CN113546434A - Double-effect energy-saving evaporation concentration system - Google Patents
Double-effect energy-saving evaporation concentration system Download PDFInfo
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- CN113546434A CN113546434A CN202110869675.XA CN202110869675A CN113546434A CN 113546434 A CN113546434 A CN 113546434A CN 202110869675 A CN202110869675 A CN 202110869675A CN 113546434 A CN113546434 A CN 113546434A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/26—Multiple-effect evaporating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/0011—Heating features
- B01D1/0041—Use of fluids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/0082—Regulation; Control
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/30—Accessories for evaporators ; Constructional details thereof
Abstract
The invention discloses a double-effect energy-saving evaporation concentration system, which can be used for preparing Mount Dill digestion granules and comprises a first-effect heater, a first-effect evaporator, a second-effect heater, a second-effect evaporator, a condenser, a vacuum pump and a heating enhancement mechanism, wherein the first-effect heater, the first-effect evaporator, the second-effect heater, the second-effect evaporator, the condenser and the vacuum pump are sequentially connected; the heating enhancement mechanism comprises a steam supplementing pipe, the first-effect evaporator is connected with the second-effect heater through a steam conveying pipe, the steam supplementing pipe is communicated with the steam conveying pipe, and a one-way valve is arranged on the steam supplementing pipe. By using the double-effect energy-saving evaporation concentration system, steam can be supplemented into the double-effect heater to improve the steam quantity and temperature, so that the concentration efficiency of the liquid medicine in the double-effect evaporator is accelerated, the steam in the first-effect evaporator is utilized to achieve the energy-saving effect, and the processing efficiency of the double-effect evaporator is improved.
Description
Technical Field
The invention relates to the technical field of traditional Chinese medicine production and processing, in particular to a double-effect energy-saving evaporation and concentration system.
Background
The product is prepared by extracting, concentrating, settling, and sterilizing. In the concentration process, because the liquid medicine is used as a heat-sensitive material and has the characteristic of easy decomposition, polymerization and oxidation due to thermal instability, a double-effect concentrator is usually adopted for low-temperature vacuum concentration. The double-effect concentrator heats and concentrates the liquid medicine of the double-effect by secondary steam generated by the first effect, and achieves the effect of saving energy by secondary utilization of the steam. In the double-effect concentrator in the prior art, the steam quantity and the temperature during the double-effect heating can not reach the effect during the first effect, so that the evaporation concentration efficiency of the liquid medicine in the double-effect is lower.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a double-effect energy-saving evaporation and concentration system which can improve the working efficiency during double-effect evaporation and concentration.
In order to achieve the purpose, the invention is realized by the following technical scheme: a double-effect energy-saving evaporation concentration system comprises a first-effect heater, a first-effect evaporator, a second-effect heater, a second-effect evaporator, a condenser, a vacuum pump and a heating enhancement mechanism, wherein the first-effect heater, the first-effect evaporator, the second-effect heater, the second-effect evaporator, the condenser and the vacuum pump are sequentially connected;
the heating enhancement mechanism comprises a steam supplementing pipe, the first-effect evaporator is connected with the second-effect heater through a steam conveying pipe, the steam supplementing pipe is communicated with the steam conveying pipe, and a one-way valve is arranged on the steam supplementing pipe.
The raw material liquid medicine of the rockery and indigestion particle is added into the first-effect evaporator and the second-effect evaporator, steam enters the first-effect heater to heat the liquid medicine, the steam of the liquid medicine enters the second-effect heater from the first-effect evaporator through the steam conveying pipe to be heated, the steam generated by the concentration of the liquid medicine of the second-effect evaporator is discharged through the condenser and the vacuum pump, and the steam supplementing pipe can appropriately supplement and add the steam into the second-effect heater, so that the heating efficiency of the liquid medicine in the second effect is improved.
The double-effect energy-saving evaporation concentration system has the beneficial effects that: the supplementary steam enters the double-effect heater, so that the steam generated in the first-effect evaporator is utilized to achieve the effect of energy conservation, the steam quantity and the temperature of the double-effect heater are increased, and the evaporation concentration efficiency of the double-effect liquid medicine is improved.
