CN113527874A - PA6-PA66 composite material - Google Patents
PA6-PA66 composite material Download PDFInfo
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- CN113527874A CN113527874A CN202110908653.XA CN202110908653A CN113527874A CN 113527874 A CN113527874 A CN 113527874A CN 202110908653 A CN202110908653 A CN 202110908653A CN 113527874 A CN113527874 A CN 113527874A
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- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 47
- 239000002131 composite material Substances 0.000 title claims abstract description 32
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 21
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 21
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 12
- 239000012779 reinforcing material Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 13
- 239000003365 glass fiber Substances 0.000 claims description 9
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 8
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- OHRVBDRGLIWLPA-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(O)=O OHRVBDRGLIWLPA-UHFFFAOYSA-N 0.000 claims description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 7
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 150000004668 long chain fatty acids Chemical class 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- -1 long chain fatty acid salt Chemical class 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000002646 long chain fatty acid esters Chemical class 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 1
- 239000004005 microsphere Substances 0.000 claims 1
- 239000002530 phenolic antioxidant Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 6
- 238000001746 injection moulding Methods 0.000 abstract description 3
- 229920002292 Nylon 6 Polymers 0.000 description 13
- 230000014759 maintenance of location Effects 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000011324 bead Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 125000003157 long chain fatty acid ester group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000008301 phosphite esters Chemical group 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2477/06—Polyamides derived from polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
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- C08K7/14—Glass
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the field of materials, in particular to a PA6-PA66 composite material which is prepared from the following raw materials in percentage by weight: PA 64-75%; PA 664-75%; 8-25% of a flame retardant; 5-20% of a reinforcing material; 1-3% of a compatilizer; 0.1 to 1 percent of antioxidant; 0.1 to 1.5 percent of lubricant. The PA6-PA66 composite material ensures that the material has high strength, high heat resistance and high fluidity, and also has the characteristics of high surface brightness, excellent dimensional stability of products, low warpage and the like; the appearance is good, the surface is bright, and the high-fluidity and easy-injection-molding characteristics are realized; the preparation method is simple in preparation process, easy to operate and free of complex equipment.
Description
Technical Field
The invention relates to the field of materials, in particular to a PA6-PA66 composite material.
Background
PA66 (nylon 66) resin and PA66 (nylon 6) resin are one of engineering plastics widely used, and PA66 and PA6 belong to crystalline materials, have good fluidity, are resistant to organic solvents, have good compatibility with glass fibers, but are easy to absorb water, have poor dimensional stability and heat resistance, have poor surface glossiness after being reinforced by the glass fibers, and particularly have insufficient dimensional stability and poor fluidity for large parts.
The reinforced filling PA66/PA6 alloy sold in the market is mostly common reinforced filling PA66/PA6 alloy, has a common surface, a common warping resistance, low heat resistance and mechanical strength and poor flowability, and is difficult to inject. At present, the heat resistance and strength problems are mainly solved by adopting a high-content glass fiber reinforced PA66/PA6 alloy, after the high-content glass fiber reinforced PA66/PA6 alloy, the heat resistance and mechanical strength of the material are greatly improved, but the appearance and dimensional stability of the material are greatly reduced, a molded part is seriously warped and deformed, the appearance and assembly of the part are influenced, and the part with high brightness cannot meet the requirements at all for some parts with high requirements.
Disclosure of Invention
In order to solve the technical problems, the invention provides a PA6-PA66 composite material with high strength and high heat resistance.
The invention adopts the following technical scheme:
a PA6-PA66 composite material is composed of the following raw materials in percentage by weight:
the technical proposal is further improved in that the intrinsic viscosity of the PA6 is 3 dl/g.
The technical proposal is further improved in that the intrinsic viscosity of the PA66 is 3 dl/g.
The technical proposal is further improved that the flame retardant comprises the following components in parts by weight: 10-15 parts of ammonium polyphosphate, 10-15 parts of modified expanded graphite, 3-6 parts of antimony trioxide and 1-3 parts of pentaerythritol phosphate.
The technical proposal is further improved in that the reinforcing material is at least one of glass fiber, glass microballoon, carbon fiber, magnesium carbonate, barium sulfate and nano montmorillonite.
The technical proposal is further improved in that the compatilizer is at least one of methacrylate-based copolymer, vinyl acetate-based copolymer and glycolic acid-based copolymer.
The technical proposal is further improved in that the antioxidant is one of phenol antioxidant or phosphite antioxidant.
