CN113571228A - Front conductive silver paste for crystalline silicon solar cell and preparation method thereof - Google Patents
Front conductive silver paste for crystalline silicon solar cell and preparation method thereof Download PDFInfo
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- CN113571228A CN113571228A CN202110748876.4A CN202110748876A CN113571228A CN 113571228 A CN113571228 A CN 113571228A CN 202110748876 A CN202110748876 A CN 202110748876A CN 113571228 A CN113571228 A CN 113571228A
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- Prior art keywords
- silver paste
- conductive silver
- crystalline silicon
- silicon solar
- solar cell
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910021419 crystalline silicon Inorganic materials 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000011521 glass Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 9
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 7
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 6
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 claims description 6
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 claims description 5
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical group OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 4
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 4
- 239000001856 Ethyl cellulose Substances 0.000 claims description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 4
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 4
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 4
- 229920001249 ethyl cellulose Polymers 0.000 claims description 4
- 239000000787 lecithin Substances 0.000 claims description 4
- 235000010445 lecithin Nutrition 0.000 claims description 4
- 229940067606 lecithin Drugs 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 3
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- -1 alcohol ester Chemical class 0.000 claims description 3
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 3
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 3
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 229950008882 polysorbate Drugs 0.000 claims description 3
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 3
- 229940116411 terpineol Drugs 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- YTLYLLTVENPWFT-UPHRSURJSA-N (Z)-3-aminoacrylic acid Chemical compound N\C=C/C(O)=O YTLYLLTVENPWFT-UPHRSURJSA-N 0.000 claims description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 claims description 2
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 claims description 2
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims description 2
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 2
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 2
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 claims description 2
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- VSYDLUXFKAXBBY-UHFFFAOYSA-N C(C=1C(C(=O)O)=CC=CC1)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(COCCO)O Chemical compound C(C=1C(C(=O)O)=CC=CC1)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.C(COCCO)O VSYDLUXFKAXBBY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000020 Nitrocellulose Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 claims description 2
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 2
- 125000004386 diacrylate group Chemical group 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 238000005530 etching Methods 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 229910000464 lead oxide Inorganic materials 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 229920001220 nitrocellulos Polymers 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229910052714 tellurium Inorganic materials 0.000 claims description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 8
- 238000000016 photochemical curing Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- KESQFSZFUCZCEI-UHFFFAOYSA-N 2-(5-nitropyridin-2-yl)oxyethanol Chemical compound OCCOC1=CC=C([N+]([O-])=O)C=N1 KESQFSZFUCZCEI-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/05—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
- H01L31/0504—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
- H01L31/0512—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module made of a particular material or composition of materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Sustainable Development (AREA)
- Computer Hardware Design (AREA)
- Life Sciences & Earth Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Conductive Materials (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention discloses a front conductive silver paste for a crystalline silicon solar cell, which comprises the following raw materials: 72-90% of silver powder; glass powder: 4-10% of metal oxide, organic carrier: 5-20% of resin, dispersant, solvent and photo-curing material, wherein the resin accounts for 4-10%, the dispersant accounts for 2-8%, the solvent accounts for 75-85% and the photo-curing material accounts for 8-15%. The invention also provides a preparation method of the solar front conductive silver paste, and the organic carrier is added in the method, so that the conductive silver paste brings a high aspect ratio, and the electrical property of the paste is further improved. The conductive silver paste comprises silver powder, glass powder and an organic carrier, wherein the organic carrier comprises one or more photocuring materials, and the material can effectively improve the height-width ratio of the printed conductive silver paste, so that the solar energy conversion efficiency of the battery is improved.
Description
Technical Field
The invention belongs to the field of new materials for solar cells, and particularly relates to a front conductive silver paste for a crystalline silicon solar cell and a preparation method thereof.
Background
Energy is the basis of economic development and social development in the world, and solar energy as a novel clean energy is renewable energy and plays an important role in the future energy development process. The crystalline silicon solar cell is the main force of the existing solar cell, and the solar conductive silver paste is an important material required to be used in the process of preparing the crystalline silicon solar cell and has a crucial influence on the efficiency of a cell.
The conventional crystalline silicon solar cell prints conductive silver paste on the surface of a cell piece through a screen printing technology, an organic carrier mainly plays a role in wetting and dispersing inorganic components, the auxiliary slurry is used for printing smoothly through a screen printing plate, finger-shaped grid lines are formed on a silicon chip, and the silicon chip is dried and sintered, so that the organic components are volatilized and burnt out without residues. Silver powder is the conductive phase of conductive silver paste and is the main component of silver paste. The glass powder is a binding phase, and is sintered at high temperature to burn through an anti-reflection layer SiN of the cellXSo that the conductive phase silver electrode can be well contacted with silicon to form ohmic contact.
