CN113571135A - Water age detection method based on parallel first-level model - Google Patents

Water age detection method based on parallel first-level model Download PDF

Info

Publication number
CN113571135A
CN113571135A CN202110609532.5A CN202110609532A CN113571135A CN 113571135 A CN113571135 A CN 113571135A CN 202110609532 A CN202110609532 A CN 202110609532A CN 113571135 A CN113571135 A CN 113571135A
Authority
CN
China
Prior art keywords
residual chlorine
water
consumption rate
chlorine
method based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110609532.5A
Other languages
Chinese (zh)
Inventor
曹玉洁
池驰
吕雪光
卫驰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Moguo Technology Co ltd
Original Assignee
Shanghai Moguo Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Moguo Technology Co ltd filed Critical Shanghai Moguo Technology Co ltd
Priority to CN202110609532.5A priority Critical patent/CN113571135A/en
Publication of CN113571135A publication Critical patent/CN113571135A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G16INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR SPECIFIC APPLICATION FIELDS
    • G16CCOMPUTATIONAL CHEMISTRY; CHEMOINFORMATICS; COMPUTATIONAL MATERIALS SCIENCE
    • G16C20/00Chemoinformatics, i.e. ICT specially adapted for the handling of physicochemical or structural data of chemical particles, elements, compounds or mixtures
    • G16C20/10Analysis or design of chemical reactions, syntheses or processes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Bioinformatics & Computational Biology (AREA)
  • Computing Systems (AREA)
  • Theoretical Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention relates to a water age detection method based on a parallel primary model, which comprises the following steps: collecting the water temperature and residual chlorine of the water outlet of the water supply and outlet equipment, and recording the collecting time; developing a three-factor orthogonal experiment according to the collected water temperature, time and residual chlorine and the initial chlorine concentration to determine the decay rate of the residual chlorine in the water outlet equipment, wherein the decay rate of the residual chlorine comprises the rapid consumption rate of the residual chlorine and the slow consumption rate of the residual chlorine; establishing an arrhenius relation model of the decay rate of the residual chlorine and the water temperature; establishing a parallel primary model according to the Arrhenius relation model to simulate the change conditions of residual chlorine and water age in the water body; and processing the parallel primary model by utilizing linear regression estimation, and performing approximate estimation on the water age of the water outlet equipment under the condition that the current residual chlorine, the initial residual chlorine and the water temperature are known. The intelligent water age detection system can realize intelligent and accurate detection of the water age of drinking water in a town water supply system.

