CN113512703A - 一种高效抑菌片的制造工艺 - Google Patents
一种高效抑菌片的制造工艺 Download PDFInfo
- Publication number
- CN113512703A CN113512703A CN202110724050.4A CN202110724050A CN113512703A CN 113512703 A CN113512703 A CN 113512703A CN 202110724050 A CN202110724050 A CN 202110724050A CN 113512703 A CN113512703 A CN 113512703A
- Authority
- CN
- China
- Prior art keywords
- film layer
- thickness
- dioxide film
- silicon dioxide
- germanium dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims abstract description 78
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 77
- 229940119177 germanium dioxide Drugs 0.000 claims abstract description 39
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 38
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 36
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 23
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000007747 plating Methods 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 16
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004544 sputter deposition Methods 0.000 claims abstract description 8
- 229910052786 argon Inorganic materials 0.000 claims abstract description 5
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 claims description 119
- 239000012528 membrane Substances 0.000 claims description 11
- 230000003385 bacteriostatic effect Effects 0.000 claims description 10
- 239000007888 film coating Substances 0.000 claims description 4
- 238000009501 film coating Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 11
- 238000002834 transmittance Methods 0.000 abstract description 5
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 3
- 206010069767 H1N1 influenza Diseases 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 201000010740 swine influenza Diseases 0.000 description 3
- 241000712461 unidentified influenza virus Species 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000002155 anti-virotic effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 silver ions Chemical class 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/081—Oxides of aluminium, magnesium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3457—Sputtering using other particles than noble gas ions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5826—Treatment with charged particles
- C23C14/5833—Ion beam bombardment
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Inorganic Chemistry (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Abstract
本发明公开了一种高效抑菌片的制造工艺，其包括选取树脂基片；采用镀膜机，通过真空溅射在树脂基片上依次镀覆第一二氧化硅膜层、第二二氧化锗膜层、第三二氧化硅膜层、第四二氧化锗膜层、第五二氧化硅膜层、第六二氧化锗膜层、及第七三氧化二铝膜层；通入氩气，对镀完膜的树脂基片进行加离子源处理；通过真空溅射在第七三氧化二铝膜层表面镀制第八银离子膜层。本发明通过二氧化硅和二氧化锗的交替膜层实现镜片的减反射功能，提高透光度，同时三氧化二铝膜层结合度好，能够附着银离子膜层，提高银离子膜层抑菌，抑菌效果达到99.9%以上，控制时间持久。
Description
技术领域
本发明属于镜片技术领域，具体地说，涉及一种高效抑菌片的制造工艺。
背景技术
随着树脂眼镜市场逐步扩大，其树脂镜片也越来越得到消费者的关注。因此随着消费者要求的多元化，树脂镜片的各方面性能和工艺都在不断的改进和完善。目前，市场上的镀膜树脂镜片，主要都是在加过硬的树脂镜片的基础上，通过真空镀膜的方法，镀有减反射膜层、顶层防水层等。以达到增强透过率、保护镜片的作用。
生活中各种各样的树脂镜片作为日常携带用品，为提供了视力矫正、保护和时尚等功能，同时由于长期佩戴树脂镜片表面必然存在各种各样的细菌、真菌，病毒等微生物，其中各种有害微生物的传播和蔓延严重威胁着人类的用眼健康和身体健康。因此人们对抗菌功能的产品也越来越重视。
如中国专利申请CN201310653170公开的由金属氧化物构成的抗菌层提出可以应用于镜片表面实现抗菌。但是镜片表面镀制抗菌层存在两个方面的缺陷：首先结构不稳定，容易产生膜层结合不良的问题，影响抗菌效果的持久性；另外，由于其提出的抗菌层是由氧化锌或氧化钙或其结合镀制而成，很明显其对能起到抗菌作用的菌类种类的范围有限，不能很好地起到抗菌保护作用。因此，需要一种全新的技术方案解决这些问题。
发明内容
有鉴于此，本发明所要解决的技术问题是提供了一种高效抑菌片的制造工艺，用于避免以往镜片抑菌效果较差的麻烦。
为了解决上述技术问题，本发明公开了一种高效抑菌片的制造工艺，其包括步骤a.选取树脂基片；
步骤b.采用镀膜机，通过真空溅射在树脂基片上依次镀覆第一二氧化硅膜层、第二二氧化锗膜层、第三二氧化硅膜层、第四二氧化锗膜层、第五二氧化硅膜层、第六二氧化锗膜层、及第七三氧化二铝膜层；
步骤c.通入氩气，对镀完膜的树脂基片进行加离子源处理，时间为10-30min；
步骤d.抽真空，真空度为3.5×10-5 mbar～1.5×10-5 mbar；
步骤e.通过真空溅射在第七三氧化二铝膜层表面镀制第八银离子膜层，同时通入氧气，流速为180-300SCCM；
步骤f.取出烘干，完成包装。
根据本发明一实施方式，其中上述第一二氧化硅膜层厚度为80-120nm；第二二氧化锗膜层厚度为30-50nm；第三二氧化硅膜层厚度为20-30nm；第四二氧化锗膜层厚度为20-30nm；第五二氧化硅膜层厚度为40-70nm；第六二氧化锗膜层厚度为30-40nm；第七三氧化二铝膜层厚度为40-70nm；第八银离子膜层厚度为5-10nm。
根据本发明一实施方式，其中上述第一二氧化硅膜层厚度为100nm；第二二氧化锗膜层厚度为40nm；第三二氧化硅膜层厚度为25nm；第四二氧化锗膜层厚度为25m；第五二氧化硅膜层厚度为55nm；第六二氧化锗膜层厚度为25nm；第七三氧化二铝膜层厚度为55nm；第八银离子膜层厚度为8nm。
根据本发明一实施方式，其中上述第八银离子膜层表面设有加硬膜层或防水膜层。
与现有技术相比，本发明可以获得包括以下技术效果：
通过二氧化硅和二氧化锗的交替膜层实现镜片的减反射功能，提高透光度，同时三氧化二铝膜层结合度好，能够附着银离子膜层，提高银离子膜层抑菌，抑菌（大肠杆菌、金黄色葡萄球菌）及抗病毒（H1N1流感病毒）效果达到99.9%以上，控制时间持久。
当然，实施本发明的任一产品必不一定需要同时达到以上所述的所有技术效果。
附图说明
此处所说明的附图用来提供对本发明的进一步理解，构成本发明的一部分，本发明的示意性实施例及其说明用于解释本发明，并不构成对本发明的不当限定。在附图中：
图1是本发明实施例的高效抑菌片示意图。
附图标记
树脂基片10，第一二氧化硅膜层21，第二二氧化锗膜层22，第三二氧化硅膜层23，第四二氧化锗膜层24，第五二氧化硅膜层25，第六二氧化锗膜层26，第七三氧化二铝膜层27，第八银离子膜层28。
具体实施方式
以下将配合附图及实施例来详细说明本发明的实施方式，借此对本发明如何应用技术手段来解决技术问题并达成技术功效的实现过程能充分理解并据以实施。
请参考图1，图1是本发明实施例的高效抑菌片示意图。如图所示，一种等离子净化汽车顶灯，其包括：
步骤a.选取树脂基片10；
步骤b.采用镀膜机，通过真空溅射在树脂基片上依次镀覆第一二氧化硅膜层21、第二二氧化锗膜层22、第三二氧化硅膜层23、第四二氧化锗膜层24、第五二氧化硅膜层25、第六二氧化锗膜层26、及第七三氧化二铝膜层27；
步骤c.通入氩气，对镀完膜的树脂基片10进行加离子源处理，时间为10-30min；
步骤d.抽真空，真空度为3.5×10-5 mbar～1.5×10-5 mbar；
步骤e.通过真空溅射在第七三氧化二铝膜层27表面镀制第八银离子膜层28，同时通入氧气，流速为180-300SCCM；
步骤f.取出烘干，完成包装。
在本发明实施方式中，树脂基片10由树脂单体加工制备而成，可根据需要选择合适的折射率单体，通过在加硬液中浸泡，加硬基片，提高树脂基片10的强度。然后在镀膜机中依次镀覆第一二氧化硅膜层21、第二二氧化锗膜层22、第三二氧化硅膜层23、第四二氧化锗膜层24、第五二氧化硅膜层25、第六二氧化锗膜层26、及第七三氧化二铝膜层27，实现减反射膜层设计，控制镜片单面反射率≤2%。
第七层必需使用三氧化二铝，其与最外层银离子结合好，增加银离子附着力；而最外层的第八层银离子膜层28，满足抑菌效果，抑菌（大肠杆菌、金黄色葡萄球菌）及抗病毒（H1N1流感病毒）效果达到99.9%以上，控制时间持久，膜厚需控制在10nm以下，保证镜片透过率≥95%。
需要了解的是，镀银前充氩气气体进行加离子源处理，同时镀银时需充氧气，保持稳定银化合物稳定态。
优选一实施方式中，第一二氧化硅膜21层厚度为80-120nm；第二二氧化锗膜层22厚度为30-50nm；第三二氧化硅膜层23厚度为20-30nm；第四二氧化锗膜层24厚度为20-30nm；第五二氧化硅膜层25厚度为40-70nm；第六二氧化锗膜层26厚度为30-40nm；第七三氧化二铝膜层27厚度为40-70nm；第八银离子膜层28厚度为5-10nm。在本实施方式中，各个膜层厚度适中，减反射效果优异，而且第七三氧化二铝膜层27附着的第八银离子膜层28稳定，附着力高，第八银离子膜层28的抑菌效果好。
优选一实施方式中，第一二氧化硅膜层21厚度为100nm；第二二氧化锗膜层22厚度为40nm；第三二氧化硅膜层23厚度为25nm；第四二氧化锗膜层24厚度为25m；第五二氧化硅膜层25厚度为55nm；第六二氧化锗膜层26厚度为25nm；第七三氧化二铝膜层27厚度为55nm；第八银离子膜层28厚度为8nm。经试验测得，在本尺寸厚度下的各个膜层，减反射效果最好，而且第八银离子膜层28附着最为密集，抑菌效果得到最大化提高。
另外，在其他实施方式中，第八银离子膜层28表面设有加硬膜层或防水膜层，实现镜片的多功能优化。
综上所述，本发明通过二氧化硅和二氧化锗的交替膜层实现镜片的减反射功能，提高透光度，同时三氧化二铝膜层结合度好，能够附着银离子膜层，提高银离子膜层抑菌，抑菌（大肠杆菌、金黄色葡萄球菌）及抗病毒（H1N1流感病毒）效果达到99.9%以上，控制时间持久。
上述说明示出并描述了本发明的若干优选实施例，但如前所述，应当理解本发明并非局限于本文所披露的形式，不应看作是对其他实施例的排除，而可用于各种其他组合、修改和环境，并能够在本文所述发明构想范围内，通过上述教导或相关领域的技术或知识进行改动。而本领域人员所进行的改动和变化不脱离本发明的精神和范围，则都应在本发明所附权利要求的保护范围内。
Claims (4)
1.一种高效抑菌片的制造工艺，其特征在于，包括：
步骤a.选取树脂基片；
步骤b.采用镀膜机，通过真空溅射在树脂基片上依次镀覆第一二氧化硅膜层、第二二氧化锗膜层、第三二氧化硅膜层、第四二氧化锗膜层、第五二氧化硅膜层、第六二氧化锗膜层、及第七三氧化二铝膜层；
步骤c.通入氩气，对镀完膜的树脂基片进行加离子源处理，时间为10-30min；
步骤d.抽真空，真空度为3.5×10-5 mbar～1.5×10-5 mbar；
步骤e.通过真空溅射在第七三氧化二铝膜层表面镀制第八银离子膜层，同时通入氧气，流速为180-300SCCM；
步骤f.取出烘干，完成包装。
2.根据权利要求1所述的高效抑菌片的制造工艺，其特征在于，其中所述第一二氧化硅膜层厚度为80-120nm；第二二氧化锗膜层厚度为30-50nm；第三二氧化硅膜层厚度为20-30nm；第四二氧化锗膜层厚度为20-30nm；第五二氧化硅膜层厚度为40-70nm；第六二氧化锗膜层厚度为30-40nm；第七三氧化二铝膜层厚度为40-70nm；第八银离子膜层厚度为5-10nm。
3.根据权利要求2所述的高效抑菌片的制造工艺，其特征在于，其中所述第一二氧化硅膜层厚度为100nm；第二二氧化锗膜层厚度为40nm；第三二氧化硅膜层厚度为25nm；第四二氧化锗膜层厚度为25m；第五二氧化硅膜层厚度为55nm；第六二氧化锗膜层厚度为25nm；第七三氧化二铝膜层厚度为55nm；第八银离子膜层厚度为8nm。
4.根据权利要求1所述的高效抑菌片的制造工艺，其特征在于，其中所述第八银离子膜层表面设有加硬膜层或防水膜层。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110724050.4A CN113512703A (zh) | 2021-06-29 | 2021-06-29 | 一种高效抑菌片的制造工艺 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110724050.4A CN113512703A (zh) | 2021-06-29 | 2021-06-29 | 一种高效抑菌片的制造工艺 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113512703A true CN113512703A (zh) | 2021-10-19 |
Family
ID=78065982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110724050.4A Pending CN113512703A (zh) | 2021-06-29 | 2021-06-29 | 一种高效抑菌片的制造工艺 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113512703A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114637059A (zh) * | 2022-02-15 | 2022-06-17 | 江苏全真光学科技股份有限公司 | 一种抗菌和抗静电性能较强的镜片 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007333806A (ja) * | 2006-06-12 | 2007-12-27 | Fujinon Corp | 反射防止膜および光学部材 |
| CN106772713A (zh) * | 2016-12-27 | 2017-05-31 | 上海康耐特光学股份有限公司 | 一种抗菌镀膜树脂镜片及其制造方法 |
-
2021
- 2021-06-29 CN CN202110724050.4A patent/CN113512703A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007333806A (ja) * | 2006-06-12 | 2007-12-27 | Fujinon Corp | 反射防止膜および光学部材 |
| CN106772713A (zh) * | 2016-12-27 | 2017-05-31 | 上海康耐特光学股份有限公司 | 一种抗菌镀膜树脂镜片及其制造方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114637059A (zh) * | 2022-02-15 | 2022-06-17 | 江苏全真光学科技股份有限公司 | 一种抗菌和抗静电性能较强的镜片 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106772713B (zh) | 一种抗菌镀膜树脂镜片及其制造方法 | |
| JP2020142494A (ja) | 抗菌透明積層体及びその製造方法 | |
| WO2004050132A3 (en) | Medical devices having antimicrobial coatings thereon | |
| RU2014128342A (ru) | Изолирующие стеклопакеты с низкоэмиссионными и антиотражающими покрытиями и/или способы их изготовления | |
| WO2005120154A3 (de) | Abrieb- und kratzfeste beschichtungen mit niedriger brechzahl auf einem substrat | |
| WO2015180455A1 (zh) | 一种驾驶员专用的防强光光学镜片及其制造方法 | |
| WO2007054656A8 (fr) | Substrat muni d'un empilement a proprietes thermiques | |
| RU2014129764A (ru) | Изделия с покрытиями с низкой эмиссионной способностью с системой (системами) барьерных слоев, включающей (включающими) множественные диэлектрические слои, и/или способы их изготовления | |
| CN113512703A (zh) | 一种高效抑菌片的制造工艺 | |
| US10234697B2 (en) | Composite high index layers for anti reflective stacks | |
| CN107728239B (zh) | 一种防蓝光防眩光镀膜树脂镜片及其制备方法 | |
| WO2002004376A1 (fr) | Element photocatalytique | |
| CN206671589U (zh) | 一种抗菌镀膜树脂镜片 | |
| US20230280504A1 (en) | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same | |
| WO2007087269A3 (en) | Antimicrobial coating methods | |
| BR0115898A (pt) | Método para a deposição com processamento a frio de uma camada contra a ofuscação | |
| AU2014355397B2 (en) | Spectacle lens | |
| KR20170086294A (ko) | 다층 코팅 및 이를 포함하는 열처리 곡 성형 및 화학 강화처리가 가능한 컬러코팅 유리 | |
| KR101487309B1 (ko) | 항균기능을 갖는 글라스 및 그 제조방법 | |
| WO2022018279A3 (en) | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same | |
| KR101472356B1 (ko) | 항균기능을 갖는 글라스 및 그 제조방법 | |
| CN105467619A (zh) | 一种杀菌防强光耐磨镜片及其制备方法 | |
| CN114637059A (zh) | 一种抗菌和抗静电性能较强的镜片 | |
| WO2019022383A3 (ko) | 저방사 유리 | |
| CN209055762U (zh) | 一种镀膜不变底色镜片 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20211019 |
|
| RJ01 | Rejection of invention patent application after publication |