CN113754372A - Wood grain imitation inorganic artificial travertine and its production process - Google Patents

Wood grain imitation inorganic artificial travertine and its production process Download PDF

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Publication number
CN113754372A
CN113754372A CN202111021549.5A CN202111021549A CN113754372A CN 113754372 A CN113754372 A CN 113754372A CN 202111021549 A CN202111021549 A CN 202111021549A CN 113754372 A CN113754372 A CN 113754372A
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additive
materials
travertine
wood
inorganic artificial
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Inventor
邓文锋
罗阳林
钟土有
汤雄跃
刘松筠
罗传德
陈兴国
陈泽良
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Guangxi Lisheng Stone Co ltd
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Guangxi Lisheng Stone Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B28B13/0205Feeding the unshaped material to moulds or apparatus for producing shaped articles supplied to the moulding device in form of a coherent mass of material, e.g. a lump or an already partially preshaped tablet, pastil or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0616Macromolecular compounds fibrous from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0625Polyalkenes, e.g. polyethylene
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    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/16Sulfur-containing compounds
    • C04B24/18Lignin sulfonic acid or derivatives thereof, e.g. sulfite lye
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    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/28Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/281Polyepoxides
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
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    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]

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  • Chemical Kinetics & Catalysis (AREA)
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Abstract

The application discloses an inorganic artificial travertine with wood grain imitation and a production process thereof, wherein the inorganic artificial travertine with wood grain imitation comprises the following raw materials in percentage by mass: 22-33% of hydraulic cementing material, 0.11-1.32% of modified additive, 70-75% of filler, 1.0-2.0% of emulsion and 0-0.5% of pigment. The wood-grain-like inorganic artificial travertine is prepared by the steps of mixing, press forming, maintaining, cutting and the like. The production process can obtain a material layer with straight textures, the height of the material distribution table is synchronously increased by the screw spiral lifter along with the stacking height of the material layer, the material distribution height is kept consistent layer by layer, the problems of material layer fracture, incoherence and disordered texture can be solved, efficient continuous production is realized, the wood grain textures are clear and uniform, a small number of holes are dotted, and the wood grain-imitated inorganic artificial travertine is obtained.

Description

Wood grain imitation inorganic artificial travertine and its production process
[ technical field ] A method for producing a semiconductor device
The invention relates to a production process of a wood-grain-like inorganic artificial travertine, in particular to a wood-grain-like inorganic artificial travertine and a production process thereof.
[ background of the invention ]
The prior inorganic artificial stone has single texture and color, and the product color mainly depends on the type and the quantity of the used natural aggregate. The inorganic artificial stone with multicolor textures sold in the market is mainly pressed by manual material distribution and a single-piece pressing plate method, and the method has the advantages of low production efficiency, low automation degree and disordered textures.
[ summary of the invention ]
The invention provides a wood-grain-imitating inorganic artificial travertine and a production process thereof, and aims to solve the problems of low production efficiency, low automation degree, disordered texture of the wood-grain-imitating inorganic artificial travertine and the like in the prior art.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
the wood-grain-like inorganic artificial travertine comprises the following raw materials in percentage by mass: 22-33% of hydraulic cementing material, 0.11-1.32% of modified additive, 70-75% of filler, 1.0-2.0% of emulsion and 0-0.5% of pigment.
Further, the modification auxiliary agent comprises one or more of an additive a, an additive b, an additive c, an additive d and an additive e.
Further, the additive a comprises one or more of aliphatic hydroxyl sulfonate polymer, polycarboxylate polymer and sulfamate polymer, and the addition amount is 1.0-2.5% by weight of the amount of the hydraulic cementing material.
Furthermore, the additive b comprises one or more of acrylamide-acrylate copolymer, starch graft acrylate, cellulose ether and salts thereof, and the addition amount is 0.05-0.2% wt of the hydraulic cementing material.
Furthermore, the additive c is one or more of polyvinyl chloride fiber and aramid fiber, and the dosage of the additive c is 0.3-0.5% of the weight of the dosage of the hydraulic cementing material.
Furthermore, the additive d is one or more of magnesium lignosulfonate and sodium citrate, and the addition amount is 0-0.2% wt of the using amount of the hydraulic cementing material.
Furthermore, the additive e comprises one or more of alkali silicate and aluminate, and the addition amount is 0-0.6% wt of the using amount of the hydraulic cementing material.
