CN113502689A - Microbial polysaccharide enhanced high-transparency filter stick forming paper and preparation method thereof - Google Patents

Microbial polysaccharide enhanced high-transparency filter stick forming paper and preparation method thereof Download PDF

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Publication number
CN113502689A
CN113502689A CN202110761870.0A CN202110761870A CN113502689A CN 113502689 A CN113502689 A CN 113502689A CN 202110761870 A CN202110761870 A CN 202110761870A CN 113502689 A CN113502689 A CN 113502689A
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CN
China
Prior art keywords
paper
microbial polysaccharide
transparency
permeability
preparation
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Pending
Application number
CN202110761870.0A
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Chinese (zh)
Inventor
詹建波
李赓
王浩
郑晗
杨扬
谢姣
朝鲁门
刘�文
余振华
王涛
张莹
余耀
余婷婷
岳保山
余江
王旭
程量
李利伟
丁卫
丁海燕
桂永发
张静
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China Tobacco Yunnan Industrial Co Ltd
Original Assignee
China Tobacco Yunnan Industrial Co Ltd
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Filing date
Publication date
Application filed by China Tobacco Yunnan Industrial Co Ltd filed Critical China Tobacco Yunnan Industrial Co Ltd
Priority to CN202110761870.0A priority Critical patent/CN113502689A/en
Publication of CN113502689A publication Critical patent/CN113502689A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/08Filter paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/52Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56Rolls
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Abstract

The invention discloses a preparation method of microbial polysaccharide enhanced high-transparency filter stick wrapping paper, which comprises the following steps: (1) pulping the fiber raw material, blending, dehydrating and forming by an inclined wire paper machine, squeezing and drying by a drying cylinder to prepare high-transparency filter rod forming base paper; (2) and adding a microbial polysaccharide solution into the high-transparency filter rod forming base paper by using a roll coating or dipping glue applying mode, and then drying to obtain the microbial polysaccharide reinforced high-transparency filter rod forming paper. The invention also discloses the high-permeability filter stick wrapping paper obtained by the preparation method and application of the high-permeability filter stick wrapping paper for improving the air permeability of a cigarette filter stick. The high-permeability filter rod wrapping paper enhanced by the microbial polysaccharide can provide the strength required by the wrapping paper on one hand, and can ensure that the wrapping paper has higher air permeability on the other hand.

