CN113314739B - Transient modeling method for hydrogen circulating pump in fuel cell system - Google Patents

Transient modeling method for hydrogen circulating pump in fuel cell system Download PDF

Info

Publication number
CN113314739B
CN113314739B CN202110514510.0A CN202110514510A CN113314739B CN 113314739 B CN113314739 B CN 113314739B CN 202110514510 A CN202110514510 A CN 202110514510A CN 113314739 B CN113314739 B CN 113314739B
Authority
CN
China
Prior art keywords
circulating pump
hydrogen
hydrogen circulating
outlet pressure
representing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202110514510.0A
Other languages
Chinese (zh)
Other versions
CN113314739A (en
Inventor
焦魁
杨子俊
杨子荣
王博文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin University
Original Assignee
Tianjin University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin University filed Critical Tianjin University
Priority to CN202110514510.0A priority Critical patent/CN113314739B/en
Publication of CN113314739A publication Critical patent/CN113314739A/en
Application granted granted Critical
Publication of CN113314739B publication Critical patent/CN113314739B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04305Modeling, demonstration models of fuel cells, e.g. for training purposes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a transient modeling method of a hydrogen circulating pump in a fuel cell system, which comprises the steps of fitting a model based on a polynomial regression method to obtain a relation function of the flow rate, the rotating speed and the outlet pressure of the hydrogen circulating pump, then coupling an inertia link of a driving motor to construct a complete transient centrifugal hydrogen circulating pump model, finally carrying out PID control on the control voltage of the driving motor, coupling and calculating the three models to obtain the transient response of the hydrogen circulating pump, and controlling the hydrogen circulating pump to meet the tail gas recovery requirement of a fuel cell stack, thereby achieving the purpose of controlling the hydrogen circulating pump. The model obviously improves the calculation rate on the premise of ensuring the simulation accuracy, can be used for calculating the working condition of the fuel cell stack under a steady state, can simulate and calculate the real-time transient response of the stack under the actual road working condition when the load is changed, can better perform linkage simulation with a fuel cell system, and has important significance for optimizing the control strategy of the fuel cell system.

Description

Transient modeling method for hydrogen circulating pump in fuel cell system
Technical Field
The invention belongs to the field of fuel cells, and particularly relates to a transient modeling method for a hydrogen circulating pump in a proton exchange membrane fuel cell.
Background
The negative impact of air quality has been an international urgent problem for decades, with motor vehicle exhaust pollution representing a significant proportion. In order to improve the air quality of cities, proton exchange membrane fuel cells attract the attention of many countries, and have the remarkable characteristics of zero greenhouse gas emission, fast load response, high energy conversion efficiency, silence, low working temperature and the like, so that fuel cell automobiles become an important direction for the development of new energy automobiles.
The fuel used by the fuel cell vehicle is derived from hydrogen stored in a high-pressure hydrogen tank. If the amount of hydrogen supplied by the vehicle fuel cell is reduced or even short of the amount of hydrogen supplied, irreversible damage and performance degradation may occur to the stack. Thus, a certain inventory of hydrogen must be maintained to maintain stack operation, but if a hydrogen recovery subsystem is not provided, unreacted hydrogen is vented directly to the environment. Besides increasing the use cost and reducing the endurance mileage, the fuel waste is critical to safety issues. In addition, for better performance, the hydrogen gas at the anode inlet of the stack often needs to be humidified, while the humidifier increases the volume and cost of the system, and the liquid water remaining in the humidifier freezes below zero, which affects the cold start speed of the fuel cell. If a hydrogen circulation pump is used in the fuel cell system, the above two problems can be effectively solved. The hydrogen circulating pump can send unreacted hydrogen at the anode outlet and steam back to the manifold of the supply system, and the unreacted hydrogen and the steam are mixed with the hydrogen supplied by the hydrogen tank and enter the cell stack again, so that the utilization rate of fuel is improved, and the function of humidifying the hydrogen is also realized.
The performance and the service life of the fuel cell can be improved by using the hydrogen circulating pump, but various complex problems occur in the specific using process, if the experiment research result is obtained by adopting a mathematical modeling method, the result is undoubtedly required by the industry, the research and development cost can be greatly reduced, and the actual problems can be predicted.
Disclosure of Invention
The invention aims to provide a transient modeling method of a centrifugal hydrogen circulating pump in a proton exchange membrane fuel cell system. The relation among the flow rate, the rotating speed and the outlet pressure of the centrifugal hydrogen circulating pump is fitted by adopting a polynomial regression method, then the inertia link of the driving motor is coupled, a transient centrifugal hydrogen circulating pump model is constructed, and finally the control voltage of the driving motor is subjected to proportional-integral-derivative control (PID) control, so that the aim of controlling the hydrogen circulating pump is fulfilled.
The technical scheme of the method is as follows: and establishing a relation model comprising the volume flow, the rotating speed and the outlet pressure of the hydrogen circulating pump, an inertia link model of the driving motor and a PID control model for controlling the voltage of the driving motor, coupling and calculating the three models to obtain the transient response of the hydrogen circulating pump, and controlling the hydrogen circulating pump to meet the tail gas recovery requirement of the fuel cell stack. The specific steps for establishing each model are as follows:
(1) establishing a relation model of volume flow, rotating speed and outlet pressure of the hydrogen circulating pump
Firstly, fitting a characteristic curve of a hydrogen circulating pump, and correcting the volume flow of gas at an inlet of the hydrogen circulating pump and the angular speed and the rotating speed of a rotor according to the following temperature and pressure:
Figure BDA0003055544890000021
wherein, Wbc、ωbcAnd NbcRespectively, the corrected volume flow, angular velocity and rotational speed, Wbl、ωblAnd NblRepresenting the actual volume flow, angular velocity and rotational speed, TinAnd PinIndicating the temperature and pressure, T, of the inlet gasrefAnd PrefRepresenting a reference temperature and pressure.
In order to improve the accuracy of data fitting, data normalization processing is performed on sample points in the characteristic curve of the disclosed (literature) hydrogen circulation pump as follows:
Figure BDA0003055544890000022
wherein x and y represent the rotational speed and the volume flow rate after data normalization processing, muNAnd muWRepresenting the mean value, σ, of the rotational speed and the volume flow of the sample pointNAnd σWThe standard deviation of the rotational speed and the volume flow at the sample point is indicated.
Based on sample points in a characteristic curve of the hydrogen circulating pump, fitting the relationship among the volume flow, the rotating speed and the outlet pressure of the hydrogen circulating pump by using a binary quadratic polynomial, wherein the relationship is as follows:
Pout=a0+a1x+a2y+a3x2+a4xy+a5y2 (1-3)
wherein, PoutRepresents the outlet pressure of the hydrogen circulation pump, a0,a1,a2,a3,a4,a5Respectively, represent polynomial fitting coefficients.
(2) Constructing an inertia link model of a driving motor
The inertia link calculation expression of the hydrogen circulating pump is as follows:
Figure BDA0003055544890000023
wherein, ω isblRepresenting the angular velocity of the rotor, t representing time, JblRepresenting the moment of inertia, tau, of the rotor part of the hydrogen circulation pumpbmRepresenting the driving torque, tau, of the driving motorblThe load torque of the hydrogen circulation pump is indicated.
The drive torque calculation expression of the drive motor is as follows:
Figure BDA0003055544890000024
wherein eta isbmIndicating the efficiency of the drive motor, RbmDenotes the drive motor resistance, κtDenotes the moment constant, κ, of the drive motorvRepresenting the voltage constant, v, of the drive motorbmIndicating the control voltage, omega, of the drive motorblRepresenting the angular velocity of the rotor.
The calculation expression of the load moment of the hydrogen circulating pump is as follows:
Figure BDA0003055544890000031
Figure BDA0003055544890000032
wherein p isblRepresents the power of the hydrogen circulation pump, cp,inDenotes the specific heat capacity at constant pressure, T, of the inlet gasinIndicating the temperature, η, of the intake airblIndicates the efficiency of the hydrogen circulation pump, Pout、PinRespectively representing the pressure at the outlet and inlet of the hydrogen circulation pump, gammag,inDenotes the specific heat ratio coefficient of the inlet gas, minRepresenting the mass flow of the inlet gas.
The calculation expression of the constant pressure specific heat capacity and specific heat ratio coefficient of the inlet gas is as follows:
Figure BDA0003055544890000036
Figure BDA0003055544890000037
wherein,
Figure BDA0003055544890000038
cp,vand
Figure BDA0003055544890000039
respectively represent the specific heat capacity at constant pressure of hydrogen, water vapor and nitrogen,
Figure BDA00030555448900000310
γvand
Figure BDA00030555448900000311
respectively represent specific heat ratio coefficients of hydrogen, water vapor and nitrogen,
Figure BDA00030555448900000312
yv,inand
Figure BDA00030555448900000313
respectively representing the mass fractions of hydrogen, water vapor and nitrogen in the inlet gas.
The calculation expression of the outlet gas temperature after being compressed by the hydrogen circulating pump is as follows:
Figure BDA0003055544890000033
wherein, ToutIndicating the temperature of the outlet gas.
(3) PID control model for constructing control voltage of driving motor
When the rotating speed of the hydrogen circulating pump is stable, the driving torque is equal to the load torque of the hydrogen circulating pump, then the stable control voltage of the driving motor is solved, and the calculation expression is as follows:
Figure BDA0003055544890000034
and comparing the actual outlet pressure with the target outlet pressure, and taking the difference value of the actual outlet pressure and the target outlet pressure as the deviation amount of PID control, thereby calculating the variation of the control voltage:
e(t)=Ptar-Pout (3-2)
Figure BDA0003055544890000035
vbm,new=vbm+u(t) (3-4)
wherein, PtarAnd PoutRespectively representing target and actual outlet pressures, e (t) representing the deviation, Kp、KI、KDRespectively representing proportional, integral and differential coefficients, u (t) representing the variation of the control voltage, vbm,newAnd represents the control voltage of the driving motor after PID control.
Correcting the volume flow of the inlet of the hydrogen circulating pump and the rotating speed at the current moment, matching with a characteristic curve of the hydrogen circulating pump to obtain the current outlet pressure, comparing the current outlet pressure with the target outlet pressure, taking the difference value of the current outlet pressure and the target outlet pressure as the deviation value of PID control, calculating the variation of the control voltage, obtaining a new rotating speed according to an inertia link model, and finally recalculating in combination with the volume flow of the inlet in such a reciprocating cycle manner to enable the actual outlet pressure to gradually approach or even be equal to the target outlet pressure.
The outlet pressure of the hydrogen circulating pump is determined by the volume flow of the inlet of the hydrogen circulating pump and the rotating speed of the rotor, the rotor of the hydrogen circulating pump is driven by a driving motor, and the rotating speed of the driving motor is determined by control voltage. Therefore, the hydrogen circulation pump transient model needs to be constructed by the three models.
And combining the model (1) and the model (2) to construct a steady-state model of the complete centrifugal hydrogen circulating pump, and then combining the model (3) to construct a transient model of the centrifugal hydrogen circulating pump, wherein the transient model can automatically adjust the rotating speed and control the outlet pressure. The former can calculate the actual stable outlet pressure of the hydrogen circulating pump under the condition of given rotating speed and volume flow, and the latter can automatically update the control voltage of the driving motor through PID control under the condition of given target outlet pressure, so as to adjust the rotating speed of the rotor, and ensure that the actual outlet pressure gradually approaches or even equals to the target outlet pressure.
The invention has the characteristics and beneficial effects that: compared with the traditional three-dimensional complex fluid mechanics analysis model, the constructed transient model of the centrifugal hydrogen circulating pump has the advantages of obvious calculation rate on the premise of ensuring the simulation accuracy, and overcomes the defects that the three-dimensional model has excessive parameters and can not be coupled into a reactor system to perform multi-component multi-subsystem combined simulation and real-time simulation. The constructed model can be used for calculating the working condition of the fuel cell stack under a steady state, and can simulate and calculate the real-time transient response of the stack under the actual road working condition when the load is changed, so that the authenticity of system level simulation is improved, and the model has wide applicability. The model can also respond to different electric pile control strategies, further optimize the control strategy of the fuel supply subsystem, effectively reduce the bench test cost in the electric pile research and development process, and has important scientific significance and economic value.
Drawings
Fig. 1 is a characteristic diagram of a centrifugal hydrogen circulation pump disclosed in the literature.
Fig. 2 is a flow diagram of a centrifugal hydrogen circulation pump control of the present invention.
FIG. 3 is the result of a binary quadratic polynomial fit of the present invention.
FIG. 4 is a performance representation of the hydrogen circulation pump model of the present invention under a PID control strategy.
FIG. 5 is a graph of the performance of the hydrogen circulation pump model of the present invention under the optimized PID control strategy.
Detailed Description
The modeling process of the present invention is further described by the following specific examples, which should be noted that the present calculation examples are illustrative and not limiting, and the scope of the present invention is not limited thereby.
A transient modeling method for hydrogen circulating pump in fuel cell system includes correcting volume flow at inlet of hydrogen circulating pump and rotation speed at current time, matching with characteristic curve of hydrogen circulating pump to obtain current outlet pressure, comparing with target outlet pressure, using difference value of two as deviation value of PID control to calculate variation of control voltage, obtaining new rotation speed according to inertial link model, and recalculating by combining with volume flow at inlet so as to make actual outlet pressure gradually approach or even equal to target outlet pressure.
The hydrogen circulating pump is a centrifugal hydrogen circulating pump. The PID control refers to proportional integral derivative control.
The examples relate to the following main parameters:
parameters of the centrifugal hydrogen circulating pump: the moment of inertia is 2.6 multiplied by 10-3kg m2Constant of driving motor kt、κv0.15N/mA and 0.15V/(rad/s) respectively, and the efficiency eta of the driving motorbmIs 0.9, the hydrogen circulation pump efficiency etablIs 0.8, motor armature resistance RbmIs 0.82 omega.
The inlet temperature of the hydrogen circulating pump is 343.15K, the inlet pressure is 0.9bar, and the inlet flow is 7.59m3H, hydrogen concentration, water vapor concentration and nitrogen concentration of the feed gas were 44.26mol/m, respectively3、9.00mol/m3And 0, the mass fraction of hydrogen, the mass fraction of water vapor and the mass fraction of nitrogen of the feed gas were 0.3551, 0.6449 and 0, respectively.
The specific heat capacity at constant pressure of hydrogen was 14283J/kg/K, the specific heat capacity at constant pressure of steam was 1867J/kg/K, and the specific heat capacity at constant pressure of nitrogen was 1038J/kg/K.
The specific heat ratio coefficient of hydrogen was 1.4378, that of water vapor was 1.3519, and that of nitrogen was 1.4008.
The current rotational speed of the drive motor is 4000 RPM.
The response process of the steady-state model of the hydrogen circulation pump in a time step when the target outlet pressure of the hydrogen circulation pump is changed from 1bar to 1.5bar is taken as an example.
Firstly, temperature and pressure correction needs to be carried out on the volume flow of gas at the inlet of the hydrogen circulating pump and the angular speed and the rotating speed of the rotor:
Figure BDA0003055544890000051
Wbc(m3 h-1) And Wbl(m3 h-1) Indicating the corrected and actual volume flow, ωbc(rad s-1) And ωbl(rad s-1) Representing corrected and actual angular velocity, Nbc(RPM) and Nbl(RPM) represents the corrected and actual volumetric flow rate speed, Tin(K) And Pin(bar) represents the temperature and pressure of the inlet gas, reference temperature Tref288K, reference pressure Pref=1bar。
And then calculating the outlet pressure of the hydrogen circulation pump at the current moment, fitting a characteristic curve graph of the hydrogen circulation pump before the outlet pressure, extracting sample points in the graph 1, constructing a model in a Python 3.7.9 programming environment, and fitting by using a scimit-learn library, wherein the fitting result is shown in FIG. 3. First, data normalization processing is performed on sample points as follows:
Figure BDA0003055544890000061
a characteristic diagram of the hydrogen circulation pump can be obtained from the published article, as shown in fig. 1. x and y represent the rotation speed and volume flow after data normalization, and the average value mu of the rotation speed of the sample pointN3714.285PRM, mean value of sample point volume flow, μW=7.032m3H, standard deviation σ of sample point rotational speedN1030.158, standard deviation σ of sample point volume flowW=4.394。
Fitting the relationship among the volume flow, the rotating speed and the outlet pressure of the hydrogen circulating pump by using a binary quadratic polynomial, wherein the relationship is as follows:
Pout=a0+a1x+a2y+a3x2+a4xy+a5y2
wherein, Pout(bar) represents the outlet pressure of the hydrogen circulation pump, a0,a1,a2,a3,a4,a5Respectively, the polynomial fitting coefficients are shown, and the values of the coefficients are shown in the following table. The coefficient of certainty of the fit results is 0.9923, which indicates that the fit between the fit results and the sample points is better (as shown in fig. 3).
Parameter(s) a0 a1 a2 a3 a4 a5
Numerical value 1.4271 0.3671 0.4356 0.0588 0.1272 0.0745
(2) Inertia link of driving motor
Calculated by a correction formula, the corrected volume flow Wbc=9.21m3H, corrected angular velocity ωbc383.74rad/s, corrected speed Nbc3664.50 RPM. And then, substituting the pressure into a polynomial equation to obtain the outlet pressure of the hydrogen circulation pump at the current moment as 1.215 bar.
The calculation expression of the constant pressure specific heat capacity and specific heat ratio coefficient of the inlet gas is as follows:
Figure BDA0003055544890000062
Figure BDA0003055544890000063
wherein,
Figure BDA0003055544890000064
cp,v(J kg-1K-1) And
Figure BDA0003055544890000065
respectively represent the specific heat capacity at constant pressure of hydrogen, water vapor and nitrogen,
Figure BDA0003055544890000068
γvand
Figure BDA0003055544890000069
respectively represent specific heat ratio coefficients of hydrogen, water vapor and nitrogen,
Figure BDA0003055544890000067
yv,inand
Figure BDA0003055544890000066
respectively representing the mass fractions of hydrogen, water vapor and nitrogen in the inlet gas.
The constant pressure specific heat capacity c of the inlet gas can be calculated through known conditionsp,in6275.93J/kg/K, specific heat ratio coefficient gamma of inlet gasg,in=1.3824。
The calculation expression of the hydrogen circulation pump power is as follows:
Figure BDA0003055544890000071
pbl(W) represents the power of the hydrogen circulation pump, cp,in(J kg-1K-1) Denotes the specific heat capacity at constant pressure, T, of the inlet gasin(K) Indicating the temperature, η, of the intake airblIndicates the efficiency of the hydrogen circulation pump, Pout(bar)、Pin(bar) represents the pressure at the outlet and inlet of the hydrogen circulation pump, respectively, gammag,inDenotes the specific heat ratio coefficient of the inlet gas, min(kg s-1) represents the mass flow rate of the inlet gas.