Description

Water age detection method based on parallel first-level model
Technical Field
The invention relates to the technical field of water age detection, in particular to a water age detection method based on a parallel first-level model.
Background
Water is not only a life line of the whole national economy but also one of the basic substances on which human beings rely for survival and development. The water supply problem is one of the key problems related to the sustainable development of China. With the acceleration of the urbanization progress of China and the rapid development of national economy, the urban water supply of China enters the rapid development period, and in order to meet the basic requirements of industrial production and resident life, the water supply industry develops from the original direction of ensuring sufficient water supply and toward improving the water supply safety, improving the water quality and carrying out modern management. Various water storage devices (such as water tanks, water tanks and the like) in the urban water supply system are indispensable important facilities for guaranteeing the life, development, production and construction of urban people. As one of the urban infrastructure, the normal operation and water quality safety of the urban water supply system relate to the safety and stability of the whole society. In recent years, the water quality in the water storage facility has been increasingly considered.
Conventional methods for calculating the water age are more, for example, a large number of experiments predict the update time of water tanks in each cell to calculate the water age, but the experiment is greatly influenced by peripheral interference, and the generated result error is large and is not representative.
Disclosure of Invention
The invention aims to provide a water age detection method based on a parallel primary model, which can realize intelligent and accurate detection of the water age of drinking water in a town water supply system.
The technical scheme adopted by the invention for solving the technical problems is as follows: the water age detection method based on the parallel primary model comprises the following steps:
(1) collecting the water temperature and residual chlorine of the water outlet of the water supply and outlet equipment, and recording the collecting time;
(2) developing a three-factor orthogonal experiment according to the collected water temperature, time and residual chlorine and the initial chlorine concentration to determine the decay rate of the residual chlorine in the water outlet equipment, wherein the decay rate of the residual chlorine comprises the rapid consumption rate of the residual chlorine and the slow consumption rate of the residual chlorine;
(3) establishing an arrhenius relation model of the decay rate of the residual chlorine and the water temperature;
(4) establishing a parallel primary model according to the Arrhenius relation model to simulate the change conditions of residual chlorine and water age in the water body;
(5) and processing the parallel primary model by utilizing linear regression estimation, and performing approximate estimation on the water age of the water outlet equipment under the condition that the current residual chlorine, the initial residual chlorine and the water temperature are known.
And (3) preprocessing zero point supplement and abnormal point deletion are carried out on the collected water temperature and residual chlorine between the step (1) and the step (2).
The step (2) is specifically as follows: and calculating the residual chlorine consumption rate of each group of data in each time interval in the three-factor orthogonal experiment by adopting a difference-by-difference method, judging a rapid attenuation stage and a slow attenuation stage of the residual chlorine according to the residual chlorine consumption rate, and calculating the rapid residual chlorine consumption rate and the slow residual chlorine consumption rate by adopting an averaging method.
And (3) enhancing the decay rate of the residual chlorine and the water temperature.
The Arrhenius relationship model established in the step (3) is as follows:
Figure BDA0003095077640000021
wherein k isbfFor fast consumption rate of residual chlorine, kbsThe slow consumption rate of residual chlorine, temp. the water temperature of water outlet equipment, R is gas constant, Af=exp(nf),As=exp(ns),nfAnd nsIs a constant coefficient, Ef=-R×mfIndicating the activation energy of the fast reaction, Es=-R×msRepresents the activation energy of the slow reaction, mfAnd msIs a constant coefficient.
The parallel first-level model established in the step (4) is as follows: c ═ C0zexp(-kbft)+C0(1-z)exp(-kbst), wherein C is the residual chlorine concentration at the current moment, C0Is the initial residual chlorine concentration, z is the ratio of the chlorine consumption of the rapid reaction to the total chlorine consumption, t is time, kbfFor fast consumption rate of residual chlorine, kbsThe slow consumption rate of residual chlorine.
The linear regression estimation in the step (5) is maximum likelihood estimation or least square estimation.
Advantageous effects
Due to the adoption of the technical scheme, compared with the prior art, the invention has the following advantages and positive effects: according to the invention, based on monitoring parameters acquired by a data acquisition unit installed in water storage equipment in a water supply coverage area, orthogonal experiments are utilized to carry out research, and a relation model between the monitoring parameters and the water age is mastered, so that a water tank water age algorithm based on a parallel first-level model is built, and the intelligent and accurate detection of the water age of drinking water in a town water supply system can be realized.
Drawings
FIG. 1 is a flow chart of the present invention.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications of the present invention may be made by those skilled in the art after reading the teaching of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
The embodiment of the invention relates to a water age detection method based on a parallel primary model, which comprises the following steps: collecting the water temperature and residual chlorine of the water outlet of the water supply and outlet equipment, and recording the collecting time; developing a three-factor orthogonal experiment according to the collected water temperature, time and residual chlorine and the initial chlorine concentration to determine the decay rate of the residual chlorine in the water outlet equipment, wherein the decay rate of the residual chlorine comprises the rapid consumption rate of the residual chlorine and the slow consumption rate of the residual chlorine; establishing an arrhenius relation model of the decay rate of the residual chlorine and the water temperature; establishing a parallel primary model according to the Arrhenius relation model to simulate the change conditions of residual chlorine and water age in the water body; and processing the parallel primary model by utilizing linear regression estimation, and performing approximate estimation on the water age of the water outlet equipment under the condition that the current residual chlorine, the initial residual chlorine and the water temperature are known.
As shown in fig. 1, the method comprises the following specific steps:
step 1, installing residual chlorine detection equipment and water temperature detection equipment in an area covered by water supply equipment according to the practical application scene of the water outlet equipment in the area covered by the water supply equipment, wherein the collected parameters comprise: water temperature temp. and residual chlorine C.
Step 2, preprocessing the acquired data by adopting a data preprocessing method to complete zero supplement and abnormal point deletion in the data;
and 3, developing a three-factor orthogonal experiment according to the collected water temperature, time and residual chlorine and the initial chlorine concentration, specifically: and calculating the residual chlorine consumption rate of each group of data in each time interval in the three-factor orthogonal experiment by adopting a difference-by-difference method, judging the fast attenuation stage and the slow attenuation stage of the residual chlorine according to the magnitude value of the residual chlorine consumption rate, and calculating the fast residual chlorine consumption rate and the slow residual chlorine consumption rate by adopting an averaging method. When the fast attenuation stage and the slow attenuation stage of the residual chlorine are judged, the judgment can be realized by setting a reasonable threshold, namely when the consumption rate of the residual chlorine exceeds the threshold, the fast attenuation stage is realized, and when the consumption rate of the residual chlorine does not exceed the threshold, the slow attenuation stage is realized.
And 4, because data with larger difference is needed during initial training of the model with the residual chlorine consumption rate changing along with the temperature, in order to improve the model precision, a data enhancement technology is needed to map the original data to a high-dimensional space so as to amplify useful information and obtain high-precision processing data. The data enhancement technique needs to follow the following principles:
(1) because of multi-source signal input, the data of all signal sources need to be amplified by a uniform method;
(2) the data cannot be distorted;
(3) the amplification of the data must be within a reasonable range;
(4) the amplification is carried out in a uniform data amplification interval;
based on the principle, the data enhancement processing is carried out on the residual chlorine rapid consumption rate, the residual chlorine slow consumption rate and the water temperature data obtained after the three-factor orthogonal experiment, and the main realization process is as follows:
(1) respectively calculating the weight values of the multi-source information by adopting an entropy weight method according to the input parameters;
(2) the enhancement of the data is accomplished using the following equation:
Bij=xij/wj
in the formula: b isijObtaining an enhancement matrix; x is the number ofijThe method comprises the following steps of (1) taking elements in original data, wherein i is the row number of the original data, and j is the column number of the original data; w is ajThe weight value of each column corresponds to the original data.
The method is adopted to enhance the original data, and the smaller data is amplified to a certain height space, so that more reasonable data information can be obtained, and the establishment of a relation model between the residual chlorine consumption rate and the water temperature is conveniently completed.
Step 5, according to each group of residual chlorine fast consumption rate k after data enhancementbfSlow consumption rate kbsAnd the water temperature Temp can establish two dependent variables as lnk respectivelybfAnd lnkbsThe independent variable is
Figure BDA0003095077640000041
First order linear equation of (1):
Figure BDA0003095077640000042
in the formula: temp is the water temperature in the water tank, DEG C; m isf,nf,ms,nsIs a constant coefficient; k is a radical ofbfFor a rapid consumption rate of residual chlorine, h-1;kbsThe slow consumption rate of residual chlorine, h-1
An arrhenius (Arrhennius) relationship model for the rate of decay of residual chlorine and the water temperature temp. was determined by two first order linear equations in equation (1):
Figure BDA0003095077640000043
wherein:
Figure BDA0003095077640000044
in the formula: r is a gas constant, J/(K.mol); efActivation energy for fast reaction, kJ/mol; esActivation energy of slow reaction, kJ/mol; a. thefIs a constant independent of temperature, h-1;AsIs a constant independent of temperature, h-1
Step 6, establishing a parallel primary model to simulate the attenuation condition of the residual chlorine in the water body, wherein the model assumes that the reaction of the residual chlorine in the water body occurs at two reaction rates, namely a fast reaction rate and a slow reaction rate, and the reaction model is as follows:
C=C0zexp(-kbft)+C0(1-z)exp(-kbst) (4)
in the formula: c is the residual chlorine concentration at the current moment, mg/L; c0Initial chlorine concentration, mg/L; z is the ratio of the chlorine consumption of the rapid reaction to the total chlorine consumption; t is time, h.
And 7, processing the parallel primary model by utilizing linear regression estimation, and carrying out approximate estimation on the water age of the current water outlet equipment to the maximum extent under the condition that the current residual chlorine, the initial residual chlorine and the water temperature are known, wherein the linear regression estimation can be maximum likelihood estimation or least square estimation.
According to the invention, the relation model of the monitoring parameters and the water age is mastered by developing research through orthogonal experiments according to the monitoring parameters acquired by the data acquisition unit arranged in the water storage equipment in the water supply coverage area, so that the water age algorithm of the water tank based on the parallel first-level model is built, and the intelligent and accurate detection of the water age of the drinking water in the urban water supply system can be realized.

Claims (7)

1. A water age detection method based on a parallel first-level model is characterized by comprising the following steps:
(1) collecting the water temperature and residual chlorine of the water outlet of the water supply and outlet equipment, and recording the collecting time;
(2) developing a three-factor orthogonal experiment according to the collected water temperature, time and residual chlorine and the initial chlorine concentration to determine the decay rate of the residual chlorine in the water outlet equipment, wherein the decay rate of the residual chlorine comprises the rapid consumption rate of the residual chlorine and the slow consumption rate of the residual chlorine;
(3) establishing an arrhenius relation model of the decay rate of the residual chlorine and the water temperature;
(4) establishing a parallel primary model according to the Arrhenius relation model to simulate the change conditions of residual chlorine and water age in the water body;
(5) and processing the parallel primary model by utilizing linear regression estimation, and performing approximate estimation on the water age of the water outlet equipment under the condition that the current residual chlorine, the initial residual chlorine and the water temperature are known.
2. The water age detection method based on the parallel primary model according to claim 1, further comprising a pretreatment of zero point supplement and abnormal point deletion for the collected water temperature and residual chlorine between the step (1) and the step (2).
3. The water age detection method based on the parallel primary model according to claim 1, wherein the step (2) is specifically as follows: and calculating the residual chlorine consumption rate of each group of data in each time interval in the three-factor orthogonal experiment by adopting a difference-by-difference method, judging a rapid attenuation stage and a slow attenuation stage of the residual chlorine according to the residual chlorine consumption rate, and calculating the rapid residual chlorine consumption rate and the slow residual chlorine consumption rate by adopting an averaging method.
4. The water age detection method based on the parallel first-order model as claimed in claim 1, further comprising enhancing the decay rate of residual chlorine and the water temperature between the step (2) and the step (3).
5. The water age detection method based on the parallel primary model according to claim 1, wherein the arrhenius relationship model established in the step (3) is:
Figure FDA0003095077630000011
wherein k isbfFor fast consumption rate of residual chlorine, kbsThe slow consumption rate of residual chlorine, temp. the water temperature of water outlet equipment, R is gas constant, Af=exp(nf),As=exp(ns),nfAnd nsIs a constant coefficient, Ef=-R×mfIndicating the activation energy of the fast reaction, Es=-R×msRepresents the activation energy of the slow reaction, mfAnd msIs a constant coefficient.
6. The water age detection method based on the parallel primary model according to claim 1, wherein the parallel primary model established in the step (4) is: c ═ C0zexp(-kbft)+C0(1-z)exp(-kbst), wherein C is the residual chlorine concentration at the current moment, C0Is the initial residual chlorine concentration, z is the ratio of the chlorine consumption of the rapid reaction to the total chlorine consumption, t is time, kbfFor fast consumption rate of residual chlorine, kbsThe slow consumption rate of residual chlorine.
7. The water age detection method based on the parallel first-order model according to claim 1, wherein the linear regression estimation in the step (5) is maximum likelihood estimation or least square estimation.
CN202110609532.5A 2021-06-01 2021-06-01 Water age detection method based on parallel first-level model Pending CN113571135A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110609532.5A CN113571135A (en) 2021-06-01 2021-06-01 Water age detection method based on parallel first-level model

