CN113669513B - Water absorption device with variable pipe diameter - Google Patents

Water absorption device with variable pipe diameter Download PDF

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Publication number
CN113669513B
CN113669513B CN202110760266.6A CN202110760266A CN113669513B CN 113669513 B CN113669513 B CN 113669513B CN 202110760266 A CN202110760266 A CN 202110760266A CN 113669513 B CN113669513 B CN 113669513B
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parts
layer
pipe diameter
rubber layer
sensitive adhesive
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CN113669513A (en
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陈军
黄裕中
张小红
赵敏
孙马全
吴宏亮
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Zhong Yu Hoses Technology Co ltd
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Zhong Yu Hoses Technology Co ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02Vinyl aromatic monomers and conjugated dienes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L55/00Devices or appurtenances for use in, or in connection with, pipes or pipe systems
    • F16L55/02Energy absorbers; Noise absorbers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/02Protection of pipes or objects of similar shape against external or internal damage or wear against cracking or buckling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use

Abstract

The invention relates to a water absorption device with a variable pipe diameter, which sequentially comprises an inner rubber layer, a pressure-sensitive rubber layer, an outer rubber layer and a spiral reinforcing rib layer from inside to outside; the pressure sensitive adhesive layer can increase the pipe diameter of the water absorbing device by at least 0.6%; the material of the pressure sensitive adhesive layer is a thermoplastic elastomer base material, and the basic performance of the material needs to reach more than 12MPa of tensile strength, more than 600% of elongation, 15-25 of Mooney viscosity and more than 70N/25mm of peel strength; the thickness is 2.5-3.5 mm; the material formula of the sensitive pressure-sensitive adhesive layer comprises the following raw materials in parts by weight: 100 parts of styrene block copolymer, 20-80 parts of nano particles, 5-8 parts of plasticizer, 10-30 parts of adhesive and 1-3 parts of anti-aging agent. The pipe diameter of the invention has variability and wider variable range, and has higher adaptability and higher loading and unloading efficiency with water absorption accessories such as interfaces and the like.

Description

Water absorption device with variable pipe diameter
Technical Field
The invention relates to the technical field of water suction appliances, in particular to a water suction appliance with a variable pipe diameter.
Background
The water sucking device is one to convey water from water source to water pump and includes water sucking pipe and water sucking accessory. The water suction pipe is a water pipe for guiding water from a water source to a water pump, and is required to have high compressive strength, good flexibility, small water suction resistance and convenient use. The vacuum powder and particle sucking machine is mainly applied to vacuum powder and particle sucking, water conveying, chemical material conveying and the like in the industries of industrial and mining, agriculture, water conservancy, civil engineering, chemical engineering, fire fighting and the like, and has wide application in the fields of farmland irrigation, industrial and mining, sand pumping, sand blasting, indoor gas, powder and dust absorption and discharge and the like. The method is mainly applied to occasions with variable environments and has high requirements on lightness, reliability and the like.
The water suction pipe in China has specifications of 65mm, 80mm, 90mm, 100mm, 125mm, 150mm and the like according to the inner diameter. The fire fighting truck is divided into a straight pipe type and a coil type according to the placement form on the fire fighting truck. Can be divided into a rubber water suction pipe and a synthetic resin water suction pipe according to the material. The rubber water suction pipe is composed of a rubber or synthetic rubber layer, a rubberized fabric layer and a metal or hard synthetic resin reinforcing spiral line. The synthetic resin suction pipe is composed of a hard synthetic resin and a metal or hard synthetic resin reinforcing spiral line, or is composed of a soft synthetic resin layer and a step layer, namely the metal or hard synthetic resin reinforcing spiral line, and the soft synthetic resin is used as a spiral body. The water suction pipe interface is used for connecting the fire pump and the water suction pipe, each interface is provided with an internal thread interface and an external thread interface, the external thread structure can be connected with a water filter, and the internal thread interface can be connected with a water pump fire hydrant.
However, the size fluctuation of the inner diameter is large when the existing spiral water suction pipe is produced, the matching performance with the size of the interface is poor in use, the loading and unloading are difficult, and the fire scene relief efficiency is seriously influenced; and the existing spiral water suction pipe has poor bursting pressure performance, and the service life is influenced in practical use.
Disclosure of Invention
In order to solve the technical problem that the prior spiral water suction pipe has poor adaptability with a connector in use, a water suction appliance with a variable pipe diameter is provided. Compared with the conventional spiral suction pipe, the spiral suction pipe serving as the water suction device has the advantages that the pipe diameter size is changeable, the variable range is wide, the spiral suction pipe has higher adaptability with water suction accessories such as interfaces and the like, and the assembly and disassembly efficiency is higher.
In order to achieve the purpose, the invention is realized by the following technical scheme:
a water absorption device with a variable pipe diameter sequentially comprises an inner rubber layer, a pressure sensitive rubber layer, an outer rubber layer and a spiral reinforcing rib layer from inside to outside; the pressure sensitive adhesive layer can increase the pipe diameter of the water absorbing device by at least 0.6%.
Furthermore, the inner rubber layer is made of a soft PVC-based material or a thermoplastic polyurethane material, the thickness of the inner rubber layer is 1.5-2.5 mm, and the Shore hardness A is 25-30.
Further, the outer rubber layer and the spiral reinforcing rib layer are made of hard PVC-based materials; the thickness of the outer adhesive layer is 4-6 mm, and the Shore hardness A is 35-40; the Shore A hardness of the spiral reinforcing rib layer is 85-90.
Furthermore, the pressure sensitive adhesive layer is made of a thermoplastic elastomer base material, and the basic performance of the material needs to reach the tensile strength of more than 12MPa, the elongation of more than 600 percent, the Mooney viscosity (ML 1+4, 100) of 15-25 and the peel strength of more than 70N/25 mm; the thickness is 2.5-3.5 mm.
Still further, the material formula of the pressure sensitive adhesive layer comprises the following raw materials in parts by weight: 100 parts of styrene block copolymer, 20-80 parts of nano particles, 5-8 parts of plasticizer, 10-30 parts of adhesive and 1-3 parts of anti-aging agent.
Preferably, the styrenic block copolymer is SBS and/or SIS.
Preferably, the nano particles are at least one of nano argil, nano superfine kaolin and tetrapod-like nano zinc oxide.
Preferably, the plasticizer is dioctyl phthalate or dioctyl terephthalate.
Preferably, the adhesive is at least one of rosin ester, terpene phenolic resin, terpene resin, C5 petroleum resin, C9 aromatic petroleum resin, coumarone resin.
Preferably, the anti-aging agent is at least one of BZ, PX and Antiazaid L122.
The beneficial technical effects are as follows:
the water absorber is a spiral water absorbing pipe, and a layer of pressure sensitive adhesive layer is added between the inner adhesive layer and the outer adhesive layer of the conventional spiral water absorbing pipe, so that the spiral water absorbing pipe has the characteristic of variable pipe diameter. The conventional spiral water suction pipe has no pipe diameter variability, has larger error in production, has poorer adaptability with auxiliary water suction appliances, and influences the assembly efficiency. However, the diameter of the water suction pipe of the invention is variable, the pipe diameter can be enlarged by adding the sensitive pressure glue layer, the water suction pipe has wider variable range, and the advantage of the enlarged pipe diameter is better adaptability with the attached water suction appliance and higher assembly efficiency.
Compared with the conventional spiral water suction pipe, the combination of the inner glue layer and the outer glue layer is tighter due to the addition of the pressure sensitive glue layer, the thickness of the whole pipe wall of the water suction pipe is increased, and the bursting pressure of the water suction pipe is improved to a certain extent; in addition, the vibration and impact generated in the using and carrying processes of the pipe body can be effectively reduced, and the application life of the water absorption pipe is prolonged.
Drawings
FIG. 1 is a schematic sectional view of a spiral suction pipe as a water absorbing device according to the present invention.
Wherein, 1-inner rubber layer, 2-sensitive pressure rubber layer, 3-outer rubber layer and 4-spiral reinforcing rib layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention and the accompanying drawings, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. The following description of at least one exemplary embodiment is merely illustrative in nature and is in no way intended to limit the invention, its application, or uses. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Unless specifically stated otherwise, the numerical values set forth in these examples do not limit the scope of the invention. Techniques, methods known to those of ordinary skill in the relevant art may not be discussed in detail, but are intended to be part of the specification where appropriate. In all examples shown and discussed herein, any particular value should be construed as merely illustrative, and not limiting. Thus, other examples of the exemplary embodiments may have different values.
Example 1
A water absorption device with a variable pipe diameter is a spiral water absorption pipe, and the structure of the spiral water absorption pipe from inside to outside is shown in figure 1, and the spiral water absorption pipe sequentially comprises an inner glue layer 1, a pressure sensitive glue layer 2, an outer glue layer 3 and a spiral reinforcing rib layer 4 from inside to outside.
Wherein the inner adhesive layer is made of soft PVC-based material or thermoplastic polyurethane material, the thickness of the inner adhesive layer is 1.5-2.5 mm, and the Shore hardness A of the inner adhesive layer is 25-30.
The outer rubber layer and the spiral reinforcing rib layer are made of hard PVC-based materials; the thickness of the outer adhesive layer is 4-6 mm, and the Shore hardness A is 35-40; the Shore A hardness of the spiral reinforcing rib layer is 85-90.
The pressure sensitive adhesive layer is made of a thermoplastic elastomer-based material and comprises the following raw materials in parts by weight: 100 parts of SIS, 20 parts of tetrapod-like nano zinc oxide, 50 parts of nano superfine kaolin, 5 parts of dioctyl terephthalate, 20 parts of terpene phenolic resin (with the softening point of more than 120 ℃), 5 parts of C5 petroleum resin, 5 parts of coumarone resin, 1 part of BZ anti-aging agent and 1 part of Antiozaid L122 anti-aging agent. The thickness is 2.5-3.5 mm. The basic properties of the pressure-sensitive adhesive layer of this example are shown in Table 1.
The overall performance of the spiral suction pipe of this example is shown in Table 2.
The spiral water suction pipe is prepared through mixing the materials, pelletizing, extruding separately on a core rod, compounding and forming in hot air channel, and cooling.
In this embodiment, the hardness of the inner glue layer, the outer glue layer and the spiral reinforcing rib layer can be adjusted by adding fillers such as white carbon black, ultrafine kaolin, calcium carbonate and the like into the PVC substrate and obtaining the materials of each layer with corresponding hardness through an optimization test, which can be performed by those skilled in the art.
Example 2
A water sucking device with a variable pipe diameter is a spiral water sucking pipe, and the structure of the water sucking device is the same as that of the water sucking device in the embodiment 1.
The pressure sensitive adhesive layer is made of a thermoplastic elastomer-based material and comprises the following raw materials in parts by weight: 100 parts of SBS, 30 parts of four-needle-shaped nano zinc oxide, 40 parts of nano superfine argil, 5 parts of dioctyl phthalate, 10 parts of terpene phenolic resin, 5 parts of C5 petroleum resin, 10 parts of coumarone resin, 1 part of PX anti-aging agent and 1 part of aniozaid L122 anti-aging agent. The thickness is 2.5-3.5 mm. The basic properties of the pressure-sensitive adhesive layer of this example are shown in Table 1.
The overall performance of the spiral suction pipe of this example is shown in Table 2.
Example 3
A water sucking device with a variable pipe diameter is a spiral water sucking pipe, and the structure of the water sucking device is the same as that of the water sucking device in the embodiment 1.
The pressure sensitive adhesive layer is made of a thermoplastic elastomer-based material and comprises the following raw materials in parts by weight: 50 parts of SBS, 50 parts of SIS, 40 parts of four-needle-shaped nano zinc oxide, 30 parts of nano superfine kaolin, 5 parts of dioctyl terephthalate, 10 parts of terpene resin, 10 parts of C9 aromatic hydrocarbon petroleum resin, 1 part of BZ antioxidant and 1 part of Antiozard L122 antioxidant. The thickness is 2.5-3.5 mm. The basic properties of the pressure-sensitive adhesive layer of this example are shown in Table 1.
The overall performance of the spiral suction pipe of this example is shown in Table 2.
Comparative example 1
This comparative example has the same structure as the absorbent tube of example 1 except that it does not contain a pressure sensitive adhesive layer.
Comparative example 2
The comparative example has the same structure as the water absorption pipe of example 1, except that 70 parts of nanometer ultrafine kaolin are selected as the nanometer particles in the pressure sensitive adhesive layer.
TABLE 1 Performance of pressure-sensitive adhesive layers of examples and comparative examples
Figure BDA0003149387030000041
As can be seen from Table 1, the addition of the tetrapod-like nano zinc oxide into the pressure-sensitive adhesive layer can reduce the Mooney viscosity of the pressure-sensitive adhesive layer and improve the tensile strength and the peel strength of the pressure-sensitive adhesive layer.
TABLE 2 spiral suction hose performance (DN 150)
Figure BDA0003149387030000051
As can be seen from Table 2, the spiral water suction pipe with the pipe diameter of 150mm is produced, compared with the spiral water suction pipe produced in the comparative example 1, the pipe diameter of the spiral water suction pipe produced conventionally has no variability and has larger error, and the adaptability to the water suction accessory is correspondingly poor. However, the pipe diameter can be enlarged and has a wider variable range (the pipe diameter is enlarged by at least 0.6%) by adding the pressure sensitive adhesive layer, and the advantage of the enlarged pipe diameter is better adaptability with the accessory water absorption appliance. In comparative example 2, the strength of the tetrapod-like nano zinc oxide was not decreased, and the corresponding burst pressure was decreased. This is because the tetrapod-like nano zinc oxide has a larger aspect ratio in 4 directions, so that the strength of the obtained pressure sensitive adhesive layer can be higher than that of the conventional nano particles.
In the invention, adhesives such as rosin ester, terpene resin and C5 petroleum resin which are compatible with SIS and SBS rubber phases PI and PB are adopted to endow the pressure sensitive adhesive layer with initial viscosity; the cohesion of the pressure sensitive adhesive layer is improved by adopting coumarone resin and C9 aromatic petroleum resin which are compatible with SIS and SBS plastic phase PS; the terpene phenolic resin is compatible with both the rubber phase and the plastic phase. The adhesive performance of the pressure sensitive adhesive layer can be adjusted through compounding of the adhesives. The selected anti-aging agent has the advantages of light color and difficult oxidation, and the aniline anti-aging agent is easy to oxidize and turns black and is difficult to adopt.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered as the technical solutions and the inventive concepts of the present invention within the technical scope of the present invention.

Claims (7)

1. The water absorption device with the variable pipe diameter is characterized by comprising an inner rubber layer, a pressure-sensitive rubber layer, an outer rubber layer and a spiral reinforcing rib layer in sequence from inside to outside; the pressure sensitive adhesive layer can increase the pipe diameter of the water absorbing device by at least 0.6%;
the material of the sensitive pressure-sensitive adhesive layer is a thermoplastic elastomer base material, and the basic performance of the material needs to reach more than 12MPa of tensile strength, more than 600% of elongation, mooney viscosity ML 1+4, 100-25 and peel strength of more than 70N/25 mm; the thickness is 2.5 to 3.5mm;
the material formula of the pressure sensitive adhesive layer comprises the following raw materials in parts by weight: 100 parts of styrene block copolymer, 20 to 80 parts of nano-particles, 5 to 8 parts of plasticizer, 10 to 30 parts of adhesive and 1 to 3 parts of antioxidant; wherein the nano particles are a mixture of one of nano argil and nano superfine kaolin and tetrapod-like nano zinc oxide.
2. The water absorption device with the variable pipe diameter according to claim 1, wherein the inner rubber layer is made of a soft PVC-based material or a thermoplastic polyurethane material, the thickness of the water absorption device is 1.5-2.5 mm, and the Shore hardness A of the water absorption device is 25-30.
3. The water absorbing device with the variable pipe diameter according to claim 1, wherein the outer rubber layer and the spiral reinforcing rib layer are made of hard PVC-based materials; the thickness of the outer rubber layer is 4-6 mm, and the Shore hardness A is 35-40; the Shore A hardness of the spiral reinforcing rib layer is 85-90.
4. A variable diameter water absorbing device as claimed in claim 1, wherein the styrenic block copolymer is SBS and/or SIS.
5. A variable diameter water absorbing device as claimed in claim 1, wherein the plasticizer is dioctyl phthalate or dioctyl terephthalate.
6. The variable diameter suction device of claim 1, wherein said adhesive is at least one of rosin esters, terpene phenolic resins, terpene resins, C5 petroleum resins, C9 aromatic petroleum resins, coumarone resins.
7. The variable pipe diameter water absorbing apparatus of claim 1, wherein the antioxidant is at least one of BZ, PX, antiozard L122.
CN202110760266.6A 2021-07-06 2021-07-06 Water absorption device with variable pipe diameter Active CN113669513B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007190769A (en) * 2006-01-18 2007-08-02 Bridgestone Corp Hose for supplying water and hot water
CN106519336A (en) * 2016-10-20 2017-03-22 马鞍山杰创塑胶科技有限公司 High strength epoxy resin cis-polybutadiene composite material for hydraulic hammer high pressure oil pipes and preparation method thereof
CN107474403A (en) * 2017-09-05 2017-12-15 武城水星天元橡塑材料科技研发有限公司 Glue material and preparation method and application inside and outside a kind of compound rubber pipe
CN110103519A (en) * 2019-04-01 2019-08-09 中裕软管科技股份有限公司 A kind of novel electrostatic prevention spiral suction hose
CN111333963A (en) * 2020-03-17 2020-06-26 一汽解放汽车有限公司 High-pressure-resistance rubber pipe and preparation method and application thereof
CN111928020A (en) * 2020-09-14 2020-11-13 湖南南山矿泉水有限公司 A antibiotic water pipe for pure water filling

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007190769A (en) * 2006-01-18 2007-08-02 Bridgestone Corp Hose for supplying water and hot water
CN106519336A (en) * 2016-10-20 2017-03-22 马鞍山杰创塑胶科技有限公司 High strength epoxy resin cis-polybutadiene composite material for hydraulic hammer high pressure oil pipes and preparation method thereof
CN107474403A (en) * 2017-09-05 2017-12-15 武城水星天元橡塑材料科技研发有限公司 Glue material and preparation method and application inside and outside a kind of compound rubber pipe
CN110103519A (en) * 2019-04-01 2019-08-09 中裕软管科技股份有限公司 A kind of novel electrostatic prevention spiral suction hose
CN111333963A (en) * 2020-03-17 2020-06-26 一汽解放汽车有限公司 High-pressure-resistance rubber pipe and preparation method and application thereof
CN111928020A (en) * 2020-09-14 2020-11-13 湖南南山矿泉水有限公司 A antibiotic water pipe for pure water filling

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