Disclosure of Invention
Therefore, the invention provides a detergent for gasoline vehicles, a preparation device and a preparation method thereof,
the technical scheme of the invention is realized as follows:
a detergent preparation device for a gasoline vehicle comprises an automatic batching and quantitative conveying control console, and a feeding system, a filtering system, a reaction system, a blending system and a pumping system which are respectively and electrically connected with the control console;
the control console comprises a meter, a pumping switch, a preheating control end, a reaction control end and a standing control end which are arranged on the control console, and the meter, the pumping switch, the preheating control end, the reaction control end and the standing control end are connected through the control console;
the feeding system comprises an auxiliary material tank and a preheater connected with the auxiliary material tank;
the filtration system comprises a primary filter, a fine filter and a base mixing tank;
the reaction system comprises a reaction kettle and an explosion-proof stirrer connected with the reaction kettle;
the blending system comprises a blending tank;
the pumping system comprises a pump and a pumping pipeline;
the auxiliary material jar passes through pumping system and is connected with primary filter, primary filter passes through pumping system and is connected with reation kettle, reation kettle passes through pumping system and is connected with the fine filter, the fine filter passes through pumping system and is connected with basic blending tank, basic blending tank passes through pumping system and is connected with the allotment jar.
The further technical scheme is that the preheating control end comprises a preheating setting end, a preheating switch and a preheating indicator lamp, wherein the preheating switch and the preheating indicator lamp are respectively connected with the preheating setting end; the reaction control end comprises a reaction stirring setting end and a reaction completion indicator light connected with the reaction stirring setting end; the standing control end comprises a standing setting end and a standing indicator lamp connected with the standing setting end.
The preparation method of the detergent for the gasoline car of the detergent preparation device for the gasoline car sequentially comprises the following steps of:
(1) preparing material supply: setting the proportion of basic auxiliary materials and blending materials on a meter of an automatic blending quantitative conveying control platform, and setting preheating temperature, primary filtering time, the rotating speed of a stirrer, reaction time of a reaction kettle and standing time of a basic tank;
respectively putting the basic auxiliary materials into the auxiliary material tank and the blending materials into the blending tank according to the proportion, and ensuring that the basic auxiliary materials and the blending materials are homogeneous, have no impurities and are all in a liquid state in the period; then the preheating switch is turned on, and the OP-10 is preheated until the preheating indicator lamp is turned on to indicate that the preheating is finished; the OP-10 preheating is that the OP-10 auxiliary material is in an emulsified state and is in a liquid state through preheating;
(2) primary filtering and mixing: starting a pumping switch, and pumping the basic auxiliary materials to a primary filter according to the proportion for primary filtering and mixing; the primary filtration functions in two ways: firstly, impurities in the auxiliary materials are filtered, and secondly, the auxiliary materials are subjected to preliminary mixing reaction, the key point of the step is the filtering time, so that the auxiliary materials are not only preliminarily mixed fully, but also unnecessary mixing time is prevented from being wasted, and the production period is prolonged;
(3) reaction stirring: after the primary filtering time is up, pumping the basic auxiliary materials mixed by primary filtering into a reaction kettle by a pumping system for reaction and stirring until an indicator lamp is on after the reaction is finished;
(4) fine filtering and standing: after the reaction and stirring are finished, pumping the basic auxiliary materials subjected to the reaction and stirring into a fine filter by a pumping system for secondary filtration, and pumping into a basic mixing tank for standing; so as to ensure that no impurities exist in the basic auxiliary materials, the cleanliness of a finished product is favorably controlled, and the risk of abrasion of an engine cylinder body is reduced;
(5) auxiliary material blending: and pumping the basic auxiliary materials after standing into a blending tank with the added blending materials by a pumping system, and mixing to prepare the finished product of the detergent for the gasoline car.
The further technical scheme is that the preheating temperature is 45-50 ℃. The OP-10 has slow or no liquefaction speed below the temperature, and the OP-10 is easy to gasify and lose above the temperature.
The further technical proposal is that the primary filtration time is 1.5-2.5 min.
The further technical scheme is that the standing time of the basic tank is 2-4 h.
The further technical proposal is that the reaction time of the reaction kettle is 12-20min, and the rotating speed of the stirrer is 1600 plus 1800 rpm. When the rotating speed is lower than the rotating speed and the reaction time of the reaction kettle, molecular chains are not opened, various chemical molecules cannot be fully fused, and when the rotating speed is higher than the rotating speed and the reaction time of the reaction kettle, the molecular chains are scattered too much, and the effect of a finished product cannot reach the best effect.
The detergent for the gasoline vehicle prepared by the preparation method comprises basic auxiliary materials and blending materials, wherein the basic auxiliary materials comprise isopropyl ether, tert-butyl alcohol, n-octane, xylene, n-decanol, OP-10 (polyoxyethylene octyl phenol ether-10) and 2-6 di-tert-butyl p-cresol, the blending materials comprise methanol and a smoke suppressor, and the smoke suppressor comprises isopropyl nitrate, ammonium perchlorate and polyether polyurethane.
The further technical scheme is that the base auxiliary materials comprise the following components in parts by weight: 15-25 parts of isopropyl ether, 5-15 parts of tert-butyl alcohol, 15-25 parts of n-octane, 5-10 parts of xylene, 30-40 parts of n-decanol, 1-5 parts of 2-6 di-tert-butyl-p-cresol and OP-102-8 parts of tert-butyl-p-cresol; the basic auxiliary materials and the blending materials are in the following weight ratio: 8.5-13.8 parts of basic auxiliary materials, 86-91.2 parts of methanol and 0.1-0.3 part of smoke suppressor.
The further technical scheme is that the smoke suppressor comprises the following components in parts by weight: isopropyl nitrate, ammonium perchlorate, polyether urethane 1:1: 1.
Compared with the prior art, the invention has the beneficial effects that:
1. the detergent for the gasoline vehicle comprises the following components:
(1) emission reduction: the detergent for the gasoline vehicle is added with the smoke suppressor, so that the emission is further reduced, on the basis of pure gasoline, the emission of carbon monoxide is reduced by 4.6%, the oxynitride is reduced by 50%, and the comprehensive carbon emission is reduced by 27.3%;
(2) and (3) low proportion: compared with the American national fortunes and gasoline which are mixed according to the proportion of 1/150, the detergent for the gasoline car is mixed with the gasoline according to the proportion of 1/500 for use, and the effect is more obvious after the detergent is used for a short time; thus, the specific component proportion of the detergent for the gasoline vehicle improves the efficiency of the detergent;
(3) the cost is low: if the alcohol is priced according to 100 ml/bottle 98 yuan, the effect is superior to the American vigour; the detergent for the gasoline vehicle has small usage amount, better effect and low cost;
(4) power increasing: oxygen is increased and combustion is supported, power is improved, and the effect is quicker and more obvious;
(5) corrosion prevention: the detergent for the gasoline vehicle has an anti-corrosion effect, and can protect internal components of the vehicle from being damaged.
(6) Carbon deposit removal: the detergent for the gasoline vehicle has no residue after physical ignition, and proves that the detergent does not generate new carbon deposit, contains effective substances for cleaning the carbon deposit in a full oil way, can clean the carbon deposit in the vehicle and enables an engine to be recovered as new.
2. The detergent preparation device for the gasoline vehicle is a semi-automatic preparation device, realizes automatic control of the preparation device through an automatic batching and quantitative conveying control console, comprises starting and monitoring of the whole system, further ensures accurate control of each preparation step, and improves production efficiency.
