CN113560767B - Welding anti-splashing agent for engineering machinery as well as preparation method and application thereof - Google Patents

Welding anti-splashing agent for engineering machinery as well as preparation method and application thereof Download PDF

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Publication number
CN113560767B
CN113560767B CN202111005422.4A CN202111005422A CN113560767B CN 113560767 B CN113560767 B CN 113560767B CN 202111005422 A CN202111005422 A CN 202111005422A CN 113560767 B CN113560767 B CN 113560767B
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welding
percent
agent
engineering machinery
splashing
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CN113560767A (en
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陈浮
黄治军
陶文哲
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Wuhan Iron and Steel Co Ltd
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Wuhan Iron and Steel Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The invention discloses a welding anti-splashing agent for engineering machinery, which comprises the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol. The anti-splashing agent is suitable for field intensive welding of engineering machinery, has the advantages of environment-friendly, safe, economical and simple contained components, easy field welding operation, good heat resistance, natural volatilization after welding, no special cleaning, no influence on the performance of a welding joint and a subsequent coating process, and contribution to improving the stability of welding arcs and the quality of welding seams.

Description

Welding anti-splashing agent for engineering machinery as well as preparation method and application thereof
Technical Field
The invention belongs to the technical field of functional materials and welding, and particularly relates to a welding anti-splashing agent for engineering machinery, and a preparation method and application thereof.
Background
With the development of engineering mechanical equipment to the directions of high strength and heavy load, welding becomes one of the most important processes in the engineering mechanical equipment, and the quality of welding is a key for influencing the operation of the engineering machinery. The on-site welding method for engineering machinery manufacturing mainly has the characteristics of manual arc welding, semi-automatic welding gas shielded welding and the like, and the distribution of welding beads is dense, intermittent, irregular and the like, and the two welding methods are also easiest to produce welding spatter which can directly influence the quality of welding seams of engineering machinery and cause obstruction to subsequent coating; and the complex postweld slag removal work is brought to operators on the welding site of the engineering machinery. How to reduce or even eliminate the adverse effects of welding spatter from the aspects of materials, equipment, processes and the like is one of the important difficulties to be solved in the welding field.
Welding spatter is mainly caused by the fact that when a short-circuit liquid bridge is contracted to be thin, the short-circuit current rapidly heats the liquid bridge, so that the liquid bridge is gasified and explodes. During the welding process, spatter is caused by metallurgical reactions, pole pressures, droplet shorts, non-axial droplet transitions, and mismatching of welding parameters. The splashing can seriously affect the appearance quality of welding, occupy a large amount of grinding time, damage the welding tool and cause adverse effects on the follow-up flaw detection process, coating process and quality. The traditional method for eliminating the spatter on the welding site mainly relies on manual polishing, and a hand-held grinder is adopted to polish the spatter on the surface of the pipeline. The operation environment is bad for operators, the operation environment is heavy, the operators are also faced with the invasion of a large amount of metal dust, the metal dust is reserved on a construction site, and the environment is damaged to different degrees. Moreover, the quality of manual polishing cannot be guaranteed, damage to the surface of the machine can be caused by improper operation, the subsequent coating is adversely affected, and potential safety hazards can be seriously brought to the operation of engineering machinery.
In recent years, a plurality of welding anti-splashing agents are also appeared, such as a patent of 'a welding anti-splashing agent for alloy steel plates and a preparation method thereof', and CN104057215A discloses a welding anti-splashing agent for galvanized steel plates and a preparation method thereof, which are characterized in that the original welding process and mechanical properties are not changed, and a non-splashing effect is achieved. However, the invention belongs to oil-based type, uses mechanical oil as an organic solvent, is not easy to remove in site operation after being coated on the surface of a workpiece, can possibly influence the subsequent coating pretreatment, and contains lead and toluene substances harmful to human bodies. And the components are more, the process is complex, and the use cost is high. The patent "welding anti-spatter liquid", CN101386716a discloses a welding anti-spatter liquid which prevents a welding ball formed by spatter from adhering to a welded product during welding, and has good cleanability, but a large amount of gas is generated during the use of the welding anti-spatter liquid, especially in a welding area, and the probability of occurrence of air hole defects of a welding line is increased.
Therefore, the anti-splashing agent which is economical and environment-friendly and is suitable for the field intensive welding of engineering machinery is further explored and optimized, and has important research and application significance.
Disclosure of Invention
The invention mainly aims at overcoming the defects of the prior art, provides the anti-splashing agent suitable for the field intensive welding of the engineering machinery, has the advantages of environment-friendly, safe, economical and simple contained components, easy field welding operation, good heat resistance, natural volatilization after the welding is finished, no special cleaning, no influence on the performance of a welding joint and the subsequent coating process, and contribution to improving the stability of welding arcs and the quality of welding seams.
In order to realize the scheme, the invention adopts the following technical scheme:
the welding anti-splashing agent for engineering machinery comprises the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol.
In the above embodiment, the particle diameter of the titanium dioxide is 10 to 45. Mu.m.
In the scheme, the nonionic surfactant is octyl phenol polyoxyethylene ether, wherein the number n of ethoxy units is 7-30.
In the above scheme, the monohydric alcohol is one or more of n-butanol, isobutanol and neopentyl alcohol.
The preparation method of the welding anti-splashing agent for engineering machinery comprises the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials comprise the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol;
2) And uniformly mixing the weighed raw materials to obtain the welding anti-splashing agent.
The invention also provides a preparation method of the powdery welding anti-splashing agent of the engineering machinery, which comprises the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials comprise the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol;
2) Mixing the weighed raw materials uniformly, heating, drying and grinding to obtain powdery particles.
In the above scheme, the grinding condition is grinding to 3000 mesh.
In the above scheme, the heating temperature is 100-400 ℃.
The application method of the powder welding anti-splashing agent for the engineering machinery comprises the following steps:
1) When the welding spot is used, the welding anti-splashing agent which is directly prepared or the powder welding anti-splashing agent and water are mixed in proportion to obtain uniform mixed liquid which is used as the welding anti-splashing liquid;
2) And spraying the welding anti-splashing liquid to a welding area and a welding groove part to perform welding construction.
In the scheme, the volume ratio of the powder welding anti-splashing agent to the water is (25-30) 70.
Preferably, the obtained welding anti-splashing liquid is further coated inside and outside a conductive nozzle and a spray pipe of the gas protection welding gun, so that the welding gun can be effectively prevented from being blocked by splashing.
The principle of the invention is as follows:
the anti-splashing agent for the on-site welding of the engineering machinery has a simple and harmless formula, and can play a role in protecting welding beads and welding guns from splashing: one of the main components of magnesium carbonate can play a role of stabilizing an electric arc and refining metal splash particles, high-content titanium dioxide has the functions of stabilizing an arc, isolating and cooling a protection surface, a nonionic surfactant has good solubility and heat stability, and has excellent film forming property, corrosion resistance and oxidation resistance, and monohydric alcohol mainly plays the roles of film forming, drying and dissolution assisting. The anti-splashing agent disclosed by the invention does not contain harmful components to human bodies and environment, is simple and easy to obtain, and is convenient to use.
Compared with the prior art, the invention has the beneficial effects that:
1) The welding spatter-preventing agent has extremely low welding spatter residual rate on the surfaces of the welding area and the base metal near the welding seam, can effectively reduce the harm caused by the welding spatter on the welding area and the base metal near the welding area, and improves the structural safety of engineering machinery;
2) The components are environment-friendly, simple, economical and practical, have good heat resistance and timeliness, and extremely low welding dust emission, and cannot cause harm to human bodies and surrounding environments.
3) The welding anti-splashing agent is neutral, does not corrode a welding structure and does not influence the subsequent coating process; the welding structure can effectively ensure the usability of the welding structure such as mechanical property and the like, and effectively prevent the extra welding defects such as air holes, slag inclusion and the like.
4) The welding anti-splashing agent has a simple use method and is convenient for on-site transportation operation; the gas protection welding gun can also play roles in preventing welding spatter from blocking a welding nozzle and the like, so that the ventilation and wire passing of the welding gun are ensured, the stability of a welding arc is improved, and the quality of a welding seam is ensured; the slag removal work of on-site operators can be omitted, the manufacturing labor and time cost is obviously reduced, and the welding production efficiency is improved.
Detailed Description
The present invention will be described in further detail with reference to the following examples in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
In the following examples, the particle size of the titanium dioxide used was 10 to 45. Mu.m.
Example 1
A powder welding anti-splashing agent for engineering machinery, a preparation method and an application method thereof comprise the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials and the mass percentages thereof are as follows: 7.5% of magnesium carbonate, 11% of titanium dioxide, 10% of nonionic surfactant (octyl phenol polyoxyethylene ether, n=30% of ethoxy unit number) and the balance of n-butanol;
2) Uniformly mixing the weighed raw materials to obtain the welding anti-splashing agent;
3) The welding can be performed by using a common spray can or directly brushing the welding area and the range of 50mm on both sides of the welding area; simultaneously, the paint is smeared in a conductive nozzle and a spray pipe of the gas protection welding gun;
wherein, the welding process selects Q345 steel plates with the specification of 500mm multiplied by 400mm multiplied by 20mm, the welding groove is 60 degrees and V-shaped, the multi-layer and multi-channel welding is carried out by adopting a gas shielded welding method, the welding current is 240 to 290A, the arc voltage is 26 to 33V, and the other parameters are operated according to the conventional method; after the first welding, the welding spatter particles with the diameter of 3mm from extremely small can be removed by a steel brush; after 1 hour interval, a second welding process is performed, and all splash particles can be cleaned; after the continuous welding is finished, all splash particles can be removed.
The welding process has stable electric arc, no defect in welding, and no welding spatter exists inside and outside the welding gun conducting nozzle and the spray pipe after welding. The slag remover has extremely low splashing residual rate, good timeliness and high temperature resistance. After the steel plate is placed for 24 hours, the welding test plate coating slag remover area has no rust phenomenon, and the welding joint is subjected to a tensile bending impact test, so that the steel plate welding technical requirements are met.
Example 2
A powder welding anti-splashing agent for engineering machinery, a preparation method and an application method thereof comprise the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials and the mass percentages thereof are as follows: 25% of magnesium carbonate, 22% of titanium dioxide, 30% of nonionic surfactant (octyl phenol polyoxyethylene ether, n=7 of ethoxy unit number) and the balance of isobutanol;
2) Uniformly mixing the weighed raw materials to obtain the welding anti-splashing agent;
3) And (3) using a common spray can or directly brushing the welding area and the two sides of the welding area within 50mm, and welding. Simultaneously, the paint is smeared in a conductive nozzle and a spray pipe of the gas protection welding gun;
wherein, the welding process selects Q550 steel plates with the specification of 500mm multiplied by 400mm multiplied by 20mm, the welding groove is 60 degrees and V-shaped, the manual electrode welding method is adopted for multi-layer and multi-channel welding, the welding current is 150 to 180A, the arc voltage is 22 to 24V, and the other parameters are operated according to the conventional method; after the first welding, the welding spatter particles with the diameter of 3mm from extremely small can be removed by a steel brush; and (3) after 1 hour of interval, welding for the second time, and cleaning all splash particles. After the continuous welding is finished, all splash particles can be removed.
The welding process has stable electric arc, no defect in welding, and no welding spatter exists inside and outside the welding gun conducting nozzle and the spray pipe after welding. The slag remover has extremely low splashing residual rate, good timeliness and high temperature resistance. After the steel plate is placed for 24 hours, the welding test plate coating slag remover area has no rust phenomenon, and the welding joint is subjected to a tensile bending impact test, so that the steel plate welding technical requirements are met.
Example 3
A powder welding anti-splashing agent for engineering machinery, a preparation method and an application method thereof comprise the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials and the mass percentages thereof are as follows: 15% of magnesium carbonate, 17% of titanium dioxide, 20% of nonionic surfactant (octyl phenol polyoxyethylene ether, n=15 of ethoxy unit number) and the balance of neopentyl alcohol;
2) Uniformly mixing the weighed raw materials to obtain the welding anti-splashing agent;
3) And (3) using a common spray can or directly brushing the welding area and the two sides of the welding area within 50mm, and welding. Simultaneously, the paint is smeared in a conductive nozzle and a spray pipe of the gas protection welding gun;
wherein, the welding process selects Q460 steel plates with the specification of 500mm multiplied by 400mm multiplied by 20mm, the welding groove is 60 degrees and V-shaped, the multi-layer and multi-channel welding is performed by adopting a gas shielded welding method, the welding current is 270 to 330A, the arc voltage is 27 to 34V, and the rest parameters are operated according to the conventional method. After the first welding, the welding spatter particles with the diameter of 3mm from extremely small can be removed by a steel brush. And (3) after 1 hour of interval, welding for the second time, and cleaning all splash particles. After the continuous welding is finished, all splash particles can be removed.
The welding process has stable electric arc, no defect in welding, and no welding spatter exists inside and outside the welding gun conducting nozzle and the spray pipe after welding. The slag remover has extremely low splashing residual rate, good timeliness and high temperature resistance. After the steel plate is placed for 24 hours, the welding test plate coating slag remover area has no rust phenomenon, and the welding joint is subjected to a tensile bending impact test, so that the steel plate welding technical requirements are met.
The above examples are presented for clarity of illustration only and are not limiting of the embodiments. Other variations and modifications of the above description will be apparent to those of ordinary skill in the art, and it is not necessary or exhaustive of all embodiments, and thus all obvious variations or modifications that come within the scope of the invention are desired to be protected.

Claims (4)

1. The welding anti-splashing agent for engineering machinery is characterized by comprising the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol;
the nonionic surfactant is octyl phenol polyoxyethylene ether, wherein the number n of ethoxy units is 7-30;
the monohydric alcohol is one or more of n-butanol, isobutanol and neopentyl alcohol.
2. The welding spatter preventing agent according to claim 1, wherein the particle diameter of the titanium dioxide is 10 to 45 μm.
3. The method for preparing the welding anti-spattering agent for engineering machinery according to any one of claims 1 to 2, which is characterized by comprising the following steps:
1) Weighing the raw materials according to the proportion, wherein the raw materials comprise the following components in percentage by mass: 7.5 to 25 percent of magnesium carbonate, 11 to 22 percent of titanium dioxide, 10 to 30 percent of nonionic surfactant and the balance of monohydric alcohol;
2) And uniformly mixing the weighed raw materials to obtain the welding anti-splashing agent.
4. The application method of the welding anti-spattering agent for the engineering machinery is characterized by comprising the following steps of:
1) When the anti-spattering agent is used on a welding site, the anti-spattering agent is directly prepared into the anti-spattering liquid for welding according to any one of claims 1-2;
2) And spraying the welding anti-splashing liquid to a welding area and a welding groove part to perform welding construction.
CN202111005422.4A 2021-08-30 2021-08-30 Welding anti-splashing agent for engineering machinery as well as preparation method and application thereof Active CN113560767B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481964A (en) * 2003-07-29 2004-03-17 沪东中华造船(集团)有限公司 Weld anti-spatter compound
JP2010274273A (en) * 2009-05-26 2010-12-09 Taseto:Kk Sputter adhesion prevention agent
CN107414344A (en) * 2017-08-02 2017-12-01 合肥安力电力工程有限公司 A kind of splash-proof welding agent for alloy-steel plate and preparation method thereof
CN109773371A (en) * 2019-02-25 2019-05-21 浙江华东科技检测有限公司 A kind of novel welding anti sling liquid, preparation method and application method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481964A (en) * 2003-07-29 2004-03-17 沪东中华造船(集团)有限公司 Weld anti-spatter compound
JP2010274273A (en) * 2009-05-26 2010-12-09 Taseto:Kk Sputter adhesion prevention agent
CN107414344A (en) * 2017-08-02 2017-12-01 合肥安力电力工程有限公司 A kind of splash-proof welding agent for alloy-steel plate and preparation method thereof
CN109773371A (en) * 2019-02-25 2019-05-21 浙江华东科技检测有限公司 A kind of novel welding anti sling liquid, preparation method and application method

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