CN113475523B - Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof - Google Patents
Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof Download PDFInfo
- Publication number
- CN113475523B CN113475523B CN202110569374.5A CN202110569374A CN113475523B CN 113475523 B CN113475523 B CN 113475523B CN 202110569374 A CN202110569374 A CN 202110569374A CN 113475523 B CN113475523 B CN 113475523B
- Authority
- CN
- China
- Prior art keywords
- hydrolysis
- combination
- acid
- resistant silicone
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention provides an aqueous solution containing a hydrolysis-resistant organic silicon auxiliary agent, which comprises a raw pesticide, a surfactant, a cosurfactant, an antifreeze agent, a thickening agent, a pH regulator, water, a hydrolysis-resistant organic silicon auxiliary agent and a hydrolysis inhibitor; the hydrolysis-resistant organic silicon assistant is polyether modified organic siloxane which is substituted at the end of a polyether block or is improved in a polyether block structure; the hydrolysis inhibitor is selected from any one of or a combination of at least two of methyldichlorosilane, aminopropylsilane, monosilane and disilane. The water aqua has the advantages of good spreading performance, strong wetting performance, rain wash resistance and better drug effect.
Description
Technical Field
The invention relates to the technical field of agriculture, in particular to an aqueous solution containing a hydrolysis-resistant organic silicon assistant and a preparation method thereof.
Background
The appearance of pesticide makes human beings get rid of the fate of eating by the weather, but simultaneously it also brings the problem of environmental pollution. The current environment-friendly green pesticide has higher creation cost and higher difficulty, the pesticide water aqua has the advantages of small environmental pollution, low toxicity to people and livestock, difficult generation of phytotoxicity, safe storage and transportation and the like, but because the water aqua does not contain an emulsifier, the adhesion performance of the water aqua on the surface of crops is relatively poor, and the pesticide effect is inferior to that of missible oil.
The agricultural organic silicon additive serving as an efficient additive has the following advantages: 1. the pesticide spreading agent is a super strong spreading agent, can wet all plants, spreads the liquid medicine to all hidden parts of crops, and better exerts the pesticide effect; 2. the pesticide is resistant to rain wash, the pesticide liquid remained on the surfaces of crops is only 20-30% in the traditional pesticide spraying, and the amount of the pesticide liquid is less in rainy days. After the agricultural organic silicon additive is used, the pesticide is retained on the surface of crops to a greater extent, so that the utilization rate of the pesticide is improved; 3. the capability of the liquid medicine to penetrate through the pores of the insects is improved, so that better pesticide effect is achieved; 4. can reduce the water consumption and the dosage and save the labor cost. The agricultural organic silicon additive is added into the aqueous solution, so that the surface tension of the aqueous solution can be effectively reduced, and the aqueous solution can exert a greater drug effect. The traditional agricultural organosilicon mainly takes trisiloxane or polysiloxane as a hydrophobic chain, but has the problem of easy hydrolysis, and the surface activity of the organosilicon auxiliary agent can be obviously reduced after the organosilicon auxiliary agent is hydrolyzed, so the organosilicon auxiliary agent can be generally used only as a tank-mixing auxiliary agent and is prepared before application, and the use by farmers is inconvenient. The traditional agricultural organic silicon assistant can keep surface activity for a long time in a pH neutral environment, but is easy to hydrolyze when the pH is too acidic or too alkaline, and at present, a plurality of experts at home and abroad are in research on hydrolysis-resistant organic silicon assistants. Momentov performance materials incorporated discloses a hydrolysis resistant organomodified dioxysilane surfactant (CN101959417A) and a hydrolysis resistant organomodified trioxasilane surfactant (CN103070168A) which are resistant to hydrolysis at a pH of about 3 to 12. Shandong university of agriculture discloses a preparation method of an anti-hydrolysis organosilane surfactant (CN102993225A), which has good anti-hydrolysis capability under acidic conditions. However, currently, there are few silicone adjuvant products that are applied to aqueous formulations.
In view of the above, the present invention is specifically proposed.
Disclosure of Invention
The invention provides an aqueous solution containing an anti-hydrolysis organosilicon auxiliary agent, which has the advantages of good spreading performance, strong wetting performance, rain wash resistance and better drug effect.
The basic concept adopted by the invention is as follows:
an aqueous solution containing a hydrolysis-resistant organic silicon auxiliary agent comprises a raw pesticide, a surfactant, a cosurfactant, an antifreeze agent, a thickening agent, a pH regulator, water, a hydrolysis-resistant organic silicon auxiliary agent and a hydrolysis inhibitor;
the hydrolysis-resistant organic silicon assistant is polyether modified organic siloxane which is substituted at the end of a polyether block or is improved in a polyether block structure;
the hydrolysis inhibitor is selected from any one of or a combination of at least two of methyldichlorosilane, aminopropylsilane, monosilane and disilane.
By way of one approach, the hydrolysis-resistant silicone additive comprises a material having the structure:
wherein m is 1-20, n is 1-10, x is 1-10, and y is 0-10.
Optionally, the surface tension of the hydrolysis-resistant organic silicon assistant is 20.6-24.1 mN/m, and the molecular weight is 479-2685.
Optionally, the hydrolysis-resistant organic silicon additive is selected from hydrolysis-resistant organic silicon additive of Mi image brand Xiwei HS604, hydrolysis-resistant organic silicon additive of Hangzhou Chongyao science and technology brand 249, high-temperature-resistant and hydrolysis-resistant organic silicon wetting agent of Anhui chemical industry Co., Ltd, hydrolysis-resistant organic silicon surfactant of Zhejiang Runjin and organic silicon new material Co., Ltd, double-tail trisiloxane surfactant of Huizhou university, double-tail trisiloxane surfactant of Hangzhou province, and double-tail trisiloxane surfactant of Hangzhou province,
319B, SE-640 and SE-429 as well as at least one of these three components.
Optionally, the hydrolysis resistant silicone additive is a combination of HS604 and 3249, HS604 and
319B or 3249 and methylallyl polyether modified trisiloxane SE-429.
As a mode, the hydrolysis-resistant organosilicon auxiliary agent accounts for 0.3-12% of the aqueous solution, preferably 0.8-8%, and more preferably 1-4.5%;
the mass fraction of the hydrolysis inhibitor in the aqueous solution is 0.01-5%, preferably 1-3%, and more preferably 1.5-3%.
