CN113462306B - Self-adhesive polymer waterproof coiled material and preparation method thereof - Google Patents
Self-adhesive polymer waterproof coiled material and preparation method thereof Download PDFInfo
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- CN113462306B CN113462306B CN202110701484.2A CN202110701484A CN113462306B CN 113462306 B CN113462306 B CN 113462306B CN 202110701484 A CN202110701484 A CN 202110701484A CN 113462306 B CN113462306 B CN 113462306B
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- 239000000463 material Substances 0.000 title claims abstract description 189
- 239000002998 adhesive polymer Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title abstract description 56
- 239000010410 layer Substances 0.000 claims abstract description 171
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000010426 asphalt Substances 0.000 claims abstract description 20
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000003825 pressing Methods 0.000 claims abstract description 18
- 239000002344 surface layer Substances 0.000 claims abstract description 17
- 239000011159 matrix material Substances 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 239000004698 Polyethylene Substances 0.000 claims description 25
- 239000012528 membrane Substances 0.000 claims description 25
- 239000010445 mica Substances 0.000 claims description 24
- 229910052618 mica group Inorganic materials 0.000 claims description 24
- 229920002545 silicone oil Polymers 0.000 claims description 23
- 229920001903 high density polyethylene Polymers 0.000 claims description 17
- 239000004700 high-density polyethylene Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 238000004078 waterproofing Methods 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000011888 foil Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000003860 storage Methods 0.000 abstract description 21
- 239000002313 adhesive film Substances 0.000 description 35
- 230000000181 anti-adherent effect Effects 0.000 description 35
- 239000011230 binding agent Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 229920000728 polyester Polymers 0.000 description 12
- 239000000428 dust Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
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- 239000000155 melt Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
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- 239000004566 building material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
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- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
- E02D31/025—Draining membranes, sheets or fabric specially adapted therefor, e.g. with dimples
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
- E04B1/665—Sheets or foils impervious to water and water vapor
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/38—Waterproofing; Heat insulating; Soundproofing; Electric insulating
- E21D11/383—Waterproofing; Heat insulating; Soundproofing; Electric insulating by applying waterproof flexible sheets; Means for fixing the sheets to the tunnel or cavity wall
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/346—Applications of adhesives in processes or use of adhesives in the form of films or foils for building applications e.g. wrap foil
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/16—Metal
- C09J2400/163—Metal in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/26—Presence of textile or fabric
- C09J2400/263—Presence of textile or fabric in the substrate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
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- C—CHEMISTRY; METALLURGY
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- C09J2495/00—Presence of bitume
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2300/00—Materials
- E02D2300/0045—Composites
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2300/00—Materials
- E02D2300/0098—Bitumen
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2450/00—Gaskets
- E02D2450/10—Membranes
- E02D2450/105—Membranes impermeable
- E02D2450/106—Membranes impermeable for liquids
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Abstract
The application relates to the field of waterproof coiled materials, and particularly discloses a self-adhesive polymer waterproof coiled material and a preparation method thereof. The self-adhesive polymer waterproof coiled material comprises a surface layer, an upper base material layer, a matrix layer, a lower base material layer and an anti-sticking film which are sequentially connected, wherein the upper base material layer and the lower base material layer comprise the following raw materials in percentage by weight: 38-50% of asphalt; 7-12% of softening oil; 4-6% of SIS; 1-3% of SBS; 9-15% of rubber powder; 20-35% of talcum powder. The preparation method comprises the following steps: preparing a mixture of an upper base material layer and a lower base material layer; coating a mixture on the surface of the carcass layer, and pressing to form an upper base material layer and a lower base material layer; one side of the upper base material layer far away from the matrix layer is covered with the surface layer, one side of the lower base material layer far away from the matrix layer is covered with the anti-sticking film, and the waterproof coiled material is subjected to secondary pressing. The self-adhesive polymer waterproof coiled material has the advantages of improving the stability of the adhesiveness of the waterproof coiled material and prolonging the storage period of the waterproof coiled material.
Description
Technical Field
The application relates to the field of waterproof coiled materials, in particular to a self-adhesive polymer waterproof coiled material and a preparation method thereof.
Background
The waterproof coiled material is mainly used for waterproof engineering of basement, subway, tunnel, pool, roofing and other parts and is a flexible building material product capable of being curled into a coiled shape. The self-adhesive polymer waterproof coiled material is a novel waterproof coiled material with development prospect, has the characteristics of water impermeability, self-adhesive property and the like, is easy to construct, can improve the laying speed, accelerates the engineering progress, and gradually becomes a new favor in the current waterproof coiled material.
In the related art, the self-adhesive polymer waterproof coiled material comprises a polyester felt carcass layer and a base material layer, wherein the two surfaces of the polyester felt carcass layer are both coated with the base material layer, one side, far away from the polyester felt carcass layer, of the base material layer is provided with a strippable PE film, and the base material layer comprises the following raw materials in percentage by weight: 40.5% of No. 90 asphalt, 11.5% of three-wire oil, 5% of SBR, 2% of SBS, 13% of rubber powder and 28% of talcum powder. When the self-adhesive polymer waterproof coiled material is used, the PE film is peeled off from the base material layer, then the waterproof coiled material is paved on the position to be waterproof treated, and the exposed base material layer and the position to be waterproof treated can be automatically adhered.
With respect to the related art in the above, the inventors consider that: because the construction site environment is abominable, self-adhesion polymer waterproofing membrane is easy damaged at the in-process PE membrane of placing, makes the binder layer expose outside, and binder layer and air direct contact, the viscidity easily descends, leads to waterproofing membrane's storage cycle to shorten.
Disclosure of Invention
In order to improve the stability of the adhesiveness of the waterproof coiled material and prolong the storage period of the waterproof coiled material, the application provides a self-adhesive polymer waterproof coiled material and a preparation method thereof.
In a first aspect, the present application provides a self-adhesive polymer waterproof roll, which adopts the following technical scheme:
the utility model provides a self-adhesion polymer waterproofing membrane, includes the superficial layer, go up basic material layer, matrix layer, lower basic material layer and antiseized membrane that connect gradually, go up basic material layer and lower basic material layer all include the raw materials of following weight percent:
38-50% of asphalt;
7-12% of softening oil;
SIS 4~6%;
SBS 1~3%;
9-15% of rubber powder;
20-35% of talcum powder.
By adopting the technical scheme, the upper base material layer and the lower base material layer play roles in self-adhesion and water resistance of the waterproof coiled material, and the anti-sticking film plays a role in isolation, so that the condition that the lower base material layer is oxidized by direct contact with the external environment to reduce viscosity can be reduced; once the anti-sticking film is broken, the lower base material layer is directly contacted with the external environment and is easy to be oxidized rapidly, so that the lower base material layer loses viscosity, therefore, SIS is adopted in the raw materials of the upper base material layer and the lower base material layer to modify, the oxidation speed of each raw material is slowed down, the viscosity stability of the waterproof coiled material is improved, and even after the anti-sticking film is broken, the waterproof coiled material can keep viscosity for a long time, so that the effect of prolonging the storage period of the waterproof coiled material is obtained.
Optionally, the asphalt is 200 # asphalt, and the upper base material layer and the lower base material layer comprise the following raw materials in percentage by weight:
46% of No. 200 asphalt;
softening oil 7%;
SIS 5%;
SBS 2%;
12% of rubber powder;
talcum powder 28%.
Through adopting above-mentioned technical scheme, adopt 200 # pitch, reduced the quantity of softening oil to further slowed down the speed that each raw materials in upper base material layer and the lower base material layer was oxidized, improved the stability of waterproofing membrane viscidity, after antiseized membrane is damaged, waterproofing membrane also can keep viscidity in longer time, consequently, obtained the effect of extension waterproofing membrane's storage period.
Optionally, the surface layer is made of polyethylene film, fine sand or aluminum foil.
By adopting the technical scheme, the surface layer can be made of polyethylene film, fine sand or aluminum foil, after the waterproof coiled material is paved on the part to be waterproof, the surface layer is exposed, so that the condition that the waterproof coiled material is directly contacted with water can be reduced, the damage of water to other layer structures of the waterproof coiled material is reduced, and the waterproof coiled material has a further waterproof effect; when the waterproof coiled material is placed and stored, the surface layer can also play a role in protecting, the other layer structures of the waterproof coiled material are isolated from the external environment, and the damage of the external environment to the other layer structures of the waterproof coiled material is reduced, so that the storage period of the waterproof coiled material is prolonged.
Optionally, the anti-sticking film comprises the following raw materials in parts by weight: 60-70 parts of PET, 30-40 parts of HDPE, 8-12 parts of POE-g-GMA.
Through adopting above-mentioned technical scheme, through POE-g-GMA improvement PET and HDPE's compatibility, make PET and HDPE blend, the antiseized membrane of preparation has higher intensity and shock resistance simultaneously, has reduced antiseized membrane and has destroyed the degree of damage by external force to the guard action to lower binder layer has been increased, and then each raw materials in upper binder layer and the lower binder layer has slowed down by the speed of oxidation, has improved the stability of waterproofing membrane viscidity, consequently, has obtained the effect of extension waterproofing membrane's storage period.
Optionally, the manufacturing process of the anti-sticking film comprises the following steps:
s1, respectively drying PET and HDPE;
s2, melting and blending PET, HDPE and POE-g-GMA according to the proportion at 260-285 ℃ to obtain a blend;
s3, extruding and tape casting the blend into film-forming sheets to obtain the anti-sticking film.
By adopting the technical scheme, the PET and the HDPE are dried respectively, the fluidity of the PET and the HDPE is improved, then the PET, the HDPE and the POE-g-GMA are subjected to melt blending, extrusion and film forming, and the prepared anti-sticking film has good strength and impact resistance, can be recycled, and saves the cost.
Optionally, the anti-sticking film also comprises 4-6 parts by weight of mica powder and 3-5 parts by weight of silicone oil.
Through adopting above-mentioned technical scheme, the roughness on release film surface can be improved to the interpolation of mica powder to improve the adhesive strength of release film and lower binder layer, and after release film surface roughness improves, make release film surface easy adhesion dust, the dust is along with the adhesion of release film adhesion to the adhesion of lower binder layer on the lower binder layer easy reduction lower binder layer, the antistatic performance on release film surface can be improved to the interpolation of silicone oil, the problem of release film surface easy adsorption dust has been alleviated, the influence of dust to lower binder layer adhesion has been reduced, thereby the stability of waterproofing membrane adhesion has been improved, consequently, the effect of extension waterproofing membrane's storage period has been obtained.
Optionally, the manufacturing process of the anti-sticking film comprises the following steps:
s1, respectively drying PET and HDPE;
s2, melting and blending PET, HDPE and POE-g-GMA according to the proportion at 260-285 ℃ to obtain a blend;
and S3, extruding and casting the blend into a film, coating silicone oil on the surface of the film, and then spraying mica powder on one surface of the film coated with the silicone oil to obtain the anti-sticking film.
Through adopting above-mentioned technical scheme, through the surface coating silicone oil at the diaphragm, can reduce the adhesive force of anti-sticking membrane, to one of them surface spraying mica powder of diaphragm, can improve the surface roughness of anti-sticking membrane, improve the joint strength of anti-sticking membrane and lower basic material layer.
In a second aspect, the present application provides a method for preparing a self-adhesive polymer waterproof roll, which adopts the following technical scheme: the preparation method of the self-adhesive polymer waterproof coiled material comprises the following steps:
(1) Preparing a mixture of an upper base material layer and a lower base material layer:
a1, mixing asphalt, softening oil, SBS, SIS and rubber powder according to a proportion under the condition of 180-220 ℃ and uniformly mixing to obtain a mixture;
a2, adding talcum powder into the mixture prepared in the step A1, cooling to 140-160 ℃, and stirring until the talcum powder is uniformly dispersed to obtain a mixture;
(2) Preparing a waterproof coiled material:
b1, uniformly coating a mixture of an upper base material layer and a lower base material layer on two surfaces of a carcass layer, and forming the upper base material layer and the lower base material layer after pressing;
and B2, covering a surface layer on one side of the upper base material layer far away from the matrix layer, covering an anti-adhesive film on one side of the lower base material layer far away from the matrix layer, and performing secondary pressing to obtain the waterproof coiled material.
By adopting the technical scheme, the carcass layer is used as a supporting part of the whole waterproof coiled material, so that the strength of the waterproof coiled material can be improved; after the mixture of the upper base material layer and the lower base material layer is prepared, the mixture is coated on the matrix layer to play roles of self-adhesion and water resistance; the surface layer is covered on the upper base material layer, is exposed when in use, plays a role in protecting other layer structures of the waterproof coiled material, and can prolong the service life of the waterproof coiled material; the anti-adhesive film covers the lower base material layer, plays an isolating role when the waterproof coiled material is placed, reduces the condition that the lower base material layer is adhered to the waterproof coiled material when the waterproof coiled material is rolled up and placed so as to influence the subsequent normal use, and simultaneously reduces the condition that the lower base material layer is oxidized to reduce the viscosity when being in direct contact with the external environment.
The preparation method of the self-adhesive polymer waterproof coiled material comprises the following steps:
(1) Preparing a mixture of an upper base material layer and a lower base material layer:
a1, mixing asphalt, softening oil, SBS, SIS and rubber powder according to a proportion under the condition of 180-220 ℃ and uniformly mixing to obtain a mixture;
a2, adding talcum powder into the mixture prepared in the step A1, cooling to 140-160 ℃, and stirring until the talcum powder is uniformly dispersed to obtain a mixture;
(2) Preparing a waterproof coiled material:
b1, uniformly coating a mixture of an upper base material layer and a lower base material layer on two surfaces of a carcass layer, and forming the upper base material layer and the lower base material layer after pressing;
b2, covering a surface layer on one side of the upper base material layer far away from the matrix layer, covering an anti-sticking film on one side of the lower base material layer far away from the matrix layer, attaching one side of the anti-sticking film with mica powder to the lower base material layer, and performing secondary pressing to obtain the waterproof coiled material, wherein the two layers are heated simultaneously in the secondary pressing process, and the temperature is set to be 120-150 ℃.
Through adopting above-mentioned technical scheme, the adhesion-preventing film has one side and the laminating of lower binder layer of mica powder, can improve the joint strength of adhesion-preventing film and lower binder layer, makes each layer structure laminating inseparabler through the secondary suppression. By pressing at 120-150 ℃, the structures of all layers are closely contacted, especially the connection strength of the anti-sticking film and the lower base material layer is improved, the situation that the anti-sticking film falls off from the lower base material layer in the storage process of the waterproof coiled material and the viscosity stability of the lower base material layer is reduced, and therefore the effect of prolonging the storage period of the waterproof coiled material is achieved.
In summary, the present application has the following beneficial effects:
1. because SIS is adopted in the raw materials of the upper base material layer and the lower base material layer for modification, the oxidation speed of each raw material is slowed down, the viscosity stability of the waterproof coiled material is improved, and the waterproof coiled material can keep viscosity for a long time even after the anti-sticking film is damaged, so that the effect of prolonging the storage period of the waterproof coiled material is obtained. .
2. The preferred mica powder and silicone oil that adopts in this application, the roughness on release film surface can be improved in the interpolation of mica powder, thereby improve the adhesive strength of release film and lower binder layer, and after release film surface roughness improves, make release film surface easy adhesion dust, the dust is along with the adhesion of release film adhesion to the adhesion of lower binder layer on easy reduction lower binder layer, the antistatic behavior on release film surface then can be improved in the interpolation of silicone oil, release the problem of release film surface easy absorption dust, the influence of dust to lower binder layer adhesion has been reduced, thereby the stability of waterproofing membrane adhesion has been improved, consequently, the effect of extension waterproofing membrane's storage period has been obtained.
3. In the application, the carcass layer is preferably used as a supporting part of the whole waterproof coiled material, so that the strength of the waterproof coiled material can be improved; after the mixture of the upper base material layer and the lower base material layer is prepared, the mixture is coated on the matrix layer to play roles of self-adhesion and water resistance; the surface layer is covered on the upper base material layer, is exposed when in use, plays a role in protecting other layer structures of the waterproof coiled material, and can prolong the service life of the waterproof coiled material; the anti-adhesive film covers the lower base material layer, plays an isolating role when the waterproof coiled material is placed, reduces the condition that the lower base material layer is adhered to the waterproof coiled material when the waterproof coiled material is rolled up and placed so as to influence the subsequent normal use, and simultaneously reduces the condition that the lower base material layer is oxidized to reduce the viscosity when being in direct contact with the external environment.
4. According to the method, through secondary pressing at the temperature of 120-150 ℃, all the layers are in close contact, especially the connection strength of the anti-sticking film and the lower base material layer is improved, the situation that the anti-sticking film falls off from the lower base material layer in the storage process of the waterproof coiled material to reduce the viscosity stability of the lower base material layer is reduced, and therefore the effect of prolonging the storage period of the waterproof coiled material is achieved.
Detailed Description
The present application is described in further detail below with reference to examples. The specific description is as follows: the following examples, in which the specific conditions are not specified, are conducted under conventional conditions or conditions recommended by the manufacturer, and the raw materials used in the following examples are commercially available from ordinary sources except for the specific descriptions.
PET was used under the trademark FR515 from DuPont, U.S.A.
The HDPE is made of FHC7260 of China oil and gas Co., ltd.
POE-g-GMA A polyester toughening agent POG-2901 manufactured by Guangzhou Dong gold plastic technology Co., ltd.
The mica powder is prepared from muscovite powder produced by Huayuan mica limited company of Ministry of Carpesium, and has a specification of 50 meshes.
The silicone oil is water-soluble silicone oil of the model DC193 of Dow Corning.
The softening oil is three-wire oil.
SIS is given the name D1161P in Korea.
SBS is used under the name D1102JSZ of Korea.
SBR adopts SBR emulsified asphalt modifier with the product number BW-HPM produced by Siebolding new material technology Co.
The rubber powder is produced by the mining industry and has 40 meshes with CAS of 94-52-0.
The talcum powder adopts 200-mesh talcum powder.
The polyester felt is 0.8mm thick.
The polyethylene film thickness was 0.4mm.
The fine sand with the grain diameter of 80 meshes is adopted, and the paving thickness is 0.4mm.
The thickness of the aluminum foil was 0.4mm.
The PE film is a polyethylene plastic film with the thickness of 0.2mm manufactured by Texas plus geotechnical materials Co.
Preparation example
Preparation example 1
The manufacturing process of the anti-sticking film comprises the following steps:
s1, drying PET at 170 ℃ for 3 hours for later use; the HDPE was dried at 85℃for 80 minutes for further use.
S2, taking 60kg of dried PET, 40kg of dried HDPE and 8kg of POE-g-GMA, and carrying out melt blending at 260 ℃ to obtain a blend.
S3, extruding and casting the blend into a film, wherein the extruder temperature is 220 ℃, 230 ℃, 235 ℃, 240 ℃, 245 ℃, 255 ℃ and 250 ℃ from one zone to eight zones respectively, and the machine head temperature is 250 ℃ and the rotating speed is 80rpm, so that the anti-sticking film with the thickness of 0.2mm is prepared.
Preparation example 2
The difference between this preparation and preparation 1 is: the weight of each raw material was different, and the melt blending temperature was different, as shown in Table 1.
Preparation example 3
The difference between this preparation and preparation 1 is: the weight of each raw material was different, and the melt blending temperature was different, as shown in Table 1.
Preparation example 4
The difference between this preparation and preparation 2 is: and (3) taking 4kg of mica powder and 3kg of silicone oil, uniformly coating silicone oil on the surface of the membrane after the membrane is prepared in the step (S3), uniformly spraying a layer of mica powder on one surface of the membrane coated with the silicone oil, and drying to obtain the anti-sticking membrane.
Preparation example 5
The difference between this preparation and preparation 4 is: the weights of the mica powder and the silicone oil are different, and the weights of the raw materials are shown in Table 1 in detail.
Preparation example 6
The difference between this preparation and preparation 4 is: the weights of the mica powder and the silicone oil are different, and the weights of the raw materials are shown in Table 1 in detail.
Preparation example 7
The difference between this preparation and preparation 5 is: the preparation example has no mica powder, and the weight of each raw material is shown in table 1.
Preparation example 8
The difference between this preparation and preparation 5 is: in the preparation example, no silicone oil is used, and the weight of each raw material is shown in Table 1.
TABLE 1
Examples
Example 1
The preparation method of the self-adhesive polymer waterproof coiled material comprises the following steps:
(1) Preparing a mixture of an upper base material layer and a lower base material layer:
a1, 38kg of No. 90 asphalt, 7kg of three-wire oil, 1kg of SBS, 4kg of SIS and 15kg of rubber powder are taken and stirred at 180 ℃ and are mixed until uniform, so as to obtain a mixture.
And A2, adding 35kg of talcum powder into the mixture prepared in the step A1, cooling to 140 ℃, and stirring until the talcum powder is uniformly dispersed to obtain a mixture for later use.
(2) Preparing a waterproof coiled material:
b1, taking a polyester felt as a matrix layer, uniformly coating a mixture of an upper base material layer and a lower base material layer on two surfaces of the polyester felt, and rolling to form the upper base material layer and the lower base material layer.
And B2, taking a polyethylene film as a surface layer, covering the polyethylene film on one side of the upper base material layer far away from the matrix layer, covering the anti-adhesive film prepared in the preparation example 1 on one side of the lower base material layer far away from the polyester felt, and rolling for the second time to prepare the waterproof coiled material with the thickness of 3 mm.
Example 2
This embodiment differs from embodiment 1 in that: the weight of each raw material is different, the stirring temperature in A1 is different, the temperature after cooling in A2 is different, and the details are shown in Table 2.
The release film was prepared by using the release film prepared in preparation example 2.
Example 3
This embodiment differs from embodiment 1 in that: the weight of each raw material is different, the stirring temperature in A1 is different, the temperature after cooling in A2 is different, and the details are shown in Table 2.
The release film prepared in preparation example 3 was used as the release film.
Example 4
This embodiment differs from embodiment 2 in that: asphalt No. 200 asphalt was used, and the weights of the other raw materials were different, as shown in Table 2.
Example 5
This embodiment differs from embodiment 4 in that: the surface layer is made of fine sand.
Example 6
This embodiment differs from embodiment 4 in that: the surface layer is made of aluminum foil.
Example 7
This embodiment differs from embodiment 4 in that:
and B2, taking a polyethylene film as a surface layer, covering the polyethylene film on the side, far away from the matrix layer, of the upper base material layer, covering the anti-sticking film prepared in preparation example 4 on the side, far away from the polyester felt, of the lower base material layer, attaching the side, with mica powder, of the anti-sticking film to the lower base material layer, and performing secondary pressing to prepare the waterproof coiled material with the thickness of 3mm, wherein the heating temperature is 120 ℃ in the secondary pressing process.
Example 8
This embodiment differs from embodiment 7 in that: the anti-adhesive film prepared in preparation example 5 was used, and the heating temperature was 140 ℃.
Example 9
This embodiment differs from embodiment 7 in that: the anti-adhesive film prepared in preparation example 6 was used, and the heating temperature was 150 ℃.
Example 10
This embodiment differs from embodiment 8 in that: the release film was prepared by using the release film prepared in preparation example 7.
Example 11
This embodiment differs from embodiment 8 in that: the release film was prepared by using the release film prepared in preparation example 8.
Example 12
This embodiment differs from embodiment 8 in that: the secondary pressing adopts a rolling process under normal temperature.
TABLE 2
Comparative example
Comparative example 1
The self-adhesive polymer waterproof coiled material in the related art is prepared according to the following steps:
(1) Preparing a mixture of a base material layer:
a1, 40.5kg of No. 90 asphalt, 11.5kg of three-wire oil, 5kg of SBR, 2kg of SBS and 13kg of rubber powder are taken and stirred at 200 ℃ until the mixture is uniform, and a mixture is obtained.
And A2, adding 28kg of talcum powder into the mixture prepared in the step A1, cooling to 150 ℃, and stirring until the talcum powder is uniformly dispersed to obtain a mixture for later use.
(2) Preparing a waterproof coiled material:
b1, taking a polyester felt carcass layer, uniformly coating mixture of base material layers on two surfaces of the polyester felt carcass layer, and rolling.
And B2, pressing a PE film on one side of the base material layer far away from the polyester felt matrix layer by a roller to prepare the waterproof coiled material with the thickness of 3 mm.
Performance test
Detection method
1. Detection of viscosity stability: the waterproof rolls prepared in examples 1 to 4 were peeled off and the lower base material was exposed, the waterproof roll prepared in comparative example 1 was peeled off and the PE film was exposed, and the waterproof rolls prepared in examples and comparative examples were subjected to peel strength tests each day according to the test method of "5.12.2 rolls and aluminum plate" in "GB23441-2009" until the peel strength of all the tested waterproof rolls was less than 1.5N/mm, and the test was ended, and the storage period was recorded when the peel strength of each of the waterproof rolls prepared in examples or comparative examples was less than 1.5N/mm, and the test results were shown in Table 3 in detail.
2. Tear strength performance test of anti-adhesive film and PE film: the test method "QB/T1130-1991" was used to test the right angle tear strength of the anti-adhesive films prepared in each preparation and the PE film used in comparative example 1, and the test results are shown in Table 4.
3. Anti-impact properties of anti-adhesive film and PE film detection: the anti-adhesive films prepared in each preparation example and the PE film used in comparative example 1 were tested for impact resistance by using a test method of GB/T8809-2015, a B-type punch was used in the test, the diameter of the corresponding clamp was (89.+ -. 0.5) mm, and the test results are shown in Table 4.
4. Antistatic properties of anti-sticking film and PE film detection: the anti-sticking film prepared in each preparation example and the PE film used in comparative example 1 were tested for resistivity by the test method of "GB/T15738-2008", the lower the resistivity, the better the anti-static property, and the test results are shown in Table 4.
5. And (3) detecting the connection strength performance between the anti-adhesive film and the lower base material layer: the average peeling force between the anti-sticking film and the lower base material layer of the waterproof coiled materials prepared in example 4 and examples 7-12 was detected by using the test method of GB8808-88, and the test speed was 300+ -50 mm/min by adopting the dimension of A method. The greater the average peel force, the higher the strength of the bond between the release film and the lower base layer, and the test results are detailed in table 5.
TABLE 3 Table 3
Examples/comparative examples | Storage period/day |
Example 1 | 182 |
Example 2 | 187 |
Examples3 | 180 |
Example 4 | 252 |
Comparative example 1 | 7 |
TABLE 4 Table 4
TABLE 5
As can be seen from the combination of example 2 and comparative example 1 and the combination of table 3, compared with comparative example 1, SIS was used in place of SBR in the waterproof roll manufactured in comparative example 1 in the waterproof roll manufactured in example 2, and the speed of oxidation of the lower base material layer or the upper base material layer after direct contact with the external environment was slowed down, thereby improving the stability of the tackiness of the waterproof roll, and as can be seen from the experimental results in table 3, the tackiness of the waterproof roll manufactured in example 2 was maintained for 187 days after peeling the anti-sticking film, and the tackiness of the waterproof roll manufactured in comparative example 1 was maintained for only 7 days after peeling the PE film, so the scheme proposed in this application achieves the effect of extending the storage period of the waterproof roll.
As can be seen from the combination of example 2 and example 4 and the combination of table 3, compared with example 2, the waterproof roll manufactured in example 4 uses 200 # asphalt instead of 90 # asphalt in example 2, the amount of three-wire oil is reduced, thereby further slowing down the oxidation speed of each raw material in the upper base material layer and the lower base material layer, improving the stability of the adhesiveness of the waterproof roll, as can be seen from the experimental results in table 3, the adhesiveness of the waterproof roll manufactured in example 2 is kept for 187 days after peeling the anti-adhesive film, and the adhesiveness of the waterproof roll manufactured in example 4 is kept for 252 days after peeling the PE film, thereby obtaining the effect of prolonging the storage period of the waterproof roll.
As can be seen from the combination of the PE films used in preparation example 2 and comparative example 1 and the table 4, the anti-sticking film prepared in preparation example 2 is made of blending PET and HDPE, and as can be seen from the experimental results in table 4, compared with the PE film, the anti-sticking film prepared in preparation example 2 has better tear resistance and impact resistance, and is less prone to breakage when being broken by external force, thereby reducing the damage degree of the anti-sticking film caused by external force, increasing the protection effect on the lower base material layer, and further prolonging the storage period of the waterproof coiled material.
As can be seen from the combination of examples 4 and 8 and the combination of tables 4 and 5, the anti-adhesive film prepared in preparation example 2 was used in example 4, the anti-adhesive film prepared in preparation example 5 was used in example 8, and mica powder and silicone oil were added to the anti-adhesive film prepared in preparation example 5, compared with the anti-adhesive film prepared in preparation example 2, it can be seen from table 5 that the average peeling force between the anti-adhesive film of example 8 and the lower base material layer was improved by 2 times compared with the average peeling force between the anti-adhesive film of example 4 and the lower base material layer, so that the connection strength between the anti-adhesive film and the lower base material layer was improved by spraying of mica powder, and at the same time, as can be seen from table 4, the anti-adhesive film prepared in preparation example 5 was also lower in resistivity than the anti-adhesive film prepared in preparation example 2, the anti-static property of the anti-adhesive film prepared in preparation example 5 was better, the problem that dust was easily absorbed on the surface of the anti-adhesive film was alleviated, the influence of dust on the lower base material layer was reduced, the stability of the adhesive roll was improved, and therefore the effect of prolonging the storage period of the waterproof roll was obtained.
As can be seen from the combination of examples 4, 8, 10 and 11 and the combination of tables 4 and 5, the anti-adhesive film prepared in example 2 was used in example 4, the anti-adhesive film prepared in example 5 was used in example 8, the anti-adhesive film prepared in example 7 was used in example 10, the anti-adhesive film prepared in example 8 was used in example 11, mica powder and silicone oil were added to the anti-adhesive film prepared in example 5, mica powder and silicone oil were not added to the anti-adhesive film prepared in example 5, and silicone oil was not added to the anti-adhesive film prepared in example 7, as can be seen from the test results of tables 4 and 5, the average peel force between the anti-adhesive film and the lower base material layer of the waterproof roll material prepared in example 8 was the largest, and the anti-adhesive film prepared in example 5 had the lowest resistivity, so that the synergy of the mica powder and silicone oil was reflected, and the anti-adhesive film prepared in example 5 was capable of improving the connection strength between the anti-adhesive film and the lower base material layer and also alleviating the problem of dust easily adsorbed on the surface of the anti-adhesive film.
It can be seen from the combination of example 8 and example 12 and the combination of table 5 that the difference between example 8 and example 12 is that example 8 is heated simultaneously during the secondary pressing process of preparing the waterproof roll, while example 12 is at normal temperature during the secondary pressing process of preparing the waterproof roll, and as can be seen from table 5, the average peeling force between the release film and the lower base material layer of the waterproof roll prepared in example 8 is 1.67 times that of example 12, thus, the effect of the process condition on improving the connection strength between the release film and the lower base material layer is reflected, thereby increasing the protective effect on the lower base material layer, and further prolonging the storage period of the waterproof roll.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (4)
1. The utility model provides a self-adhesion polymer waterproofing membrane which characterized in that: the anti-sticking adhesive comprises a surface layer, an upper base material layer, a carcass layer, a lower base material layer and an anti-sticking film which are sequentially connected, wherein the upper base material layer and the lower base material layer comprise the following raw materials in percentage by weight:
38-50% of No. 200 asphalt;
7-12% of softening oil;
SIS 4~6%;
SBS 1~3%;
9-15% of rubber powder;
20-35% of talcum powder;
the anti-sticking film comprises the following raw materials in parts by weight: 60-70 parts of PET, 30-40 parts of HDPE, 8-12 parts of POE-g-GMA, 4-6 parts of mica powder and 3-5 parts of silicone oil;
the manufacturing process of the anti-sticking film comprises the following steps:
s1, respectively drying PET and HDPE;
s2, melting and blending PET, HDPE and POE-g-GMA according to the proportion at 260-285 ℃ to obtain a blend;
and S3, extruding and casting the blend into a film, coating silicone oil on the surface of the film, and then spraying mica powder on one surface of the film coated with the silicone oil to obtain the anti-sticking film.
2. A self-adhesive polymeric water-resistant web as claimed in claim 1, wherein: the asphalt is No. 200 asphalt, and the upper base material layer and the lower base material layer comprise the following raw materials in percentage by weight:
46% of No. 200 asphalt;
softening oil 7%;
SIS 5%;
SBS 2%;
12% of rubber powder;
talcum powder 28%.
3. A self-adhesive polymeric water-resistant web as claimed in claim 1, wherein: the surface layer is made of polyethylene film, fine sand or aluminum foil.
4. A method for preparing a self-adhesive polymer waterproof coiled material according to any one of claims 1 to 3, which is characterized in that: the method comprises the following steps:
(1) Preparing a mixture of an upper base material layer and a lower base material layer:
a1, mixing asphalt, softening oil, SBS, SIS and rubber powder according to a proportion under the condition of 180-220 ℃ and uniformly mixing to obtain a mixture;
a2, adding talcum powder into the mixture prepared in the step A1, cooling to 140-160 ℃, and stirring until the talcum powder is uniformly dispersed to obtain a mixture;
(2) Preparing a waterproof coiled material:
b1, uniformly coating a mixture of an upper base material layer and a lower base material layer on two surfaces of a carcass layer, and forming the upper base material layer and the lower base material layer after pressing;
b2, covering a surface layer on one side of the upper base material layer far away from the matrix layer, covering an anti-sticking film on one side of the lower base material layer far away from the matrix layer, attaching one side of the anti-sticking film with mica powder to the lower base material layer, and performing secondary pressing to obtain the waterproof coiled material, wherein the two layers are heated simultaneously in the secondary pressing process, and the temperature is set to be 120-150 ℃.
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