CN113552212B - Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof - Google Patents
Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof Download PDFInfo
- Publication number
- CN113552212B CN113552212B CN202110696021.1A CN202110696021A CN113552212B CN 113552212 B CN113552212 B CN 113552212B CN 202110696021 A CN202110696021 A CN 202110696021A CN 113552212 B CN113552212 B CN 113552212B
- Authority
- CN
- China
- Prior art keywords
- tuning fork
- cylindrical barrel
- gas
- radial
- photoacoustic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N29/00—Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
- G01N29/02—Analysing fluids
- G01N29/022—Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/1702—Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N29/00—Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
- G01N29/22—Details, e.g. general constructional or apparatus details
- G01N29/24—Probes
- G01N29/2418—Probes using optoacoustic interaction with the material, e.g. laser radiation, photoacoustics
- G01N29/2425—Probes using optoacoustic interaction with the material, e.g. laser radiation, photoacoustics optoacoustic fluid cells therefor
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/1702—Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids
- G01N2021/1704—Systems in which incident light is modified in accordance with the properties of the material investigated with opto-acoustic detection, e.g. for gases or analysing solids in gases
Abstract
The invention relates to a photoacoustic spectroscopy sounder, which comprises: a cylindrical barrel having a central axis and a line of symmetry perpendicular to the central axis; the incident window is arranged at the inlet end of the cylindrical barrel; a light-transmitting exit window arranged at the outlet end of the cylindrical barrel; the air inlet and outlet are arranged on the outer wall of the cylindrical barrel; a radial cavity air chamber enclosed between the entrance and exit windows; and fixing the quartz tuning fork arranged in the radial cavity air chamber, so that the symmetry line of the cylindrical barrel penetrates into the quartz tuning fork base along the middle of the gap between the two fork arms of the quartz tuning fork, and the central axis of the cylindrical barrel vertically passes through the gap between the two fork arms of the quartz tuning fork. Still relate to a gas detection device, include foretell optoacoustic spectroscopy sound detector. The radial resonance mode adopted by the invention has low requirement on the length of the resonance cavity, so that the beam collimation is more convenient; the output signal is greatly enhanced in a strong radial resonance mode; and the radial cavity can be used as a resonant cavity and an air chamber at the same time, so that the structure is simplified and the volume is reduced.
Description
Technical Field
The invention relates to a gas sensing technology, in particular to a radial cavity quartz enhanced photoacoustic spectroscopy (RC-QEPAS) sound detector and a gas detection device adopting the sound detector.
Background
Photoacoustic spectrometry (PAS) is a zero background optical gas sensing technology with the advantages of high sensitivity, high selectivity and large dynamic range. The principle of PAS is that gas molecules undergo a non-radiative transition after being irradiated with laser light to generate a local pressure. If the laser is modulated, the resulting local pressure will vary periodically, creating an acoustic wave. Compared with other laser absorption spectrums, the photoacoustic spectrum has the biggest characteristic of not depending on the length of a light propagation path, allowing the absorption path length to be short in a sample with a small volume, and the concentration response to be highly linear. As a variation of PAS, quartz enhanced photoacoustic spectroscopy (QEPAS) technology has developed rapidly since its invention in 2002. In QEPAS, a strongly resonant Quartz Tuning Fork (QTF) with piezoelectric properties is used as a transducer to convert acoustic signals into electrical signals. Because QTF has the advantage of with low costs, small, high Q value, QEPAS sensor is compacter than traditional optoacoustic spectrum sensor, has stronger noise immunity ability. Thanks to these advantages of QEPAS, it is widely cited in atmospheric pollutants monitoring, agriculture and industry, and medical diagnostic process control. In recent years, QEPAS has been applied to monitoring nitric oxide and methane in automotive emissions to atmospheric gases.
To improve the performance of the QEPAS sensor, a miniature acoustic resonator (AmR) is used to create acoustic resonances to enhance acoustic signals, such as for on-axis quartz-enhanced photoacoustic spectroscopy (on-beam QEPAS) devices, off-axis quartz-enhanced photoacoustic spectroscopy (off-beam QEPAS) devices, and their variants. To date, all of these QEPAS devices are based on axial resonance, which requires that the length of the resonant cavity be much greater than its diameter. In QEPAS, the laser beam typically needs to pass through a gap of about 300 μm between the two arms of the tuning fork and one or more thin tubes of several hundred microns in diameter and about 9cm or more in total length. The cavity must be placed precisely at a distance of about a few hundred microns from the tuning fork plane to obtain a strong coupling. The QEPAS signal is inversely proportional to the QTF resonance frequency, which performs better at low resonance frequencies when the relaxation rate of the gas molecules is low. But a low resonance frequency results in a longer resonant cavity. In this case, especially when a long wavelength light source such as a quantum cascade laser and a THz light source is used, the difficulty of beam collimation is greater.
