CN113621866A - Manufacturing method of supporting roll for rolling battery pole piece - Google Patents

Manufacturing method of supporting roll for rolling battery pole piece Download PDF

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Publication number
CN113621866A
CN113621866A CN202110730773.5A CN202110730773A CN113621866A CN 113621866 A CN113621866 A CN 113621866A CN 202110730773 A CN202110730773 A CN 202110730773A CN 113621866 A CN113621866 A CN 113621866A
Authority
CN
China
Prior art keywords
steel
tempering
roller
pole piece
battery pole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110730773.5A
Other languages
Chinese (zh)
Inventor
韩维国
辛胜朋
党坤会
梁建立
史会强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinosteel Xingtai Machinery and Mill Roll Co Ltd
Original Assignee
Sinosteel Xingtai Machinery and Mill Roll Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinosteel Xingtai Machinery and Mill Roll Co Ltd filed Critical Sinosteel Xingtai Machinery and Mill Roll Co Ltd
Priority to CN202110730773.5A priority Critical patent/CN113621866A/en
Publication of CN113621866A publication Critical patent/CN113621866A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/002Hybrid process, e.g. forging following casting
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/25Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/30Stress-relieving
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/38Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for roll bodies
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten

Abstract

The invention relates to the technical field of roller manufacturing, in particular to a method for manufacturing a supporting roller for rolling a battery pole piece; adding chemical components and weight percentage in the refined steel, refining by adopting an LF/VD refining furnace, removing impurities, removing gas in molten steel, and pouring into steel ingots; forging a steel ingot, performing stress relief annealing treatment, and performing rough machining to obtain a roller blank; carrying out thermal refining on the rough-machined roller blank, tempering the roller blank after thermal refining, and carrying out finish machining according to the required size after tempering is finished to manufacture a battery pole piece supporting roller; the invention improves the solidification quality of steel ingots, the flaw detection qualification rate of the roller and the accident resistance of the roller.

Description

Manufacturing method of supporting roll for rolling battery pole piece
Technical Field
The invention relates to the technical field of roller manufacturing, in particular to a method for manufacturing a supporting roller for rolling a battery pole piece.
Background
Along with the development of the battery industry, the battery pole piece is used as an important component of the battery, the demand is continuously increased, the accident resistance of a user to a roller is more and more important, the C content in the material is in a higher range because the battery pole piece supporting roller is required to have higher hardness, and the hardness of the supporting roller required by the user is more than 70HSD, so that the problems of poor solidification quality of steel ingots, poor toughness and plasticity of products and the like caused by the high C content are solved.
Disclosure of Invention
Aiming at the problems, the invention aims to improve the solidification quality and the toughness and the plasticity of a steel ingot, and simultaneously meet the use requirements of users, the accident resistance and the like.
In order to achieve the purpose, the invention provides the following technical scheme:
a manufacturing method of a supporting roll for rolling a battery pole piece comprises the following steps:
step 1, steel refining: adding chemical components and weight percentage in the steel to reach the required steel making range, refining by adopting an LF/VD refining furnace, removing impurities by using a reduction method, vacuumizing by VD to remove gas in molten steel, and pouring into steel ingots;
step 2, forging and heat treatment after forging: forging the steel ingot in the step 1, performing stress relief annealing treatment at the stress relief annealing temperature of 600-800 ℃, and performing rough machining to obtain a roller blank;
and 3, final heat treatment: quenching and tempering the roller blank after rough machining in the step 2, wherein the quenching and tempering heat preservation temperature is 850-950 ℃, and the heat preservation time is 20-30 h; tempering the roll blank after the quenching and tempering treatment, wherein the tempering temperature is 350-500 ℃, the heat preservation time is 30-40h, and finish machining is carried out according to the required size after the tempering is finished to manufacture the battery pole piece roll.
The technical scheme of the invention is further improved as follows: the steel comprises the following chemical components in percentage by weight: 0.55-0.70% of C; 0.35 to 0.50 percent of Si; 0.25-0.35% of Mn; 1.7-2.1% of Cr; 0.20-0.50% of Mo; ni is less than or equal to 0.30 percent; s is less than or equal to 0.025 percent; p is less than or equal to 0.025 percent; the balance of Fe and a small amount of impurities.
Compared with the prior art, the manufacturing method of the support roll for rolling the battery pole piece has the following beneficial effects:
1. the invention provides a method for manufacturing a supporting roller for rolling a battery pole piece, which reduces the content of C element in the original material and improves the content of Si in the original material; particularly, the C content is reduced, so that the solidification quality of the steel billet is greatly improved, the Si content is improved, the strength of a steel ingot matrix is ensured, the solidification quality of the steel billet is improved, the defects of segregation, looseness and the like of a product can be improved, the flaw detection quality of a core part of the product is improved, and finally the roller has better quality and higher accident resistance.
2. The invention provides a method for manufacturing a supporting roller for rolling a battery pole piece, which adjusts the components of the original production material, improves the solidification quality of steel ingots, improves the flaw detection qualification rate of a roller and improves the accident resistance of the roller on the premise of meeting the use requirements of users.
Detailed Description
The technical solution of the present invention will be clearly and completely described by the following detailed description. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The rolling method of the supporting roller of the battery pole piece reduces the content of C element in the original material, improves the solidification quality of steel ingots, improves the content of Si in the original material, and ensures the strength of a material matrix; the steel comprises the following chemical components in percentage by weight: 0.55-0.70% of C; 0.35 to 0.50 percent of Si; 0.25-0.35% of Mn; 1.7-2.1% of Cr; 0.20-0.50% of Mo; ni is less than or equal to 0.30 percent; s is less than or equal to 0.025 percent; p is less than or equal to 0.025 percent; the balance of Fe and a small amount of impurities; the solidification quality of steel ingots is improved, the flaw detection qualification rate of the roller is improved, the accident resistance of the roller is improved, and the requirements of users are met; the solidification quality of the steel billet is further improved, the defects of segregation, looseness and the like of the product can be improved, the flaw detection quality of the core of the product is improved, and finally the roller has better quality and higher accident resistance.
Further, the manufacturing method of the supporting roll for rolling the battery pole piece comprises the following steps:
step 1, steel refining: adding chemical components and weight percentage in the steel to reach the required steel making range, refining by adopting an LF/VD refining furnace, removing impurities by using a reduction method, removing gas in molten steel by VD vacuumizing, and pouring into steel ingots;
step 2, forging and heat treatment after forging: forging the steel ingot in the step 1, performing stress relief annealing treatment at the stress relief annealing temperature of 600-800 ℃, and performing rough machining to obtain a roller blank;
and 3, final heat treatment: quenching and tempering the roller blank after rough machining in the step 2, wherein the quenching and tempering heat preservation temperature is 850-950 ℃, and the heat preservation time is 20-30 h; tempering the roll blank after the quenching and tempering treatment, wherein the tempering temperature is 350-500 ℃, the heat preservation time is 30-40h, and finish machining is carried out according to the required size after the tempering is finished to manufacture the battery pole piece supporting roll.
The invention selects the chemical components and the content of steel to be cast into steel billets, and the following table is the chemical components in the steel; (in wt% per unit, the remainder being Fe and a small amount of impurities)
C Si Mn Cr Mo Ni P S
0.61 0.45 0.31 1.82 1.35 0.11 0.022 0.003
Adding the chemical components and the weight percentage of the steel in the table above for refining, refining by adopting an LF/VD refining furnace, removing impurities by using a reduction method, vacuumizing by VD to remove gas in molten steel, and pouring into steel ingots;
the stress-relief annealing temperature of the steel billet is 600-800 ℃, and then rough machining is carried out to obtain a roller billet;
quenching and tempering the rough-machined roller blank, wherein the quenching and heat preservation of the quenching and tempering is 850-950 ℃, and the heat preservation time is 20-30 h; tempering the roll blank after the quenching and tempering treatment, wherein the tempering temperature is 350-500 ℃, the heat preservation time is 30-40h, and finish machining is carried out according to the required size after the tempering is finished to manufacture the battery pole piece supporting roll.
The chemical components and the contents of the steel materials in the table are used for processing the battery pole piece supporting roll, and the Shore hardness tester of the special roll is used for detecting that the surface hardness of the roll body of the battery pole piece supporting roll is 72-74 HSD.
The above-mentioned embodiments are merely illustrative of the preferred embodiments of the present invention, and do not limit the scope of the present invention, and various modifications and improvements of the technical solution of the present invention by those skilled in the art without departing from the spirit of the present invention should fall within the protection scope defined by the appended claims.

Claims (2)

1. A method for manufacturing a supporting roll for rolling a battery pole piece is characterized by comprising the following steps:
step 1, steel refining: adding chemical components and weight percentage in the steel to reach the required steel making range, refining by adopting an LF/VD refining furnace, removing impurities by using a reduction method, removing gas in molten steel by VD vacuumizing, and pouring into steel ingots;
step 2, forging and heat treatment after forging: forging the steel ingot in the step 1, performing stress relief annealing treatment at the stress relief annealing temperature of 600-800 ℃, and performing rough machining to obtain a roller blank;
and 3, final heat treatment: quenching and tempering the roller blank after rough machining in the step 2, wherein the quenching and tempering heat preservation temperature is 850-950 ℃, and the heat preservation time is 20-30 h; tempering the roll blank after the quenching and tempering treatment, wherein the tempering temperature is 350-500 ℃, the heat preservation time is 30-40h, and finish machining is carried out according to the required size after the tempering is finished to manufacture the battery pole piece supporting roll.
2. A method for manufacturing a back-up roll for rolling a battery pole piece according to claim 1, characterized in that: the steel comprises the following chemical components in percentage by weight: 0.55-0.70% of C; 0.35 to 0.50 percent of Si; 0.25-0.35% of Mn; 1.7-2.1% of Cr; 0.20-0.50% of Mo; ni is less than or equal to 0.30 percent; s is less than or equal to 0.025 percent; p is less than or equal to 0.025 percent; the balance of Fe and a small amount of impurities.
CN202110730773.5A 2021-06-30 2021-06-30 Manufacturing method of supporting roll for rolling battery pole piece Pending CN113621866A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110730773.5A CN113621866A (en) 2021-06-30 2021-06-30 Manufacturing method of supporting roll for rolling battery pole piece

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110730773.5A CN113621866A (en) 2021-06-30 2021-06-30 Manufacturing method of supporting roll for rolling battery pole piece

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CN113621866A true CN113621866A (en) 2021-11-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114535943A (en) * 2021-12-28 2022-05-27 中钢集团邢台机械轧辊有限公司 Preparation method of large pole piece roller

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5686697A (en) * 1979-12-14 1981-07-14 Hitachi Ltd Production of working roll for hot rolling
CN101186995A (en) * 2007-10-15 2008-05-28 莱芜钢铁集团有限公司 Medium carbon bearing steel and its preparation method
CN103397267A (en) * 2013-07-12 2013-11-20 中钢集团邢台机械轧辊有限公司 Cold roll for rolling lithium battery guard plate and manufacturing method thereof
CN105239012A (en) * 2015-10-15 2016-01-13 中钢集团邢台机械轧辊有限公司 Semi-high-speed steel cold rolling work roller high in accident resistance and manufacturing method of semi-high-speed steel cold rolling work roller
CN108277443A (en) * 2018-01-29 2018-07-13 二重(德阳)重型装备有限公司 4200mm or more wide and heavy plate mills backing roll and its manufacturing process
US20180347019A1 (en) * 2015-12-04 2018-12-06 Nippon Steel & Sumitomo Metal Corporation Rolled Rod for Cold-Forged Thermally Refined Article
CN112795853A (en) * 2020-12-16 2021-05-14 中钢集团邢台机械轧辊有限公司 Manufacturing method of equal-hardness Cr5 supporting roll
CN112853203A (en) * 2020-12-30 2021-05-28 中钢集团邢台机械轧辊有限公司 Cr2 forged steel supporting roll and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5686697A (en) * 1979-12-14 1981-07-14 Hitachi Ltd Production of working roll for hot rolling
CN101186995A (en) * 2007-10-15 2008-05-28 莱芜钢铁集团有限公司 Medium carbon bearing steel and its preparation method
CN103397267A (en) * 2013-07-12 2013-11-20 中钢集团邢台机械轧辊有限公司 Cold roll for rolling lithium battery guard plate and manufacturing method thereof
CN105239012A (en) * 2015-10-15 2016-01-13 中钢集团邢台机械轧辊有限公司 Semi-high-speed steel cold rolling work roller high in accident resistance and manufacturing method of semi-high-speed steel cold rolling work roller
US20180347019A1 (en) * 2015-12-04 2018-12-06 Nippon Steel & Sumitomo Metal Corporation Rolled Rod for Cold-Forged Thermally Refined Article
CN108277443A (en) * 2018-01-29 2018-07-13 二重(德阳)重型装备有限公司 4200mm or more wide and heavy plate mills backing roll and its manufacturing process
CN112795853A (en) * 2020-12-16 2021-05-14 中钢集团邢台机械轧辊有限公司 Manufacturing method of equal-hardness Cr5 supporting roll
CN112853203A (en) * 2020-12-30 2021-05-28 中钢集团邢台机械轧辊有限公司 Cr2 forged steel supporting roll and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114535943A (en) * 2021-12-28 2022-05-27 中钢集团邢台机械轧辊有限公司 Preparation method of large pole piece roller

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Application publication date: 20211109

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