CN113429921A - Hot-melt pressure-sensitive adhesive and pre-paved waterproof coiled material applying same - Google Patents

Hot-melt pressure-sensitive adhesive and pre-paved waterproof coiled material applying same Download PDF

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Publication number
CN113429921A
CN113429921A CN202110826093.3A CN202110826093A CN113429921A CN 113429921 A CN113429921 A CN 113429921A CN 202110826093 A CN202110826093 A CN 202110826093A CN 113429921 A CN113429921 A CN 113429921A
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sensitive adhesive
parts
melt pressure
hot
antioxidant
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CN202110826093.3A
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CN113429921B (en
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陈志伟
杨小育
龚兴宇
黄祖行
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Weinan Keshun New Material Co ltd
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Weinan Keshun New Material Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09J157/02—Copolymers of mineral oil hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
    • C09J193/04—Rosin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35—Heat-activated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/383—Natural or synthetic rubber
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/66—Sealings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C

Abstract

The application discloses hot melt pressure sensitive adhesive and use this hot melt pressure sensitive adhesive's pre-paved waterproofing membrane. The raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of an olefin copolymer containing alpha-olefin; 30-180 parts of hydrogenated synthetic rubber; 20-180 parts of a plasticizer; 40-300 parts of tackifying resin; 2-12 parts of a composite antioxidant; 2-12 parts of a composite light stabilizer. The hot-melt pressure-sensitive adhesive has excellent ultraviolet aging resistance.

Description

Hot-melt pressure-sensitive adhesive and pre-paved waterproof coiled material applying same
Technical Field
The application belongs to the technical field of waterproof materials, and particularly relates to a hot-melt pressure-sensitive adhesive and a pre-paved waterproof coiled material.
Background
The existing waterproof coiled materials can be divided into self-adhesive waterproof coiled materials, wet-paved waterproof coiled materials and pre-paved waterproof coiled materials according to different construction processes. The construction process of pre-spreading waterproof roll includes spreading waterproof roll in advance, pouring concrete and adhering the concrete to the roll firmly. However, in actual construction, after the pre-laid waterproofing membrane is laid, concrete may need to be left for a certain period of time to be poured due to a change in construction plan. In the process, the waterproof coiled material is easy to age under the action of ultraviolet light to influence the bonding performance of the waterproof coiled material.
Disclosure of Invention
The application provides in a first aspect a hot melt pressure sensitive adhesive comprising the following raw material components in parts by weight:
Figure BDA0003173633970000011
according to the hot melt pressure sensitive adhesive of the present application, since the raw material thereof includes the olefin copolymer containing α -olefin, the olefin copolymer containing α -olefin has a lower degree of unsaturation compared to synthetic rubber, and photo-oxidative aging is less likely to occur due to irradiation of ultraviolet light, so that the hot melt pressure sensitive adhesive of the present application has excellent ultraviolet aging resistance. In addition, the ultraviolet aging resistance of the hot melt pressure sensitive adhesive is further improved by utilizing the matching of the composite light stabilizer and the olefin copolymer containing alpha-olefin. According to the hot-melt pressure-sensitive adhesive, the hot-melt pressure-sensitive adhesive is not easy to age and crack under the action of ultraviolet rays, and can still keep better bonding strength.
In an alternative embodiment of the first aspect of the present application, the above-mentioned olefin copolymer containing α -olefin is selected from at least one of an amorphous α -olefin copolymer and a polyolefin elastomer POE, preferably a polyolefin elastomer POE prepared with a metallocene as a catalyst.
In an alternative embodiment of the first aspect of the present application, the polyolefin elastomer POE has a melt index of 10 to 40g/min measured at 190 ℃, under a load of 2.16kg, and with a pore diameter of 2.1 mm.
In an alternative embodiment of the first aspect of the present application, the amorphous α -olefin copolymer has a melt viscosity of 2000 to 100000mPa · s measured at 190 ℃ and a weight average molecular weight Mw40000-100000, number average molecular weight MnIs 5000 to 30000.
In an alternative embodiment of the first aspect of the present application, the polyolefin elastomer POE is an ethylene-octene copolymer, preferably an ethylene-octene copolymer prepared using a metallocene as a catalyst.
In an alternative embodiment of the first aspect of the present application, the hot melt pressure sensitive adhesive comprises the following raw material components by weight:
Figure BDA0003173633970000021
in an alternative embodiment of the first aspect of the present application, the weight ratio of the olefin copolymer comprising alpha-olefin to the hydrogenated synthetic rubber is 1 (1 to 1.2).
In an alternative embodiment of the first aspect of the present application, the hydrogenated synthetic rubber is selected from at least one of the hydrogenated styrene thermoplastic elastomer SEBS or the hydrogenated styrene thermoplastic elastomer SEPS.
In an alternative embodiment of the first aspect of the present application, the styrene content of the hydrogenated synthetic rubber is preferably 10 to 30 wt%.
In an alternative embodiment of the first aspect of the present application, the plasticizer is selected from at least one of paraffinic oil, aromatic oil and naphthenic oil, preferably naphthenic oil;
and/or the tackifying resin is selected from at least one of C5 petroleum resin, C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin, C9 hot polymerized petroleum resin, C9 cold polymerized petroleum resin, rosin resin and terpene phenolic resin;
and/or, the compound antioxidant is selected from at least two of hindered phenol antioxidants and phosphite antioxidants;
and/or the composite light stabilizer is at least two selected from benzotriazole light stabilizer, triazine light stabilizer and hindered amine light stabilizer.
In an alternative embodiment of the first aspect of the present application, the complex antioxidant is selected from at least two of antioxidant 1010, antioxidant 168, antioxidant 1076, antioxidant 1726, preferably a combination of at least one of antioxidant 1010, antioxidant 1076 or antioxidant 1726 and antioxidant 168.
In an alternative embodiment of the first aspect of the present application, the composite light stabilizer is selected from at least two of the ultraviolet light absorbers UV-326, UV-1577, light stabilizer 770, and light stabilizer 622, preferably a combination of at least one of the ultraviolet light absorbers UV-326 or UV-1577 with at least one of the light stabilizer 770 and the light stabilizer 622.
The second aspect of the application provides a pre-paved waterproof roll, which comprises a surface anti-sticking protective layer, a self-sticking layer and a main body waterproof material layer, wherein,
the surface anti-sticking protective layer comprises at least one of isolation paint, reaction sand, quartz sand, silt and mullite sand, and the isolation paint is preferably at least one of acrylate paint and polyurethane paint;
the self-adhesive layer comprises a hot melt pressure sensitive adhesive according to any one of the embodiments of the first aspect of the present application;
the main body waterproof material layer comprises at least one of polyethylene terephthalate, polyvinyl chloride, ethylene-vinyl acetate copolymer, ethylene copolymer modified asphalt resin, polyethylene, polypropylene and thermoplastic polyolefin.
According to the pre-paved waterproofing membrane of the second aspect of the application, the self-adhesive layer of the pre-paved waterproofing membrane comprises the hot-melt pressure-sensitive adhesive according to any one of the embodiments of the first aspect of the application, and the phenomena of ultraviolet aging and peeling strength reduction caused by ultraviolet irradiation of the self-adhesive layer of the pre-paved waterproofing membrane are reduced. According to the pre-paved waterproofing membrane of the second aspect of the application, even under the irradiation of ultraviolet rays, the high peeling strength can be still maintained, and the pre-paved waterproofing membrane has excellent ultraviolet aging resistance.
In the optional embodiment of the second aspect of the present application, the main body waterproof material layer is a high density polyethylene layer, the surface anti-sticking protective layer is a mullite sand layer, and the thickness of the self-sticking layer is 0.15-0.5 mm.
Detailed Description
In order to make the purpose, technical solution and advantageous technical effects of the present invention clearer, the present invention is further described in detail with reference to the following embodiments. It should be understood that the embodiments described in this specification are only for the purpose of explaining the present application and are not intended to limit the present application.
For the sake of brevity, only some numerical ranges are explicitly disclosed herein. However, any lower limit may be combined with any upper limit to form ranges not explicitly recited; and any lower limit may be combined with any other lower limit to form a range not explicitly recited, and similarly any upper limit may be combined with any other upper limit to form a range not explicitly recited. Also, although not explicitly recited, each point or individual value between endpoints of a range is encompassed within the range. Thus, each point or individual value can form a range not explicitly recited as its own lower or upper limit in combination with any other point or individual value or in combination with other lower or upper limits.
In the description herein, when a composition is described as containing, comprising, or including a particular component, or when a process is described as containing, comprising, or including a particular process step, it is contemplated that the composition of the present application also consists essentially of, or consists of, the component, and that the process of the present application also consists essentially of, or consists of, the process step.
The use of the terms "comprising," "including," "containing," and "having" are generally to be construed as open-ended and non-limiting unless otherwise expressly specified.
In the description herein, it is to be noted that, unless otherwise specified, "above" and "below" are inclusive, and "a plurality" of "one or more" means two or more.