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110609532.5A CN113571135A (en) 2021-06-01 2021-06-01 Water age detection method based on parallel first-level model

Publications (1)

Publication Number Publication Date
CN113571135A true CN113571135A (en) 2021-10-29

Family

ID=78160981

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110609532.5A Pending CN113571135A (en) 2021-06-01 2021-06-01 Water age detection method based on parallel first-level model

Country Status (1)

Country Link
CN (1) CN113571135A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100875372B1 (en) * 2007-12-31 2008-12-22 한국수자원공사 A device for consecutive measuring residual chlorine in water distribution system
CN102707027A (en) * 2012-06-12 2012-10-03 浙江大学 Method for determining chlorine demand for rapid reaction in chlorine residual decay after chlorination

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100875372B1 (en) * 2007-12-31 2008-12-22 한국수자원공사 A device for consecutive measuring residual chlorine in water distribution system
CN102707027A (en) * 2012-06-12 2012-10-03 浙江大学 Method for determining chlorine demand for rapid reaction in chlorine residual decay after chlorination

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王旭冕: "城市供水系统水质安全性与余氯控制的研究", 《中国优秀硕士学位论文全文数据库 工程科技II辑》, pages 160 - 22 *

Similar Documents

Publication Publication Date Title
CN104376380B (en) A kind of ammonia nitrogen concentration Forecasting Methodology based on recurrence self organizing neural network
CN111291937A (en) Method for predicting quality of treated sewage based on combination of support vector classification and GRU neural network
CN104965971B (en) A kind of ammonia nitrogen concentration flexible measurement method based on fuzzy neural network
CN101630376B (en) Soft-sensing modeling method and soft meter of multi-model neural network in biological fermentation process
CN112001527B (en) Industrial production process target data prediction method of multi-feature fusion depth neural network
CN102854296A (en) Sewage-disposal soft measurement method on basis of integrated neural network
CN106249724B (en) A kind of polynary molten steel quality forecast Control Algorithm of blast furnace and system
CN105510546A (en) Intelligent biochemical oxygen demand (BOD) detection method based on self-organizing recursion radial basis function (RBF) neural network
CN103606006A (en) Sludge volume index (SVI) soft measuring method based on self-organized T-S fuzzy nerve network
CN102262147A (en) Soft measurement method and system for effluent chemical oxygen demand (COD) of waste water treatment system
CN104199389B (en) The optimization method of golden hydrometallurgy replacement process
CN108088974B (en) Soft measurement method for effluent nitrate nitrogen in anaerobic simultaneous denitrification methanogenesis process
CN110866659A (en) On-line prediction method for caustic ratio in dissolution process of high-pressure pipeline in Bayer-process alumina production
CN115169733B (en) Deep learning-based method for predicting resuspension amount of internal solitary waves on deep sea sediment
CN104951803A (en) Soft measurement method applied to dry point of aviation kerosene of atmospheric-pressure distillation tower and based on dynamic moving window LSSVM (least squares support vector machine)
CN105445344A (en) Temperature compensation method of system for detecting heavy metals in water environment
CN105320987A (en) Satellite telemetry data intelligent interpretation method based on BP neural network
CN109711435A (en) A kind of support vector machines on-Line Voltage stability monitoring method based on genetic algorithm
CN102542126A (en) Soft measurement method based on half supervision learning
CN114169242A (en) Intelligent control algorithm for analyzing ecological oxygenation of river channel based on parameter uncertainty
CN103952724B (en) For the optimization weight Relative Principal Component Analysis Algorithm of aluminium cell condition trouble diagnosis
CN106706491B (en) Intelligent detection method for membrane bioreactor-MBR water permeability
CN115371642A (en) Geological statistics inversion method for hydrogeological parameter dynamic change characteristics
CN112819087B (en) Method for detecting abnormality of BOD sensor of outlet water based on modularized neural network
CN111204867B (en) Membrane bioreactor-MBR membrane pollution intelligent decision-making method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination