CN113698811B - Cooling coating and cooling coating - Google Patents
Cooling coating and cooling coating Download PDFInfo
- Publication number
- CN113698811B CN113698811B CN202111169026.5A CN202111169026A CN113698811B CN 113698811 B CN113698811 B CN 113698811B CN 202111169026 A CN202111169026 A CN 202111169026A CN 113698811 B CN113698811 B CN 113698811B
- Authority
- CN
- China
- Prior art keywords
- resin
- filler
- equal
- cooling coating
- putty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 105
- 239000011248 coating agent Substances 0.000 title claims abstract description 101
- 238000001816 cooling Methods 0.000 title claims abstract description 94
- 238000005057 refrigeration Methods 0.000 claims abstract description 77
- 230000005855 radiation Effects 0.000 claims abstract description 75
- 239000000945 filler Substances 0.000 claims abstract description 68
- 229920005989 resin Polymers 0.000 claims abstract description 58
- 239000011347 resin Substances 0.000 claims abstract description 58
- 239000003973 paint Substances 0.000 claims abstract description 56
- 238000002310 reflectometry Methods 0.000 claims abstract description 43
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000011324 bead Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- 239000000919 ceramic Substances 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 238000002834 transmittance Methods 0.000 claims description 12
- 239000002518 antifoaming agent Substances 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 11
- 229920000647 polyepoxide Polymers 0.000 claims description 11
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- 229920005749 polyurethane resin Polymers 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 229920001225 polyester resin Polymers 0.000 claims description 6
- 239000004645 polyester resin Substances 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 239000005083 Zinc sulfide Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- SJLOMQIUPFZJAN-UHFFFAOYSA-N oxorhodium Chemical compound [Rh]=O SJLOMQIUPFZJAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910003450 rhodium oxide Inorganic materials 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 229920006122 polyamide resin Polymers 0.000 claims description 3
- 229920005672 polyolefin resin Polymers 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 235000010215 titanium dioxide Nutrition 0.000 claims 2
- 239000007788 liquid Substances 0.000 abstract description 43
- 238000010276 construction Methods 0.000 abstract description 23
- 239000002994 raw material Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 10
- 239000010410 layer Substances 0.000 description 108
- 230000000052 comparative effect Effects 0.000 description 18
- 239000000758 substrate Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 239000002671 adjuvant Substances 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- -1 alcohol ester Chemical class 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000013035 waterborne resin Substances 0.000 description 2
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- 239000011426 gypsum mortar Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229940116423 propylene glycol diacetate Drugs 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a cooling coating and a cooling coating, wherein the cooling coating comprises liquid putty, the liquid putty comprises first resin and first filler, the sunlight reflectivity of the first filler in a 0.3-2.5 mu m waveband is greater than or equal to 85%, and the sunlight reflectivity of a putty layer formed by using the liquid putty in the 0.3-2.5 mu m waveband is greater than or equal to 88%. The reflectivity of the cooling coating prepared by the cooling coating to sunlight with a wave band of 0.3-2.5 mu m reaches over 88 percent, the indoor temperature of a building can be effectively reduced, meanwhile, the construction procedure is simple, the raw material cost and the construction cost of the radiation refrigeration finish paint layer are low, and further the raw material cost, the construction cost and the weather resistance of the cooling coating are low.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a cooling coating and a cooling coating.
Background
In order to reduce the indoor temperature of a building, a cooling coating is generally required to be arranged on the roof or the wall of the building. The traditional cooling coating comprises a bottom putty layer, a supporting layer, a face putty layer and a radiation refrigeration finish paint layer, wherein 3-6 radiation refrigeration finish paint layers are required to be applied in order to enable the reflectivity of the cooling coating to the sunlight with the wave band of 0.3-2.5 mu m to reach more than 88%, the thickness of each radiation refrigeration finish paint layer is about 30-50 mu m, and the total thickness of the radiation refrigeration finish paint layers reaches 0.2-0.5 mm. However, the construction procedure is complicated due to the multiple construction of the radiation refrigeration finish paint layer, and the raw material cost and the construction cost of the radiation refrigeration finish paint layer are high, so that the reflectivity of the cooling coating to the sunlight with the wave band of 0.3-2.5 μm is usually less than 88% in practical application.
Disclosure of Invention
Based on the above, there is a need for a cooling coating and a cooling coating, wherein the reflectivity of the cooling coating made of the cooling coating to sunlight with a wave band of 0.3 μm to 2.5 μm reaches above 88%, the indoor temperature of a building can be effectively reduced, and meanwhile, the construction procedure is simple, the raw material cost and the construction cost of the radiation refrigeration finish paint layer are low, and further the raw material cost and the construction cost of the cooling coating are low.
The invention provides a cooling coating, which comprises liquid putty, wherein the liquid putty comprises first resin and first filler, the sunlight reflectivity of the first filler in a 0.3-2.5 mu m waveband is greater than or equal to 85%, and the sunlight reflectivity of a putty layer formed by using the liquid putty in a 0.3-2.5 mu m waveband is greater than or equal to 88%.
