CN113308310B - Wax removing water composition, application and preparation method thereof - Google Patents
Wax removing water composition, application and preparation method thereof Download PDFInfo
- Publication number
- CN113308310B CN113308310B CN202110551781.3A CN202110551781A CN113308310B CN 113308310 B CN113308310 B CN 113308310B CN 202110551781 A CN202110551781 A CN 202110551781A CN 113308310 B CN113308310 B CN 113308310B
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- Prior art keywords
- wax
- water composition
- removing water
- cleaning
- composition
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims abstract description 6
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- 238000004140 cleaning Methods 0.000 claims description 39
- 238000004018 waxing Methods 0.000 claims description 16
- 229920005372 Plexiglas® Polymers 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 description 18
- 239000011521 glass Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000005556 hormone Substances 0.000 description 2
- 229940088597 hormone Drugs 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a wax removing water composition, which comprises the following components in parts by weight: 5.0 to 10 parts of fatty acid methyl ester ethyl oxide; 2.5 to 4.5 parts of dimethyl glutarate; 0.5 to 1 part of dimethyl succinate; 84.5 to 92 portions of water. In addition, the invention also discloses application of the wax removing water composition, and the wax removing water composition is used for removing wax on the surface. In addition, the invention also discloses a preparation method of the wax removing composition, which comprises the following steps: mixing fatty acid methyl ester ethyl oxide, dimethyl glutarate and dimethyl succinate with water. Furthermore, the invention also discloses a using method of the wax removing water composition, which comprises the following steps: and (3) coating the wax-removing water composition on the surface of an object to be cleaned, and wiping off the wax-removing water composition after a period of time.
Description
Technical Field
The invention belongs to the technical field of cleaning agents, and particularly relates to a novel wax removing water composition, application and a preparation method thereof.
Background
The application range of the wax is quite wide, and some products need to be protected by surface protection wax before being used by customers so as to prevent the surfaces of the products from being scratched and the like, such as vehicles and the like, in links such as transportation and the like.
For example, in the production of a mold in the manufacturing industry, a release agent is used, and a release agent is usually used mainly in the form of wax and oil, and wax remains on the surface of the product after the release agent is used, and cleaning is required.
Compared with the wax removal products in the current market, some wax removal products contain nonylphenol polyoxyethylene ether (environmental hormone), some wax removal products contain strong alkaline substances and the like, and some wax removal products need to be heated in the preparation process. Some use procedures require the use of ultrasound or the like.
Furthermore, some of the wax-removing surfaces are made of organic glass, and the organic glass belongs to acrylic materials, such as a headlight in a vehicle, but the acrylic materials are easy to react with a plurality of substances, so that the wax-removing effect on the organic glass surfaces in the prior art is not ideal.
For example: the publication number is: CN107761120a, publication date is 2018, 3, 6, and chinese patent literature entitled "a de-waxing water for alloy polished work pieces and a method for producing the same" discloses a de-waxing water for alloy polished work pieces. However, in the technical proposal disclosed in the patent document, the wax removing water also comprises nonanylphenol polyoxyethylene ether, which is very not friendly to the environment.
Also for example: chinese patent document with publication number CN 109370801a, publication date 2019, month 2 and 22, entitled "a method for cleaning wax for glass and bonding wax" discloses a wax-removing water for glass. However, in the technical proposal disclosed in the patent document, the wax removing water is required to be matched with ultrasonic cleaning, and the use and the operation are inconvenient.
For another example: chinese patent publication No. CN 107118854a, publication date 2017, 9, 1, entitled "acidic dewaxed water composition" discloses an acidic dewaxed water composition. However, in the technical solution disclosed in the patent document, since the acid substance is contained, the acid substance is easily in direct contact with a user during use, and is harmful to human health, and adversely affects the skin.
Based on this, it is desirable to have a wax-removing water composition that is simple to prepare, safe to transport and store, and free of volatile organic compounds (VOCs for short).
Disclosure of Invention
In view of the problems and disadvantages of the prior art, it is an object of the present invention to provide a wax removal water composition, use and method of making the same. The wax removing water composition is simple to prepare and adopts a water-based technology; non-inflammable and explosive products, and are safe to transport and store; no VOC is contained, and the environment protection requirement is met; has no pungent smell, is convenient to use, can be directly used for wax, and can be erased. In addition, the wax removing water composition is water based, so that the wax removing water composition can not corrode various materials, such as paint surfaces, leather and the like. In particular, the wax-removing water composition does not corrode the wiped surfaces such as plexiglas.