In a further improvement of the above technical solution, the lubricant is at least one of a long-chain fatty acid, a long-chain fatty acid salt, a long-chain fatty acid ester, or an amide derivative.
The technical scheme is further improved in that the preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
The further improvement of the technical scheme is that the temperature of the first zone of the double-screw extruder is 210-minus 245 ℃, the temperature of the second zone is 260-minus 275 ℃, the temperature of the third zone is 260-minus 275 ℃, the temperature of the fourth zone is 265-minus 275 ℃, the temperature of the fifth zone is 250-minus 270 ℃, the temperature of the sixth zone is 250-minus 270 ℃, the temperature of the seventh zone is 250-minus 270 ℃, the temperature of the eighth zone is 250-minus 270 ℃, the temperature of the ninth zone is 260-minus 275 ℃, the temperature of the head is 260-minus 280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
The invention has the beneficial effects that:
the PA6-PA66 composite material ensures that the material has high strength, high heat resistance and high fluidity, and also has the characteristics of high surface brightness, excellent dimensional stability of products, low warpage and the like; the appearance is good, the surface is bright, and the high-fluidity and easy-injection-molding characteristics are realized; the preparation method is simple in preparation process, easy to operate and free of complex equipment.
Detailed Description
The present invention will be further described with reference to the following examples for better understanding of the present invention, but the embodiments of the present invention are not limited thereto.
A PA6-PA66 composite material is composed of the following raw materials in percentage by weight:
further, the intrinsic viscosity of the PA6 was 3 dl/g.
Further, the intrinsic viscosity of the PA66 was 3 dl/g.
Further, the flame retardant comprises the following components in parts by weight: 10-15 parts of ammonium polyphosphate, 10-15 parts of modified expanded graphite, 3-6 parts of antimony trioxide and 1-3 parts of pentaerythritol phosphate.
Further, the reinforcing material is at least one of glass fiber, glass beads, carbon fiber, magnesium carbonate, barium sulfate and nano montmorillonite.
Further, the compatilizer is at least one of a methacrylate-based copolymer, a vinyl acetate-based copolymer and a glycolic acid-based copolymer.
Further, the antioxidant is one of a phenol antioxidant or a phosphite antioxidant.
Further, the lubricant is at least one of a derivative of a long-chain fatty acid, a long-chain fatty acid salt, a long-chain fatty acid ester, or an amide.
Further, the preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
Further, the temperature of the first zone of the double-screw extruder is 210-245 ℃, the temperature of the second zone is 260-275 ℃, the temperature of the third zone is 260-275 ℃, the temperature of the fourth zone is 265-275 ℃, the temperature of the fifth zone is 250-270 ℃, the temperature of the sixth zone is 250-270 ℃, the temperature of the seventh zone is 250-270 ℃, the temperature of the eighth zone is 250-270 ℃, the temperature of the ninth zone is 260-275 ℃, the temperature of the head is 260-280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
Example 1
A PA6-PA66 composite material is composed of the following raw materials in percentage by weight: PA 645%; PA 6629%; 8% of a flame retardant; 15% of a reinforcing material; 1% of a compatilizer; 0.5 percent of antioxidant; 1.5 percent of lubricant.
The intrinsic viscosity of the PA6 is 3 dl/g; the intrinsic viscosity of the PA66 was 3 dl/g.
The flame retardant comprises the following components in parts by weight: 10 parts of ammonium polyphosphate, 10 parts of modified expanded graphite, 3 parts of antimony trioxide and 1 part of pentaerythritol phosphate.
The reinforcing material is glass fiber.
The compatilizer is a methacrylate-based copolymer.
The antioxidant is a phenol antioxidant.
The lubricant is a long chain fatty acid.
The preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
The temperature of the first zone of the double-screw extruder is 210-245 ℃, the temperature of the second zone is 260-275 ℃, the temperature of the third zone is 260-275 ℃, the temperature of the fourth zone is 265-275 ℃, the temperature of the fifth zone is 250-270 ℃, the temperature of the sixth zone is 250-270 ℃, the temperature of the seventh zone is 250-270 ℃, the temperature of the eighth zone is 250-270 ℃, the temperature of the ninth zone is 260-275 ℃, the temperature of the head is 260-280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
Example 2
A PA6-PA66 composite material is composed of the following raw materials in percentage by weight: PA 650%; PA 6620%; 15% of flame retardant; 12% of a reinforcing material; 1.5% of a compatilizer; 1% of antioxidant; 0.5 percent of lubricant.
The intrinsic viscosity of the PA6 is 3 dl/g; the intrinsic viscosity of the PA66 was 3 dl/g.
The flame retardant comprises the following components in parts by weight: 12 parts of ammonium polyphosphate, 10 parts of modified expanded graphite, 5 parts of antimony trioxide and 1 part of pentaerythritol phosphate.
The reinforcing material is glass beads.
The compatilizer is a methacrylate-based copolymer.
The antioxidant is phosphite ester antioxidant.
The lubricant is long-chain fatty acid salt.
The preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
The temperature of the first zone of the double-screw extruder is 210-245 ℃, the temperature of the second zone is 260-275 ℃, the temperature of the third zone is 260-275 ℃, the temperature of the fourth zone is 265-275 ℃, the temperature of the fifth zone is 250-270 ℃, the temperature of the sixth zone is 250-270 ℃, the temperature of the seventh zone is 250-270 ℃, the temperature of the eighth zone is 250-270 ℃, the temperature of the ninth zone is 260-275 ℃, the temperature of the head is 260-280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
Example 3
A PA6-PA66 composite material is composed of the following raw materials in percentage by weight: PA 670%; PA 6610%; 10% of flame retardant; 6% of a reinforcing material; 3% of a compatilizer; 0.5 percent of antioxidant; 0.5 percent of lubricant.
The intrinsic viscosity of the PA6 is 3 dl/g; the intrinsic viscosity of the PA66 was 3 dl/g.
The flame retardant comprises the following components in parts by weight: 10 parts of ammonium polyphosphate, 10 parts of modified expanded graphite, 3 parts of antimony trioxide and 1 part of pentaerythritol phosphate.
The reinforcing material is carbon fiber.
The compatilizer is a glycolic acid-based copolymer.
The antioxidant is a phenol antioxidant.
The lubricant is long-chain fatty acid ester.
The preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
The temperature of the first zone of the double-screw extruder is 210-245 ℃, the temperature of the second zone is 260-275 ℃, the temperature of the third zone is 260-275 ℃, the temperature of the fourth zone is 265-275 ℃, the temperature of the fifth zone is 250-270 ℃, the temperature of the sixth zone is 250-270 ℃, the temperature of the seventh zone is 250-270 ℃, the temperature of the eighth zone is 250-270 ℃, the temperature of the ninth zone is 260-275 ℃, the temperature of the head is 260-280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
Example 4
A PA6-PA66 composite material is composed of the following raw materials in percentage by weight: PA 65%; PA 6675%; 8% of a flame retardant; 10% of a reinforcing material; 1% of a compatilizer; 0.5 percent of antioxidant; 0.5 percent of lubricant.
The intrinsic viscosity of the PA6 is 3 dl/g; the intrinsic viscosity of the PA66 was 3 dl/g.
The flame retardant comprises the following components in parts by weight: 15 parts of ammonium polyphosphate, 15 parts of modified expanded graphite, 6 parts of antimony trioxide and 3 parts of pentaerythritol phosphate.
The reinforcing material is glass fiber.
The compatilizer is a methacrylate-based copolymer.
The antioxidant is a phenol antioxidant.
The lubricant is a long chain fatty acid.
The preparation method of the PA6-PA66 composite material comprises the following steps: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
The temperature of the first zone of the double-screw extruder is 210-245 ℃, the temperature of the second zone is 260-275 ℃, the temperature of the third zone is 260-275 ℃, the temperature of the fourth zone is 265-275 ℃, the temperature of the fifth zone is 250-270 ℃, the temperature of the sixth zone is 250-270 ℃, the temperature of the seventh zone is 250-270 ℃, the temperature of the eighth zone is 250-270 ℃, the temperature of the ninth zone is 260-275 ℃, the temperature of the head is 260-280 ℃, the retention time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
Comparative example 1
The prior PA6-PA66 composite material.
Performance testing
The PA6-PA66 composite samples from examples 1-4 and comparative example 1 were compared for performance testing using ASTM standards. The test performance is compared as shown in the following table:
from the above test data it can be seen that: the A66-PA6 alloy prepared by the invention has greatly improved mechanical property indexes such as tensile strength, bending modulus, impact strength and the like; the appearance is good, the surface is bright, and the high-fluidity and easy-injection-molding characteristics are realized; the formed product has low warping degree and good appearance, and is beneficial to assembly and post-processing; the high-voltage switch can be widely applied to products in the fields of electronic appliances such as contactors, leakage protectors, breaker shells and the like.