As one mode, the technical product comprises glyphosate, ammonium glyphosate, potassium glyphosate, dimethylamine glyphosate, isopropylamine glyphosate, glufosinate, diquat, hymexazol, dicamba, isopropylamine dicamba, dimethylamine dicamba, validamycin, kasugamycin, ningnanmycin, lime sulphur, bentazone, 2,4 drops of triethanolamine, 2,4 drops of dimethylamine, pyrimidine nucleoside antibiotics, chlormequat chloride, 2 methyl 4 chloride sodium salt, 2 methyl 4 chloride dimethylamine salt, 2 methyl 4 chloride isopropylamine salt, ethephon, amobam, dimehypo, fomesafen, acifluorfen, propamocarb hydrochloride, picloram, methoxyfenamic acid, mefenamic acid, ammonium mefenamic acid, formamidine hydrochloride, choline chloride, oligosaccharins, amino oligosaccharins, lentinan, 14-hydroxy brassinol, 14-hydroxy brassinosteroids, Carvacrol, matrine, indoleacetic acid, berberine hydrochloride, chitosan, maleic hydrazide, clopyralid, nitenpyram, S-abscisic acid, triclopyr triethylamine salt, polyoxin, naphthylacetic acid, metham, imazazole sulfate, zhongshengmycin, diethyl aminoethyl hexanoate, tetramycin, xinafamine acetate, benzylaminopurine, furfurylaminopurine, emodin methyl ether, mepiquat, bacillus subtilis, brassinolide, propionyl brassinolide, 28-epihomobrassinolide, cyanamide, peroxyacetic acid, compound sodium nitrophenolate, paraquat, pyrimidine nucleoside antibiotics, cuaminosulfate, difenzoquat, imazethapyr, and C-type botulinum toxin.
By way of example, the prodrug is a combination of 2 methyl 4 chloroisopropylamine salt and glyphosate isopropylamine salt, a combination of glyphosate ammonium salt and glufosinate, a combination of dicamba isopropylamine salt and glyphosate isopropylamine salt, a combination of 2,4 d dimethylamine salt and glyphosate isopropylamine salt, a combination of 2 methyl 4 chloro and glyphosate, a combination of bentazone and bispyribac-sodium, or a combination of a carbamyl ester and ethephon.
In one embodiment, the surfactant is obtained by blending a surfactant having an HLB value of 8 to 18 and having hydrophilicity and a surfactant having lipophilicity at a volume ratio of 1: 8-8: 1.
in one embodiment, the hydrophilic surfactant is a nonionic surfactant, and the lipophilic surfactant is an anionic surfactant.
The hydrophilic surfactant comprises one or a combination of at least two of tallow amine polyoxyethylene ether, alkylaryl polyoxyethylene ether, alkylaryl formaldehyde resin polyoxyethylene ether, benzyl diphenol polyoxyethylene ether, phenethyl phenol polyoxyethylene (n ═ 15-30) ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, nonylphenol polyoxyethylene ether, phenethyl nonylphenol polyoxyethylene ether, diphenol polyoxyethylene ether, alkylphenol polyoxyethylene ether formaldehyde condensate, octane glycoside ethyl trimethyl ammonium chloride, decane glycoside ethyl trimethyl ammonium chloride, dodecaneglycoside ethyl trimethyl ammonium chloride, tetradecane glycoside ethyl trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride and betaine.
As one mode, the nonionic surfactant is a combination of the agricultural emulsion 100# and alkylaryl formaldehyde resin polyoxyethylene ether, a combination of alkylaryl polyoxyethylene ether and phenethyl nonylphenol polyoxyethylene ether, a combination of nonylphenol polyoxyethylene ether and benzyl diphenol polyoxyethylene ether, or a combination of the agricultural emulsion 600#, alkylaryl polyoxyethylene ether and diphenol polyoxyethylene ether, a combination of octoglycoside ethyl trimethyl ammonium chloride and dodecyl trimethyl ammonium chloride, or a combination of tetradecane glycoside ethyl trimethyl ammonium chloride and dodecyl trimethyl ammonium chloride.
As one mode, the lipophilic surfactant is one or a combination of at least two of fatty alcohol ether sodium sulfate, fatty alcohol ether carboxylate, fatty alcohol polyoxyethylene ether phosphate, dodecylbenzene sulfonic acid, sodium dodecylbenzene sulfonate, farm emulsion 2000#, sulfated castor oil aqueous solution, sodium dodecylsulfate, styrene polyoxyethylene ether ammonium sulfate salt and alpha-sodium alkenyl sulfonate.
Optionally, the anionic surfactant is a combination of agricultural milk 2000# and fatty alcohol polyoxyethylene ether phosphate, a combination of dodecylbenzene sulphonic acid and agricultural milk 2000#, or a combination of sodium lauryl sulphate, an aqueous solution of sulphated castor oil and sodium alpha-alkenyl sulphonate.
In one mode, the cosurfactant is one of ethanol, ethylene glycol, n-butanol, n-pentanol, n-hexanol, n-heptanol, n-octanol, isopropanol, primary pentanol, secondary pentanol, n-butyric acid, glycerol, polyglycerol ester or a combination of at least two thereof.
By one approach, the co-surfactant is a combination of ethanol and n-heptanol, glycerol and isopropanol, or a combination of n-butyric acid, n-pentanol and primary pentanol.
In one mode, the antifreeze is one or a combination of at least two of methanol, ethanol, ethylene glycol, propylene glycol, urea, water-soluble amide and calcium chloride.
Optionally, the antifreeze agent is a combination of methanol and urea, ethylene glycol and calcium chloride, ethanol and urea, or ethanol, a water-soluble amide and calcium chloride.
Optionally, the thickener is any one of or a combination of at least two of sodium chloride, potassium chloride, ammonium chloride, monoethanolamine chloride, diethanolamine chloride, sodium sulfate, sodium phosphate, disodium phosphate and pentasodium triphosphate, lauryl alcohol, myristyl alcohol, decyl alcohol, hexanol, octanol, cetyl alcohol, stearyl alcohol, behenyl alcohol, lauric acid, linoleic acid, linolenic acid, myristic acid, stearic acid, starch, gum arabic, pectin, agar, gelatin, algin, carrageenan, dextrin, magnesium aluminum silicate, xanthan gum.
Optionally, the thickener is a combination of sodium chloride and dextrin, lauryl alcohol and stearic acid, starch and pectin, sodium phosphate and xanthan gum, or potassium chloride, decanol and linoleic acid.
Optionally, the pH adjusting agent is any one of or a combination of at least two of citric acid, hydrochloric acid, potassium citrate, sodium citrate, dimethylamine, malic acid, lactic acid, tartaric acid, adipic acid, isopropylamine, fumaric acid, phosphoric acid, sodium carbonate, carbonic acid, sodium hydroxide, potassium hydroxide, and ammonia.
Optionally, the pH adjusting agent is a combination of sodium hydroxide and potassium hydroxide, isopropylamine and dimethylamine, hydrochloric acid and fumaric acid, or adipic acid, sodium carbonate and tartaric acid.
In one mode, the mass fractions of the components in the aqueous solution are as follows:
by one way, the content of each component in the water agent is as follows:
the invention also provides a preparation method of the aqueous solution containing the hydrolysis-resistant organic silicon assistant, and the aqueous solution is obtained by uniformly mixing all the components in the aqueous solution.
As one mode, the preparation method comprises the following steps:
mixing the raw pesticide, water, an antifreeze agent, a thickening agent and a pH regulator to form a solution A, mixing a surfactant, a cosurfactant, a hydrolysis-resistant organic silicon additive and a hydrolysis inhibitor to form a solution B, adding the solution A into the solution B under a high-speed shearing condition, shearing for 5-15 min, and regulating to 5-8 by using the pH regulator to obtain the water-soluble organic silicon polymer.
Optionally, the shearing speed of the high-speed shearing condition is 10000-15000 r/min.
Compared with the prior art, the invention has the following advantages:
1. the hydrolysis-resistant organic silicon assistant is polyether modified organic siloxane, and is structurally improved compared with the conventional polyether modified organic silicon assistant, for example, a polyether block is improved from side substitution to end substitution, or the structure of the polyether block is improved, so that the molecular weight is larger; the anti-hydrolysis organosilicon auxiliary agent has lower surface tension (20.3 mN/m-24.1 mN/m), and the surface activity in an aqueous system is kept stable for a long time, the hydrolysis problem is avoided, and the good surface performance can be kept stably for a long time.
2. Furthermore, the hydrolysis inhibitor comprises any one or at least two of methyl dichlorosilane, aminopropyl silane, monosilane, disilane and the like, and is compounded and combined with the hydrolysis-resistant organic silicon assistant for use, so that the prepared water agent has clear and transparent appearance, and the product appearance and other quality control indexes are not abnormal after storage stability test and long-term stability test, thereby meeting the requirements.
3. Furthermore, a pH buffer reagent is added in the water aqua disclosed by the invention, the stability of the pH value of the water aqua is ensured, and the hydrolysis-resistant organic silicon auxiliary agent further reduces the probability of hydrolysis in a relatively mild environment.
4. Furthermore, a hydrolysis inhibitor is added into the water aqua, the hydrolysis inhibitor is further selectively added on the basis of the hydrolysis-resistant organic silicon assistant, and the preferred hydrolysis inhibitor can effectively inhibit the hydrolysis of the hydrolysis-resistant organic silicon assistant under extreme conditions.
5. The water aqua provided by the invention has obviously improved drug effect, can reduce the dosage of the preparation, and can reduce the dosage by at least 20%; the water aqua provided by the invention has low toxicity, is environment-friendly and has low toxicity to people and livestock.
6. The addition amount of the hydrolysis-resistant organosilicon auxiliary agent in the aqueous solution provided by the invention is higher than that in the conventional use, and the effect of the effective components in the aqueous solution can be better enhanced.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention are clearly and completely described below. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without any inventive step, are within the scope of protection of the invention.
The chemical agent not specifically described in the present invention is a general chemical agent commercially available.
The invention provides an aqueous solution containing a hydrolysis-resistant organic silicon auxiliary agent, which comprises a raw pesticide, a surfactant, a cosurfactant, an antifreeze agent, a thickening agent, a pH regulator, water, a hydrolysis-resistant organic silicon auxiliary agent and a hydrolysis inhibitor;
the hydrolysis-resistant organic silicon assistant is polyether modified organic siloxane which is substituted at the end of a polyether block or is improved in a polyether block structure;
the hydrolysis inhibitor is selected from any one or the combination of at least two of methyldichlorosilane, aminopropylsilane, monosilane and disilane.
By one approach, the hydrolysis-resistant silicone additive includes a material having the structure:
wherein m is 1-20, n is 1-10, x is 1-10, and y is 0-10.
In some specific embodiments, the anti-hydrolysis organosilicon auxiliary agent is selected from anti-hydrolysis organosilicon auxiliary agent of Mediachwei HS604, anti-hydrolysis organosilicon auxiliary agent of Chongzhou Chongyao science and technology No. 249, high-temperature-resistant and hydrolysis-resistant organosilicon wetting agent of Anhui chemical industry Co., Ltd, hydrolysis-resistant organosilicon surfactant of Zhejiang Runjiang and organosilicon new material Co., Ltd, double-tail trisiloxane surfactant of Huizhou university, double-tail trisiloxane surfactant of Heizhou Kaishu,
319B, SE-640 and SE-429 as well as at least one of these three components.
In some embodiments, the hydrolysis resistant silicone additive is a combination of HS604 and 3249, HS604 and
319B, or 3249 and methallyl polyether modified trisiloxane SE-429.
3249, SE-429 and SE-429 used in the examples of the present invention
319B procurement information for hydrolysis-resistant silicone adjuvants is shown in Table 1 below.
TABLE 1
In some specific embodiments, the aqueous solution containing the hydrolysis-resistant organosilicon auxiliary agent comprises the following components in percentage by mass:
in some embodiments, the content of each component in the aqueous solution is as follows:
example 1
Formulation 1 is as follows: 41% of glyphosate isopropylamine salt, 32490.5%, 2% of methyldichlorosilane, 1% of benzyldiphenol polyoxyethylene ether, 8% of fatty alcohol ether sodium sulfate, 3.2% of isopropylamine, 3% of glycerol, 1.5% of ethylene glycol, 2% of sodium sulfate and the balance of water to 100%.
Example 2
Formulation 2 was as follows: 41% of glyphosate isopropylamine salt, HS 6042.1%, 1.5% of methyldichlorosilane, 3.2% of dodecyl trimethyl ammonium chloride, 2.5% of sodium dodecyl sulfate, 3% of n-hexanol, 2.6% of isopropylamine, 2.5% of n-heptanol, 1.5% of urea, 2% of pectin and water to be the balance of 100%.
Example 3
Formulation 3 is as follows: 2.5% of dicamba isopropylamine salt, 50.5% of glyphosate isopropylamine salt, SE-4291.3% of methyl allyl polyether modified trisiloxane, 1.5% of aminopropylsilane, 1.5% of alkylaryl polyoxyethylene ether, 6.5% of fatty alcohol ether sodium sulfate, 2.6% of ethanol, 1.5% of urea, 2% of hexanol, 1.5% of isopropylamine and water, wherein the water is supplemented to 100%.
Example 4
Formulation 4 is as follows: 48% of dicamba isopropylamine salt, 32492%, 2% of monosilane, 4% of octodecyl ethyl trimethyl ammonium chloride, 8% of sodium dodecyl benzene sulfonate, 5.1% of isopropanol, 2.5% of urea, 2% of gelatin, 2% of isopropylamine and the balance of water to 100%.
Example 5
Formulation 5 is as follows: 14% of dicamba dimethylamine salt, 30% of 2, 4-D dimethylamine salt, 32491%, 1.8% of methyl dichlorosilane, 4% of nonylphenol polyoxyethylene ether, 0.5% of agricultural emulsion 2000#, 5% of ethylene glycol, 2% of propylene glycol, 2% of dimethylamine, 1% of potassium chloride and the balance of water to 100%.
Example 6
Formulation 6 is as follows: 19% of glufosinate-ammonium, 4291% of methyl allyl polyether modified trisiloxane SE-4291%, 2.0% of monosilane, 4% of dodecyl glucoside ethyl trimethyl ammonium chloride, 2000# of agricultural emulsion, 3.8% of n-butyric acid, 2% of urea, 2% of lauric acid, 1% of citric acid and water, wherein the water is added to the total amount of 100%.
Example 7
Formulation 7 was as follows: 30% of glufosinate-ammonium, 6041.1% of HS, 1.5% of methyl dichlorosilane, 3.6% of alkylaryl polyoxyethylene ether, 5.5% of styrene polyoxyethylene ammonium sulfate, 3% of ethanol, 2% of urea, 2% of lauric acid, 1% of citric acid and water, wherein the water is added to 100%.
Example 8
Formulation 8 is as follows: 33% of glyphosate ammonium salt, 6% of glufosinate ammonium, HS 6042%, 2% of disilane, 5% of betaine, 5% of styrene polyoxyethylene ether ammonium sulfate salt, 3% of n-octanol, 2% of urea, 2% of lauric acid, 1% of ammonia water and the balance of water to 100%.
Example 9
Formulation 9 is as follows: 10% of glufosinate-ammonium, 3% of sodium dimethyltetrachloro-salt, 32494.5%, 3.0% of methyl dichlorosilane, 5.8% of phenethyl phenol polyoxyethylene (n-15-30) ether, 5.4% of dodecylbenzene sulfonic acid, 3.5% of ethylene glycol, 2% of urea, 2% of lauric acid, 1% of ammonia water and the balance of water to 100%.
Example 10
Formulation 10 is as follows: 20 percent of diquat,
319B 2％、2.5% of disilane, 3% of alkyl aryl formaldehyde resin polyoxyethylene ether, 15% of styrene polyoxyethylene ether ammonium sulfate, 4% of n-butyric acid, 3% of urea, 1% of citric acid, 1% of sodium chloride and the balance of water to 100%.
Example 11
Formulation 11 was as follows: 25 percent of bentazone,
319B 1.3%, disilane 1.6%, phenethylphenol polyoxyethylene (n 15-30) ether 6.8%, sodium alpha-olefin sulfonate 2%, n-butanol 4.5%, urea 2%, lauric acid 2%, ammonia 1%, and water in balance to 100%
Example 12
Formulation 12 is as follows: 20% of diquat, 32492.2%, 2.6% of methyl dichlorosilane, 5% of alkyl aryl formaldehyde resin polyoxyethylene ether, 6% of dodecyl benzene sulfonic acid, 3% of ethanol, 2% of urea, 2% of lauric acid, 1% of ammonia water and the balance of water to 100%.
Example 13
Formulation 13 is as follows: 65% of 2 methyl 4 chlorodimethylamine salt, HS 6041.3%, 2.3% of methyl dichlorosilane, 5% of tetradecane glycoside ethyl trimethyl ammonium chloride, 11% of alpha-sodium alkenyl sulfonate, 3% of glycol, 2% of urea, 2% of lauric acid, 1% of dimethylamine and the balance of water to 100%.
Example 14
Formulation 14 is as follows: 8 percent of ningnanmycin,
319B 2%, disilane 1.5%, nonylphenol polyoxyethylene ether 4%, sodium dodecyl sulfate 10%, n-hexyl alcohol 4%, urea 2%, lauric acid 2%, ammonia water 1%, and water to 100%.
Example 15
Formulation 15 is as follows: 2 percent of kasugamycin,
319B 3%, disilane 2.5%, phenethylphenol polyoxyethylene (n 15-30) ether 2%, sodium alpha-olefin sulfonate 11%, ethylene glycol 5%, and urine2% of essence, 2% of lauric acid, 1% of ammonia water and water to 100%.
Example 16
Formulation 16 was as follows: 2.4% of validamycin, 32491%, 2% of methyl dichlorosilane, 13% of benzyl diphenol polyoxyethylene ether, 2% of alpha-sodium alkenyl sulfonate, 3.5% of isopropanol, 5% of urea, 2% of citric acid, 2% of pectin and water in balance to 100%.
Example 17
Formulation 17 was as follows: 15% of hymexazol, 32494%, 4.5% of methyl dichlorosilane, 5% of tallow amine polyoxyethylene ether, 4.7% of dodecyl benzene sulfonic acid, 2% of ethylene glycol, 0.05% of xanthan gum, 4% of urea, 1% of dimethylamine and water to be supplemented to 100%.
Example 18
Formulation 18 is as follows: 18 percent of dimehypo,
319B 1%, disilane 1.5%, benzyldiphenol polyoxyethylene ether 4%, alpha-sodium alkenyl sulfonate 5%, primary amyl alcohol 3%, urea 3%, ammonium chloride 2%, isopropylamine 1%, and water to 100%.
Example 19
Formulation 19 was as follows: 2% of validamycin, 20% of dimehypo, HS 6044.5%, 1.8% of methyldichlorosilane, 4% of phenethylphenol polyoxyethylene (n is 15-30) ether, 3% of styrene polyoxyethylene ether ammonium sulfate, 6% of isopropanol, 2% of ethylene glycol, 2% of lauryl alcohol, 1% of citric acid and the balance of water to 100%.
Example 20
The formulation 20 is as follows: 2% of matrine, 6042.3% of HS, 1.9% of methyl dichlorosilane, 8% of phenethyl nonyl phenol polyoxyethylene ether, 7% of dodecylbenzene sulfonic acid, 6% of n-butyric acid, 4% of urea, 2% of lauric acid, 1% of citric acid and water in balance to 100%.
Example 21
Formulation 21 is as follows: 0.11 percent of indoleacetic acid,
319B 1.8%, disilane 1.5%, tallow amine polyoxy2% of vinyl ether, 7% of styrene polyoxyethylene ether ammonium sulfate, 3% of ethylene glycol, 4% of urea, 2% of lauric acid, 1% of citric acid and water, wherein the water is supplemented to 100%.
Example 22
Formulation 22 is as follows: 0.01% of brassinolide, 32492% of methyldichlorosilane, 0.5% of phenethyl phenol polyoxyethylene (n is 15-30) ether, 5% of styrene polyoxyethylene ether ammonium sulfate, 5% of ethanol, 2% of lauric acid, 1% of citric acid, 5% of urea and water which are added to be up to 100%.
Example 23
Formulation 23 is as follows: 40% of ethephon, 32492.5%, 2.3% of methyl dichlorosilane, 4% of benzyl diphenol polyoxyethylene ether, 2% of alpha-sodium alkenyl sulfonate, 3% of ethylene glycol, 3% of calcium chloride, 3.5% of urea, 1% of ammonia water and the balance of water to 100%.
The above examples 1-23 were prepared as follows:
dissolving the corresponding raw medicine in water for later use, uniformly mixing the surfactant and the cosurfactant, adding the corresponding hydrolysis-resistant organic silicon auxiliary agent, uniformly mixing, finally adding the antifreeze agent, the thickening agent and the pH regulator, and uniformly stirring to obtain the aqueous solution.
Example 24
The difference between this example and example 1 is only the preparation method, the component formula is the same as example 1, and the preparation method is specifically as follows:
mixing a raw pesticide, water, an antifreeze agent, a thickening agent and a pH regulator to form a solution A, mixing a surfactant, a cosurfactant, an anti-hydrolysis organic silicon auxiliary agent and a hydrolysis inhibitor to form a solution B, adding the solution A into the solution B to be sheared for 10min under the high-speed shearing condition that the shearing speed is 14000r/min, and then regulating the pH regulator to 5-8 to obtain the water-soluble organic silicon polymer.
Comparative example 1
The difference between the comparative example and the example 1 is that the surfactant sodium cocoyl glutamate is added instead of the surfactant benzyldiphenol polyoxyethylene ether and the fatty alcohol ether sodium sulfate, and the rest is consistent with the example 1.
Comparative example 2
The difference between the comparative example and the example 2 is that the surfactant sodium cocoyl glutamate 5.7% is added instead of the surfactant lauryl trimethyl ammonium chloride and lauryl sodium sulfate, and the rest is consistent with the example 2.
Comparative example 3
The difference between the comparative example and the example 3 is that the surfactant sodium cocoyl glutamate is added instead of the surfactant alkyl aryl polyoxyethylene ether and the fatty alcohol ether sodium sulfate, and the rest is consistent with the example 3.
Comparative example 4
The comparative example is different from example 1 in that benzyl diphenol polyoxyethylene ether and sodium fatty alcohol ether sulfate are not added, and the rest is consistent with example 1.
Comparative example 5
The difference between the comparative example and the example 1 is that the dosage of the ethylene glycol is changed to 10.5% without adding the benzyl diphenol polyoxyethylene ether and the fatty alcohol ether sodium sulfate, and the rest is consistent with the example 1.
Comparative example 6
This comparative example differs from example 1 in that no ethylene glycol was added and the rest remained the same as example 1.
Comparative example 7
The difference between the comparative example and the example 1 is that the dosage of the benzyldiphenol polyoxyethylene ether and the dosage of the fatty alcohol ether sodium sulfate are respectively changed to 1.75 percent and 8.75 percent without adding ethylene glycol, and the rest is consistent with the example 1.
Comparative example 8
The comparative example is different from example 1 in that benzyl diphenol polyoxyethylene ether, sodium fatty alcohol ether sulfate and ethylene glycol are not added, and the rest is the same as example 1.
Comparative example 9
The difference between the comparative example and the example 1 is that the dosage of the methyl dioxysilane is changed to 12.5 percent without adding the benzyl diphenol polyoxyethylene ether, the fatty alcohol ether sodium sulfate and the ethylene glycol, and the rest is consistent with the example 1.
Comparative example 10
This comparative example differs from example 1 in that no ethylene glycol and methyl dioxysilane were added, the others remaining the same as in example 1.
Comparative example 11
The difference between the comparative example and the example 1 is that the dosage of the benzyl diphenol polyoxyethylene ether and the dosage of the fatty alcohol ether sodium sulfate are respectively changed to 2.75 percent and 9.75 percent without adding ethylene glycol and methyl dioxy silane, and the rest is consistent with the example 1.
Comparative example 12
This comparative example differs from example 1 in that benzyl diphenol polyoxyethylene ether, sodium fatty alcohol ether sulfate and methyl dioxysilane are not added, and the rest is identical to example 1.
Comparative example 13
The comparative example is different from example 1 in that the amount of ethylene glycol was changed to 12.5% without adding benzyldiphenol polyoxyethylene ether, sodium fatty alcohol ether sulfate and methyl dioxysilane, and the rest was the same as example 1.
Comparative example 14
This comparative example differs from example 1 in that there is no methyldichlorosilane and the others remain the same as example 1.
Comparative example 15
This comparative example differs from example 1 in that there is no hydrolysis resistant silicone additive 3249, the others remaining the same as example 1.
Comparative example 16
This comparative example differs from example 1 in that hydrolysis resistant silicone additive 3249 was replaced with 248, the others remaining the same as example 1.
Comparative example 17
The comparative example differs from example 1 in that the hydrolysis resistant silicone additive 3249 was present in an amount of 0.2%, and the others were in agreement with example 1.
Comparative example 18
The comparative example differs from example 1 in that the hydrolysis resistant silicone additive 3249 content was 13%, the others remaining the same as example 1.
Comparative example 19
This comparative example differs from example 1 in that it does not contain the glyphosate isopropylamine salt bulk drug, and otherwise remains the same as example 1.
The aqueous formulations of the examples and comparative examples shown in table 2 below were tested for surface tension and retention time. A control solution of glyphosate isopropylamine salt was prepared by mixing 3249 with other conventional surfactants. Spray liquid of comparative example 1 is prepared firstly, the spray liquid is prepared according to the proportion of water agent to water of 1:100, then the water agent of the embodiment of the invention shown in table 2 is diluted with water according to the spray concentration of the comparative example 1, the surface tension is tested by a static surface tension meter after the uniform stirring, and the test result is shown in table 2.
TABLE 2 surface tension test results
As can be seen from the above table, the components of the aqueous solution of the present invention are not completely used in comparative examples 14 to 18, and the surface tension of the test data is much worse than that of the examples of the present invention.
The following table 3 shows the appearances of the aqueous solutions of examples 1 to 3 of the present invention and comparative examples 1 to 13, and it can be seen that the aqueous solutions of examples 1 to 3 of the present invention are more compatible with the hydrolysis-resistant silicone additive, and the comparative examples 1 to 13 are not completely made of the components of the present invention and are not compatible with the hydrolysis-resistant silicone additive.
TABLE 3 appearance of the aqueous solution
Some of the herbicides of the examples of the present invention were field tested according to the method described in GBT17980.42-2000, and their herbicidal performance is shown in Table 4.
TABLE 4 comparison of the herbicidal Performance results with conventional herbicides
As shown in the table, compared with the existing products in the market, the water aqua of the invention can obviously improve the weeding performance of the herbicide and reduce the dosage of the herbicide.
The herbicidal performance of the aqueous formulations prepared in example 1 and comparative examples 14 to 18 immediately after the storage at room temperature for 1 year and the herbicidal performance after the storage at room temperature for 1 year were each measured, and the results are shown in table 5.
TABLE 5 herbicidal performance results for different formulations
As shown in the table, the components of the aqueous agent of the invention are not completely adopted in the comparative examples 14 to 19, and the test data shows that the weeding performance is much worse than that of the examples of the invention.
The part of the bactericide of the embodiment of the invention is subjected to field experiments according to the method described in GB/T17980.20-2000, and the sterilizing effect is shown in Table 6.
TABLE 6 germicidal performance results
As shown in the table, the water aqua of the invention can obviously improve the sterilization performance of the bactericide and reduce the dosage of the bactericide.
Some of the insecticides of the examples of the present invention were field tested according to the method described in GB/T17980.3-2000, and their insecticidal properties are shown in Table 7.
TABLE 7 insecticidal Performance results
As shown in the table, the water aqua of the invention can obviously improve the insecticidal performance of the insecticide and reduce the dosage of the insecticide.
The solution of example 14 is diluted by 1500 times, the solution of example 23 is diluted by 500 times, the solution is uniformly stirred and then sprayed on the surface of crops, and the indexes of the crop yield, the maturity rate and the like are counted, and the specific results are shown in table 8.
TABLE 8 growth regulator Effect results
As shown in the table, the water aqua can obviously improve the performance of the plant growth regulator and reduce the dosage of the plant regulator.
Although the embodiments of the present invention have been described above, the above description is only for the convenience of understanding the present invention, and is not intended to limit the present invention. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (24)
1. The aqueous solution containing the hydrolysis-resistant organosilicon auxiliary agent is characterized by comprising the following components in percentage by mass:
0.01 to 65 percent of raw medicine
0.1 to 41 percent of surfactant
0.1-10% of cosurfactant
0.3-12% of hydrolysis-resistant organic silicon additive
0.01 to 5 percent of hydrolysis inhibitor
1 to 5 percent of antifreeze agent
1 to 5 percent of thickening agent
1-4% of pH regulator
Water to 100%
The hydrolysis-resistant organic silicon assistant is polyether modified organic siloxane which is substituted at the end of a polyether block or is improved in a polyether block structure;
the hydrolysis inhibitor is selected from any one or the combination of at least two of methyldichlorosilane, aminopropylsilane, monosilane and disilane;
the hydrolysis-resistant silicone additive comprises a substance having the following structure:
wherein m =1~20, n =1~10, x =1~10, y =0~ 10.
2. The aqueous agent containing the hydrolysis-resistant silicone auxiliary according to claim 1, wherein the surface tension of the hydrolysis-resistant silicone auxiliary is 20.6mN/m to 24.1mN/m, and the molecular weight is 479 to 2685.
3. The aqua containing the hydrolysis-resistant silicone additive according to claim 1, wherein the hydrolysis-resistant silicone additive is selected from hydrolysis-resistant silicone additive of Mei brand Xiwei HS604, hydrolysis-resistant silicone additive of Hangzhou Chongyao science and technology brand 3249, high temperature and hydrolysis resistant silicone wetting agent of Anhui chemical industry Co., Ltd, hydrolysis resistant silicone surfactant of Zhejiang Runjin and New Silicone Material Co., Ltd, two-tailed trisiloxane surfactant of Huizhou university, FTRT ® 319B, SE-640 and SE-429 as well as at least one of these three components.
4. The aqueous aqua containing the hydrolysis-resistant silicone additive as claimed in claim 1, wherein the hydrolysis-resistant silicone additive is any one of a hydrolysis-resistant silicone additive of Mei brand Xiwei HS604, a hydrolysis-resistant silicone additive combination of Hangzhou Chongyao technology brand 3249, a hydrolysis-resistant silicone additive of Mei brand Xiwei HS604 and FTRT 319B, or a hydrolysis-resistant silicone additive of Hangzhou Chongyao technology brand 3249 and a methyl allyl polyether modified trisiloxane SE-429 combination.
5. The aqueous formulation containing an anti-hydrolysis silicone adjuvant according to claim 1, wherein the active compound comprises glyphosate, ammonium glyphosate, potassium glyphosate, dimethylamine glyphosate, isopropylamine glyphosate, glufosinate, diquat, hymexazol, dicamba, isopropylamine dicamba, dimethylamine dicamba, jinggangmycin, kasugamycin, ningnanmycin, lime sulfur, bentazone, 2,4 drops of triethanolamine, 2,4 drops of dimethylamine, pyrimidine nucleoside antibiotics, chlormequat chloride, 2 methyl 4 chloride sodium salt, 2 methyl 4 chloride dimethylamine salt, 2 methyl 4 chloride isopropylamine salt, ethephon, metiram, dimehypo, fomesafen, propamocarb hydrochloride, picloram, imazamox, imazethapyr, ammonium mefenamic acid, amifostine hydrochloride, monoamitraz hydrochloride, mefenamic acid hydrochloride, methamidothion, imax, imazamethamidophos, imab, and imab, Choline chloride, oligosaccharins, amino oligosaccharins, lentinan, 14-hydroxy brassinols, carvacrol, matrine, indoleacetic acid, berberine hydrochloride, chitosan, maleic acid, clopyralid, nitenpyram, S-abscisic acid, triclopyr triethylamine salt, polyoxin, naphthylacetic acid, metam, imazalil sulfate, zhongshengmycin, diethyl aminoethyl hexanoate, octamycin, sympathomin acetate, benzylaminopurine, furfuryl aminopurine, emodin methyl ether, mepiquat chloride, bacillus subtilis, brassinolide, propionyl brassinolide, 28-epihomobrassinolide, cyanamide, peroxyacetic acid, dinitrophenol sodium, paraquat, cuaminosulfan, difenzoquat, imazethapyr, and botulinum type C.
6. The aqueous agent containing an hydrolysis-resistant silicone adjuvant according to claim 1, wherein the technical material is a combination of 2 methyl 4 chloro isopropylamine salt and glyphosate isopropylamine salt, a combination of ammonium glyphosate and glufosinate, a combination of dicamba isopropylamine salt and glyphosate isopropylamine salt, a combination of 2, 4D dimethylamine salt and glyphosate isopropylamine salt, a combination of 2 methyl 4 chloro and glyphosate, a combination of bentazone and bispyribac-sodium, or a combination of an amide ester and ethephon.
7. The aqueous solution containing the hydrolysis-resistant silicone auxiliary agent according to claim 1, wherein the surfactant is prepared by mixing a hydrophilic surfactant and a lipophilic surfactant with HLB value = 8-18, and the mixing volume ratio of the hydrophilic surfactant to the lipophilic surfactant is 1: 8-8: 1.
8. the aqueous agent containing a hydrolysis resistant silicone adjuvant according to claim 7 wherein the hydrophilic surfactant is a nonionic surfactant and the lipophilic surfactant is an anionic surfactant.
9. The aqueous solution containing the hydrolysis-resistant silicone auxiliary agent according to claim 7, wherein the hydrophilic surfactant comprises one or a combination of at least two of tallow amine polyoxyethylene ether, alkylaryl polyoxyethylene ether, alkylaryl formaldehyde resin polyoxyethylene ether, benzyl diphenol polyoxyethylene ether, phenylethylphenol polyoxyethylene (n = 15-30) ether, phenylethylphenol polyoxyethylene polyoxypropylene ether, nonylphenol polyoxyethylene ether, phenylethylnonylphenol polyoxyethylene ether, diphenol polyoxyethylene ether, alkylphenol polyoxyethylene ether formaldehyde condensate, octane glycoside ethyl trimethyl ammonium chloride, decane glycoside ethyl trimethyl ammonium chloride, dodecaneglycoside ethyl trimethyl ammonium chloride, tetradecane glycoside ethyl trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride and betaine.
10. The aqueous solution containing the hydrolysis-resistant silicone auxiliary agent according to claim 7, wherein the lipophilic surfactant is one or a combination of at least two of sodium fatty alcohol ether sulfate, carboxylic acid salt of fatty alcohol ether, fatty alcohol polyoxyethylene ether phosphate, dodecylbenzene sulfonic acid, sodium dodecylbenzene sulfonate, Nongru 2000#, aqueous solution of sulfated castor oil, sodium dodecylsulfate, ammonium styrene polyoxyethylene ether sulfate salt and sodium alpha-alkenyl sulfonate.
11. The aqueous agent containing the hydrolysis-resistant silicone auxiliary according to claim 8, wherein the non-ionic surfactant is a combination of Nongru # 100 and an alkylaryl formaldehyde resin polyoxyethylene ether, a combination of an alkylaryl polyoxyethylene ether and a phenethyl nonylphenol polyoxyethylene ether, a combination of a nonylphenol polyoxyethylene ether and a benzyl diphenol polyoxyethylene ether, or a combination of Nongru # 600, an alkylaryl polyoxyethylene ether and a diphenol polyoxyethylene ether, a combination of octane glycoside ethyltrimethyl ammonium chloride and dodecyl trimethyl ammonium chloride, or a combination of tetradecane glycoside ethyltrimethyl ammonium chloride and dodecyl trimethyl ammonium chloride.
12. The aqueous agent containing the hydrolysis-resistant silicone auxiliary according to claim 8, wherein the anionic surfactant is a combination of Nongru 2000# and fatty alcohol polyoxyethylene ether phosphate, a combination of dodecylbenzene sulfonic acid and Nongru 2000#, or a combination of sodium lauryl sulfate, an aqueous solution of sulfated castor oil, and sodium α -alkenyl sulfonate.
13. The aqueous agent containing a hydrolysis-resistant silicone auxiliary according to claim 1, wherein the co-surfactant is one or a combination of at least two of ethanol, ethylene glycol, n-butanol, n-pentanol, n-hexanol, n-heptanol, n-octanol, isopropanol, primary pentanol, secondary pentanol, n-butyric acid, glycerol, and polyglycerol ester.
14. The aqueous hydrolysis resistant silicone adjuvant of claim 13 wherein said co-surfactant is a combination of ethanol and n-heptanol, glycerol and isopropanol, or a combination of n-butyric acid, n-pentanol and primary pentanol.
15. The aqueous agent containing the hydrolysis-resistant silicone auxiliary according to claim 1, wherein the antifreeze is one or a combination of at least two of methanol, ethanol, ethylene glycol, propylene glycol, urea, water-soluble amide and calcium chloride.
16. The aqueous agent containing an hydrolysis resistant silicone adjuvant of claim 15 wherein the anti-freeze agent is a combination of methanol and urea, a combination of ethylene glycol and calcium chloride, a combination of ethanol and urea, or a combination of ethanol, a water soluble amide and calcium chloride.
17. The aqueous agent containing a hydrolysis-resistant silicone auxiliary according to claim 1, wherein the thickener is any one of sodium chloride, potassium chloride, ammonium chloride, monoethanolamine chloride, diethanolamine chloride, sodium sulfate, sodium phosphate, disodium phosphate and pentasodium triphosphate, lauryl alcohol, myristyl alcohol, decyl alcohol, hexanol, octanol, cetyl alcohol, stearyl alcohol, behenyl alcohol, lauric acid, linoleic acid, linolenic acid, myristic acid, stearic acid, starch, gum arabic, pectin, agar, gelatin, algin, carrageenan, dextrin, magnesium aluminum silicate, xanthan gum, or a combination of at least two thereof.
18. The aqueous hydrolysis resistant silicone adjuvant formulation of claim 17 wherein said thickener is a combination of sodium chloride and dextrin, lauryl alcohol and stearic acid, starch and pectin, sodium phosphate and xanthan gum, or potassium chloride, decanol and linoleic acid.
19. The aqueous solution containing the hydrolysis-resistant silicone additive according to claim 1, wherein the pH adjuster is any one of or a combination of at least two of citric acid, hydrochloric acid, potassium citrate, sodium citrate, dimethylamine, malic acid, lactic acid, tartaric acid, adipic acid, isopropylamine, fumaric acid, phosphoric acid, sodium carbonate, carbonic acid, sodium hydroxide, potassium hydroxide, and ammonia.
20. The aqueous agent containing an hydrolysis-resistant silicone additive as claimed in claim 19, wherein the pH adjuster is a combination of sodium hydroxide and potassium hydroxide, a combination of isopropylamine and dimethylamine, a combination of hydrochloric acid and fumaric acid, or a combination of adipic acid, sodium carbonate and tartaric acid.
21. The aqueous preparation containing the hydrolysis-resistant organosilicon auxiliary agent according to claim 1, wherein the aqueous preparation contains the following components:
0.01 to 65 percent of raw medicine
1 to 20 percent of surfactant
2-5% of cosurfactant
0.5-4.5% of hydrolysis-resistant organic silicon additive
1.5 to 3 percent of hydrolysis inhibitor
1.5 to 5 percent of antifreeze agent
2 to 3.5 percent of thickening agent
1-3% of pH regulator
And (4) water is added to 100 percent.
22. The method for preparing the aqueous solution containing the hydrolysis-resistant organosilicon auxiliary agent according to any one of claims 1 to 21, wherein the components in the aqueous solution are uniformly mixed to obtain the hydrolysis-resistant organosilicon auxiliary agent.
23. The method of claim 22, comprising the steps of:
mixing the raw pesticide, water, an antifreeze agent, a thickening agent and a pH regulator to form a solution A, mixing a surfactant, a cosurfactant, a hydrolysis-resistant organic silicon additive and a hydrolysis inhibitor to form a solution B, adding the solution A into the solution B under a high-speed shearing condition, shearing for 5-15 min, and regulating to 5-8 by using the pH regulator to obtain the water-soluble organic silicon polymer.
24. The method according to claim 23, wherein the high shear conditions have a shear rate of 10000 to 15000 r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110569374.5A CN113475523B (en) | 2021-05-25 | 2021-05-25 | Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110569374.5A CN113475523B (en) | 2021-05-25 | 2021-05-25 | Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113475523A CN113475523A (en) | 2021-10-08 |
| CN113475523B true CN113475523B (en) | 2022-09-23 |
Family
ID=77933612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110569374.5A Active CN113475523B (en) | 2021-05-25 | 2021-05-25 | Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113475523B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114557340B (en) * | 2022-03-15 | 2023-08-01 | 浙江新安化工集团股份有限公司 | Low-foam crystallization-resistant pesticide aqueous agent and preparation process thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101011062B (en) * | 2007-02-06 | 2010-05-19 | 张家港市骏博化工有限公司 | Organosilicon pesticide booster and preparing method thereof |
| CN102993225A (en) * | 2012-09-28 | 2013-03-27 | 山东农业大学 | Preparation method of anti-hydrolysis organosilane surfactant |
| CN104412963A (en) * | 2013-08-29 | 2015-03-18 | 浙江新安化工集团股份有限公司 | Agricultural auxiliary agent, granules and preparation method of agricultural auxiliary agent and granules |
| CN106538593A (en) * | 2016-11-01 | 2017-03-29 | 山东科信生物化学有限公司 | A kind of phosphine oxamate aqua and its surfactant |
-
2021
- 2021-05-25 CN CN202110569374.5A patent/CN113475523B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN113475523A (en) | 2021-10-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6250020B2 (en) | Amine surfactants and amine oxide surfactants for controlling spray drift of herbicides | |
| CA1333226C (en) | Liquid herbicidal agents | |
| EP0668015B1 (en) | Pesticidal compositions containing zinc oxide | |
| ES2357782T3 (en) | AGROCHEMICAL COMPOSITIONS THAT INCLUDE MODIFIED POLYSYLOXANES WITH ALQUILENDIOL. | |
| AU650091B2 (en) | Glyphosate compositions and their use | |
| AU2014230940B2 (en) | Cellulose ether as a drift control agent and rainfastness agent | |
| EP0441764A1 (en) | Glyphosate compositions and their use | |
| JPH10513478A (en) | Glyphosate formulations containing etheramine surfactants | |
| US20090270258A1 (en) | Pesticide and/or herbicide compositions and methods of their use | |
| CN105025710A (en) | Agricultural pesticide compositions | |
| CN101884326A (en) | Preparation and application technology for waxy bacillus suspension agent | |
| KR100787071B1 (en) | Use of amine compounds with improved biodegradability as adjuvants for pesticides and fertilisers | |
| CN113475523B (en) | Aqueous agent containing hydrolysis-resistant organic silicon auxiliary agent and preparation method thereof | |
| US20060063676A1 (en) | Method for enhancing deposition of an agrochemical | |
| CN108770843A (en) | A kind of spray adjuvants and preparation method thereof and include its spray liquid | |
| CN106922714A (en) | Plant growth regulator composition with synergistic effect | |
| AU2010244980B2 (en) | Dispersants in high-electrolyte solutions | |
| CN108719313B (en) | Aqueous suspension agent and preparation method and application thereof | |
| CN112400910A (en) | Environment-friendly low-irritation pesticide special for gardens and preparation method thereof | |
| AU2015234291B2 (en) | Amine and amine oxide surfactants for controlling herbicide spray drift | |
| CN114557340A (en) | Low-foam anti-crystallization pesticide aqueous solution and preparation process thereof | |
| CN104396979B (en) | A kind of bactericide and uses thereof | |
| CN106922653A (en) | A kind of synergy atomization adjuvant and preparation method thereof | |
| US20170325460A1 (en) | Stable aqueous herbicidal compositions | |
| CN107889823A (en) | A kind of complex composition and preparation of the lactams of ketoxime containing isolonglifolene and zinc thiazole |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |