CN113577794A - Safe and nontoxic children bubble liquid and preparation method thereof - Google Patents
Safe and nontoxic children bubble liquid and preparation method thereof Download PDFInfo
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- CN113577794A CN113577794A CN202110887229.1A CN202110887229A CN113577794A CN 113577794 A CN113577794 A CN 113577794A CN 202110887229 A CN202110887229 A CN 202110887229A CN 113577794 A CN113577794 A CN 113577794A
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- 239000007788 liquid Substances 0.000 title claims abstract description 68
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 45
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title abstract description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 60
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000341 volatile oil Substances 0.000 claims abstract description 42
- 238000003756 stirring Methods 0.000 claims abstract description 35
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- 239000000419 plant extract Substances 0.000 claims abstract description 31
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- 239000012190 activator Substances 0.000 claims abstract description 15
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- LUKBXSAWLPMMSZ-OWOJBTEDSA-N Trans-resveratrol Chemical compound C1=CC(O)=CC=C1\C=C\C1=CC(O)=CC(O)=C1 LUKBXSAWLPMMSZ-OWOJBTEDSA-N 0.000 claims abstract description 14
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- 239000002994 raw material Substances 0.000 claims abstract description 10
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 108010059892 Cellulase Proteins 0.000 claims description 10
- 229940106157 cellulase Drugs 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 10
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- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- 239000004302 potassium sorbate Substances 0.000 claims description 7
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- 235000010241 potassium sorbate Nutrition 0.000 claims description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
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- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 240000002657 Thymus vulgaris Species 0.000 claims description 3
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- 239000001585 thymus vulgaris Substances 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 2
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
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- 235000006679 Mentha X verticillata Nutrition 0.000 claims 1
- 235000002899 Mentha suaveolens Nutrition 0.000 claims 1
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- 238000012360 testing method Methods 0.000 description 18
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- 241000283973 Oryctolagus cuniculus Species 0.000 description 10
- 206010030113 Oedema Diseases 0.000 description 6
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- 230000002688 persistence Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 206010015150 Erythema Diseases 0.000 description 3
- 231100000321 erythema Toxicity 0.000 description 3
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- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
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- WEXRUCMBJFQVBZ-UHFFFAOYSA-N pentobarbital Chemical compound CCCC(C)C1(CC)C(=O)NC(=O)NC1=O WEXRUCMBJFQVBZ-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/28—Soap-bubble toys; Smoke toys
Landscapes
- Cosmetics (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
The invention discloses safe and non-toxic children bubble liquid which comprises the following raw materials in percentage by mass: 15-40% of alkyl glycoside, 1-2% of plant extract active agent, 0.5-2.5% of hydroxypropyl methyl cellulose, 1-8% of glycerol, 0.05-0.3% of plant extract essential oil, 1-5% of edible sugar, 0.5-2% of preservative, 0.1-1% of spherical nano silicon dioxide and the balance of purified water; wherein, the plant extract active agent is obtained by crushing resveratrol, freezing and thawing and then carrying out enzymolysis. The invention also discloses a preparation method of the safe and nontoxic children bubble liquid, which comprises the steps of adding the spherical nano silicon dioxide into water, stirring, adding the hydroxypropyl methyl cellulose, and continuously stirring to obtain a premix; adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and antiseptic into the premix, and stirring to obtain safe and nontoxic bubble liquid for children.
Description
Technical Field
The invention relates to the technical field of bubble liquid, in particular to safe and non-toxic bubble liquid for children and a preparation method thereof.
Background
The bubble liquid is a liquid required in the children bubble-blowing game, and can be blown into circular bubbles. Bubbles are formed by the surface tension of water, which is the mutual traction force existing in the interior of the object perpendicular to the contact surface of two adjacent parts when the object is subjected to a tensile force. The water surface has stronger attraction between water molecules than between water molecules and air, and the water molecules are adhered together. The bubble liquid "breaks" the surface tension, which reduces the surface tension to 1/3, which is the only normal condition for blowing bubbles, and the bubble disappears as soon as the bubble surface breaks as the water evaporates. While light passing through the bubble film is refracted at both the top and bottom of the film, the soap film can contain up to about 150 different layers. The messy color combinations we see are caused by unbalanced film layers. The thickest film layer reflects red light, the thinnest reflects purple light, and the middle reflects seven colors of light.