When the rotating speed of the hydrogen circulating pump is stable, the driving torque is equal to the load torque of the hydrogen circulating pump, then the stable control voltage of the driving motor is solved, and the calculation expression is as follows:
Figure BDA0003055544890000072
the mass flow m of the inlet gas can be calculated by knowing the conditionsin=5.30×10-4kg/s, power p of the hydrogen circulation pumpbl123.57W, control voltage v of the drive motorbm=64.62V。
(3) PID control and transient response
A schematic diagram of the hydrogen circulation pump control scheme is shown in fig. 2. And comparing the actual outlet pressure with the target outlet pressure, and taking the difference value of the actual outlet pressure and the target outlet pressure as the deviation amount of PID control, thereby calculating the variation of the control voltage:
e(t)=Ptar-Pout
Figure BDA0003055544890000073
vbm,new=vbm+u(t)
Ptar(bar) and Pout(bar) represents the target outlet pressure and the actual outlet pressure, respectively, e (t), (t) represents the deviation, u (t) (V) represents the variation of the control voltage, v (v) represents the variation of the control voltagebm,newAnd (V) represents the drive motor control voltage after PID control. In this example, the proportionality coefficient Kp2.842, integral coefficient KI232.770, the differential coefficient KD=1.854。
The set of coefficients is optimized. If a default value is used, e.g. Kp=KI=KDThe control effect is shown in fig. 4 as 1. It can be seen that under the condition of using the set of coefficients, the time for the outlet pressure of the hydrogen circulating pump to reach the target pressure is long, and the fluctuation is large, so that the use of the hydrogen circulating pump is not facilitated. The control effect of the optimized coefficient on the hydrogen circulating pump is shown in figure 5, compared with figure 4, the time for the outlet pressure of the hydrogen circulating pump to reach the target pressure is greatly shortened, and the vibration is hardly generated, so that the aim of efficiently controlling the hydrogen circulating pump is fulfilled.
The deviation e (t) is 0.285V, the change u (t) of the control voltage is +12.72V, and the drive motor control voltage V after PID control can be calculated under known conditionsbm,new=77.34V。
The drive torque calculation expression of the drive motor is as follows:
Figure BDA0003055544890000081
τbm(N m) represents a driving torque, η, of the driving motorbmIndicating the efficiency of the drive motor, Rbm(Ω) represents a drive motor resistance, κtDenotes the moment constant, κ, of the drive motorvRepresenting the voltage constant, v, of the drive motorbm(V) represents driveControl voltage, omega, of the motorbl(rad s-1) Representing the angular velocity of the rotor.
The calculation expression of the load moment of the hydrogen circulating pump is as follows:
Figure BDA0003055544890000082
τbl(N m) represents the load moment, p, of the hydrogen circulation pumpbl(W) represents the power of the hydrogen circulation pump, ωbl(rad s-1) denotes the actual angular velocity.
The driving torque tau of the driving motor after PID control can be calculated through known conditionsbm2.388N m, hydrogen circulation pump load torque τ at the present timebl=0.295N m。
The inertia link calculation expression of the hydrogen circulating pump is as follows:
Figure BDA0003055544890000083
ωbl(rad s-1) Representing the angular velocity of the rotor, t(s) representing time, Jbl(kg m2) The moment of inertia of the rotor part of the hydrogen circulation pump is shown.
Through the above formula and known conditions, the new rotor angular velocity ω after PID control can be calculatedbl,new499.38rad/s new rotor speed Nbl=4768.71RPM。
And finally, substituting the rotor rotating speed and the air inlet flow at the current moment into a correction expression and a relational expression of volume flow, rotating speed and outlet pressure, so that the outlet pressure of the hydrogen circulating pump at the current moment is 1.447bar, the difference between the outlet pressure and the target pressure is 1.5bar and 0.053bar, the outlet pressure at the previous moment is 1.215bar, and the difference between the outlet pressure and the target pressure is 0.285 bar. Therefore, after the optimization control of the PID, the difference between the outlet pressure of the hydrogen circulating pump and the target pressure is rapidly reduced.
After that, the above steps are continuously circulated, so that the outlet pressure of the hydrogen circulating pump gradually approaches or even equals to the target pressure.

Claims (3)

1. The transient modeling method of the hydrogen circulating pump in the fuel cell system is characterized in that: establishing a relation model comprising the volume flow, the rotating speed and the outlet pressure of the hydrogen circulating pump, an inertia link model of the driving motor and a PID control model for controlling the voltage of the driving motor, performing coupling calculation on the three models to obtain the transient response of the hydrogen circulating pump, and controlling the hydrogen circulating pump to meet the tail gas recovery requirement of the fuel cell stack, wherein the specific steps of establishing each model are as follows:
(1) establishing a relation model of volume flow, rotating speed and outlet pressure of the hydrogen circulating pump
Firstly, fitting a characteristic curve of a hydrogen circulating pump, and correcting the volume flow of gas at an inlet of the hydrogen circulating pump and the angular speed and the rotating speed of a rotor according to the following temperature and pressure:
Figure FDA0003055544880000011
wherein, Wbc、ωbcAnd NbcRespectively, the corrected volume flow, angular velocity and rotational speed, Wbl、ωblAnd NblRepresenting the actual volume flow, angular velocity and rotational speed, TinAnd PinIndicating the temperature and pressure, T, of the inlet gasrefAnd PrefWhich represents a reference temperature and pressure,
in order to improve the accuracy of data fitting, the data standardization process is performed on the sample points in the characteristic curve of the disclosed hydrogen circulation pump, as follows:
Figure FDA0003055544880000012
wherein x and y represent the rotational speed and the volume flow rate after data normalization processing, muNAnd muWRepresenting the mean value, σ, of the rotational speed and the volume flow of the sample pointNAnd σWRepresenting a sampleThe standard deviation of the rotational speed and the volume flow of a point,
based on sample points in a characteristic curve of the hydrogen circulating pump, fitting the relationship among the volume flow, the rotating speed and the outlet pressure of the hydrogen circulating pump by using a binary quadratic polynomial, wherein the relationship is as follows:
Pout=a0+a1x+a2y+a3x2+a4xy+a5y2 (1-3)
wherein, PoutRepresents the outlet pressure of the hydrogen circulation pump, a0,a1,a2,a3,a4,a5Respectively representing polynomial fitting coefficients;
(2) constructing an inertia link model of a driving motor
The inertia link calculation expression of the hydrogen circulating pump is as follows:
Figure FDA0003055544880000013
wherein, ω isblRepresenting the angular velocity of the rotor, t representing time, JblRepresenting the moment of inertia, tau, of the rotor part of the hydrogen circulation pumpbmRepresenting the driving torque, tau, of the driving motorblThe load torque of the hydrogen circulation pump is indicated,
the drive torque calculation expression of the drive motor is as follows:
Figure FDA0003055544880000021
wherein eta isbmIndicating the efficiency of the drive motor, RbmDenotes the drive motor resistance, κtDenotes the moment constant, κ, of the drive motorvRepresenting the voltage constant, v, of the drive motorbmIndicating the control voltage, omega, of the drive motorblWhich is indicative of the angular velocity of the rotor,
the calculation expression of the load moment of the hydrogen circulating pump is as follows:
Figure FDA0003055544880000022
Figure FDA0003055544880000023
wherein p isblRepresents the power of the hydrogen circulation pump, cp,inDenotes the specific heat capacity at constant pressure, T, of the inlet gasinIndicating the temperature, η, of the intake airblIndicates the efficiency of the hydrogen circulation pump, Pout、PinRespectively representing the pressure at the outlet and inlet of the hydrogen circulation pump, gammag,inDenotes the specific heat ratio coefficient of the inlet gas, minWhich represents the mass flow rate of the inlet gas,
the calculation expression of the constant pressure specific heat capacity and specific heat ratio coefficient of the inlet gas is as follows:
Figure FDA0003055544880000024
Figure FDA0003055544880000025
wherein,
Figure FDA0003055544880000026
cp,vand
Figure FDA0003055544880000027
respectively represent the specific heat capacity at constant pressure of hydrogen, water vapor and nitrogen,
Figure FDA0003055544880000028
γvand
Figure FDA0003055544880000029
respectively represent hydrogen and waterThe specific heat ratio coefficient of the vapor and the nitrogen,
Figure FDA00030555448800000210
yv,inand
Figure FDA00030555448800000211
respectively represents the mass fractions of hydrogen, water vapor and nitrogen in the inlet gas,
the calculation expression of the outlet gas temperature after being compressed by the hydrogen circulating pump is as follows:
Figure FDA00030555448800000212
wherein, ToutWhich is indicative of the temperature of the outlet gas,
(3) PID control model for constructing control voltage of driving motor
When the rotating speed of the hydrogen circulating pump is stable, the driving torque is equal to the load torque of the hydrogen circulating pump, then the stable control voltage of the driving motor is solved, and the calculation expression is as follows:
Figure FDA00030555448800000213
and comparing the actual outlet pressure with the target outlet pressure, and taking the difference value of the actual outlet pressure and the target outlet pressure as the deviation amount of PID control, thereby calculating the variation of the control voltage:
e(t)=Ptar-Pout (3-2)
Figure FDA0003055544880000031
vbm,new=vbm+u(t) (3-4)
wherein, PtarAnd PoutAre respectively provided withRepresenting target and actual outlet pressures, e (t) representing the deviation, Kp、KI、KDRespectively representing proportional, integral and differential coefficients, u (t) representing the variation of the control voltage, vbm,newThe control voltage of the driving motor after PID control is represented;
correcting the volume flow of the inlet of the hydrogen circulating pump and the rotating speed at the current moment, matching with a characteristic curve of the hydrogen circulating pump to obtain the current outlet pressure, comparing the current outlet pressure with the target outlet pressure, taking the difference value of the current outlet pressure and the target outlet pressure as the deviation value of PID control, calculating the variation of the control voltage, obtaining a new rotating speed according to an inertia link model, and finally recalculating in combination with the volume flow of the inlet in such a reciprocating cycle manner to enable the actual outlet pressure to gradually approach or even be equal to the target outlet pressure.
2. The transient modeling method for a hydrogen circulation pump in a fuel cell system according to claim 1, characterized in that: the hydrogen circulating pump is a centrifugal hydrogen circulating pump.
3. The transient modeling method for a hydrogen circulation pump in a fuel cell system according to claim 1, characterized in that: the PID control refers to proportional integral derivative control.
CN202110514510.0A 2021-05-08 2021-05-08 Transient modeling method for hydrogen circulating pump in fuel cell system Active CN113314739B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110514510.0A CN113314739B (en) 2021-05-08 2021-05-08 Transient modeling method for hydrogen circulating pump in fuel cell system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110514510.0A CN113314739B (en) 2021-05-08 2021-05-08 Transient modeling method for hydrogen circulating pump in fuel cell system

Publications (2)

Publication Number Publication Date
CN113314739A CN113314739A (en) 2021-08-27
CN113314739B true CN113314739B (en) 2021-12-24

Family

ID=77373023

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110514510.0A Active CN113314739B (en) 2021-05-08 2021-05-08 Transient modeling method for hydrogen circulating pump in fuel cell system

Country Status (1)

Country Link
CN (1) CN113314739B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114218813B (en) * 2022-02-18 2022-05-17 中国汽车技术研究中心有限公司 Fuel cell flow resistance function construction method and flow resistance value prediction method
CN114744254A (en) * 2022-04-28 2022-07-12 武汉雄韬氢雄燃料电池科技有限公司 Modeling method of hydrogen circulating pump in fuel cell system
CN116525879B (en) * 2023-04-19 2024-02-02 江苏申氢宸科技有限公司 High-power fuel cell hydrogen supply circulation system and method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848351A (en) * 2016-12-26 2017-06-13 天津大学 The method that proton exchange film fuel battery performance forecast model is set up
CN106951677A (en) * 2017-02-20 2017-07-14 天津大学 The method that Proton Exchange Membrane Fuel Cells transient process model is set up
CN111613815A (en) * 2020-05-26 2020-09-01 东风汽车集团有限公司 Fuel cell hydrogen circulation system and control method thereof
CN112635802A (en) * 2020-12-24 2021-04-09 海卓动力(青岛)能源科技有限公司 Hydrogen control method for vehicle proton exchange membrane fuel cell system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106848351A (en) * 2016-12-26 2017-06-13 天津大学 The method that proton exchange film fuel battery performance forecast model is set up
CN106951677A (en) * 2017-02-20 2017-07-14 天津大学 The method that Proton Exchange Membrane Fuel Cells transient process model is set up
CN111613815A (en) * 2020-05-26 2020-09-01 东风汽车集团有限公司 Fuel cell hydrogen circulation system and control method thereof
CN112635802A (en) * 2020-12-24 2021-04-09 海卓动力(青岛)能源科技有限公司 Hydrogen control method for vehicle proton exchange membrane fuel cell system

Also Published As

Publication number Publication date
CN113314739A (en) 2021-08-27

Similar Documents

Publication Publication Date Title
CN113314739B (en) Transient modeling method for hydrogen circulating pump in fuel cell system
CN109145363B (en) Transient modeling method for centrifugal air compressor in fuel cell system
CN109524693B (en) Model predictive control method for fuel cell air supply system
CN111403783B (en) Decoupling control method for fuel cell air inlet system
CN110970642A (en) Air system control method of fuel cell
CN111584906B (en) Fuel supply method of fuel cell system based on deep reinforcement learning
CN109815644A (en) Fuel battery engines gas handling system control method based on map and Linear-Quadratic Problem
RU2692464C1 (en) Fuel cell system and method of controlling fuel cell system
CN116111144B (en) Modeling method of hydrogen circulating pump in fuel cell system
CN113221373B (en) Method and system for optimizing circulating water cold-end system configured with multiple mechanical ventilation cooling towers
CN113571747B (en) Fuel cell air system control method
CN113140765A (en) Fuel cell air inlet flow and pressure decoupling control method and system
CN112670539A (en) Method for accurately obtaining relation between output current and output power of fuel cell system
CN114857061B (en) Modeling and multi-target control method for aviation fuel cell air supply system
CN111628196A (en) Air system control method of fuel cell
Chen et al. Efficiency improvement and Thermo-economic analysis of proton exchange membrane fuel cell system with energy recovery for both air and hydrogen
CN212011145U (en) Fuel cell with decoupling control
CN114759229A (en) Fuel cell control system
CN114725433A (en) Feeding control method of proton exchange membrane hydrogen fuel cell power system
CN117725700A (en) System, method and equipment for managing split-axis gas turbine based on digital twin technology
CN108119387A (en) Modeling and flow control methods of a kind of high speed compressor under And of Varying Depth
CN110212216A (en) Fuel cell peroxide with stochastic prediction function is than control method and system
CN113775424B (en) EGR control method and device and electronic equipment
Hasegawa et al. Modeling of the dynamic behavior of an integrated fuel cell system including fuel cell stack, air system, hydrogen system, and cooling system
Wang et al. Air Feeding Adaptive Backstepping Sliding Mode Control for Automotive Fuel Cell System

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant