CN113337316A - 一种高清洁醇醚燃料的制备方法 - Google Patents

一种高清洁醇醚燃料的制备方法 Download PDF

Info

Publication number
CN113337316A
CN113337316A CN202110462572.1A CN202110462572A CN113337316A CN 113337316 A CN113337316 A CN 113337316A CN 202110462572 A CN202110462572 A CN 202110462572A CN 113337316 A CN113337316 A CN 113337316A
Authority
CN
China
Prior art keywords
parts
alcohol ether
cleanness
ether fuel
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110462572.1A
Other languages
English (en)
Inventor
张同永
李强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Xinqiang Environmental Protection Fuel Co ltd
Original Assignee
Guizhou Xinqiang Environmental Protection Fuel Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou Xinqiang Environmental Protection Fuel Co ltd filed Critical Guizhou Xinqiang Environmental Protection Fuel Co ltd
Priority to CN202110462572.1A priority Critical patent/CN113337316A/zh
Publication of CN113337316A publication Critical patent/CN113337316A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/20—Organic compounds containing halogen
    • C10L1/205—Organic compounds containing halogen carboxylic radical containing compounds or derivatives, e.g. salts, esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2366—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amine groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

本发明提供一种高清洁醇醚燃料的制备方法，包括以下步骤：步骤(1).按质量配比加入甲醇或乙醇、煤基费托合成汽油组分油分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，步骤(2).按质量配比加入清净增效剂、分散剂、助溶剂、防腐抑制剂通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，直到完全混合，将混合液静置，成为醇醚燃料。本发明添加适度的清净增效剂、分散剂、助溶剂、防腐抑制剂等复合添加剂，采取科学的配方调配而成的一种新型清洁燃料，具有燃烧充分、抗爆性强、节能减排、通用性高等优点，可广泛用于点燃式发动机。

Description

一种高清洁醇醚燃料的制备方法
技术领域
本发明涉及清洁燃料技术领域，具体为一种高清洁醇醚燃料的制备方法。
背景技术
能源就是向自然界提供能量转化的物质(矿物质能源，核物理能源，大气环流能源，地理性能源)。能源是人类活动的物质基础。在某种意义上讲，人类社会的发展离不开优质能源的出现和先进能源技术的使用。在当今世界，能源的发展，能源和环境，是全世界、全人类共同关心的问题，也是我国社会经济发展的重要问题。
无污染燃料又称清洁燃料。燃烧时能产生高热值而不污染环境的燃料。天然燃料中只有少数地区的天然气属于这种燃料。获得大量的无污染燃料的方法是对现有天然燃料进行无害化处理，或研制新型的无污染燃料。以石油为原料制成的液化石油气、脱硫重油等，都是少灰、低硫的实用燃料。我国的国情是贫油、富煤、少气、能源消耗大，发展替代能源是我国能源发展的必然选择。
发明内容
本发明所解决的技术问题在于提供一种高清洁醇醚燃料的制备方法，以解决上述背景技术中提出的问题。
本发明所解决的技术问题采用以下技术方案来实现：一种高清洁醇醚燃料的制备方法，包括以下步骤：
步骤(1).按质量配比加入甲醇5～30份、煤基费托合成汽油组分20～60份、异辛烷5～30份分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，调和方法为以160～5000赫兹的频率进行振荡混合20～60分钟；
步骤(2).按质量配比加入清净增效剂1～5份、分散剂1.5～3份、助溶剂0.01～2份、防腐抑制剂0.01～0.5份通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，调和方法为以500～20000赫兹的频率进行振荡混合30～90分钟；
步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，通过循环泵及第三管道混合器调和，再转入到调和罐中，循环该调和步骤，直到完全混合，将混合液静置1-4小时，成为醇醚燃料。
所述醇醚燃料的质量配比为甲醇或乙醇20份、煤基费托合成汽油组分14份、清净增效剂1份、分散剂1.5份、助溶剂0.01份、防腐抑制剂0.01份。
所述醇醚燃料的质量配比为甲醇或乙醇80份、煤基费托合成汽油组分75份、清净增效剂5份、分散剂3份、助溶剂2份、防腐抑制剂0.5份。
所述醇醚燃料的质量配比为甲醇或乙醇60份、煤基费托合成汽油组分50份、清净增效剂3份、分散剂2份、助溶剂1份、防腐抑制剂0.3份。
所述清净增效剂包括硝酸环己酯、硝酸异辛酯、硝酸异戊酯、硝酸正戊酯、2-甲基硝酸正戊酯、草酸正丁酯、草酸二异戊酯、碳酸二甲酯、碳酸二乙酯、脂肪酸甲酯中的一种或几种混合。
所述分散剂包括聚异丁烯琥珀酰亚胺、聚异丁烯丁二酰亚胺、聚异丁烯基胺、聚醚胺、聚烯胺中的一种或几种混合。
助溶剂包括二甲醚、异丙醚、正丙醚、乙醚、甲酸甲酯、氯甲酸甲酯、甲基丙烯酸甲酯、亚磷酸三甲酯、碳酸二甲酯或碳酸二乙酯中的一种或几种混合。
所述防腐抑制剂包括乙醇胺、二乙醇胺、三乙胺、十六烷胺、十八烷胺、油酸胺或硝基苯胺中的一种或几种混合。
与现有技术相比，本发明的有益效果是：本发明添加适度的清净增效剂、分散剂、助溶剂、防腐抑制剂等复合添加剂，采取科学的配方调配而成的一种新型清洁燃料，具有燃烧充分、抗爆性强、节能减排、通用性高等优点，可广泛用于点燃式发动机。
具体实施方式
为了使本发明的实现技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
一种高清洁醇醚燃料的制备方法，包括以下步骤：
步骤(1).按质量配比加入按质量配比加入甲醇5份、煤基费托合成汽油组分20份、异辛烷5份分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，调和方法为以160～5000赫兹的频率进行振荡混合20～60分钟；步骤(2).按质量配比加入清净增效剂1份、分散剂1.5份、助溶剂0.01份、防腐抑制剂0.01份通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，调和方法为以500～20000赫兹的频率进行振荡混合30～90分钟；步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，通过循环泵及第三管道混合器调和，再转入到调和罐中，循环该调和步骤，直到完全混合，将混合液静置1-4小时，成为醇醚燃料。本实施例中所述清净增效剂包括硝酸环己酯、硝酸异辛酯、硝酸异戊酯、硝酸正戊酯、2-甲基硝酸正戊酯、草酸正丁酯、草酸二异戊酯、碳酸二甲酯、碳酸二乙酯、脂肪酸甲酯中的一种或几种混合。所述分散剂包括聚异丁烯琥珀酰亚胺、聚异丁烯丁二酰亚胺、聚异丁烯基胺、聚醚胺、聚烯胺中的一种或几种混合。助溶剂包括二甲醚、异丙醚、正丙醚、乙醚、甲酸甲酯、氯甲酸甲酯、甲基丙烯酸甲酯、亚磷酸三甲酯、碳酸二甲酯或碳酸二乙酯中的一种或几种混合。所述防腐抑制剂包括乙醇胺、二乙醇胺、三乙胺、十六烷胺、十八烷胺、油酸胺或硝基苯胺中的一种或几种混合。
实施例2
一种高清洁醇醚燃料的制备方法，包括以下步骤：
步骤(1).按质量配比加入按质量配比加入甲醇30份、煤基费托合成汽油组分60份、异辛烷30份分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，调和方法为以160～5000赫兹的频率进行振荡混合20～60分钟；步骤(2).按质量配比加入清净增效剂5份、分散剂3份、助溶剂2份、防腐抑制剂0.5份通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，调和方法为以500～20000赫兹的频率进行振荡混合30～90分钟；步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，通过循环泵及第三管道混合器调和，再转入到调和罐中，循环该调和步骤，直到完全混合，将混合液静置1-4小时，成为醇醚燃料。本实施例中所述清净增效剂包括硝酸环己酯、硝酸异辛酯、硝酸异戊酯、硝酸正戊酯、2-甲基硝酸正戊酯、草酸正丁酯、草酸二异戊酯、碳酸二甲酯、碳酸二乙酯、脂肪酸甲酯中的一种或几种混合。所述分散剂包括聚异丁烯琥珀酰亚胺、聚异丁烯丁二酰亚胺、聚异丁烯基胺、聚醚胺、聚烯胺中的一种或几种混合。助溶剂包括二甲醚、异丙醚、正丙醚、乙醚、甲酸甲酯、氯甲酸甲酯、甲基丙烯酸甲酯、亚磷酸三甲酯、碳酸二甲酯或碳酸二乙酯中的一种或几种混合。所述防腐抑制剂包括乙醇胺、二乙醇胺、三乙胺、十六烷胺、十八烷胺、油酸胺或硝基苯胺中的一种或几种混合。
实施例3
一种高清洁醇醚燃料的制备方法，包括以下步骤：
步骤(1).按质量配比加入按质量配比加入甲醇15份、煤基费托合成汽油组分40份、异辛烷15份分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，调和方法为以160～5000赫兹的频率进行振荡混合20～60分钟；步骤(2).按质量配比加入清净增效剂3份、分散剂2份、助溶剂1份、防腐抑制剂0.3份通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，调和方法为以500～20000赫兹的频率进行振荡混合30～90分钟；步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，通过循环泵及第三管道混合器调和，再转入到调和罐中，循环该调和步骤，直到完全混合，将混合液静置1-4小时，成为醇醚燃料。本实施例中所述清净增效剂包括硝酸环己酯、硝酸异辛酯、硝酸异戊酯、硝酸正戊酯、2-甲基硝酸正戊酯、草酸正丁酯、草酸二异戊酯、碳酸二甲酯、碳酸二乙酯、脂肪酸甲酯中的一种或几种混合。所述分散剂包括聚异丁烯琥珀酰亚胺、聚异丁烯丁二酰亚胺、聚异丁烯基胺、聚醚胺、聚烯胺中的一种或几种混合。助溶剂包括二甲醚、异丙醚、正丙醚、乙醚、甲酸甲酯、氯甲酸甲酯、甲基丙烯酸甲酯、亚磷酸三甲酯、碳酸二甲酯或碳酸二乙酯中的一种或几种混合。所述防腐抑制剂包括乙醇胺、二乙醇胺、三乙胺、十六烷胺、十八烷胺、油酸胺或硝基苯胺中的一种或几种混合。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明的要求保护范围由所附的权利要求书及其等效物界定。

Claims (8)

1.一种高清洁醇醚燃料的制备方法，其特征在于：包括以下步骤：
步骤(1).按质量配比加入甲醇或乙醇按质量配比加入甲醇5～30份、煤基费托合成汽油组分20～60份、异辛烷5～30份分别通过生产自动化控制系统控制在第一管道混合器中调和均匀，调和方法为以160～5000赫兹的频率进行振荡混合20～60分钟；
步骤(2).按质量配比加入清净增效剂1～5份、分散剂1.5～3份、助溶剂0.01～2份、防腐抑制剂0.01～0.5份通过生产自动化控制系统控制，与步骤(1)调和均匀的混合物一起在第二管道混合器中调和均匀，调和方法为以500～20000赫兹的频率进行振荡混合30～90分钟；
步骤(3).将上述步骤(2)调和均匀的混合物加入到调和罐中，通过循环泵及第三管道混合器调和，再转入到调和罐中，循环该调和步骤，直到完全混合，将混合液静置1-4小时，成为醇醚燃料。
2.根据权利要求1所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述醇醚燃料的质量配比为按质量配比加入甲醇5份、煤基费托合成汽油组分20份、异辛烷5份、清净增效剂1份、分散剂1.5份、助溶剂0.01份、防腐抑制剂0.01份。
3.根据权利要求1所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述醇醚燃料的质量配比为按质量配比加入甲醇30份、煤基费托合成汽油组分60份、异辛烷30份、清净增效剂5份、分散剂3份、助溶剂2份、防腐抑制剂0.5份。
4.根据权利要求1所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述醇醚燃料的质量配比为按质量配比加入甲醇15份、煤基费托合成汽油组分40份、异辛烷15份、清净增效剂3份、分散剂2份、助溶剂1份、防腐抑制剂0.3份。
5.根据权利要求1-4任意一项所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述清净增效剂包括硝酸环己酯、硝酸异辛酯、硝酸异戊酯、硝酸正戊酯、2-甲基硝酸正戊酯、草酸正丁酯、草酸二异戊酯、碳酸二甲酯、碳酸二乙酯、脂肪酸甲酯中的一种或几种混合。
6.根据权利要求1-4任意一项所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述分散剂包括聚异丁烯琥珀酰亚胺、聚异丁烯丁二酰亚胺、聚异丁烯基胺、聚醚胺、聚烯胺中的一种或几种混合。
7.根据权利要求1-4任意一项所述的一种高清洁醇醚燃料的制备方法，其特征在于：助溶剂包括二甲醚、异丙醚、正丙醚、乙醚、甲酸甲酯、氯甲酸甲酯、甲基丙烯酸甲酯、亚磷酸三甲酯、碳酸二甲酯或碳酸二乙酯中的一种或几种混合。
8.根据权利要求1-4任意一项所述的一种高清洁醇醚燃料的制备方法，其特征在于：所述防腐抑制剂包括乙醇胺、二乙醇胺、三乙胺、十六烷胺、十八烷胺、油酸胺或硝基苯胺中的一种或几种混合。
CN202110462572.1A 2021-04-27 2021-04-27 一种高清洁醇醚燃料的制备方法 Pending CN113337316A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110462572.1A CN113337316A (zh) 2021-04-27 2021-04-27 一种高清洁醇醚燃料的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110462572.1A CN113337316A (zh) 2021-04-27 2021-04-27 一种高清洁醇醚燃料的制备方法

Publications (1)

Publication Number Publication Date
CN113337316A true CN113337316A (zh) 2021-09-03

Family

ID=77468874

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110462572.1A Pending CN113337316A (zh) 2021-04-27 2021-04-27 一种高清洁醇醚燃料的制备方法

Country Status (1)

Country Link
CN (1) CN113337316A (zh)

Similar Documents

Publication Publication Date Title
CN103642547B (zh) 一种复合柴油添加剂及其制备方法
JP2004528453A5 (zh)
CN108998129B (zh) 一种利用超声波技术合成的生物燃油添加剂及制作方法
CN102517101A (zh) 一种车用甲醇柴油燃料及其制备方法
CN105296022B (zh) 一种燃油添加剂及其制备方法
MXPA04012633A (es) Metodo y composicion para usar beta-caroteno estabilizado como mejorador de cetano en combustibles diesel hidrocarbonaceos.
CN105296023B (zh) 一种燃油添加剂及其制备方法
CN111647447A (zh) 一种费托合成液蜡环保型生物燃料及其制备工艺
CN102504890A (zh) 一种复合型甲醇柴油及其制备方法
MXPA06000066A (es) Aditivo para combustible de hidrocarburos y procesos relacionados.
CN101928625B (zh) 一种新型的发动机用燃料添加剂
CN113337316A (zh) 一种高清洁醇醚燃料的制备方法
CN101210204A (zh) 一种添加剂及其车用甲醇柴油和制备方法
CN102268305A (zh) 一种车用环保甲醇柴油及其配制方法
CN101445751A (zh) 非剪切形环保节能掺水柴油添加剂
CN104312644B (zh) 一种用于柴油发动机的混合燃料及其应用
Rajesh et al. Investigation on performance and emission of pongamia biodiesel using diethyl ether and zinc oxide as additive in diesel engine
KR20170033756A (ko) 온실가스, 질소산화물 및 입자상 물질 저감을 위한 연료첨가제
CN104263431B (zh) 一种汽车燃料组合物
CN113337314A (zh) 一种生物柴油调和燃料的制备方法
CN110724568A (zh) 一种甲醇基体混合清洁液体燃料及其制备方法
KR100699086B1 (ko) 연료첨가제
CN110157498A (zh) 一种车用epm45航醇燃料及制作方法
CN101597524A (zh) 化合柴油
Chaudhary et al. Optimization of performance and emission parameters of hydrogen enriched dual fuel diesel engine using response surface methodology

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication