CN1137730A - Composite liquid for electric heating film - Google Patents
Composite liquid for electric heating film Download PDFInfo
- Publication number
- CN1137730A CN1137730A CN 95106218 CN95106218A CN1137730A CN 1137730 A CN1137730 A CN 1137730A CN 95106218 CN95106218 CN 95106218 CN 95106218 A CN95106218 A CN 95106218A CN 1137730 A CN1137730 A CN 1137730A
- Authority
- CN
- China
- Prior art keywords
- electric heating
- heating film
- film
- ethanol
- indium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005485 electric heating Methods 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 title claims abstract description 9
- 239000002131 composite material Substances 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004065 semiconductor Substances 0.000 claims abstract description 8
- 229910003437 indium oxide Inorganic materials 0.000 claims abstract description 7
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 9
- 235000014121 butter Nutrition 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000008020 evaporation Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000011550 stock solution Substances 0.000 abstract 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
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- Chemically Coating (AREA)
Abstract
The composite liquid for electric heating film is one kind of impurity semiconductor liquid for making electric heating film and is colorless transparent liquid compounded with tin tetrachloride, antimony trichloride, indium oxide, methanol, ethanol, hydrochloric acid and hydrofluoric acid. The electric heating household appliance made by the stock solution and the evaporation process has the advantages of beautiful appearance, high bonding strength between the film and the body, high thermal efficiency, high temperature resistance, acid resistance, alkali resistance and good chemical stability, and is a proper raw material for manufacturing the electric heating film household appliance.
Description
The present invention is a kind of stoste of being made the extrinsic semiconductor material of electric heating film by number of chemical element being used to of being combined to.
Electric current can produce heat during by metal alloy, semiconductor.Utilize this physical characteristic of metal and semi-conducting material, people have made multiple electrically heated material.What be applied to electric heater the earliest is the resistance wire electrothermal furnace made with nichrome wire, be formed on the electrical bar of making on the refractory material with the resistance filament winding, these all are that heat is used, its heating mechanism is a radiation heating, owing to will conduct heat energy by air dielectric, the heat efficiency is low, and power consumption is many, naked light is arranged, dangerous, volume is big, and is fragile.And, be not all to be heat on the commercial Application, often need low-temperature heat, thereby produced semiconductive ceramic (PTC) device of heating, and 200 ℃-310 ℃ of its maximum heating temperatures, temperature is on the low side again, have radiation heating equally, the heat efficiency is low, the deficiency that power consumption is big.For the temperature heating in realizing and the raising heat efficiency, electric heating film materials such as carbon film, Zinc oxide film have successively appearred.Carbon film is a kind of coating, is coated on the nonmetal heated object, and is opaque, bond strength is low, compactness is poor.Though Zinc oxide film can be transparent, must make with the process that the vacuum of complexity is plated, the cost height costs an arm and a leg.And to have occurred with butter of tin and trichloride antimony be that raw material is made the semi-conducting material that transparent glass film is used.Though this material can be used for making transparent electro-conductive glass, its cost is still expensive.Over nearly 10 years on China and the foreign patent documents to the manufacturing of electric heating film with use many records are also arranged: as " the transparent material handbook of China Standard Press's in April, 1986 publication, " the practical chemistry product formulary " that Sichuan science tech publishing house publishes in June, 1987, Chinese application number is 90101938.0,91218094.3,90221909.X, 91231824.4,92211809.4,902125353.X, 89206619.9,90222193.0 Deng patent application and Japan Patent JP04156917, JP04276699, JP05287072 has new innovation and creation.Therefore, in the electric heating film technical field, also be what a hundred flowers contend in beauty, quality is respectively arranged, each has something to recommend him, can seek to be suitable for practical material, produce exquisite utensil, be only and get ahead of others.
The objective of the invention is to manufacture experimently and a kind ofly can produce heat efficiency height, the bond strength height, make easy, the stoste of the novel semiconductor material of the manufacturing electric heating film that price is lower.
The objective of the invention is to realize with following technical scheme: selecting butter of tin, trichloride antimony and indium oxide for use is basic batching, methyl alcohol, ethanol, concentrated hydrochloric acid, hydrofluoric acid are solvent, be batching, at normal temperatures, in beaker, mixed successively and promptly made water white stoste, can place the evaporation ware of evaporation stove, the technological measures such as temperature control of taking suitably to heat promptly can be made desired electric heating film on plating piece.
The formulation ratio of a kind of embodiment of the present invention by solid weight than, liquid capacity than being respectively:
Butter of tin 99.0-99.8%
Trichloride antimony 0.19-0.90%
Indium oxide 0.001-0.10%
Methyl alcohol 35-50%
Ethanol 40-60%
Concentrated hydrochloric acid 0.5-0.9%
Hydrofluoric acid 0.09-0.4%
It produces program is earlier butter of tin to be dissolved in the methyl alcohol, then adds trichloride antimony, indium oxide, ethanol, hydrofluoric acid, concentrated hydrochloric acid respectively and stirs into water white liquid, encapsulates standby.
Electrical heated appliance gloss fineness with the present invention manufactures experimently out has reached higher standard, and its key technical indexes is as follows:
1. bond strength＞the 8N/CM of electrode/nesa coating/glass ceramics
2
2. the heat efficiency＞95%.
3. film fusing point＞1700 ℃.
4. the chemical characteristic of film is good:
(1) in the 30%NaOH aqueous solution, soaks 24 hours characteristic no changes;
(2) dense H
2SO
4Soak 24 hours characteristic no changes in the solution.
Therefore, the present invention is the suitable material of fabricator electrical appliance electric heating film, can be used for making various in warm electrical heated appliance.
Claims (2)
1. an extrinsic semiconductor material stoste that is used to make electric heating film is characterized in that prescription is: butter of tin, trichloride antimony, indium oxide, methyl alcohol, ethanol, concentrated hydrochloric acid, hydrofluoric acid; Proportioning is: solid weight ratio, liquid capacity are through being respectively:
Butter of tin 99.0-99.8%
Trichloride antimony 0.19-0.90%
Indium oxide 0.001-0.10%
Methyl alcohol 35-50%
Ethanol 40-60%
Concentrated hydrochloric acid 0.5-0.9%
Hydrofluoric acid 0.09-0.4%
2. by the described extrinsic semiconductor material of claim 1 stoste, it is characterized in that producing program is butter of tin to be dissolved in then adding trichloride antimony, indium oxide, ethanol, hydrofluoric acid, concentrated hydrochloric acid in the methyl alcohol respectively earlier, is stirred into water white liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95106218 CN1137730A (en) | 1995-06-02 | 1995-06-02 | Composite liquid for electric heating film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95106218 CN1137730A (en) | 1995-06-02 | 1995-06-02 | Composite liquid for electric heating film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1137730A true CN1137730A (en) | 1996-12-11 |
Family
ID=5075798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95106218 Pending CN1137730A (en) | 1995-06-02 | 1995-06-02 | Composite liquid for electric heating film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1137730A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102036433A (en) * | 2010-12-21 | 2011-04-27 | 吕一诺 | Infrared electric heating film heating tube with double-film layer structure as well as preparation method and application thereof |
| CN102129979A (en) * | 2010-01-14 | 2011-07-20 | 台湾积体电路制造股份有限公司 | Semiconductor device and its manufacture method |
-
1995
- 1995-06-02 CN CN 95106218 patent/CN1137730A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102129979A (en) * | 2010-01-14 | 2011-07-20 | 台湾积体电路制造股份有限公司 | Semiconductor device and its manufacture method |
| CN102129979B (en) * | 2010-01-14 | 2014-09-10 | 台湾积体电路制造股份有限公司 | Semiconductor device and its manufacture method |
| CN102036433A (en) * | 2010-12-21 | 2011-04-27 | 吕一诺 | Infrared electric heating film heating tube with double-film layer structure as well as preparation method and application thereof |
| CN102036433B (en) * | 2010-12-21 | 2012-08-22 | 吕一诺 | Infrared electric heating film heating tube with double-film layer structure as well as preparation method and application thereof |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |