CN113416385A - Sports flying disc made of composite material and preparation method thereof - Google Patents

Sports flying disc made of composite material and preparation method thereof Download PDF

Info

Publication number
CN113416385A
CN113416385A CN202110834875.1A CN202110834875A CN113416385A CN 113416385 A CN113416385 A CN 113416385A CN 202110834875 A CN202110834875 A CN 202110834875A CN 113416385 A CN113416385 A CN 113416385A
Authority
CN
China
Prior art keywords
flying disc
polymethyl methacrylate
composite material
chopped carbon
disc made
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110834875.1A
Other languages
Chinese (zh)
Inventor
刘向
徐维
樊帆
吴汉冲
金浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangmen Carbon Cloud Technology Co ltd
Original Assignee
Jiangmen Carbon Cloud Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangmen Carbon Cloud Technology Co ltd filed Critical Jiangmen Carbon Cloud Technology Co ltd
Priority to CN202110834875.1A priority Critical patent/CN113416385A/en
Publication of CN113416385A publication Critical patent/CN113416385A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63HTOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H33/00Other toys
    • A63H33/18Throwing or slinging toys, e.g. flying disc toys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/12Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • B29C70/443Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding and impregnating by vacuum or injection
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2201/00Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as reinforcement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2233/00Use of polymers of unsaturated acids or derivatives thereof, as reinforcement
    • B29K2233/04Polymers of esters
    • B29K2233/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2263/00Use of EP, i.e. epoxy resins or derivatives thereof as reinforcement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/52Sports equipment ; Games; Articles for amusement; Toys
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length

Abstract

The invention relates to a sports flying disc made of composite materials and a preparation method thereof, wherein the raw materials for preparing the sports flying disc comprise, by weight, 10-25 parts of chopped carbon fibers, 1-7 parts of polymethyl methacrylate powder, 10-70 parts of epoxy resin and 10-50 parts of curing agent. The sports flying disc has the advantages of high and low temperature resistance, difficult fracture and strong bending resistance.

Description

Sports flying disc made of composite material and preparation method thereof
Technical Field
The invention relates to leisure and entertainment equipment, in particular to a sports flying disc made of composite materials and a preparation method thereof.
Background
The flying disc sport is a simple outdoor sport item which is suitable for both the old and the young; in the flying disc movement, the material of the moving flying disc is a key factor influencing the flying disc movement effect; at present, most of sports flying discs at home and abroad are made of polypropylene (PP) materials, although the sports flying discs made of the PP materials have the advantages of light weight, good toughness and good chemical resistance, the sports flying discs have the defects of poor low-temperature resistance and the like, when the environmental temperature is low, the impact resistance of the sports flying discs is reduced, and particularly in autumn and winter in the north, the existing sports flying discs often cause crack damage to disc bodies and even integral fracture due to low temperature.
Accordingly, further improvements to existing sports flying discs are needed.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provides a sports flying disc made of composite materials and a preparation method thereof.
The purpose of the invention is realized as follows:
a sports flying disc made of composite materials is prepared from 10-25 parts by weight of chopped carbon fibers, 1-7 parts by weight of polymethyl methacrylate powder, 10-70 parts by weight of epoxy resin and 10-50 parts by weight of curing agent.
The mass ratio of the chopped carbon fibers to the polymethyl methacrylate to the epoxy resin to the curing agent is 20: 1: 40: 20, or 15: 5: 32: 13, or 25: 1: 45: 30, or 20: 1: 10: 10, or 20: 1: 70: 50.
the length of the chopped carbon fiber is 1.0-12.0 mm.
The particle diameter of the polymethyl methacrylate powder is 5-10 μm.
The mass ratio of the polymethyl methacrylate powder to the chopped carbon fibers is (1: 3-1): 25.
a method for preparing a sports flying disc made of composite material comprises the following steps,
s1, shearing the unidirectional carbon fiber tows: shearing the unidirectional carbon fiber tows to the required length through shearing equipment to prepare chopped carbon fibers for later use;
s2, adding polymethyl methacrylate powder: adding polymethyl methacrylate powder into the chopped carbon fiber prepared in the step S1 according to a proper mass ratio to prepare a mixed material of the chopped carbon fiber and the polymethyl methacrylate powder;
s3, adding an epoxy resin adhesive and a curing agent: mixing epoxy resin glue and a curing agent according to a proper mass ratio, adding the mixture into S2 to obtain a mixed material, and fully stirring to obtain carbon fiber mixed slurry;
s4, feeding to a forming die: coating a release agent on the forming die, and putting the carbon fiber mixed slurry prepared in the step S3 into the forming die;
s5, filling into a vacuum bag: placing the forming mould into a vacuum bag for vacuum pumping treatment;
s6, heating and curing: curing and heating are carried out while the vacuum bag is vacuumized, the heating temperature is 100-120 ℃, and the heating time is 6-10 hours;
s7, demolding treatment: and (4) demolding the semi-finished moving flying disc prepared in the step (S6), and performing surface treatment to prepare the moving flying disc.
In S3, the mass ratio of the mixed liquid of the epoxy resin and the curing agent to the chopped carbon fibers is 1: 1-6: 1.
in S4, the release agent is an organic paraffin-based release agent.
In S5, the vacuum pump for vacuum pumping is a mechanical pump, and the vacuum pumping degree is greater than or equal to 10 Pa.
The forming die is a stainless steel die or an aluminum alloy die, wherein the melting point of the aluminum alloy die is not lower than 600 ℃.
The invention has the following beneficial effects:
the moving flying disc is made of main body materials such as chopped carbon fibers, polymethyl methacrylate (PMMA) powder, epoxy resin and the like; the chopped carbon fibers and the epoxy resin can enable the motion frisbee to have the advantages of high and low temperature resistance, strong impact resistance, corrosion resistance, difficult fracture and the like; and the density of the flying disc can be adjusted by adjusting the proportion of the chopped carbon fibers, the epoxy resin and the curing agent according to actual needs, so that a proper density range is obtained. In addition, the prepared sports flying disc has the advantages of good elasticity, strong bending resistance and the like by doping polymethyl methacrylate (PMMA) powder in a certain proportion in the chopped carbon fibers, so that the elasticity of the sports flying disc can be increased, and the hand feeling of the sports flying disc in motion is improved.
Detailed Description
The present invention will be further described with reference to the following examples.
The invention relates to a sports flying disc, which comprises the following raw materials, by weight, 10-25 parts of chopped carbon fibers, 1-7 parts of polymethyl methacrylate powder, 10-70 parts of epoxy resin and 10-50 parts of a curing agent.
First embodiment
In the sports flying disc according to this embodiment, the mass ratio of the chopped carbon fibers, the polymethyl methacrylate, the epoxy resin, and the curing agent is 20: 1: 40: 20, namely 20 parts of chopped carbon fibers, 1 part of polymethyl methacrylate powder, 40 parts of epoxy resin and 20 parts of curing agent.
Further, the chopped carbon fibers have a length of 1.0 to 12.0 mm.
Further, the particle diameter of the polymethyl methacrylate powder is 5 μm to 10 μm.
Further, the mass ratio of the polymethyl methacrylate powder to the chopped carbon fibers was 1: 20.
The preparation method of the sports flying disc related to the embodiment comprises the following steps,
s1, shearing the unidirectional carbon fiber tows: shearing the unidirectional carbon fiber tows to the required length through shearing equipment to prepare chopped carbon fibers for later use;
s2, adding polymethyl methacrylate powder: adding polymethyl methacrylate powder into the chopped carbon fiber prepared in the step S1 according to a proper mass ratio to prepare a mixed material of the chopped carbon fiber and the polymethyl methacrylate powder;
s3, adding an epoxy resin adhesive and a curing agent: mixing epoxy resin glue and a curing agent according to a proper mass ratio, adding the mixture into S2 to obtain a mixed material, and fully stirring to obtain carbon fiber mixed slurry;
s4, feeding to a forming die: coating a layer of release agent on the inner surface of a forming die, and putting the carbon fiber mixed slurry prepared in the step S3 into the forming die;
s5, filling into a vacuum bag: putting the forming mould into a vacuum bag, then inserting the vacuum bag, sealing the vacuum bag with vacuum mud, and then vacuumizing;
s6, heating and curing: curing and heating are carried out while the vacuum bag is vacuumized through a vacuum tube connected with a vacuum pump, the heating temperature is 100-120 ℃, the heating time is 6-10 hours, and curing and heating are carried out until the chopped carbon fibers on the surface of the carbon fiber mixed slurry are completely cured, so as to prepare a semi-finished product of the flying disc;
s7, demolding treatment: and (5) demolding the semi-finished moving flying disc prepared in the step (S6), carrying out surface treatment such as grinding and polishing on the surface of the semi-finished moving flying disc, and finally smearing a layer of carbon fiber surface adhesive on the surface to prepare the moving flying disc.
Further, in S3, the mass ratio of the mixed liquid of the epoxy resin and the curing agent to the chopped carbon fibers is 1: 1-6: 1, the ratio of 3:1 is preferred in the present embodiment.
Further, in S4, the release agent is an organic paraffin-based release agent.
Further, in S5, the vacuum pump for evacuation is a mechanical pump, and the degree of evacuation is greater than or equal to 10 Pa.
Further, the forming die is an aluminum alloy die (or a stainless steel die), and the melting point of the aluminum alloy die is not lower than 600 ℃.
Second embodiment
In the sports flying disc according to this embodiment, the mass ratio of the chopped carbon fibers, the polymethyl methacrylate, the epoxy resin, and the curing agent is 15: 5: 32: 13, namely 15 parts of chopped carbon fiber, 5 parts of polymethyl methacrylate powder, 40 parts of epoxy resin and 20 parts of curing agent. Wherein the mass ratio of the polymethyl methacrylate powder to the chopped carbon fibers is 1: 3.
Other parts not described above are the same as those of the first embodiment, and are not explained in detail here.
Third embodiment
In the sports flying disc according to this embodiment, the mass ratio of the chopped carbon fibers, the polymethyl methacrylate, the epoxy resin, and the curing agent is 25: 1: 45: 30, namely 15 parts of chopped carbon fibers, 5 parts of polymethyl methacrylate powder, 40 parts of epoxy resin and 20 parts of curing agent. Wherein the mass ratio of the polymethyl methacrylate powder to the chopped carbon fibers is 1: 25.
Other parts not described above are the same as those of the first embodiment, and are not explained in detail here.
Fourth embodiment
In the sports flying disc according to this embodiment, the mass ratio of the chopped carbon fibers, the polymethyl methacrylate, the epoxy resin, and the curing agent is 20: 1: 10: the epoxy resin composition comprises, by weight, 15 parts of chopped carbon fibers, 5 parts of polymethyl methacrylate powder, 40 parts of epoxy resin and 20 parts of a curing agent. Wherein the mass ratio of the mixed liquid of the epoxy resin and the curing agent to the short carbon fiber is 1: 1.
other parts not described above are the same as those of the first embodiment, and are not explained in detail here.
Fifth embodiment
In the sports flying disc according to this embodiment, the mass ratio of the chopped carbon fibers, the polymethyl methacrylate, the epoxy resin, and the curing agent is 20: 1: 70: 50, namely 15 parts of chopped carbon fiber, 5 parts of polymethyl methacrylate powder, 40 parts of epoxy resin and 20 parts of curing agent. Wherein the mass ratio of the mixed liquid of the epoxy resin and the curing agent to the chopped carbon fibers is 6: 1.
other parts not described above are the same as those of the first embodiment, and are not explained in detail here.
The foregoing is a preferred embodiment of the present invention, and the basic principles, principal features and advantages of the invention are shown and described. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are intended to illustrate the principles of the invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, and the invention is intended to be protected by the following claims. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (10)

1. A sports flying disc made of composite material, characterized by: the preparation raw materials comprise, by weight, 10-25 parts of chopped carbon fibers, 1-7 parts of polymethyl methacrylate powder, 10-70 parts of epoxy resin and 10-50 parts of a curing agent.
2. The flying disc made of composite material according to claim 1, wherein: the mass ratio of the chopped carbon fibers to the polymethyl methacrylate to the epoxy resin to the curing agent is 20: 1: 40: 20, or 15: 5: 32: 13, or 25: 1: 45: 30, or 20: 1: 10: 10, or 20: 1: 70: 50.
3. the flying disc made of composite material according to claim 1, wherein: the length of the chopped carbon fiber is 1.0-12.0 mm.
4. The flying disc made of composite material according to claim 1, wherein: the particle diameter of the polymethyl methacrylate powder is 5-10 μm.
5. The flying disc made of composite material according to claim 1, wherein: the mass ratio of the polymethyl methacrylate powder to the chopped carbon fibers is (1: 3-1): 25.
6. a method for preparing a sports flying disc made of composite materials is characterized by comprising the following steps: comprises the following steps of (a) carrying out,
s1, shearing the unidirectional carbon fiber tows: shearing the unidirectional carbon fiber tows to the required length through shearing equipment to prepare chopped carbon fibers for later use;
s2, adding polymethyl methacrylate powder: adding polymethyl methacrylate powder into the chopped carbon fiber prepared in the step S1 according to a proper mass ratio to prepare a mixed material of the chopped carbon fiber and the polymethyl methacrylate powder;
s3, adding an epoxy resin adhesive and a curing agent: mixing epoxy resin glue and a curing agent according to a proper mass ratio, adding the mixture into S2 to obtain a mixed material, and fully stirring to obtain carbon fiber mixed slurry;
s4, feeding to a forming die: coating a release agent on the forming die, and putting the carbon fiber mixed slurry prepared in the step S3 into the forming die;
s5, filling into a vacuum bag: placing the forming mould into a vacuum bag for vacuum pumping treatment;
s6, heating and curing: curing and heating are carried out while the vacuum bag is vacuumized, the heating temperature is 100-120 ℃, and the heating time is 6-10 hours;
s7, demolding treatment: and (4) demolding the semi-finished moving flying disc prepared in the step (S6), and performing surface treatment to prepare the moving flying disc.
7. A method of making a sports flying disc made of composite material as claimed in claim 6, wherein: in S3, the mass ratio of the mixed liquid of the epoxy resin and the curing agent to the chopped carbon fibers is 1: 1-6: 1.
8. a method of making a sports flying disc made of composite material as claimed in claim 6, wherein: in S4, the release agent is an organic paraffin-based release agent.
9. A method of making a sports flying disc made of composite material as claimed in claim 6, wherein: in S5, the vacuum pump for vacuum pumping is a mechanical pump, and the vacuum pumping degree is greater than or equal to 10 Pa.
10. A method of making a sports flying disc made of composite material as claimed in claim 6, wherein: the forming die is a stainless steel die or an aluminum alloy die, wherein the melting point of the aluminum alloy die is not lower than 600 ℃.
CN202110834875.1A 2021-07-23 2021-07-23 Sports flying disc made of composite material and preparation method thereof Pending CN113416385A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110834875.1A CN113416385A (en) 2021-07-23 2021-07-23 Sports flying disc made of composite material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110834875.1A CN113416385A (en) 2021-07-23 2021-07-23 Sports flying disc made of composite material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN113416385A true CN113416385A (en) 2021-09-21

