CN113621334A - Special adhesive for sticker stone - Google Patents
Special adhesive for sticker stone Download PDFInfo
- Publication number
- CN113621334A CN113621334A CN202010382212.6A CN202010382212A CN113621334A CN 113621334 A CN113621334 A CN 113621334A CN 202010382212 A CN202010382212 A CN 202010382212A CN 113621334 A CN113621334 A CN 113621334A
- Authority
- CN
- China
- Prior art keywords
- parts
- stone
- sticker
- special adhesive
- polyester resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004575 stone Substances 0.000 title claims abstract description 51
- 239000000853 adhesive Substances 0.000 title claims abstract description 38
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 38
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 21
- 239000000126 substance Substances 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 26
- 239000005543 nano-size silicon particle Substances 0.000 claims description 18
- 235000012239 silicon dioxide Nutrition 0.000 claims description 18
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 17
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 17
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 claims description 8
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 abstract description 8
- 239000003292 glue Substances 0.000 abstract description 7
- 238000004383 yellowing Methods 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 108010053481 Antifreeze Proteins Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000002969 artificial stone Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The application discloses special glue for sticker stone, which comprises 960-985 parts of unsaturated polyester resin, 1-5 parts of nano inorganic powder, 1-5 parts of accelerator, 5-15 parts of chemical fiber and 10-30 parts of curing agent, wherein the materials are sequentially put into a stirring kettle and stirred for 30-60 minutes to an even state to obtain the special glue for sticker stone. The sticker stone processed by the adhesive can be cut or edged at will, does not warp edges, peel or fall off, and has excellent leveling property, freeze-thaw resistance, weather resistance, yellowing resistance, and high bonding force and strength.
Description
Technical Field
The application relates to the technical field of artificial stone, in particular to a special adhesive for sticker stone.
Background
The processing technology of the 'sticker stone' is that a layer of decorative material color paper with designed patterns is directly pasted on a 'problem product', most of the decorative material color paper is imitated to the color, the texture, the wood color and the texture of natural stone, or after the 'problem product' is processed into a required curved surface modeling style, a layer of color paper with designed patterns is pasted on the decorative material color paper, and then a layer of resin layer is coated on the pasted paper to protect the surface and improve the texture and the glossiness.
The development of green recycling economy and the reduction of resource waste are the Chinese governments and development guidelines and economic concepts advocated by various countries all over the world. The special adhesive for the sticker stone is a brand-new stone surface treatment processing technology, so that the utilization rate of stone resources is improved, problem products are changed into valuable, and sustainable development and green circular economy of the stone industry are realized.
At present, the common stone paper pasting glue used in the industry often has the problems of bulging, poor bonding force, cracking after solidification and the like in the paper pasting process, and the attractiveness of the stone surface is seriously influenced. The nano silicon dioxide has a three-dimensional network structure, has a large specific surface area, shows great activity, can form a network structure when resin is cured, and greatly enhances the strength and adhesive force of a resin layer. Meanwhile, the nano silicon dioxide has extremely strong ultraviolet resistance and infrared reflection resistance, and forms a shielding effect in the resin layer, thereby achieving the purposes of ultraviolet aging resistance and thermal aging resistance.
Disclosure of Invention
The invention aims to provide the special adhesive for the sticker stone, and the special adhesive for the sticker stone with high adhesion, high strength and lower curing temperature can be prepared by the method. In order to achieve the purpose, the invention provides the following technical scheme:
the embodiment of the application discloses special glue for sticker stone materials, which is characterized in that 960-985 parts of unsaturated polyester resin, 1-5 parts of nano inorganic powder, 1-5 parts of accelerator, 5-15 parts of chemical fiber and 10-30 parts of curing agent are sequentially added into a stirring kettle and stirred for 30-60 minutes to an even state to obtain the special glue for sticker stone materials.
Preferably, in the adhesive special for the sticker stone, the unsaturated polyester resin is a modified unsaturated polyester resin, has the performances of good leveling property, fast surface drying, yellowing resistance and the like, and has high tensile, bending and compressive strength and chemical corrosion resistance.
Preferably, in the special adhesive for the sticker stone, the nano inorganic powder is one or more of nano silicon dioxide and precipitated barium sulfate.
Preferably, in the special adhesive for the sticker stone, the accelerator is one or more of cobalt naphthenate or a colorless accelerator LCC-F.
Preferably, in the special adhesive for the sticker stone, the chemical fiber is a high-strength monofilament with the diameter of 20-30 microns.
Preferably, in the special adhesive for the sticker stone, the curing agent is one or more of trimellitic anhydride, methyl tetrahydrophthalic anhydride and dicyandiamide.
The invention has the advantages that: the application provides a pair of special glue of sticker stone material, but the sticker stone material that adopts this glue to make cuts or the edging wantonly, and the sticker does not stick up the limit, skinning, drops, and has excellent levelling nature, anti freeze thawing resistance, weather resistance, yellowing resistance, higher adhesion and intensity. The problems of bulging, poor bonding force and cracking after curing and the like caused by the use of the traditional stone adhesive are effectively solved.
Detailed Description
The preparation method of the special adhesive for the sticker stone will be described with reference to the following examples.
Example 1:
according to the mass fraction, 960 parts of unsaturated polyester resin, 2 parts of nano-dioxide, 2 parts of cobalt naphthenate, 5 parts of chemical fiber and 12 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, so that the special adhesive for the paster stone is obtained.
Example 2:
according to the mass fraction, 960 parts of unsaturated polyester resin, 3 parts of nano silicon dioxide, 2 parts of cobalt naphthenate, 5 parts of chemical fiber and 12 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, so that the special adhesive for the sticker stone is obtained.
Example 3:
and (2) sequentially putting 960 parts of unsaturated polyester resin, 4 parts of nano silicon dioxide, 2 parts of cobalt naphthenate, 5 parts of chemical fiber and 12 parts of trimellitic anhydride into a stirring kettle according to mass fraction, and stirring for 30-60 minutes to a uniform state to obtain the special adhesive for the sticker stone.
Example 4:
and (2) sequentially putting 960 parts of unsaturated polyester resin, 5 parts of nano silicon dioxide, 2 parts of cobalt naphthenate, 5 parts of chemical fiber and 12 parts of trimellitic anhydride into a stirring kettle according to mass fraction, and stirring for 30-60 minutes to a uniform state to obtain the special adhesive for the sticker stone.
Example 5:
according to the mass fraction, 965 parts of unsaturated polyester resin, 1 part of nano silicon dioxide, 2 parts of precipitated barium sulfate, 3 parts of cobalt naphthenate, 10 parts of chemical fiber and 15 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 6:
according to the mass fraction, 965 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 1 part of precipitated barium sulfate, 3 parts of cobalt naphthenate, 10 parts of chemical fiber and 15 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 7:
according to the mass fraction, 965 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 3 parts of precipitation-grade barium sulfate, 3 parts of cobalt naphthenate, 10 parts of chemical fiber and 15 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 8:
according to the mass fraction, 965 parts of unsaturated polyester resin, 3 parts of nano silicon dioxide, 2 parts of precipitated barium sulfate, 3 parts of cobalt naphthenate, 10 parts of chemical fiber and 15 parts of trimellitic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 9:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 13 parts of chemical fiber and 20 parts of trimellitic anhydride are sequentially added into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, so that the special adhesive for the paster stone is obtained.
Example 10:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 13 parts of chemical fiber, 10 parts of trimellitic anhydride and 5 parts of methyl tetrahydrophthalic anhydride are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, so that the special adhesive for the sticker stone is obtained.
Example 11;
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 5 parts of trimellitic anhydride, 10 parts of methyl tetrahydrophthalic anhydride and 1 part of dicyandiamide are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, so that the special adhesive for the sticker stone is obtained.
Example 12:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 3 parts of colorless accelerant LCC-F3, 13 parts of chemical fiber, 3 parts of trimellitic anhydride, 10 parts of methyl tetrahydrophthalic anhydride and 3 parts of dicyandiamide are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 13:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 25 parts of colorless accelerant LCC-F3, 13 parts of chemical fiber, 5 parts of trimellitic anhydride, 7 parts of methyl tetrahydrophthalic anhydride and 5 parts of dicyandiamide are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 14:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 25 parts of colorless accelerant LCC-F3, 13 parts of chemical fiber, 5 parts of trimellitic anhydride, 10 parts of methyl tetrahydrophthalic anhydride and 5 parts of dicyandiamide are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
Example 15:
according to the mass fraction, 980 parts of unsaturated polyester resin, 2 parts of nano silicon dioxide, 2 parts of precipitation-grade barium sulfate, 1 part of cobalt naphthenate, 25 parts of colorless accelerant LCC-F3, 13 parts of chemical fiber, 5 parts of trimellitic anhydride, 10 parts of methyl tetrahydrophthalic anhydride and 5 parts of dicyandiamide are sequentially put into a stirring kettle and stirred for 30-60 minutes to be in a uniform state, and the special adhesive for the sticker stone is obtained.
The properties of the special adhesive for decal stone obtained in the last examples 1 to 17 are as follows:
as can be seen from the table, the strength loss rates (average values) of the paster stone prepared by the special adhesive for paster stone disclosed by the application are all less than 1% after alternate cyclic curing for 5 times at 70 ℃/24h and-20 ℃/24h, the falling ball impact heights of 450g of steel balls are all more than 1000mm, and the freeze-thaw resistance and the impact resistance are in the leading level in the industry.
The present embodiments are to be considered as illustrative and not restrictive, and the scope of the patent is to be determined by the appended claims.
Claims (6)
1. The special adhesive for the sticker stone is characterized by being prepared by sequentially adding 960-985 parts of unsaturated polyester resin, 1-5 parts of nano inorganic powder, 1-5 parts of accelerator, 5-15 parts of chemical fiber and 10-30 parts of curing agent into a stirring kettle in parts by mass, and stirring for 30-60 minutes to a uniform state.
2. The special adhesive for paster stone as claimed in claim 1, wherein the unsaturated polyester resin is modified unsaturated polyester resin.
3. The special adhesive for paster stone as claimed in claim 1, wherein said nano inorganic powder is one or more of nano silicon dioxide and precipitated barium sulfate.
4. The special adhesive for the sticker stone as claimed in claim 1, wherein the accelerator is one or more of cobalt naphthenate or a colorless accelerator LCC-F.
5. The special adhesive for paster stones according to claim 1, wherein the chemical fibers are high-strength monofilaments with a diameter of 20-30 microns.
6. The special adhesive for paster stone as claimed in claim 1, wherein said curing agent is one or more of trimellitic anhydride, methyl tetrahydrophthalic anhydride and dicyandiamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010382212.6A CN113621334A (en) | 2020-05-08 | 2020-05-08 | Special adhesive for sticker stone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010382212.6A CN113621334A (en) | 2020-05-08 | 2020-05-08 | Special adhesive for sticker stone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113621334A true CN113621334A (en) | 2021-11-09 |
Family
ID=78377185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010382212.6A Pending CN113621334A (en) | 2020-05-08 | 2020-05-08 | Special adhesive for sticker stone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113621334A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851483A (en) * | 2010-06-08 | 2010-10-06 | 武汉市科达云石护理材料有限公司 | Stone jointing adhesive |
| CN101857790A (en) * | 2010-06-08 | 2010-10-13 | 武汉市科达云石护理材料有限公司 | Special color stone grout |
| CN108913045A (en) * | 2018-07-24 | 2018-11-30 | 甘肃金润玉石业有限公司 | A kind of breakage marble slabs method for repairing and mending |
-
2020
- 2020-05-08 CN CN202010382212.6A patent/CN113621334A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851483A (en) * | 2010-06-08 | 2010-10-06 | 武汉市科达云石护理材料有限公司 | Stone jointing adhesive |
| CN101857790A (en) * | 2010-06-08 | 2010-10-13 | 武汉市科达云石护理材料有限公司 | Special color stone grout |
| US20120302687A1 (en) * | 2010-06-08 | 2012-11-29 | Du Kunwen | Adhesive |
| RU2012158119A (en) * | 2010-06-08 | 2014-07-20 | Ухань Кэда Марбл Протектив Матириалз Ко., Лтд. | BINDING MATERIAL FOR STONE CONNECTION |
| CN108913045A (en) * | 2018-07-24 | 2018-11-30 | 甘肃金润玉石业有限公司 | A kind of breakage marble slabs method for repairing and mending |
Non-Patent Citations (3)
| Title |
|---|
| 廖宏,马玉珍,魏大超: "191不饱和聚酯胶粘剂的改性研究", 粘接, no. 04 * |
| 彭永利,黄志雄,秦岩,梅启林: "新型石材专用胶粘剂的研究", 武汉化工学院学报, no. 03 * |
| 枫轩;: "不饱和聚酯树脂粘接技术", 热固性树脂, no. 03 * |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20211109 |