Further, the hydraulic cementing material comprises one or more of Portland cement, aluminate cement, activated kaolin and gypsum; the pigment comprises one or more of titanium dioxide, iron oxide red powder, iron yellow powder, iron black powder, carbon black powder, medium chrome yellow and lemon yellow; the emulsion is water-based epoxy resin emulsion.
Further, the filler comprises one or more of calcium carbonate powder, calcium carbonate sand, quartz sand and active silica fume, the particle size distribution of the calcium carbonate powder is 400-3000 meshes, the particle size distribution of the calcium carbonate sand is 40-100 meshes, the particle size distribution of the quartz sand is 40-120 meshes, and the particle size distribution of the active silica fume is 1000-3000 meshes.
The invention also provides a production process of the wood-grain-imitated inorganic artificial travertine, which comprises the following steps:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 8-14 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 3-10cm, taking out the materials adhered on the stirring wall, and then continuously stirring the materials until large lumps with the diameter of more than 40cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 5-15 circles at a rotating speed of 3-8r/min to obtain a multicolor inorganic travertine material;
(4) the material is put into an extrusion type material distribution port and is extruded into a flaky material layer by pressurization;
(5) the lower material receiving mould is used for receiving materials by a synchronous swinging constant-speed trolley, and the material layers are controlled to be flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square materials by steam at 35-65 ℃ for 24-72h, and turning to natural water spraying for curing for 15 days;
(8) cutting the rough material along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-imitated inorganic artificial travertine.
The invention has the following beneficial effects:
(1) the additive a used in the invention can reduce the water consumption required by material mixing and improve the material fluidity.
(2) The additive b used in the invention is used for stabilizing the moisture in the material and reducing the water loss of the material.
(3) The additive e used in the invention can be used for cement solidification in severe cold weather and can slow down the cement solidification in severe cold weather, and the cement hydration reaction can be accelerated by the accelerator.
(4) The polyvinyl chloride fibers are uniformly dispersed in various raw materials, and can form a staggered net structure, so that cracking is reduced, and the breaking strength of the wood-grain-like inorganic artificial travertine is enhanced; the magnesium lignosulfonate can be used for delaying the cement hydration time, reducing the heat release peak value and avoiding the concentrated formation of cracks by the heat release, thereby improving the breaking strength of the wood-like inorganic artificial travertine; the waterborne epoxy resin emulsion is filled in gaps of raw materials such as polyvinyl chloride fiber, magnesium lignosulfonate and the like, so that the bonding performance of the polyvinyl chloride fiber and the magnesium lignosulfonate is enhanced, and the function is better played.
(5) The invention adopts hydraulic cementing material, modified auxiliary agent, filler, emulsion and pigment to be evenly stirred and is formed by layer-by-layer material distribution and vibration under atmospheric pressure; the wood-grain-imitated inorganic travertine slab is obtained by steam high-temperature curing and reinforcement and longitudinal cutting along the direction of the cloth layer, and solves the problem that the inorganic travertine depends on aggregate in terms of flower color and texture and is difficult to produce fine texture products in batches.
(6) The invention adopts a continuous automatic wood grain imitation raw material production device to produce multicolor inorganic stone, an extrusion type long strip-shaped feed opening is used for forming a sheet material state, a regular swing trolley below a material distribution opening is used for bearing materials which are horizontally placed layer by layer, when the materials are fed, the extrusion force and the gravity are utilized to straighten textures, the material layers are horizontally placed in a mould layer by layer, the two ends of the die can be pulled and folded to obtain a material layer with straight texture, the height of the material distribution table is synchronously lifted by a screw spiral lifter along with the stacking height of the material layer to keep the consistent height of the material distribution layer by layer, can solve the problems of material layer fracture, incoherence and disordered texture, realizes high-efficiency continuous production, has clear and uniform wood grain texture, decorates a small number of holes, obtains the wood grain-imitated inorganic artificial travertine, the flexural strength is more than 9MPa, the compressive strength is more than 80.1MPa, and the combustion performance grade is A1, which shows that the wood-grain-imitated inorganic artificial travertine prepared by the production process has excellent performance.