The bubble water is one of important toys of children, the safety of bubble water solution should be specially paid attention to when the bubble water is purchased, bubble water manufacturers on the market can look like cow hair, various bubble water is full of bubbles, the common defect is that bubbles are easy to break, and alkaline ingredients in the bubble water solution can corrode the skin of children.
Considering the safety problem of bubble water, the bubble water is worthy of being updated by related technicians, and under the trend that health consciousness and environmental consciousness are increasingly improved, the bubble water which is natural and environment-friendly and not easy to break can be popular with parents and children, so that the bubble water has great significance.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a safe and non-toxic children bubble liquid and a preparation method thereof.
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 15-40% of alkyl glycoside, 1-2% of plant extract active agent, 0.5-2.5% of hydroxypropyl methyl cellulose, 1-8% of glycerol, 0.05-0.3% of plant extract essential oil, 1-5% of edible sugar, 0.5-2% of preservative, 0.1-1% of spherical nano silicon dioxide and the balance of purified water.
The plant extraction active agent is prepared by the following specific operations: crushing 10-20 parts of resveratrol according to parts by weight, adding 20-50 parts of water, mixing, freezing at-10 to-20 ℃ for 1-2h, thawing to room temperature, adding 0.1-0.2 part of cellulase for enzymolysis for 5-10h, adding 1-2 parts of sodium stearate, stirring at 40-60 ℃ for 5-10h, squeezing, filtering, concentrating and drying to obtain the plant extraction active agent.
Wherein, the plant extract active agent is obtained by crushing resveratrol, freezing and thawing and then carrying out enzymolysis.
Preferably, the plant extract essential oil is at least one of orange essential oil, rose essential oil, rosemary essential oil, lavender essential oil, lemon essential oil, clove essential oil, peppermint essential oil, and thyme essential oil.
Preferably, the edible sugar is at least one of sucrose, maltose and glucose.
Preferably, the preservative is citric acid and/or potassium sorbate.
Preferably, the spherical nano-silica has a particle size of 40-200nm and a specific surface area of 1050-1170m2Per g, pore volume of 0.81-0.93cm3/g。
Preferably, the apparent density of the hydroxypropyl methylcellulose is from 0.52 to 0.6g/cm3The surface tension of the 2% aqueous solution is 50 to 54 dyne/cm.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano-silica into water, stirring for 1-2h at the speed of 1200r/min of 1000-;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
The spherical nano silicon dioxide has a unique structure, so that the spherical nano silicon dioxide has very strong reflection performance in ultraviolet and visible light wave bands, but the spherical nano silicon dioxide is easy to agglomerate, easily causes poor bubble uniformity and is very easy to crack. The nano-silicon dioxide is uniformly dispersed into the aqueous solution under the action of the hydroxypropyl methyl cellulose, can generate hydrogen bond adsorption with the hydroxypropyl methyl cellulose, is not easy to generate agglomeration and sedimentation even standing for a long time, and has high stability.
The technical effects of the invention are as follows:
1. the components of the invention are harmless to human body, and the invention is nontoxic, non-irritant and safe, and is verified by tests on human skin, so that the children playing with the bubble can not be harmed by contact, thus the baby can play the bubble safely and happily, parents can not worry about chemical components to corrode the skin of the children, and toxic substances can hurt eyes of the children;
2. the components are reasonably adjusted and matched, and the resveratrol is formed by scientifically matching pure plant extraction components, wherein the internal fiber structure of the resveratrol is damaged after being frozen, the solubility of a hydroxyl-containing compound in water can be increased under the action of sodium stearate through enzymolysis of cellulase, and a plant extraction active agent enters water, so that the alkalinity of an aqueous solution can be enhanced, the surface tension can be increased, a gas-liquid mixture can be stored for a long time in the shaking process of a bubble liquid, the foam quantity is increased, the surface tension of the bubble is increased, and the bubble durability is high;
3. the plant extraction activator obtained by the invention contains a large amount of hydroxyl, has excellent compatibility with alkyl glycoside, has obvious synergistic effect, is hardly influenced by water hardness, has rich foam and fine hand feeling; when a child plays with bubbles, the child can easily contact the bubbles, the bubbles can be attached to the body of the child for a long time, and the bubble durability is high.
4. According to the invention, the hydroxypropyl methyl cellulose is added to be compounded with the plant extraction active agent, so that the solubility of the hydroxypropyl methyl cellulose is excellent under an alkaline condition, the cohesion of bubble water molecules can be effectively slowed, the wall thickness of bubbles can be increased, the tension of the bubbles can be increased, and the persistence of the bubbles can be further enhanced.
Drawings
FIG. 1 is a comparison of the erythema scores in test example 1.
FIG. 2 is a comparative graph of the edema scores in test example 1.
FIG. 3 is a graph showing the comparison of the persistence of the bubble liquid for children in test example 2.
FIG. 4 is a graph comparing the number of bubbles of the bubble liquid for children in test example 3.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
Example 1
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 15% of alkyl glycoside, 2% of plant extraction active agent, 0.5% of hydroxypropyl methyl cellulose, 8% of glycerol, 0.05% of orange essential oil, 5% of sucrose, 0.5% of potassium sorbate, 1% of spherical nano silicon dioxide and the balance of purified water;
wherein the spherical nano-silica has a particle size of 40-200nm and a specific surface area of 1057m2Per g, pore volume of 0.85cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.52g/cm3The surface tension of the 2% aqueous solution was 51 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: crushing 10 parts of resveratrol, adding 50 parts of water, mixing, freezing at-10 ℃ for 2h, thawing to room temperature, adding 0.1 part of cellulase for enzymolysis for 10h, adding 1 part of sodium stearate, stirring at 60 ℃ for 5h, squeezing, filtering, concentrating and drying to obtain the plant extraction activator.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring for 1h at the speed of 1200r/min, reducing the speed to 300r/min, adding the hydroxypropyl methyl cellulose, and continuing stirring for 10min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
Example 2
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 40% of alkyl glycoside, 1% of plant extraction active agent, 2.5% of hydroxypropyl methyl cellulose, 1% of glycerol, 0.3% of lavender essential oil, 1% of glucose, 2% of citric acid, 0.1% of spherical nano silicon dioxide and the balance of purified water;
wherein the spherical nano-silica has a particle diameter of 40-200nm and a specific surface area of 1099m2Per g, pore volume of 0.81cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.54g/cm3The surface tension of the 2% aqueous solution was 50 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: crushing 20 parts of resveratrol, adding 20 parts of water, mixing, freezing at-20 ℃ for 1h, thawing to room temperature, adding 0.2 part of cellulase for enzymolysis for 5h, adding 2 parts of sodium stearate, stirring at 40 ℃ for 10h, squeezing, filtering, concentrating and drying to obtain the plant extraction activator.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring for 2h at the speed of 1000r/min, reducing the speed to 200r/min, adding hydroxypropyl methyl cellulose, and continuing stirring for 20min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
Example 3
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 20% of alkyl glycoside, 1.8% of plant extraction active agent, 1% of hydroxypropyl methyl cellulose, 6% of glycerol, 0.05% of peppermint essential oil, 0.05% of lemon essential oil, 2% of maltose, 2% of glucose, 0.2% of citric acid, 0.8% of potassium sorbate, 0.7% of spherical nano-silica and the balance of purified water;
wherein the spherical nano-silica has a particle size of 40-200nm and a specific surface area of 1111m2Per g, pore volume of 0.93cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.55g/cm3The surface tension of the 2% aqueous solution was 54 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: pulverizing 13 parts of resveratrol, adding 40 parts of water, mixing, freezing at-12 ℃ for 1.7h, thawing to room temperature, adding 0.13 part of cellulase for enzymolysis for 8h, adding 1.3 parts of sodium stearate, stirring at 55 ℃ for 7h, squeezing, filtering, concentrating, and drying to obtain the plant extract activator.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring for 1.3h at a speed of 1150r/min, reducing the speed to 280r/min, adding hydroxypropyl methyl cellulose, and continuously stirring for 13min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