The invention patent CN 107919179 a proposes an organic carrier, which includes microgel particles and organic siloxane, and can better provide printing fluency of the slurry, and the aspect ratio of the printed grid line is improved to a certain extent, but the grid line still has a larger widening after sintering, and the widening of the grid line can increase the shading area on the surface of the battery piece, thereby reducing the short-circuit current and affecting the improvement of the efficiency.
Disclosure of Invention
In order to solve the technical problems, the invention provides a front conductive silver paste for a crystalline silicon solar cell and a preparation method thereof.
The technical scheme adopted by the invention is as follows:
the front conductive silver paste for the crystalline silicon solar cell comprises the following raw materials in percentage by weight:
conductive metal: 72-90% of silver powder;
glass powder: 4-10% of metal oxide, and is used for etching the anti-reflection layer of the cell and enabling the electrode and the cell to form ohmic contact;
organic carrier: 5-20% of resin, 2-8% of dispersing agent, 75-85% of solvent and 8-15% of light-cured material.
Preferably, the raw materials of the material comprise the following components in percentage by weight: conductive metal: 80-90% of silver powder; glass powder: is metal oxide accounting for 4-8%; organic carrier: 6-14% of resin, 3-6% of dispersant, 75-80% of solvent and 10-12% of light-cured material.
Further, the light-curable material is an acrylic monomer or resin containing one or more multifunctional groups.
Further, the polyfunctional acrylic monomer is ethoxylated 1.6 hexanediol diacrylate, tripropylene glycol diacrylate, dipropylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, propoxylated (2) neopentyl glycol diacrylate, diethylene glycol diacrylate phthalate, tripropylene glycol diacrylate, ethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, 1, 6-hexanediol diacrylate, ethoxylated 1.6 hexanediol diacrylate, 1, 4-butanediol diacrylate, ethoxylated (4) bisphenol A diacrylate, polyethylene glycol (200) diacrylate, trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated (3) glycerol triacrylate, One or more of pentaerythritol triacrylate, pentaerythritol tetraacrylate and dipentaerythritol pentaacrylate.
Furthermore, the multifunctional resin is one or more of epoxy acrylate, polyurethane acrylate, polyester acrylate, polyether acrylate, amino acrylate and acrylate.
Further, the organic carrier in the conductive silver paste at least comprises one or more than one monomer or resin containing 3 functional groups and more than one monomer or resin.
Further, the conductive silver powder comprises spherical silver powder, flake silver powder and nano silver powder, preferably the spherical silver powder, the particle diameter of the spherical silver powder is 2-6 mu m, and the tap density is more than 4 g/cm3。
Further, the metal oxide is at least one of lead oxide, zinc oxide, tellurium oxide, aluminum oxide and bismuth oxide.
Further, the resin comprises one or more of methyl cellulose, ethyl cellulose, cellulose acetate butyrate, nitrocellulose, rosin, modified rosin, polyvinyl alcohol, polyester resin and acrylic resin.
Further, the solvent in the organic carrier comprises one or more of terpineol, tributyl citrate, diethylene glycol butyl ether acetate, diethylene glycol dibutyl ether, diethylene glycol butyl ether, DBE, alcohol ester twelve, 2, 4-trimethyl-1, 3-pentanediol diisobutyrate, triethylene glycol and tripropylene glycol methyl ether;
further, the dispersing agent comprises one or more of lecithin, glyceryl monooleate, polyethylene glycol and polysorbate.
The invention also provides a preparation method of the front conductive silver paste for the crystalline silicon solar cell, which comprises the following steps:
1) according to the weight ratio of the materials, 4-10% of resin, 2-8% of dispersant, 75-85% of solvent and 8-15% of light-cured material are uniformly mixed by using a dispersing, emulsifying and stirring integrated machine, heated and dissolved uniformly at a constant temperature, cooled and filtered to obtain an organic carrier, wherein the heating and dissolving temperature is 60-70 ℃ at the constant temperature, and preferably 65 ℃;
2) adding the organic carrier, the glass powder and the silver powder obtained in the step 1) into a centrifuge or a planetary mixer according to the feeding proportion, uniformly mixing, and then grinding for 6-8 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the crystalline silicon solar cell.
According to the front conductive silver paste for the crystalline silicon solar cell and the preparation method thereof, the performance of the conductive silver paste is improved by adding the photocuring material. After the conductive silver paste is printed on the silicon wafer, the conductive silver paste passes through the drying section, and because the photocuring material is cured, the grid line cannot collapse or widen, so that the molding of the grid line is ensured, and after the silicon wafer passes through the sintering section, the photocuring material can be basically burnt out and cannot be remained in the grid line. The light-cured material can avoid the condition that the common thermoplastic resin is softened in the drying section and collapses, and meanwhile, the light-cured material can avoid the problem that the conventional thermosetting resin is added into slurry to cause storage. After the paste is printed, the grid lines are not collapsed or widened in the sintering process, so that the height-width ratio of the grid lines is improved, and the photoelectric conversion efficiency of the solar cell can be improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it should be apparent that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It is noted that the terms "comprises" and "comprising," and any variations thereof, in the description and claims of this invention, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, method, article, or apparatus.
Example 1
The preparation method of the front conductive silver paste for the crystalline silicon solar cell comprises the following steps:
1) according to parts by weight, 45 parts of oleyl alcohol, 10 parts of tributyl citrate, 10 parts of diethylene glycol butyl ether acetate, 10 parts of DBE, 2 parts of ethyl cellulose, 2 parts of rosin resin, 6 parts of lecithin, 6 parts of ethoxylated 1.6 hexanediol diacrylate, 4 parts of tripropylene glycol diacrylate and 5 parts of dipropylene glycol diacrylate are mixed and stirred uniformly, heated and stirred for 1h at the constant temperature of 65 ℃, cooled and filtered to prepare the organic carrier;
2) adding 8 parts by weight of organic carrier, 4 parts by weight of glass powder (zinc oxide) and 88 parts by weight of silver powder into a planetary mixer in sequence, uniformly mixing, and grinding for 8 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the solar cell.
Example 2
The preparation method of the front conductive silver paste for the crystalline silicon solar cell comprises the following steps:
1) mixing and stirring 40 parts by weight of diethylene glycol butyl ether, 10 parts by weight of DBE, 8 parts by weight of alcohol ester twelve, 12 parts by weight of 2,2, 4-trimethyl-1, 3-pentanediol diisobutyrate, 4 parts by weight of butyric acid fiber acetate, 4 parts by weight of modified rosin, 8 parts by weight of polysorbate, 4 parts by weight of ethylene glycol diacrylate, 3 parts by weight of triethylene glycol diacrylate, 4 parts by weight of tetraethylene glycol diacrylate and 3 parts by weight of 1, 6-hexanediol diacrylate uniformly, heating and stirring for 1h at the constant temperature of 70 ℃, cooling and filtering to prepare the organic carrier;
2) adding 12 parts by weight of organic carrier, 5 parts by weight of glass powder (bismuth oxide) and 83 parts by weight of silver powder into a planetary mixer in sequence, uniformly mixing, and grinding for 7 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the solar cell.
Example 3
The preparation method of the front conductive silver paste for the crystalline silicon solar cell comprises the following steps:
1) according to parts by weight, 50 parts of terpineol, 10 parts of 2,2, 4-trimethyl-1, 3-pentanediol diisobutyrate, 10 parts of triethylene glycol, 12 parts of tripropylene glycol methyl ether, 2 parts of polyester resin, 3 parts of acrylic resin, 3 parts of glycerol monooleate, 4 parts of epoxy acrylate, 3 parts of polyurethane acrylate and 3 parts of polyether acrylate are mixed and stirred uniformly, heated and stirred for 1 hour at the constant temperature of 65 ℃, cooled and filtered to prepare the organic carrier;
2) adding 15 parts by weight of organic carrier, 5 parts by weight of glass powder (bismuth oxide) and 80 parts by weight of silver powder into a planetary mixer in sequence, uniformly mixing, and grinding for 8 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the solar cell.
Example 4
The preparation method of the front conductive silver paste for the crystalline silicon solar cell comprises the following steps:
1) according to parts by weight, 45 parts of oleyl alcohol, 15 parts of tributyl citrate, 10 parts of diethylene glycol butyl ether acetate, 10 parts of DBE, 2 parts of ethyl cellulose, 2 parts of rosin resin, 6 parts of lecithin, 6 parts of glycerol monooleate and 4 parts of polyethylene glycol are mixed and stirred uniformly, heated and stirred for 1 hour at the constant temperature of 65 ℃, cooled and filtered to prepare the organic carrier;
2) adding 8 parts by weight of organic carrier, 4 parts by weight of glass powder (zinc oxide) and 88 parts by weight of silver powder into a planetary mixer in sequence, uniformly mixing, and grinding for 8 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the solar cell.
The relevant experimental data are characterized as shown in the following table:
characteristics of | Example 1 | Example 2 | Example 3 | Example 4 |
Efficiency (%) | 22.68 | 22.69 | 22.70 | 22.63 |
Current (mA) | 10.7530 | 10.7630 | 10.7653 | 10.7204 |
Voc(V) | 0.6849 | 0.6850 | 0.6845 | 0.6847 |
Height (mum) | 18.21 | 18.32 | 18.90 | 16.01 |
Width (mum) | 35.22 | 35.65 | 35.87 | 40.02 |
Aspect ratio | 0.517 | 0.513 | 0.527 | 0.40 |
The conductive silver pastes of example 1, example 2 and example 3 were added with the photo-curable material, while example 4 was not added, and it can be seen from the data that example 4 does not use the photo-curable material, the aspect ratio of the grid lines is lower, the current is significantly lower than the other three experiments, and the efficiency is also lower.
Claims (10)
1. The front conductive silver paste for the crystalline silicon solar cell is characterized by comprising the following raw materials in percentage by weight:
conductive metal: 72-90% of silver powder;
glass powder: 4-10% of metal oxide, and is used for etching the anti-reflection layer of the cell and enabling the electrode and the cell to form ohmic contact;
organic carrier: 5-20% of resin, 2-8% of dispersing agent, 75-85% of solvent and 8-15% of light-cured material.
2. The front conductive silver paste for the crystalline silicon solar cell according to claim 1, wherein the raw materials comprise the following components in percentage by weight:
conductive metal: 80-90% of silver powder;
glass powder: is metal oxide accounting for 4-8%;
organic carrier: 6-14% of resin, 3-6% of dispersant, 75-80% of solvent and 10-12% of light-cured material.
3. The front conductive silver paste for the crystalline silicon solar cell of claim 1, wherein the light-curable material is an acrylic monomer or resin containing one or more multifunctional groups.
4. The front conductive silver paste for crystalline silicon solar cells as recited in claim 3, wherein the multifunctional acrylic monomer is ethoxylated 1.6 hexanediol diacrylate, tripropylene glycol diacrylate, dipropylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, propoxylated (2) neopentyl glycol diacrylate, diethylene glycol diacrylate phthalate, tripropylene glycol diacrylate, ethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, 1, 6-hexanediol diacrylate, ethoxylated 1.6 hexanediol diacrylate, 1, 4-butanediol diacrylate, ethoxylated (4) bisphenol A diacrylate, polyethylene glycol (200) diacrylate, trimethylolpropane triacrylate, One or more of ethoxylated trimethylolpropane triacrylate, propoxylated (3) glycerol triacrylate, pentaerythritol tetraacrylate and dipentaerythritol pentaacrylate.
5. The front conductive silver paste for the crystalline silicon solar cell as recited in claim 3, wherein the multifunctional resin is one or more of epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, amino acrylate and acrylate.
6. The front conductive silver paste for the crystalline silicon solar cell according to claim 3 or 4, wherein the organic vehicle in the conductive silver paste at least comprises one or more monomers or resins containing 3 functional groups and more.
7. The front-side conductive silver paste for crystalline silicon solar cells according to claim 1, wherein the conductive silver metal powder comprises spherical silver powder, flake silver powder and nano silver powder, preferably spherical silver powderThe powder has particle diameter of 2-6 μm and tap density of more than 4 g/cm3The metal oxide is at least one of lead oxide, zinc oxide, tellurium oxide, aluminum oxide and bismuth oxide.
8. The front conductive silver paste for the crystalline silicon solar cell as recited in claim 1, wherein the resin comprises one or more of methyl cellulose, ethyl cellulose, cellulose acetate butyrate, nitrocellulose, rosin, modified rosin, polyvinyl alcohol, polyester resin and acrylic resin.
9. The front conductive silver paste for the crystalline silicon solar cell as recited in claim 1, wherein the solvent in the organic vehicle comprises one or more of terpineol, tributyl citrate, diethylene glycol butyl ether acetate, diethylene glycol dibutyl ether, diethylene glycol butyl ether, DBE, alcohol ester twelve, 2, 4-trimethyl-1, 3-pentanediol diisobutyrate, triethylene glycol, tripropylene glycol methyl ether, and the dispersant comprises one or more of lecithin, glycerol monooleate, polyethylene glycol, and polysorbate.
10. The preparation method of the front conductive silver paste for the crystalline silicon solar cell according to any one of claims 1 to 9, characterized by comprising the following steps:
1) according to the weight ratio of the materials, 4-10% of resin, 2-8% of dispersant, 75-85% of solvent and 8-15% of light-cured material are uniformly mixed by using a dispersing, emulsifying and stirring integrated machine, heated and dissolved uniformly at a constant temperature, cooled and filtered to obtain an organic carrier, wherein the heating and dissolving temperature is 60-70 ℃, and preferably 65 ℃;
2) adding the organic carrier, the glass powder and the silver powder obtained in the step 1) into a centrifuge or a planetary mixer according to the feeding proportion, uniformly mixing, and then grinding for 6-8 times by a three-roll grinder until the fineness of the slurry is less than 7 mu m to obtain the front conductive silver paste for the crystalline silicon solar cell.
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