3. The preparation method of the detergent for the gasoline vehicle, disclosed by the invention, has the advantages that the whole preparation process is carried out at normal temperature and normal pressure, and pollutant discharge is not generated; and OP-10 preheating and temperature control, primary filtration and filtration time control, reaction stirring rotation speed and time control, fine filtration standing and other preparation steps ensure the maximum efficiency of the preparation method, thereby reducing the production cost, shortening the production period and improving the productivity.
Detailed Description
For a better understanding of the technical content of the present invention, a specific embodiment is provided below, and the present invention is further described with reference to the accompanying drawings.
Referring to fig. 1-2, the detergent preparation device for gasoline vehicles of the present invention comprises an automatic dosing and quantitative conveying console 2, and a feeding system, a filtering system, a reaction system, a blending system and a pumping system 10 electrically connected to the console respectively;
the console 2 comprises a meter 201, a pumping switch 202, a preheating control end 203, a reaction control end 204 and a standing control end 205 which are arranged on the console, and the meter 201, the pumping switch 202, the preheating control end 203, the reaction control end 204 and the standing control end 205 are connected through the console 2;
the feeding system comprises an auxiliary material tank 1 and a preheater 3 connected with the auxiliary material tank 1;
the filtration system comprises a primary filter 4, a fine filter 5 and a base mixing tank 8;
the reaction system comprises a reaction kettle 7 and an explosion-proof stirrer 6 connected with the reaction kettle 7;
the blending system comprises a blending tank 9;
the pumping system 10 includes a pump and pumping tubing;
the auxiliary material jar passes through pumping system and is connected with primary filter, primary filter passes through pumping system and is connected with reation kettle, reation kettle passes through pumping system and is connected with the fine filter, the fine filter passes through pumping system and is connected with basic blending tank, basic blending tank passes through pumping system and is connected with the allotment jar.
The preheating control end comprises a preheating setting end, a preheating switch and a preheating indicator lamp, wherein the preheating switch and the preheating indicator lamp are respectively connected with the preheating setting end; the reaction control end comprises a reaction stirring setting end and a reaction completion indicator light connected with the reaction stirring setting end; the standing control end comprises a standing setting end and a standing indicator lamp connected with the standing setting end.
The detergent for gasoline cars was prepared according to the above detergent preparation apparatus for gasoline cars, in a specific method example 1-3.
Example 1
The preparation method of the detergent for the gasoline vehicle sequentially comprises the following steps of:
(1) preparing material supply: the proportioning of the basic auxiliary materials and the blending materials is set on a meter 201 of an automatic blending quantitative conveying control platform 2, and the preheating temperature, the primary filtering time, the rotating speed of a stirrer, the reaction time of a reaction kettle and the standing time of a basic tank are set;
respectively putting basic auxiliary materials into the auxiliary material tank 1 and the blending materials into the blending tank 9 according to the proportion, then opening a preheating switch, and preheating the OP-10 at the preheating temperature of 45 ℃ until a preheating indicator lamp is turned on to indicate that the preheating is finished;
(2) primary filtering and mixing: starting a pumping switch 202, pumping the basic auxiliary materials to a primary filter 4 according to the proportion for primary filtering and mixing, wherein the primary filtering time is 1.5 min;
(3) reaction stirring: after the primary filtering time is up, pumping the basic auxiliary materials mixed by primary filtering into a reaction kettle 7 by a pumping system 10 for reaction and stirring, wherein the reaction time of the reaction kettle 7 is 12min, and the rotating speed of the stirrer 6 is 1600 rpm until a reaction completion indicator lamp is on;
(4) fine filtering and standing: after the reaction and stirring are finished, pumping the basic auxiliary materials subjected to the reaction and stirring into a fine filter 5 by a pumping system 10 for secondary filtration, pumping into a basic mixing tank 8 for standing, wherein the standing time of the basic mixing tank 8 is 2 hours;
(5) auxiliary material blending: and pumping the basic auxiliary materials after standing into a blending tank 9 into which the blending materials are put by a pumping system 10, and mixing to prepare the finished product of the detergent for the gasoline car.
Example 2
The preparation method of the detergent for the gasoline vehicle sequentially comprises the following steps of:
(1) preparing material supply: the proportioning of the basic auxiliary materials and the blending materials is set on a meter 201 of an automatic blending quantitative conveying control platform 2, and the preheating temperature, the primary filtering time, the rotating speed of a stirrer, the reaction time of a reaction kettle and the standing time of a basic tank are set;
respectively putting basic auxiliary materials into the auxiliary material tank 1 and the blending materials into the blending tank 9 according to the proportion, then opening a preheating switch, and preheating the OP-10 at the preheating temperature of 48 ℃ until a preheating indicator lamp is turned on to indicate that the preheating is finished;
(2) primary filtering and mixing: starting a pumping switch 202, pumping the basic auxiliary materials to a primary filter 4 according to the proportion for primary filtering and mixing, wherein the primary filtering time is 2 min;
(3) reaction stirring: after the primary filtering time is up, pumping the basic auxiliary materials mixed by primary filtering into a reaction kettle 7 by a pumping system 10 for reaction and stirring, wherein the reaction time of the reaction kettle 7 is 18min, and the rotating speed of the stirrer 6 is 1700 rpm until a reaction completion indicator lamp is on;
(4) fine filtering and standing: after the reaction and stirring are finished, pumping the basic auxiliary materials subjected to the reaction and stirring into a fine filter 5 by a pumping system 10 for secondary filtration, pumping into a basic mixing tank 8 for standing, wherein the standing time of the basic mixing tank 8 is 3 hours;
(5) auxiliary material blending: and pumping the basic auxiliary materials after standing into a blending tank 9 into which the blending materials are put by a pumping system 10, and mixing to prepare the finished product of the detergent for the gasoline car.
Example 3
The preparation method of the detergent for the gasoline vehicle sequentially comprises the following steps of:
(1) preparing material supply: the proportioning of the basic auxiliary materials and the blending materials is set on a meter 201 of an automatic blending quantitative conveying control platform 2, and the preheating temperature, the primary filtering time, the rotating speed of a stirrer, the reaction time of a reaction kettle and the standing time of a basic tank are set;
respectively putting basic auxiliary materials into the auxiliary material tank 1 and the blending materials into the blending tank 9 according to the proportion, then opening a preheating switch, and preheating the OP-10 at the preheating temperature of 50 ℃ until a preheating indicator lamp is turned on to indicate that the preheating is finished;
(2) primary filtering and mixing: starting a pumping switch, pumping the basic auxiliary materials to a primary filter according to the proportion for primary filtering and mixing, wherein the primary filtering time is 2.5 min;
(3) reaction stirring: after the primary filtering time is up, pumping the basic auxiliary materials mixed by primary filtering into a reaction kettle 7 by a pumping system 10 for reaction and stirring, wherein the reaction time of the reaction kettle 7 is 20min, and the rotating speed of the stirrer 6 is 1800 rpm until a reaction completion indicator lamp is on;
(4) fine filtering and standing: after the reaction and stirring are finished, pumping the basic auxiliary materials subjected to the reaction and stirring into a fine filter 5 by a pumping system 10 for secondary filtration, pumping into a basic mixing tank 8 for standing, wherein the standing time of the basic mixing tank 8 is 4 hours;
(5) auxiliary material blending: and pumping the basic auxiliary materials after standing into a blending tank 9 into which the blending materials are put by a pumping system 10, and mixing to prepare the finished product of the detergent for the gasoline car.
The following examples 4-6 are the raw material formulations of the detergents for gasoline vehicles according to the present invention.
Example 4
The detergent for the gasoline vehicle comprises basic auxiliary materials and blending materials, wherein the basic auxiliary materials comprise isopropyl ether, tert-butyl alcohol, n-octane, xylene, n-decanol, OP-10 and 2-6 di-tert-butyl-p-cresol, the blending materials comprise methanol and a smoke suppressor, and the smoke suppressor comprises isopropyl nitrate, ammonium perchlorate and polyether polyurethane.
The weight ratio of the basic auxiliary materials is as follows: 15 parts of isopropyl ether, 5 parts of tert-butyl alcohol, 15 parts of n-octane, 5 parts of xylene, 30 parts of n-decanol, 102 parts of OP-102 parts and 1 part of 2-6 di-tert-butyl-p-cresol; the basic auxiliary materials and the blending materials are in the following weight ratio: 8.5 parts of basic auxiliary materials, 86 parts of methanol and 0.1 part of smoke suppressor.
The smoke suppressor comprises the following components in parts by weight: isopropyl nitrate, ammonium perchlorate, polyether urethane 1:1: 1.
Example 5
The detergent for the gasoline vehicle comprises basic auxiliary materials and blending materials, wherein the basic auxiliary materials comprise isopropyl ether, tert-butyl alcohol, n-octane, xylene, n-decanol, OP-10 and 2-6 di-tert-butyl-p-cresol, the blending materials comprise methanol and a smoke suppressor, and the smoke suppressor comprises isopropyl nitrate, ammonium perchlorate and polyether polyurethane.
The weight ratio of the basic auxiliary materials is as follows: 20 parts of isopropyl ether, 10 parts of tert-butyl alcohol, 20 parts of n-octane, 8 parts of xylene, 34 parts of n-decanol, 105 parts of OP-105 parts and 3 parts of 2-6-di-tert-butyl-p-cresol; the basic auxiliary materials and the blending materials are in the following weight ratio: 10 parts of basic auxiliary materials, 89.8 parts of methanol and 0.2 part of smoke suppressor.
The smoke suppressor comprises the following components in parts by weight: isopropyl nitrate, ammonium perchlorate, polyether urethane 1:1: 1.
Example 6
The detergent for the gasoline vehicle comprises basic auxiliary materials and blending materials, wherein the basic auxiliary materials comprise isopropyl ether, tert-butyl alcohol, n-octane, xylene, n-decanol, OP-10 and 2-6 di-tert-butyl-p-cresol, the blending materials comprise methanol and a smoke suppressor, and the smoke suppressor comprises isopropyl nitrate, ammonium perchlorate and polyether polyurethane.
The weight ratio of the basic auxiliary materials is as follows: 25 parts of isopropyl ether, 15 parts of tertiary butanol, 25 parts of n-octane, 10 parts of xylene, 40 parts of n-decanol, 108 parts of OP-108 parts and 5 parts of 2-6 di-tert-butyl-p-cresol; the basic auxiliary materials and the blending materials are in the following weight ratio: 13.8 parts of basic auxiliary materials, 91.2 parts of methanol and 0.3 part of smoke suppressor.
The smoke suppressor comprises the following components in parts by weight: isopropyl nitrate, ammonium perchlorate, polyether urethane 1:1: 1.
Comparative example 1
Compared with the embodiment 5, the weight ratio of the smoke suppressor to the ammonium perchlorate is 1:1, and the rest is the same as the embodiment 5.
Exhaust pollutant detection
The American Libitong, foreign name (LIBITU) is a manufacturer of globally known automobile coatings and special chemicals, has the research and development, production and market promotion experiences of automobile professional chemicals for more than 60 years, the Libitong series products cover various fields of engineering machinery, spaceflight, automobiles, ships and the like, the products are specified or recommended by famous automobile companies such as general companies, Daimler-Klisler companies, the public and the like, and the excellent product performance is highly praised by various automobile manufacturers and after-sale markets. The American LibiTuo C66 is a high-end product in the market at present, is produced by LibiTuo combined chemical company, and currently implements the enterprise standard Q/SZLX 329.
The pure gasoline in tables 1-2 is the Dandong Jindong gasoline station No. 92 non-national standard gasoline.
Vehicle emissions detection
The detergent for gasoline vehicles (hereinafter referred to as the detergent) prepared by the preparation methods of the detergent for gasoline vehicles described in the embodiments 2 and 5 is applied to a gasoline engine using 12 years, samples (the american lipsoto smokeless carbon detergent C66 and the detergent) are mixed with gasoline, and detection is performed according to GB18285-2018 "pollutant emission limit and measurement method for gasoline vehicles", and the change condition of each index measured value of the vehicle in the tail gas detection process by using a simple transient condition method is shown in table 1.
And (3) testing vehicle information: vehicle brand: respectively, vehicle model: SGM7205ATA, date of birth: 2009-04-15, engine type: LTD, engine displacement: 2.0/L.
Environmental parameters: ambient temperature: 15.2 ℃ mean, atmospheric pressure: 96.8kPa, relative humidity: 22.5% mean.
TABLE 1
And (3) detection results: when the engine exhaust pollutants used for 12 years are subjected to online detection after half an hour under the mixed state of different samples and gasoline, various emission indexes are obviously improved, and the specific result is as follows: (1) emission reduction: on the basis of pure gasoline, the detergent reduces the carbon monoxide emission by 4.6%, reduces the oxynitride by 50%, and reduces the comprehensive carbon emission by 27.3%; (2) and (3) low proportion: compared with the American national fortunes and gasoline which are mixed according to the proportion of 1/150, the detergent for the gasoline car is mixed with the gasoline according to the proportion of 1/500 for use, and the effect is more obvious after the detergent is used for a short time; thus, the specific component proportion of the detergent for the gasoline vehicle improves the efficiency of the detergent; (3) the cost is low: the detergent for the gasoline car has the advantages of small using amount, better effect and low cost.
Second, laboratory discharge detection
The detergent for gasoline car (hereinafter referred to as the present detergent) sample, the comparative sample (american lipsotop carbolic detergent C66) prepared by the detergent preparation method for gasoline car described in example 2 and example 5, and the detergent for gasoline car (hereinafter referred to as the comparative detergent) prepared by the detergent preparation method for gasoline car described in example 2 and comparative example 1 were subjected to laboratory emission tests, and two samples were mixed with gasoline # 92 at a ratio of 1: 500, mixing, and observing the residual carbon deposit in the crucible and the amount of water surface flotage in the bomb tube (namely the amount of the carbon deposit) after the unit fuel is combusted in the instrument; after ignition in the crucible, flame, smell and residue were observed. The results are shown in Table 2.
TABLE 2
As can be seen from Table 2, after the combustion in the closed environment of the instrument, the carbon deposition amount of the detergent is lower than that of American Triton carbon C66 and is also lower than that of a comparative detergent, which shows that the smoke suppressor component proportion in the detergent, particularly the addition of polyether polyurethane, has obvious smoke suppression effect, and the smoke discharged by an automobile is generally reflected by the carbon deposition amount. The carbon deposit is removed, the vehicle engine is not abraded, and the carbon hydrogen, carbon monoxide and nitrogen oxide detected in the automobile exhaust emission are less.
By open environment ignition, the detergent is cleaner, more environment-friendly and harmless than American national force absolute carbon C66 in the aspects of flame, smell and residues. The detergent has higher combustion temperature and higher power of an engine (with high octane number) proved by blue flame; the detergent is completely burnt out without residue and carbon deposition, so that the detergent is environment-friendly, fully combusted, high in internal oxygen content and free of new carbon deposition after combustion; in a word, the detergent has more remarkable advantages on improving the automobile exhaust emission, the sufficiency of fuel combustion and the effect of cleaning carbon deposit, and has the functions of increasing oxygen, supporting combustion and improving power; the economy is higher, and the wide application is recommended.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.