Example 4
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 35% of alkyl glycoside, 1.2% of plant extraction active agent, 2% of hydroxypropyl methyl cellulose, 2% of glycerol, 0.25% of thyme essential oil, 2% of maltose, 1.5% of citric acid, 0.3% of spherical nano silicon dioxide and the balance of purified water;
wherein the particle diameter of the spherical nano silicon dioxide is 40-200nm, and the specific surface area is 1154m2Per g, pore volume of 0.87cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.6g/cm3The surface tension of the 2% aqueous solution was 52 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: crushing 17 parts of resveratrol, adding 30 parts of water, mixing, freezing at-18 ℃ for 1.3h, thawing to room temperature, adding 0.17 part of cellulase for enzymolysis for 6h, adding 1.7 parts of sodium stearate, stirring at 45 ℃ for 9h, squeezing, filtering, concentrating and drying to obtain the plant extraction active agent.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring at 1050r/min for 1.7h, reducing the speed to 220r/min, adding hydroxypropyl methyl cellulose, and continuing stirring for 17min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
Example 5
A safe and nontoxic bubble liquid for children comprises the following raw materials in percentage by mass: 28% of alkyl glycoside, 1.5% of plant extraction active agent, 1.5% of hydroxypropyl methyl cellulose, 4% of glycerol, 0.1% of rose essential oil, 0.05% of rosemary essential oil, 1% of sucrose, 2% of glucose, 1.3% of potassium sorbate, 0.5% of spherical nano silicon dioxide and the balance of purified water;
wherein the spherical nanometer silicon dioxide has particle diameter of 40-200nm and specific surface area of 1169m2Per g, pore volume of 0.90cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.57g/cm3The surface tension of the 2% aqueous solution was 53 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: crushing 15 parts of resveratrol, adding 35 parts of water, mixing, freezing at-15 ℃ for 1.5h, thawing to room temperature, adding 0.15 part of cellulase for enzymolysis for 7h, adding 1.5 parts of sodium stearate, stirring at 50 ℃ for 8h, squeezing, filtering, concentrating and drying to obtain the plant extraction active agent.
The preparation method of the safe and nontoxic children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring at the speed of 1100r/min for 1.5h, reducing the speed to 250r/min, adding the hydroxypropyl methyl cellulose, and continuing stirring for 15min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
Comparative example 1
The commercially available children bubble liquid is purchased from Chuangle science and technology limited of Shantou, Longhu region.
Comparative example 2
The children bubble liquid comprises the following raw materials in percentage by mass: 28% of alkyl glycoside, 1.5% of hydroxypropyl methyl cellulose, 4% of glycerol, 0.1% of rose essential oil, 0.05% of rosemary essential oil, 1% of sucrose, 2% of glucose, 1.3% of potassium sorbate, 0.5% of spherical nano silicon dioxide and the balance of purified water;
wherein the spherical nanometer silicon dioxide has particle diameter of 40-200nm and specific surface area of 1169m2Per g, pore volume of 0.90cm3(ii)/g; the apparent density of the hydroxypropyl methylcellulose is 0.57g/cm3The surface tension of the 2% aqueous solution was 53 dyne/cm.
The preparation method of the children bubble liquid comprises the following steps:
s1, adding the spherical nano silicon dioxide into water, stirring at the speed of 1100r/min for 1.5h, reducing the speed to 250r/min, adding the hydroxypropyl methyl cellulose, and continuing stirring for 15min to obtain a premix;
s2, adding alkyl glycoside, glycerol, plant extracted essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the children bubble liquid.
Comparative example 3
The children bubble liquid comprises the following raw materials in percentage by mass: 28% of alkyl glycoside, 1.5% of plant extraction active agent, 1.5% of hydroxypropyl methyl cellulose, 4% of glycerol, 0.1% of rose essential oil, 0.05% of rosemary essential oil, 1% of sucrose, 2% of glucose, 1.3% of potassium sorbate and the balance of purified water;
wherein the apparent density of hydroxypropyl methylcellulose is 0.57g/cm3The surface tension of the 2% aqueous solution was 53 dyne/cm.
The plant extraction active agent is prepared by the following specific operations: crushing 15 parts of resveratrol, adding 35 parts of water, mixing, freezing at-15 ℃ for 1.5h, thawing to room temperature, adding 0.15 part of cellulase for enzymolysis for 7h, adding 1.5 parts of sodium stearate, stirring at 50 ℃ for 8h, squeezing, filtering, concentrating and drying to obtain the plant extraction active agent.
The preparation method of the children bubble liquid comprises the following steps:
s1, adding hydroxypropyl methyl cellulose into water, and stirring for 15min to obtain a premix;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the children bubble liquid.
Test example 1
The non-toxic safe bubble liquid for children obtained in example 5 and the bubble liquids for children obtained in comparative examples 1-3 were subjected to irritation test, and the specific steps were as follows:
taking a rabbit to be detected, removing the hair on the back of the rabbit by using sterilized surgical scissors, removing the residual hair by using a proper amount of depilatory cream, and cleaning the residual depilatory cream and the fallen hair by using warm water; placing the unhaired rabbits in a dry and clean feeding environment, and feeding for 24 hours; taking out the treated rabbit, injecting 1% sodium pentobarbital into ear edge vein, the dosage is 30mg/kg, when the rabbit is coma, dividing the two sides of the back into 6 areas which are symmetrical left and right, and marking the areas as a test part, a positive control part and a negative control part;
uniformly coating 150 mu L of the safe and nontoxic child bubble liquid obtained in the example 5, 150 mu L of the child bubble liquid obtained in the comparative example 1, 150 mu L of the child bubble liquid obtained in the comparative example 2 and 150 mu L of the child bubble liquid obtained in the comparative example 3 on a test part; 150 mu L of lauryl sodium sulfate aqueous solution with the mass fraction of 20 wt% is immersed into gauze with proper size and is pasted on a positive control part; 150 μ L of 1 XPBS solution was dipped in gauze of appropriate size and applied to the negative control area;
selecting breathable gauze with proper size to wrap a tested area of the rabbit, fixing the breathable gauze by using an adhesive tape, feeding the rabbit for 4 hours in a dry and clean culture environment, removing the gauze and an experimental sample, carefully cleaning the rabbit with warm water, and removing residual substances on the back of the rabbit;
the condition of erythema and edema of the tested part on the back of the rabbit at each time period is recorded after 0h, 1h, 24h, 48h, 72h and 96h of removing the samples for the experiment respectively.
The evaluation criteria are as follows:
the erythema scores are shown in FIG. 1, and the edema scores are shown in FIG. 2 (since each group showed edema only 1h after the end of the test, and then edema resolved, FIG. 2 is a plot of edema only 1h after the test for each group of samples).
As can be seen from fig. 1 and 2: the safe and nontoxic children bubble liquid obtained by the invention has extremely weak irritation and safe use, and is suitable for children.
Test example 2
The safe and nontoxic child bubble liquid obtained in the example 5 and the child bubble liquids obtained in the comparative examples 1 to 3 are subjected to a persistence test and are detected by adopting an artificial bubble blowing mode. The measurement object is the fifth bubble of the bubble rod blowing bubbles at one time. The start and end times are calculated from the bubble completely disengaging the bubble stick until the bubble has completely disappeared from the air.
The results are shown in FIG. 3, and it can be seen from FIG. 3 that: the safety nontoxic bubble liquid for children obtained by the invention has better persistence than that of a comparative example, and can be more popular with children.
Test example 3
The safe and nontoxic bubble liquid for children obtained in the example 5 and the bubble liquid for children obtained in the comparative examples 1 to 3 are subjected to a bubble blowing test, and the specific steps are as follows:
adding the bubble liquid into a bubble machine, wherein the bubble machine is an astronaut bubble machine with a Huaile brand, and the model is 1103A; starting a switch, counting the number of bubbles blown out by the bubble machine one by one.
The results are shown in FIG. 4, and it can be seen from FIG. 4 that: the safe and nontoxic bubble liquid for children, which is obtained by the invention, has the bubble number superior to that of a comparative example, and can be more popular with children.
Test example 4
The safe and nontoxic bubble liquid for children obtained in the example 5 and the bubble liquid for children obtained in the comparative examples 1 to 3 are subjected to visual effect tests, and the specific steps are as follows:
adding the bubble liquid into a bubble machine, wherein the bubble machine is an astronaut bubble machine with a Huaile brand, and the model is 1103A; the bubble blowing is respectively carried out under the conditions of indoor and outdoor sufficient illumination in the daytime, the bubble color is observed, and the test results are as follows:
from the above table, it can be seen that: the safe and nontoxic bubble liquid for children, which is obtained by the invention, has bright color and can be enjoyed by children.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (9)
1. The safe and nontoxic bubble liquid for children is characterized by comprising the following raw materials in percentage by mass:
15-40% of alkyl glycoside, 1-2% of plant extract active agent, 0.5-2.5% of hydroxypropyl methyl cellulose, 1-8% of glycerol, 0.05-0.3% of plant extract essential oil, 1-5% of edible sugar, 0.5-2% of preservative, 0.1-1% of spherical nano silicon dioxide and the balance of purified water;
wherein, the plant extract active agent is obtained by crushing resveratrol, freezing and thawing and then carrying out enzymolysis.
2. The safe and non-toxic children bubble liquid according to claim 1, wherein the plant-derived essential oil is at least one of orange essential oil, rose essential oil, rosemary essential oil, lavender essential oil, lemon essential oil, clove essential oil, mint essential oil, and thyme essential oil.
3. The safe and non-toxic bubble generating liquid for children as claimed in claim 1, wherein the edible sugar is at least one of sucrose, maltose and glucose.
4. The safe and non-toxic bubble generating liquid for children as claimed in claim 1, wherein the preservative is citric acid and/or potassium sorbate.
5. The safe and non-toxic bubble liquid as claimed in claim 1, wherein the spherical nano-silica has a particle size of 40-200nm, a specific surface area of 1050-1170m2Per g, pore volume of 0.81-0.93cm3/g。
6. The safe and non-toxic bubble generating liquid for children as claimed in claim 1, wherein the apparent density of hydroxypropyl methylcellulose is 0.52-0.6g/cm3The surface tension of the 2% aqueous solution is 50 to 54 dyne/cm.
7. The safe and non-toxic bubble generating liquid for children as claimed in claim 1, wherein the plant extract activator is prepared by the following steps: pulverizing resveratrol, adding water, mixing, freezing at-10-20 deg.C for 1-2 hr, thawing to room temperature, adding cellulase for enzymolysis for 5-10 hr, adding sodium stearate, stirring at 40-60 deg.C for 5-10 hr, squeezing, filtering, concentrating, and drying to obtain plant extract activator.
8. The safe and nontoxic bubble liquid for children as claimed in claim 7, wherein the mass ratio of resveratrol, cellulase and sodium stearate is 10-20: 0.1-0.2: 1-2.
9. A method for preparing the safe and nontoxic bubble liquid for children as claimed in any one of claims 1-8, comprising the steps of:
s1, adding the spherical nano-silica into water, stirring for 1-2h at the speed of 1200r/min of 1000-;
s2, adding alkyl glycoside, plant extract activator, glycerol, plant extract essential oil, edible sugar and preservative into the premix, and uniformly stirring to obtain the safe and nontoxic children bubble liquid.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115594988A (en) * | 2022-11-02 | 2023-01-13 | 河源市云彩实业有限公司（Cn） | Extrusion-molded foam pigment and preparation method thereof |
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Application publication date: 20211102 |