CN113400758A - Physical foaming lightweight sheet and preparation method thereof - Google Patents

Physical foaming lightweight sheet and preparation method thereof Download PDF

Info

Publication number
CN113400758A
CN113400758A CN202110834197.9A CN202110834197A CN113400758A CN 113400758 A CN113400758 A CN 113400758A CN 202110834197 A CN202110834197 A CN 202110834197A CN 113400758 A CN113400758 A CN 113400758A
Authority
CN
China
Prior art keywords
melt
foaming agent
air outlet
sheet
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110834197.9A
Other languages
Chinese (zh)
Inventor
陈志强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Useon Nanjing Extrusion Machinery Co ltd
Original Assignee
Useon Nanjing Extrusion Machinery Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Useon Nanjing Extrusion Machinery Co ltd filed Critical Useon Nanjing Extrusion Machinery Co ltd
Priority to CN202110834197.9A priority Critical patent/CN113400758A/en
Publication of CN113400758A publication Critical patent/CN113400758A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/22Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • B29C44/24Making multilayered articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122Hydrogen, oxygen, CO2, nitrogen or noble gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/002Panels; Plates; Sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0264Polyester
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/042Nanopores, i.e. the average diameter being smaller than 0,1 micrometer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/044Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon

Abstract

The application relates to a physical foaming lightweight sheet and a preparation method thereof, wherein the sheet comprises a sheet, the sheet comprises a middle layer and side layers, the side layers are positioned on two sides of the middle layer, and a plurality of micro bubbles are arranged in the middle layer; the preparation method comprises the following steps: s1: melting raw materials: melting the material of the middle layer; melting the side layer material S2; after the intermediate melt is plasticized, injecting a physical foaming agent into the intermediate melt to obtain a melt containing the foaming agent; s3: molding: and (3) introducing the side melt and the melt containing the foaming agent into a forming die, so that the side melt is positioned on two sides of the melt containing the foaming agent, and then demolding to obtain the lightweight sheet. The application can effectively reduce the weight of the sheet and facilitate the subsequent processing and use of the sheet.