The above summary of the present application is not intended to describe each disclosed embodiment or every implementation of the present application. The following description more particularly exemplifies illustrative embodiments. At various points throughout this application, guidance is provided through a list of embodiments that can be used in various combinations. In each instance, the list is merely a representative group and should not be construed as exhaustive.
According to the construction process of pre-laying the waterproof roll, firstly laying the waterproof roll, then pouring concrete, and the concrete can be firmly bonded with the roll. The inventor finds that after the pre-paved waterproof roll is paved, concrete needs to be poured after being left for a certain time due to the change of a construction plan because of the requirement of actual construction. In the period, because the hot-melt pressure-sensitive adhesive used in the self-adhesive layer in the prior art does not have good ultraviolet aging resistance, under the action of ultraviolet rays in sunlight, the self-adhesive layer of the pre-paved waterproof roll is easy to age and crack, so that the bonding strength is reduced, and finally, the phenomenon of layering and falling off of the pre-paved waterproof roll can be caused.
In view of the above, the application provides a hot-melt pressure-sensitive adhesive, a preparation method thereof and a pre-paved waterproof roll.
The application provides in a first aspect a hot melt pressure sensitive adhesive comprising the following raw material components in parts by weight:
Figure BDA0003173633970000051
according to the hot melt pressure sensitive adhesive of the first aspect of the present application, since the raw material thereof includes the olefin copolymer containing α -olefin, the olefin copolymer containing α -olefin has a lower degree of unsaturation compared to synthetic rubber, and photo-oxidative aging is less likely to occur due to irradiation of ultraviolet light, the hot melt pressure sensitive adhesive according to the present application has excellent ultraviolet aging resistance. In addition, the ultraviolet aging resistance of the hot melt pressure sensitive adhesive is further improved by utilizing the matching of the composite light stabilizer and the olefin copolymer containing alpha-olefin. According to the hot-melt pressure-sensitive adhesive, the hot-melt pressure-sensitive adhesive is not easy to age and crack under the action of ultraviolet rays, and can still keep better bonding strength.
In the hot melt pressure sensitive adhesive provided by the first aspect of the present application, the olefin copolymer containing α -olefin contained in the raw material is a nonpolar polymer. The conventional synthetic rubber contains carbon-carbon double bonds inside, and the two ends of the carbon-carbon double bonds are connected with different groups, so that the two carbon atom electron cloud densities are different, and finally the carbon-carbon double bonds have certain weak polarity, so that the synthetic rubber belongs to a weak polarity polymer. Conventional synthetic rubbers are poorly compatible with olefin copolymers containing alpha-olefins according to the principle of similar compatibility. If the conventional synthetic rubber is used as a raw material of the hot-melt pressure-sensitive adhesive, the cohesive strength of the hot-melt pressure-sensitive adhesive at the later use stage is weakened, and the bonding effect is poor.
The hydrogenated synthetic rubber reduces the content of the whole carbon-carbon double bonds by hydrogenating the carbon-carbon double bonds of the non-hydrogenated synthetic rubber, thereby reducing the polarity of the hydrogenated synthetic rubber and improving the compatibility of the hydrogenated synthetic rubber and the olefin copolymer containing alpha-olefin.
The hot melt pressure sensitive adhesive of the raw material comprising the hydrogenated synthetic rubber and the olefin copolymer containing alpha-olefin provided by the first aspect of the application has good compatibility with the hot melt pressure sensitive adhesive of the olefin copolymer containing alpha-olefin, and can still keep higher cohesive strength in the later period of use.
In some embodiments, the above-described olefin copolymer comprising an α -olefin may be selected from at least one of an amorphous α -olefin copolymer and a polyolefin elastomer POE.
The amorphous alpha-olefin copolymer is a random copolymer obtained by polymerizing alpha-olefin (such as ethylene, propylene, 1-butylene and the like), and has low molecular weight and high randomness.
Polyolefin elastomers POE include copolymers of C4-C8 alpha-olefins with ethylene. In some embodiments, the polyolefin elastomer POE may preferably be a polyolefin elastomer POE prepared using a metallocene catalyst.
The inventor finds that the hot-melt pressure-sensitive adhesive prepared by using the polyolefin elastomer POE prepared by using metallocene as a catalyst has excellent ultraviolet aging resistance. The polyolefin elastomer POE has narrow relative molecular mass distribution and uniform short chain branch distribution on one hand, and on the other hand, as the molecular chain is saturated and contains less tertiary carbon atoms, the polyolefin elastomer POE can be used as the raw material of the hot-melt pressure-sensitive adhesive, and can obviously improve the ultraviolet aging resistance of the hot-melt pressure-sensitive adhesive.
In some embodiments, the polyolefin elastomer POE may have a melt index of 10 to 40g/min measured at 190 ℃, under a load of 2.16kg, and with a pore diameter of 2.1 mm.
The melt index of the polyolefin elastomer POE is in a proper range, so that the impact resistance, the environmental stress cracking resistance and the chemical medium resistance of the hot-melt pressure-sensitive adhesive containing the polyolefin elastomer POE can be improved, and the performances of the hot-melt pressure-sensitive adhesive, such as breaking strength, hardness, toughness, ageing resistance stability and the like, can be improved.
In some embodiments, the amorphous α -olefin copolymer has a melt viscosity of 2000 to 100000 mPa-s (absolute viscosity) measured at 190 ℃w40000-100000, number average molecular weight MnIs 5000 to 30000.
Melt viscosity and M of amorphous alpha-olefin copolymerw、MnIn a proper range, the ultraviolet aging resistance of the hot melt pressure sensitive adhesive can be improved, and the adhesive property, strength, elasticity, toughness and abrasion resistance of the hot melt pressure sensitive adhesive can also be improved.
In some embodiments, the polyolefin elastomer POE may preferably be an ethylene-octene copolymer, and more preferably an ethylene-octene copolymer prepared by using metallocene as a catalyst.
Compared with other polyolefin elastomers POE, the ethylene-octene copolymer has more carbon atoms, longer branched chains, better tensile strength, rheological property, fast and slow cracking resistance and impact resistance, and can further improve the performances of the hot melt pressure sensitive adhesive such as breaking strength, hardness, toughness, ageing resistance stability and the like.
In some embodiments, the hot melt pressure sensitive adhesive may comprise the following raw material components by weight:
Figure BDA0003173633970000071
by adopting the raw material components in parts by weight, the hot-melt pressure-sensitive adhesive has better ultraviolet aging resistance.
In some embodiments, the weight ratio of the above-mentioned olefin copolymer containing an α -olefin to the hydrogenated synthetic rubber may be 1 (1 to 1.2).
The inventors have found that the amount ratio of the olefin copolymer containing α -olefin to the hydrogenated synthetic rubber is an important factor affecting the performance of the hot melt pressure sensitive adhesive. As the amount of the olefin copolymer containing α -olefin used relative to the hydrogenated synthetic rubber increases, the normal peel strength of the hot melt pressure sensitive adhesive decreases. On the contrary, as the amount of the alpha-olefin-containing olefin copolymer relative to the hydrogenated synthetic rubber is decreased, the peel strength of the hot melt pressure sensitive adhesive after ultraviolet aging is decreased. In order to make the hot-melt pressure-sensitive adhesive have excellent normal-state peel strength and peel strength after ultraviolet aging, the inventor selects the dosage proportion of the olefin copolymer containing alpha-olefin and hydrogenated synthetic rubber, so that the provided hot-melt pressure-sensitive adhesive has excellent service performance.
In some embodiments, the hydrogenated synthetic rubber may be selected from at least one of a hydrogenated styrene thermoplastic elastomer SEBS or a hydrogenated styrene thermoplastic elastomer SEPS.
In some embodiments, the styrene content of the hydrogenated synthetic rubber may be 10 to 30 wt%.
The polarity of the hydrogenated synthetic rubber increases with the styrene content, and the resistance to thermo-oxidative ageing increases with the styrene content. The inventor selects hydrogenated synthetic rubber with the styrene content of 10-30 wt%, and can ensure the compatibility of the hydrogenated synthetic rubber and an olefin copolymer containing alpha-olefin and simultaneously give consideration to the thermal oxidation aging resistance of the hot-melt pressure-sensitive adhesive.
In some embodiments, the plasticizer may be at least one selected from the group consisting of paraffin oil, aromatic oil, and naphthenic oil, preferably naphthenic oil.
The naphthenic oil is further preferably prepared by a three-stage high-pressure hydrogenation process. Compared with the conventional naphthenic oil containing partially hydrogenated unsaturated aromatic hydrocarbon, the naphthenic oil prepared by the three-section high-pressure hydrogenation process has the advantages that unsaturated bonds of non-hydrocarbon compounds are deeply removed, and the ultraviolet aging resistance is more excellent. The naphthenic oil prepared by the three-stage high-pressure hydrogenation process is used as a raw material of the hot-melt pressure-sensitive adhesive, and the ultraviolet aging resistance of the hot-melt pressure-sensitive adhesive can be further improved.
In some embodiments, the naphthenic oil may be further preferably a cramaezkinh-series naphthenic oil product.
In some embodiments, the tackifying resin may be selected from at least one of C5 petroleum resin, C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin, C9 hot polymerized petroleum resin, C9 cold polymerized petroleum resin, rosin resin, and terpene phenolic resin.
In some embodiments, the complex antioxidant may be selected from at least two of hindered phenolic antioxidants and phosphite antioxidants.
It is understood that the complex antioxidant may comprise at least two antioxidants of the hindered phenol antioxidants, may comprise at least two antioxidants of the phosphite antioxidants, and may comprise at least one of the hindered phenol antioxidants and at least one of the phosphite antioxidants. The complex antioxidant may preferably be a complex antioxidant containing at least one antioxidant selected from hindered phenol antioxidants and at least one antioxidant selected from phosphite antioxidants.
In some embodiments, the above-mentioned composite light stabilizer may be selected from at least two of a benzotriazole-based light stabilizer, a triazine-based light stabilizer, and a hindered amine-based light stabilizer.
It will be readily understood that the above-mentioned composite light stabilizer may be selected from at least two of the same type of light stabilizer, or from at least two of different types of light stabilizers. The composite light stabilizer may preferably be a combination of at least one of a benzotriazole light stabilizer and a triazine light stabilizer with a hindered amine light stabilizer.
In some embodiments, the complex antioxidant may preferably be at least two of antioxidant 1010, antioxidant 168, antioxidant 1076, antioxidant 1726, further preferably a combination of at least one of antioxidant 1010, antioxidant 1076, or antioxidant 1726 and antioxidant 168.
In some embodiments, the composite light stabilizer may preferably be at least two of the ultraviolet absorber UV-326, the ultraviolet absorber UV-1577, the light stabilizer 770, the light stabilizer 622, further preferably a combination of at least one of the ultraviolet absorber UV-326 or the ultraviolet absorber UV-1577 and at least one of the light stabilizer 770, the light stabilizer 622.
The second aspect of the application provides a pre-paved waterproof roll, which comprises a surface anti-sticking protective layer, a self-sticking layer and a main body waterproof material layer, wherein,
the surface anti-adhesion protective layer comprises at least one of a release coating, reaction sand, quartz sand, silt and mullite sand, and the release coating is preferably at least one of an acrylate coating and a polyurethane coating.
The self-adhesive layer comprises a hot melt pressure sensitive adhesive according to any embodiment of the first aspect of the present application.
The main body waterproof material layer comprises at least one of polyethylene terephthalate, polyvinyl chloride, ethylene-vinyl acetate copolymer, ethylene copolymer modified asphalt resin, polyethylene, polypropylene and thermoplastic polyolefin.
According to the pre-paved waterproof roll material of the second aspect, the self-adhesive layer of the pre-paved waterproof roll material comprises the hot-melt pressure-sensitive adhesive according to any embodiment of the first aspect of the application, and the phenomena of aging and peeling strength reduction caused by ultraviolet irradiation of the self-adhesive layer of the pre-paved waterproof roll material are reduced. According to the pre-paved waterproofing membrane of the second aspect of the application, even under the irradiation of ultraviolet rays, the high peeling strength can be still maintained, and the pre-paved waterproofing membrane has excellent ultraviolet aging resistance.
In some embodiments, the main waterproof material layer may be a high density polyethylene layer, the surface anti-sticking protective layer may be a mullite layer, and the thickness of the self-sticking layer may be 0.15-0.5 mm.
Examples
The present disclosure is more particularly described in the following examples that are intended as illustrations only, since various modifications and changes within the scope of the present disclosure will be apparent to those skilled in the art. Unless otherwise indicated, all parts, percentages, and ratios reported in the following examples are on a weight basis, and all reagents used in the examples are commercially available or synthesized according to conventional methods and can be used directly without further treatment, and the equipment used in the examples is commercially available.
Example 1
The hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 60 parts of SEBS, 70 parts of KNH series naphthenic oil, 120 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 7701 parts of light stabilizer.
Adding the raw materials of the hot-melt pressure-sensitive adhesive into a reaction kettle, vacuumizing at 160 ℃, and stirring until the raw materials are uniformly mixed and are in a state without particles, thus obtaining the hot-melt pressure-sensitive adhesive.