Appropriate changes and modifications to the embodiments described above will become apparent to those skilled in the art from the disclosure and teachings of the foregoing description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (10)
1. The PA6-PA66 composite material is characterized by comprising the following raw materials in percentage by weight:
2. the PA6-PA66 composite material of claim 1, wherein the PA6 has an intrinsic viscosity of 3 dl/g.
3. The PA6-PA66 composite material of claim 1, wherein the PA66 has an intrinsic viscosity of 3 dl/g.
4. The PA6-PA66 composite material as claimed in claim 1, wherein the flame retardant comprises the following components in parts by weight: 10-15 parts of ammonium polyphosphate, 10-15 parts of modified expanded graphite, 3-6 parts of antimony trioxide and 1-3 parts of pentaerythritol phosphate.
5. The PA6-PA66 composite material of claim 1, wherein the reinforcing material is at least one of glass fibers, glass microspheres, carbon fibers, magnesium carbonate, barium sulfate, and nano-montmorillonite.
6. The PA6-PA66 composite material of claim 1, wherein the compatibilizer is at least one of a methacrylate-based copolymer, a vinyl acetate-based copolymer, and a glycolic acid-based copolymer.
7. The PA6-PA66 composite material of claim 1, wherein the antioxidant is one of a phenolic antioxidant or a phosphite antioxidant.
8. The PA6-PA66 composite material of claim 1, wherein the lubricant is at least one of a derivative of a long chain fatty acid, a long chain fatty acid salt, a long chain fatty acid ester, or an amide.
9. The PA6-PA66 composite material of claim 1, wherein the PA6-PA66 composite material is prepared by a method comprising the steps of: putting the components in a high-speed mixer according to the weight percentage, mixing for 6-8 minutes, discharging, adding into a double-screw extruder, and performing melt extrusion and granulation.
10. The PA6-PA66 composite material as claimed in claim 9, wherein the first zone temperature of the twin-screw extruder is 210-245 ℃, the second zone temperature is 260-275 ℃, the third zone temperature is 260-275 ℃, the fourth zone temperature is 265-275 ℃, the fifth zone temperature is 250-270 ℃, the sixth zone temperature is 250-270 ℃, the seventh zone temperature is 250-270 ℃, the eighth zone temperature is 250-270 ℃, the ninth zone temperature is 260-275 ℃, the head temperature is 260-280 ℃, the residence time of each zone is 3.5-4min, and the vacuum pressure of each zone is-0.07-0.15 MPa.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735601A (en) * | 2009-12-23 | 2010-06-16 | 东莞市信诺橡塑工业有限公司 | Heat and flame resistant nylon composite |
| CN101760016A (en) * | 2008-11-21 | 2010-06-30 | 上海普利特复合材料股份有限公司 | Flame-retarded enhanced PA66 composite special for wire connector box |
| CN102234422A (en) * | 2011-05-06 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Flame-retardant nylon resin composition and preparation method thereof |
| CN105542446A (en) * | 2015-11-12 | 2016-05-04 | 浙江铧淳塑料有限公司 | High-fluidity and easy-injection molding PA6-PA66 composite material and preparation method thereof |
| CN113045889A (en) * | 2021-04-12 | 2021-06-29 | 苏州润佳高分子材料有限公司 | Halogen-free flame-retardant nylon |
-
2021
- 2021-08-09 CN CN202110908653.XA patent/CN113527874A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760016A (en) * | 2008-11-21 | 2010-06-30 | 上海普利特复合材料股份有限公司 | Flame-retarded enhanced PA66 composite special for wire connector box |
| CN101735601A (en) * | 2009-12-23 | 2010-06-16 | 东莞市信诺橡塑工业有限公司 | Heat and flame resistant nylon composite |
| CN102234422A (en) * | 2011-05-06 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Flame-retardant nylon resin composition and preparation method thereof |
| CN105542446A (en) * | 2015-11-12 | 2016-05-04 | 浙江铧淳塑料有限公司 | High-fluidity and easy-injection molding PA6-PA66 composite material and preparation method thereof |
| CN113045889A (en) * | 2021-04-12 | 2021-06-29 | 苏州润佳高分子材料有限公司 | Halogen-free flame-retardant nylon |
Non-Patent Citations (1)
| Title |
|---|
| 俞志明: "中国化工商品大全 第三卷", vol. 1, 中国物资出版社, pages: 3628 * |
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