CN113628816B - Inhibition method of GIL/GIS metal particles based on functional gradient modification of insulator surface - Google Patents

Inhibition method of GIL/GIS metal particles based on functional gradient modification of insulator surface Download PDF

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CN113628816B
CN113628816B CN202110948884.3A CN202110948884A CN113628816B CN 113628816 B CN113628816 B CN 113628816B CN 202110948884 A CN202110948884 A CN 202110948884A CN 113628816 B CN113628816 B CN 113628816B
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epoxy resin
gil
gis
surface layer
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CN113628816A (en
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李进
王禹淮
杜伯学
梁虎成
董佳楠
姚航
王雨帆
赵仁勇
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Tianjin University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B19/00Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
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Abstract

The invention discloses a GIL/GIS metal particle lifting inhibition method based on insulator surface layer function gradient modification. Based on the epoxy resin insulator surface layer functional gradient optimization design, the epoxy resin insulator is subjected to surface layer functional gradient modification by utilizing a fluorination treatment technology, so that the epoxy resin insulator with the surface layer functional gradient modification is obtained. The high-voltage direct current GIL/GIS system provided with the surface layer functional gradient modified epoxy resin insulator can reduce the axial gradient force required by the movement of metal particles to the weak insulation position, and has an obvious inhibiting effect on the lifting of the metal particles with different shapes at different positions away from the epoxy resin insulator. The surface layer function gradient modification treatment is carried out on the epoxy resin insulator, so that the inhibition of the movement of metal particles in a GIL/GIS system is realized. Has important value and significance for treating metal particle pollution in high-voltage direct current GIL/GIS.

Description

基于绝缘子表层功能梯度改性的GIL/GIS金属微粒启举抑制 方法Inhibition of Initiation of GIL/GIS Metal Particles Based on Functional Gradient Modification of Insulator Surface method

技术领域technical field

本发明涉及电气工程高压输电领域,具体涉及一种基于绝缘子表层功能梯度改性的GIL/GIS金属微粒启举抑制方法。The invention relates to the field of high-voltage power transmission in electrical engineering, in particular to a GIL/GIS metal particle heave suppression method based on the functional gradient modification of the surface layer of an insulator.

背景技术Background technique

高压直流GIL/GIS长期运行时,普通盆式绝缘子或支柱绝缘子表面电荷积聚极不均匀,对附近的金属微粒产生向绝缘子表面运动的电场轴向梯度力,故绝缘子附近的金属微粒易向绝缘子表面运动,最终引发气隙击穿、局部放电、沿面闪络等绝缘故障,严重劣化高压直流GIL/GIS的绝缘性能。During the long-term operation of high-voltage direct current GIL/GIS, the surface charge accumulation of ordinary pot insulators or post insulators is extremely uneven, and an axial gradient force of the electric field is generated on the nearby metal particles to move towards the surface of the insulator, so the metal particles near the insulator tend to move toward the surface of the insulator. Movement will eventually cause insulation faults such as air gap breakdown, partial discharge, and flashover along the surface, seriously deteriorating the insulation performance of high-voltage DC GIL/GIS.

发明内容Contents of the invention

本发明的目的在于克服现有技术的不足,提供一种基于环氧树脂绝缘子表层功能梯度改性的GIL/GIS金属微粒启举抑制方法,在高压直流GIL/GIS中金属微粒运动治理方面提供一种新的治理思路。The purpose of the present invention is to overcome the deficiencies of the prior art, to provide a GIL/GIS metal particle activation suppression method based on the functional gradient modification of the surface layer of epoxy resin insulators, and to provide a method for the movement of metal particles in high-voltage direct current GIL/GIS. A new way of governance.

为了实现上述目的,本发明所用的技术方案如下:一种基于绝缘子表层功能梯度改性的GIL/GIS金属微粒启举抑制方法,包括下列步骤:In order to achieve the above object, the technical scheme used in the present invention is as follows: a kind of GIL/GIS metal particle initiation suppression method based on insulator surface layer functional gradient modification, comprises the following steps:

(1)基于高压直流(包括±160kV、±200kV、±320kV、±550kV、±800kV)GIL/GIS运行工况下环氧树脂绝缘子(包括盆式绝缘子/支柱绝缘子)表面电势分布,将环氧树脂绝缘子表面划分为三个区域。环氧树脂绝缘子安装前,将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘住。将绝缘子放置在反应釜内,反应釜内充入体积比为1:10~1:1的氟气与惰性气体的混合气体,反应气体温度10~50℃、气体压力0.01~0.1Mpa,对环氧树脂绝缘子进行15-30min的表层结构改性处理,改性处理后区域一的表面电导率为5.02×10-14S-5.05×10- 14S。(1) Based on the surface potential distribution of epoxy resin insulators (including pot insulators/pillar insulators) under high voltage DC (including ±160kV, ±200kV, ±320kV, ±550kV, ±800kV) GIL/GIS operating conditions, the epoxy The surface of the resin insulator is divided into three regions. Before installing the epoxy resin insulator, stick area 2 and area 3 with polytetrafluoroethylene anti-corrosion tape. Place the insulator in the reactor, and fill the reactor with a mixed gas of fluorine gas and inert gas with a volume ratio of 1:10 to 1:1, the reaction gas temperature is 10-50°C, the gas pressure is 0.01-0.1Mpa, The oxygen resin insulator undergoes surface structure modification treatment for 15-30 minutes, and the surface conductivity of area 1 after modification treatment is 5.02×10 -14 S-5.05×10 - 14 S.

(2)去除区域三的聚四氟乙烯抗腐蚀胶带,将绝缘子放入反应釜内进行15-30min的表层结构氟化处理,获得表层功能梯度改性的环氧树脂绝缘子。表层功能梯度改性的环氧树脂绝缘子表面电导率呈梯度分布,其中,区域一表面电导率:6.50×10-13S-6.55×10- 13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S。(2) Remove the polytetrafluoroethylene anti-corrosion tape in area 3, put the insulator into the reaction kettle for 15-30min surface structure fluorination treatment, and obtain the epoxy resin insulator with surface functional gradient modification. The surface conductivity of the epoxy resin insulator modified by the surface functional gradient is distributed in a gradient, among which, the surface conductivity of area 1: 6.50×10 -13 S-6.55×10 - 13 S, the surface conductivity of area 2: 5.80×10 -15 S-5.85×10 -15 S, area three surface conductivity: 5.02×10 -14 S-5.05×10 -14 S.

(3)对装有表层功能梯度改性环氧树脂绝缘子的高压直流GIL/GIS系统进行1~10小时额定直流电压预压,预压结束后测试距离环氧树脂绝缘子凸面不同位置处的金属微粒(包括球形金属微粒、线性金属微粒、金属粉尘)启举电压。(3) Preload the high-voltage DC GIL/GIS system equipped with surface functional gradient modified epoxy resin insulators for 1 to 10 hours with rated DC voltage. After the preloading, test the metal particles at different positions from the convex surface of the epoxy resin insulator (Including spherical metal particles, linear metal particles, metal dust) boost voltage.

进一步地,高压直流GIL/GIS涉及的电压等级包括±160kV、±200kV、±320kV、±550kV、±800kV。Further, the voltage levels involved in the high-voltage direct current GIL/GIS include ±160kV, ±200kV, ±320kV, ±550kV, and ±800kV.

进一步地,环氧树脂绝缘子包括盆式绝缘子、支柱绝缘子。Further, epoxy resin insulators include pot insulators and post insulators.

进一步地,金属微粒包括球形金属微粒、线性金属微粒、金属粉末。Further, metal particles include spherical metal particles, linear metal particles, and metal powder.

与现有技术相比,本发明的技术方案所带来的有益效果是:Compared with the prior art, the beneficial effects brought by the technical solution of the present invention are:

本发明通过对环氧树脂绝缘子表层功能梯度改性,优化运行工况下绝缘子的电场分布,削弱金属微粒产生向绝缘子表面运动的电场轴向梯度力,进而实现对高压直流GIL/GIS中金属微粒运动的抑制。表层功能梯度改性的绝缘子制作工艺流程简单可靠,且不需要改变高压直流GIL/GIS原有的机械结构,便于促进高压直流GIL/GIS的推广运用。The invention optimizes the electric field distribution of the insulator under operating conditions by modifying the functional gradient of the surface layer of the epoxy resin insulator, weakens the axial gradient force of the electric field generated by the metal particles moving to the surface of the insulator, and then realizes the control of the metal particles in the high-voltage DC GIL/GIS Inhibition of movement. The production process of insulators with surface functional gradient modification is simple and reliable, and does not need to change the original mechanical structure of high-voltage direct current GIL/GIS, which facilitates the promotion and application of high-voltage direct current GIL/GIS.

本发明对环氧树脂绝缘子进行表层功能梯度改性处理,根据制作方案,表层功能梯度改性的盆式绝缘子表面电导率呈梯度分布,优化长期运行条件下盆式绝缘子表面电荷分布,减小金属微粒向绝缘薄弱处运动所需的电场轴向梯度力,对距离绝缘子不同位置处的金属微粒启举具有明显的抑制效果。因此,设计和制造具有抑制高压直流GIL/GIS中金属微粒运动功能的表层功能梯度改性盆式绝缘子对于治理高压直流GIL/GIS中金属微粒污染具有现实意义。In the present invention, the epoxy resin insulator is subjected to surface functional gradient modification treatment. According to the production plan, the surface conductivity of the basin-type insulator modified by the surface-layer function gradient presents a gradient distribution, which optimizes the surface charge distribution of the basin-type insulator under long-term operation conditions and reduces the metal The axial gradient force of the electric field required for the particles to move to the weak point of the insulation has an obvious inhibitory effect on the lifting of the metal particles at different positions from the insulator. Therefore, it is of practical significance to design and manufacture surface functionally gradient modified pot insulators that can inhibit the movement of metal particles in HVDC GIL/GIS for the control of metal particle pollution in HVDC GIL/GIS.

附图说明Description of drawings

为了清楚地说明本发明技术方案的实施过程,下面对实施过程描述中所需要的附图进行简单的介绍。下列附图仅是示意性的,并不是限制性的。In order to clearly illustrate the implementation process of the technical solution of the present invention, the accompanying drawings required in the description of the implementation process are briefly introduced below. The following drawings are only schematic and not limiting.

图1是±160kV表面功能梯度改性的盆式绝缘子设计示意图;Figure 1 is a schematic diagram of the design of basin insulators with surface functional gradient modification of ±160kV;

图2是对比±160kV直流GIL/GIS内安装普通盆式绝缘子和表层功能梯度改性的盆式绝缘子对其凸面距离绝缘子不同位置金属微粒启举电压结果图。Figure 2 is a comparison of the results of the lift-up voltage of metal particles at different positions of the insulator from the convex surface of the ordinary pot insulator installed in the ±160kV DC GIL/GIS and the pot insulator with a functional gradient modification on the surface.

具体实施方式detailed description

结合下列附图和具体实施案例对本发明做进一步的详细说明。应当理解,此处的具体实施案例仅用于解释本发明,并不用于限定本发明。The present invention will be further described in detail in conjunction with the following drawings and specific implementation examples. It should be understood that the specific implementation cases herein are only used to explain the present invention, not to limit the present invention.

实施例1Example 1

本发明涉及一种基于盆式绝缘子表层结构梯度改性的GIL/GIS金属微粒启举抑制方法,利用表层结构梯度改性技术对盆式绝缘子表面进行梯度结构改性,相对于普通盆式绝缘子,高电导表面结构梯度改性的盆式绝缘子在长期运行条件下表面电荷分布更加均匀,从根源上减小了金属微粒向盆式绝缘子运动所需的电场轴向梯度力,实现对高压直流GIL/GIS金属微粒运动的抑制。The invention relates to a GIL/GIS metal particle initiation suppression method based on gradient modification of the surface structure of basin-type insulators. The surface structure gradient modification technology is used to modify the gradient structure of the surface of basin-type insulators. Compared with ordinary basin-type insulators, The basin-type insulator with gradient modified surface structure of high conductivity has a more uniform surface charge distribution under long-term operating conditions, which fundamentally reduces the axial gradient force of the electric field required for the movement of metal particles to the basin-type insulator, and realizes the high-voltage DC GIL/ Inhibition of motion of metal particles in GIS.

具体盆式绝缘子表面功能梯度氟化处理流程如下:The specific functional gradient fluorination treatment process on the surface of pot insulators is as follows:

(1)基于环氧树脂盆式绝缘子实际运行下的电场分布,将盆式绝缘子表层划分为三个区域,其中区域一、区域三进行不同时间的表层结构改性处理、区域二不进行表层结构改性处理。(1) Based on the electric field distribution of the epoxy resin pot insulator under actual operation, the surface of the pot insulator is divided into three regions, of which the surface structure modification treatment is carried out at different times in region 1 and region 3, and the surface structure is not carried out in region 2 modified treatment.

(2)将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘贴,然后将环氧树脂盆式绝缘子放置在真空氟化反应釜内,反应釜内充入体积比为1:6的氟气与氮气混合气体,反应条件为:气体温度10℃、气体压力0.04Mpa,对环氧树脂盆式绝缘子的区域一进行15min的表层结构改性处理,改性处理后区域一表面结构改性后表面电导率为5.02×10-14S-5.05×10-14S。(2) Paste areas 2 and 3 with polytetrafluoroethylene anti-corrosion tape, then place the epoxy resin pot insulator in the vacuum fluorination reactor, and fill the reactor with fluorine gas with a volume ratio of 1:6 Mix gas with nitrogen, the reaction conditions are: gas temperature 10°C, gas pressure 0.04Mpa, carry out surface structure modification treatment on the area 1 of the epoxy resin pot insulator for 15 minutes, after the modification treatment, the surface structure of the area 1 is modified. The electrical conductivity is 5.02×10 -14 S-5.05×10 -14 S.

(3)去除区域三的聚四氟乙烯抗腐蚀胶带,将环氧树脂盆式绝缘子放入真空氟化反应釜内进行15min的表层结构处理,表层结构改性处理后获得区域一表面电导率:6.50×10-13S-6.55×10-13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S的具有抑制高压直流GIL/GIS金属微粒启举功能的表层结构梯度改性的盆式绝缘子。(3) Remove the PTFE anti-corrosion tape in area 3, put the epoxy resin pot insulator into the vacuum fluorination reactor for 15 minutes of surface structure treatment, and obtain the surface conductivity of area 1 after the surface structure modification treatment: 6.50×10 -13 S-6.55×10 -13 S, area 2 surface conductivity: 5.80×10 -15 S-5.85×10 -15 S, area 3 surface conductivity: 5.02×10 -14 S-5.05×10 -14 S pot insulator with surface structure gradient modification with the function of inhibiting the initiation of high-voltage direct current GIL/GIS metal particles.

(4)利用缩比直流GIL/GIS系统分析高电导表层梯度改性盆式绝缘子在不同运行工况下对其凹凸面、距离绝缘子不同位置的金属微粒启举抑制效果。(4) Using the scaled direct current GIL/GIS system to analyze the inhibitory effect of the gradient modified pot insulator on the high conductivity surface under different operating conditions on the concave-convex surface and the metal particles at different positions from the insulator.

(5)根据实验结果,对比普通GIL/GIS盆式绝缘子,表层结构梯度改性的GIL/GIS盆式绝缘子对不同位置处的金属微粒运动具有显著的抑制效果,见图2。(5) According to the experimental results, compared with ordinary GIL/GIS basin insulators, GIL/GIS basin insulators with surface structure gradient modification have a significant inhibitory effect on the movement of metal particles at different positions, as shown in Figure 2.

实施例2Example 2

本发明涉及一种基于支柱绝缘子表层结构梯度改性的GIL/GIS金属微粒启举抑制方法,利用表层结构梯度改性技术对支柱绝缘子表面进行梯度结构改性,相对于普通支柱绝缘子,高电导表面结构梯度改性的支柱绝缘子在长期运行条件下表面电荷分布更加均匀,从根源上减小了金属微粒向支柱绝缘子运动所需的电场轴向梯度力,实现对高压直流GIL/GIS金属微粒运动的抑制。The invention relates to a GIL/GIS metal particle initiation suppression method based on the gradient modification of the surface structure of post insulators. The surface structure gradient modification technology is used to modify the gradient structure of the post insulator surface. Compared with ordinary post insulators, the surface with high conductivity The post insulator with structural gradient modification has a more uniform surface charge distribution under long-term operating conditions, which fundamentally reduces the axial gradient force of the electric field required for the movement of metal particles to the post insulator, and realizes the control of the movement of high-voltage DC GIL/GIS metal particles. inhibition.

具体支柱绝缘子表面功能梯度氟化处理流程如下:The specific functional gradient fluorination treatment process on the surface of post insulators is as follows:

1)基于环氧树脂支柱绝缘子实际运行下的电场分布,将支柱绝缘子表层划分为三个区域,其中区域一、区域三进行不同时间的表层结构改性处理、区域二不进行表层结构改性处理。1) Based on the electric field distribution of the epoxy resin post insulator under actual operation, the surface layer of the post insulator is divided into three areas, of which area 1 and area 3 are subjected to surface structure modification treatment at different times, and area 2 is not subjected to surface structure modification treatment .

2)将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘贴,然后将环氧树脂支柱绝缘子放置在真空氟化反应釜内,反应釜内充入体积比为1:10的氟气与氦气混合气体,反应条件为:气体温度30℃、气体压力0.1Mpa,对环氧树脂支柱绝缘子的区域一进行25min的表层结构改性处理,改性处理后区域一表面结构改性后表面电导率为5.02×10-14S-5.05×10-14S。2) Paste areas 2 and 3 with polytetrafluoroethylene anti-corrosion tape, then place epoxy resin post insulators in a vacuum fluorination reactor, and fill the reactor with fluorine gas and helium at a volume ratio of 1:10 Gas mixed gas, the reaction conditions are: gas temperature 30°C, gas pressure 0.1Mpa, the surface structure modification treatment of the area 1 of the epoxy resin post insulator for 25 minutes, the surface conductivity of the area 1 after modification treatment 5.02×10 -14 S-5.05×10 -14 S.

3)去除区域三的聚四氟乙烯抗腐蚀胶带,将环氧树脂支柱绝缘子放入真空氟化反应釜内进行30min的表层结构处理,表层结构改性处理后获得区域一表面电导率:6.50×10-13S-6.55×10-13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S的具有抑制高压直流GIL/GIS金属微粒启举功能的表层结构梯度改性的支柱绝缘子。3) Remove the PTFE anti-corrosion tape in area 3, put the epoxy resin post insulator into the vacuum fluorination reactor for 30min surface structure treatment, and obtain area 1 surface conductivity after the surface structure modification treatment: 6.50× 10 -13 S-6.55×10 -13 S, area 2 surface conductivity: 5.80×10 -15 S-5.85×10 -15 S, area 3 surface conductivity: 5.02×10 -14 S-5.05×10 -14 S post insulators with surface structure gradient modification with the function of suppressing the initiation of high-voltage DC GIL/GIS metal particles.

4)利用缩比直流GIL/GIS系统分析高电导表层梯度改性支柱绝缘子在不同运行工况下对其凹凸面、距离绝缘子不同位置的金属微粒启举抑制效果。4) Using the scaled DC GIL/GIS system, the effect of suppressing the lifting of metal particles on the uneven surface and different positions of the distance from the insulator of the high-conductivity surface gradient modified post insulator is analyzed under different operating conditions.

实施例3Example 3

1)基于高压直流GIL/GIS运行工况下环氧树脂绝缘子表面电势分布,将环氧树脂绝缘子表面划分为三个区域;1) Based on the surface potential distribution of the epoxy resin insulator under the high-voltage DC GIL/GIS operating condition, the surface of the epoxy resin insulator is divided into three regions;

2)环氧树脂绝缘子安装前,将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘住;2) Before installing the epoxy resin insulator, stick area 2 and area 3 with PTFE anti-corrosion tape;

3)将绝缘子放置在反应釜内,反应釜内充入体积比为1:1的氟气与氦气混合气体,反应气体温度10℃、气体压力0.01Mpa,对环氧树脂绝缘子进行15min的表层结构改性处理,改性处理后区域一的表面电导率为5.02×10-14S-5.05×10-14S;3) Place the insulator in the reaction kettle, fill the reaction kettle with a mixed gas of fluorine gas and helium gas with a volume ratio of 1:1, the reaction gas temperature is 10°C, the gas pressure is 0.01Mpa, and the surface layer of the epoxy resin insulator is treated for 15 minutes. Structural modification treatment, the surface conductivity of area 1 after modification treatment is 5.02×10 -14 S-5.05×10 -14 S;

4)去除区域三的聚四氟乙烯抗腐蚀胶带,将绝缘子放入反应釜内进行15~30min的表层结构氟化处理,获得表层功能梯度改性的环氧树脂绝缘子;4) Remove the polytetrafluoroethylene anti-corrosion tape in area 3, put the insulator into the reactor for 15-30 minutes of surface structure fluorination treatment, and obtain the epoxy resin insulator with surface functional gradient modification;

表层功能梯度改性的环氧树脂绝缘子表面电导率呈梯度分布,其中,区域一表面电导率:6.50×10-13S-6.55×10-13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S。The surface conductivity of epoxy resin insulators modified by surface functional gradient is distributed in gradient, among which, the surface conductivity of area 1: 6.50×10 -13 S-6.55×10 -13 S, the surface conductivity of area 2: 5.80×10 -15 S-5.85×10 -15 S, area three surface conductivity: 5.02×10 -14 S-5.05×10 -14 S.

实施例4Example 4

1)基于高压直流GIL/GIS运行工况下环氧树脂绝缘子表面电势分布,将环氧树脂绝缘子表面划分为三个区域;1) Based on the surface potential distribution of the epoxy resin insulator under the high-voltage DC GIL/GIS operating condition, the surface of the epoxy resin insulator is divided into three regions;

2)环氧树脂绝缘子安装前,将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘住;2) Before installing the epoxy resin insulator, stick area 2 and area 3 with PTFE anti-corrosion tape;

3)将绝缘子放置在反应釜内,反应釜内充入体积比为1:6的氟气与氩气混合气体,反应气体温度50℃、气体压力0.1Mpa,对环氧树脂绝缘子进行30min的表层结构改性处理,改性处理后区域一的表面电导率为5.02×10-14S-5.05×10-14S;3) Place the insulator in the reactor, fill the reactor with a mixed gas of fluorine and argon with a volume ratio of 1:6, the temperature of the reaction gas is 50°C, the pressure of the gas is 0.1Mpa, and the surface layer of the epoxy resin insulator is covered for 30 minutes. Structural modification treatment, the surface conductivity of area 1 after modification treatment is 5.02×10 -14 S-5.05×10 -14 S;

4)去除区域三的聚四氟乙烯抗腐蚀胶带,将绝缘子放入反应釜内进行15~30min的表层结构氟化处理,获得表层功能梯度改性的环氧树脂绝缘子;4) Remove the polytetrafluoroethylene anti-corrosion tape in area 3, put the insulator into the reactor for 15-30 minutes of surface structure fluorination treatment, and obtain the epoxy resin insulator with surface functional gradient modification;

表层功能梯度改性的环氧树脂绝缘子表面电导率呈梯度分布,其中,区域一表面电导率:6.50×10-13S-6.55×10-13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S;The surface conductivity of epoxy resin insulators modified by surface functional gradient is distributed in gradient, among which, the surface conductivity of area 1: 6.50×10 -13 S-6.55×10 -13 S, the surface conductivity of area 2: 5.80×10 -15 S-5.85×10 -15 S, area three surface conductivity: 5.02×10 -14 S-5.05×10 -14 S;

4)对装有表层功能梯度改性环氧树脂绝缘子的高压直流GIL/GIS系统进行10小时额定直流电压预压,预压结束后测试距离环氧树脂绝缘子凸面不同位置处的金属微粒启举电压。4) Perform a 10-hour rated DC voltage preload on the high-voltage DC GIL/GIS system equipped with surface functional gradient modified epoxy resin insulators. After the preload is completed, test the metal particle startup voltage at different positions from the convex surface of the epoxy resin insulator .

实施例5Example 5

1)基于高压直流GIL/GIS运行工况下环氧树脂绝缘子表面电势分布,将环氧树脂绝缘子表面划分为三个区域;1) Based on the surface potential distribution of the epoxy resin insulator under the high-voltage DC GIL/GIS operating condition, the surface of the epoxy resin insulator is divided into three regions;

2)环氧树脂绝缘子安装前,将区域二、区域三用聚四氟乙烯抗腐蚀胶带粘住;2) Before installing the epoxy resin insulator, stick area 2 and area 3 with PTFE anti-corrosion tape;

3)将绝缘子放置在反应釜内,反应釜内充入体积比为1:8的氟气与氦气的混合气体,反应气体温度30℃、气体压力0.05Mpa,对环氧树脂绝缘子进行20min的表层结构改性处理,改性处理后区域一的表面电导率为5.02×10-14S-5.05×10-14S;3) Place the insulator in the reaction kettle, fill the reaction kettle with a mixed gas of fluorine gas and helium gas with a volume ratio of 1:8, the reaction gas temperature is 30°C, the gas pressure is 0.05Mpa, and the epoxy resin insulator is insulated for 20 minutes. Surface structure modification treatment, the surface conductivity of area 1 after modification treatment is 5.02×10 -14 S-5.05×10 -14 S;

4)去除区域三的聚四氟乙烯抗腐蚀胶带,将绝缘子放入反应釜内进行15~30min的表层结构氟化处理,获得表层功能梯度改性的环氧树脂绝缘子;4) Remove the polytetrafluoroethylene anti-corrosion tape in area 3, put the insulator into the reactor for 15-30 minutes of surface structure fluorination treatment, and obtain the epoxy resin insulator with surface functional gradient modification;

表层功能梯度改性的环氧树脂绝缘子表面电导率呈梯度分布,其中,区域一表面电导率:6.50×10-13S-6.55×10-13S、区域二表面电导率:5.80×10-15S-5.85×10-15S、区域三表面电导率:5.02×10-14S-5.05×10-14S;The surface conductivity of epoxy resin insulators modified by surface functional gradient is distributed in gradient, among which, the surface conductivity of area 1: 6.50×10 -13 S-6.55×10 -13 S, the surface conductivity of area 2: 5.80×10 -15 S-5.85×10 -15 S, area three surface conductivity: 5.02×10 -14 S-5.05×10 -14 S;

4)对装有表层功能梯度改性环氧树脂绝缘子的高压直流GIL/GIS系统进行1~10小时额定直流电压预压,预压结束后测试距离环氧树脂绝缘子凸面不同位置处的金属微粒启举电压。4) Preload the high-voltage DC GIL/GIS system equipped with surface functionally gradient modified epoxy resin insulators for 1 to 10 hours at rated DC voltage, and test the metal particles at different positions from the convex surface of the epoxy resin insulator after preloading. lift voltage.

本发明并不限于上文描述的实施方式。以上对具体实施方式的描述旨在描述和说明本发明的技术方案,上述的具体实施方式仅仅是示意性的,并不是限制性的。在不脱离本发明宗旨和权利要求所保护的范围情况下,本领域的普通技术人员在本发明的启示下还可做出很多形式的具体变换,这些均属于本发明的保护范围之内。The present invention is not limited to the embodiments described above. The above description of the specific embodiments is intended to describe and illustrate the technical solution of the present invention, and the above specific embodiments are only illustrative and not restrictive. Without departing from the gist of the present invention and the scope of protection of the claims, those skilled in the art can also make many specific changes under the inspiration of the present invention, and these all belong to the protection scope of the present invention.

Claims (4)

1. A GIL/GIS metal particle lift inhibition method based on insulator surface layer function gradient modification is characterized by comprising the following steps
1) Dividing the surface of the epoxy resin insulator into three areas based on the surface potential distribution of the epoxy resin insulator under the high-voltage direct current GIL/GIS operation condition;
2) Before the epoxy resin insulator is installed, adhering the polytetrafluoroethylene corrosion-resistant adhesive tapes for the second region and the third region;
3) Placing the insulator in a reaction kettle, and filling the insulator into the reaction kettle in a volume ratio of 1: 10-1: 1, the temperature of reaction gas is 10-50 ℃, the gas pressure is 0.01-0.1 Mpa, the surface layer structure modification treatment is carried out on the epoxy resin insulator for 15-30min, and the surface conductivity of the first area after the modification treatment is 5.02 multiplied by 10 -14 S-5.05×10 - 14 S;
4) Removing the polytetrafluoroethylene corrosion-resistant adhesive tape in the third area, and putting the insulator into a reaction kettle for fluorination treatment of a surface layer structure for 15-30min to obtain an epoxy resin insulator with a surface layer modified in a functional gradient manner;
the surface conductivity of the epoxy resin insulator with the surface layer modified in a functional gradient manner is distributed in a gradient manner, wherein the surface conductivity of the first region is as follows: 6.50X 10 -13 S-6.55×10 -13 S, surface conductivity of the second region: 5.80X 10 -15 S-5.85×10 -15 S, conductivity of surface of region: 5.02X 10 -14 S-5.05×10 -14 S;
4) And (3) carrying out rated direct current voltage prepressing for 1-10 hours on the high-voltage direct current GIL/GIS system provided with the surface layer functional gradient modified epoxy resin insulator, and testing the metal particle lifting voltage at different positions away from the convex surface of the epoxy resin insulator after the prepressing is finished.
2. The method for inhibiting the initiation of the GIL/GIS metal particles based on the functional gradient modification of the surface layer of the insulator, as claimed in claim 1, is characterized in that the inert gas is selected from nitrogen, argon or helium.
3. The method for inhibiting lifting of GIL/GIS metal particles based on insulator surface layer function gradient modification of claim 1, wherein the test metal particles comprise spherical metal particles, linear metal particles and metal dust.
4. The method for inhibiting initiation of metal particles in GIL/GIS based on insulator surface layer function gradient modification according to claim 1, wherein the voltage classes involved in high voltage direct current GIL/GIS include +/-160 kV, + 200kV, + 320kV, + 550kV, + 800kV.
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