CN113354053A - Ammonia-oxygen mixed feeding system and working method thereof - Google Patents

Ammonia-oxygen mixed feeding system and working method thereof Download PDF

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Publication number
CN113354053A
CN113354053A CN202110759666.5A CN202110759666A CN113354053A CN 113354053 A CN113354053 A CN 113354053A CN 202110759666 A CN202110759666 A CN 202110759666A CN 113354053 A CN113354053 A CN 113354053A
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Prior art keywords
ammonia
oxygen
pressure
automatic
dissolver
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CN202110759666.5A
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Inventor
王钊
王宁飞
张小宏
贾予平
哈燕萍
郭金平
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Xian Thermal Power Research Institute Co Ltd
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Xian Thermal Power Research Institute Co Ltd
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Priority to CN202110759666.5A priority Critical patent/CN113354053A/en
Priority to PCT/CN2021/115546 priority patent/WO2023279502A1/en
Publication of CN113354053A publication Critical patent/CN113354053A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Accessories For Mixers (AREA)

Abstract

The invention discloses an ammonia-oxygen mixed feeding system and a working method thereof.A outlet of an ammonia source system is communicated with an inlet of an ammonia dissolver through a first-stage pressure reducer, an automatic pressure regulator and a second pressure transmitter; the automatic control system is connected with the delivery pump, the automatic pressure regulator, the first pressure transmitter, the second pressure transmitter and the automatic voltage stabilizer, the system and the working method thereof can meet the requirements of full working condition and full automatic operation of the thermal power generating unit, and the system has the characteristics of low cost, strong maintenance convenience and high space utilization rate.

Description

Ammonia-oxygen mixed feeding system and working method thereof
Technical Field
The invention belongs to the technical field of feedwater treatment of a thermal power plant, and relates to an ammonia-oxygen mixed feeding system and a working method thereof.
Background
For large thermal power generating unit, water treatment system in furnace
It is usually designed to: at the initial stage of starting the unit, adding a certain amount of ammonia into a water vapor system by using ammonia adding equipment in a furnace, and adjusting the pH of feed water to 9.2-9.6 to perform in-furnace anti-corrosion treatment (AVT (O)); in the normal operation stage, while a certain amount of ammonia is added into a water vapor system by using ammonia adding equipment in a furnace, trace oxygen is added into the water vapor system by using oxygen adding equipment, the pH value of feed water is adjusted to 8.5-9.3, the oxygen content of the feed water is adjusted to 10-150ug/L, and the feed water are subjected to in-furnace corrosion prevention treatment (OT) together; when the hydrogen conductivity of the feed water exceeds a standard value under an OT operation working condition, stopping oxygenation in time, switching to an AVT (O) working condition for operation, and controlling the pH value of the feed water to be 9.2-9.6 by using an ammonia addition system; and stopping oxygen supply to the water 4 hours before the machine set stops, rapidly increasing the ammonia supply amount, and controlling the pH value of the water supply to be 9.6-10.5.
In order to meet the design requirements, ammonia adding devices and oxygen adding devices need to be arranged respectively, but the ammonia adding devices and the oxygen adding devices which are independently arranged in the actual operation of a plurality of power plants have the following common problems:
1. the existing ammonia and oxygen adding device can not meet the requirements of full-working-condition and full-automatic operation of a thermal power generating unit.
Under the full-working-condition operation condition of the unit, in order to keep the pH value of feed water and dissolved oxygen to meet the corrosion and scale prevention requirements of the unit, the ammonia adding device and the oxygen adding device need to be coordinately controlled, so that the ammonia adding amount and the oxygen adding amount are always kept in the optimal proportion.
However, when the existing ammonia adding device switches between working conditions such as starting, normal Operation (OT), abnormal water quality (avt (o)), shutdown and the like and performs deep peak regulation, the difference of the adding amount of ammonia water is more than 10 times, and the adding amount of ammonia water is far beyond the automatic regulation range of an ammonia adding system (the difference between the maximum value and the minimum value of variable frequency regulation flow is not more than 5 times). Therefore, when the existing ammonia adding system is switched among working conditions such as starting, normal Operation (OT), water quality abnormity (AVT (O)), shutdown and the like and is subjected to deep peak regulation, operating personnel are required to manually adjust operating parameters on site (such as changing the stroke of an ammonia adding metering pump, adjusting the concentration of ammonia water in an ammonia solution tank and the like) so as to meet the control requirement of the pH value of feed water.
Meanwhile, the traditional oxygenation device designed and produced according to DL 5000-.
Therefore, the prior ammonia and oxygen adding device can not realize the automatic control of the water supply pH and dissolved oxygen full working conditions and can not realize the coordination control.
2. The modification cost of the existing ammonia and oxygen adding system coordination control is higher.
The existing ammonia and oxygen adding device for the thermal power generating unit has the problems of simple hardware function, inappropriate type selection of key components such as an ammonia adding metering pump, an oxygen adding regulating valve, an oxygen adding flow meter and the like, low automation degree and the like. The modification of the ammonia adding device is generally performed only around automatic ammonia preparation and automatic ammonia addition, and the automatic ammonia preparation device, the improper ammonia adding metering pump for replacement and selection, the ammonia adding control cabinet, the automatic ammonia adding control program and pictures of an upper computer and the like need to be added, so that the water supply pH adjusting range of the modified ammonia adding device is not substantially improved, and full-working-condition and full-automatic operation cannot be realized. If full-working-condition and full-automatic operation needs to be met, the complexity and cost of transformation are greatly increased. The oxygen adding device is transformed to generally remove the traditional oxygen adding device integrally, and is replaced by a novel automatic oxygen adding device with high control precision, stability and reliability. On the premise of realizing automatic control of the ammonia adding device and the oxygen adding device respectively, corresponding upper computer coordination control software and hardware are required to be added so as to realize the coordination control of the water supply pH and the dissolved oxygen all-condition, and the total modification cost is higher.
3. The ammonia and oxygen adding devices have the advantages of high operation and maintenance cost, poor maintenance convenience, large occupied area and low space utilization rate.
The traditional ammonia adding device prepares ammonia from an ammonia source into ammonia water with a certain concentration, then utilizes a conveying device such as a metering pump and the like to inject a dosing point, wherein the adding medium is liquid ammonia water, and controls the adding amount of the ammonia water by adopting frequency conversion regulation; the traditional oxygenation device generally utilizes gas pressure to directly inject oxygen into an oxygenation point, and adopts a regulating valve to control the addition of the oxygen. The two sets of devices are various in manufacturers, good in equipment quality, different in function setting and complex in part variety, so that the operation and maintenance cost is high, and the maintenance convenience is poor. And the number of the devices and the pipelines is large, the occupied area is large, and the space utilization rate is low.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides an ammonia-oxygen mixed feeding system and a working method thereof, the system and the working method thereof can meet the requirements of full-working-condition and full-automatic operation of a thermal power generating unit, and the system has the characteristics of low cost, strong maintenance convenience and high space utilization rate.
In order to achieve the purpose, the ammonia-oxygen mixed adding system comprises an oxygen-enriched water generator, a delivery pump, an ammonia dissolver, a first pressure transmitter, an automatic voltage stabilizer, a primary pressure reducer, an automatic voltage regulator, a second pressure transmitter and an automatic control system;
the outlet of the ammonia source system is communicated with the inlet of an ammonia dissolver through a first-stage pressure reducer, an automatic pressure regulator and a second pressure transmitter, an industrial pure oxygen or compressed air pipeline and a demineralized water pipeline are communicated with the inlet of an oxygen-enriched water generator through an automatic control system, the outlet of the oxygen-enriched water generator is communicated with the inlet of the ammonia dissolver through a delivery pump, and the outlet of the ammonia dissolver is communicated with the dosing point of a water supply, condensed water or high-pressure-plus-drainage system in a thermal power plant furnace through a first pressure transmitter and an automatic pressure stabilizer;
the automatic control system is connected with the delivery pump, the automatic pressure regulator, the first pressure transmitter, the second pressure transmitter and the automatic voltage stabilizer.
The second pressure transmitter is communicated with the inlet of the ammonia dissolver through a check valve.
The ammonia source system is an ammonia bottle or an ammonia area.
The outlet of the ammonia dissolver is communicated with the dosing point of the water supply, the condensed water or the high-pressure hydrophobic system in the thermal power plant through the first pressure transmitter, the automatic voltage stabilizer and the dosing pipeline.
The automatic control system automatically controls and adjusts the conveying speed of the conveying pump, the output pressure of the automatic pressure regulator and the constant pressure constant value of the automatic pressure stabilizer, so as to realize the pH value and the dissolved oxygen value in the water treatment system in the ammonia-oxygen mixed feeding control furnace.
The working method of the ammonia-oxygen mixed feeding system comprises the following steps:
demineralized water and industrial pure oxygen or compressed air enter an oxygen-enriched water generator, oxygen-enriched water solution with stable oxygen content concentration is generated in the oxygen-enriched water generator, the oxygen-enriched water solution is conveyed to an ammonia dissolver through a conveying pump, outlet backpressure of the ammonia dissolver is set through an automatic voltage stabilizer, the outlet backpressure of the ammonia dissolver is monitored through a first pressure transmitter, ammonia gas output by an ammonia source system is decompressed through a first-stage decompressor and then enters the ammonia dissolver after being adjusted to enter ammonia pressure through an automatic voltage regulator, wherein the ammonia inlet pressure of the ammonia dissolver is monitored through a second pressure transmitter, the ammonia gas is dissolved in the oxygen-enriched water solution in the ammonia dissolver to generate ammonia-oxygen water solution with set concentration, and then the ammonia-oxygen water solution is conveyed to a dosing point of a water supply, condensed water or a high-pressure hydrophobic system.
The automatic control system adjusts the oxygen adding amount of the flow control system of the delivery pump so as to adjust the dissolved oxygen value of the feed water in the furnace; and when the flow of the delivery pump is changed, adjusting the automatic pressure stabilizer in real time to keep the outlet back pressure of the ammonia dissolver constant.
The invention has the following beneficial effects:
the ammonia-oxygen mixed addition system and the working method thereof have the advantages that during specific operation, the ammonia gas is dissolved in the oxygen-enriched water with stable concentration by utilizing the characteristic of easy dissolution of the ammonia gas to form ammonia-oxygen aqueous solution, the ammonia concentration in the ammonia-oxygen aqueous solution is adjusted in real time by controlling different ammonia gas dissolution pressures, and meanwhile, the pH value and the oxygen value of a water vapor system in the furnace are subjected to full-working-condition coordination control by integrally and automatically adjusting the ammonia-oxygen water addition amount and the ammonia dissolution pressure, so that the requirements of full-working-condition and full-automatic operation of a thermal power generating unit are met. In addition, the invention integrates the traditional two sets of equipment for adding ammonia and oxygen into a set of independent and complete ammonia-oxygen mixed addition equipment, thereby not only realizing the accurate control of the pH value and dissolved oxygen in the furnace and the coordination control of the whole working condition, but also effectively simplifying the system, reducing the cost of respectively modifying and upgrading the two sets of independent devices for adding ammonia and oxygen, improving the maintenance convenience, saving the occupied area of field equipment and pipelines and improving the space utilization efficiency of a main factory building.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
