CN113321852A - Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 - Google Patents
Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 Download PDFInfo
- Publication number
- CN113321852A CN113321852A CN202110658528.8A CN202110658528A CN113321852A CN 113321852 A CN113321852 A CN 113321852A CN 202110658528 A CN202110658528 A CN 202110658528A CN 113321852 A CN113321852 A CN 113321852A
- Authority
- CN
- China
- Prior art keywords
- lae
- antibacterial agent
- essential oil
- plant essential
- packaging film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003242 anti bacterial agent Substances 0.000 title claims abstract description 47
- 239000000341 volatile oil Substances 0.000 title claims abstract description 37
- 239000002131 composite material Substances 0.000 title claims abstract description 26
- 229920006280 packaging film Polymers 0.000 title claims abstract description 19
- 239000012785 packaging film Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 17
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 claims abstract description 13
- 230000002195 synergetic effect Effects 0.000 claims abstract description 7
- 238000004945 emulsification Methods 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 238000010101 extrusion blow moulding Methods 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 238000001694 spray drying Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 7
- 229920000858 Cyclodextrin Polymers 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009210 therapy by ultrasound Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 2
- 229920001896 polybutyrate Polymers 0.000 claims description 2
- 229920001610 polycaprolactone Polymers 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 9
- 238000000265 homogenisation Methods 0.000 claims 2
- 235000013305 food Nutrition 0.000 abstract description 9
- 230000003993 interaction Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 16
- 238000004806 packaging method and process Methods 0.000 description 6
- -1 Hydroxypropyl- Chemical group 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 4
- 239000004626 polylactic acid Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 244000223014 Syzygium aromaticum Species 0.000 description 2
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 2
- 229920008262 Thermoplastic starch Polymers 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 235000017803 cinnamon Nutrition 0.000 description 2