Description

Microbial polysaccharide enhanced high-transparency filter stick forming paper and preparation method thereof
Technical Field
The invention belongs to the technical field of paper matched with cigarettes, and particularly relates to filter stick forming paper with high air permeability and high strength and a preparation method thereof.
Background
The filter tip wrapping paper is mainly used for wrapping acetate fiber tows in a cigarette filter tip, is positioned between an acetate fiber tow core and an outer layer tipping paper in the structure of the cigarette filter tip, and is divided into a common type and a high-permeability type. The high-permeability filter plug wrap (high-permeability wrap for short) refers to a wrap with higher air permeability, and generally refers to a wrap with air permeability higher than 3000 CU. The cigarette filter tip adopts high-permeability forming paper to dilute smoke, so that the tar content of cigarettes is greatly reduced, and the tar and harm reducing effects are achieved.
The desired high permeability plug wrap needs to have a certain strength in addition to a high air permeability. In order to achieve higher air permeability, the high-permeability filter rod forming paper is low in basis weight, the beating degree of the used paper pulp is low, but the strength performance of the lower beating degree formed paper is poor, the strength is too low, paper breakage is easy to occur during paper machine production, the production efficiency is influenced, and the hair falling phenomenon is serious during filter rod processing, so that the strength of the paper needs to be increased by utilizing a reinforcing agent, and in order to achieve an ideal effect, the air permeability of the paper is not influenced while the reinforcing agent is required to be enhanced.
The dry strength agent commonly used in the paper making industry mainly comprises organic synthetic high molecular compounds and polysaccharide and derivatives thereof, such as PVA, oxidized starch and the like, and in consideration of the safety of the auxiliary agent for the tobacco products, the reinforcing agent of the paper matched with the cigarettes does not generally adopt the organic synthetic high molecular compounds, but mainly adopts polysaccharide substances.
The polysaccharide is widely available, and can be obtained from animal and plant, or obtained by microorganism fermentation technology. The microbial polysaccharide is a biopolymer which is generated by microorganisms such as bacteria, fungi, blue algae and the like in a metabolic process and has a protection effect on the microorganisms, and the microbial polysaccharide has wide attention due to stable performance and high quality and high efficiency in recent years.
The invention provides a method for improving high-permeability plug wrap paper by utilizing microbial polysaccharide for the first time, and the method is used for preparing filter stick plug wrap paper with high air permeability and high strength so as to meet the production, processing and use requirements of the cigarette industry.
Disclosure of Invention
The invention provides a high-permeability filter stick forming paper enhanced by utilizing microbial polysaccharide and a preparation method thereof, and the obtained high-permeability filter stick forming paper is used for improving the air permeability of a cigarette filter stick.
In order to achieve the purpose, the invention adopts the technical scheme that:
the invention discloses a preparation method of microbial polysaccharide enhanced high-transparency filter rod wrapping paper, which comprises the following steps:
(1) pulping the fiber raw material, blending, dehydrating and forming by an inclined wire paper machine, squeezing and drying by a drying cylinder to prepare high-transparency filter rod forming base paper;
(2) and adding a microbial polysaccharide solution into the high-transparency filter rod forming base paper by using a roll coating or dipping glue applying mode, and then drying to obtain the microbial polysaccharide reinforced high-transparency filter rod forming paper.
Preferably, the microbial polysaccharide in the step (2) is one or more of pullulan polysaccharide (also called aureobasidium pullulans), glucan or alpha-cyclodextrin; the gluing amount of the microbial polysaccharide is 1-20% of the quality of the high-transparency filter stick wrap paper.
Preferably, the fiber raw material in the step (1) is one or more of softwood pulp, softwood mercerized pulp or viscose fiber.
Preferably, the softwood pulp accounts for 50-100% by mass, and the beating degree of the softwood pulp is 12-25 DEG SR; the needle-leaved wood silk polishing slurry accounts for 0-50% by mass, and the beating degree of the needle-leaved wood silk polishing slurry is 10-25 DEG SR; the mass percentage of the viscose fiber is 0-50%.
Preferably, in the batching process in the step (1), a wet strength agent is added into the pulp, and the amount of the wet strength agent is 0.1-1.5% of the mass of the dry weight of the fiber raw material.
Preferably, the wet strength agent is a polyamide epichlorohydrin resin (PAE).
The raw materials used in the preparation method are all food-grade products.
The invention discloses the high-transparency filter stick wrapping paper prepared by the preparation method in a second aspect.
Preferably, the performance of the high-permeability plug wrap is as follows: the quantitative content is 24-30g/m2Tensile energy absorption value of not less than 10J/m2The air permeability is 5000-30000CU, and the air permeability variation coefficient is less than or equal to 10 percent.
The third aspect of the invention discloses application of the high-permeability filter plug wrap paper in improving the air permeability of a cigarette filter.
The raw materials used in the preparation method are all food-grade products.
The invention has the beneficial effects that:
1. the invention uses the high-transparency filter stick forming paper enhanced by microbial polysaccharide for the first time. The microbial polysaccharide is one or more of pullulan polysaccharide (also called aureobasidium pullulans polysaccharide), glucan or alpha-cyclodextrin. Pullulan is a polymeric polysaccharide formed by repeatedly connecting glucose into maltotriose through alpha-1, 4-glycosidic bond combination, and other maltotriose through alpha-1, 6-glycosidic bond combination at two ends. Dextran is an oligosaccharide formed by polymerization of several glucose molecules, and has a branched structure. Alpha-cyclodextrin is a cyclic oligosaccharide compound consisting of 6 glucose units linked by 1, 4-glycosidic bonds. The microbial polysaccharide structure contains more hydroxyl, and the microbial polysaccharide structure can be combined with the hydroxyl in the fiber to form a hydrogen bond after being added into paper, so that the strength of the paper is increased. The high-permeability filter rod wrapping paper enhanced by the microbial polysaccharide can provide the strength required by the wrapping paper on one hand, and can ensure that the wrapping paper has higher air permeability on the other hand.
2. According to the invention, softwood pulp with low beating degree is taken as a main raw material for papermaking, so that on one hand, the strength required by papermaking can be provided, and on the other hand, higher air permeability can be ensured. The coniferous wood yarn smooth pulp or viscose fiber is matched in the filter stick forming paper, so that the bulk and porosity of the paper can be improved, the air permeability is increased, and the high-air-permeability filter stick forming paper with the air permeability higher than 20000CU can be prepared.
Detailed Description
The present invention will be described in further detail with reference to examples, but the following examples are not intended to limit the present invention. All percentages used in the present invention are mass percentages unless otherwise indicated.
Example 1
The raw material of the fiber is 100 percent of softwood pulp, the beating degree is 18 DEG SR, the adding amount of the PAE wet strength agent in the paper pulp is 0.5 percent of the dry fiber mass, and the paper pulp is subjected to dehydration forming, squeezing and drying by a drying cylinder by an inclined wire paper machine to prepare the high-transparency filter rod forming base paper. And (3) dipping the base paper in a pullulan solution, and drying the base paper by a drying part to obtain the high-transparency filter stick forming paper, wherein the gluing amount of the pullulan is 4.5 percent of the quality of the high-transparency filter stick forming paper.
The performance of the plug wrap obtained in this example was as follows: quantitative determination of 25.2g/m2Tensile energy absorption value of 19.7J/m2Air permeability of 7012CU, air permeability coefficient of variation of 4.8%.
Comparative example 1
The base paper was the same as in example 1, the base paper impregnation solution was oxidized starch, and the sizing amount was 4.5% of the mass of the high-permeability plug wrap. The properties of the obtained plug wrap were as follows: quantitative determination of 25.0g/m2Tensile energy absorption value of 13.6J/m2Air permeability 6442CU, air permeability coefficient of variation 6.53%.
Comparative example 2
The base paper was the same as in example 1, except that the base paper impregnation solution was PVA (polyvinyl alcohol) and the sizing amount was 4.5% of the mass of the high-permeability plug wrap. The properties of the obtained plug wrap were as follows: quantitative determination of 25.3g/m2Tensile energy absorption value of 14.2J/m26236CU, air permeability coefficient of variation of 5.67%.
As can be seen from a comparison of example 1 with comparative examples 1 and 2, the use of pullulan for reinforcing high-permeability plug wrap has less influence on air permeability, but the strength (tensile energy absorption value) is superior to that of oxidized starch or PVA-reinforced high-permeability plug wrap.
Example 2
The fiber raw materials are 65% of softwood pulp and 35% of softwood silk polish; the beating degree of softwood pulp is 18 degrees SR, and the beating degree of mercerized pulp is 12 degrees SR; the addition amount of the PAE wet strength agent in the paper pulp is 0.5 percent of the mass of the absolutely dry fiber; and (3) carrying out dewatering forming, squeezing and drying treatment on the paper pulp by using an inclined wire paper machine to obtain the high-transparency filter rod forming base paper. And (3) rolling a pullulan solution on the base paper, and drying the base paper by a drying part to prepare the high-transparency filter stick forming paper, wherein the gluing amount of the pullulan is 9.0 percent of the quality of the high-transparency filter stick forming paper.
The performance of the plug wrap prepared in this example was as follows: quantitative determination of 26.7g/m2Tensile energy absorption value of 13.5J/m2Air permeability 20124CU, and an air permeability coefficient of variation of 3.2%.
Comparative example 3
The base paper was the same as in example 2, the base paper impregnation solution was oxidized starch, and the sizing amount was also 9.0% of the quality of the high-permeability plug wrap. The properties of the obtained plug wrap were as follows: quantitative determination of 26.2g/m2Tensile energy absorption value of 9.82J/m2Air permeability 18403CU, air permeability coefficient of variation 7.25%.
As can be seen from a comparison of example 2 and comparative example 3, the use of pullulan to reinforce a high-permeability plug wrap also had less effect on air permeability, but the strength (tensile energy absorption value) was also superior to that of oxidized starch-reinforced high-permeability plug wrap.
Example 3
The fiber raw materials are 80% of softwood pulp and 20% of viscose fiber; the beating degree of the softwood pulp is 20 DEG SR, and the addition amount of the PAE wet strength agent in the paper pulp is 0.7 percent of the mass of absolute dry fibers; and (3) carrying out dewatering forming, squeezing and drying treatment on the paper pulp by using an inclined wire paper machine to obtain the high-transparency filter rod forming base paper. And (3) roller-coating a pullulan and alpha-cyclodextrin mixed solution on the base paper, and drying the base paper by a drying part to prepare the high-transparency filter stick forming paper, wherein the gluing amount of the polysaccharide is 10.0 percent of the quality of the high-transparency filter stick forming paper.
The performance of the plug wrap prepared in this example was as follows: quantitative determination of 28.1g/m2Tensile energy absorption value of 17.8J/m2The air permeability is 11063CU, and the air permeability coefficient of variation is 2.9%.
Example 4
The fiber raw materials comprise 60% of softwood pulp, 25% of viscose fiber and 15% of softwood silky luster pulp; the beating degree of the softwood pulp is 19 DEG SR, and the addition amount of the PAE wet strength agent in the paper pulp is 0.6 percent of the mass of absolute dry fibers; and (3) carrying out dewatering forming, squeezing and drying treatment on the paper pulp by using an inclined wire paper machine to obtain the high-transparency filter rod forming base paper. And (3) dipping the base paper in the mixed solution of pullulan polysaccharide and glucan, and drying the base paper by a drying part to obtain the high-transparency filter stick forming paper, wherein the gluing amount of the polysaccharide is 12.2% of the mass of the high-transparency filter stick forming paper.
The performance of the plug wrap prepared in this example was as follows: quantitative determination of 25.5g/m2Tensile energy absorption value of 16.9J/m2Air permeability 25373CU, air permeability coefficient of variation 2.6%.
From examples 3 and 4, it is clear that the use of a high permeability plug wrap reinforced with a microbial polysaccharide provides the strength required for the wrap, while also ensuring a high air permeability of the wrap.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (9)

1. A preparation method of microbial polysaccharide enhanced high-transparency filter rod wrapping paper is characterized by comprising the following steps:
(1) pulping the fiber raw material, blending, dehydrating and forming by an inclined wire paper machine, squeezing and drying by a drying cylinder to prepare high-transparency filter rod forming base paper;
(2) and adding a microbial polysaccharide solution into the high-transparency filter rod forming base paper by using a roll coating or dipping glue applying mode, and then drying to obtain the microbial polysaccharide reinforced high-transparency filter rod forming paper.
2. A high-transparency filter plug wrap according to claim 1, wherein the microbial polysaccharide in the step (2) is one or more of pullulan, glucan or alpha-cyclodextrin; the gluing amount of the microbial polysaccharide is 1-20% of the quality of the high-transparency filter stick wrap paper.
3. The preparation method according to claim 1, wherein the fiber raw material in the step (1) is one or more of softwood pulp, softwood mercerized pulp or viscose fiber.
4. The preparation method according to claim 3, wherein the softwood pulp is 50-100% in mass percent and has a freeness of 12-25 ° SR; the needle-leaved wood silk polishing slurry accounts for 0-50% by mass, and the beating degree of the needle-leaved wood silk polishing slurry is 10-25 DEG SR; the mass percentage of the viscose fiber is 0-50%.
5. The method for preparing the fiber raw material, according to the claim 1, is characterized in that in the batching process of the step (1), a wet strength agent is added into the pulp, and the amount of the wet strength agent is 0.1-1.5% of the mass of the fiber raw material.
6. The method of manufacturing according to claim 5, characterized in that the wet strength agent is a polyamide epichlorohydrin resin.
7. A high-permeability plug wrap prepared by the preparation method according to any one of claims 1 to 6.
8. A high transmission plug wrap according to claim 7, wherein said high transmission plug wrap is of a natureCan be as follows: the quantitative content is 24-30g/m2Tensile energy absorption value of not less than 10J/m2The air permeability is 5000-30000CU, and the air permeability variation coefficient is less than or equal to 10 percent.
9. Use of a high permeability plug wrap according to claim 7 or 8 for increasing the air permeability of a cigarette filter.
CN202110761870.0A 2021-07-06 2021-07-06 Microbial polysaccharide enhanced high-transparency filter stick forming paper and preparation method thereof Pending CN113502689A (en)

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* Cited by examiner, † Cited by third party
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CN114960267A (en) * 2022-05-27 2022-08-30 云南中烟工业有限责任公司 Aerogel filter rod spirally wrapped by double-layer high-transparency forming paper
CN115182199A (en) * 2022-06-14 2022-10-14 浙江凯恩新材料有限公司 High-strength high-stiffness high-transparency filter stick forming paper, preparation method, application and cigarette product

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114960267A (en) * 2022-05-27 2022-08-30 云南中烟工业有限责任公司 Aerogel filter rod spirally wrapped by double-layer high-transparency forming paper
CN115182199A (en) * 2022-06-14 2022-10-14 浙江凯恩新材料有限公司 High-strength high-stiffness high-transparency filter stick forming paper, preparation method, application and cigarette product

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