In order to achieve the above object, the present invention is achieved by:
in a first aspect, the invention provides a wax removing water composition, which comprises the following components in parts by weight:
in the above-mentioned scheme, the fatty acid methyl ester ethyl oxide is set to 5 to 10 parts because: when the content of the fatty acid methyl ester ethyl oxide is too low, the cleaning effect is reduced; when the content of the fatty acid methyl ester ethyl oxide is too high, the lifting effect is not obviously increased, but the material cost is increased.
Preferably, the fatty acid methyl ester ethyl oxide is prepared from CAS 65218-33-7.
Preferably, the wax removing water composition comprises 6-9 parts by weight of fatty acid methyl ester ethyl oxide.
Preferably, the wax removing water composition further comprises dimethyl adipate, and the weight part of the dimethyl adipate is 0.075-0.1 part.
Preferably, the weight part of dimethyl glutarate in the wax removing water composition is 2.5-4 parts.
Preferably, the weight part of the dimethyl succinate in the wax removing water composition is 0.75-1 part.
In a second aspect, the present invention provides the use of a de-waxing water composition as described above for surface de-waxing and cleaning of mould release agents.
Preferably, the surface dewaxing includes large surface (e.g., vehicle surface) dewaxing, metal work piece surface dewaxing, plastic part surface dewaxing, and plexiglass surface dewaxing.
In a third aspect, the present invention provides a method for preparing the wax removing water composition, which comprises the following steps:
mixing fatty acid methyl ester ethyl oxide, dimethyl glutarate and dimethyl succinate with water.
In a fourth aspect, the present invention provides a method for using the wax removing water composition, the method comprising the steps of:
and (3) coating the wax-removing water composition on the surface of an object to be cleaned, and wiping off the wax-removing water composition after a period of time.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention has easy preparation and adopts an aqueous formula, so that the scheme is more friendly to the environment compared with the prior art;
2. the use is convenient, the direct use is realized, and the excellent wax removing effect can be realized without using other cleaning equipment such as an ultrasonic machine;
3. non-inflammable and explosive products, and are safe to store and transport;
4. the paint surface and the organic glass and other materials are not corroded;
5. the product does not contain VOC, and all components are not in the hazardous chemical substance catalogue, thereby meeting the requirements of environmental protection development trend.
6. Compared with the prior art, the ultrasonic wave-free medical instrument does not contain harmful substances such as nonanylphenol polyoxyethylene ether (environmental hormone), strong alkali and the like, so that the ultrasonic wave-free medical instrument does not need to be used during use, and has certain advantages.
7. The preparation is more convenient, heating is not needed, and the wax removing water composition can be obtained at normal temperature.
Drawings
Other features, objects and advantages of the present invention will become more apparent upon reading of the detailed description of non-limiting embodiments, given with reference to the accompanying drawings in which:
FIGS. 1a-1c are photographs of waxing of a clean sample of the wax-removing water composition of example 1, wherein FIG. 1a is a photograph of the sample prior to waxing, and FIG. 1b is a photograph of the sample prior to waxing, and are labeled in blocks for comparison; FIG. 1c is a photograph after cleaning;
FIGS. 2a-2b are photographs of waxing of a cleaning sample piece using the wax-removing water composition of example 2 or 3, wherein FIG. 2a is a photograph before cleaning; FIG. 2b is a photograph after cleaning;
FIGS. 3a-3b are photographs of waxing of a cleaning sample piece using the wax-removing water composition of examples 4 or 5; wherein FIG. 3a is a photograph of a wax-removing water composition using the present patent, and FIG. 3b is a photograph after cleaning;
FIGS. 4a-4c are photographs of the wax-removing water composition of example 1 when cleaning a plexiglass, wherein FIG. 4a shows the tests performed on a plexiglass; FIG. 4b shows a photograph of a wax-removed water composition of example 1 in a plexiglass; FIG. 4c shows the absence of corrosion of the tested plexiglas;
FIGS. 5a-5b are photographs of the wax removal effect of the wax removal water composition of example 6, wherein FIG. 5a is a photograph of the wax removal water composition of the present patent, and FIG. 5b is the effect after cleaning;
fig. 6a-6c show the wax removal effect of the comparative wax remover of comparative examples 1 or 2, wherein fig. 6a is a photograph of the sample before wax-containing cleaning, fig. 6b is a photograph of the sample after cleaning, and fig. 6c is a photograph of the sample after cleaning.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the present invention, but are not intended to limit the invention in any way. It should be noted that variations and modifications could be made by those skilled in the art without departing from the inventive concept. These are all within the scope of the present invention.
TABLE 1 formulation tables for examples 1-6 and comparative examples 1, 2
In examples 1 to 6 and comparative examples 1 to 2 above, the compositions of examples 1 to 5 of the present invention were obtained by mixing the raw materials with water uniformly.
The wax removal effect of examples 1-5 described above may be seen with reference to fig. 1a to 3b. Wherein, FIGS. 1a-c are photographs of the waxing of the cleaning sample piece of the composition of example 1, wherein FIG. 1a is a photograph of the sample piece before the waxing, and FIG. 1b is a photograph of the sample piece before the waxing, and the photographs are marked by a block for comparison; FIG. 1c is a photograph after cleaning, and the cleaning effect is obvious by comparison;
FIGS. 2a-b are photographs of waxing of a cleaning sample piece using the composition of example 2 or 3, wherein FIG. 2a is a photograph prior to cleaning; FIG. 2b is a photograph after cleaning, and the cleaning effect is obvious by comparison;
FIGS. 3a-b are photographs of waxing of a cleaning sample piece using the composition of examples 4 or 5; wherein fig. 3a is a photograph before cleaning, fig. 3b is a photograph after cleaning, and the cleaning effect is obvious by comparison.
Fig. 5a and 5b show the wax removing effect of the wax removing composition of example 6, wherein fig. 5a is a photograph of the wax removing composition of the present patent, and fig. 5b is a cleaning effect, and it can be seen from comparison that example 6 has the wax removing effect, but the effect is slightly weaker than example 2 with a certain wax residue.
Fig. 6a-6c show the wax removal effect of the comparative wax remover of comparative examples 1 or 2, wherein fig. 6a is a photograph of the sample before wax-containing cleaning, fig. 6b is a photograph of the sample after cleaning, and fig. 6c is a photograph of the sample after cleaning. As can be seen from the pictures of fig. 6a-6c, the wax removal effect of comparative examples 1, 2 is significantly inferior to this case, especially the surface restoration of comparative examples 1, 2 is not bright enough compared to example 1, i.e. the cleaning effect is much reduced. In contrast, with the wax remover composition of the present embodiment, the wax layer is removed significantly and the surface is restored to brightness after the wax layer is erased, as can be seen in conjunction with fig. 1c, 2b, 3b, 4c and 5 b.
It should be noted that, the black frame mark positions of the pictures in the drawings of the specification are wax removing areas.
In addition, the wax removal water compositions of examples 1 to 6 may be applied to the following objects: cleaning surface protection wax, wax residue on a workpiece, release agent residue and the like, and wax films or wax residues on various surfaces of an object to be rubbed, such as a vehicle, a metal piece, a plastic piece and the like; residual release agent.
In addition, the technical characteristics of the product of the wax removing water composition of the present invention are shown in the following table 2.
Table 2.
The wax removal water composition of the embodiment of the invention is used for testing on organic glass, and the test results can be referred to fig. 4a to 4c, wherein fig. 4a shows the organic glass appearance before testing, and fig. 4b shows the appearance of the wax removal water composition of the embodiment coated on organic glass; FIG. 4c shows that after a period of time (e.g., 10 minutes) no corrosion phenomena have occurred on the plexiglass.
As is apparent from a combination of fig. 4a to 4c, the wax removal water composition employing the present embodiment does not corrode the organic glass material. It should be pointed out that the organic glass belongs to an acrylic material and is easy to react with other various substances, and the wax removing water composition of the scheme can obviously show that the organic glass does not react with the organic glass.
Furthermore, as can be seen from the use of the above examples, the wax removing water composition of the present invention has the following advantages in use:
1. the cleaning device is very suitable for use environments with larger cleaning areas, and after the cleaning device is used, the surfaces of the articles to be cleaned are bright.
2. The wax removing water composition is convenient and fast to use, and especially cannot be limited by places and the size of articles to be cleaned.