- XJTMYVOVQZMMKX-KRWDZBQOSA-N ethyl (2s)-5-(diaminomethylideneamino)-2-(dodecanoylamino)pentanoate Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(=O)OCC)CCCN=C(N)N XJTMYVOVQZMMKX-KRWDZBQOSA-N 0.000 description 2
- 238000009920 food preservation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004628 starch-based polymer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
- C08K5/31—Guanidine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Manufacturing & Machinery (AREA)
- Biodiversity & Conservation Biology (AREA)
- Botany (AREA)
- Materials Engineering (AREA)
- Packages (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明提出的是一种LAE和植物精油复合抗菌剂及可降解抗菌包装薄膜的制备方法，利用LAE和羟丙基‑β‑环糊精协同乳化作用，以及利用羟丙基‑β‑环糊精的空腔结构包埋LAE和植物精油制备复合抗菌剂，并通过挤压热加工使复合抗菌剂与热加工温度较低的可降解材料混合完成可降解抗菌包装薄膜。本发明利用表面活性剂LAE和羟丙基‑β‑环糊精协同乳化，增强包埋乳化的效果，利用空腔结构对LAE和植物精油的保护提高复合抗菌剂的热稳定性，与热加工温度低的可降解材料复合进一步提高利用度和抗菌效果，降低其与食品中其他物质的相互作用，具有协同抗菌作用，可以降低每种抗菌剂的添加量，提高使用安全性和抗菌保鲜能力。
Description
技术领域
本发明涉及的是抗菌材料的制备方法，特别是一种Nα-月桂酰-L-精氨酸乙酯盐酸盐和植物精油复合抗菌可降解抗菌包装薄膜及其制备方法，属于食品保鲜技术领域。
背景技术
植物精油是由植物产生的具有芳香气味的代谢产物，不溶于水，易溶于乙醇等有机溶剂。作为一种天然提取物，植物精油具有广谱抗菌性，但在使用过程中存在易挥发、易氧化、气味强、使用量大等缺点。Nα-月桂酰-L-精氨酸乙酯盐酸盐（Nα-lauroyl-L-arginateethylester，简称LAE）是一种阳离子表面活性剂，同时对多种食源性病原菌有较高的抑制活性，但LAE由于其阳离子性质容易与食品中阴离子成分相互作用，导致抗菌防腐能力下降；LAE在高于约50 ppm的浓度下会产生苦味，可能会影响食品的接受度。上述这些问题使得植物精油和LAE在使用过程中仍然伴随着一些限制。
此外，现有食品保鲜工艺中，抗菌剂主要使用方法之一是将其制成抗菌膜，特别是环保可降解抗菌膜，但是目前抗菌膜的制备主要采用流延法，该法使用大量溶剂、产量低、不适合大规模生产，大部分停留在实验阶段。挤压吹塑热加工是廉价、成熟的生产薄膜材料的工业化生产方法。但这种方法加工温度高，会加大植物精油等抗菌剂的损耗，甚至导致失活，使薄膜抗菌效果下降。因此，提高抗菌剂耐热性和利用度是挤压吹塑制备抗菌包装需要解决的关键难题。
发明内容
本发明的目的在于克服植物精油和LAE在现有食品保鲜实际应用过程中的局限性，和在挤压吹塑制备抗菌膜时热稳定性低的问题，提出一种利用羟丙基-β-环糊精所具有的独特的外亲水内疏水的空腔结构及其与LAE协同乳化对LAE和植物精油进行包埋乳化，提高两种抗菌材料的热稳定性和利用度，并改善两者对食品气味的影响，进而与热加工温度较低的可降解材料通过挤压热加工法混合，并利用植物精油和LAE的协同抗菌作用，得到一种含安全且高效的复合抗菌剂的可降解抗菌包装薄膜的制备方法。
本发明的技术解决方案：一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，具体包括如下步骤：
1）在室温下将质量分数为1~10%的羟丙基-β-环糊精固体粉末溶解于纯水中，得到环糊精溶液；
2）称取质量分数为0.5~5%的LAE固体粉末，加入步骤1）制备的环糊精溶液中充分溶解，得到包埋乳化剂水溶液；
3）在步骤2）制备的包埋乳化剂水溶液中加入体积分数为0.5~5%的植物精油，经过高速分散12000-18000 r/min下处理5-15 min，超声200-750 W功率下处理5-10 min或高压均质20-100MPa下处理，1-3个循环，每个阶段持续1分钟，得到液体复合抗菌剂；
4）将步骤3）制备的液体复合抗菌剂进一步通过喷雾干燥得到复合抗菌剂固体粉末，喷雾干燥处理的进口温度最高为170℃，出口温度最高为100℃，雾化器转速为20～40Hz，进料速度为15～30 r/min，根据进料速度调节出口温度；
5）将步骤4）制备的质量分数为2-7%复合抗菌剂固体粉末与质量分数为68-82%的可降解材料（淀粉、PBAT、PLA、PHB和PCL中的一种或任意多种复合材料）、质量分数为15-20%甘油、质量分数为1-5%硬脂酸通过高速搅拌机混合得到粉料，将制备的粉料通过双螺杆挤出机熔融挤出后冷却切粒得到热塑性母粒，双螺杆挤出机熔融区温度设置为80-130℃；再通过挤压吹塑机制备挤压吹塑得到可降解包装薄膜，挤压吹塑机熔融区温度设置为80-130℃。
与现有技术相比，本发明的优点在于：
1）利用表面活性剂LAE和羟丙基-β-环糊精协同乳化增强包埋乳化的效果；
2）利用羟丙基-β-环糊精的空腔包埋，对LAE和植物精油均有较好的保护作用，进一步提高LAE和植物精油热稳定性和两种抗菌剂的利用度；
3）制备的复合抗菌剂与热加工温度较低的可降解材料混合，进一步提高挤压热加工生产抗菌包装中抗菌剂的利用度和抗菌效果；
4）利用羟丙基-β-环糊精的空腔包埋，对LAE和植物精油均有较好的保护作用降低了LAE和植物精油与食品中其他物质的相互作用，提高两种抗菌剂抗菌效果，降低高浓度下的强烈风味，对抗菌剂起到缓释作用；
5）两种抗菌剂的复合对微生物有协同增效作用，提高抗菌保鲜能力，且可以降低每种抗菌剂的添加量，提高使用安全性。
具体实施方式
下面根据多个实施例进一步说明本发明的技术方案。在本说明书的描述中，各实施例的内容意指结合其描述的具体技术特征包含于本发明的至少一个实施方式中。在本说明书中，对上述术语的示意性表述不一定指的是相同的实施方式或示例。而且，描述的具体技术特征可以在任何的一个或多个实施方式或示例中以合适的方式结合。
实施例1
室温下将羟丙基-β-环糊精粉末（3% w/v）溶解于100 mL纯水中，再添加Nα-月桂酰-L-精氨酸乙酯盐酸盐固体粉末（1% w/v）充分溶解后，逐滴加入肉桂精油（3% v/v），继续搅拌2 h，高速分散器18000 r/min条件下处理5 min，最后在450 W功率下，超声处理10min，得到羟丙基-β-环糊精/肉桂精油/Nα-月桂酰-L-精氨酸乙酯盐酸盐复合抗菌剂。
将所得的复合抗菌剂进行喷雾干燥，喷雾干燥器的进口温度为150℃，出口温度最高为100℃，雾化器转速为30 Hz，进料速度为25 r/min，得到复合抗菌剂固体粉末。
将淀粉置于高速搅拌机，再添加5% 的复合抗菌剂固体粉末、1%硬脂酸、20%的甘油（以混合粉料质量分数计），混合30 min，置于聚乙烯包装袋密封24 h，备用。
将制备的粉料均匀喂入双螺杆造粒机，挤出机熔融区温度设置为90℃，螺杆转动频率为18 Hz，粉料经双螺杆挤出机熔融挤出后，冷却切粒，密封包装备用。
将挤压吹塑机加热至设定的温度，平衡30 min，将制备的热塑性淀粉均匀喂入吹塑机，待吹塑机头出料后，将材料拉着上牵引夹棍处，夹紧，并以一定压力吹胀淀粉膜，冷却后制得淀粉挤压吹塑抗菌膜。该包装可以用于食品包装内包装，避免与水接触。
实施例2
室温下将羟丙基-β-环糊精粉末（5% w/v）溶解于100 mL纯水中，再添加Nα-月桂酰-L-精氨酸乙酯盐酸盐固体粉末（2% w/v）充分溶解后，逐滴加入丁香精油（4% v/v），继续搅拌2 h，高速分散器18000 r/min条件下处理5 min，最后在450 W功率下，超声处理10min，得到羟丙基-β-环糊精/丁香精油/Nα-月桂酰-L-精氨酸乙酯盐酸盐复合抗菌剂。
将所得的复合抗菌剂进行喷雾干燥，喷雾干燥器的进口温度为150℃，出口温度最高为100℃，雾化器转速为25 Hz，进料速度为25 r/min，得到复合抗菌剂固体粉末。
将PLA（聚乳酸）、PHB（聚-β-羟丁酸）按一定质量比（3∶1）置于高速搅拌机，再添加7% 的复合抗菌剂固体粉末、0.8%硬脂酸、25%的甘油（以混合粉料质量分数计），混合30min，置于聚乙烯包装袋密封24 h，备用。
将制备的粉料均匀喂入双螺杆造粒机，挤出机熔融区温度设置为140℃，螺杆转动频率为18 Hz，粉料经双螺杆挤出机熔融挤出后，冷却切粒，密封包装备用。
将挤压吹塑机加热至设定的温度，平衡30 min，将制备的热塑性淀粉均匀喂入吹塑机，待吹塑机头出料后，将材料拉着上牵引夹棍处，夹紧，并以一定压力吹胀PLA/PHB膜，冷却后制得PLA/PHB挤压吹塑抗菌膜。该包装可以用于食品的外包装，延长食品保鲜期。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (10)
1.一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，利用LAE和植物精油的协同抗菌性，LAE和羟丙基-β-环糊精协同乳化作用，以及利用羟丙基-β-环糊精的空腔结构包埋LAE和植物精油制备复合抗菌剂，提高LAE和植物精油的热稳定性和抗菌性，并通过挤压热加工使复合抗菌剂与热加工温度较低的可降解材料混合完成可降解抗菌包装薄膜；其特征在于，该方法具体包括如下步骤：
1）在室温下将羟丙基-β-环糊精固体粉末溶解于纯水中，得到环糊精溶液；
2）称取LAE固体粉末，加入步骤1）制备的环糊精溶液中充分溶解，得到包埋乳化剂水溶液；
3）在步骤2）制备的包埋乳化剂水溶液中加入植物精油，经过高速分散和超声处理或高压均质后得到液体复合抗菌剂；
4）将步骤3）制备的液体复合抗菌剂进一步通过喷雾干燥得到复合抗菌剂固体粉末；
5）将步骤4）制备的复合抗菌剂固体粉末与可降解材料、甘油、硬脂酸通过高速搅拌机混合得到粉料，将制备的粉料通过双螺杆挤出机熔融挤出后冷却切粒得到热塑性母粒，再通过挤压吹塑机制备挤压吹塑得到可降解抗菌包装薄膜。
2.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤1）中羟丙基-β-环糊精的质量分数为1~10%。
3.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤2）中LAE固体粉末的质量分数为0.5~5%。
4.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤3）中植物精油的体积分数为0.5~5%。
5.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤3）中高速分散的具体条件为在12000-18000 r/min下处理5-15min，超声处理的具体条件为在200-750 W功率下处理5-10 min，或采用高压均质在20-100MPa下处理，1-3个循环，每个阶段持续1分钟。
6.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤4）中喷雾干燥处理的进口温度最高为170℃，出口温度最高为100℃，雾化器转速为20～40 Hz，进料速度为15～30 r/min，根据进料速度调节出口温度。
7.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤5）中复合抗菌剂固体粉末的质量分数为2-7%，可降解材料的质量分数为68-82%，甘油的质量分数为15-20%，硬脂酸的质量分数为1-5%。
8.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤5）中的可降解材料为淀粉、PBAT、PLA、PHB和PCL中的一种或任意多种复合材料。
9.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤5）中双螺杆挤出机熔融区温度设置为80-130℃。
10.根据权利要求1所述的一种LAE和植物精油复合抗菌剂及可降解包装薄膜的制备方法，其特征在于：所述步骤5）中挤压吹塑机熔融区温度设置为80-130℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110658528.8A CN113321852B (zh) | 2021-06-15 | 2021-06-15 | Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110658528.8A CN113321852B (zh) | 2021-06-15 | 2021-06-15 | Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113321852A true CN113321852A (zh) | 2021-08-31 |
| CN113321852B CN113321852B (zh) | 2022-03-25 |
Family
ID=77421224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110658528.8A Active CN113321852B (zh) | 2021-06-15 | 2021-06-15 | Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113321852B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881206A (zh) * | 2021-10-15 | 2022-01-04 | 明新孟诺卡(江苏)新材料有限公司 | 一种具备天然抗菌功能色母粒及其制备工艺 |
| CN115960446A (zh) * | 2022-12-27 | 2023-04-14 | 浙江农林大学 | 一种精油/羧基化纳米纤维素/聚乳酸包装膜的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604343A (zh) * | 2012-02-23 | 2012-07-25 | 江南大学 | 一种具有缓释性能的食品抗菌包装材料及其制备方法 |
-
2021
- 2021-06-15 CN CN202110658528.8A patent/CN113321852B/zh active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604343A (zh) * | 2012-02-23 | 2012-07-25 | 江南大学 | 一种具有缓释性能的食品抗菌包装材料及其制备方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881206A (zh) * | 2021-10-15 | 2022-01-04 | 明新孟诺卡(江苏)新材料有限公司 | 一种具备天然抗菌功能色母粒及其制备工艺 |
| CN115960446A (zh) * | 2022-12-27 | 2023-04-14 | 浙江农林大学 | 一种精油/羧基化纳米纤维素/聚乳酸包装膜的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113321852B (zh) | 2022-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113321852B (zh) | Lae和植物精油复合抗菌剂及可降解包装薄膜制备方法 | |
| CN110591117B (zh) | 一种利用白果壳纤维素稳定的Pickering乳液及其制备方法 | |
| Zhang et al. | Electrospinning of nanofibers: Potentials and perspectives for active food packaging | |
| Vahedikia et al. | Biodegradable zein film composites reinforced with chitosan nanoparticles and cinnamon essential oil: Physical, mechanical, structural and antimicrobial attributes | |
| CN107746499B (zh) | 一种双向拉伸透气膜 | |
| CN102786702B (zh) | 一种控释抗菌膜的制备方法 | |
| CN102504345A (zh) | 一次性使用可控完全降解塑料包装袋及其制备方法 | |
| US11542392B1 (en) | Multifunctional particle additive for enhancement of toughness and degradation in biodegradable polymers | |
| CN105968489A (zh) | 一种聚乙烯抗菌包装薄膜的制备方法 | |
| CN102604343A (zh) | 一种具有缓释性能的食品抗菌包装材料及其制备方法 | |
| CN109082086A (zh) | 一种聚乳酸高透气膜的制备方法 | |
| Cheng et al. | Electrospun polyvinyl alcohol/chitosan nanofibers incorporated with 1, 8-cineole/cyclodextrin inclusion complexes: Characterization, release kinetics and application in strawberry preservation | |
| Chen et al. | Encapsulation of tea polyphenols into high amylose corn starch composite nanofibrous film for active antimicrobial packaging | |
| Marand et al. | Ixiolirion tataricum mucilage/chitosan based antioxidant films activated by free and nanoliposomal fennel essential oil | |
| Bangar et al. | Valorization of wheat straw in food packaging: A source of cellulose | |
| Li et al. | Microfluidic spinning of fucoxanthin-loaded nanofibers for enhancing antioxidation and clarification of fruit juice | |
| CN107325438A (zh) | 一种用于医用包装的聚氯乙烯材料及其制备方法 | |
| GB2608202A (en) | Method for producing low-cost fully biodegradable disposable straw | |
| Zhang et al. | The developments and trends of electrospinning active food packaging: A review and bibliometrics analysis | |
| KR100202097B1 (ko) | 해조류를 이용한 식품가공방법 | |
| Hu et al. | Preparation and characterization of starch/PBAT film containing hydroxypropyl-β-cyclodextrin/ethyl lauroyl arginate/cinnamon essential oil microcapsules and its application in the preservation of strawberry | |
| CN111333918A (zh) | 一种双醛纳米纤维素/麦卢卡蜂蜜抗菌复合薄膜的制备方法 | |
| CN112409643B (zh) | 一种防霉型中药饮品包装袋及其加工方法 | |
| CN109233232A (zh) | 一种制备高阻隔性聚乳酸纳米包装膜的方法 | |
| CN109836739A (zh) | 生物降解pva速溶膜及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230824 Address after: Room J370, 8th Floor, No. 1112 Hanggui Road, Anting Town, Jiading District, Shanghai, 201804 Patentee after: Shanghai Linzhi Intelligent Technology Co.,Ltd. Address before: 210046 No.3, Wenyuan Road, Qixia District, Nanjing City, Jiangsu Province Patentee before: NANJING University OF FINANCE AND ECONOMICS |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231029 Address after: A05, Huanpu Economic Industrial Park, No. 1, Huandong Main Road, Dongli Free Trade Zone (Airport Economic Zone), Tianjin, 300000 Patentee after: Tianjin Suxing Material Technology Co.,Ltd. Address before: Room J370, 8th Floor, No. 1112 Hanggui Road, Anting Town, Jiading District, Shanghai, 201804 Patentee before: Shanghai Linzhi Intelligent Technology Co.,Ltd. |