30 parts of propylene oxide-ethylene oxide copolyether triol, 25 parts of polyethylene glycol butanediol adipate, 16 parts of 1, 4-bis (isocyanatomethyl) cyclohexane, 5 parts of diethylene glycol, 0.5 part of HDI trimer, 0.05 part of organic bismuth catalyst, 0.2 part of foaming agent cyclopentane and 0.1 part of flame retardant dibromophenol.
The preparation method of the noctilucent easy-cleaning adhesive tape comprises the following steps:
1) preparing surface coating slurry, elastic foam layer slurry, bottom coating slurry, pressure-sensitive adhesive layer slurry and release layer slurry according to a formula, and preparing base film flame-retardant PVC with the thickness of 25-250 mu m;
2) coating the base coat slurry (with the thickness of 1-5 microns) obtained in the step 1) on the surface of the base film, drying, coating the elastic foam layer slurry (with the thickness of 50-150 microns) obtained in the step 1), and compounding the surface coating slurry (with the thickness of 1-5 microns) obtained in the step 1) to obtain a semi-finished base film;
3) coating the pressure-sensitive adhesive layer slurry (with the thickness of 30-100 microns) obtained in the step 1) and the composite release layer slurry (with the thickness of 0.1-50 microns) on the surface of the semi-finished base film obtained in the step 2), and curing to obtain the noctilucent easy-to-clean adhesive tape.
Example 2
The embodiment provides a luminous easy-to-clean adhesive tape, which comprises a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises the following components in parts by weight: 150 parts of water-based organic silicon modified polyacrylic resin miniemulsion, 80 parts of water-based fluororesin emulsion, 300 parts of pigment (the pigment is 50 parts of iron oxide red, 100 parts of carbon black, 20 parts of titanium dioxide, 30 parts of superfine talcum powder and 100 parts of rutile), 80 parts of nano oxide particles, 55 parts of nano particle luminous powder, 3 parts of anti-settling agent, 11 parts of antistatic agent, 3 parts of dispersing agent, 2 parts of defoaming agent, 0.5 part of sterilization preservative, 1.5 parts of pH regulator, 12 parts of film forming agent, 3 parts of thickening agent and 100 parts of deionized water; the preparation method of the water-based organic silicon modified polyacrylic resin miniemulsion comprises the following steps: 15 parts by weight of methyl methacrylate and 25 parts by weight of n-butyl acrylate are taken as acrylate comonomers, 5 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 15 parts by weight of methyltriethoxy silane are taken as functional organic silicon monomers, and a miniemulsion polymerization method is adopted to prepare the water-based organic silicon modified polyacrylic resin miniemulsion.
The preparation method of the water-based fluororesin emulsion comprises the following steps: 30 parts by weight of 1H,1H, 7H-dodecafluoro-1-heptyloxy sodium acetate is used as an emulsifier, and 65 parts by weight of vinylidene fluoride, 20 parts by weight of chlorotrifluoroethylene and 20 parts by weight of vinyl ether monomers are subjected to ternary polymerization to obtain the aqueous fluororesin emulsion. .
The nano oxide particles are a mixture of hafnium oxide, silicon oxide, zirconium oxide and titanium oxide in a mass ratio of 3:1:2: 3.
The film forming agent is a mixture of alcohol ester twelve and isopropanol in a mass ratio of 1: 4.
The release layer comprises the following components in parts by weight: 3 parts of non-silicone oil release agent, 0.2 part of cross-linking agent, 0.15 part of adhesive force additive, 0.17 part of release force regulator and 97.66 parts of solvent; wherein the non-silicone oil release agent is K1000, the cross-linking agent is benzoyl peroxide, the adhesion additive is a titanic acid coupling agent, the release force regulator is straight-chain alkane, and the solvent is butanone.
The pressure-sensitive adhesive layer comprises the following components in parts by weight: 15 parts of phosphorus acrylic acid monomer, 47 parts of butyl acrylate, 10 parts of methyl methacrylate, 3 parts of acrylic acid, 10 parts of allyl alcohol, 0.5 part of nitric acid, 8 parts of melamine, 8 parts of curing agent diphenylmethane diisocyanate and 4 parts of initiator ammonium persulfate.
The base coat comprises the following components in parts by weight: 30 parts of acrylic acid, 18 parts of methyl acrylate, 15 parts of ethyl acrylate, 15 parts of 2-ethylhexyl acrylate, 12 parts of methyl methacrylate, 25 parts of butyl acrylate, 7 parts of dimethylolpropionic acid, 6 parts of triethylamine, 4 parts of a silane coupling agent, 3.5 parts of a sealing agent, 7 parts of dodecyl diphenyl ether disulfonic acid, 4 parts of a tackifier, 3 parts of aqueous silicone oil and 300 parts of deionized water.
The elastic foam layer comprises the following components in parts by weight: 20 parts of polytetramethylene ether glycol, 35 parts of propylene oxide-ethylene oxide copolyether triol, 30 parts of polyethylene glycol butanediol adipate, 22 parts of 1, 4-bis (isocyanatomethyl) cyclohexane, 10 parts of diethylene glycol, 1 part of HDI trimer, 0.5 part of an organic bismuth catalyst, 0.7 part of a foaming agent HFC-245fa and 1.2 parts of a flame retardant dibromophenol.
The preparation method of the noctilucent easy-cleaning adhesive tape comprises the following steps:
1) preparing surface coating slurry, elastic foam layer slurry, bottom coating slurry, pressure-sensitive adhesive layer slurry and release layer slurry according to a formula, and preparing base film flame-retardant PVC with the thickness of 25-250 mu m;
2) coating the base coat slurry (with the thickness of 1-5 microns) obtained in the step 1) on the surface of the base film, drying, coating the elastic foam layer slurry (with the thickness of 50-150 microns) obtained in the step 1), and compounding the surface coating slurry (with the thickness of 1-5 microns) obtained in the step 1) to obtain a semi-finished base film;
3) coating the pressure-sensitive adhesive layer slurry (with the thickness of 30-100 microns) obtained in the step 1) and the composite release layer slurry (with the thickness of 0.1-50 microns) on the surface of the semi-finished base film obtained in the step 2), and curing to obtain the noctilucent easy-to-clean adhesive tape.
Example 3
The embodiment provides a luminous easy-to-clean adhesive tape, which comprises a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises the following components in parts by weight: 200 parts of water-based organic silicon modified polyacrylic resin miniemulsion, 100 parts of water-based fluororesin emulsion, 400 parts of pigment (the pigment is 200 parts of iron oxide red, 150 parts of titanium dioxide and 50 parts of superfine mica powder), 100 parts of nano oxide particles, 100 parts of nano particle luminous powder, 5 parts of anti-settling agent, 12 parts of antistatic agent, 4 parts of dispersing agent, 3 parts of defoaming agent, 1 part of sterilizing preservative, 2 parts of pH regulator, 15 parts of film forming agent, 4 parts of thickening agent and 200 parts of deionized water; the preparation method of the water-based organic silicon modified polyacrylic resin miniemulsion comprises the following steps: the water-based organic silicon modified polyacrylic resin miniemulsion is prepared by using 12 parts by weight of methyl methacrylate and 20 parts by weight of n-butyl acrylate as acrylate comonomers, using 3 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 12 parts by weight of methyl triethoxy silane as functional organic silicon monomers and adopting a miniemulsion polymerization method.
The preparation method of the water-based fluororesin emulsion comprises the following steps: 25 parts by weight of 1H,1H, 7H-dodecafluoro-1-heptyloxy sodium acetate is used as an emulsifier, and 50 parts by weight of vinylidene fluoride, 18 parts by weight of chlorotrifluoroethylene and 17 parts by weight of vinyl ether monomers are subjected to ternary polymerization to obtain the aqueous fluororesin emulsion.
The nano-oxide particles are a mixture of hafnium oxide, silicon oxide, zirconium oxide and titanium oxide in a mass ratio of 4:1:3: 5.
The film forming agent is a mixture of alcohol ester twelve and isopropanol with the mass ratio of 1: 5.
The release layer comprises the following components in parts by weight: 2.7 parts of non-silicone oil release agent, 0.3 part of cross-linking agent, 0.2 part of adhesive force additive, 0.2 part of release force regulator and 99.38 parts of solvent; wherein the non-silicone oil release agent is K1000, the cross-linking agent is benzoyl peroxide, the adhesion additive is a titanic acid coupling agent, the release force regulator is straight-chain alkane, and the solvent is butanone.
The pressure-sensitive adhesive layer comprises the following components in parts by weight: 17 parts of phosphorus acrylic acid monomer, 57 parts of butyl acrylate, 14 parts of methyl methacrylate, 6 parts of acrylic acid, 8 parts of allyl alcohol, 0.3 part of nitric acid, 5 parts of melamine, 5 parts of curing agent diphenylmethane diisocyanate and 3 parts of initiator ammonium persulfate.
The base coat comprises the following components in parts by weight: 20 parts of acrylic acid, 10 parts of methyl acrylate, 10 parts of ethyl acrylate, 10 parts of 2-ethylhexyl acrylate, 10 parts of methyl methacrylate, 20 parts of butyl acrylate, 5 parts of dimethylolpropionic acid, 5 parts of triethylamine, 3 parts of a silane coupling agent, 3 parts of a sealing agent, 5 parts of dodecyl diphenyl ether disulfonic acid, 3 parts of a tackifier, 3 parts of aqueous silicone oil and 200 parts of deionized water.
The elastic foam layer comprises the following components in parts by weight: 30 parts of polytetramethylene ether glycol, 45 parts of propylene oxide-ethylene oxide copolyether triol, 35 parts of polyethylene glycol butanediol adipate, 30 parts of 1, 4-bis (isocyanatomethyl) cyclohexane, 12 parts of diethylene glycol, 2 parts of HDI trimer, 1 part of an organic bismuth catalyst, 1 part of a foaming agent HFC-245fa and 2 parts of a flame retardant dibromophenol.
The preparation method of the noctilucent easy-cleaning adhesive tape comprises the following steps:
1) preparing surface coating slurry, elastic foam layer slurry, bottom coating slurry, pressure-sensitive adhesive layer slurry and release layer slurry according to a formula, and preparing base film flame-retardant PVC with the thickness of 25-250 mu m;
2) coating the base coat slurry (with the thickness of 1-5 microns) obtained in the step 1) on the surface of the base film, drying, coating the elastic foam layer slurry (with the thickness of 50-150 microns) obtained in the step 1), and compounding the surface coating slurry (with the thickness of 1-5 microns) obtained in the step 1) to obtain a semi-finished base film;
3) coating the pressure-sensitive adhesive layer slurry (with the thickness of 30-100 microns) obtained in the step 1) and the composite release layer slurry (with the thickness of 0.1-50 microns) on the surface of the semi-finished base film obtained in the step 2), and curing to obtain the noctilucent easy-to-clean adhesive tape.
Comparative example 1, same as example 1, except that the surface layer was not coated.
Comparative example 2, same as example 1, except that no aqueous silicone-modified polyacrylic resin miniemulsion was added to the surface layer.
Comparative example 3, the same as example 1, except that no nano-oxide particles were added to the surface layer.
The product properties are shown in Table 1.
TABLE 1 Performance data
As can be seen from Table 1, comparative example 1 has no surface coating, so that both easy-cleaning property and abrasion resistance are poor; comparative example 2 no aqueous silicone-modified polyacrylic resin miniemulsion was added, the easy-to-clean performance was inferior to that of example 1, and the friction coefficient and wear rate were comparable to those of example 1; in contrast, comparative example 3, in which no nano-oxide particles were added, had an easy-to-clean performance comparable to that of example 1, and had a friction coefficient and a wear rate substantially different from those of example 1.
Therefore, the adhesive tape provided by the invention has the advantages that the abrasion resistance is ensured, the easy-cleaning performance is obviously improved, and the adhesive tape has certain anti-mould performance and weather resistance; meanwhile, the adhesive tape disclosed by the invention uses the noctilucent powder, so that the adhesive tape has a noctilucent function.
While the invention has been described with respect to a preferred embodiment, it will be understood by those skilled in the art that the foregoing and other changes, omissions and deviations in the form and detail thereof may be made without departing from the scope of this invention. Those skilled in the art can make various changes, modifications and equivalent arrangements, which are equivalent to the embodiments of the present invention, without departing from the spirit and scope of the present invention, and which may be made by utilizing the techniques disclosed above; meanwhile, any changes, modifications and variations of the above-described embodiments, which are equivalent to those of the technical spirit of the present invention, are within the scope of the technical solution of the present invention.
Claims (10)
1. The noctilucent easy-cleaning adhesive tape is characterized by comprising a base film, a surface coating, an elastic foam layer, a bottom coating, a pressure-sensitive adhesive layer and a release layer, wherein the surface coating comprises the following components in parts by weight: 100-200 parts of water-based organic silicon modified polyacrylic resin miniemulsion, 50-100 parts of water-based fluororesin emulsion, 200-400 parts of pigment, 10-100 parts of nano oxide particles, 10-100 parts of nano particle noctilucent powder, 2-5 parts of anti-settling agent, 10-12 parts of antistatic agent, 1-4 parts of dispersing agent, 1-3 parts of defoaming agent, 0.1-1 part of sterilizing preservative, 0.5-2 parts of pH regulator, 10-15 parts of film forming agent, 1-4 parts of thickening agent and 60-200 parts of deionized water.
2. A luminous easy-to-clean adhesive tape as claimed in claim 1, characterized in that the preparation method of the water-based silicone modified polyacrylic resin miniemulsion comprises: the water-based organic silicon modified polyacrylic resin miniemulsion is prepared by taking 10-15 parts by weight of methyl methacrylate and 15-25 parts by weight of n-butyl acrylate as acrylate comonomers, taking 1-5 parts by weight of 3- (methacryloyloxy) propyl trimethoxy silane and 10-15 parts by weight of methyl triethoxy silane as functional organic silicon monomers and adopting a miniemulsion polymerization method.
3. A luminous easy-to-clean adhesive tape as defined in claim 1, wherein the aqueous fluororesin emulsion is prepared by the following steps: 20-30 parts by weight of 1H,1H, 7H-dodecafluoro-1-heptyloxy sodium acetate is used as an emulsifier, and binary or ternary copolymerization is carried out on 45-65 parts by weight of vinylidene fluoride and 10-20 parts by weight of chlorotrifluoroethylene or 10-20 parts by weight of vinyl ether monomers to obtain the aqueous fluororesin emulsion.
4. A luminous easy-to-clean adhesive tape as claimed in claim 1, wherein the nano oxide particles are a mixture of hafnium oxide, silicon oxide, zirconium oxide and titanium oxide in a mass ratio of 2-4:1:1-3: 1-5.
5. A luminous easy-to-clean adhesive tape as claimed in claim 1, wherein the film former comprises a mixture of alcohol ester dodeca and isopropanol in a mass ratio of 1: 3-5.
6. A luminous easy-to-clean adhesive tape according to any one of claims 1 to 5, characterized in that the release layer comprises the following components in parts by weight: 0.5-3 parts of non-silicone oil release agent, 0.05-0.3 part of cross-linking agent, 0.02-0.2 part of adhesive force additive, 0.05-0.2 part of release force regulator and 96.3-99.38 parts of solvent.
7. A luminous easy-to-clean adhesive tape according to any one of claims 1 to 5, characterized in that the pressure-sensitive adhesive layer comprises the following components in parts by weight: 10-17 parts of phosphorus acrylic acid monomer, 42-57 parts of butyl acrylate, 8-14 parts of methyl methacrylate, 2-6 parts of acrylic acid, 4-10 parts of allyl alcohol, 0.1-0.5 part of nitric acid, 3-8 parts of melamine, 3-8 parts of curing agent and 2-4 parts of initiator.
8. A luminous easy-to-clean adhesive tape according to any one of claims 1 to 5, characterized in that the primer layer comprises the following components in parts by weight: 20-40 parts of acrylic acid, 10-20 parts of methyl acrylate, 10-20 parts of ethyl acrylate, 10-20 parts of 2-ethylhexyl acrylate, 10-20 parts of methyl methacrylate, 20-40 parts of butyl acrylate, 5-10 parts of dimethylolpropionic acid, 5-8 parts of triethylamine, 3-5 parts of a silane coupling agent, 3-5 parts of a sealing agent, 5-15 parts of dodecyl diphenyl ether disulfonic acid, 3-5 parts of a tackifier, 3-5 parts of aqueous silicone oil and 400 parts of 200-ion water.
9. A luminous easy-to-clean adhesive tape according to any one of claims 1 to 5, characterized in that the elastic foam layer comprises the following components in parts by weight: 10-30 parts of polytetramethylene ether glycol, 30-45 parts of propylene oxide-ethylene oxide copolyether triol, 25-35 parts of polyethylene glycol butanediol adipate, 16-30 parts of 1, 4-bis (isocyanatomethyl) cyclohexane, 5-12 parts of diethylene glycol, 0.5-2 parts of HDI trimer, 0.05-1 part of catalyst, 0.2-1 part of foaming agent and 0.1-2 parts of flame retardant.
10. A method for preparing a luminous easy-to-clean adhesive tape as defined in any one of claims 1 to 9, which comprises the following steps:
1) preparing surface coating slurry, elastic foam layer slurry, bottom coating slurry, pressure-sensitive adhesive layer slurry and release layer slurry according to a formula, and preparing a base film;
2) coating the base coat slurry obtained in the step 1) on the surface of the base film, drying, coating the elastic foam layer slurry obtained in the step 1), and compounding the surface coating slurry obtained in the step 1) to obtain a semi-finished base film;
3) coating the pressure-sensitive adhesive layer slurry obtained in the step 1) on the surface of the semi-finished base film obtained in the step 2), compounding the release layer slurry, and curing to obtain the noctilucent easy-to-clean adhesive tape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111148502.5A CN113789132A (en) | 2021-09-27 | 2021-09-27 | Noctilucent easy-to-clean adhesive tape and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111148502.5A CN113789132A (en) | 2021-09-27 | 2021-09-27 | Noctilucent easy-to-clean adhesive tape and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113789132A true CN113789132A (en) | 2021-12-14 |
Family
ID=78877484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111148502.5A Pending CN113789132A (en) | 2021-09-27 | 2021-09-27 | Noctilucent easy-to-clean adhesive tape and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113789132A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067062A (en) * | 2007-06-08 | 2007-11-07 | 东莞拓扑实业有限公司 | High performance outer wall paint and its prepn |
| CN107603503A (en) * | 2017-08-30 | 2018-01-19 | 浙江欧丽数码喷绘材料有限公司 | A kind of waterborne flame retardant bright gum PVC and preparation method thereof in vain |
| CN108084927A (en) * | 2016-11-19 | 2018-05-29 | 辽宁东夫材料科技有限公司 | A kind of water soluble acrylic acid adhesive and preparation method thereof |
| CN208471975U (en) * | 2018-05-17 | 2019-02-05 | 昆山锦悦电子有限公司 | A kind of multifunctional protection film |
| CN109575828A (en) * | 2018-12-06 | 2019-04-05 | 浙江欧仁新材料有限公司 | Heat resistant type foam double-faced adhesive band and preparation method thereof |
| CN110003752A (en) * | 2019-04-15 | 2019-07-12 | 深圳市普利司德高分子材料有限公司 | A kind of release film protective film technological process of production |
-
2021
- 2021-09-27 CN CN202111148502.5A patent/CN113789132A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067062A (en) * | 2007-06-08 | 2007-11-07 | 东莞拓扑实业有限公司 | High performance outer wall paint and its prepn |
| CN108084927A (en) * | 2016-11-19 | 2018-05-29 | 辽宁东夫材料科技有限公司 | A kind of water soluble acrylic acid adhesive and preparation method thereof |
| CN107603503A (en) * | 2017-08-30 | 2018-01-19 | 浙江欧丽数码喷绘材料有限公司 | A kind of waterborne flame retardant bright gum PVC and preparation method thereof in vain |
| CN208471975U (en) * | 2018-05-17 | 2019-02-05 | 昆山锦悦电子有限公司 | A kind of multifunctional protection film |
| CN109575828A (en) * | 2018-12-06 | 2019-04-05 | 浙江欧仁新材料有限公司 | Heat resistant type foam double-faced adhesive band and preparation method thereof |
| CN110003752A (en) * | 2019-04-15 | 2019-07-12 | 深圳市普利司德高分子材料有限公司 | A kind of release film protective film technological process of production |
Non-Patent Citations (4)
| Title |
|---|
| 惠文华等: "《摩擦学与耐磨性设计》", 30 November 1993, 东南大学出版社 * |
| 王颖欣等: "有机硅改性聚丙烯酸酯细乳液的制备", 《化学反应工程与工艺》 * |
| 翟丛丛: "含氟水性涂料的制备", 《中国优秀硕士学位论文全文数据库工程科技I辑》 * |
| 陈泽森等: "《水性建筑涂料生产技术》", 31 January 2017, 中国纺织出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111087950B (en) | Adhesive, double-sided tape applying adhesive and preparation method of double-sided tape | |
| CN102027089B (en) | Adhesive sheet for protecting coating film | |
| CN103360968A (en) | Surface protecting film | |
| CN102712184B (en) | Weatherable sheet for solar cell module, product obtained using the sheet, and process for producing the weatherable sheet for solar cell module | |
| CN105199593A (en) | Modified polyurethane fireproof coating with wear resistance | |
| CN105348946A (en) | Matt release film | |
| CN103547647B (en) | Adhesive composition for multilayer sheets, and backside protective sheet for solar cells | |
| CN105452409A (en) | Adhesive sheet | |
| CN103534325B (en) | Laminated chip adhesive composition and solar cell backside protective sheet | |
| CN101191029A (en) | Primer composition for metal substrate and its preparation method and multilayer coat | |
| EP3246371B1 (en) | Anti-fouling composition, and anti-fouling sheet | |
| CN102911568A (en) | Aqueous fluorine carbon coating material and preparation technology thereof | |
| WO2019016754A1 (en) | Flexible conductive display film | |
| CN103045030B (en) | A kind of waterproof paint | |
| CN104745071A (en) | Polyurethane waterproof flame-retardant paint and preparation method thereof | |
| TW201600577A (en) | Double-sided adhesive sheet | |
| JP2021130802A (en) | Surface coating solution composition and polyester film structure | |
| CN113789132A (en) | Noctilucent easy-to-clean adhesive tape and preparation method thereof | |
| CN113913111A (en) | Coating and rolling combined integrated waterproof coiled material and preparation method thereof | |
| CN104845482A (en) | High-adhesion shock-resistant anti-corrosion mechanical paint | |
| KR101564658B1 (en) | Optical film | |
| CN213767552U (en) | Diaphragm with micro-nano grating structure | |
| US10316195B2 (en) | Zinc-based composite material and use thereof | |
| CN113930159A (en) | Flame-retardant macromolecular self-adhesive film waterproof roll and preparation method thereof | |
| CN103525280A (en) | Formula of spray polyurea high-strength elastic waterproof coating and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211214 |