Description

Physical foaming lightweight sheet and preparation method thereof
Technical Field
The application relates to the field of plastic products, in particular to a physically foamed lightweight sheet and a preparation method thereof.
Background
Blister is a common processing technology of plastics and is widely applied to the manufacture of packaging materials of electronics, electrical appliance industry, food industry, cosmetic industry, stationery and the like. The main principle of plastic uptake is that after a flat plastic hard sheet is heated to be soft, the plastic hard sheet is adsorbed on the surface of a mould in vacuum, and after cooling, the plastic hard sheet is molded to obtain a corresponding plastic product.
The blister packaging product mainly comprises a blister shell, a tray, a blister box and the like, and the blister packaging not only has the advantages of saving raw and auxiliary materials, light weight, convenient transportation and sealing performance, but also meets the requirement of environment-friendly green packaging.
With respect to the related art in the above, the inventors consider that: the processing of the sheet in the blister process is usually integrated, which results in a heavy sheet, which is not favorable for the subsequent processing and use of the sheet.
Disclosure of Invention
In order to reduce the weight of the sheet, the application provides a physically foamed lightweight sheet and a preparation method thereof.
In a first aspect, the present application provides a physically foamed lightweight sheet, which adopts the following technical scheme:
the utility model provides a physics foaming lightweight sheet, includes intermediate level and avris layer, the avris layer is located the intermediate level both sides, be provided with a plurality of microbubbles in the intermediate level.
Through adopting above-mentioned technical scheme, the intermediate level is because the existence of microbubble to can reduce the density in intermediate level, thereby can reduce the holistic density of sheet, alleviate the weight of sheet, the setting on limit side layer simultaneously for the avris of sheet belongs to the entity, thereby can reduce the influence to sheet mechanical properties that arouses because the setting of microbubble, thereby this application can obtain a lightweight sheet.
Optionally, the pore size of the microbubbles is from 0.05 to 400 microns.
By adopting the technical scheme, the aperture of the micro-bubbles is controlled in a proper range, the requirement of reducing the weight of the sheet is met, and meanwhile, the influence on the mechanical property of the sheet is further reduced.
Optionally, the foaming magnification of the sheet is 1.05-5.
By adopting the technical scheme, the foaming ratio refers to the ratio of the volume of the micro bubbles to the volume of the sheet material without the micro bubbles, and the foaming ratio is controlled in a proper range, so that the influence on the mechanical property of the sheet material caused by the existence of the micro pores is reduced.
Optionally, the sheet has a cell density of 105-1016Pieces/cm 3.
By adopting the technical scheme, the tear strength of the sheet material can be influenced by the density of the cells, and the density of the cells is controlled within a proper range, so that the mechanical property of the sheet material can be relatively improved.
Optionally, the ratio of the thickness of the middle layer to the total thickness of the two side layers is 1-100.
By adopting the technical scheme and the proper thickness ratio, the middle layer meets the requirement on the weight reduction effect of the sheet, and the side layer meets the requirement on maintaining the mechanical property of the sheet.
In a second aspect, the present application provides a method for preparing a physically foamed lightweight sheet, which adopts the following technical scheme: a preparation method of a physical foaming lightweight sheet comprises the following steps:
s1: melting raw materials:
melting of the material of the intermediate layer: heating and melting the intermediate layer material, and adding a pore nucleating agent into the melted intermediate layer material to obtain an intermediate melt;
melting of the side edge layer material: heating and melting the material of the side edge layer to obtain a side edge melt;
s2: physical blowing agent injection
After the intermediate melt is plasticized, injecting a physical foaming agent into the intermediate melt to obtain a melt containing the foaming agent;
s3: shaping of
And (3) introducing the side melt and the melt containing the foaming agent into a forming die to enable the side melt to be positioned at two sides of the melt containing the foaming agent, then demolding, and expanding and foaming the melt containing the foaming agent to obtain the lightweight sheet.
By adopting the technical scheme, the microbubbles in the middle layer can be refined by adding the pore nucleating agent; after the middle melt is plasticized, injecting a physical foaming agent into the middle melt, so that the physical foaming agent is uniformly distributed in the middle melt, finally introducing the side melt and the melt containing the foaming agent into a forming die, so that the side melt and the melt containing the foaming agent are fused, meanwhile, the side melt seals two sides of the melt containing the foaming agent, and when the side melt is discharged from the die, the melt containing the foaming agent is recovered to normal pressure, and the physical foaming agent foams under the action of high temperature.
Optionally, in step S2, the pressure of the physical foaming agent is 2 to 20 MPa.
By adopting the technical scheme, proper pressure is selected, and the physical foaming agent is uniformly distributed in the intermediate melt while the conveying of the intermediate melt is not influenced.
Optionally, the physical foaming agent is one or more of nitrogen, carbon dioxide and C3-C6 alkane.
By adopting the technical scheme, the proper physical foaming agent is selected, so that the interlayer material can be well foamed.
Optionally, the raw material of the sheet is one or more of PET, PLA, PS, ABS, and PP.
By adopting the technical scheme, the PET (polyethylene terephthalate) has good physical and mechanical properties, and has good creep resistance, fatigue resistance, friction resistance and dimensional stability; PLA is biodegradable plastic polylactic acid, has good processing performance and good thermal stability; PS is polystyrene, and has the properties of good electrical insulation property, easy coloring, good processing fluidity, good rigidity and the like; ABS refers to acrylonitrile-butadiene-styrene copolymer, and is a thermoplastic high polymer material structure with high strength, good toughness and easy processing and molding; PP (polypropylene) as a thermoplastic material also has excellent mechanical properties; the sheet prepared by the material has good processing performance and service performance.
Optionally, in step S2, the physical foaming agent is pumped into the intermediate melt through an air pumping device, and an air outlet end of the air pumping device is connected to an extruder for melting the raw material; the inflating device comprises an air storage tank, an air supply pipe, an air collecting hood, an air outlet pipe and a synchronous opening and closing piece, wherein the air supply pipe is connected with the air storage tank, an air pump is arranged on the air supply pipe, the air collecting hood is arranged on the outer peripheral wall of the extruder charging barrel, a separating ring plate is arranged in the air collecting hood, the ring inner wall of the separating ring plate is opposite to the outer peripheral wall of the extruder charging barrel, the separating ring plate divides the air collecting hood into a containing ring cavity close to the extruder charging barrel and an air collecting ring cavity positioned at one side of the containing ring cavity far away from the extruder charging barrel, and the air supply pipe is communicated with the air collecting ring cavity; the air inlet end of the air outlet pipe is uniformly distributed on the separating ring plate, the air outlet end of the air outlet pipe extends into the material cylinder of the extruder, the air outlet pipe is communicated with the air collecting ring cavity, and a sealing plate is rotatably arranged on the inner side wall of the air inlet end of the air outlet pipe through a rotating shaft;
the synchronous opening and closing piece comprises a positioning torsion spring, a positioning support block, a linkage gear and a synchronous gear ring, the positioning torsion spring is arranged between a rotating shaft and an outlet pipe side wall, the positioning support block is arranged on one side, away from an outlet pipe air outlet end, of the outlet pipe inner side wall, the positioning support block is tightly supported with a sealing plate, the sealing plate seals the outlet pipe, the rotating shaft extends out of a gas collecting hood, the linkage gear is arranged in one-to-one correspondence with the rotating shaft, the linkage gear is arranged at one end, extending out of the gas collecting hood, of the rotating shaft, the synchronous gear ring is arranged on the outer peripheral wall of a material cylinder of the extruder in a rotating mode, and the linkage gear is meshed with the synchronous gear ring.
By adopting the technical scheme, the physical foaming agent enters the gas-collecting hood in advance, so that the gas-collecting hood is filled with the physical foaming agent, and after the pressure in the gas-collecting hood reaches the specified value, the positioning torsion spring is overcome to promote the rotating shaft to drive the closing plate to rotate; and due to the meshing action of the synchronous gear ring and the linkage gear, all the rotating shafts drive the corresponding closing plates to synchronously rotate, all the air outlet pipes are synchronously opened, so that the physical foaming agent is simultaneously and uniformly injected into different positions of the material barrel of the extruder, and the physical foaming agent is uniformly distributed in the intermediate melt.
In summary, the present application includes at least one of the following beneficial technical effects:
1. the arrangement of the micro bubbles can reduce the density of the middle layer, so that the overall density of the sheet can be reduced, the weight of the sheet is reduced, the cost is reduced, and the sheet has the characteristics of environmental protection;
2. the side layers of the solid body are arranged on the two sides of the middle layer at the same time when the micro bubbles are arranged on the middle layer, so that the foamed middle layer is enhanced, the influence of the micro bubbles on the mechanical property of the sheet material is further reduced, and the application range of the product can be expanded;
3. the sheet material has good buffering and heat-insulating properties due to the arrangement of the middle layer with the micro bubbles, and can be used in the fields of automobile sound insulation, building refrigeration house heat insulation and the like;
4. the application provides a preparation method of a lightweight sheet material, the lightweight sheet material can be conveniently obtained, and the diameter of microbubbles is 0.05-400 microns, preferably 0.05-300 microns, more preferably 0.05-20 microns, and most preferably 0.05-0.07 microns;
drawings
Fig. 1 is a schematic view of a sheet structure in example 1 of the present application.
Fig. 2 is a schematic view of the structure of the pump-up device in embodiment 1 of the present application.
Fig. 3 is a plan view of the structure of the air pump in embodiment 1 of the present application.
Fig. 4 is a sectional view taken along line a-a of fig. 3.
Fig. 5 is an enlarged view B in fig. 4.
Fig. 6 is a sectional view taken along line C-C of fig. 3.
Fig. 7 is an enlarged view at D in fig. 6.
Description of reference numerals: 11. an intermediate layer; 12. an edge side layer; 2. microbubbles; 3. an air pump device; 31. a gas storage tank; 32. a gas supply pipe; 321. an air pump; 33. a gas-collecting hood; 331. a separating ring plate; 332. an accommodating ring cavity; 333. a gas collecting ring cavity; 34. an air outlet pipe; 341. a fixed tube; 3411. a guide chute; 3412. a connecting rod; 342. a movable tube; 3421. a guide slider; 3422. a limiting spring; 343. a rotating shaft; 344. a closing plate; 35. synchronously opening and closing the parts; 351. positioning a torsion spring; 352. positioning a resisting block; 353. a linkage gear; 354. a synchronizing ring gear; 4. a charging barrel; 5. a stressed block; 6. a bearing ring.
Detailed Description
The present application is described in further detail below with reference to figures 1-7.
The embodiment of the application discloses light sheet of physics foaming.
Example 1
As shown in fig. 1, a physically foamed lightweight sheet, the material of the sheet is polyethylene terephthalate, the sheet includes a middle layer 11 and side layers 12, the side layers 12 are located on two sides of the middle layer 11, in this embodiment, the thickness of the middle layer 11 is 1 mm, the thickness of each of the two side layers is 0.143 mm, and the ratio of the thickness of the middle layer 11 to the total thickness of the two side layers 12 is 3.5. Meanwhile, a plurality of closed micro bubbles 2 are arranged in the middle layer 11, the aperture of each micro bubble 2 is 0.05-0.07 micron, the foaming ratio of the sheet is 1.05, and the cell density is 1016Pieces/cm 3.
The embodiment 1 of the application also discloses an inflating device.
As shown in fig. 2 and 3, the inflation device 3 in the present embodiment is used in combination with an extruder, the inflation device 3 includes an air tank 31, an air supply pipe 32 and an air collecting hood 33, the air supply pipe of the air supply pipe 32 is communicated with the air outlet end of the air tank 31, and an air pump 321 is installed on the air supply pipe 32; the gas collecting hood 33 is a ring-shaped hood, and the gas collecting hood 33 is covered on the outer peripheral wall of the barrel 4 of the extruder, and the ring inner side end wall of the gas collecting hood 33 is fixedly connected with the outer peripheral wall of the barrel 4 of the extruder.
As shown in fig. 4 and 5, a separating ring plate 331 is further integrally connected between the axially opposite inner side walls of the gas collecting hood 33, so that the inner wall of the separating ring plate 331 is opposite to the outer peripheral wall of the extruder barrel 4, meanwhile, the separating ring plate 331 separates the gas collecting hood 33 into two chambers, namely, an accommodating ring cavity 332 and a gas collecting ring cavity 333, the accommodating ring cavity 332 is close to the extruder barrel 4, the gas collecting ring cavity 333 is located at the side of the accommodating ring cavity 332 away from the extruder barrel 4, and the gas outlet end of the gas supply pipe 32 is communicated with the gas collecting ring cavity 333; the inflating device 3 further comprises six air outlet pipes 34 and synchronous opening and closing members 35, air inlet ends of the six air outlet pipes 34 are uniformly distributed on the separating annular plate 331 along the circumferential direction of the separating annular plate 331, and the air inlet end of the air outlet pipe 34 is communicated with the air collecting annular cavity 333.
As shown in fig. 5 and 7, the air outlet end of the air outlet pipe 34 extends into the barrel 4 of the extruder, a rotating shaft 343 is rotatably disposed on the inner side wall of the air inlet end of the air outlet pipe 34, and a closing plate 344 is fixedly connected to the rotating shaft 343. Initially, the closing plate 344 closes the gas outlet pipe 34, and only when the physical foaming agent is gathered in the gas collecting ring cavity 333, the pressure in the gas collecting ring cavity 333 reaches a specified magnitude, the synchronous opening and closing member 35 drives all the closing plates 344 to synchronously rotate, so that the gas outlet pipe 34 is synchronously opened, and thus the physical foaming agent can be uniformly pumped into each position in the basic material cylinder 4 under the action of the air pump 321.
As shown in fig. 5 and 7, the synchronous opening and closing member 35 includes a positioning torsion spring 351, a positioning abutting block 352, a linkage gear 353 and a synchronous gear ring 354, the positioning torsion spring 351 is fixedly connected between the rotating shaft 343 and the side wall of the air outlet pipe 34, the positioning abutting block 352 is fixedly connected to the side of the inner side wall of the air outlet pipe 34 far away from the air outlet end of the air outlet pipe 34, when the positioning torsion spring 351 is in a natural state, the positioning abutting block 352 abuts against the closing plate 344, and the closing plate 344 closes the air outlet pipe 34; in this embodiment, the same side ends of the six rotating shafts 343 extend out of the gas collecting hood 33, the linkage gears 353 are arranged in one-to-one correspondence with the rotating shafts 343, the linkage gears 353 are fixedly connected to the end of the rotating shafts 343 extending out of the gas collecting hood 33, the synchronizing gear ring 354 is rotatably arranged on the outer peripheral wall of the barrel 4 of the extruder, and the linkage gears 353 are all meshed with the outer peripheral wall of the synchronizing gear ring 354. Therefore, when the pressure in the gas collecting ring cavity 333 reaches a specified value, the elasticity of the positioning torsion spring 351 can be overcome, and all the sealing plates 344 rotate synchronously due to the meshing of the synchronous gear ring 354 and the linkage gear 353, so that the six gas outlet pipes 34 can be opened synchronously.
As shown in fig. 5 and 6, in the present embodiment, each air outlet pipe 34 includes a fixed pipe 341 and a movable pipe 342, the fixed pipe 341 communicates with the partition ring plate 331, a guide sliding groove 3411 is axially disposed on an inner peripheral wall of the fixed pipe 341, the movable pipe 342 penetrates through the fixed pipe 341, an outer peripheral wall of the movable pipe 342 is sealed by fitting with the inner peripheral wall of the fixed pipe 341, a guide slider 3421 is integrally connected to the outer peripheral wall of the movable pipe 342, and the guide slider 3421 is slidably connected to a groove wall of the guide sliding groove 3411 along the axial direction of the fixed pipe 341; and a limit spring 3422 is fixedly connected between the side walls of the guide sliding block 3421 and the guide sliding groove 3411 close to the partition ring plate 331.
As shown in fig. 5 and 7, the inner wall of the fixed tube 341 is provided with a connecting rod 3412, the connecting rod 3412 is integrally connected with a force-bearing blocking block 5, the inner peripheral wall of the movable tube 342 is provided with a bearing ring 6, the inner diameter of the bearing ring 6 is gradually reduced along the direction away from the separating ring plate 331, the force-bearing blocking block 5 is a conical block, and when the limiting spring 3422 is in a natural state, the force-bearing blocking block 5 is inserted on the inner wall of the bearing ring 6 and is attached to the inner wall of the bearing ring 6; while the side of the movable tube 342 that protrudes beyond the fixed tube 341 protrudes into the barrel 4 of the extruder.
As shown in fig. 5 and 7, after the physical foaming agent enters the fixed pipe 341, as the pressure in the fixed pipe 341 increases, the pressure of the limiting spring 3422 is overcome, the movable pipe 342 moves away from the partition ring plate 331, the force-bearing block 5 is separated from the support ring 6, the physical foaming agent enters the movable pipe 342 through the gap between the force-bearing block 5 and the support ring 6, and simultaneously, as the pressure in the fixed pipe 341 is released, the movable pipe 342 is pulled back to the original position by the limiting spring 3422, so that the movable pipe 342 slides back and forth in the fixed pipe 341, and the air outlet end of the movable pipe 342 moves in the barrel 4 of the extruder along the axial direction, so that the physical foaming agent can be injected into the barrel 4 of the extruder more uniformly.
The operating principle of the inflating device in embodiment 1 of the application is as follows: when the air pump 321 is started, the physical foaming agent in the air storage tank 31 enters the air collecting hood 33 through the air supply pipe 32, after the pressure in the air collecting hood 33 reaches a certain value, the closing plate 344 synchronously rotates under the meshing action of the synchronous gear ring 354 and the linkage gear 353, the physical foaming agent enters the fixed pipe 341, the movable pipe 342 is promoted to slide, and the physical foaming agent is pumped into the material cylinder 4 of the extruder through the movable pipe 342.
The application embodiment 1 also discloses a preparation method of the physical foaming lightweight sheet.
A preparation method of a physical foaming lightweight sheet comprises the following steps:
the sheet material in the examples of the present application was polyethylene terephthalate, wherein the polyethylene terephthalate was obtained from Kadaler plastics materials Co., Ltd, Dongguan, having a product number of 530.
S1: melting raw materials:
melting the material of the intermediate layer 11: adding the material of the middle layer 11 into a double-screw extruder, heating and melting at 260-280 ℃, and then adding a pore nucleating agent into the screw extruder, wherein the pore nucleating agent in the embodiment is graphite powder to obtain a middle melt;
melting the material of the side layer 12: adding the material of the side layer 12 into a single-screw extruder, and heating and melting at 260-280 ℃ to obtain a side melt;
s2: physical blowing agent injection
After the intermediate melt is plasticized, starting an inflating device 3, controlling the inflating pressure of a physical foaming agent to be 20MPa, injecting the physical foaming agent into the intermediate melt, wherein the physical foaming agent is carbon dioxide in the embodiment, and finally obtaining the melt containing the foaming agent, wherein the mass ratio of the physical foaming agent to the total amount of the sheet raw materials is 5%;
s3: shaping of
And (2) introducing the side melt and the melt containing the foaming agent into a forming die by using a melt distributor, so that the side melt is positioned on two sides of the melt containing the foaming agent, then demolding, recovering the normal pressure of the melt containing the foaming agent during demolding, and foaming the physical foaming agent under the action of high temperature to obtain the lightweight sheet.
Examples 2 to 11
Examples 2 to 11 differ from example 1 in the expansion ratio of the sheet, the diameter of cells 2 and the cell density of the sheet, as shown in the following table.
TABLE 1
Figure BDA0003172235870000071
Examples 12 to 15
Examples 12-15 differ from example 1 in that: the ratio of the thickness of the middle layer 11 to the total thickness of the two side layers 12 is different, as shown in the following table.
Figure BDA0003172235870000072
Comparative examples 1 to 2
Comparative examples 1-2 differ from example 1 in the foaming ratio of the sheet and the diameter of cells 2, as specified in the following table:
TABLE 3
Figure BDA0003172235870000081
Comparative example 3 differs from example 1 in that comparative example 3 does not contain microbubbles and therefore does not contain a step of injecting a material blowing agent.
And (3) performance detection:
the tear strengths of examples 1-10 and comparative examples 1-7 were tested and the results are shown in the following table.
TABLE 4
Figure BDA0003172235870000082
Figure BDA0003172235870000091
According to the detection results of the examples 1-3 and the comparative example 3, the sheet material provided by the invention can reduce the weight of the sheet material and simultaneously enable the sheet material to still have good mechanical properties by arranging proper micro bubbles, wherein the sheet material of the example 1 has the best performance.
As can be seen from examples 4-8, when the cell density is changed, the corresponding diameter of the micro-bubbles is also changed, and the magnitude of the cell density affects the tear strength of the sheet material, and the tear strength of the sheet material is better as the cell density is larger. Meanwhile, as can be seen from the test results of comparative examples 1 and 2, if the cell density and cell diameter are not well controlled, even if the weight of the sheet is reduced, the mechanical properties of the sheet are deteriorated, which affects the use of the sheet.
From the results of the tests of examples 9 to 11, it is understood that the influence of the expansion ratio on the sheet properties is not large, and the combination of examples 4 to 8 shows that the size of the cell density and the size of the cell diameter influence each other.
From the results of the tests of example 1 and examples 12 to 15, it is understood that the ratio of the thickness of the intermediate layer 11 to the total thickness of the both side layers 12 has a certain influence on the tear strength of the sheet, wherein the ratio of the thickness of the intermediate layer 11 to the total thickness of the both side layers 12 of example 1 is the optimum value.
The present application thus reduces the weight of the sheet material by providing suitable microbubbles while maintaining the mechanical properties of the sheet material constant or substantially constant. Moreover, the sheet material is light in weight, so that the transportation cost and the use cost of the sheet material are reduced, and the economic and environmental benefits are greater.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.

Claims (10)

1. A physically foamed lightweight sheet characterized in that: including intermediate level (11) and limit side layer (12), limit side layer (12) are located intermediate level (11) both sides, be provided with a plurality of microbubble (2) in intermediate level (11).
2. The lightweight sheet according to claim 1, wherein: the pore size of the micro-bubbles (2) is 0.05-400 microns.
3. The physically foamed lightweight sheet according to claim 1, wherein: the foaming magnification of the sheet is 1.05-5.
4. The physically foamed lightweight sheet according to claim 1, wherein: the sheet had a cell density of 105-1016Per cm3
5. The physically foamed lightweight sheet according to claim 1, wherein: the ratio of the thickness of the middle layer (11) to the total thickness of the two side layers (12) is 1-100.
6. A method of making a physically foamed lightweight sheet according to any of claims 1 to 5, characterized in that: the method comprises the following steps:
s1: melting raw materials:
melting the material of the intermediate layer (11): heating and melting the material of the middle layer (11), and adding a pore nucleating agent into the melted material of the middle layer (11) to obtain a middle melt;
melting the material of the side layer (12): heating and melting the material of the side layer (12) to obtain a side melt;
s2: physical blowing agent injection
After the intermediate melt is plasticized, injecting a physical foaming agent into the intermediate melt to obtain a melt containing the foaming agent;
s3: shaping of
And (3) introducing the side melt and the melt containing the foaming agent into a forming die, so that the side melt is positioned on two sides of the melt containing the foaming agent, and then demolding to obtain the lightweight sheet.
7. The method for preparing a physically foamed lightweight sheet according to claim 6, wherein: in the step S2, the pressure of the physical foaming agent is 2-20 MPa.
8. The method for preparing a physically foamed lightweight sheet according to claim 6, wherein: the physical foaming agent is one or more of nitrogen, carbon dioxide and C3-C6 alkane.
9. The method for preparing a physically foamed lightweight sheet according to claim 6, wherein: the raw material of the sheet is one or more of PET, PLA, PS, ABS and PP.
10. The method for preparing a physically foamed lightweight sheet according to claim 6, wherein: in the step S2, the physical foaming agent is pumped into the intermediate melt through an air pumping device (3), and the air outlet end of the air pumping device (3) is connected with an extruder for melting raw materials; the inflating device (3) comprises a gas storage tank (31), a gas supply pipe (32), a gas collecting hood (33), a gas outlet pipe (34) and a synchronous opening and closing piece (35), the gas supply pipe (32) is connected with the gas storage tank (31), a gas pump (321) is arranged on the gas supply pipe (32), the gas collecting hood (33) is arranged on the peripheral wall of the extruder charging barrel (4), a separating ring plate (331) is arranged in the gas collecting hood (33), the inner wall of the separating ring plate (331) is opposite to the peripheral wall of the extruder charging barrel (4), the separating ring plate (331) separates the gas collecting hood (33) into an accommodating ring cavity (332) close to the extruder charging barrel (4) and a gas collecting ring cavity (333) located at one side, far away from the extruder charging barrel (4), of the accommodating ring cavity (332), and the gas supply pipe (32) is communicated with the gas collecting ring cavity (333); the air inlet ends of the air outlet pipes (34) are uniformly distributed on the separating ring plate (331), the air outlet ends of the air outlet pipes (34) extend into a charging barrel (4) of the extruder, the air outlet pipes (34) are communicated with the air collecting ring cavity (333), and the inner side wall of the air inlet ends of the air outlet pipes (34) is rotatably provided with a sealing plate (344) through a rotating shaft (343);
the synchronous opening and closing piece (35) comprises a positioning torsion spring (351), a positioning abutting block (352), a linkage gear (353) and a synchronous gear ring (354), the positioning torsion spring (351) is arranged between the rotating shaft (343) and the side wall of the air outlet pipe (34), the positioning resisting block (352) is arranged on one side of the inner side wall of the air outlet pipe (34) far away from the air outlet end of the air outlet pipe (34), the positioning abutting block (352) abuts against the closing plate (344), the closing plate (344) closes the air outlet pipe (34), the rotating shaft (343) extends out of the gas collecting hood (33), the linkage gears (353) are arranged corresponding to the rotating shaft (343) one by one, the linkage gear (353) is arranged at one end of the rotating shaft (343) extending out of the gas-collecting hood (33), the synchronous gear ring (354) is rotationally arranged on the outer peripheral wall of the charging barrel (4) of the extruder, and the linkage gears (353) are all meshed with the synchronous gear ring (354).
CN202110834197.9A 2021-07-21 2021-07-21 Physical foaming lightweight sheet and preparation method thereof Pending CN113400758A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110834197.9A CN113400758A (en) 2021-07-21 2021-07-21 Physical foaming lightweight sheet and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110834197.9A CN113400758A (en) 2021-07-21 2021-07-21 Physical foaming lightweight sheet and preparation method thereof

Publications (1)

Publication Number Publication Date
CN113400758A true CN113400758A (en) 2021-09-17

Family

ID=77687423

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110834197.9A Pending CN113400758A (en) 2021-07-21 2021-07-21 Physical foaming lightweight sheet and preparation method thereof

Country Status (1)

Country Link
CN (1) CN113400758A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207415754U (en) * 2017-09-21 2018-05-29 深圳市欧丽塑胶原材料有限公司 A kind of double screw extruder
CN108621358A (en) * 2018-06-19 2018-10-09 华南理工大学 A kind of differential gas injection structures and methods
CN113056372A (en) * 2018-12-05 2021-06-29 金孝植 Multilayer-structure polylactic resin foamed sheet prepared by co-extrusion foaming method, molded article, method for producing same, and apparatus for producing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN207415754U (en) * 2017-09-21 2018-05-29 深圳市欧丽塑胶原材料有限公司 A kind of double screw extruder
CN108621358A (en) * 2018-06-19 2018-10-09 华南理工大学 A kind of differential gas injection structures and methods
CN113056372A (en) * 2018-12-05 2021-06-29 金孝植 Multilayer-structure polylactic resin foamed sheet prepared by co-extrusion foaming method, molded article, method for producing same, and apparatus for producing same

Similar Documents

Publication Publication Date Title
US4136220A (en) Process for the molding of plastic structural web and the resulting articles
US4247515A (en) Process for molding of plastic structural web articles
EP2318208B1 (en) Multilayer thermoplastic sheet materials and thermoformed articles prepared therefrom
CN102070841B (en) Polypropylene foam sheet prepared from composite foaming agent and production method thereof
CN102080912B (en) Integrally molded refrigerator door and manufacturing method thereof
CN101077603B (en) Method for preparing foamed plastic products
JPH10128795A (en) Molded piece
CN104401076A (en) HDPE(high-density polyethylene) membrane composited by high foaming of LDPE(Low-Density Polyethylene) and preparation method of HDPE membrane
WO2016053987A2 (en) Multi-layer thermoformed polymeric foam articles and methods
CN103085219A (en) Microporous foamed rubber-plastic heat insulation product and preparation method thereof
WO2001036521A2 (en) Thermoformed polyolefin foams and methods of their production
US11773232B2 (en) Thermoformed polymeric foam articles and methods
WO1999055513A1 (en) Method and system for forming low-density polymer foam article
CN107471530A (en) The twice-die-opening device and method being molded for chemical blowing and in-mold decoration composite injection molding
CN113400758A (en) Physical foaming lightweight sheet and preparation method thereof
CN110142911A (en) The injection molding apparatus and technique of a kind of polymer micro foamed material and its application
EP1332030B1 (en) Method for the production of biodegradable foamed products
US11034814B2 (en) Core material for fiber reinforced composite and fiber reinforced composite having the same
CN107932828B (en) A kind of pressure fluid auxiliary foam injection molding technique
Pop-Iliev et al. Single-step rotational foam molding of skin-surrounded polyethylene foams
CN110815699A (en) Micro-foaming injection molding process
US20190030769A1 (en) Method for producing a climate control box
CN216941544U (en) Foaming mold with controllable mold cavity space
JP2003039512A (en) Thermoplastic resin foamed molded object
JP2001269960A (en) Method for manufacturing in-mold foam molding made from aromatic polyester-based resin

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210917

RJ01 Rejection of invention patent application after publication