Further, steam conveying pipe includes that one imitates connecting pipe and two imitates the connecting pipe, one imitates the connecting pipe and two imitates the one end that the connecting pipe kept away from each other and is connected with one effect evaporimeter and two effect heaters respectively, one imitates the connecting pipe and two imitates the one end that the connecting pipe is close to each other and all is equipped with the external screw thread, and is connected through having the internal screw thread screwed pipe, steam supply pipe is connected with two imitate the connecting pipe.
The first-effect connecting pipe and the second-effect connecting pipe are connected through the threaded connecting pipe, so that the first-effect connecting pipe and the second-effect connecting pipe can be detached, the second-effect part can be used as an independent single-effect concentration device, and the single-effect concentration device has higher processing efficiency.
Furthermore, two condensation pipes are arranged on the condenser, the two-effect evaporator is connected with the condenser through one condensation pipe, and external threads are arranged on the other condensation pipe.
After taking the steam conveying pipe apart, two condenser pipes of condenser accessible are connected with one imitate the connecting pipe and two effect connecting pipes respectively to work as two independent single effect enrichment facility, reach the effect that promotes machining efficiency through getting rid of energy-conserving effect.
Furthermore, a rotatable tee ball is arranged at the joint of the two-effect connecting pipe and the steam supplementing pipe, a T-shaped channel is arranged inside the tee ball, and the three ends of the T-shaped channel are respectively communicated with the two ends of the two-effect connecting pipe and the steam supplementing pipe.
After the steam conveying pipe is disassembled, the two-effect connecting pipe is added with steam through the steam replenishing pipe. Through rotating the tee bend ball, can let two-effect connecting pipe be in multiple connected state to be adapted to the different processing methods of device.
Further, the heating reinforcing mechanism also comprises a heating wire, and the inner wall of the two-effect connecting pipe is provided with the heating wire.
When the steam amount generated in the single-effect evaporator is sufficient, steam can be heated by the heating wires to raise the temperature without supplementing steam.
The device comprises a terrace, a first-effect heater, a second-effect evaporator, a condenser, a first-effect evaporator, a second-effect heater, a second-effect evaporator and a second-effect evaporator, wherein the terrace is provided with a base, the base is arranged on the terrace, is disc-shaped and comprises an inner disc and an outer ring, the outer ring can rotate relative to the inner disc, and the first-effect heater, the first-effect evaporator, the second-effect heater, the second-effect evaporator and the condenser are sequentially arranged on the base along the radial direction of the base;
the double-effect heater, the double-effect evaporator and the condenser are arranged on the inner disc, and the single-effect heater and the single-effect evaporator are arranged on the outer ring.
After the double-effect concentration system is disassembled into two single-effect concentration devices, the outer ring can rotate relative to the inner disc, so that the one-effect heater and the one-effect evaporator rotate to the other side of the condenser, and the one-effect connecting pipe of the one-effect evaporator is connected with the other condenser pipe, so that the single-effect concentrator is installed.
Further, a plurality of pulleys are arranged at the bottom of the outer circular ring in the circumferential direction.
The pulley can be convenient for the outer ring and rotate for interior disc, avoids the too big rotation of being difficult to of weight.
Furthermore, gaps are formed in the side, close to each other, of each of the outer ring and the inner disc, two gaps are symmetrically formed in the inner disc, and the inner sides of the gaps are provided with upward inclined surfaces;
the double-wedge-shaped structure is characterized by further comprising a double wedge block, the side face of the double wedge block can be attached to the inclined plane, a through hole is formed in the double wedge block in the axial direction, a pressing rod is inserted into the through hole, and a pressing block is arranged on the pressing rod in the circumferential direction.
When two gaps of the outer ring are aligned with the gaps of the inner disc, the corresponding devices are in a single-effect concentration state or a double-effect concentration state respectively, the double wedge blocks are inserted into the aligned gaps, the pressing rod is aligned with the through hole and inserted downwards, the double wedge blocks are pressed downwards through the pressing block, the double wedge blocks are attached to the inclined plane and extrude the outer ring and the inner disc towards two sides, and the outer ring and the inner disc are fixed relatively and cannot rotate.
Furthermore, the top of the pressing rod is provided with threads around the circumferential direction, an inner gear ring is arranged on the outer side of the pressing rod around the circumferential direction, a transmission column is arranged between the pressing rod and the inner gear ring, one end of the transmission column is provided with a gear meshed with the inner gear ring, the other end of the transmission column is provided with threads meshed with the pressing rod around the circumferential direction, and the transmission column can move around the pressing rod in the circumferential direction.
The transmission post is around circumferential direction, through the cooperation of gear and ring gear, drives the rotation of transmission post, can make depression bar along axial motion under the cooperation of screw thread to push down double wedge through the briquetting, compare in directly pushing down double wedge, this kind of mode has higher precision.
Further, a motor is arranged above the transmission column, the motor is rotatably connected with the transmission column through a transmission arm and can drive the transmission column to move circumferentially around the pressing rod, and the motor is arranged on the outer ring through a support.
The motor drives the transmission arm to rotate, the transmission column can be driven to rotate around the circumferential direction, namely, the pressing rod and the pressing block can be driven to press the double wedges downwards, and the fixation of the outer circular ring and the inner circular disc is completed.
Drawings
In order to more clearly illustrate the embodiments of the present invention, the drawings, which are required to be used in the embodiments, will be briefly described below. In all the drawings, the elements or parts are not necessarily drawn to actual scale.
FIG. 1 is a front view of a dual-effect energy-saving evaporative concentration system provided in an embodiment of the present invention;
FIG. 2 is a schematic view of a vapor transfer line of the dual-effect energy-saving evaporative concentration system shown in FIG. 1;
FIG. 3 is a top plan view of the dual-effect energy-saving evaporative concentration system shown in FIG. 1;
FIG. 4 is a schematic view of the inner disc and outer ring gap of the dual-effect energy-saving evaporative concentration system shown in FIG. 1;
reference numerals: 10-one-effect part, 11-one-effect heater, 12-one-effect evaporator;
20-two-effect part, 21-two-effect heater, 22-two-effect evaporator, 23-steam delivery pipe, 231-one-effect connecting pipe, 232-two-effect connecting pipe, 233-threaded pipe and 234-tee ball;
30-condenser, 31-vacuum pump;
40-a heating enhancement mechanism, 41-a steam supplementing pipe and 42-a heating wire;
50-base, 51-inner circle, 52-outer circle, 53-gap, 54-double wedge, 55-pressure bar, 551-pressure block, 56-transmission column, 561-gear, 57-inner gear ring, 58-transmission arm, 59-motor, 591-support.
Detailed Description
Embodiments of the present invention will be described in detail below with reference to the accompanying drawings. The following examples are only for illustrating the technical solutions of the present invention more clearly, and therefore are only examples, and the protection scope of the present invention is not limited thereby.
Referring to fig. 1 to 4, the invention provides a double-effect energy-saving evaporation concentration system, which comprises a first-effect heater 11, a first-effect evaporator 12, a second-effect heater 21, a second-effect evaporator 22, a condenser 30 and a vacuum pump 31, which are connected in sequence, wherein steam is added into the first-effect heater 11 to heat liquid medicine, the liquid medicine generates steam in the concentration process of the first-effect evaporator 12 and enters the second-effect heater 21 to heat the liquid medicine, and a heating enhancing mechanism 40 is arranged between the first-effect evaporator 12 and the second-effect heater 21 and can supplement the steam to enter the second-effect heater 21 so as to enhance the efficiency of concentration and evaporation.
Specifically, as shown in fig. 1 to 3, the first-effect heater 11 and the first-effect evaporator 12 are the first-effect portion 10, and the second-effect heater 21 and the second-effect evaporator 22 are the second-effect portion 20 in this embodiment. The first-effect evaporator 12 is connected with the second-effect heater 21 through the steam conveying pipe 23, the heating enhancing mechanism 40 comprises a steam supplementing pipe 41, a one-way valve is arranged on the steam supplementing pipe 41, one end of the steam supplementing pipe is connected with the steam conveying pipe 23, supplementing steam can be added into the second-effect heater 21 to improve the steam quantity of the second-effect part 20, and therefore the concentration efficiency of the liquid medicine in the second-effect evaporator 22 is improved. As shown in fig. 2, in the present embodiment, the steam delivery pipe 23 includes a first-effect connection pipe 231 and a second-effect connection pipe 232 connected to each other, and ends of the first-effect connection pipe 231 and the second-effect connection pipe 232, which are far away from each other, are connected to the first-effect evaporator 12 and the second-effect heater 21, respectively, and ends, which are close to each other, are provided with external threads and connected to each other through a threaded pipe 233 having internal threads.
After the steam conveying pipe 23 is disassembled, the first effect part 10 and the second effect part 20 can be disassembled. The condenser 30 is provided with two condensation pipes, one of which is connected to the two-effect evaporator 22, and the other of which is provided with external threads capable of being connected to the one-effect connection pipe 231. The first-effect evaporator 12 is disconnected from the second-effect part 20 and is connected with the condenser 30, the double-effect concentration system can be changed into two single-effect concentration devices, the second-effect part 20 directly provides a large amount of high-temperature steam through the steam supplementing pipe 41, and compared with the double-effect concentration system, the two single-effect concentration devices have higher processing efficiency although the energy-saving effect is reduced, and can be replaced in two modes, namely a single-effect mode and a double-effect mode according to the actual requirements of energy conservation and efficiency during production and processing.
A rotatable tee ball 234 is arranged at the joint of the two-effect connecting pipe 232 and the steam supplementing pipe 41, a T-shaped channel communicated with three directions is arranged in the tee ball 234, the three directions are respectively communicated with two ends of the steam supplementing pipe 41 and the two-effect connecting pipe 232, and by rotating the tee ball 234, various communication modes can be realized, including closing the steam supplementing pipe 41, communicating the one-effect connecting pipe 231 with the two-effect connecting pipe 232; the first-effect connection pipe 231 is closed, and the second-effect connection pipe 232 and the steam supplement pipe 41 are communicated, so that the method is applicable to both the single-effect mode and the double-effect mode.
Further, the heating enhancing mechanism 40 further includes a heating wire 42 disposed in the two-effect connection pipe 232, and the heating wire 42 can raise the temperature of the steam entering the two-effect portion 20 to further increase the concentration efficiency of the two-effect portion 20. In case the amount of steam provided by the effect section 10 is sufficient, the steam supplementary pipe 41 may be closed and only heated by the heating wire 42.
Specifically, the base 50 is arranged on the floor, the base 50 is disc-shaped and comprises an inner disc 51 and an outer circular ring 52 sleeved outside, the first-effect heater 11, the first-effect evaporator 12, the second-effect heater 21, the second-effect evaporator 22 and the condenser 30 are sequentially arranged on the base 50 along the radial direction, the first-effect part 10 is arranged on the outer circular ring 52, and the second-effect part 20 and the condenser 30 are arranged on the inner disc 51. The inner disc 51 is fixedly arranged on the ground and the outer ring 52 is slidably connected with the inner ring and can rotate relative to the inner disc 51 so as to rotate the one-effect part 10 to the other side to be connected with the condenser 30 when the single-effect mode is replaced. Since the apparatus is heavy, the bottom of the outer ring 52 is provided with a plurality of pulleys around the circumference to facilitate rotation.
As shown in fig. 3 and 4, the adjacent sides of the outer ring 52 and the inner ring are both provided with two notches 53, the inner disc 51 is symmetrically provided with two notches 53, the notches 53 of the outer ring 52 can be matched with the two notches 53 of the inner disc 51, and when the notches 53 are matched, the first effect part 10 can be respectively connected with the second effect part 20 and the condenser 30, so as to be used in the single effect mode and the double effect mode. The inner side surfaces of the notches 53 are provided with upward inclined surfaces, when the inner and outer notches 53 correspond to each other, the double wedge blocks 54 can be inserted inwards, the two side surfaces of the double wedge blocks 54 can be attached to the inclined surfaces of the two sides, the double wedge blocks 54 are axially provided with through holes, the pressing rods 55 are inserted inside the through holes, pressing blocks 551 are arranged at the upper end portions of the pressing rods 55 around the circumferential direction, after the pressing rods 55 are inserted downwards, the pressing blocks 551 press the double wedge blocks 54 downwards, and extrude the inner disc 51 and the outer ring 52 towards the two sides, and the outer ring 52 is sleeved on the inner disc 51, so that the outer ring 52 can be fixed relative to the inner disc 51 and cannot rotate, and the device can work conveniently.
Furthermore, the top of the pressure lever 55 is circumferentially provided with threads, the outer side of the pressure lever is circumferentially provided with an inner gear ring 57, a transmission column 56 is arranged between the pressure lever 55 and the inner gear ring 57, the top end of the transmission column 56 is provided with a gear 561 engaged with the inner gear ring 57, and the bottom of the transmission column is circumferentially provided with threads matched with the threads of the pressure lever 55. The outer ring 52 is provided with a support 591, the support 591 is provided with a motor 59 positioned above the pressure rod 55, and an output shaft of the motor 59 is axially arranged along the pressure rod 55 and is connected with the transmission column 56 through a transmission arm 58, so that the transmission column 56 can be driven to axially rotate around the pressure rod 55.
The motor 59 rotates to drive the transmission arm 58 to rotate around the circumferential direction, the transmission arm 58 is rotatably connected with the transmission column 56, the transmission column 56 can be driven to rotate around the circumferential direction, the transmission column 56 rotates under the matching of the gear 561 and the inner gear ring 57, and the transmission column 56 drives the pressing rod 55 to move axially under the matching of the threads, so that the double wedge blocks 54 can be pressed downwards. Compared with the mode of directly pressing the double wedge blocks 54 downwards, the transmission mode has higher control precision and avoids damaging the device.
The working principle of the double-effect energy-saving evaporation concentration system is as follows: adding the raw material liquid medicine for producing the Mount Bushan Xiaojie granules into a first-effect evaporator and a second-effect evaporator, starting a vacuum pump 31 to vacuumize the evaporators and heaters so as to achieve the aim of low-temperature vacuum concentration, adding steam into the first-effect heater 11, heating, evaporating and concentrating the liquid medicine reciprocating in the first-effect heater 11 and the first-effect evaporator 12, feeding the steam generated by the liquid medicine into the second-effect heater 21 from a steam conveying pipe 23, and simultaneously adding steam into the second-effect heater 21 through a steam supplementing pipe 41 so that the liquid medicine in the second-effect heater 21 and the second-effect evaporator 22 can achieve better evaporation and concentration effects. When it is desired to further increase the concentration rate, the outer ring 52 can be rotated to rotate the first effect portion 10 relative to the second effect portion 20 to the other side of the condenser 30 and connected to the condenser tubes to form two single effect concentration units. After the base 50 is adjusted, the double wedge 54 is inserted into the notch 53, and the double wedge 54 is driven to press down by the motor 59 and the transmission column 56, so that the outer ring 52 is fixed relative to the inner disc 51, and the installation is completed.
Use above-mentioned energy-conserving evaporative concentration system of economic benefits and social benefits, can add the steam of replenishment in the part to two effects, both reached energy-conserving effect, promoted machining efficiency again to can switch over in single-effect and two kinds of modes of economic benefits and social benefits, adjust according to energy-conserving and machining efficiency's demand, have higher practicality.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; such modifications and substitutions do not depart from the spirit and scope of the present invention, and they should be construed as being included in the following claims and description.
Claims (10)
1. The utility model provides a economic benefits and social benefits evaporation concentration system which characterized in that: the system comprises a first-effect heater, a first-effect evaporator, a second-effect heater, a second-effect evaporator, a condenser and a vacuum pump which are connected in sequence, and further comprises a heating enhancement mechanism;
the heating enhancement mechanism comprises a steam supplementing pipe, the first-effect evaporator is connected with the second-effect heater through a steam conveying pipe, the steam supplementing pipe is communicated with the steam conveying pipe, and a one-way valve is arranged on the steam supplementing pipe.
2. The dual effect energy saving evaporative concentration system of claim 1 wherein: the steam conveying pipe comprises a first effect connecting pipe and a second effect connecting pipe, one end, far away from each other, of the first effect connecting pipe and the second effect connecting pipe is connected with a first effect evaporator and a second effect heater respectively, one end, close to each other, of the first effect connecting pipe and the second effect connecting pipe is provided with external threads and is connected with the first effect evaporator and the second effect heater through threaded pipes with internal threads, and the steam supplementing pipe is connected with the second effect connecting pipe.
3. The dual effect energy saving evaporative concentration system of claim 2, wherein: the condenser is provided with two condensation pipes, the two-effect evaporator is connected with the condenser through one condensation pipe, and the other condensation pipe is provided with external threads.
4. The dual effect energy saving evaporative concentration system of claim 2, wherein: the steam supply device is characterized in that a rotatable tee ball is arranged at the joint of the two-effect connecting pipe and the steam supply pipe, a T-shaped channel is arranged inside the tee ball, and the three ends of the T-shaped channel are respectively communicated with the two ends of the two-effect connecting pipe and the steam supply pipe.
5. The dual effect energy saving evaporative concentration system of claim 2, wherein: the heating enhancement mechanism further comprises a heating wire, and the inner wall of the two-effect connecting pipe is provided with the heating wire.
6. The dual effect energy saving evaporative concentration system of claim 2, wherein: the device comprises a terrace, and is characterized by further comprising a base, wherein the base is arranged on the terrace, is disc-shaped, and comprises an inner disc and an outer ring, the outer ring can rotate relative to the inner disc, and the first-effect heater, the first-effect evaporator, the second-effect heater, the second-effect evaporator and the condenser are sequentially arranged on the base along the radial direction of the base;
the double-effect heater, the double-effect evaporator and the condenser are arranged on the inner disc, and the single-effect heater and the single-effect evaporator are arranged on the outer ring.
7. The dual effect energy saving evaporative concentration system of claim 6, wherein: and a plurality of pulleys are arranged at the bottom of the outer circular ring in the circumferential direction.
8. The dual effect energy saving evaporative concentration system of claim 6, wherein: gaps are formed in the side, close to each other, of each of the outer ring and the inner disc, the inner discs are symmetrically provided with two gaps, and the inner sides of the gaps are provided with upward inclined surfaces;
the double-wedge-shaped structure is characterized by further comprising a double wedge block, the side face of the double wedge block can be attached to the inclined plane, a through hole is formed in the double wedge block in the axial direction, a pressing rod is inserted into the through hole, and a pressing block is arranged on the pressing rod in the circumferential direction.
9. The dual effect energy saving evaporative concentration system of claim 8, wherein: the top of the pressing rod is provided with threads around the circumferential direction, an inner gear ring is arranged on the outer side of the pressing rod around the circumferential direction, a transmission column is arranged between the pressing rod and the inner gear ring, one end of the transmission column is provided with a gear meshed with the inner gear ring, the other end of the transmission column is provided with threads meshed with the pressing rod around the circumferential direction, and the transmission column can move around the pressing rod in the circumferential direction.
10. The dual effect energy saving evaporative concentration system of claim 9 wherein: the motor is arranged above the transmission column, the motor is rotatably connected with the transmission column through the transmission arm and can drive the transmission column to move circumferentially around the pressing rod, and the motor is arranged on the outer ring through the support.
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Address after: 556000 No. 12, Chunhui West Avenue, Kaili Development Zone, Qiandongnan Miao and Dong Autonomous Prefecture, Guizhou Province Patentee after: Hongyun Pharmaceutical (Guizhou) Co.,Ltd. Address before: 556000 No. 12, Chunhui West Avenue, Kaili Development Zone, Qiandongnan Miao and Dong Autonomous Prefecture, Guizhou Province Patentee before: GUIZHOU FEIYUNLING PHARMACEUTICAL Co.,Ltd. |