CN113600773A - Pouring process of low-oxygen-concentration continuous casting tundish - Google Patents

Pouring process of low-oxygen-concentration continuous casting tundish Download PDF

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Publication number
CN113600773A
CN113600773A CN202110869223.1A CN202110869223A CN113600773A CN 113600773 A CN113600773 A CN 113600773A CN 202110869223 A CN202110869223 A CN 202110869223A CN 113600773 A CN113600773 A CN 113600773A
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China
Prior art keywords
tundish
molten steel
argon
continuous casting
pouring process
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CN202110869223.1A
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Chinese (zh)
Inventor
钱志友
程传良
苏迪
童兴亚
魏庆明
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Nanjing Iron and Steel Co Ltd
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Nanjing Iron and Steel Co Ltd
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Priority to CN202110869223.1A priority Critical patent/CN113600773A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/18Controlling or regulating processes or operations for pouring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/111Treating the molten metal by using protecting powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/50Pouring-nozzles
    • B22D41/58Pouring-nozzles with gas injecting means

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

The invention discloses a pouring process of a continuous casting tundish with low oxygen concentration, which relates to the technical field of steel production. Spiral argon blowing is initiated, a rotary argon airflow atmosphere is formed near a ladle down nozzle and a long nozzle in the pouring process, oxygen suction is controlled to the maximum extent, the purity of molten steel is guaranteed, and secondary pollution is reduced.

Description

Pouring process of low-oxygen-concentration continuous casting tundish
Technical Field
The invention relates to the technical field of steel production, in particular to a pouring process of a continuous casting tundish with low oxygen concentration.
Background
The continuous casting tundish is a refractory container between a ladle and a crystallizer. Tundish metallurgy has been developed rapidly in recent years in the steel industry in China, and various ladle refining techniques have been developed with increasing requirements for steel quality, aiming at improving the purity of molten steel and cleaning the molten steel. The molten steel refined outside the furnace can be said to be clean, but the molten steel can be polluted after being poured into a tundish. The main performance of foreign inclusions is that the casting is not in place, the existence of the inclusions not only influences the castability of molten steel, but also is difficult to carry out continuous casting operation, and the quality of steel is endangered. The foreign impurities are mainly secondary oxidation products of molten steel in the casting process, most of the foreign impurities are macro-impurities with coarse particles, and in order to ensure the quality of final products, the content of non-metallic impurities in the steel is reduced as much as possible. Practice shows that cracks exist at all parts of the casting blank with inclusions. Therefore, the tundish cannot be regarded as a simple molten steel transfer vessel.
The 'N' of molten steel is increased in the continuous casting production process, the main expression form is caused by incomplete protection casting, so that the rolled product has the defects of hairline, delamination, cracking and the like, and the quality and the fluidity of the molten steel and the recovery rate of alloy elements, particularly the recovery rate of Al and Ca, are reduced.
Disclosure of Invention
Aiming at the technical problems, the invention overcomes the defects of the prior art and provides a pouring process of a low-oxygen-concentration continuous casting tundish, wherein before a ladle is poured, argon is blown in an impact area of the tundish in a spiral argon blowing mode, the argon is sunk into the tundish to be discharged and extrude air in the tundish, spiral closed argon gas mist is formed at the upper part of the liquid level of molten steel in the impact area, a protective sleeve and a ladle water outlet area when the molten steel is poured, and air is isolated from entering the tundish through the protective sleeve and the ladle water outlet, so that the secondary oxidation of the molten steel is reduced.
The technical scheme of the invention is further defined as follows:
the pouring process of the continuous casting tundish with low oxygen concentration is characterized in that spiral argon blowing is carried out 5-10 minutes before the ladle is poured, and a rotary argon airflow atmosphere is formed near a water outlet and a long water outlet of the ladle.
The pouring process of the continuous casting tundish with low oxygen concentration adopts a protection sleeve argon-sealed protection mode to pour molten steel from a steel ladle to the tundish.
In the pouring process of the continuous casting tundish with low oxygen concentration, the covering agent is added into the tundish in the pouring process, and the molten steel in an impact area keeps slightly turning over in the production process, so that the molten steel is strictly prevented from being exposed.
In the pouring process of the continuous casting tundish with low oxygen concentration, the purity of argon is set to be 99.5-99.8%, the pressure of sealed argon is set to be 0.3-0.4MPa, and the flow of an argon blowing device is set to be 150L/min.
According to the pouring process of the continuous casting tundish with low oxygen concentration, when the molten steel amount of the tundish reaches the designed capacity of 2/3, the argon blowing flow of the protective sleeve is adjusted to be 90L/min, a stable argon atmosphere is formed at the upper part of the molten steel surface, and the molten steel cannot be overturned.
The invention has the beneficial effects that:
(1) the method takes the pouring of the tundish with low oxygen concentration as a core, ensures the purity of the molten steel through full-protection pouring, initiates a spiral argon blowing operation method, forms a rotary argon atmosphere near a ladle long nozzle in the pouring process, controls oxygen suction to the maximum extent, improves the purity of the molten steel, finally improves the quality of a casting blank, and successfully solves the problem that the molten steel is secondarily oxidized in the continuous casting pouring and pouring processes;
(2) in the invention, in order to avoid oxidation of molten steel in contact with air in the pouring process, the pouring of the tundish adopts a mode of protecting a sleeve and forming an argon atmosphere by argon sealing and argon blowing in the tundish, which is favorable for preventing secondary oxidation, and the immersion type water gap protection can ensure the purity of the molten steel in the pouring process;
(3) the covering slag has good spreadability, and can isolate air from contacting with molten steel, so that the purity of the molten steel is further improved, the possibility of secondary oxidation of the molten steel is effectively reduced, and the quality of the molten steel is improved.
Drawings
FIG. 1 is a schematic view of a spiral argon blowing apparatus according to the present invention;
wherein: 1. a gas source; 2. a tundish cover; 3. an air intake handle; 4. and (4) blowing the air.
Detailed Description
Example 1
The pouring process of the continuous casting tundish with low oxygen concentration provided by the embodiment comprises the following steps:
before the ladle is cast, argon is blown in an impact area of the tundish through a spiral argon blowing device (shown in figure 1), the tundish argon is filled for 10min, the purity of the argon is set to be 99.8%, the pressure of the sealed argon is set to be 0.4MPa, the flow is set to be 150L/min, and the argon is blown continuously in the production process;
pouring molten steel into a tundish from a steel ladle by adopting a protection sleeve argon seal protection mode, when the tonnage of the tundish reaches 15t, adding a covering agent more than or equal to 150kg from a temperature measuring hole in a first furnace, adding the covering agent more than or equal to 200kg from a sleeve hole at 20t, and then adding the covering agent according to the situation, wherein the total adding amount of the first furnace is more than or equal to 400 kg;
when the molten steel amount of the tundish reaches the designed capacity of 2/3, the flow rate of the protective sleeve is reduced to 90L/min, the molten steel in the impact area is slightly turned over in the production process, and the molten steel is not turned over.
When the tonnage of the tundish is stabilized to be more than 36t, sampling when the ladle molten steel is poured to 80 +/-10 t, randomly sampling and randomly sampling the ladle sample and the gas sample in a furnace 5:
TABLE 1
Figure 113446DEST_PATH_IMAGE001
In example 1, the N increase test from the comparative refining to the continuous casting tundish is carried out, and as can be seen from Table 1, the N increase is 3ppm at most and 0ppm at least, and the N increase of the rest of the heats is between 1 and 2 ppm.
Example 2
The pouring process of the continuous casting tundish with low oxygen concentration provided by the embodiment is different from the pouring process of the continuous casting tundish with low oxygen concentration provided by the embodiment 1 in that: and filling argon in the tundish for 8min, setting the pressure of the sealed argon to be 0.2MPa and setting the flow to be 120L/min.
And (3) taking a tundish sample when the tonnage of the tundish is stabilized to be more than 36t and the ladle molten steel is poured to 80 +/-10 t, and randomly sampling the tundish sample and the gas sample in the 5-furnace:
TABLE 2
Figure 844641DEST_PATH_IMAGE002
In example 2, the tests of increasing N in the comparative refining to continuous casting tundish were carried out, and it can be seen from Table 2 that the N increases were all 4ppm or less.
Example 3
The pouring process of the continuous casting tundish with low oxygen concentration provided by the embodiment is different from the pouring process of the continuous casting tundish with low oxygen concentration provided by the embodiment 1 in that: and filling argon in the tundish for 5min, setting the pressure of the sealed argon to be 0.3MPa and setting the flow to be 100L/min.
And (3) taking a tundish sample when the tonnage of the tundish is stabilized to be more than 36t and the ladle molten steel is poured to 80 +/-10 t, and randomly sampling the tundish sample and the gas sample in the 5-furnace:
TABLE 3
Figure 306847DEST_PATH_IMAGE003
In example 3, comparative refining to continuous casting tundish N increase test was carried out, and it can be seen from Table 3 that the N increase was between 1 and 3 ppm.
As can be seen from tables 1 to 3, the refining to continuous casting tundish protection pouring process has lower occurrence rate of N increase. The filling of argon can rapidly discharge redundant air before the pouring of the tundish is started, a stable argon atmosphere is formed at the upper part of the molten steel surface of the tundish in the production process, a covering agent is added to cover the molten steel surface, and spiral argon gas fog is formed in the area between the protective sleeve and the water outlet of the ladle to prevent air from contacting the molten steel, so that the purity of the molten steel in the pouring process is ensured. Because the purity of the argon gas is higher, the quality of the molten steel can be greatly improved, the secondary oxidation of the molten steel is reduced, and the impurities in the molten steel can float to the maximum extent due to the arrangement of the pressure and the flow, so that the quality of the molten steel can be further improved, and the casting blank has better internal quality.
In addition to the above embodiments, the present invention may have other embodiments. All technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope of the claims of the present invention.

Claims (6)

1. A pouring process of a continuous casting tundish with low oxygen concentration is characterized in that: before the ladle is cast, argon is blown in an impact area of the tundish in a spiral argon blowing mode, the argon sinks into the tundish to be discharged and extrude air in the tundish, spiral closed argon gas mist is formed in the upper part of the liquid level of molten steel in the impact area, the protective sleeve and a ladle water outlet area when molten steel is cast, and air is isolated from entering the tundish through the protective sleeve and the ladle water outlet to reduce secondary oxidation of the molten steel.
2. The low oxygen concentration continuous casting tundish pouring process according to claim 1, wherein: and performing spiral argon blowing 5-10 minutes before the pouring of the ladle, and forming a rotary argon gas flow atmosphere near a ladle down nozzle and a long nozzle.
3. The low oxygen concentration continuous casting tundish pouring process according to claim 1, wherein: and pouring molten steel from the steel ladle to the tundish in an argon sealing protection mode of the protective sleeve.
4. The low oxygen concentration continuous casting tundish pouring process according to claim 1, wherein: and adding a covering agent into the tundish in the pouring process, and keeping the molten steel in an impact area to slightly turn over in the production process, so that the molten steel is strictly prevented from being exposed.
5. The low oxygen concentration continuous casting tundish pouring process according to claim 1, wherein: the purity of the argon is set to be 99.5-99.8%, the pressure of the sealed argon is set to be 0.3-0.4MPa, and the flow of the argon blowing device is set to be 150L/min.
6. The low oxygen concentration continuous casting tundish pouring process according to claim 1, wherein: when the molten steel amount of the tundish reaches the designed capacity of 2/3, the argon blowing flow of the protective sleeve is adjusted to 90L/min, a stable argon atmosphere is formed at the upper part of the molten steel surface, and the molten steel cannot be overturned.
CN202110869223.1A 2021-07-30 2021-07-30 Pouring process of low-oxygen-concentration continuous casting tundish Pending CN113600773A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457210A (en) * 2021-12-24 2022-05-10 浦项(张家港)不锈钢股份有限公司 Method for controlling purity of tundish molten steel during ladle changing period

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06344098A (en) * 1993-06-08 1994-12-20 Sumitomo Metal Ind Ltd Method and device for sealing molten steel pouring flow
CN204018701U (en) * 2014-07-21 2014-12-17 马钢(集团)控股有限公司 Continuous casting T shape tundish impact area argon-blowing device
CN204075107U (en) * 2014-10-08 2015-01-07 舞阳钢铁有限责任公司 A kind of ingot steel casting argon protective device
CN205763829U (en) * 2016-05-30 2016-12-07 中原特钢股份有限公司 A kind of device of continuous casting tundish submerged nozzle argon for protecting pouring
CN106270431A (en) * 2016-08-30 2017-01-04 山东钢铁股份有限公司 Promote tundish metallurgy ability and reduce argon-blowing device and the using method of mouth of a river wadding stream
CN106881457A (en) * 2017-03-28 2017-06-23 马鞍山钢铁股份有限公司 Molten steel pours device and part is sealed with argon and the method that part carries out argon envelope is sealed using argon
CN108067598A (en) * 2018-01-03 2018-05-25 河钢股份有限公司承德分公司 The method for reducing low-carbon low-silicon steel continuous casting head stove nitrogen in steel content
CN210125731U (en) * 2019-03-26 2020-03-06 宣化钢铁集团有限责任公司 Immersion type water gap argon sealing protection pouring device
CN112317706A (en) * 2020-09-11 2021-02-05 南京钢铁股份有限公司 Argon protection pouring operation method for continuous casting tundish

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06344098A (en) * 1993-06-08 1994-12-20 Sumitomo Metal Ind Ltd Method and device for sealing molten steel pouring flow
CN204018701U (en) * 2014-07-21 2014-12-17 马钢(集团)控股有限公司 Continuous casting T shape tundish impact area argon-blowing device
CN204075107U (en) * 2014-10-08 2015-01-07 舞阳钢铁有限责任公司 A kind of ingot steel casting argon protective device
CN205763829U (en) * 2016-05-30 2016-12-07 中原特钢股份有限公司 A kind of device of continuous casting tundish submerged nozzle argon for protecting pouring
CN106270431A (en) * 2016-08-30 2017-01-04 山东钢铁股份有限公司 Promote tundish metallurgy ability and reduce argon-blowing device and the using method of mouth of a river wadding stream
CN106881457A (en) * 2017-03-28 2017-06-23 马鞍山钢铁股份有限公司 Molten steel pours device and part is sealed with argon and the method that part carries out argon envelope is sealed using argon
CN108067598A (en) * 2018-01-03 2018-05-25 河钢股份有限公司承德分公司 The method for reducing low-carbon low-silicon steel continuous casting head stove nitrogen in steel content
CN210125731U (en) * 2019-03-26 2020-03-06 宣化钢铁集团有限责任公司 Immersion type water gap argon sealing protection pouring device
CN112317706A (en) * 2020-09-11 2021-02-05 南京钢铁股份有限公司 Argon protection pouring operation method for continuous casting tundish

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457210A (en) * 2021-12-24 2022-05-10 浦项(张家港)不锈钢股份有限公司 Method for controlling purity of tundish molten steel during ladle changing period

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Application publication date: 20211105