In particular, compared with the prior art, the cleaning mode in the wax removing process is mainly matched with ultrasonic cleaning, and in the use process, the to-be-cleaned object needs to be placed into an ultrasonic machine, however, the ultrasonic machine has size limitation, so that the prior wax removing object has great limitation in cleaning.
The foregoing describes specific embodiments of the present invention. It is to be understood that the invention is not limited to the particular embodiments described above, and that various changes and modifications may be made by one skilled in the art within the scope of the claims without affecting the spirit of the invention.
It should be noted that the prior art part in the protection scope of the present invention is not limited to the embodiments set forth in the present application, and all prior art that does not contradict the scheme of the present invention, including but not limited to the prior patent document, the prior publication, the prior disclosure, the use, etc., can be included in the protection scope of the present invention.
In addition, the combination of the features described in the present application is not limited to the combination described in the claims or the combination described in the embodiments, and all the features described in the present application may be freely combined or combined in any manner unless contradiction occurs between them.
The foregoing describes specific embodiments of the present invention. It is to be understood that the invention is not limited to the particular embodiments described above, and that various changes or modifications may be made by those skilled in the art within the scope of the appended claims without affecting the spirit of the invention. The embodiments of the present application and features in the embodiments may be combined with each other arbitrarily without conflict.
Claims (4)
1. The wax removing water composition is characterized by comprising the following components in parts by weight:
5.0-10 parts of fatty acid methyl ester ethyl oxide;
2.5-4.5 parts of dimethyl glutarate;
0.5-1 part of dimethyl succinate;
84.5-92 parts of water;
the preparation method of the wax removing water composition comprises the following steps:
uniformly mixing fatty acid methyl ester ethyl oxide, dimethyl glutarate and dimethyl succinate with water;
the CAS accession number of the fatty acid methyl ester ethyl oxide is CAS 65218-33-7.
2. Use of the de-waxing water composition according to claim 1, for surface de-waxing and cleaning of mould release agents.
3. The use according to claim 2, wherein the surface dewaxing is one of large surface dewaxing, metal work piece surface dewaxing, plastic part surface dewaxing, plexiglass surface dewaxing.
4. A method of using the wax-removing water composition of claim 1, comprising the steps of:
and (3) coating the wax-removing water composition on the surface of an object to be cleaned, and wiping off the wax-removing water composition after a period of time.
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CN202110551781.3A CN113308310B (en) | 2021-05-20 | 2021-05-20 | Wax removing water composition, application and preparation method thereof |
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CN202110551781.3A CN113308310B (en) | 2021-05-20 | 2021-05-20 | Wax removing water composition, application and preparation method thereof |
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CN113308310B true CN113308310B (en) | 2023-12-19 |
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Citations (4)
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---|---|---|---|---|
CN101517058A (en) * | 2006-09-29 | 2009-08-26 | Ecoholdings有限公司 | Graffiti cleaning solution including a non-aqueous concentrate and diluted aqueous solution |
CN105802582A (en) * | 2016-05-23 | 2016-07-27 | 昆山金城试剂有限公司 | Rare earth grinding fluid |
CN107761115A (en) * | 2017-10-19 | 2018-03-06 | 江门市濠成化工科技有限公司 | A kind of Wax removal water for steel polishing workpiece and preparation method thereof |
CN110684982A (en) * | 2019-11-19 | 2020-01-14 | 上海赛敏环保科技有限公司 | Environment-friendly cleaning agent and preparation method thereof |
-
2021
- 2021-05-20 CN CN202110551781.3A patent/CN113308310B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101517058A (en) * | 2006-09-29 | 2009-08-26 | Ecoholdings有限公司 | Graffiti cleaning solution including a non-aqueous concentrate and diluted aqueous solution |
CN105802582A (en) * | 2016-05-23 | 2016-07-27 | 昆山金城试剂有限公司 | Rare earth grinding fluid |
CN107761115A (en) * | 2017-10-19 | 2018-03-06 | 江门市濠成化工科技有限公司 | A kind of Wax removal water for steel polishing workpiece and preparation method thereof |
CN110684982A (en) * | 2019-11-19 | 2020-01-14 | 上海赛敏环保科技有限公司 | Environment-friendly cleaning agent and preparation method thereof |
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Title |
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脂肪酸甲酯乙氧基化物的合成及其性能研究;刘岢鑫;中国博士学位论文全文数据库工程科技Ⅰ辑;第13-17页 * |
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