CN113788662A - Single-component polyethylene polypropylene fiber waterproof coiled material adhesive - Google Patents

Single-component polyethylene polypropylene fiber waterproof coiled material adhesive Download PDF

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Publication number
CN113788662A
CN113788662A CN202111230463.3A CN202111230463A CN113788662A CN 113788662 A CN113788662 A CN 113788662A CN 202111230463 A CN202111230463 A CN 202111230463A CN 113788662 A CN113788662 A CN 113788662A
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polyethylene polypropylene
powder
coiled material
parts
waterproof coiled
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张雪松
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Qinhuangdao Songyan Building Materials Co ltd
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Qinhuangdao Songyan Building Materials Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A single-component polyethylene polypropylene fiber waterproof coiled material adhesive is composed of the following raw materials in parts by weight: 100 parts of sulphoaluminate cement, 29-31 parts of latex powder, 0.8-1.1 parts of melamine type water reducing agent, 0.08-0.12 part of sodium polyphosphate dispersing agent, 0.08-0.12 part of organosilicon defoaming agent and 38-42 parts of quartz powder; the latex powder is any one of ethylene/lauric acid/vinyl chloride terpolymer rubber powder, styrene/acrylic acid copolymer rubber powder, acrylic acid copolymer rubber powder and butadiene/styrene copolymer rubber powder. The single-component polyethylene polypropylene waterproof coiled material adhesive is used for waterproof construction of polyethylene polypropylene waterproof coiled materials, has high bonding strength, good flexibility and waterproof sealing performance, and solves the problem of inconvenience in production, packaging, storage, transportation and use of liquid material and powder material double-component polyethylene polypropylene waterproof coiled material adhesives.

Description

Single-component polyethylene polypropylene fiber waterproof coiled material adhesive
Technical Field
The invention relates to an adhesive used for a waterproof coiled material, in particular to a single-component polyethylene polypropylene fiber waterproof coiled material adhesive.
Background
The polyethylene polypropylene fiber waterproof coiled material is a waterproof material widely applied, and the market quantity is in the first place in the high polymer waterproof coiled material. The polyethylene polypropylene fiber waterproof coiled material needs to be matched with an adhesive to form composite waterproof during construction, so that the matched adhesive has definite requirements, not only needs to have good bonding performance and waterproof sealing performance, but also needs to have certain flexibility, and the requirements are met in CECS 199 which is mainly compiled by the China Association for engineering construction standardization: 2006 "technical code for composite waterproof engineering of polyethylene polypropylene coiled material" has clear regulations. In addition, when the joints and special parts of the coiled material (such as the coiled material and materials of iron, aluminum, PVC, and the like) are bonded, the adhesive is required to be firmly bonded so as to achieve the waterproof sealing effect. At present, the polymer modified cement bonding material used by the polyethylene polypropylene waterproof coiled material has good bonding performance with a base layer (cement base), but the waterproof sealing performance and the flexibility are poor, so that the composite waterproof requirement of the composite waterproof engineering technical specification cannot be met, and the problems of bonding and sealing of seams and special parts cannot be solved. In order to improve the flexibility and the waterproof sealing performance of the adhesive, when the content of the polymer in the adhesive is increased, namely the polymer cement ratio is increased, the adhesive cannot be solidified when the common portland cement is adopted.
In order to solve the problems, a previous patent application with an authorization publication number of CN108892458B of the applicant discloses a polyethylene polypropylene waterproof coiled material adhesive, wherein the polyethylene polypropylene waterproof coiled material adhesive uses sulphoaluminate cement to replace common silicate cement, and a plurality of auxiliary agents are added, so that the adhesive can still be cured when the poly-cement ratio is increased, and the adhesive is used for waterproof construction of a polyethylene polypropylene waterproof coiled material, and achieves the purposes of sealing, preventing water and improving flexibility. However, the polyethylene polypropylene waterproof coiled material adhesive is a bi-component product, namely the product consists of two parts, namely liquid material and powder material, and has certain defects compared with a single-component product, namely the two parts, namely the liquid material and the powder material, are required to be produced, packaged, stored and transported respectively, and meanwhile, the problems of corrosion prevention and freezing prevention of the liquid material storage and transportation need to be considered.
The 'Chinese building waterproof' journal (3.16.2007) is published with a 'research on a single-component water-resistant polyethylene polypropylene composite waterproof coiled material bonding material', the bonding material in the text consists of ordinary portland cement, quartz sand, dry milk, HPMC (hydroxy propyl methyl cellulose) and other additives, the performance of the product is better than that of the bonding material prepared by using 107 cement as a bonding material, but the product does not meet the requirements of 'polyethylene polypropylene coiled material composite waterproof engineering technical specification', the bonding peel strength of the coiled material and the coiled material also does not meet the requirements of JC/T863-2011 'macromolecule waterproof coiled material adhesive' standard which is more than or equal to 1.5N/mm, the bonding peel strength of other materials is lower at special positions, and in short, the bonding material does not meet the requirements of the current relevant standards.
Disclosure of Invention
The invention aims to provide a single-component polyethylene polypropylene waterproof coiled material adhesive aiming at the defects of the prior art. The single-component polyethylene polypropylene waterproof coiled material adhesive is used for waterproof construction of polyethylene polypropylene waterproof coiled materials, has high bonding strength, good flexibility and waterproof sealing performance, and solves the problem of inconvenience in production, packaging, storage, transportation and use of liquid material and powder material double-component polyethylene polypropylene waterproof coiled material adhesives.
The technical scheme for realizing the purpose is as follows: the single-component polyethylene polypropylene fiber waterproof coiled material adhesive is prepared from the following raw materials in parts by weight: 100 parts of sulphoaluminate cement, 29-31 parts of latex powder, 0.8-1.1 parts of melamine type water reducing agent, 0.08-0.12 part of sodium polyphosphate dispersing agent, 0.08-0.12 part of organosilicon defoaming agent and 38-42 parts of quartz powder; the latex powder is any one of ethylene/lauric acid/vinyl chloride terpolymer rubber powder, styrene/acrylic acid copolymer rubber powder, acrylic acid copolymer rubber powder and butadiene/styrene copolymer rubber powder.
The sulfoaluminate cement is 525# quick-hardening sulfoaluminate cement.
The single-component polyethylene polypropylene fiber waterproof coiled material adhesive is characterized in that the quartz powder is 350-400 meshes of quartz powder.
The latex powder is water-soluble redispersible powder, and the powder can be quickly redispersed into emulsion after contacting with water.
The single-component polyethylene polypropylene fiber waterproof coiled material adhesive is prepared by uniformly mixing the powder materials and removing blocks. When the single-component polyethylene polypropylene fiber waterproof coiled material is used for waterproof construction, the single-component polyethylene polypropylene fiber waterproof coiled material adhesive and water are mixed according to the weight ratio of 1: 0.3-0.35, adding the single-component polyethylene polypropylene fiber waterproof coiled material adhesive into water while stirring by using an electric stirrer, and stirring until no coagulum, no precipitate and uniformity exist, so that the single-component polyethylene polypropylene fiber waterproof coiled material adhesive can be used.
The single-component polyethylene polypropylene waterproof coiled material adhesive has excellent performance, adopts sulphoaluminate cement, replaces corresponding emulsion with latex powder, and is added with various additives, can still be cured when the poly-cement ratio is increased, is used for composite waterproof construction of polyethylene polypropylene waterproof coiled materials, has high bonding strength, can be firmly bonded with various building materials, has good waterproof sealing performance, and has certain flexibility.
The 350-400-mesh quartz powder is added into the single-component polyethylene polypropylene fiber waterproof coiled material adhesive, so that protective colloid polyvinyl alcohol which is used for absorbing dispersible emulsion powder particles by cement mortar can be formed, the emulsion cannot be damaged by water after being formed into a film, or the emulsion is dispersed for the second time, and meanwhile, the characteristic that fine particles of the quartz powder easily penetrate into pores of non-woven fabrics on the surface of the polyethylene polypropylene fiber waterproof coiled material is utilized, so that the strength of the adhesive is uniformly distributed, and the strength and the flexibility of the adhesive are kept.
The single-component polyethylene polypropylene fiber waterproof coiled material adhesive is single-component powder, is easy to produce, store and transport, has small volume and light weight, only needs to be added with water when in use, and is convenient to use.
The single-component polyethylene polypropylene fiber waterproof coiled material adhesive is non-toxic, harmless and pollution-free, and belongs to a green and environment-friendly product.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the following detailed description of the present invention is provided.
Example 1
The production method is characterized by adopting conventional dry powder mortar production equipment, and adding 100 parts by weight of 525# quick-hardening sulphoaluminate cement, 30 parts by weight of ethylene/lauric acid/vinyl chloride terpolymer emulsion powder, 1.0 part by weight of melamine type water reducing agent, 0.1 part by weight of sodium polyphosphate dispersing agent, 0.1 part by weight of organic silicon defoaming agent and 40 parts by weight of 350-400-mesh quartz powder into a mixer. The adding sequence is that firstly 525# quick hardening sulphoaluminate cement is added, then ethylene/lauric acid/chloroethylene terpolymer emulsion powder is added under stirring, and then melamine type water reducing agent, sodium polyphosphate dispersing agent, organic silicon defoaming agent and quartz powder are added under stirring. The melamine water reducing agent, the sodium polyphosphate dispersing agent, the organic silicon defoaming agent and the quartz powder are added in no sequence. Stirring until all the powder materials are uniformly mixed without agglomeration, weighing according to the requirements, sealing and packaging to obtain the single-component polyethylene polypropylene fiber waterproof coiled material adhesive.
When in use, a certain amount of the single-component polyethylene polypropylene fiber waterproof coiled material adhesive is taken, then 32 percent of water by weight is weighed, the single-component polyethylene polypropylene fiber waterproof coiled material adhesive is added into the water by an electric stirrer while stirring, and the mixture is stirred until no coagulum, no sediment and uniformity exist, so that the single-component polyethylene polypropylene fiber waterproof coiled material adhesive can be used.
The single-component polyethylene polypropylene fiber waterproof coiled material adhesive prepared according to the embodiment 1 is used for a polyethylene polypropylene fiber waterproof coiled material bonding sample and is sent to a detection mechanism for detection.
The results of the tests according to the standards in the technical code of polyethylene polypropylene coiled material composite waterproof engineering are shown in table 1.
Table 1:
Figure BDA0003315681500000021
the results of the standard detection according to JC/T863-2011 polymeric waterproof coiled material adhesive are shown in the table 2.
Table 2:
serial number Inspection item Standard requirements Test results
1 Peel strength (coil-to-coil), N/mm ≥1.5 1.9
2 Peel strength (coil-substrate, cement-based), N/mm ≥1.5 2.4
3 Peel strength (coil-aluminum plate), N/mm - 2.1
4 Peel strength (coil-PVC sheet), N/mm - 1.6
5 Peel strength (coil-iron plate), N/mm - 2.0
6 Peel strength, retention after immersion in water% ≥70 91
The detection result shows that the adhesive has high bonding strength, good waterproof sealing performance, particularly good flexibility, meets the composite waterproof requirement of the polyethylene polypropylene waterproof coiled material, is suitable for bonding the coiled material with a substrate (cement base), the coiled material with the coiled material, the joint of the coiled material and special parts (such as the coiled material with materials of iron, aluminum, PVC and the like), and has good bonding and waterproof sealing performance. It should be noted that the peel strength of the bonded sample after 168 hours of immersion in water did not decrease, but increased, and the water resistance of the adhesive was found to be excellent. And the single-component powder product is easy to produce, store and transport and is very convenient to use.
Example 2
The operation is carried out according to the embodiment 1, and the difference is that styrene/acrylic acid copolymer rubber powder is used for replacing ethylene/lauric acid/vinyl chloride terpolymer rubber powder to prepare the single-component polyethylene polypropylene waterproof coiled material adhesive which is used for a polyethylene polypropylene waterproof coiled material bonding sample and is sent to a detection mechanism for detection.
The results of the tests according to the standards in the technical code of polyethylene polypropylene coiled material composite waterproof engineering are shown in Table 3.
Table 3:
Figure BDA0003315681500000031
the results of the standard detection according to JC/T863-2011 polymeric waterproofing membrane adhesive are shown in Table 4.
Table 4:
serial number Inspection item Standard requirements Test results
1 Peel strength (coil-to-coil), N/mm ≥1.5 2.0
2 Peel strength (coil-substrate, cement-based), N/mm ≥1.5 2.4
3 Peel strength (coil-aluminum plate), N/mm - 2.1
4 Peel strength (coil-PVC sheet), N/mm - 2.0
5 Peel strength (coil-iron plate), N/mm - 1.9
6 Peel strength, retention after immersion in water% ≥70 92
The detection result proves that the performance is also excellent.
Example 3
The operation is carried out according to the embodiment 1, and the difference is that acrylic acid copolymer rubber powder is used for replacing ethylene/lauric acid/vinyl chloride terpolymer rubber powder to prepare the single-component polyethylene polypropylene waterproof coiled material adhesive which is used for bonding samples of polyethylene polypropylene waterproof coiled materials and is sent to a detection mechanism for detection.
The results of the tests according to the standards in the technical Specification for composite waterproof engineering of polyethylene polypropylene fiber coiled materials are shown in Table 5.
Table 5:
Figure BDA0003315681500000032
the results of the standard detection according to JC/T863-2011 polymeric waterproofing membrane adhesive are shown in Table 6.
Table 6:
Figure BDA0003315681500000033
Figure BDA0003315681500000041
the detection result proves that the performance is also excellent.
Example 4
The operation is carried out according to the embodiment 1, and the difference is that butadiene/styrene copolymer rubber powder is used for replacing ethylene/lauric acid/vinyl chloride terpolymer rubber powder to prepare the single-component polyethylene polypropylene waterproof coiled material adhesive which is used for a polyethylene polypropylene waterproof coiled material bonding sample and is sent to a detection mechanism for detection.
The results of the tests according to the standards in the technical Specification for composite waterproof engineering of polyethylene polypropylene fiber coiled materials are shown in Table 7.
Table 7:
Figure BDA0003315681500000042
the results of the standard detection according to JC/T863-2011 polymeric waterproofing membrane adhesive are shown in Table 8.
Table 8:
serial number Inspection item Standard requirements Test results
1 Peel strength (coil-to-coil), N/mm ≥1.5 1.6
2 Peel strength (coil-substrate, cement-based), N/mm ≥1.5 2.4
3 Peel strength (coil-aluminum plate), N/mm - 2.1
4 Peel strength (coil-PVC sheet), N/mm - 1.5
5 Peel strength (coil-iron plate), N/mm - 1.5
6 Peel strength, retention after immersion in water% ≥70 81
The test results show that the performance of the single-component polyethylene polypropylene waterproof coiled material adhesive prepared by replacing ethylene/lauric acid/vinyl chloride terpolymer rubber powder with butadiene/styrene copolymer rubber powder is lower than that of the single-component polyethylene polypropylene waterproof coiled material adhesive of example 1, but the performance of the single-component polyethylene polypropylene waterproof coiled material adhesive can still meet the requirements of the standards.
The above embodiments are merely preferred examples of the present invention, which is not limited thereto, and the present invention is not limited thereto, and those skilled in the art should understand that any simple modification, equivalent change, addition or substitution made within the spirit scope of the present invention should fall within the protection scope of the present invention.

Claims (3)

1. The single-component polyethylene polypropylene waterproof coiled material adhesive is characterized by comprising the following raw materials in parts by weight: 100 parts of sulphoaluminate cement, 29-31 parts of latex powder, 0.8-1.1 parts of melamine type water reducing agent, 0.08-0.12 part of sodium polyphosphate dispersing agent, 0.08-0.12 part of organosilicon defoaming agent and 38-42 parts of quartz powder; the latex powder is any one of ethylene/lauric acid/vinyl chloride terpolymer rubber powder, styrene/acrylic acid copolymer rubber powder, acrylic acid copolymer rubber powder and butadiene/styrene copolymer rubber powder.
2. The one-component polyethylene polypropylene waterproof coil adhesive as claimed in claim 1, wherein the sulphoaluminate cement is 525# rapid hardening sulphoaluminate cement.
3. The single-component polyethylene polypropylene waterproof coiled material adhesive as claimed in claim 1, wherein the quartz powder is 350-400 mesh quartz powder.
CN202111230463.3A 2021-10-22 2021-10-22 Single-component polyethylene polypropylene fiber waterproof coiled material adhesive Pending CN113788662A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396055A (en) * 2013-07-19 2013-11-20 北京东方雨虹防水技术股份有限公司 Special cement adhesive for waterproof backing TPO coils and preparation method thereof
CN108892458A (en) * 2018-08-15 2018-11-27 秦皇岛市松岩建材有限公司 Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof
CN109180105A (en) * 2018-09-27 2019-01-11 天津市禹红建筑防水材料有限公司 A kind of flexible adhesion powder and preparation method for polyethylene polypropylene fiber waterproof coiled material
CN109370322A (en) * 2018-11-28 2019-02-22 北京宝辰联合科技股份有限公司 A kind of single polymer water-repellent paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396055A (en) * 2013-07-19 2013-11-20 北京东方雨虹防水技术股份有限公司 Special cement adhesive for waterproof backing TPO coils and preparation method thereof
CN108892458A (en) * 2018-08-15 2018-11-27 秦皇岛市松岩建材有限公司 Polyethylene polypropylene fiber waterproof coiled material adhesive and preparation method thereof
CN109180105A (en) * 2018-09-27 2019-01-11 天津市禹红建筑防水材料有限公司 A kind of flexible adhesion powder and preparation method for polyethylene polypropylene fiber waterproof coiled material
CN109370322A (en) * 2018-11-28 2019-02-22 北京宝辰联合科技股份有限公司 A kind of single polymer water-repellent paint

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
戴智等: "胶粘剂在建筑工程中应用", 《化学建材》 *
郭晓潞,徐玲琳,吴凯编著: "《水泥基材料结构与性能》", 31 July 2020, 中国建材工业出版社 *

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