Disclosure of Invention
The invention provides a quartz reinforced photoacoustic spectrometry acoustic detector with a radial cavity and a gas detection device adopting the acoustic detector, and aims to at least solve the technical problems that in the prior art, light beams in a QEPAS (quantum optical fiber array) in the current one-dimensional axial resonance mode are difficult to collimate, the requirement on the building precision of a resonant cavity is high, and the like.
The technical scheme of the invention relates to a photoacoustic spectrometry sound detector, which comprises: a cylindrical barrel having a central axis and a line of symmetry perpendicular to the central axis; a light-transmissive entrance window disposed at an entrance end of the cylindrical barrel; the light-transmitting emergent window is arranged at the outlet end of the cylindrical barrel; a gas inlet and a gas outlet provided at an outer wall of the cylindrical barrel, wherein preferably the gas inlet and the gas outlet may be symmetrically arranged with respect to the symmetry line; a radial cavity air chamber enclosed between the incident window and the exit window, the radial cavity air chamber being communicated with the air inlet and the air outlet; and a quartz tuning fork fixedly arranged in the radial cavity air chamber, so that the symmetry line of the cylindrical barrel penetrates into the quartz tuning fork base along the middle of the gap between the two fork arms of the quartz tuning fork, and the central axis of the cylindrical barrel vertically passes through the gap between the two fork arms of the quartz tuning fork.
Further, the incident window and the exit window are made of a high-transmittance material sheet of near-infrared light; the included angles between the incident window and the exit window and the symmetry line of the cylindrical barrel are respectively 4-6 degrees, and preferably 5 degrees.
Further, the quartz tuning fork is a strong resonance type quartz tuning fork with a standard size; the cavity radius size of the radial cavity air chamber of the cylindrical barrel is 6mm to 6.6mm; the chamber length dimension of the radial chamber air chamber of the cylinder is 6.5mm to 7.5mm.
Further, the cavity radius size of the radial cavity air chamber of the cylindrical barrel is 6.4mm; the chamber length dimension of the radial chamber air chamber of the cylinder is 6.9mm.
Further, the cylinder is connected with the cylinders of the air inlet and the air outlet through threaded holes.
Further, the cylinder is composed of an aluminum alloy material.
The technical scheme of the invention also relates to a gas detection device which comprises the photoacoustic spectrum sound measurer.
Further, the gas detection device further comprises: a function generator; the driving board is connected with a modulation signal output end of the function generator; a laser driven by the drive plate; a lens group arranged in an emergent light path of the laser, wherein the photoacoustic spectrum sound detector is positioned in the emergent light path of the lens group; the power meter is positioned on an emergent light path of a radial cavity gas chamber of the photoacoustic spectrum sound measurer; the ground wire is connected with a first pin of a quartz tuning fork of the photoacoustic spectrum sound measurer; the preamplifier is connected with a second pin of the quartz tuning fork of the photoacoustic spectrum sound measurer; the phase-locked amplifier is connected with the output end of the preamplifier and is connected with the synchronous signal output end of the function generator; a computing device having a data acquisition card connected to an output of the lock-in amplifier and an output of the power meter.
Further, the gas detection device further comprises: the mechanical pump is connected to the gas outlet of the photoacoustic spectrometry sound detector through a gas flow control valve; pressure gauge and filter core, the filter core passes through the pressure gauge and is connected to the air inlet of optoacoustic spectroscopy sound detector, wherein, works as gas flow control valve makes mechanical pump work and intercommunication during the gas outlet, the gas that is surveyed is got into through the filter core after getting rid of impurity the air inlet radial chamber air chamber to the atmospheric pressure of whole gas circuit is measured by the pressure gauge.
The technical scheme of the invention also relates to a gas detection method, which comprises the following steps:
A. triggering a laser to generate a light path in a resonant cavity, modulating the working current of the laser by using the natural frequency of a quartz tuning fork, enabling the wavelength of output light of the laser to sweep a target gas absorption line, and then modulating the depth of the working current of the laser until output acousto-optic signals between pins of the quartz tuning fork reach a preset amplitude;
B. when target gas in the photoacoustic spectrometry sound detector is excited by laser, acquiring an electric signal between pins of the quartz tuning fork, and converting and storing the electric signal into a photoacoustic signal count value after signal amplification processing of a front-end and a phase lock;
C. and calculating the target gas concentration value corresponding to the current photoacoustic signal count value according to the linear relation between the preset calibrated photoacoustic signal count value and the target gas concentration.
The invention has the beneficial effects that:
1. the radial resonance mode adopted by the photoacoustic spectroscopic sound measurer has low requirement on the length of the resonance cavity, so that the light beam is more convenient to collimate;
2. the photoacoustic spectrometry sound detector greatly enhances the QEPAS signal in a strong radial resonance mode, thereby improving the signal-to-noise ratio of an output signal;
3. the radial cavity can act as both a resonant cavity and a gas cell, which simplifies the construction of the sensor and reduces the volume of the gas sample.