[ description of the drawings ]
FIG. 1 is a schematic view of an inorganic artificial travertine with wood grain imitation;
wherein, the cloth is distributed along the ABCD horizontal plane and cut parallel to the BCGF plane;
FIG. 2 is an extruded cloth diagram of a wood grain-like inorganic artificial travertine product;
FIG. 3 is a diagram of an inorganic artificial travertine slab with simulated wood grains cut without polishing treatment;
FIG. 4 is a drawing of a vacuum-pumped inorganic artificial travertine slab with simulated wood grains.
[ detailed description ] embodiments
In order to facilitate a better understanding of the invention, the following examples and the accompanying figures 1 to 4 illustrate embodiments which are within the scope of the invention, but do not limit the scope of the invention.
The wood grain-like inorganic artificial travertine comprises the following raw materials in percentage by mass: 22-33% of hydraulic cementing material, 0.11-1.32% of modified additive, 70-75% of filler, 1.0-2.0% of emulsion and 0-0.5% of pigment;
the hydraulic cementing material comprises one or more of Portland cement, aluminate cement, activated kaolin and gypsum;
the modification auxiliary agent comprises one or more of an additive a, an additive b, an additive c, an additive d and an additive e;
the additive a comprises one or more of aliphatic hydroxyl sulfonate polymer, polycarboxylate polymer and sulfamate polymer, and the addition amount of the additive a is 1.0-2.5% of the weight of the hydraulic cementing material;
the additive b comprises one or more of acrylamide-acrylate copolymer cross-linked polymer, starch graft acrylate, cellulose ether and salts thereof, and the addition amount is 0.05-0.2% wt of the hydraulic cementing material;
the additive c is one or more of polyvinyl chloride fiber and aramid fiber, and the dosage of the additive c is 0.3-0.5 wt% of that of the hydraulic cementing material;
the additive d is one or more of magnesium lignosulfonate and sodium citrate, and the addition amount of the additive d is 0-0.2% wt of the using amount of the hydraulic cementing material;
the additive e comprises one or more of alkali silicate and aluminate, and the addition amount is 0-0.6 wt% of the dosage of the hydraulic cementing material;
the filler comprises one or more of calcium carbonate powder, calcium carbonate sand, quartz sand and active silica fume, the particle size distribution of the calcium carbonate powder is 400-3000 meshes, the particle size distribution of the calcium carbonate sand is 40-100 meshes, the particle size distribution of the quartz sand is 40-120 meshes, and the particle size distribution of the active silica fume is 1000-3000 meshes;
the emulsion is water-based epoxy resin emulsion;
the pigment comprises one or more of titanium dioxide, iron oxide red powder, iron yellow powder, iron black powder, carbon black powder, medium chrome yellow and lemon yellow;
the production process of the wood grain-like inorganic artificial travertine comprises the following steps:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 8-14 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 3-10cm, taking out the materials adhered on the stirring wall, and then continuously stirring the materials until large lumps with the diameter of more than 40cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 5-15 circles at a rotating speed of 3-8r/min to obtain a multicolor inorganic travertine material;
(4) the material is put into an extrusion type material distribution port and is extruded into a flaky material layer by pressurization;
(5) the lower material receiving mould is used for receiving materials by a synchronous swinging constant-speed trolley, and the material layers are controlled to be flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square materials by steam at 35-65 ℃ for 24-72h, and turning to natural water spraying for curing for 15 days;
(8) cutting the rough material along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-imitated inorganic artificial travertine.
The present invention is illustrated by the following more specific examples.
Example 1
The wood-grain-like inorganic artificial travertine comprises the following raw materials in percentage by mass: 26.74 percent of hydraulic cementing material, 0.46 percent of modified additive, 71.7 percent of filler, 1.0 percent of emulsion and 0.1 percent of pigment;
the hydraulic cementing material is portland cement;
the modification auxiliary agent comprises an additive a, an additive b, an additive c and an additive e;
the additive a is aliphatic hydroxy sulfonate polymer, and the addition amount is 1.2% wt of the using amount of the hydraulic cementing material;
the additive b is starch grafted acrylate, and the addition amount of the additive b is 0.1% wt of the using amount of the hydraulic cementing material;
the additive c is aramid fiber, and the dosage of the additive c is 0.3 wt% of the dosage of the hydraulic cementing material;
the additive e is water glass, and the addition amount of the additive e is 0.1 percent wt of the dosage of the hydraulic cementing material;
the filler is calcium carbonate powder, and the particle size distribution of the calcium carbonate powder is 400-600 meshes;
the emulsion is water-based epoxy resin emulsion;
the pigment is iron yellow powder;
the production process of the wood grain-like inorganic artificial travertine comprises the following steps:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 10 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 4cm, taking out the materials adhered to the stirring wall, and then continuously stirring the materials until large lumps with the diameter of 40cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 15 circles at a rotating speed of 3r/min to obtain a multicolor inorganic travertine material;
(4) the material is fed to an extrusion type material distribution port, and is extruded into a sheet-shaped material layer with the thickness of 2cm by self gravity and pressure, the distance between the material distribution port and the bottom of the die is 8cm, and the material distribution port is horizontally lifted by 2cm every 6 min;
(5) the material receiving mould below is used for receiving materials by a synchronous constant-speed trolley, the stroke of the trolley is 270cm, and the trolley runs back and forth at a constant speed of 45cm/min, so that material layers are flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square stock by steam, controlling the temperature to be 38 ℃, curing for 70h, and then turning to natural water spraying for curing for 15 days;
(8) cutting the rough material along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-imitated inorganic artificial travertine.
Example 2
The wood-grain-like inorganic artificial travertine comprises the following raw materials in percentage by mass: 24.1% of hydraulic cementing material, 0.6% of modified auxiliary agent, 73.4% of filler, 1.6% of emulsion and 0.3% of pigment;
the hydraulic cementing material consists of aluminate cement and gypsum according to the mass ratio of 2: 1;
the modification auxiliary agent comprises an additive a, an additive b, an additive c and an additive d;
the additive a is polycarboxylate polymer, and the addition amount is 1.9% wt of the using amount of the hydraulic cementing material;
the additive b is an acrylamide-acrylate copolymer cross-linked product, and the addition amount of the additive b is 0.1 wt% of the dosage of the hydraulic cementing material;
the additive c is polyvinyl chloride fiber, and the dosage of the additive c is 0.4 percent of the dosage of the hydraulic cementing material;
the additive d is magnesium lignosulfonate, and the addition amount of the additive d is 0.1% wt of the using amount of the hydraulic cementing material;
the filler consists of calcium carbonate powder and calcium carbonate sand according to the mass ratio of 4:1, the particle size distribution of the calcium carbonate powder is 400-600 meshes, and the particle size distribution of the calcium carbonate sand is 40-100 meshes;
the emulsion is water-based epoxy resin emulsion;
the pigment is composed of titanium dioxide, iron oxide red powder, iron oxide yellow powder and iron oxide black powder according to the mass ratio of 2:1:1: 1;
the production process of the wood grain-like inorganic artificial travertine comprises the following steps:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 12 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 6cm, taking out the materials adhered to the stirring wall, and then continuously stirring the materials until large lumps with the diameter of 41cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 10 circles at the rotating speed of 6r/min to obtain a multicolor inorganic travertine material;
(4) the material is fed to an extrusion type material distribution port, and is extruded into a 3cm thick sheet material layer by self gravity and pressure, the distance between the material distribution port and the bottom of the die is 10cm, and the material distribution port is horizontally lifted by 3cm every 4.5 min;
(5) the material receiving mould below is used for receiving materials by a synchronous constant-speed trolley, the stroke of the trolley is 270cm, and the trolley runs back and forth at a constant speed of 60cm/min, so that material layers are flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square stock by steam, controlling the temperature to be 54 ℃, curing for 60 hours, and then turning to natural water spraying for curing for 15 days;
(8) the rough material is cut along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-like inorganic artificial travertine, which is shown in figures 1-4.
Example 3
The wood-grain-like inorganic artificial travertine comprises the following raw materials in percentage by mass: 27.8 percent of hydraulic cementing material, 0.5 percent of modified auxiliary agent, 70.1 percent of filler, 1.2 percent of emulsion and 0.4 percent of pigment;
the hydraulic cementing material is portland cement;
the modification auxiliary agent comprises an additive a, an additive b, an additive c and an additive d;
the additive a is aliphatic hydroxy sulfonate polymer, and the addition amount is 1.2% wt of the using amount of the hydraulic cementing material;
the additive b is starch grafted acrylate, and the addition amount of the additive b is 0.1% wt of the using amount of the hydraulic cementing material;
the additive c is polyvinyl chloride fiber, and the dosage of the additive c is 0.3 percent of the dosage of the hydraulic cementing material;
the additive d is sodium citrate, and the addition amount of the additive d is 0.1 percent wt of the dosage of the hydraulic cementing material;
the additive e is calcium aluminate, and the addition amount of the additive e is 0.1 percent wt of the dosage of the hydraulic cementing material;
the filler consists of calcium carbonate powder and quartz sand according to the mass ratio of 3:1, the particle size distribution of the calcium carbonate powder is 400-mesh and 600-mesh, and the particle size distribution of the quartz sand is 40-120-mesh;
the emulsion is water-based epoxy resin emulsion;
the pigment iron yellow powder, the iron black powder and the medium chrome yellow are composed according to the mass ratio of 1:2: 1;
the production process of the wood grain-like inorganic artificial travertine comprises the following steps:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 8-14 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 3-10cm, taking out the materials adhered on the stirring wall, and then continuously stirring the materials until large lumps with the diameter of more than 40cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 5-15 circles at a rotating speed of 3-8r/min to obtain a multicolor inorganic travertine material;
(4) the material is fed to an extrusion type material distribution port, and is extruded into a sheet material layer with the thickness of 1.5cm by self gravity and pressure, the distance between the material distribution port and the bottom of the die is 6cm, and the material distribution port is horizontally lifted by 2cm every 9 min;
(5) the material receiving mould below is used for receiving materials by a synchronous constant-speed trolley, the stroke of the trolley is 270cm, and the trolley runs back and forth at a constant speed of 30cm/min, so that material layers are flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square materials by steam at 35-65 ℃ for 24-72h, and turning to natural water spraying for curing for 15 days;
(8) cutting the rough material along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-imitated inorganic artificial travertine.
Comparative example 1
The production process is basically the same as that of example 2, except that polyvinyl chloride fibers, magnesium lignosulfonate and aqueous epoxy resin emulsion are absent in the raw materials for preparing the wood-grain-like inorganic artificial travertine.
Comparative example 2
The production process was substantially the same as that of example 2, except that polyvinyl chloride fibers were absent from the raw materials for preparing the wood grain-imitating inorganic artificial travertine.
Comparative example 3
The process was substantially the same as that of example 2, except that the raw material for producing the wood grain-like inorganic artificial travertine was deficient in magnesium lignosulfonate.
Comparative example 4
The process was substantially the same as that of example 2, except that the raw materials for preparing the wood grain-imitating inorganic artificial travertine lacked the aqueous epoxy resin emulsion.
The production processes of examples 1-3 and comparative examples 1-4 are adopted to prepare the wood grain-imitated inorganic artificial travertine, the flexural strength, the compression strength and the combustion performance grade are detected, and the detection results are as follows:
Figure BDA0003241621330000131
remarking: the breaking strength is detected by adopting the national standard GB 35157 and 2017; the breaking strength is detected by adopting the national standard GB 35157 and 2017; the combustion performance grade is detected by using the national standard GB 8624-.
From the above table, it can be seen that:
(1) as can be seen from the indexes of the examples 1-3, the flexural strength of the wood-grain-like inorganic artificial travertine prepared by the invention is more than 9MPa, the compressive strength is more than 80.1MPa, and the combustion performance grade is A1, which shows that the wood-grain-like inorganic artificial travertine prepared by the production process of the invention has excellent performance; by combining the data indexes of examples 1-3, it can be seen that example 2 is the most preferred example.
(2) From the flexural strength data of example 2 and comparative example 1, the effect value of flexural strength generated when polyvinyl chloride fiber, magnesium lignosulfonate, and aqueous epoxy resin emulsion are used together is 9.6-5.7-3.9 (MPa); from the flexural strength data of example 2 and comparative example 2, the effect value of the flexural strength produced when the polyvinyl chloride fiber was used alone was 9.6 to 8.5 to 1.1 (MPa); from the flexural strength data of example 2 and comparative example 3, the effect value of the flexural strength produced when magnesium lignosulfonate was used alone was 9.6 to 8.8 to 0.8 (MPa); from the flexural strength data of example 2 and comparative example 4, the effect value of the flexural strength produced by the aqueous epoxy resin emulsion alone was calculated to be 9.6 to 8.3 to 1.3 (MPa); by combining the data, the effect value of the flexural strength generated by the polyvinyl chloride fiber, the magnesium lignosulfonate and the aqueous epoxy resin emulsion in a superimposed manner when the polyvinyl chloride fiber, the magnesium lignosulfonate and the aqueous epoxy resin emulsion are respectively and independently used is calculated to be 1.1+0.8+1.3 to 3.2(MPa), and in conclusion, the percentage (3.9-3.2) ÷ 3.2 × 100% >, which is more than 10% of the effect value of the flexural strength generated by the polyvinyl chloride fiber, the magnesium lignosulfonate and the aqueous epoxy resin emulsion in a superimposed manner when the polyvinyl chloride fiber, the magnesium lignosulfonate and the aqueous epoxy resin emulsion are respectively and independently used, is higher than the percentage (3.9-3.2) ÷ 3.2 × 100% >, which is higher than 10%, so that the polyvinyl chloride fiber, the magnesium lignosulfonate and the aqueous epoxy resin emulsion play a synergistic effect in the preparation of the wood grain-like inorganic artificial travertine and the flexural strength is synergistically improved. This is because: the polyvinyl chloride fibers are uniformly dispersed in various raw materials to form a staggered net structure, so that cracking is reduced, and the breaking strength of the wood-grain-like inorganic artificial travertine is enhanced; the magnesium lignosulfonate can be used for delaying the cement hydration time, reducing the heat release peak value and avoiding the concentrated formation of cracks by the heat release, thereby improving the breaking strength of the wood-like inorganic artificial travertine; the waterborne epoxy resin emulsion is filled in gaps of raw materials such as polyvinyl chloride fiber, magnesium lignosulfonate and the like, so that the bonding performance of the polyvinyl chloride fiber and the magnesium lignosulfonate is enhanced, and the function is better played.
The above description should not be taken as limiting the invention to the specific embodiments, but rather, as will be readily apparent to those skilled in the art to which the invention pertains, numerous simplifications or substitutions may be made without departing from the spirit of the invention, which should be construed to fall within the scope of the invention as defined in the claims appended hereto.

Claims (10)

1. The wood-grain-like inorganic artificial travertine is characterized by comprising the following raw materials in percentage by mass: 22-33% of hydraulic cementing material, 0.11-1.32% of modified additive, 70-75% of filler, 1.0-2.0% of emulsion and 0-0.5% of pigment.
2. The wood-grain-imitating inorganic artificial travertine as claimed in claim 1, wherein said modification auxiliary comprises one or more of additive a, additive b, additive c, additive d and additive e.
3. The artificial travertine with simulated wood grains according to claim 2, wherein said additive a comprises one or more of aliphatic hydroxysulfonate polymer, polycarboxylate polymer and sulfamate polymer, and the addition amount is 1.0-2.5% wt of the amount of hydraulic binder.
4. The artificial travertine with simulated wood grains according to claim 2, wherein said additive b comprises one or more of acrylamide-acrylate copolymer, starch graft acrylate, cellulose ether and its salt, and the addition amount is 0.05-0.2% wt of the hydraulic binder.
5. The artificial travertine with simulated wood grains according to claim 2, wherein said additive c is one or more of polyvinyl chloride fiber and aramid fiber, and is used in an amount of 0.3-0.5% wt of the amount of the hydraulic binder.
6. The artificial travertine with simulated wood grains according to claim 2, wherein said additive d is one or more of magnesium lignosulfonate and sodium citrate, added in an amount of 0-0.2% wt of the amount of hydraulic cement.
7. The artificial travertine with simulated wood grains according to claim 2, wherein said additive e comprises one or more of alkali silicate and aluminate, and the addition amount is 0-0.6% wt of the hydraulic binder.
8. The wood-grain-imitating inorganic artificial travertine as claimed in claim 1, wherein said hydraulic binder comprises one or more of portland cement, aluminate cement, activated kaolin, gypsum; the pigment comprises one or more of titanium dioxide, iron oxide red powder, iron yellow powder, iron black powder, carbon black powder, medium chrome yellow and lemon yellow; the emulsion is water-based epoxy resin emulsion.
9. The wood-like inorganic artificial travertine as claimed in claim 1, wherein said filler comprises one or more of calcium carbonate powder, calcium carbonate sand, quartzite sand and activated silica fume, the particle size distribution of the calcium carbonate powder is 400-mesh-600 mesh, the particle size distribution of the calcium carbonate sand is 40-100 mesh, the particle size distribution of the quartzite sand is 40-120 mesh, and the particle size distribution of the activated silica fume is 1000-mesh-3000 mesh.
10. A process for producing the wood grain-like inorganic artificial travertine as claimed in any one of claims 1 to 9, comprising the steps of:
(1) weighing hydraulic cementing materials, modified auxiliary agents, fillers and pigments according to a ratio, then putting the materials into a stirrer, and uniformly stirring the materials at a rotating speed of 8-14 r/min;
(2) adding weighed emulsion after the materials are uniformly stirred, continuously stirring, carrying out reverse stirring when the materials are in a block shape with the diameter of 3-10cm, taking out the materials adhered on the stirring wall, and then continuously stirring the materials until large lumps with the diameter of more than 40cm appear;
(3) conveying the extension materials into a main stirrer through a belt, and stirring the materials for 5-15 circles at a rotating speed of 3-8r/min to obtain a multicolor inorganic travertine material;
(4) the material is put into an extrusion type material distribution port and is extruded into a flaky material layer by pressurization;
(5) the lower material receiving mould is used for receiving materials by a synchronous swinging constant-speed trolley, and the material layers are controlled to be flatly stacked in the mould;
(6) after the material distribution is finished, the material is vibrated and pressed to form to obtain the wood-grain-like inorganic artificial travertine square stock;
(7) curing the square materials by steam at 35-65 ℃ for 24-72h, and turning to natural water spraying for curing for 15 days;
(8) cutting the rough material along the material distribution direction and perpendicular to the material distribution layer to obtain the wood grain-imitated inorganic artificial travertine.
CN202111021549.5A 2021-09-01 2021-09-01 Wood grain imitation inorganic artificial travertine and its production process Pending CN113754372A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB236714A (en) * 1924-06-17 1925-07-16 Leonard George Nicoll Improvements in and relating to decorated or ornamental structural material
CN101941233A (en) * 2010-08-17 2011-01-12 广东新粤建材有限公司 Preparation method of artificial stone with imitated wood grain pattern and artificial stone
CN102343623A (en) * 2011-09-22 2012-02-08 佛山市河之舟机电有限公司 Method and equipment for distributing lines and textures in artificial stones
CN103214214A (en) * 2013-02-26 2013-07-24 黄彰标 Preparation raw materials and preparation method of inorganic man-made rock
CN103848641A (en) * 2012-11-29 2014-06-11 上海古猿人石材有限公司 Artificial stone with irregular pore and preparation method thereof
CN104402492A (en) * 2014-11-18 2015-03-11 上海古猿人石材有限公司 Nature-imitated travertine as well as composition and manufacture method thereof
CN106866084A (en) * 2016-12-28 2017-06-20 广西利升石业有限公司 A kind of large scale inorganic type artificial stone and preparation method thereof
CN112318680A (en) * 2020-11-02 2021-02-05 东台市艺和园装饰品有限公司 Production process of artificial travertine
CN112408903A (en) * 2020-11-17 2021-02-26 广西利升石业有限公司 Square material type flame-retardant noctilucent artificial stone and production process thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB236714A (en) * 1924-06-17 1925-07-16 Leonard George Nicoll Improvements in and relating to decorated or ornamental structural material
CN101941233A (en) * 2010-08-17 2011-01-12 广东新粤建材有限公司 Preparation method of artificial stone with imitated wood grain pattern and artificial stone
CN102343623A (en) * 2011-09-22 2012-02-08 佛山市河之舟机电有限公司 Method and equipment for distributing lines and textures in artificial stones
CN103848641A (en) * 2012-11-29 2014-06-11 上海古猿人石材有限公司 Artificial stone with irregular pore and preparation method thereof
CN103214214A (en) * 2013-02-26 2013-07-24 黄彰标 Preparation raw materials and preparation method of inorganic man-made rock
CN104402492A (en) * 2014-11-18 2015-03-11 上海古猿人石材有限公司 Nature-imitated travertine as well as composition and manufacture method thereof
CN106866084A (en) * 2016-12-28 2017-06-20 广西利升石业有限公司 A kind of large scale inorganic type artificial stone and preparation method thereof
CN112318680A (en) * 2020-11-02 2021-02-05 东台市艺和园装饰品有限公司 Production process of artificial travertine
CN112408903A (en) * 2020-11-17 2021-02-26 广西利升石业有限公司 Square material type flame-retardant noctilucent artificial stone and production process thereof

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