And (3) blade-coating a self-adhesive layer on the high-density polyethylene waterproof material layer by using a hot-melt pressure-sensitive adhesive blade coating machine, wherein the thickness of the adhesive layer is 0.25-0.35 mm, spreading a layer of mullite sand of 30-60 meshes on the surface of the adhesive layer, and pressing and bonding by using a roller to obtain the pre-paved waterproof roll.
Example 2
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-butylene copolymer, 60 parts of hydrogenated styrene-butadiene rubber, 70 parts of KNH series naphthenic oil, 120 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-15772 parts of ultraviolet absorbent and 6221 parts of light stabilizer.
Example 3
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 15 parts of SEBS, 15 parts of SEPS, 65 parts of KNH series naphthenic oil, 120 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 6221 parts of light stabilizer.
Example 4
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-hexene copolymer, 60 parts of SEBS, 70 parts of conventional naphthenic oil, 120 parts of tackifying resin, 10101 parts of antioxidant, 1681 parts of antioxidant, UV-15771 parts of ultraviolet light absorber and 7701 parts of light stabilizer.
Example 5
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 50 parts of SEPS, 30 parts of KNH series naphthenic oil, 45 parts of conventional naphthenic oil, 100 parts of tackifying resin, 10101 parts of antioxidant, 17262 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 7701 parts of light stabilizer.
Example 6
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 80 parts of SEBS, 35 parts of KNH series naphthenic oil, 50 parts of tackifying resin, 17262 parts of antioxidant, 1681 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 6221 parts of light stabilizer.
Example 7
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-propylene-1-butene polymer, 15 parts of SEBS, 15 parts of SEPS, 65 parts of KNH series naphthenic oil, 120 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 6221 parts of light stabilizer.
Comparative example 1
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of SEBS, 35 parts of KNH serial naphthenic oil, 60 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 7701 parts of light stabilizer.
Comparative example 2
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 20 parts of SEBS, 35 parts of KNH series naphthenic oil, 60 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 7701 parts of light stabilizer.
Comparative example 3
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-propylene-1-butene polymer, 100 parts of SEBS, 100 parts of SEPS, 35 parts of KNH series naphthenic oil, 60 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant, UV-3262 parts of ultraviolet absorbent and 7701 parts of light stabilizer.
Comparative example 4
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 30 parts of SEBS, 35 parts of KNH series naphthenic oil, 60 parts of tackifying resin, 10101 parts of antioxidant, 1682 parts of antioxidant and 7701 parts of light stabilizer.
Comparative example 5
The process described in example 1 was repeated with the modifications that: the raw material formula of the hot-melt pressure-sensitive adhesive comprises the following components in parts by weight: 30 parts of ethylene-octene copolymer, 10 parts of SEBS (styrene-ethylene-butylene-styrene copolymer), 10 parts of SEPS (styrene-ethylene-styrene copolymer), 15 parts of KNH (polyethylene-vinyl-ketone) naphthenic oil, 30 parts of tackifying resin, 10101 parts of antioxidant and 6221 parts of light stabilizer.
Test section
The pre-laid waterproof rolls in the examples 1 to 7 and the pre-laid waterproof rolls in the comparative examples 1 to 5 were subjected to a physical mechanical property test, and the test results are shown in the following table 1:
table 1 performance test table for pre-laid waterproof rolls of examples 1 to 7 and comparative examples 1 to 5
Figure BDA0003173633970000121
TABLE 1 continuation
Figure BDA0003173633970000131
Comparing examples 1-7 with comparative examples 1-5, it can be seen that, after the olefin copolymer containing alpha-olefin is added to the hot-melt pressure-sensitive adhesive, compared with comparative example 1, the peel strength attenuation of the pre-paved waterproof roll prepared by using the hot-melt pressure-sensitive adhesives of examples 1-7 is significantly lower. Compared with comparative examples 2-5, the pressure-sensitive adhesive prepared by the raw material components of the hot-melt pressure-sensitive adhesive in the application can be applied to pre-paved waterproof coiled materials, so that the coiled materials have better ultraviolet aging resistance. In addition, the pre-paved waterproofing membrane in the embodiment using the ethylene-octene copolymer, KNH series naphthenic oil or the composite antioxidant and composite light stabilizer which are preferred in the application has particularly outstanding ultraviolet aging resistance.
The pre-paved waterproof roll is prepared by using the hot-melt pressure-sensitive adhesive of the olefin copolymer containing the alpha-olefin as the raw material, the unsaturated degree of the olefin copolymer containing the alpha-olefin is low, and photo-oxidative aging is not easy to occur due to irradiation of ultraviolet light, so that the photo-oxidative aging degree of the self-adhesive layer of the pre-paved waterproof roll is greatly reduced, and the phenomenon that the peeling strength is greatly reduced after the ultraviolet aging of the self-adhesive layer of the pre-paved waterproof roll is reduced.
According to the embodiment 1-7, the hot-melt pressure-sensitive adhesive and the pre-paved waterproof roll have excellent ultraviolet aging resistance. Particularly, the ethylene-octene copolymer, SEBS and/or SEPS and the highly hydrogenated KNH series naphthenic oil are adopted, so that the reduction of the peeling strength of the self-adhesive layer of the pre-paved waterproof roll after ultraviolet aging can be reduced to a greater extent.
While the invention has been described with reference to specific embodiments, the scope of the invention is not limited thereto, and those skilled in the art can easily conceive various equivalent modifications or substitutions within the technical scope of the invention. Therefore, the protection scope of the present application shall be subject to the protection scope of the claims.

Claims (10)

1. The hot-melt pressure-sensitive adhesive comprises the following raw material components in parts by weight:
Figure FDA0003173633960000011
2. the hot melt pressure sensitive adhesive according to claim 1, wherein the olefin copolymer comprising alpha-olefin is selected from at least one of an amorphous alpha-olefin copolymer and a polyolefin elastomer POE, preferably a polyolefin elastomer POE prepared with metallocene as a catalyst.
3. The hot-melt pressure-sensitive adhesive according to claim 2, wherein the polyolefin elastomer POE has a melt index of 10-40 g/min measured at 190 ℃ under a load of 2.16kg and a hole inner diameter of 2.1 mm;
and/or the amorphous alpha-olefin copolymer has a melt viscosity of 2000 to 100000mPa & s measured at 190 ℃, and the weight average molecular weight M of the amorphous alpha-olefin copolymerw40000-100000, and the number average molecular weight M of the amorphous alpha-olefin copolymernIs 5000 to 30000.
4. Hot-melt pressure-sensitive adhesive according to claim 2 or 3, wherein the polyolefin elastomer POE is an ethylene-octene copolymer, preferably an ethylene-octene copolymer prepared with metallocene as catalyst.
5. The hot melt pressure sensitive adhesive of claim 1, comprising the following raw material components by weight:
Figure FDA0003173633960000012
wherein the weight ratio of the olefin copolymer containing alpha-olefin to the hydrogenated synthetic rubber is preferably 1 (1-1.2).
6. The hot melt pressure sensitive adhesive according to claim 1, wherein the hydrogenated synthetic rubber is selected from at least one of a hydrogenated styrene thermoplastic elastomer (SEBS) or a hydrogenated styrene thermoplastic elastomer (SEPS), and preferably has a styrene content of 10 to 30 wt%.
7. The hot melt pressure sensitive adhesive according to claim 1 or 5, wherein the plasticizer is selected from at least one of paraffinic oil, aromatic oil, and naphthenic oil, preferably naphthenic oil;
and/or the tackifying resin is selected from at least one of C5 petroleum resin, C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin, C9 hot polymerized petroleum resin, C9 cold polymerized petroleum resin, rosin resin and terpene phenolic resin;
and/or, the compound antioxidant is selected from at least two of hindered phenol antioxidants and phosphite antioxidants;
and/or the composite light stabilizer is selected from at least two of benzotriazole light stabilizer, triazine light stabilizer and hindered amine light stabilizer.
8. The hot melt pressure sensitive adhesive according to claim 1 or 5, wherein the compound antioxidant is selected from at least two of antioxidant 1010, antioxidant 168, antioxidant 1076, antioxidant 1726, preferably a combination of at least one of antioxidant 1010, antioxidant 1076 or antioxidant 1726 and antioxidant 168;
and/or, the composite light stabilizer is selected from at least two of ultraviolet light absorber UV-326, ultraviolet light absorber UV-1577, light stabilizer 770 and light stabilizer 622, preferably the combination of at least one of ultraviolet light absorber UV-326 or ultraviolet light absorber UV-1577 and at least one of light stabilizer 770 and light stabilizer 622.
9. A pre-paved waterproof coiled material comprises a surface anti-sticking protective layer, a self-adhesive layer and a main body waterproof material layer, wherein,
the surface anti-sticking protective layer comprises at least one of isolation paint, reaction sand, quartz sand, silt and mullite sand, and the isolation paint is preferably at least one of acrylate paint and polyurethane paint;
the self-adhesive layer comprises the hot melt pressure sensitive adhesive according to any one of claims 1 to 8;
the main body waterproof material layer comprises at least one of polyethylene terephthalate, polyvinyl chloride, ethylene-vinyl acetate copolymer, ethylene copolymer modified asphalt resin, polyethylene, polypropylene and thermoplastic polyolefin.
10. The pre-paved waterproof roll as claimed in claim 9, wherein the main waterproof material layer is a high-density polyethylene layer, the surface anti-sticking layer is a mullite layer, and the thickness of the self-sticking layer is 0.15-0.5 mm.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115058220A (en) * 2022-07-15 2022-09-16 赤壁凯利隆科技有限公司 Hot-melt type ultralow-temperature pressure-sensitive adhesive and preparation method thereof
CN115505356A (en) * 2022-10-27 2022-12-23 广州市豪特粘接材料有限公司 Hot melt adhesive for air conditioner back plate and preparation method thereof
CN115627127A (en) * 2022-11-01 2023-01-20 河北宇阳泽丽防水材料有限公司 Self-adhesive high-molecular waterproof coiled material and preparation method thereof
CN115820158A (en) * 2022-12-14 2023-03-21 东莞澳中新材料科技股份有限公司 Adhesive for double-sided hot-melt adhesive tape and application thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100056682A1 (en) * 2008-09-02 2010-03-04 Lubrizol Advanced Materials, Inc. Soft Thermoplastic Elastomer Composition
CN102046739A (en) * 2008-03-31 2011-05-04 汉高股份两合公司 Hot melt adhesive
CN103214998A (en) * 2013-04-17 2013-07-24 岳阳东方雨虹防水技术有限责任公司 Preparation method of high-temperature resistant hot-melt pressure-sensitive adhesive
CN104640949A (en) * 2012-08-28 2015-05-20 汉高股份有限及两合公司 Hot melt adhesive
JP2015120825A (en) * 2013-12-24 2015-07-02 積水フーラー株式会社 Hot melt adhesive
CN106221629A (en) * 2016-08-15 2016-12-14 江苏凯伦建材股份有限公司 A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application
CN109735271A (en) * 2018-12-25 2019-05-10 上海邦中新材料有限公司 A kind of hot melt adhesive and its method based on SEBS
CN111040652A (en) * 2019-12-03 2020-04-21 江苏凯伦建材股份有限公司 High-molecular pre-laid waterproof coiled material

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102046739A (en) * 2008-03-31 2011-05-04 汉高股份两合公司 Hot melt adhesive
US20100056682A1 (en) * 2008-09-02 2010-03-04 Lubrizol Advanced Materials, Inc. Soft Thermoplastic Elastomer Composition
CN104640949A (en) * 2012-08-28 2015-05-20 汉高股份有限及两合公司 Hot melt adhesive
CN103214998A (en) * 2013-04-17 2013-07-24 岳阳东方雨虹防水技术有限责任公司 Preparation method of high-temperature resistant hot-melt pressure-sensitive adhesive
JP2015120825A (en) * 2013-12-24 2015-07-02 積水フーラー株式会社 Hot melt adhesive
CN106221629A (en) * 2016-08-15 2016-12-14 江苏凯伦建材股份有限公司 A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application
CN109735271A (en) * 2018-12-25 2019-05-10 上海邦中新材料有限公司 A kind of hot melt adhesive and its method based on SEBS
CN111040652A (en) * 2019-12-03 2020-04-21 江苏凯伦建材股份有限公司 High-molecular pre-laid waterproof coiled material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115058220A (en) * 2022-07-15 2022-09-16 赤壁凯利隆科技有限公司 Hot-melt type ultralow-temperature pressure-sensitive adhesive and preparation method thereof
CN115505356A (en) * 2022-10-27 2022-12-23 广州市豪特粘接材料有限公司 Hot melt adhesive for air conditioner back plate and preparation method thereof
CN115505356B (en) * 2022-10-27 2023-09-22 广州市豪特粘接材料有限公司 Hot melt adhesive for air conditioner backboard and preparation method thereof
CN115627127A (en) * 2022-11-01 2023-01-20 河北宇阳泽丽防水材料有限公司 Self-adhesive high-molecular waterproof coiled material and preparation method thereof
CN115627127B (en) * 2022-11-01 2024-02-20 河北宇阳泽丽防水材料有限公司 Self-adhesive high-molecular waterproof coiled material and preparation method thereof
CN115820158A (en) * 2022-12-14 2023-03-21 东莞澳中新材料科技股份有限公司 Adhesive for double-sided hot-melt adhesive tape and application thereof

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