Drawings
Fig. 1 is a perspective view of a photoacoustic spectrometry sound measurer according to an embodiment of the present invention, in which a window part is displayed in transparency.
Figure 2 is a cross-sectional view of a photoacoustic spectroscopy microphone in an embodiment in accordance with the present invention.
FIG. 3a is a simulation graph of sound pressure distribution in a photoacoustic spectroscopy microphone based on RC-QEPAS.
Fig. 3b is a graph of sound pressure level versus distance d from the central axis in simulation verification of the photoacoustic spectroscopy sounder.
Fig. 3c is a graph of the sound pressure level versus the cavity radius R in a simulation verification of a photoacoustic spectroscopy sounder.
Fig. 3d is a graph of the relationship between the sound pressure level and the cavity length L in simulation verification of the photoacoustic spectroscopy sounder.
Fig. 4 is a block diagram of a gas detection apparatus according to an embodiment of the present invention.
FIG. 5 is a graph of resonance curves of a bare tuning fork and RC-QEPAS.
FIG. 6 is a graph of the second harmonic signal of a bare tuning fork and RC-QEPAS.
Detailed Description
The conception, the specific structure and the technical effects of the present invention will be clearly and completely described in conjunction with the embodiments and the accompanying drawings to fully understand the objects, the schemes and the effects of the present invention.
It should be noted that, unless otherwise specified, when a feature is referred to as being "fixed" or "connected" to another feature, it may be directly fixed or connected to the other feature or indirectly fixed or connected to the other feature. Furthermore, unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art. The terminology used in the description herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Referring to fig. 1 and 2, in some embodiments, a photoacoustic spectroscopy microphone 5 according to the present invention comprises: a cylindrical barrel 50, a quartz tuning fork 55 arranged within a radial cavity gas chamber 56 of the cylindrical barrel 50, an entrance window 51 and an exit window 52. The outer wall of the cylindrical barrel 50 is also provided with an air inlet 53 and an air outlet 54. In these embodiments, the cylindrical drum 50 is defined to have a central axis (A1) and a line of symmetry (A2) perpendicular to the central axis (A1).
Preferably, the present invention employs a cylindrical aluminum can 50 of comparable diameter to length for ease of machining and precision. The quartz tuning fork 55 is a standard sized, strongly resonant quartz tuning fork 55 (QTF) using a tuning fork with a resonant frequency of 32768 Hz. Wherein, the width, the thickness and the gap of the QTF vibrating arm are respectively 600 μm,330 μm and 300 μm.
The propagation direction of the laser Light (LA) of the central axis (A1) shown in fig. 1 is a direction from left to right shown in fig. 2. Wherein, the incident window 51 is provided at the entrance end of the Laser (LA) of the cylindrical drum 50; an exit window 52 is provided at the exit end of the Laser (LA) from the cylindrical barrel 50. The air inlet 53 and the air outlet 54 are arranged symmetrically with respect to the line of symmetry (A2). The entrance window 51 and the exit window 52 are made of a highly transparent material (e.g., caF) for near infrared light 2 ) Is made of the sheet of (1). Preferably, the entrance window 51 and the exit window 52 are obliquely installed to face each other so as to be at an angle of 4 ° to 6 °, more preferably about 5 °, to the line of symmetry (A2) of the cylindrical drum 50, respectively. The obliquely installed entrance window 51 and exit window 52 can avoid the laser(LA) the effect of interference phenomena occurs as the window passes through.
The radial chamber plenum 56 communicates with the inlet port 53 and the outlet port 54 by a radial chamber plenum 56 (also referred to as a micro plenum) in the enclosed space between the entrance window 51 and the exit window 52. By "radial" air chambers is understood air chambers which are radially distributed perpendicular to the central axis. The quartz tuning fork 55 is fixedly arranged in the radial cavity air chamber 56 such that the symmetry line (A2) of the cylindrical barrel 50 penetrates into the quartz tuning fork 55 seat along the middle of the gap between the two prongs of the quartz tuning fork 55, and the central axis (A1) of the cylindrical barrel 50 vertically passes through the gap between the two prongs of the quartz tuning fork 55. Therefore, the symmetrical and vertical geometric relationship in this embodiment facilitates the laser alignment operation. In addition, the cylindrical tube 50 may be coupled with the columns of the air inlet 53 and the air outlet 54 through screw holes in consideration of convenience of machining.
In further embodiments, the optimal size of the radial cavity plenum 56 may be calculated in the following manner. It should be understood that the size of the optimized design in the present invention is not simply obtained by limited experiments, but is obtained by the creative labor calculation, and the reason and process are also illustrated by the following calculation mode and simulation.
