CN113462167A - Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof - Google Patents
Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof Download PDFInfo
- Publication number
- CN113462167A CN113462167A CN202110910055.6A CN202110910055A CN113462167A CN 113462167 A CN113462167 A CN 113462167A CN 202110910055 A CN202110910055 A CN 202110910055A CN 113462167 A CN113462167 A CN 113462167A
- Authority
- CN
- China
- Prior art keywords
- rubber
- vulcanization
- parts
- mold frame
- upper cover
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 229920001971 elastomer Polymers 0.000 claims abstract description 86
- 239000000463 material Substances 0.000 claims abstract description 65
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004088 foaming agent Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 239000010703 silicon Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 13
- 238000004073 vulcanization Methods 0.000 claims description 81
- 238000000465 moulding Methods 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 25
- 238000004898 kneading Methods 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 238000010074 rubber mixing Methods 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 239000010935 stainless steel Substances 0.000 claims description 8
- 239000004945 silicone rubber Substances 0.000 claims description 6
- 239000004636 vulcanized rubber Substances 0.000 claims description 5
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims description 3
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 2
- 238000007731 hot pressing Methods 0.000 abstract description 6
- 230000005855 radiation Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 4
- 230000001413 cellular effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229920001821 foam rubber Polymers 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/04—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam
- B29C35/045—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam using gas or flames
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
- C08J2383/07—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Abstract
The invention discloses a bendable folded high neutron shielding efficient organic silicon rubber and a preparation method thereof, wherein 110 silicon raw rubber is used as base rubber, and fumed silica and nuclear power grade B are added4C powder or foaming agent, and hot-pressing and vulcanizing under the action of a vulcanizing agent. According to different components of the material, the borosilicate rubber prepared by the invention can achieve a neutron shielding rate of over 99.9% no matter for fast neutrons, intermediate energy neutrons or slow neutrons. Can be widely applied to the neutron protection of a spallation neutron source, a nuclear facility pipeline and the personnel protection of a neutron radiation field; at the same time the materialThe material preparation process is simple and can be continuously extruded and molded.
Description
Technical Field
The invention relates to the technical field of special rubber materials, in particular to bendable folded high neutron shielding efficient organic silicon rubber and a preparation method thereof.
Background
The Chinese Spallation Neutron Source (CSNS) plan builds two target stations, each target station comprises about 20 spectrometers, at present, only 15% of the spectrometers are built, and in the next 10 years, 17 neutron spectrometers are put into construction. CSNS has limited space for construction, requires the use of a large amount of radiation shielding material at target stations, hot rooms, neutron tube systems, sample frames, scatter frames, detection frames, neutron choppers, scintillation detectors, and the like, and these parts have different shapes and complex structures, which require the shielding material to be flexible, freely cuttable and bendable, and adhesive. The neutron shielding material used in the early construction completely depends on the import, so that the construction period of the spectrometer is greatly increased, and the performance improvement of the neutron spectrometer is limited to a certain extent. Therefore, the autonomy of the engineering-grade high-performance flexible neutron shielding material can provide a powerful support for the construction of large scientific research devices in China, and the problem that the high-end shielding material depends on imported 'necks'. The development and application research of the flexible high-efficiency neutron shielding material not only has great economic value, but also can powerfully promote the development of the technology of large scientific research devices such as a spallation neutron source and the like, and has good social value.
Disclosure of Invention
The invention aims to solve the problems and provide bendable folded high neutron shielding efficient organic silicon rubber and a preparation method thereof, according to the characteristics of the molecular structure of an organic silicon material, the flexibility and the good tensile property of related materials are endowed, and the organic silicon rubber can be hot-pressed, cured and formed and can also be extruded for hot vulcanization forming4And C, uniformly mixing the powder C and a vulcanizing agent, and then carrying out hot press molding. According to the requirements of application scenes, a certain amount of closed-cell foaming agent can be added into the rubber compound, so that the flexibility of the material is further improved, and the material can be repeatedly folded at will. The material utilizes H atoms rich in 110 silica gel to slow down the diffusion rate of neutrons, and then utilizes B in the material10The slow neutrons are absorbed, and the neutron shielding effect is achieved.
The invention realizes the purpose through the following technical scheme:
the organic silicon rubber with bendable and bendable folding high neutron shielding efficiency comprises the following components in parts by weight:
100 parts of 110 silicon crude rubber, 20-45 parts of fumed silica and B4C5-100 parts, and vulcanizing agent 0.5-6.5 parts.
The organic silicon rubber with bendable and bendable folding high neutron shielding efficiency comprises the following components in parts by weight:
100 parts of 110 silicon crude rubber, 20-45 parts of fumed silica and B4C5-100 parts, vulcanizing agent 0.5-6.5 parts and foaming agent 1-6 parts.
The further scheme is that the foaming agent is one or more of sodium bicarbonate, a foaming agent H, a foaming agent F-36, a foaming agent AC, a foaming agent OBSH and a foaming agent AK.
In a further scheme, the vulcanizing agent is one or more of BPO, Biediwu and DCP.
Further, the B is4C is nuclear grade powder.
The invention also provides a preparation method of the bendable folded high neutron shielding efficient organic silicon rubber, which comprises the following steps:
a: preparing a rubber compound: adding 110 silicon crude rubber, fumed silica and B into a kneader in sequence according to the proportion4C, closing the upper cover and opening the kneading machine to knead the powder; kneading for 60 minutes, and after the inorganic powder and the 110 silicon crude rubber are completely fused, starting the kneading machine to heat the material; when the temperature of the material reaches 120 +/-10 ℃, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for 60 +/-30 minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding a vulcanizing agent, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches 3.5 +/-0.1 mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting vulcanization temperature, pressure and vulcanization time, starting the vulcanizing machine for hot-press vulcanization molding, taking out the mold frame after vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: putting the first-stage vulcanized molding rubber sheet into a blast oven with set temperature and time for second-stage vulcanization; and after the second-stage vulcanization is finished, taking out the vulcanized rubber sheet to obtain a final product.
The invention also provides a preparation method of the bendable folded high neutron shielding efficient organic silicon rubber, which comprises the following steps:
a: preparing a rubber compound: adding 110 silicon crude rubber, fumed silica and B into a kneader in sequence according to the proportion4C, closing the upper cover and opening the kneading machine to knead the powder; kneading for 60 minutes, and after the inorganic powder and the 110 silicon crude rubber are completely fused, starting the kneading machine to heat the material; when the temperature of the material reaches 120 +/-10 ℃, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for 60 +/-30 minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding a foaming agent and a vulcanizing agent, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches 3.5 +/-0.1 mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting vulcanization temperature, pressure and vulcanization time, starting the vulcanizing machine for hot-press vulcanization molding, taking out the mold frame after vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: putting the first-stage vulcanized molding rubber sheet into a blast oven with set temperature and time for second-stage vulcanization; and after the second-stage vulcanization is finished, taking out the vulcanized rubber sheet to obtain a final product.
The invention has the beneficial effects that:
the borosilicate rubber can be prepared into two types of flexible borosilicate rubber sheets without foam holes and flexible borosilicate rubber foam cushions with foam holes according to different application scenes, and has the characteristics of softness, smoothness, high tensile strength and continuous extrusion molding. According to different application scenes, materials with different H and B contents are prepared and used for shielding radiation neutrons with different energy levels, and the neutron shielding rate of the borosilicate rubber can reach more than 99.9% no matter for fast neutrons, intermediate energy neutrons or slow neutrons. Due to the excellent neutron shielding rate and good flexibility, the neutron shielding material can be widely applied to a spallation neutron source, nuclear facility pipeline neutron protection and neutron radiation field personnel protection. Meanwhile, the preparation of the material can be realized by hot pressing and continuous extrusion molding.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
The first embodiment is as follows:
a: preparing a rubber compound: 100 parts of 110 silica crude rubber, 20 parts of fumed silica and 5 parts of B are sequentially added into a kneader4And C, closing the upper cover of the powder body, opening the kneading machine for about 60 minutes, and opening the kneading machine to heat the material when the inorganic powder body is completely compatible with the 110 silicon crude rubber. When the temperature of the material reaches (120 +/-10) DEG C, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for (60 +/-30) minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed rubber material;
b: mixing the rubber materials: and (3) putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding 1.5 parts of BPO and 2 parts of DCP, and mixing for 6-8 times again. High speed roller spacing, and the thickness of the film reaches about 3.5 mm. Taking the film off the roller completely, placing the film on a clean stainless steel plate, cutting the film according to the size of a vulcanization mold frame, placing the cut film into the mold frame, and covering an upper cover of the mold frame;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting the vulcanization temperature to be 115 ℃, the pressure to be 65MPa and the vulcanization time to be 5 minutes, and starting the vulcanizing machine to carry out hot-pressing vulcanization molding; after the vulcanization is finished, taking out the mold frame, opening the upper cover and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: and (3) putting the first-stage vulcanized formed film into a blast oven with set temperature and time of 160 ℃ and 30 minutes respectively, performing second-stage vulcanization, and taking out the vulcanized film after the second-stage vulcanization is finished to obtain a final product.
Example two
A: preparing a rubber compound: 100 parts of 110 silica raw rubber, 30 parts of fumed silica and 30 parts of B are sequentially added into a kneader4C, closing the upper cover of the powder body, starting kneading for about 60 minutes, and starting the kneading machine to heat the material when the inorganic powder body is completely compatible with the 110 silicon crude rubber; when the temperature of the material reaches (120 +/-10) DEG C, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for (60 +/-30) minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed rubber material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove bubbles in the rubber material, repeatedly mixing for 10 times, adding 3 parts of foaming agent H, 1 part of BPO and 0.5 part of DCP, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches about 3.5mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting the vulcanization temperature at 120 ℃, the pressure at 65MPa and the vulcanization time for 10 minutes, starting the vulcanizing machine to perform hot-pressing vulcanization molding, taking out the mold frame after the vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: and (3) putting the first-stage vulcanized formed rubber sheet into a blast oven with set temperature and time of 160 ℃ and 30 minutes respectively, and performing second-stage vulcanization. And after the second-stage vulcanization is finished, taking out the vulcanized rubber sheet to obtain a final product.
Example three:
a: preparing a rubber compound: 100 parts of 110 silica raw rubber, 40 parts of fumed silica and 80 parts of B are sequentially added into a kneader4C, closing the upper cover of the powder body, starting kneading for about 60 minutes, and starting the kneading machine to heat the material when the inorganic powder body is completely compatible with the 110 silicon crude rubber; when the temperature of the material reaches (120 +/-10) DEG C, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for (60 +/-30) minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed rubber material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding 3 parts of BPO and 1 part of bis-penta vulcanizing agent, and mixing for 6-8 times again; the roller spacing is high, so that the thickness of the film reaches about 3.5 mm; taking the film off the roller completely, placing the film on a clean stainless steel plate, cutting the film according to the size of a vulcanization mold frame, placing the cut film into the mold frame, and covering an upper cover of the mold frame;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, and setting the vulcanization temperature to be 120 ℃, the pressure to be 65MPa and the vulcanization time to be 10 minutes; starting a vulcanizing machine to carry out hot-pressing vulcanization molding, taking out the mold frame after vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: and (3) putting the first-stage vulcanized formed film into a blast oven with set temperature and time of 160 ℃ and 30 minutes respectively, performing second-stage vulcanization, and taking out the vulcanized film after the second-stage vulcanization is finished to obtain a final product.
Example four:
a: preparing a rubber compound: 100 parts of 110 silica crude rubber, 45 parts of fumed silica and 100 parts of B are added into a kneader in sequence4C powder, closing the upper cover, opening and kneading for about 60 minutes, and taking inorganic powder as the powderAfter being completely compatible with 110 silicon crude rubber, starting a kneading machine to heat the raw material; when the temperature of the material reaches (120 +/-10) DEG C, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for (60 +/-30) minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed rubber material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove bubbles in the rubber material, repeatedly mixing for 10 times, adding 1 part of foaming agent AC, 6 parts of BPO and 0.5 part of DCP, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches about 3.5mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: and (3) putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting the vulcanization temperature to be 120 ℃, the pressure to be 65MPa and the vulcanization time to be 10 minutes, starting the vulcanizing machine to perform hot-pressing vulcanization molding, taking out the mold frame after the vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet.
D: and (3) secondary vulcanization molding: and (3) putting the first-stage vulcanized formed film into a blast oven with set temperature and time of 160 ℃ and 30 minutes respectively, performing second-stage vulcanization, and taking out the vulcanized film after the second-stage vulcanization is finished to obtain a final product.
The borosilicate rubber of the embodiment is prepared into two types of non-cellular flexible borosilicate silicone rubber sheets and cellular flexible borosilicate rubber foam cushion materials according to different application scenes; and according to different application scenes, materials with different H and B contents are prepared and used for neutron shielding in different energy levels, and the neutron shielding rate of the borosilicate rubber can reach more than 99.9% no matter for fast neutrons, intermediate energy neutrons or slow neutrons.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims. It should be noted that the various technical features described in the above embodiments can be combined in any suitable manner without contradiction, and the invention is not described in any way for the possible combinations in order to avoid unnecessary repetition. In addition, any combination of the various embodiments of the present invention is also possible, and the same should be considered as the disclosure of the present invention as long as it does not depart from the spirit of the present invention.
Claims (7)
1. The organic silicon rubber with bendable and foldable high neutron shielding efficiency is characterized by comprising the following components in parts by weight:
100 parts of 110 silicon crude rubber, 20-45 parts of fumed silica and B4C5-100 parts, and vulcanizing agent 0.5-6.5 parts.
2. The organic silicon rubber with bendable and foldable high neutron shielding efficiency is characterized by comprising the following components in parts by weight:
100 parts of 110 silicon crude rubber, 20-45 parts of fumed silica and B4C5-100 parts, vulcanizing agent 0.5-6.5 parts and foaming agent 1-6 parts.
3. The bendable folding high neutron shielding performance silicone rubber according to claim 2, wherein the foaming agent is one or more of sodium bicarbonate, foaming agent H, foaming agent F-36, foaming agent AC, foaming agent OBSH and foaming agent AK.
4. The bendable folded high neutron shielding effectiveness silicone rubber according to claim 1 or 2, wherein the vulcanizing agent is one or more of BPO, Biddi-five, DCP.
5. The bendable folded high neutron shielding performance silicone rubber according to any one of claims 1 to 4, wherein B is4C is nuclear grade powder.
6. The method for preparing the bendable folding high neutron shielding performance silicone rubber according to any one of claims 1, 4 and 5, which comprises the following steps:
a: preparing a rubber compound: adding 110 silicon crude rubber, fumed silica and B into a kneader in sequence according to the proportion4C, closing the upper cover and opening the kneading machine to knead the powder; kneading for 60 minutes, and after the inorganic powder and the 110 silicon crude rubber are completely fused, starting the kneading machine to heat the material; when the temperature of the material reaches 120 +/-10 ℃, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for 60 +/-30 minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding a vulcanizing agent, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches 3.5 +/-0.1 mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting vulcanization temperature, pressure and vulcanization time, starting the vulcanizing machine for hot-press vulcanization molding, taking out the mold frame after vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: putting the first-stage vulcanized molding rubber sheet into a blast oven with set temperature and time for second-stage vulcanization; and after the second-stage vulcanization is finished, taking out the vulcanized rubber sheet to obtain a final product.
7. The method for preparing the bendable folded high neutron shielding effectiveness silicone rubber according to any one of claims 2 to 5, comprising the following steps:
a: preparing a rubber compound: adding 110 silicon crude rubber, fumed silica and B into a kneader in sequence according to the proportion4C, closing the upper cover and opening the kneading machine to knead the powder; kneading for 60 minutesOpening the kneading machine to heat the raw material when the inorganic powder and the 110 silica gel are completely fused; when the temperature of the material reaches 120 +/-10 ℃, starting the kneader and vacuumizing to more than 0.75 MPa.s, extracting for 60 +/-30 minutes, stopping vacuumizing and heating, opening the upper cover of the kneader, naturally cooling to room temperature, and taking out the kneaded mixed material;
b: mixing the rubber materials: putting the kneaded mixed rubber material on a roller of a two-roller rubber mixing mill, repeatedly rolling to remove air bubbles in the rubber material, repeatedly mixing for 10 times, adding a foaming agent and a vulcanizing agent, and mixing for 6-8 times again; the roller spacing is high, the thickness of the film reaches 3.5 +/-0.1 mm, the film is completely taken down from the roller and placed on a clean stainless steel plate, the film is cut according to the size of a vulcanization mold frame and placed in the mold frame, and an upper cover of the mold frame is covered;
c: first-stage vulcanization molding: putting the vulcanization mold frame with the rubber sheet into a flat vulcanizing machine, setting vulcanization temperature, pressure and vulcanization time, starting the vulcanizing machine for hot-press vulcanization molding, taking out the mold frame after vulcanization is finished, opening the upper cover, and taking out the molded rubber sheet;
d: and (3) secondary vulcanization molding: putting the first-stage vulcanized molding rubber sheet into a blast oven with set temperature and time for second-stage vulcanization; and after the second-stage vulcanization is finished, taking out the vulcanized rubber sheet to obtain a final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110910055.6A CN113462167B (en) | 2021-08-09 | 2021-08-09 | Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110910055.6A CN113462167B (en) | 2021-08-09 | 2021-08-09 | Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113462167A true CN113462167A (en) | 2021-10-01 |
| CN113462167B CN113462167B (en) | 2022-08-30 |
Family
ID=77867705
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110910055.6A Active CN113462167B (en) | 2021-08-09 | 2021-08-09 | Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113462167B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113698773A (en) * | 2021-10-15 | 2021-11-26 | 中国建材检验认证集团安徽有限公司 | Flame-retardant silicone rubber flexible neutron shielding material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115484A (en) * | 1993-07-30 | 1996-01-24 | 青岛橡胶制品六厂 | Protecting material for fast neutron radiation |
| US20140312536A1 (en) * | 2011-05-13 | 2014-10-23 | Korea Atomic Energy Research Institute | Epoxy resin composition for neutron shielding, and method for preparing the same |
| CN104744945A (en) * | 2015-03-24 | 2015-07-01 | 南京航空航天大学 | Neutron shield material with flame-retardant neutron shield heat-shielding performance and preparation method thereof |
| CN108998790A (en) * | 2018-08-21 | 2018-12-14 | 中国船舶重工集团公司第七二五研究所 | A kind of aluminum-based boron carbide preparation method of composite coating |
| CN109608881A (en) * | 2018-12-24 | 2019-04-12 | 折家乐 | A kind of preparation method of rubber neutron shielding material |
-
2021
- 2021-08-09 CN CN202110910055.6A patent/CN113462167B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1115484A (en) * | 1993-07-30 | 1996-01-24 | 青岛橡胶制品六厂 | Protecting material for fast neutron radiation |
| US20140312536A1 (en) * | 2011-05-13 | 2014-10-23 | Korea Atomic Energy Research Institute | Epoxy resin composition for neutron shielding, and method for preparing the same |
| CN104744945A (en) * | 2015-03-24 | 2015-07-01 | 南京航空航天大学 | Neutron shield material with flame-retardant neutron shield heat-shielding performance and preparation method thereof |
| CN108998790A (en) * | 2018-08-21 | 2018-12-14 | 中国船舶重工集团公司第七二五研究所 | A kind of aluminum-based boron carbide preparation method of composite coating |
| CN109608881A (en) * | 2018-12-24 | 2019-04-12 | 折家乐 | A kind of preparation method of rubber neutron shielding material |
Non-Patent Citations (2)
| Title |
|---|
| 吴鹏等: "新型柔性硼基苯基硅橡胶中子屏蔽材料的制备和性能研究", 《化工新型材料》 * |
| 文全东等: "热硫化苯基硅生胶/碳化硼复合材料的制备及相关性能研究", 《化工新型材料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113698773A (en) * | 2021-10-15 | 2021-11-26 | 中国建材检验认证集团安徽有限公司 | Flame-retardant silicone rubber flexible neutron shielding material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113462167B (en) | 2022-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113462167B (en) | Bendable folded high neutron shielding performance organic silicon rubber and preparation method thereof | |
| CN102708937B (en) | Anti-thermal neutron radiation shielding material and preparation method thereof | |
| WO2015101242A1 (en) | High filling and high resilience soft foaming polyethylene material and preparation method thereof | |
| CN109181055A (en) | Radiant crosslinked polyethylene foam and its preparation method and application | |
| CN110256977A (en) | The coloured EVA film of single layer, preparation method and application and solar cell module | |
| CN101717581B (en) | Peroxidated heat-vulcanized silicone rubber resistant to irradiation and preparation method thereof | |
| CN105670137B (en) | A kind of polybutene foamed material and preparation method thereof | |
| CN107383293B (en) | A kind of preparation method of the polyether-ether-ketone suitable for 3D printing | |
| CN104788965B (en) | A kind of high anti-tear corrosion-resistant silicon rubber and its preparation method and application | |
| CN103254402B (en) | Preparation method of water-swellable elastomer material | |
| CN101768362A (en) | Condensed room temperature vulcanized silicone rubber with radiation-resistant property and preparation method thereof | |
| CN110240757A (en) | Ethylene propylene diene rubber flexibility base neutron shielding material and preparation method thereof | |
| CN101717583B (en) | Additional hot vulcanized silicon rubber with radiation resistant property and preparation method thereof | |
| CN102399390A (en) | Preparation method of radiation-crosslinked polypropylene | |
| CN111087710A (en) | Compression molding heat-insulation mute rubber-plastic sound-absorbing board and preparation method thereof | |
| CN116855191A (en) | High-impact adhesive film and preparation method thereof | |
| CN106243315A (en) | A kind of roof of the vehicle the PU cystosepiment of low plasticization temperature and production technology thereof | |
| CN115195004A (en) | Capacitor polypropylene film high-temperature breakdown performance improving method based on gamma ray irradiation crosslinking modification | |
| CN104403240B (en) | High light-shading solar battery back membrane material and preparation method thereof | |
| CN106700400A (en) | High-damping silicone rubber modified ABS (acrylonitrile-butadiene-styrene) acoustic insulating material preparation method based on low-frequency noise protection | |
| WO2021103340A1 (en) | Low-temperature supercritical foaming process | |
| CN103971775A (en) | High temperature resistance neutron shield material and preparation method thereof | |
| CN101791859A (en) | Manufacturing method of ultra-high molecular weight polyethylene radiation-resistant plate | |
| CN105437447A (en) | Foaming method for foamed plastic board | |
| CN110028794A (en) | A kind of tungsten lead doped silicon rubber-base flexible material having radiation shield function and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240428 Address after: No. 1 Kaiyue Road, Youxian High tech Industrial Park (South Park), Youxian District, Mianyang City, Sichuan Province, 621000 Patentee after: Sichuan Maike Hedun New Material Technology Co.,Ltd. Country or region after: China Address before: Mianyang City, Sichuan Province, 621000 Mountain Road No. 64 Patentee before: INSTITUTE OF CHEMICAL MATERIALS OF CHINA ACADEMY OF ENGINEERING AND PHYSICS Country or region before: China |
|
| TR01 | Transfer of patent right |