Family

ID=77718233

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110834875.1A Pending CN113416385A (en) 2021-07-23 2021-07-23 Sports flying disc made of composite material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN113416385A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111361180A (en) * 2020-02-14 2020-07-03 大连交通大学 Carbon fiber fine structure component and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111361180A (en) * 2020-02-14 2020-07-03 大连交通大学 Carbon fiber fine structure component and preparation method thereof

Similar Documents

Publication Publication Date Title
CN103146147B (en) A kind of epoxy resin toughened/glass fibre prepreg and preparation method
CN102146196B (en) Preparation method of high damping epoxy resin composite
CN101544851A (en) Metallic bond hollow sphere-shaped super-hard compound material and manufacturing method thereof
CN106349650A (en) Epoxy resin composition, preparing method, preparing method of prepreg and preparing method of composite
CN103289313B (en) A kind of preparation method improveing glass-reinforced plastic material
WO1995012633A1 (en) Thermoplastic syntactic foams and their preparation
CN103254566B (en) A kind of impact-resistant glass-reinforced plastic material
CN105542219A (en) Preparation method for light high-strength composite hollow sphere
CN103074020A (en) Room-temperature cured, low-viscosity and low temperature-resistant adhesive
CN103980668A (en) Preparation method of carbon nano-tube/amorphous carbon/epoxy resin composite material
CN107033543A (en) A kind of low-temperature setting high-fire resistance energy resin combination and preparation method
WO2004067615A3 (en) Epoxy resin compositions, methods of preparing, and articles made therefrom
CN113416510B (en) Epoxy resin pouring sealant and preparation method thereof
CN113416385A (en) Sports flying disc made of composite material and preparation method thereof
CN113480832A (en) 180 ℃ vacuum infusion epoxy resin-based composite material with TG of 170-
CN104130575B (en) One has high-dimensional stability resin compound and preparation method thereof
KR20200076505A (en) Mhethod for manufacturing of carbon fiber reinforced plastic
CN105542471A (en) Release-type high-energy adhesive product and preparation method thereof
CN107573482A (en) A kind of polyurethane buoyant material and preparation method thereof
CN103289314B (en) A kind of improvement glass-reinforced plastic material
CN116694030A (en) Ultra-light high-strength composite material and preparation method and application thereof
CN107541016B (en) A kind of preparation method of biomass modified epoxy resin
CN106883559A (en) A kind of preparation method of high rigidity carbon fibre composite resin matrix
CN104045975B (en) Preparation method of particle reinforced and toughened resin based fibrous composite material
CN113999484A (en) Light-weight high-strength high-impact-resistance high-modulus nano modified epoxy resin composition for wind power blade main beam and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210921

RJ01 Rejection of invention patent application after publication