First, the sound pressure in the photoacoustic cell of the radial chamber gas cell 56 can be described by equation (1):
where c is the speed of sound, γ is the adiabatic coefficient, and H is the intensity of the heat source. The eigen-resonance modes in the photoacoustic cell are determined by a homogeneous wave equation and boundary conditions as follows:
where L and R are the length and radius of the radial cavity, respectively, as shown in fig. 2 and 3 a. m, n, and i are indices of eigenvalues of the azimuthal mode, axial mode, and radial mode, respectively. The resonance frequency of a lossless cylindrical resonator is expressed as:
in the formula of alpha mi Is the ith zero (in pi) of the first derivative of the bezier function of order m. All QEPAS resonators in the prior art are based on a one-dimensional axial resonance mode, and the mni index corresponds to the (0,1,0) mode. The first order radial mode, i.e., the (0,0,1) mode, is used in embodiments of the present invention. Also used in this embodiment is a resonant frequency of 32768Hz, i.e. the first radial resonant frequency f of the radial cavity 001 Standard quartz tuning fork 55. Therefore, the dimensions R and L of the radial cavity can be solved by equation (3), while in combination with the boundary conditions of equation (2), a larger sound pressure level result is obtained. The cavity radius size of the radial cavity air chamber 56 of the cylindrical barrel 50 is 6mm to 6.6mm, preferably 6.4mm through theoretical calculation; the radial chamber plenum 56 of the cylindrical drum 50 has a chamber length dimension of 6.5mm to 7.5mm, preferably 6.9mm.
Then, the sound pressure distribution in the radial cavity quartz enhanced photoacoustic spectrometry sounder according to the present invention can be simulated by finite element simulation. Wherein the width, thickness and gap of the QTF vibrating arm are respectively set to be 600 μm,330 μm and 300 μm. The radius and length of the radial cavity are set to 6.4mm and 6.9mm, respectively. A pressure acoustic module is used. The walls of the radial cavity and the surface of the QTF are set as hard soundfield boundaries. It is assumed that a cylindrical monopole domain source with a frequency of 32768Hz is used as the sound source. The material is air, and the sound velocity in the air at room temperature is 343m/s.
The sound pressure distribution in the radial cavity obtained is shown in figure 3 a. The sound pressure is greatest at a distance d =0mm from the central axis (> 16 dB), becomes smaller as d increases and falls to 0 where d is about 4 mm. As d continues to increase, the sound pressure increases in an opposite phase, as shown in fig. 3a and 3 b.
Furthermore, the effect of the radius and length of the radial cavity on the sound pressure distribution has also been analyzed. Fig. 3c depicts the sound pressure level versus radial cavity radius between the two arms of the QTF. Since the sound velocity in air at room temperature was 343m/s and the resonance frequency was determined to be 32768Hz, a sound pressure level in the range of the cavity radius from 6mm to 6.6mm was simulated. The peak reached 16.60dB at a radius of 6.4 mm. The full width at half maximum is 0.0159mm, corresponding to a Q value of about 400. The optimized cavity radius was set to 6.4mm and the sound pressure level versus cavity length is shown in figure 3 c. The sound pressure level between the two arms of the QTF increases from-1.98 dB to 16.60dB as L increases from 6.5mm to 6.9mm. When L exceeds 6.9mm, the sound pressure starts to decrease. The optimal cavity radius of 6.4mm and cavity length of 6.9mm were obtained, consistent with the theoretical calculations in the above example.
Therefore, compared with the conventional photoacoustic spectrometry acoustic detector 5, in which the QEPAS resonant cavities all adopt a one-dimensional axial resonance mode (the photoacoustic spectrometry acoustic detector 5 needs to adopt a slender stainless steel tube as an acoustic resonant cavity, which is not beneficial to the collimation of light beams and has high accuracy requirement for installation), the present invention adopts a radial resonance mode, and adopts a cylindrical cavity with radial resonance as an acoustic resonant cavity and an air chamber, so that the acoustic signals can be significantly enhanced by using the radial resonance, and the structure of the whole photoacoustic spectrometry acoustic detector can be made more compact as well as the volume of the air chamber becomes smaller.
Referring to fig. 4, in an embodiment according to the present invention, a gas detection apparatus using the sound meter includes a function generator 1, a drive plate 2, a laser 3, a lens group 4, a spectrum sound meter 5 of the above embodiment, a power meter 6, a mechanical pump 7, a gas flow control valve 8, a pressure gauge 9, a filter element 10, a preamplifier 14, a lock-in amplifier 15, and a computing device 16 with a data acquisition card.
The first pin 12 of the quartz tuning fork 55 of the spectroscopic sonographer 5 is connected to ground 11. The modulation signal output end of the function generator 1 is connected with a laser driving board 2. The laser driving board 2 drives the DFB laser 3. And a lens group 4, a collimator and a spectrum sound detector 5 are arranged on an emergent light path of the DFB laser 3. The second leg 13 of the quartz tuning fork 55 is connected to a lock-in amplifier 15 via a preamplifier 14. The computer device 16 is provided with a data acquisition card. The signal output terminal of the lock-in amplifier 15 is connected to a signal input terminal of the data acquisition card. The signal output end of the data acquisition card is connected with the signal input end of the computer. The synchronizing signal output of the function generator 1 is connected to the synchronizing signal input of the lock-in amplifier 15. And a power meter 6 is arranged on an emergent light path of the radial cavity air chamber 56. The signal output end of the power meter 6 is connected with the other signal input end of the data acquisition card. The power meter 6 is placed at the exit window 52 of the spectral sounder to detect the power of the exiting light.
A modulation frequency f of the function generator 1 0 Is sent to the laser driving board 2, and the laser driving board 2 can adjust and control the injection current and the temperature of the laser 3. The emission center wavelength of the laser 3 corresponds to the target absorption line of the gas to be measured. The light emitted from the laser 3 is optically shaped by the lens 4 and enters the spectral sounder 5, as shown in fig. 1. Collimated light beam first passes through CaF 2 The finished entrance window 51 then enters a quartz tuning fork 55. The light beam emitted from the quartz tuning fork 55 passes through the micro air cell 56 and then exits through the exit window 52. The light emitted from the exit window 52 enters the power meter 6, and power detection is performed thereon. The micro air chamber 56 has an inlet 53 and an outlet 54 to ensure that the gas to be measured can smoothly enter the micro air chamber 56, and the gas is uniformly mixed in the micro air chamber 56 during measurement. The outlet 54 is connected to a mechanical pump 7 with a gas flow control valve 8, and the inlet 53 is in turn connected to a pressure gauge 9 and to the filter cartridge 10. When the mechanical pump 7 works, external air is sucked into the micro air chamber 56 after impurities are removed through the filter element 10, the pressure of the whole air path is measured by the pressure gauge 9, and the air flow rate is controlled by the air flow control valve 8. The exciting light emitted by the laser 3 excites the gas to be measured to generate sound waves, and the sound waves push the tuning fork to vibrate to generate an electric signal which is output by the pin 13. The electrical signal is first amplified and processed by a preamplifier 14, and then sent to a lock-in amplifier 15 for second harmonic demodulation. The reference signal demodulated by the lock-in amplifier 15 comes from the synchronous port of the function generator 1. The signals demodulated by the lock-in are sent to a computer device 16 with a data acquisition card to acquire and record the data. In addition, the concentration of the gas to be measured can be displayed on a mobile computer in real time and on line, and the system has the functions of high precision, strong portability and on-line monitoring.
Therefore, when detecting a constant amount of gas, a target detection line close to the center wavelength of the light source is selected. The laser 3 temperature is locked in by the temperature control circuit of the DFB laser 3 and the wavelength of the laser 3 is swept across the target absorption line by controlling the drive current. Specifically, with the second harmonic detection technique, the current of the laser 3 is frequency modulated by an f/2 signal generated by the function generator 1, where f is the resonant frequency of the tuning fork used. After the gas to be detected is excited by laser, the acoustic wave signal generated by de-excitation is collected by QTF and converted into corresponding electric signal. The electrical signal passes through a preamplifier 14, is locked and amplified in sequence, and then enters a system of computer equipment through a data acquisition card. After the data is calculated by software, the gas concentration information is finally displayed on a screen through a human-computer interactive interface. When a certain gas is measured, calibration is carried out in advance through a standard gas with known concentration, and the calibrated gas can be measured by the calibrated device. In one embodiment, the gas detection method according to the present invention comprises the steps of: A. triggering a laser to generate a light path in a resonant cavity, modulating the working current of the laser by using the natural frequency of a quartz tuning fork, enabling the wavelength of output light of the laser to sweep a target gas absorption line, and then modulating the depth of the working current of the laser until output acousto-optic signals between pins of the quartz tuning fork reach a preset amplitude; B. when target gas in the photoacoustic spectrometry sound detector is excited by laser, acquiring electric signals between pins of a quartz tuning fork, and converting and storing the electric signals into photoacoustic signal count values after signal amplification processing of a front-end and a phase lock; C. and calculating the target gas concentration value corresponding to the current photoacoustic signal count value according to the linear relation between the preset photoacoustic signal count value and the target gas concentration.
In a more specific embodiment, the gas detection apparatus using the sound meter according to the present invention operates as follows.
First, a 1.39 μm near infrared fiber coupled Distributed Feedback (DFB) semiconductor laser 3 was used as the excitation source. The high precision semiconductor laser driver board 2 is then used to control the temperature and injection current of the semiconductor laser 3. Second harmonic wavelength modulation techniques are used to improve the detection sensitivity of QEPAS. Using a signal generator to generate the cycleTriangular wave with period of 400s and frequency f 0 Sine wave of/2 (f) 0 The resonant frequency of the spectral sounder). Second harmonic wavelength modulation techniques are used to reduce the effects of background noise due to stray light and other gaseous absorption line cross talk. The laser beam is focused through the QTF two-arm gap by a self-focusing lens (OZ optics). The focal length of the self-focusing lens is 11mm and the diameter of the optical waist is about 100 μm. The electrical signal output by the QTF is amplified by a 10M Ω custom transimpedance preamplifier 14. The lock-in amplifier 15 is used to demodulate the second harmonic signal. And controlling the whole system of the gas detection device and calculating the concentration of the gas by a LabView program on computer equipment.
In one example of validation, the resonance characteristics of a bare tuning fork and an inventive RC-QEPAS were compared. In RC-QEPAS, a radial cavity with a radius of 6.4mm and a length of 6.9mm is coupled to the QTF for an optimal radial resonance effect. The resonance curves of RC-QEPAS and the bare tuning fork are shown in FIG. 5. The resonant frequency of the QTF, after being coupled to the radial cavity, varied from 32780.8 Hz to 32777.1Hz. And the intensity of resonance is more than 2 times of that of the cavity of the naked tuning fork. The Q value of RC-QEPAS (8220) is lower than that of a bare tuning fork (10446). A low Q value indicates a strong coupling between the QTF and the radial cavity.
In one example of validation, the second harmonic signals of a bare tuning fork and the inventive RC-QEPAS are shown in fig. 6. The laser temperature was set to 17.6 ℃. The injection current is changed from 43mA to 57mA, and the corresponding emission wavelength is 7194.4cm -1 To 7195.1cm -1 . According to the Hitran database, is located at 7194.8cm -1 Absorption line intensity of 3.07x10 -21 The water absorption line in cm/mol is chosen. As shown in FIG. 5, the peak voltage of the second harmonic signal of RC-QEPAS is 2.2mV and the peak voltage of the second harmonic signal of the bare tuning fork device is 0.195mV. The 1 sigma noise obtained by RC-QEPAS and the naked tuning fork is 1.87x 10 respectively -3 mV and 1.69x10 -3 mV. The signal-to-noise ratio of the RC-QEPAS is increased by more than one order of magnitude compared with a bare tuning fork.
The present invention is not limited to the above embodiments, and any modifications, equivalent substitutions, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention as long as the technical effects of the present invention are achieved by the same means. The invention is capable of other modifications and variations in its technical solution and/or its implementation, within the scope of protection of the invention.
Claims (10)
1. A photoacoustic spectroscopy sonometer (5) characterized in that it comprises:
a cylindrical barrel (50), the cylindrical barrel (50) having a central axis (A1) and a line of symmetry (A2) perpendicular to the central axis (A1);
a light-transmissive entrance window (51) disposed at an entrance end of the cylindrical barrel (50);
a light-transmissive exit window (52) disposed at an exit end of the cylindrical barrel (50);
an air inlet (53) and an air outlet (54) which are arranged on the outer wall of the cylindrical barrel (50);
a radial chamber plenum (56) enclosed between the entrance window (51) and the exit window (52), the radial chamber plenum (56) communicating with the air inlet (53) and the air outlet (54);
a quartz tuning fork (55) fixedly arranged in the radial cavity air chamber (56) so that a symmetry line (A2) of the cylindrical tube (50) penetrates into a quartz tuning fork (55) seat along the middle of a gap between two arms of the quartz tuning fork (55), and a central axis (A1) of the cylindrical tube (50) vertically passes through the gap between the two arms of the quartz tuning fork (55).
2. A photoacoustic spectroscopy audiometer (5) according to claim 1,
the incident window (51) and the exit window (52) are made of thin sheets of near-infrared light high-transmittance materials;
the included angles between the incident window (51) and the emergent window (52) and the symmetrical line (A2) of the cylindrical barrel (50) are 4-6 degrees.
3. A photoacoustic spectroscopy audiometer (5) according to claim 1 or 2,
the quartz tuning fork (55) is a strong resonance type quartz tuning fork (55) with a standard size;
the cavity radius size of the radial cavity air chamber (56) of the cylindrical barrel (50) is 6mm to 6.6mm;
the chamber length dimension of the radial chamber air chamber (56) of the cylindrical drum (50) is 6.5mm to 7.5mm.
4. A photoacoustic spectroscopy audiometer (5) according to claim 3,
the cavity radius size of the radial cavity air chamber (56) of the cylindrical barrel (50) is 6.4mm;
the chamber length dimension of the radial chamber plenum (56) of the cylindrical barrel (50) is 6.9mm.
5. A photoacoustic spectroscopy audiometer (5) according to claim 1,
the cylindrical barrel (50) is connected with the columns of the air inlet (53) and the air outlet (54) through threaded holes.
6. A photoacoustic spectroscopy audiometer (5) according to claim 1,
the cylindrical barrel (50) is made of an aluminum alloy material.
7. A gas detection arrangement, characterized by comprising a photoacoustic spectroscopy audiometer (5) according to any one of claims 1 to 6.
8. The gas detection apparatus of claim 7, further comprising:
a function generator (1);
the driving plate (2) is connected with the modulation signal output end of the function generator (1);
a laser (3) driven by the drive board (2);
a lens group (4) arranged in an emergent light path of the laser (3), wherein the photoacoustic spectroscopy sound measurer (5) is positioned in the emergent light path of the lens group (4);
the power meter (6) is positioned on an emergent light path of a radial cavity gas chamber (56) of the photoacoustic spectrum sound measurer (5);
the ground wire (11) is connected with a first pin (12) of a quartz tuning fork of the photoacoustic spectrum sound measurer (5);
the preamplifier (14) is connected with a second pin (13) of the quartz tuning fork of the photoacoustic spectrum sound measurer (5);
the phase-locked amplifier (15) is connected with the output end of the preamplifier (14), and the phase-locked amplifier (15) is connected with the synchronous signal output end of the function generator (1);
a computing device having a data acquisition card connected to the output of the lock-in amplifier (15) and to the output of the power meter (6).
9. The gas detection apparatus of claim 8, further comprising:
a mechanical pump (7), the mechanical pump (7) being connected to the gas outlet (54) of the photoacoustic spectroscopy sonicator (5) through a gas flow control valve (8);
a pressure gauge (9) and a filter element (10), the filter element (10) being connected to an air inlet (53) of the photoacoustic spectroscopy sound meter (5) by the pressure gauge (9),
wherein, when the gas flow control valve (8) makes the mechanical pump (7) work and communicates with the gas outlet (54), the detected gas is sucked into the radial chamber air chamber (56) through the gas inlet (53) after impurities are removed by the filter element (10), and the gas pressure of the whole gas path is measured by the pressure gauge (9).
10. A gas detection method based on the gas detection apparatus according to any one of claims 7 to 9, comprising the steps of:
A. triggering the laser (3) to generate a light path in the resonant cavity, modulating the working current of the laser (3) by the natural frequency of the quartz tuning fork (55), enabling the wavelength of the output light of the laser (3) to sweep through a target gas absorption line, and then modulating the depth of the working current of the laser (3) until the output optical acoustic-electric signals between the pins of the quartz tuning fork (55) reach a preset amplitude;
B. when target gas in the photoacoustic spectrometry sound detector (5) is excited by laser, acquiring electric signals between pins of the quartz tuning fork (55), and converting and storing the electric signals into photoacoustic signal count values after signal amplification processing of preposition and phase locking;
C. and calculating the target gas concentration value corresponding to the current photoacoustic signal count value according to the linear relation between the preset photoacoustic signal count value and the target gas concentration.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110696021.1A CN113552212B (en) | 2021-06-23 | 2021-06-23 | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof |
| PCT/CN2022/079902 WO2022267555A1 (en) | 2021-06-23 | 2022-03-09 | Radial cavity quartz-enhanced photoacoustic spectrophone and gas detection device comprising same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110696021.1A CN113552212B (en) | 2021-06-23 | 2021-06-23 | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113552212A CN113552212A (en) | 2021-10-26 |
| CN113552212B true CN113552212B (en) | 2023-03-28 |
Family
ID=78102348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110696021.1A Active CN113552212B (en) | 2021-06-23 | 2021-06-23 | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN113552212B (en) |
| WO (1) | WO2022267555A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113552212B (en) * | 2021-06-23 | 2023-03-28 | 暨南大学 | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof |
| CN114397246A (en) * | 2022-01-24 | 2022-04-26 | 暨南大学 | Clamp type crystal oscillator for photoacoustic spectrum detection and gas detection device thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101813621A (en) * | 2009-02-19 | 2010-08-25 | 中国科学院安徽光学精密机械研究所 | Quartz tuning fork strengthened photoacoustic spectroscopy gas sensor based on acoustic resonator |
| CN105651374A (en) * | 2016-01-27 | 2016-06-08 | 山西大学 | Single-tube and coaxial photo-acoustic spectrum sound detector and gas detection device adopting sound detector |
| CN108226050A (en) * | 2018-03-02 | 2018-06-29 | 苏州感闻环境科技有限公司 | A kind of resonant mode photoacoustic cell for the detection of gas optoacoustic spectroscopy |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2019307B1 (en) * | 2007-07-24 | 2018-10-03 | Axetris AG | Method and gas sensor for performing quartz-enhanced photoacoustic spectroscopy |
| CN104237135B (en) * | 2014-10-22 | 2017-11-03 | 东北林业大学 | CO gas detecting systems and method based on quartz tuning fork strengthened optoacoustic spectroscopy |
| CN104316466A (en) * | 2014-11-05 | 2015-01-28 | 山东大学 | Photoacoustic spectrometry gas detection device capable of correcting resonant frequency of quartz tuning fork in real time |
| US10444199B2 (en) * | 2016-04-08 | 2019-10-15 | The Chinese University Of Hong Kong | Evanescent-wave quartz-enhanced photoacoustic sensor with resonator elements |
| FR3054666B1 (en) * | 2016-07-27 | 2018-07-20 | Office National D'etudes Et De Recherches Aerospatiales (Onera) | MECHANICAL RESONATOR OPTIMIZED TO OPERATE IN A FLUID |
| CN106290165A (en) * | 2016-09-08 | 2017-01-04 | 山西大学 | General frequency strengthens optoacoustic spectroscopy acousimeter and uses the gas detection apparatus of this acousimeter |
| CN109975214B (en) * | 2019-04-03 | 2021-04-23 | 哈尔滨工业大学 | Gas concentration detection device and method for quartz photoacoustic spectroscopy |
| CN110044824B (en) * | 2019-05-06 | 2021-08-24 | 安徽大学 | Quartz tuning fork-based dual-spectrum gas detection device and method |
| CN113552212B (en) * | 2021-06-23 | 2023-03-28 | 暨南大学 | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof |
-
2021
- 2021-06-23 CN CN202110696021.1A patent/CN113552212B/en active Active
-
2022
- 2022-03-09 WO PCT/CN2022/079902 patent/WO2022267555A1/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101813621A (en) * | 2009-02-19 | 2010-08-25 | 中国科学院安徽光学精密机械研究所 | Quartz tuning fork strengthened photoacoustic spectroscopy gas sensor based on acoustic resonator |
| CN105651374A (en) * | 2016-01-27 | 2016-06-08 | 山西大学 | Single-tube and coaxial photo-acoustic spectrum sound detector and gas detection device adopting sound detector |
| CN108226050A (en) * | 2018-03-02 | 2018-06-29 | 苏州感闻环境科技有限公司 | A kind of resonant mode photoacoustic cell for the detection of gas optoacoustic spectroscopy |
Non-Patent Citations (1)
| Title |
|---|
| 石英增强光声传感技术研究进展;董磊;《中国激光》;《中国激光》杂志社有限公司;20180910;第45卷(第9期);第1-9页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113552212A (en) | 2021-10-26 |
| WO2022267555A1 (en) | 2022-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104237135B (en) | CO gas detecting systems and method based on quartz tuning fork strengthened optoacoustic spectroscopy | |
| CN113552212B (en) | Radial cavity quartz enhanced photoacoustic spectrum sound detector and gas detection device thereof | |
| CN105651374B (en) | The coaxial optoacoustic spectroscopy acousimeter of single tube and the gas detection apparatus for using the acousimeter | |
| CN110044824B (en) | Quartz tuning fork-based dual-spectrum gas detection device and method | |
| CN101512317A (en) | Stable photo acoustic trace gas detector with optical power enhancement cavity | |
| WO2003104767A2 (en) | Quartz-enhanced photoacoustic spectroscopy | |
| CN104849214A (en) | Enhanced multi-group photoacoustic spectrum gas sensing device based on quartz tuning fork | |
| CN112147076B (en) | Absorption optical path enhanced double-resonance photoacoustic spectrum trace gas detection system | |
| CN110346296A (en) | A kind of multi-cavity type is partly begun to speak resonance light sound pond and multiple gases measuring system simultaneously | |
| Dewey Jr | Opto-acoustic spectroscopy | |
| CN110927096A (en) | Mid-infrared gas measurement system based on four-mirror optical feedback | |
| CN112924388A (en) | Orthogonal dual channel acoustic resonance module and device comprising same | |
| CN105784643A (en) | Device and method for reducing fluorescent background of gas Raman spectrum | |
| CN113295620B (en) | Optical fiber coupled all-solid-state enhanced photoacoustic spectroscopy gas photoacoustic detection module and method | |
| Petzold et al. | Novel design of a resonant photoacoustic spectrophone for elemental carbon mass monitoring | |
| US4449825A (en) | Optical measuring apparatus employing a laser | |
| CN106290165A (en) | General frequency strengthens optoacoustic spectroscopy acousimeter and uses the gas detection apparatus of this acousimeter | |
| CN114235699B (en) | Trace gas concentration's detection device | |
| CN115561195A (en) | Single-cavity double-comb light source and gas detection system based on same | |
| CN114002184B (en) | Multi-resonance enhanced photoacoustic spectrum multi-component gas simultaneous detection device and method | |
| CN106802278B (en) | The quartz enhanced photoacoustic spectroscopy acousimeter and gas detection apparatus of double wave abdomen excitation | |
| Yang et al. | Detection of Dissolved Gas in Transformer Oil Based on All-Optical Photoacoustic Spectroscopy | |
| CN113029957A (en) | Gas sensor based on evanescent wave | |
| CN116067890A (en) | Photoacoustic spectrum sound detector and gas detection device | |
| CN113267453B (en) | Passive tuning fork resonance enhanced all-fiber three-gas detection photoacoustic spectroscopy system and detection method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |