CN113551845B - Inorganic membrane assembly detection device and method - Google Patents

Inorganic membrane assembly detection device and method Download PDF

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Publication number
CN113551845B
CN113551845B CN202110821633.9A CN202110821633A CN113551845B CN 113551845 B CN113551845 B CN 113551845B CN 202110821633 A CN202110821633 A CN 202110821633A CN 113551845 B CN113551845 B CN 113551845B
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inorganic membrane
membrane module
detection
inorganic
air
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CN113551845A (en
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杨森
周立臣
粱德炽
于成龙
张述贵
张国冻
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China National Offshore Oil Corp CNOOC
CNOOC China Ltd Zhanjiang Branch
CNOOC China Ltd Hainan Branch
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China National Offshore Oil Corp CNOOC
CNOOC China Ltd Zhanjiang Branch
CNOOC China Ltd Hainan Branch
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01MTESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G01M3/00Investigating fluid-tightness of structures
    • G01M3/02Investigating fluid-tightness of structures by using fluid or vacuum
    • G01M3/04Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention belongs to the technical field of inorganic membranes, and particularly relates to an inorganic membrane component detection device and method. In the scheme, pressurized gas is utilized to permeate the inorganic membrane component to generate bubbles in the detection liquid, so that the size and intensity of the bubbles can be used as reference quantity for judging whether the inorganic membrane component is defective or not, and the detection liquid is more obvious and easy to observe compared with the direct observation of the water yield of the inorganic membrane component, and therefore the judgment accuracy is higher.

Description

Inorganic membrane assembly detection device and method
Technical Field
The invention belongs to the technical field of inorganic membranes, and particularly relates to an inorganic membrane component detection device and method.
Background
The inorganic film is an inorganic or high molecular material with special selective separation function, and can separate fluid into two non-communicated parts so as to make one or several substances in the fluid permeate and separate other substances, so that it can be extensively used in the fields of medicine and water treatment, etc.
The plate-type ceramic membrane is an inorganic membrane, and is of a hollow cube structure, one surface of the cube is provided with openings, the other surfaces of the cube are densely provided with micropores, the distribution of the micropores is generally uniform, the permeability is different according to different molecular diameters of permeated substances within a certain membrane pore diameter range, the pressure difference at two sides of the membrane is used as driving force, the membrane is used as a filter medium, and under the action of certain pressure, when feed liquid flows through the surface of the membrane, only water, inorganic salt and small molecular substances are allowed to permeate the membrane, and macromolecular substances such as suspended matters, glue and microorganisms in the water are prevented from passing through the membrane.
For a general plate-type ceramic membrane, the pore diameter of micropores reaches the micron level or below, so if defects such as cracks and the like appear, the area of the defects is far larger than that of the micropores, and part of macromolecular substances possibly pass through the cracks to interfere with the filtering effect.
When the inorganic membrane component is used in the water purifying equipment, pressurized raw water injected into the equipment is filtered to obtain purified water, and then the purified water is led out of the equipment along a pipeline, and if the inorganic membrane component has a defect part, the filtering efficiency of the equipment and the purity of produced water can be affected. It is therefore necessary to ensure the integrity of the inorganic membrane used, and it is often necessary to leak test the inorganic membrane module to determine if it is defective. At present, a plurality of modes are adopted to detect various parameters in a practical process and judge whether the ceramic membrane component has defects according to rules, such as the detection method of the inorganic membrane component disclosed in Chinese patent CN101650268B, which is applied to a tubular ceramic membrane, and judges whether the membrane tubes are broken or not through the liquid output of each membrane tube; in addition, it is not possible to determine the defective position of the inorganic membrane module, and it is not easy to repair the inorganic membrane module.
Disclosure of Invention
The invention provides an inorganic membrane module detection device and method for overcoming at least one defect in the prior art, which are easier to judge whether the inorganic membrane module has the defect, improve the detection and judgment accuracy of the inorganic membrane module, and simultaneously can determine the defect position of the inorganic membrane module, thereby facilitating the subsequent maintenance work.
In order to solve the technical problems, the invention adopts the following technical scheme:
The utility model provides an inorganic membrane module detection device for whether detect inorganic membrane module is qualified, including holding the detection container that detects liquid, the connecting piece that the activity set up in the detection container, compressed gas subassembly, connecting piece and inorganic membrane module intercommunication and sealing fit, connecting piece still communicates with compressed gas subassembly.
According to the scheme, the inorganic membrane component can be placed into the detection liquid, gas is filled into the inorganic membrane component, the gas can quickly pass through micropores of the inorganic membrane component through pressurization and generate bubbles in the detection liquid, the pore diameter of the micropores of the inorganic membrane component is small, the pores of cracks are larger than those of the micropores, the sizes and the intensity of the bubbles generated after the pressurized gas passes through the inorganic membrane component are obviously different, and therefore the detection liquid is easy to distinguish, and whether the inorganic membrane component has defects can be judged by observing whether uniform bubbles are generated on the inorganic membrane component or not, so that the defects of the inorganic membrane component are amplified through the bubbles, the defects are easier to observe, and the judgment accuracy can be improved.
Preferably, the compressed gas assembly comprises an air pump, an air pipe and an adjusting piece for adjusting the output air pressure of the air pump, wherein the connecting piece is communicated with an inflation connector, one end of the air pipe is communicated with the air pump, and the other end of the air pipe is provided with an air tap which is spliced with the inflation connector.
Preferably, a gas filter in communication with the gas tube is also included.
Preferably, the adjusting member is a valve, and the compressed gas assembly further comprises a barometer disposed between the valve and the air tap.
Preferably, the connecting piece is fixedly provided with a handle.
The scheme also provides an inorganic membrane component detection method, which comprises the following steps:
S1: completely immersing the inorganic membrane component into detection liquid in a detection container;
S2: filling gas with a first preset pressure value into the inorganic membrane component through the compressed gas component for a first preset time;
S3: judging whether the inorganic membrane module is qualified or not according to whether uniform bubbles are generated on the side wall of the inorganic membrane module, if so, entering a step S4; if not, entering step S5;
S4: taking out the inorganic membrane module from the detection liquid, and confirming whether the inorganic membrane module is qualified according to whether the uniform atomization phenomenon is generated on the side wall of the inorganic membrane module, if so, ending the current step; if not, entering step S5;
s5: defect locations of the inorganic membrane modules are determined.
In order to avoid misjudgment, the method adds a step of judging whether the inorganic membrane module is qualified or not, screens out the defective inorganic membrane module under double judgment, and confirms the defect position of the defective inorganic membrane module so as to facilitate subsequent maintenance.
Preferably, the step S4 of confirming whether the inorganic membrane module is acceptable specifically includes the following steps:
s41: stopping filling the gas with the first preset pressure value into the inorganic membrane component;
S42: taking out the inorganic membrane component from the detection container;
S43: filling gas with a second preset pressure value into the inorganic membrane component for a second preset time;
S44: judging whether the surface of the inorganic membrane component generates uniform atomization phenomenon, if so, stopping the current step and confirming that the inorganic membrane component is qualified; if not, the inorganic membrane module is completely immersed in the detection liquid in the detection container again, and the step S5 is performed.
Preferably, the step S5 specifically includes: and filling gas with a third preset pressure value into one end of the inorganic membrane module in the flowing direction for a third preset time, slowly lifting the inorganic membrane module from the detection container, observing the condition of bubbles generated on the surface of the inorganic membrane module, marking the positions of non-uniform bubbles generated on the surface of the inorganic membrane module, and confirming the positions as defect positions.
Preferably, the first preset pressure value is 1KG/cm 2~2KG/cm2, the second preset pressure value is 0.5KG/cm 2~1.5KG/cm2, and the third preset pressure value is 2KG/cm 2~3KG/cm2.
Preferably, the detection liquid is one of water or ethanol, and the gas is one of air or helium.
Compared with the prior art, the beneficial effects are that:
In the scheme, pressurized gas is utilized to permeate the inorganic membrane component to generate bubbles in the detection liquid, defects of the inorganic membrane component are amplified and displayed through the bubbles, so that the size and intensity of the bubbles can be used as reference quantity for judging whether the inorganic membrane component has defects or not, and compared with the method for directly observing the water yield of the inorganic membrane component, the method is more obvious and easy to observe, and therefore the judging accuracy is higher; in addition, a step of observing the atomization condition of the surface of the inorganic membrane component is added to judge whether the inorganic membrane component is qualified or not, and the probability of misjudgment is greatly reduced under a double judging mechanism.
Drawings
FIG. 2 is a schematic diagram showing the structure of an inorganic membrane module detection apparatus according to embodiment 1 of the present invention;
FIG. 1 is a schematic flow chart of the method for detecting an inorganic membrane module according to embodiment 2 of the present invention.
The device comprises a 100-inorganic membrane component, a 1-detection container, 11-detection liquid, a 2-connecting piece, a 21-gas charging connector, a 22-handle, a 3-compressed gas component, a 31-gas pump, a 32-gas pipe, a 33-regulating piece, a 34-gas nozzle, a 35-gas pressure meter and a 4-gas filter.
Detailed Description
The drawings are for illustrative purposes only and are not to be construed as limiting the invention; for the purpose of better illustrating the embodiments, certain elements of the drawings may be omitted, enlarged or reduced and do not represent the actual product dimensions; it will be appreciated by those skilled in the art that certain well-known structures in the drawings and descriptions thereof may be omitted. The positional relationship described in the drawings are for illustrative purposes only and are not to be construed as limiting the invention.
The same or similar reference numbers in the drawings of embodiments of the invention correspond to the same or similar components; in the description of the present invention, it should be understood that, if there are orientations or positional relationships indicated by terms "upper", "lower", "left", "right", "long", "short", etc., based on the orientations or positional relationships shown in the drawings, this is merely for convenience in describing the present invention and simplifying the description, and is not an indication or suggestion that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, so that the terms describing the positional relationships in the drawings are merely for exemplary illustration and are not to be construed as limitations of the present patent, and that it is possible for those of ordinary skill in the art to understand the specific meaning of the terms described above according to specific circumstances.
The technical scheme of the invention is further specifically described by the following specific embodiments with reference to the accompanying drawings:
Example 1
An embodiment of an inorganic membrane module detection device is shown in fig. 1, and is used for detecting whether an inorganic membrane module 100 is qualified or not, and the device comprises a detection container 1 containing detection liquid 11, a connecting piece 2 movably arranged in the detection container 1, and a compressed gas module 3, wherein the connecting piece 2 is communicated with the inorganic membrane module 100 and is in sealing fit, and the connecting piece 2 is also communicated with the compressed gas module 3.
In this embodiment, there are two inorganic membrane modules 100, and the water inlets of the inorganic membrane modules 100 are respectively in sealed communication with the connecting piece 2, so that the detection efficiency can be improved. Specifically, the connecting piece 2 should be hollow and provided with a joint 21 matched with the inorganic membrane assembly 100, and meanwhile, the joint 21 is provided with a sealing ring to be in sealing connection with the inorganic membrane assembly, so that the phenomenon that gas leaks from a joint and loses pressure, and bubbles or atomization which are easy to observe cannot be generated is avoided.
The compressed gas assembly 3 in this embodiment includes an air pump 31 for providing compressed gas, an air pipe 32, and an adjusting member 33 for adjusting the output air pressure of the air pump 31, the connecting member 2 is provided with an inflation connector 21 in a communicating manner, one end of the air pipe 32 is communicated with the air pump 31, and the other end is provided with an air tap 34 inserted into the inflation connector 21. The output air pressure of the air pump 31 can be conveniently adjusted through the adjusting piece 33 so as to adapt to the air pressure requirements of different detection stages; in addition, through air cock 34 and inflatable structure 21 can realize the quick connect of trachea 32 and connecting piece 2, improves detection efficiency.
In order to avoid clogging or other secondary damage of the inorganic membrane module 100 caused by foreign substances contained in the input gas, the embodiment further includes a gas filter 4 in communication with the gas pipe 32, and the pressurized gas from the gas pump 31 may be filtered.
The adjusting member 33 in this embodiment is a valve, and the compressed gas assembly 3 further includes a barometer 35 disposed between the valve and the air tap 34. Thus, the opening of the valve can be conveniently controlled according to the air pressure value required by each step to adjust the air pressure output by the air pump 31, and the air pressure value can be monitored by the air pressure meter 35 to ensure that proper air pressure can be output, and air bubbles or atomization phenomena which are easy to observe are generated.
The lifting handle 22 is fixedly arranged on the connecting piece 2 in the embodiment, and the lifting handle 22 can drive the inorganic membrane assembly 100 on the connecting piece 2 to move up and down in the detection process, so that the depth of the inorganic membrane assembly 100 in the detection liquid is controlled, and the inorganic membrane assembly 100 is conveniently lifted or lowered to carry out multiple tests.
Of course, a vertical guide may be provided to the detection vessel 1, and the inorganic membrane module 100 may be mounted on the guide to move in the vertical direction.
In this scheme, can put into the inorganic membrane module 100 and detect liquid 11 in, through filling gas into the inorganic membrane module 100, gas can be passed through from the micropore of inorganic membrane module 100 and produce the bubble in detecting liquid 11 fast through pressurizing, because the micropore aperture of inorganic membrane module 100 is very little, the hole of crackle can be than micropore big more, the bubble size and the intensity that produce after the pressurized gas through both can obviously be different, consequently very easily distinguish, whether it has the defect through whether produce even bubble judgement on the inorganic membrane module 100 of observing, amplify the defect of inorganic membrane module 100 through the bubble like this, make it be more easy to observe, can improve judgement correct rate.
Example 2:
as shown in fig. 2, a first embodiment of an inorganic membrane module detection method using the inorganic membrane module detection apparatus of embodiment 1 includes the steps of:
S1: completely immersing the inorganic membrane component into detection liquid in a detection container;
S2: the output air pressure of the air pump is regulated through a valve, and air with a first preset pressure value is filled into a water inlet of the inorganic membrane component for a first preset time;
s3: judging whether the inorganic membrane module is qualified according to whether uniform bubbles are generated on the side wall of the inorganic membrane module, if so, entering a step S4; if not, entering step S5;
S4: confirming whether the inorganic membrane module is qualified according to whether the uniform atomization phenomenon is generated on the side wall of the inorganic membrane module, if so, ending the current step; if not, entering step S5;
s5: defect locations of the inorganic membrane modules are determined.
Because only whether the bubbles generated by the inorganic membrane component are uniform or not is observed so as to judge whether the inorganic membrane is defective or not, a double judging mechanism is arranged, and the probability of misjudgment can be greatly reduced.
Specifically, the step S4 of confirming whether the inorganic membrane module is acceptable in the present embodiment specifically includes:
s41: closing the air pipe through the valve, and stopping filling the gas with the first preset pressure value into the inorganic membrane component;
S42: lifting the connecting piece from the detection liquid through the handle, and simultaneously taking out the inorganic membrane component from the detection container; at this time, due to capillary action, the detection liquid enters into the micropores of the inorganic membrane module and is adsorbed on the inorganic membrane module;
S43: the output air pressure of the air pump is regulated through a valve, and air with a second preset pressure value is filled into one end of the water inlet of the inorganic membrane component for a second preset time; thus, similar to the principle of generating bubbles in the detection liquid, the detection liquid adsorbed in micropores of the inorganic membrane module can be blown out to generate an atomization phenomenon on the surface of the inorganic membrane module, if the inorganic membrane module is qualified, uniform water mist can be formed on the surface of the inorganic membrane module because the micropores are not greatly different, and if the inorganic membrane module is defective, the area of the defect is far greater than that of the micropores, so that the water mist generated at the defect position is obviously different from other positions;
s44: judging whether the surface of the inorganic membrane component generates uniform atomization phenomenon, if so, confirming that the inorganic membrane component is qualified and stopping the current step; if not, the inorganic membrane module is completely immersed in the detection liquid in the detection container again, and the step S5 is performed.
Step S5 in this embodiment specifically includes: and filling gas with a third preset pressure value into the water inlet of the inorganic membrane module for a third preset time, slowly lifting the inorganic membrane module from the detection container, observing the condition of bubbles generated on the surface of the inorganic membrane module, marking the positions of non-uniform bubbles generated on the surface of the inorganic membrane module, and confirming the positions as defect positions, so that the inorganic membrane module can be maintained conveniently later. In this way, the defect judgment is performed on the inorganic membrane component for the third time, so that the probability of misjudgment is further reduced.
The first preset pressure value in this embodiment is 1KG/cm 2, the second preset pressure value is 0.5KG/cm 2, and the third preset pressure value is 2KG/cm 2.
The detection liquid in the embodiment is water, and the gas is air; of course, the detection liquid can also be a nontoxic, harmless and non-corrosive liquid such as ethanol, and the gas can also be helium or other inert gases, and it should be understood that, according to common knowledge, a person skilled in the art can use the gas to react with the detection liquid in a chemical manner, and the gas should be slightly soluble or insoluble in the detection liquid, so as to ensure that bubbles can be generated normally.
In this embodiment, by filling the pressurized gas into the inorganic membrane module, the gas passes through the micropores of the inorganic membrane module quickly and generates bubbles in the detection liquid, and since the pore diameter of the micropores of the inorganic membrane module is very small, the pores of the cracks are much larger than those of the micropores, and therefore, compared with the bubbles generated in the micropores, the bubbles generated by the cracks are larger, the rate is slower, and the bubbles are easier to separate, so that the method can be used as a reference for judging whether the inorganic membrane module has defects.
Example 3
The difference between this embodiment and embodiment 2 is only that the first preset pressure is 2KG/cm 2, the second preset pressure is 1.5KG/cm 2, and the third preset pressure is 3KG/cm 2.
Example 4
The difference between this embodiment and embodiment 2 or embodiment 3 is only that the first preset pressure is 1.5KG/cm 2, the second preset pressure is 1KG/cm 2, and the third preset pressure is 2.5KG/cm 2.
The present application is described with reference to flowchart illustrations or block diagrams of methods, apparatus (systems) and computer program products according to embodiments of the application, it being understood that each flowchart illustration or block in the flowchart illustrations or block diagrams, and combinations of flowcharts or blocks in the flowchart illustrations or block diagrams, can be implemented by computer program instructions. These computer program instructions may be provided to a processor of a general purpose computer, special purpose computer, embedded processor, or other programmable data processing apparatus to produce a machine, such that the instructions, which execute via the processor of the computer or other programmable data processing apparatus, create means for implementing the functions specified in the flowchart flow or flows and/or block diagram block or blocks.
While embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives and variations may be made to the above embodiments by one of ordinary skill in the art within the scope of the invention.
It is to be understood that the above examples of the present invention are provided by way of illustration only and not by way of limitation of the embodiments of the present invention. Other variations or modifications of the above teachings will be apparent to those of ordinary skill in the art. It is not necessary here nor is it exhaustive of all embodiments. Any modification, equivalent replacement, improvement, etc. which come within the spirit and principles of the invention are desired to be protected by the following claims.

Claims (7)

1. An inorganic membrane module detection method using an inorganic membrane module detection device, wherein the inorganic membrane module detection device is used for detecting whether an inorganic membrane module (100) is qualified or not, the inorganic membrane module detection device comprises a detection container (1) containing detection liquid (11), a connecting piece (2) and a compressed gas module (3) which are movably arranged in the detection container (1), the connecting piece (2) is communicated with the inorganic membrane module (100) and is in sealing fit, the connecting piece (2) is also communicated with the compressed gas module (3), and the detection method comprises the following steps:
S1: completely immersing the inorganic membrane component into detection liquid in a detection container;
S2: the output air pressure of the compressed air component is regulated by the regulating piece, and air with a first preset pressure value is filled into the inorganic membrane component for a first preset time;
S3: judging whether the inorganic membrane module is qualified or not according to whether uniform bubbles are generated on the side wall of the inorganic membrane module, if so, entering a step S4; if not, entering step S5;
S4: taking out the inorganic membrane module from the detection liquid, and confirming whether the inorganic membrane module is qualified according to whether the uniform atomization phenomenon is generated on the side wall of the inorganic membrane module, if so, ending the current step; if not, entering step S5;
S5: determining the defect position of the inorganic membrane component;
the step S4 of confirming whether the inorganic membrane module is qualified specifically comprises the following steps:
s41: stopping filling the gas with the first preset pressure value into the inorganic membrane component;
S42: taking out the inorganic membrane component from the detection container;
S43: the output air pressure of the compressed air component is regulated by the regulating piece, and air with a second preset pressure value is filled into the inorganic membrane component for a second preset time;
s44: judging whether the surface of the inorganic membrane component generates uniform atomization phenomenon, if so, confirming that the inorganic membrane component is qualified and stopping the current step; if not, the inorganic membrane module is completely immersed in the detection liquid in the detection container again, and the step S5 is performed.
2. The method for detecting an inorganic membrane module using the device for detecting an inorganic membrane module according to claim 1, wherein: the step S5 specifically includes: and filling gas with a third preset pressure value into one end of the inorganic membrane module in the flowing direction for a third preset time, slowly lifting the inorganic membrane module from the detection container, observing the condition of bubbles generated on the surface of the inorganic membrane module, marking the positions of non-uniform bubbles generated on the surface of the inorganic membrane module, and confirming the positions as defect positions.
3. An inorganic membrane module inspection method using an inorganic membrane module inspection apparatus according to claim 1 or 2, characterized in that: the detection liquid is one of water or ethanol, and the gas is one of air or helium.
4. The method for detecting an inorganic membrane module using the device for detecting an inorganic membrane module according to claim 1, wherein: the compressed gas assembly (3) comprises an air pump (31), an air pipe (32) and an adjusting piece (33) for adjusting the output air pressure of the air pump (31), an inflation connector (21) is arranged on the connecting piece (2) in a communicating mode, one end of the air pipe (32) is communicated with the air pump (31), and an air nozzle (34) connected with the inflation connector (21) in an inserting mode is arranged on the other end of the air pipe.
5. The method for detecting an inorganic membrane module using an apparatus for detecting an inorganic membrane module according to claim 4, wherein: also comprises a gas filter (4) in communication with the gas pipe (32).
6. The method for detecting an inorganic membrane module using an apparatus for detecting an inorganic membrane module according to claim 4, wherein: the adjusting piece (33) is a valve, and the compressed gas assembly (3) further comprises a barometer (35) arranged between the valve and the air tap (34).
7. The method for detecting an inorganic membrane module using the device for detecting an inorganic membrane module according to claim 1, wherein: a handle (22) is fixedly arranged on the connecting piece (2).
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