In one embodiment, the cooling coating comprises a radiation refrigeration coating matched with the liquid putty, the sunlight reflectivity of a radiation refrigeration finish paint layer formed by the radiation refrigeration coating in a wave band of 0.3-2.5 μm is greater than or equal to 82%, and the atmospheric window emissivity in a wave band of 8-13 μm is greater than or equal to 88%.
In an embodiment, the first filler comprises at least one of calcium carbonate, barium sulfate, alumina, ceramic powder, aluminum silicate, talc, titanium dioxide, magnesium oxide, ceramic beads, or glass beads.
In one embodiment, the first filler has a reflectance of ultraviolet light, visible light, and infrared light of the sunlight of greater than or equal to 85%.
In one embodiment, the first filler has a mass of 200 parts by weight to 700 parts by weight based on 100 parts by weight of the first resin.
In one embodiment, the first resin has an elastic modulus of less than or equal to 2 MPa.
In one embodiment, the first resin has a solar transmittance of 90% or more in a wavelength band of 0.3 μm to 2.5 μm.
In one embodiment, the first resin includes at least one of an epoxy resin, a polyester resin, a polyacrylate resin, a polyamide resin, a polyurethane resin, a polyolefin resin, or a fluororesin.
In one embodiment, the liquid putty further comprises an auxiliary agent, wherein the mass of the auxiliary agent is less than or equal to 25 parts by weight based on 100 parts by weight of the first resin, and the auxiliary agent comprises at least one of a film forming auxiliary agent, a dispersing agent, a thickening agent or a defoaming agent.
In one embodiment, the radiation refrigeration coating comprises a second resin and a second filler and/or a third filler distributed in the second resin, the second resin comprises at least one of epoxy resin, polyester resin, polyurethane resin, acrylic resin or organic silicon resin, the second filler comprises at least one of aluminum silicate, pearl powder, silicon dioxide, heavy calcium powder, barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, ceramic beads or glass beads, and the third filler comprises at least one of aluminum oxide, zinc oxide, zirconium oxide, cerium oxide, lanthanum oxide, rhodium oxide or magnesium oxide.
The utility model provides a cooling coating that obtains by foretell cooling coating preparation, is including setting up in the putty layer on existing substrate surface, wherein, the substrate of putty layer is first resin, it has first filler to distribute in the putty layer, the thickness of putty layer is less than or equal to 1 mm.
In one embodiment, the cooling coating comprises a radiation refrigeration finish paint layer with the thickness of 15-60 μm, the radiation refrigeration finish paint layer is arranged on the surface, away from the existing substrate, of the putty layer in a laminated mode, the reflectivity of the cooling coating to sunlight with the wave band of 0.3-2.5 μm reaches over 88%, and the emissivity of an atmospheric window with the wave band of 8-13 μm is larger than or equal to 88%.
In the cooling coating, the first resin is used as a binder for the liquid putty, and the first resin has light transmittance, so that the first filler can fully reflect ultraviolet light, visible light and infrared light in sunlight, the sunlight reflectivity of a putty layer in a 0.3-2.5 mu m waveband is larger than or equal to 88%, when the putty layer and a radiation refrigeration finish coat layer with the sunlight reflectivity of 0.3-2.5 mu m waveband larger than or equal to 82% are stacked, the reflectivity of the cooling coating to the sunlight in the 0.3-2.5 mu m waveband reaches above 88%, and the emissivity of an atmospheric window in the 8-13 mu m waveband is larger than or equal to 88%, so that the indoor temperature of a building can be effectively reduced.
Meanwhile, when the thickness of the radiation refrigeration finish paint layer is below 15-60 mu m, the reflectivity of the radiation refrigeration finish paint layer to sunlight with a wave band of 0.3-2.5 mu m reaches above 88%, and the atmospheric window emissivity in a wave band of 8-13 mu m is larger than or equal to 88%, so that the radiation refrigeration finish paint layer only needs one construction, the putty layer and the radiation refrigeration finish paint layer are matched for use, only 2 procedures of the putty layer and the radiation refrigeration finish paint layer are needed, the construction procedure is simple and convenient, the high reflectivity of the putty layer can be utilized to effectively reduce the raw material cost and the construction cost of the radiation refrigeration finish paint layer, the raw material cost and the construction cost of the cooling coating are further reduced, and the simple procedure and the low cost can obtain the high reflectivity.
Drawings
Fig. 1 is a schematic structural diagram of a cooling coating according to an embodiment of the present invention.
In the figure: 10. a putty layer; 101. a first filler; 20. a radiation refrigeration finish paint layer; 201. a second filler; 202. a third filler; 30. and a protective layer.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the accompanying examples. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The cooling coating provided by the invention is mainly used for preparing a cooling coating, and the applicant finds that when the cooling coating is prepared by adopting the cooling coating, when the thickness of a radiation refrigeration finish paint layer is less than or equal to 60 micrometers, the reflectivity of the cooling coating to sunlight in a wave band of 0.3-2.5 micrometers is improved along with the improvement of the reflectivity of a putty layer to the sunlight in the wave band, but when the thickness of the radiation refrigeration finish paint layer is more than 60 micrometers, the light transmission effect of the radiation refrigeration finish paint layer is reduced, the effect of the putty layer on the reflection of the sunlight in the wave band of 0.3-2.5 micrometers cannot be achieved, and even if the reflectivity of the putty layer to the sunlight in the wave band of 0.3-2.5 micrometers is improved, the reflectivity of the cooling coating to the sunlight in the wave band of 0.3-2.5 micrometers cannot be improved along with the improvement of the reflectivity.
In order to enable the reflectivity of the cooling coating prepared by the cooling coating to the sunlight with the wave band of 0.3-2.5 microns to reach more than 88 percent, the indoor temperature of a building can be effectively reduced, meanwhile, the construction procedure is simple, the raw material cost and the construction cost of the radiation refrigeration finish paint layer are reduced, and further the raw material cost and the construction cost of the cooling coating are reduced.
The cooling coating provided by the invention comprises liquid putty, wherein the liquid putty comprises first resin and first filler, the sunlight reflectivity of the first filler in a wave band of 0.3-2.5 mu m is more than or equal to 85%, and the sunlight reflectivity of a putty layer formed by using the liquid putty in a wave band of 0.3-2.5 mu m is more than or equal to 88%.
In one embodiment, the first filler comprises at least one of calcium carbonate, barium sulfate, alumina, ceramic powder, aluminum silicate, titanium dioxide, magnesium oxide, ceramic beads, or glass beads; in order to enable the sunlight reflectivity of the first filler in a wave band of 0.3-2.5 microns to be higher, the sunlight reflectivity of the putty layer in a wave band of 0.3-2.5 microns is further improved to be more than 90%, and meanwhile, the indoor temperature of a building is better reduced, preferably, the reflectivity of the first filler to ultraviolet light, visible light and infrared light in sunlight is greater than or equal to 85%; the first filler further preferably includes at least one of calcium carbonate, barium sulfate, alumina, or glass beads.
The putty layer formed by the liquid putty has excellent emissivity of an atmospheric window in a wave band of 8-13 mu m, and in one embodiment, the emissivity of the atmospheric window in the wave band of 8-13 mu m of the putty layer formed by the liquid putty is greater than or equal to 86%.
In order to provide the first filler with higher solar reflectance and atmospheric window emissivity, in an embodiment, the particle size of the first filler is 1 μm to 40 μm, and more preferably 5 μm to 20 μm, the shape of the first filler is not further limited, and the first filler may be any one of rod-like, spherical, ellipsoidal, or irregular.
In order to make the putty layer formed by the liquid putty have higher reflectivity to sunlight with a wave band of 0.3-2.5 μm and avoid cracking of the putty layer in construction, in one embodiment, the mass of the first filler is 200-700 parts by weight, and more preferably 350-550 parts by weight based on 100 parts by weight of the first resin.
It will be appreciated that in order to better avoid cracking of the putty layer, in one embodiment, the first resin has a modulus of elasticity less than or equal to 2 MPa.
It can be understood that the light transmittance of the first resin affects the cooling effect of the cooling coating layer, and the light transmittance of the first resin is improved, on one hand, the absorption of the first resin on visible light can be reduced, so that the cooling coating layer has a better cooling effect, on the other hand, the reflectance of the first filler in the putty layer on ultraviolet light, visible light and infrared light in sunlight can be fully exerted, in order to further improve the sunlight reflectance of the putty layer in a 0.3 μm-2.5 μm waveband to more than 90%, the first resin with high sunlight transmittance is preferred, and in an embodiment, the sunlight transmittance of the first resin in a 0.3 μm-2.5 μm waveband is greater than or equal to 90%.
In one embodiment, the first resin includes at least one of an epoxy resin, a polyester resin, a polyacrylate resin, a polyamide resin, a polyurethane resin, a polyolefin resin, or a fluororesin. It will be appreciated that the first resin may be a water-borne resin, a solventless resin or a solvent-borne resin, preferably the first resin is a water-borne resin.
In one embodiment, the liquid putty further comprises an auxiliary agent, wherein the mass of the auxiliary agent is less than or equal to 25 parts by weight based on 100 parts by weight of the first resin.
In one embodiment, the adjuvant comprises at least one of a film forming adjuvant, a dispersant, a thickener, or a defoamer.
When the adjuvant comprises a film-forming adjuvant, which helps to enhance the film-forming properties of the liquid putty, lower the freezing temperature of the liquid putty, and improve the wet film properties of the liquid putty, such as leveling, sag resistance, in one embodiment, the film-forming adjuvant comprises at least one of an alcohol ester twelve, propylene glycol butyl ether, propylene glycol diacetate, dipropylene glycol dimethyl ether, ethylene glycol butyl ether, specific glycol methyl ether, propylene glycol, or benzyl alcohol, the mass of the film-forming adjuvant being less than or equal to 15 parts by weight based on 100 parts by weight of the first resin.
When the auxiliary agent includes a dispersant, the dispersant can improve the compatibility of the first resin with the first filler, and in one embodiment, the dispersant includes at least one of polyvinyl ether and its derivatives, polyacrylate, polymethacrylate, or salts of maleic anhydride-styrene copolymer, and the mass of the dispersant is less than or equal to 4 parts by weight based on 100 parts by weight of the first resin.
When the auxiliary agent comprises the thickening agent, the thickening agent can adjust the viscosity of the liquid putty, so that the liquid putty is prevented from being cooled during construction, the phenomenon of sagging of the liquid putty is caused, the good leveling property during construction is ensured, a smooth putty layer is formed, and the liquid putty is endowed with excellent storage stability.
In the production process of the liquid putty, a large amount of stable bubbles are not beneficial to smooth production and coating effect and performance in the coating process of the liquid putty, and a defoaming agent can be added for defoaming. When the auxiliary agent includes an antifoaming agent, the antifoaming agent can suppress the generation of bubbles and accelerate the collapse of generated bubbles, and in one embodiment, the antifoaming agent includes at least one of silicone antifoaming agent, polyether antifoaming agent, and fatty alcohol antifoaming agent, specifically, the antifoaming agent includes at least one of polydimethylsiloxane, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, and higher alcohol, and the mass of the antifoaming agent is less than or equal to 3 parts by weight based on 100 parts by weight of the first resin.
In one embodiment, the liquid putty further comprises a solvent, wherein the solvent is water, and the mass of the solvent is less than or equal to 500 parts by weight based on 100 parts by weight of the first resin.
In the cooling coating, when a putty layer formed by liquid putty and a radiation refrigeration finish paint layer with the sunlight reflectivity of 0.3-2.5 mu m wave band more than or equal to 82 percent are arranged in a laminated mode, the reflectivity of a cooling coating made of the cooling coating to the sunlight of 0.3-2.5 mu m wave band reaches more than 88 percent.
In one embodiment, the cooling coating comprises a radiation refrigeration coating matched with liquid putty, the sunlight reflectivity of a radiation refrigeration finish paint layer formed by the radiation refrigeration coating in a wave band of 0.3-2.5 μm is greater than or equal to 82%, and the atmospheric window emissivity in a wave band of 8-13 μm is greater than or equal to 88%.
It should be noted that when the thickness of the radiation refrigeration finish paint layer is 15 μm to 60 μm, the putty layer and the radiation refrigeration finish paint layer have a synergistic effect, so that the solar reflectance of the cooling coating layer in the 0.3 μm to 2.5 μm band is higher than that of the putty layer and the radiation refrigeration finish paint layer, in an embodiment, when the solar reflectance of the radiation refrigeration finish paint layer formed by the radiation refrigeration paint in the 0.3 μm to 2.5 μm band is greater than or equal to 82% and less than 88%, the reflectance of the cooling coating layer formed by the cooling paint to the solar of the 0.3 μm to 2.5 μm band reaches above 88%, therefore, in an embodiment, the solar reflectance of the radiation refrigeration finish paint layer formed by the radiation refrigeration paint in the 0.3 μm to 2.5 μm band is greater than or equal to 82%, preferably, the solar reflectance of the radiation refrigeration finish paint layer formed by the radiation refrigeration paint in the 0.3 μm to 2.5 μm band is greater than or equal to 82%, and less than 88%.
It should be noted that when the thickness of the radiation refrigeration finish paint layer is greater than 60 μm, the reflectivity of the putty layer cannot play a role well, and the sunlight reflectivity of the cooling coating layer in the wave band of 0.3 μm to 2.5 μm is lower than that of the putty layer and the radiation refrigeration finish paint layer, while when the thickness of the radiation refrigeration finish paint layer is less than 15 μm, the reflectivity of the radiation refrigeration finish paint layer cannot play a role well, and the sunlight reflectivity of the cooling coating layer in the wave band of 0.3 μm to 2.5 μm is lower than that of the putty layer and the radiation refrigeration finish paint layer.
The radiation refrigeration finish paint layer formed by the radiation refrigeration coating can emit heat through the atmospheric window in an infrared radiation mode, so that the cooling effect of the cooling coating is further improved, and the indoor temperature of a building can be further effectively reduced; in addition, the second filler and/or the third filler in the radiation refrigeration coating can improve the weather resistance of the cooling coating; the cooling coating can be subjected to color mixing through the selection of the types of the second filler and/or the third filler so as to meet the requirements of customers.
In one embodiment, the radiation-curable coating includes a second resin and a second filler and/or a third filler distributed in the resin.
In order to better improve the cooling effect of the cooling coating on the indoor space of the building, in one embodiment, the light transmittance of the second resin in the wave band of 0.3-2.5 μm is greater than or equal to 90%.
In one embodiment, the second resin includes at least one of an epoxy resin, a polyester resin, a polyurethane resin, an acrylic resin, or a silicone resin.
In one embodiment, the second filler comprises at least one of aluminum silicate, pearl powder, silicon dioxide, heavy calcium powder, barium sulfate, talc, titanium dioxide, zinc sulfide, ceramic powder, ceramic beads, or glass beads. In order to enable the cooling coating to better reduce the indoor temperature of the building, preferably, the reflectivity of the second filler to visible light and near infrared light is greater than or equal to 80%, and the infrared emissivity in an atmospheric window of 8-13 μm is greater than 80%, and specifically, the second filler preferably comprises at least one of aluminum silicate, pearl powder, heavy calcium powder, barium sulfate, talcum powder, titanium dioxide, zinc sulfide, ceramic powder, ceramic beads or glass beads; the mass of the second filler is 5 parts by weight to 80 parts by weight, more preferably 10 parts by weight to 40 parts by weight, based on 100 parts by weight of the second resin.
In an embodiment, the third filler comprises at least one of alumina, zinc oxide, zirconia, ceria, lanthana, rhodium oxide, or magnesia. In order to enable the cooling coating to better reduce the indoor temperature of the building, the reflectivity of the third filler to ultraviolet light and visible light is preferably greater than or equal to 80%, and the infrared emissivity in an atmospheric window of 8-13 μm is greater than 80%, and particularly, the third filler preferably comprises at least one of alumina, zirconia, ceria, lanthana or rhodium oxide; the mass of the third filler is 0.5 parts by weight to 20 parts by weight, and more preferably 0.5 parts by weight to 10 parts by weight, based on 100 parts by weight of the second resin.
The invention also provides an application method of the cooling coating, which comprises the following steps:
providing liquid putty, forming the liquid putty on the surface of the existing substrate, and drying to form a putty layer; and forming a radiation refrigeration finish paint layer on the surface of the putty layer far away from the existing matrix to obtain the cooling coating.
In one embodiment, a method of forming a radiation-refrigerated topcoat layer includes: and forming the radiation refrigeration coating on the surface of the putty layer, and drying to form the radiation refrigeration finish paint layer.
Optionally, the liquid putty may be formed on the surface of the existing substrate by brushing, rolling, spraying, or the like, and the radiation refrigeration coating may be formed on the surface of the putty layer by brushing, rolling, spraying, or the like.
In the cooling coating prepared by adopting the cooling coating, when the thickness of the radiation refrigeration finish paint layer is 15-60 mu m, the reflectivity of the cooling coating to sunlight with a wave band of 0.3-2.5 mu m is more than or equal to 88 percent, and the emissivity of an atmospheric window with a wave band of 8-13 mu m is more than or equal to 88 percent, so that the radiation refrigeration finish paint layer only needs one construction, the construction procedure is simple and convenient, the raw material cost and the construction cost of the radiation refrigeration finish paint layer 20 can be effectively reduced, and the raw material cost and the construction cost of the cooling coating are further reduced.
In addition, the cooling coating prepared by the cooling coating has excellent artificial climate aging resistance, and in one embodiment, the weather resistance of the cooling coating is tested by referring to GB/T9755-.
As shown in fig. 1, the cooling coating of an embodiment made of the cooling coating includes a putty layer 10 disposed on a surface of an existing substrate, wherein a base material of the putty layer 10 is a first resin, and first fillers 101 are distributed in the putty layer 10.
In this embodiment, the cooling coating further includes a radiation refrigeration finish paint layer 20 with a thickness of 15 μm to 60 μm, and the radiation refrigeration finish paint layer 20 is stacked on the surface of the putty layer 10 away from the existing substrate.
In one embodiment, the matrix material of the radiation refrigeration topcoat layer 20 is a second resin, and the second filler 201 and/or the third filler 202 are distributed in the radiation refrigeration topcoat layer.
In one embodiment, the thickness of the putty layer 10 is less than or equal to 1mm for better reducing the production cost of the cooling coating.
In an embodiment, the cooling coating further includes a protective layer 30, and the protective layer 30 is stacked on the surface of the radiation refrigeration topcoat layer 20 away from the putty layer 10, so as to provide surface protection, prevent the cooling effect of the cooling coating from being reduced due to surface contamination, and simultaneously improve the weather resistance of the cooling coating.
In one embodiment, the material of the protective layer 30 includes one or more of polyacrylic resin, polyurethane resin, fluorocarbon resin, and silicone resin.
When the cooling coating is applied, the cooling coating is arranged on the surface of the existing substrate, wherein the surface of the radiation refrigeration finish paint layer 20 of the cooling coating, which is far away from the putty layer 10, is a light incident side, or when the cooling coating is also provided with the protective layer 30, the surface of the protective layer 30, which is far away from the radiation refrigeration finish paint layer 20, is a light incident side.
Specifically, the existing substrate includes an exterior wall or a roof of a building.
In one embodiment, a leveling layer is further stacked between the existing base body and the cooling coating, and the leveling layer is beneficial to increasing the adhesive force of the cooling coating on the existing base material. The leveling layer can be cement plastering mortar, gypsum mortar or external wall liquid putty, etc.
The present invention will be described in further detail with reference to specific examples and comparative examples. It is understood that the following examples are more specific to the apparatus and materials used, and in other embodiments, are not limited thereto.
Example 1
The cooling coating of embodiment 1, comprising liquid putty and radiation refrigeration coating used in cooperation with the liquid putty.
Wherein the liquid putty comprises a first resin: 100 parts by weight of an epoxy resin, a first filler: 500 parts by weight of barium sulfate, film-forming aid: 9.1 parts by weight of alcohol ester twelve, dispersant: 1.8 parts by weight of polymethacrylate, thickener: 0.9 parts by weight of associative polyurethane thickener, defoamer: 0.1 part by weight of polydimethylsiloxane, solvent: 25 parts by weight of water, wherein the elastic modulus of the epoxy resin is 1.6MPa, and the sunlight transmittance in a wave band of 0.3-2.5 μm is 91.2%.
The radiation refrigeration coating comprises a second resin: 100 parts by weight of an epoxy resin, a second filler: 8 parts by weight of titanium dioxide, a third filler: 4 parts by weight of alumina.
Forming liquid putty on the surface of the existing substrate roof, and drying to form a putty layer 10, wherein the thickness of the putty layer 10 is 0.5 mm; and forming the radiation refrigeration coating on the surface of the putty layer 10, and drying to form a radiation refrigeration finish paint layer 20, wherein the thickness of the radiation refrigeration finish paint layer 20 is 30 mu m, so as to obtain the cooling coating.
Example 2
Example 2 the embodiment of example 1 is referenced, except that the thickness of the radiant refrigeration topcoat layer 20 is 20 μm.
Example 3
Example 3 the embodiment of example 1 is referenced, except that the thickness of the radiant refrigeration topcoat layer 20 is 60 μm.
Example 4
Example 4 the embodiment of example 1 was referenced except that the radiation refrigeration coating included a second resin: 100 parts by weight of an epoxy resin, a second filler: 8 parts of titanium dioxide.
Example 5
Example 5 the embodiment of example 1 was referenced, except that the radiation refrigeration coating included a second resin: 100 parts by weight of an epoxy resin, a third filler: 4 parts by weight of alumina.
Example 6
Example 6 the embodiment of example 1 is referred to, except that the first filler in the liquid putty: 200 parts by weight of calcium carbonate.
Example 7
Example 7 the embodiment of example 1 is referenced, except that the first filler in the liquid putty: 700 parts by weight of calcium carbonate.
Example 8
Example 8 the embodiment of example 1 was referenced, except that the first resin in the liquid putty: 100 parts by weight of polyurethane resin, wherein the elastic modulus of the polyurethane resin is 1.6MPa, and the sunlight transmittance in a wave band of 0.3-2.5 mu m is 92.2%.
Example 9
Example 9 the embodiment of example 1 was referenced, except that the first resin in the liquid putty: 100 parts by weight of polyacrylate resin, wherein the elastic modulus of the polyacrylate resin is 2.2MPa, and the sunlight transmittance in a wave band of 0.3-2.5 μm is 93.3%.
Example 10
Example 10 the embodiment of example 1 was referenced, except that the first resin in the liquid putty was replaced with a silicone resin having an elastic modulus of 1.8MPa and a solar light transmittance of 87.4% in the 0.3 μm to 2.5 μm wavelength band.
Comparative example 1
Comparative example 1 the embodiment of example 1 is referenced, except that the first filler in the liquid putty: 500 parts by weight of silica.
Comparative example 2
Comparative example 2 the embodiment of example 1 was referenced, except that the thickness of the radiant refrigeration topcoat layer 20 was 70 μm.
Comparative example 3
Comparative example 3 the embodiment of example 1 is referred to with the difference that the thickness of the radiation refrigeration topcoat layer 20 is 13 μm.
Comparative example 4
Comparative example 4 the embodiment of example 1 is referenced, except that the first filler in the liquid putty: 500 parts by weight of talc powder.
Comparative example 5
Comparative example 5 the embodiment of example 1 was referenced, except that the reduced temperature coating did not include a radiant cooling topcoat layer.
Comparative example 6
Comparative example 6 the embodiment of example 1 was referenced, except that the radiation-curable coating material did not contain the second filler and the third filler, and correspondingly, the radiation-curable topcoat layer did not contain the second filler and the third filler.
The optical properties of the above examples 1 to 10 and comparative examples 1 to 6 were measured, and the test criteria are as follows, and the test results are shown in Table 1.
Solar reflectance: reference is made to the specification of 6.4 in JG/T235-2014.
Atmospheric window emissivity: reference is made to the specification of T/ZZB 2304-2021.
TABLE 1
In Table 1, the reflectance to sunlight represents the reflectance to sunlight of a wavelength band of 0.3 μm to 2.5 μm; the emissivity at the atmospheric window represents the emissivity at the atmospheric window in the 8 μm-13 μm band.
The artificial weather aging resistance of the cooling coatings of the above examples 1-10 and comparative examples 1-6 is tested by referring to the specification of GB/T9755-: the temperature-reducing coatings provided by examples 1-10 and comparative examples 1-4 have no bubbling, peeling and cracks within 600h, the temperature-reducing coating provided by comparative example 5 has abnormal conditions such as bubbling and peeling within 60h, and the temperature-reducing coating provided by comparative example 6 has abnormal conditions such as bubbling and peeling within 400 h.
The technical features of the above embodiments can be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the above embodiments are not described, but should be considered as the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above examples only show some embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (5)
1. A cooling coating is characterized by comprising a putty layer arranged on the surface of an existing matrix and a radiation refrigeration finish paint layer which is arranged on the surface of the putty layer far away from the existing matrix in a laminated manner;
the sunlight reflectivity of the putty layer at a wave band of 0.3-2.5 microns is larger than or equal to 88%, the thickness of the putty layer is smaller than or equal to 1mm, a base material of the putty layer is first resin, first fillers are distributed in the putty layer, the sunlight transmittance of the first resin at a wave band of 0.3-2.5 microns is larger than or equal to 90%, the first resin comprises at least one of epoxy resin, polyester resin, polyacrylate resin, polyamide resin, polyurethane resin, polyolefin resin or fluororesin, the sunlight reflectivity of the first fillers at a wave band of 0.3-2.5 microns is larger than or equal to 85%, and the first fillers comprise at least one of calcium carbonate, barium sulfate, aluminum oxide, ceramic powder, aluminum silicate, talcum powder, titanium dioxide, magnesium oxide, ceramic beads or glass beads;
the thickness of the radiation refrigeration finish paint layer is 15-60 mu m, the sunlight reflectivity of the radiation refrigeration finish paint layer in a wave band of 0.3-2.5 mu m is greater than or equal to 82%, the atmospheric window emissivity in a wave band of 8-13 mu m is greater than or equal to 88%, the base material of the radiation refrigeration finish paint layer is second resin, second filler and/or third filler are/is further distributed in the radiation refrigeration finish paint layer, the second resin comprises at least one of epoxy resin, polyester resin, polyurethane resin, acrylic resin or organic silicon resin, the second filler comprises at least one of aluminum silicate, pearl powder, silicon dioxide, heavy calcium powder, barium sulfate, talcum powder, titanium white, zinc sulfide, ceramic powder, ceramic beads or glass beads, and the third filler comprises aluminum oxide, zinc oxide, zirconium oxide, At least one of cerium oxide, lanthanum oxide, rhodium oxide, or magnesium oxide;
the reflectivity of the cooling coating to sunlight with a wave band of 0.3-2.5 μm reaches over 88%, and the emissivity of an atmospheric window with a wave band of 8-13 μm is greater than or equal to 88%.
2. The cooling coating of claim 1, wherein the first filler has a reflectivity of 85% or more of ultraviolet light, visible light, and infrared light of sunlight.
3. The cooling coating of claim 1, wherein the mass of the first filler is 200 parts by weight to 700 parts by weight based on 100 parts by weight of the first resin.
4. The temperature reduction coating of claim 1, wherein the first resin has an elastic modulus of less than or equal to 2 MPa.
5. The cooling coating according to any one of claims 1-4, wherein the putty layer further comprises an auxiliary agent, the auxiliary agent comprises at least one of a film forming auxiliary agent, a dispersing agent, a thickening agent or a defoaming agent, and the mass of the auxiliary agent is less than or equal to 25 parts by weight based on 100 parts by weight of the first resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111169026.5A CN113698811B (en) | 2021-09-30 | 2021-09-30 | Cooling coating and cooling coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111169026.5A CN113698811B (en) | 2021-09-30 | 2021-09-30 | Cooling coating and cooling coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113698811A CN113698811A (en) | 2021-11-26 |
| CN113698811B true CN113698811B (en) | 2022-08-02 |
Family
ID=78662657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111169026.5A Active CN113698811B (en) | 2021-09-30 | 2021-09-30 | Cooling coating and cooling coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113698811B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114525612B (en) * | 2022-02-22 | 2023-07-11 | 宁波瑞凌新能源科技有限公司 | Cooling fiber, preparation method thereof and textile |
| CN117567894B (en) * | 2024-01-11 | 2024-04-05 | 中稀易涂科技发展有限公司 | High-emission rare earth-based radiation refrigeration coating |
| CN118006156A (en) * | 2024-01-11 | 2024-05-10 | 中稀易涂科技发展有限公司 | High-performance rare earth-based radiation refrigeration coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951721A (en) * | 1971-04-21 | 1976-04-20 | Hitachi, Ltd. | Method of forming a mechanically strong reflective surface |
| JP2001334208A (en) * | 2000-03-23 | 2001-12-04 | Kansai Paint Co Ltd | Repair coating method |
| CN106118307A (en) * | 2016-07-05 | 2016-11-16 | 马承银 | A kind of building coating with heat-insulation and heat-preservation function and preparation method thereof |
| CN108299979A (en) * | 2016-09-12 | 2018-07-20 | 广东华润涂料有限公司 | The true stone coating system of heat reflectivity |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368488C (en) * | 2003-08-06 | 2008-02-13 | 关桂南 | Heat insulation leak-proof antifouling outer wall mastic |
| CN103351697A (en) * | 2013-06-25 | 2013-10-16 | 天长市开林化工有限公司 | Elastic thermal insulation exterior wall putty |
| CN108084831A (en) * | 2017-12-25 | 2018-05-29 | 安徽科创美涂料科技股份有限公司 | The preparation method of architectural reflective heat-insulation paint and the construction wall using the coating |
| CN109457594B (en) * | 2018-11-22 | 2020-12-11 | 云南交通运输职业学院 | Concrete bridge protection structure layer with heat insulation and temperature reduction functions and construction method thereof |
| CN212897422U (en) * | 2020-06-30 | 2021-04-06 | 佛山市顺德区佳涂乐恒融建筑装饰有限公司 | Heat-insulating putty outer wall coating structure |
| CN112341914A (en) * | 2020-11-04 | 2021-02-09 | 中建二局第一建筑工程有限公司 | Heat insulation coating and preparation method thereof |
| CN112500730A (en) * | 2020-12-18 | 2021-03-16 | 北京三棵树新材料科技有限公司 | Outer wall flexible putty powder with light reflection capability and preparation method thereof |
-
2021
- 2021-09-30 CN CN202111169026.5A patent/CN113698811B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951721A (en) * | 1971-04-21 | 1976-04-20 | Hitachi, Ltd. | Method of forming a mechanically strong reflective surface |
| JP2001334208A (en) * | 2000-03-23 | 2001-12-04 | Kansai Paint Co Ltd | Repair coating method |
| CN106118307A (en) * | 2016-07-05 | 2016-11-16 | 马承银 | A kind of building coating with heat-insulation and heat-preservation function and preparation method thereof |
| CN108299979A (en) * | 2016-09-12 | 2018-07-20 | 广东华润涂料有限公司 | The true stone coating system of heat reflectivity |
Non-Patent Citations (1)
| Title |
|---|
| 《Preparation and Experimental Study on a New Type of Exterior Wall Putty》;Zhang, GL;《CONSTRUCTION AND URBAN PLANNING, PTS 1-4》;20131204;全文 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113698811A (en) | 2021-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113698811B (en) | Cooling coating and cooling coating | |
| TWI740202B (en) | Radiative cooling functional coating, method for manufacturing the same and application thereof, and selective radiative cooling functional coating and composite material | |
| JP6707150B2 (en) | Sealing material for photovoltaic module and method for manufacturing the sealing material | |
| CN100554355C (en) | A kind of thermal-insulating external-wall coating of nano-composite water and preparation method thereof | |
| CN106700789B (en) | Water-based building energy-saving coating and preparation method thereof | |
| CN103756540B (en) | A kind of roofing heat insulating reflecting coating and preparation method thereof | |
| JP2019518113A5 (en) | ||
| CN102226054A (en) | Sunlight reflective insulation paint | |
| KR102439658B1 (en) | Infrared reflective clear oating compositions for elastomeric wall and roof coatings | |
| CN110105798A (en) | Cement base radiation refrigeration dry powder paint, building coating, coating production | |
| KR102207388B1 (en) | Method for forming a heat-shielding and water-resistant coating with two layers structure using 2-coat-type aqueous heat-shielding and water-resistant paint for rooftop or roof | |
| CN101565581A (en) | Reflective heat-insulation coating and preparation method thereof | |
| CN114539861B (en) | Water-based radiation refrigeration coating and preparation method thereof | |
| KR20190090957A (en) | 2-coat-type aqueous heat-shielding and water-resistant paint for rooftop or roof, method for forming a heat-shielding and water-resistant coating with two layers structure using the same, and a heat-shielding and water-resistant coating with two layers structure thereby | |
| CN113563779B (en) | Polymer cement radiation refrigeration paint and coating | |
| CN112745712A (en) | Scrape-coatable light high-efficiency radiation refrigeration coating and preparation method and application thereof | |
| CN108659657A (en) | A kind of building external paint and its application | |
| KR101225069B1 (en) | Multi-functional paint composition and method of manufacturing paint film using the same | |
| CN113999579B (en) | Diffuse reflection paint and diffuse reflection coating | |
| CN109880469A (en) | A kind of weather-proof exterior coating of Art Design | |
| JP4959128B2 (en) | How to paint exterior walls of buildings | |
| CN107987597A (en) | Heat insulating coatings used for building exterior wall and preparation method thereof | |
| CN105295574B (en) | A kind of reflective heat-insulation paint and preparation method thereof | |
| CN113265885A (en) | Cooling film cloth | |
| CN112300680B (en) | Reflective heat-insulating coating system and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240729 Address after: Unit 220, Building 1-1, Fujian Haiyuan Huachuang New Material Products Co., Ltd., No. 16 Jinzhou North Road, Jianxin Town, Cangshan District, Fuzhou City, Fujian Province 350028 Patentee after: Fujian Ruiling New Energy Technology Co.,Ltd. Country or region after: China Address before: No.88, Dongfeng Road, Fenghua District, Ningbo City, Zhejiang Province, 315000 Patentee before: NINGBO RUILING NEW ENERGY TECHNOLOGY Co.,Ltd. Country or region before: China Patentee before: Ningbo Ruiling New Energy Materials Research Institute Co.,Ltd. |