Wherein, 1 is the oxygen-enriched water generator, 2 is the delivery pump, 3 is the ammonia dissolver, 4 is first pressure transmitter, 5 is automatic voltage stabilizer, 6 is the first-stage pressure reducer, 7 is automatic voltage regulator, 8 is the second pressure transmitter, 9 is the check valve, 10 is automatic control system.
Detailed Description
In order to make the technical solutions of the present invention better understood, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments, and are not intended to limit the scope of the present disclosure. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present disclosure. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
There is shown in the drawings a schematic block diagram of a disclosed embodiment in accordance with the invention. The figures are not drawn to scale, wherein certain details are exaggerated and possibly omitted for clarity of presentation. The shapes of various regions, layers and their relative sizes and positional relationships shown in the drawings are merely exemplary, and deviations may occur in practice due to manufacturing tolerances or technical limitations, and a person skilled in the art may additionally design regions/layers having different shapes, sizes, relative positions, according to actual needs.
Referring to fig. 1, the ammonia-oxygen mixed feeding system of the present invention comprises an oxygen-enriched water generator 1, a delivery pump 2, an ammonia dissolver 3, a first pressure transmitter 4, an automatic pressure stabilizer 5, a first-stage pressure reducer 6, an automatic pressure regulator 7, a second pressure transmitter 8, a check valve 9 and an automatic control system 10;
the outlet of the ammonia source system is communicated with the inlet of the ammonia dissolver 3 through a first-stage pressure reducer 6, an automatic pressure regulator 7, a second pressure transmitter 8 and a check valve 9, an industrial pure oxygen or compressed air pipeline and a demineralized water pipeline are communicated with the inlet of the oxygen-enriched water generator 1 through an automatic control system 10, the outlet of the oxygen-enriched water generator 1 is communicated with the inlet of the ammonia dissolver 3 through a delivery pump 2, the outlet of the ammonia dissolver 3 is communicated with the dosing point of a water supply, condensed water or high-pressure hydrophobic system in the thermal power plant furnace through a first pressure transmitter 4 and an automatic voltage stabilizer 5, and the ammonia source system is an ammonia bottle or an ammonia area.
The automatic control system 10 is connected with the delivery pump 2, the automatic pressure regulator 7, the first pressure transmitter 4, the second pressure transmitter 8 and the automatic pressure stabilizer 5, and the automatic control system 10 automatically controls and regulates the delivery rate of the delivery pump 2, the output pressure of the automatic pressure regulator 7 and the pressure stabilization constant value of the automatic pressure stabilizer 5, so that the pH value and the dissolved oxygen value in the ammonia-oxygen mixed addition control furnace internal water treatment system are realized, and the coordinated control of the pH value and the dissolved oxygen value of the feed water in the thermal power plant is realized.
The working method of the ammonia-oxygen mixed addition system comprises the following steps:
demineralized water and industrial pure oxygen or compressed air enter an oxygen-enriched water generator 1, an oxygen-enriched water solution with stable oxygen content concentration is generated in the oxygen-enriched water generator 1, the oxygen-enriched water solution is conveyed to an ammonia dissolver 3 through a conveying pump 2, the outlet backpressure of the ammonia dissolver 3 is set through adjusting an automatic voltage stabilizer 5, the outlet backpressure of the ammonia dissolver 3 is monitored through a first pressure transmitter 4, ammonia gas output by an ammonia source system is decompressed through a first-stage decompressor 6 and then enters the ammonia dissolver 3 after being adjusted by an automatic voltage regulator 7, wherein the ammonia inlet pressure of the ammonia dissolver 3 is monitored through a second pressure transmitter 8, the ammonia gas is dissolved in the oxygen-enriched water solution in the ammonia dissolver 3 to generate an ammonia-oxygen water solution with set concentration, and then the ammonia-oxygen water solution is conveyed to a dosing point of a water supply, condensed water or a high-pressure drainage system through a dosing pipeline.
In the conveying process, the automatic control system 10 controls the oxygen adding amount of the system by adjusting the flow rate of the conveying pump 2, and then adjusts the water supply dissolved oxygen value in the furnace; when the flow of the delivery pump 2 changes, the automatic pressure stabilizer 5 is adjusted in real time to keep the outlet back pressure of the ammonia dissolver 3 constant.
According to the water supply flow in the furnace and the real-time flow of the delivery pump 2, the automatic pressure regulator 7 is adjusted to control the ammonia inlet pressure of the ammonia dissolver 3, further control the ammonia concentration in the ammonia-oxygen aqueous solution in the ammonia dissolver 3, and finally adjust the pH value of the water supply in the furnace, so that the pH value and the dissolved oxygen value of the water supply in the furnace realize the coordination control of all working conditions.

Claims (7)

1. An ammonia-oxygen mixed adding system is characterized by comprising an oxygen-enriched water generator (1), a delivery pump (2), an ammonia dissolver (3), a first pressure transmitter (4), an automatic voltage stabilizer (5), a first-stage pressure reducer (6), an automatic voltage regulator (7), a second pressure transmitter (8) and an automatic control system (10);
an outlet of the ammonia source system is communicated with an inlet of an ammonia dissolver (3) through a first-stage pressure reducer (6), an automatic pressure regulator (7) and a second pressure transmitter (8), an industrial pure oxygen or compressed air pipeline and a demineralized water pipeline are communicated with an inlet of an oxygen-enriched water generator (1) through an automatic control system (10), an outlet of the oxygen-enriched water generator (1) is communicated with an inlet of the ammonia dissolver (3) through a delivery pump (2), and an outlet of the ammonia dissolver (3) is communicated with a dosing point of a feed water, a condensed water or a high-pressure hydrophobic system in a furnace of a thermal power plant through a first pressure transmitter (4) and an automatic voltage stabilizer (5);
the automatic control system (10) is connected with the delivery pump (2), the automatic pressure regulator (7), the first pressure transmitter (4), the second pressure transmitter (8) and the automatic voltage stabilizer (5).
2. The ammonia-oxygen mixing system according to claim 1, wherein the second pressure transmitter (8) is in communication with the inlet of the ammonia dissolver (3) via a non-return valve (9).
3. The ammonia-oxygen mixing and feeding system as set forth in claim 1, wherein the ammonia source system is an ammonia bottle or an ammonia zone.
4. The ammonia-oxygen mixing and feeding system as claimed in claim 1, wherein the outlet of the ammonia dissolver (3) is communicated with the dosing point of the feed water, the condensate water or the high-pressure and hydrophobic system in the thermal power plant through the first pressure transmitter (4), the automatic pressure stabilizer (5) and the dosing pipeline.
5. The ammonia-oxygen mixing system as claimed in claim 1, wherein the automatic control system (10) automatically controls and adjusts the delivery rate of the delivery pump (2), the output pressure of the automatic pressure regulator (7) and the constant pressure value of the automatic pressure stabilizer (5) to control the pH value and the dissolved oxygen value in the water treatment system in the ammonia-oxygen mixing furnace.
6. A method of operating the ammonia-oxygen admixture system according to claim 1, comprising the steps of:
demineralized water and industrial pure oxygen or compressed air enter an oxygen-enriched water generator (1) to generate an oxygen-enriched water solution with stable oxygen content concentration in the oxygen-enriched water generator (1), the oxygen-enriched water solution is conveyed to an ammonia dissolver (3) through a conveying pump (2), the outlet back pressure of the ammonia dissolver (3) is adjusted through an automatic voltage stabilizer (5), the outlet backpressure of the ammonia dissolver (3) is monitored by a first pressure transmitter (4), the ammonia gas output by the ammonia source system is decompressed by a first-stage decompressor (6), the pressure of the ammonia gas is adjusted by an automatic pressure regulator (7) and then enters the ammonia dissolver (3), wherein, the ammonia inlet pressure of the ammonia dissolver (3) is monitored by the second pressure transmitter (8), ammonia gas is dissolved in the oxygen-enriched water solution in the ammonia dissolver (3) to generate ammonia-oxygen water solution with set concentration, and then the ammonia-oxygen water solution is conveyed to the feed water, the condensed water or the dosing point of the high pressure water drainage system.
7. The working method of the ammonia-oxygen mixed adding system as claimed in claim 6, wherein the automatic control system (10) adjusts the dissolved oxygen value of the feed water in the furnace by adjusting the adding oxygen amount of the flow control system of the delivery pump (2); when the flow of the delivery pump (2) changes, the automatic pressure stabilizer (5) is adjusted in real time to keep the outlet back pressure of the ammonia dissolver (3) constant.
CN202110759666.5A 2021-07-05 2021-07-05 Ammonia-oxygen mixed feeding system and working method thereof Pending CN113354053A (en)

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CN202110759666.5A CN113354053A (en) 2021-07-05 2021-07-05 Ammonia-oxygen mixed feeding system and working method thereof
PCT/CN2021/115546 WO2023279502A1 (en) 2021-07-05 2021-08-31 Ammonia-oxygen mixing and adding system and working method therefor

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CN202110759666.5A CN113354053A (en) 2021-07-05 2021-07-05 Ammonia-oxygen mixed feeding system and working method thereof

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Citations (3)

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CN111377517A (en) * 2020-05-01 2020-07-07 西安热工研究院有限公司 System and method for treating water in thermal power plant furnace based on ammonia oxygen water
CN215403298U (en) * 2021-07-05 2022-01-04 西安热工研究院有限公司 Ammonia-oxygen mixed feeding system

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CN101851020B (en) * 2010-04-29 2012-02-01 浙江省电力试验研究院 DC boiler feed water selective oxidation treatment process
CN103880230B (en) * 2014-03-26 2015-04-08 西安热工研究院有限公司 Segmental oxidation treatment system and treatment method of thermodynamic system of novel coal-fired power plant

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Publication number Priority date Publication date Assignee Title
CN110217900A (en) * 2019-04-18 2019-09-10 西安热工研究院有限公司 A kind of automatic oxygenation of power plant water supply and the collaboration precise control device and method of ammonification
CN111377517A (en) * 2020-05-01 2020-07-07 西安热工研究院有限公司 System and method for treating water in thermal power plant furnace based on ammonia oxygen water
CN215403298U (en) * 2021-07-05 2022-01-04 西安热工研究院有限公司 Ammonia-oxygen mixed feeding system

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王宁飞 等: ""氨氧混加联动控制技术的可行性分析"", 《中国环境科学学会2019年科学技术年会——环境工程技术创新与应用分论坛文集(四)》, pages 693 *

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