CN113307930A - Cold-resistant high-static-stiffness polyurethane microporous elastic base plate - Google Patents
Cold-resistant high-static-stiffness polyurethane microporous elastic base plate Download PDFInfo
- Publication number
- CN113307930A CN113307930A CN202110814037.8A CN202110814037A CN113307930A CN 113307930 A CN113307930 A CN 113307930A CN 202110814037 A CN202110814037 A CN 202110814037A CN 113307930 A CN113307930 A CN 113307930A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- cold
- polyurethane
- polyurethane microporous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention relates to a cold-resistant high-static-stiffness polyurethane microporous elastic base plate, and belongs to the technical field of polyurethane microporous elastomers. The elastic cushion plate is obtained by curing and molding the component A and the component B, and the density of the elastic cushion plate is 650kg/m3～700kg/m3And a polyurethane microporous elastic backing plate with static rigidity (23 +/-2.3) kN/mm under the loading of 1 kN-35 kN, wherein the component A is PTMEG1000, PTMEG2000, EP330, BDO and H2O, AK7703, BDMAE and T12, wherein the component B is a prepolymer with an NCO value of 12-15 formed by stirring and reacting a compound containing-NCO groups with polytetrahydrofuran ether polyol at 80-100 ℃ for 4-6 h, the pressure in micropores in the elastic backing plate is properly increased by optimizing the raw material components and the component content in the elastic backing plate, and the elastic backing plate has good cold resistance on the premise of meeting the use requirements of other indexes such as static rigidity, dynamic-static rigidity ratio and the like, thereby obtaining the high-static-rigidity polyurethane microporous elastic backing plate for the urban railway passenger transport line, which meets the requirements of various indexes.
Description
Technical Field
The invention relates to a cold-resistant high-static-stiffness polyurethane microporous elastic base plate, and belongs to the technical field of polyurethane microporous elastomers.
Background
The polyurethane microporous elastic base plate with a certain shape and size prepared by the die has excellent mechanical properties, wear resistance, fatigue resistance, water resistance, high insulativity, light weight and the like, and is gradually popularized and applied in the field of rail transit. The elastic cushion plate for the urban railway passenger transport line has different requirements on static rigidity according to different actual pressures of specific application places, and under the loading of 1 kN-35 kN, the static rigidity mainly comprises three categories of (23 +/-2.3) kN/mm, (15 +/-1.5) kN/mm and (8 +/-0.8) kN/mm. The elastic base plate for the urban railway passenger transport line with different static stiffness needs to meet the following requirements: under the conditions of long-term circulation under the pressure of 1 kN-35 kN and the circulation strain of 10% -30%, the elastic cushion plate not only passes more than 300 million fatigue tests under the loading condition, but also has the dynamic and static rigidity ratio lower than 1.35 and the service life longer than 6 years, and is required to have better cold resistance, and the static rigidity change rate of the elastic cushion plate is lower than 20% at minus 35 ℃ for 16h so as to meet the use requirements of high-cold regions such as northeast China, Xinjiang and the like. However, the high-performance polyurethane microporous elastic backing plate for the urban railway passenger transport line in China at present almost entirely depends on import, which is mainly because the polyurethane microporous elastic backing plate researched and developed in China emphasizes the performances of rigidity, dynamic-static rigidity ratio, fatigue resistance and the like of the material, the cold resistance of the polyurethane microporous elastic backing plate is difficult to meet the requirements, the volume shrinkage rate of the material is high under the low-temperature condition, the rigidity and the modulus are obviously increased, the elasticity is reduced, the vibration reduction effect of the material in the low-temperature environment is seriously influenced, and the popularization and the use are limited.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a cold-resistant high static rigidity polyurethane microporous elastic cushion plate, which is characterized in that the raw material components and the content of each component of the polyurethane microporous elastic cushion plate are optimized, and on the premise of ensuring that the polyurethane microporous elastic cushion plate meets the use requirements of other indexes such as static rigidity, dynamic and static rigidity ratio and the like, the pressure in micropores in the polyurethane microporous elastic cushion plate is properly increased, so that the volume shrinkage rate of the polyurethane elastic cushion plate at low temperature is reduced, the static rigidity change rate of the polyurethane elastic cushion plate at minus 35 ℃ for 16h is lower than 20%, and the high static rigidity ((23 +/-2.3) kN/mm and 1 kN-35 kN) loaded polyurethane microporous elastic cushion plate for the urban railway passenger transport line meeting the requirements of each index is obtained.
The purpose of the invention is realized by the following technical scheme.
A cold-resistant high-static-stiffness polyurethane microporous elastic backing plate is obtained by curing and molding a component A and a component B, and the density of the elastic backing plate is 650kg/m3～700kg/m3And the static rigidity under the loading of 1 kN-35 kN is (23 +/-2.3) kN/mmThe board meets various index requirements of the elastic backing board for the urban rail passenger transport line.
The component A is prepared by uniformly mixing polyether polyol, a chain extender, a foaming agent, a foam stabilizer and a catalyst; the polyether polyol comprises polytetrahydrofuran ether glycol (PTMEG1000) with a molecular weight of 1000, polytetrahydrofuran ether glycol (PTMEG2000) with a molecular weight of 2000 and polyoxypropylene triol (EP330) with a molecular weight of 5000; the chain extender is 1, 4-Butanediol (BDO); the foaming agent is H2O; the foam stabilizer is AK7703 available from Jiangsu Maisrd; the catalyst comprises bis (dimethylaminoethyl) ether (BDMAE) and dibutyltin dilaurate (T12);
taking the total mass of the raw materials for preparing the component A as 100 parts, the raw materials for preparing the component A and the mass contents of the components are as follows:
the component B is a prepolymer with an NCO value of 12-15 formed by stirring and reacting a compound containing-NCO groups and polytetrahydrofuran ether polyol at the temperature of 80-100 ℃ for 4-6 h.
Component A contains active-H (active H and H in polyol-OH)2The sum of active groups in O) and-NCO groups contained in the component B (the-NCO groups remained after the compound containing the-NCO groups reacts with the polytetrahydrofuran ether polyol) are subjected to quantitative reaction, and the molar ratio of the active groups to the-NCO groups is 1.00: (0.98-1.03), preferably 1.00: (0.99 to 1.01).
Further, preheating the component A to 35 +/-2) DEG C and the component B to 45 +/-2℃, uniformly mixing the preheated component A and the preheated component B, pouring the mixture into a mold preheated to 65 +/-5℃, placing the mold at 65 +/-5℃, curing for 10-15 min, and forming the cold-resistant polyurethane microporous elastic cushion plate with high static rigidity in the mold.
Further, the total mass of the raw materials for preparing the component A is 100 parts, so that the raw materials for preparing the component A and the mass contents of the components are as follows:
further, in the preparation of the component B, the compound containing-NCO groups is diphenylmethane diisocyanate (MDI); the polytetrahydrofuran ether polyol is a mixture of PTMEG1000 and PTMEG2000, and accordingly, the mass ratio of the PTMEG1000 to the PTMEG2000 is more preferably 1.3-1.7: 1.
Further, when the compound containing the-NCO group is MDI and the polytetrahydrofuran ether polyol is a mixture of PTMEG1000 and PTMEG2000, the raw material components for preparing the B component and the mass contents of the components are as follows, based on 100 parts by mass of the total raw materials for preparing the B component:
PTMEG 100025-40 parts
PTMEG 200015-25 parts
40-60 parts of MDI.
Has the advantages that:
(1) according to the invention, by selecting the raw material components for preparing the polyurethane microporous elastic base plate and regulating and controlling the content of each component, on the premise of ensuring that the polyurethane microporous elastic base plate meets the use requirements of other indexes such as static stiffness, dynamic-static stiffness ratio and the like, the pressure in micropores in the polyurethane microporous elastic base plate is properly increased, so that the volume change rate of the polyurethane microporous elastic base plate at low temperature is reduced, and the prepared density is 650kg/m3～700kg/m3And the static rigidity change rate of the polyurethane microporous elastic base plate with the static rigidity of ((23 +/-2.3) kN/mm and the loading of 1 kN-35 kN) is less than 20 percent at the temperature of-35 ℃ for 16h, so that the vibration reduction effect of the polyurethane microporous elastic base plate at low temperature is ensured, and various index requirements used by urban railway passenger lines are met.
(2) In the polyurethane microporous elastic backing plate, the glass transition temperature of the polyurethane elastomer matrix is as low as-66 ℃, so that the phenomenon that the rigidity of the elastic backing plate is obviously increased due to the glass transition phenomenon of macromolecules is avoided at-35 ℃, and only the contraction of the polyurethane elastomer matrix and gas in micropores occurs at low temperature.
(3) In the polyurethane microporous elastic base plate, chemical foaming agent H2CO generated in the preparation process of the polyurethane microporous elastic base plate under the influence of O content2Amount of gas by regulating H2The content of O can properly increase the amount of gas in micropores in the polyurethane elastomer matrix on the premise of not increasing the volume occupied by the gas in the prepared polyurethane micropore elastic cushion plate, thereby increasing the pressure of the gas in the micropores. However, H2Too high an amount of O leads to the formation of CO2The amount of gas is increased, the pressure in the micropores is too high, the walls of the micropores are easy to break through in the gel forming process of the polyurethane elastomer, the closed pore rate is reduced, and the low-temperature volume shrinkage rate of the product is increased; in addition, the hardness and rigidity of the product are increased due to the excessive pressure in the micropores, and the product hardness and rigidity exceed the product performance index range.
(4) In the polyurethane microporous elastic base plate, the foam stabilizer plays the key roles of adjusting the closed pore rate of micropores, adjusting the nucleation number of the micropores and adjusting the uniformity of the sizes of the micropores, and the closed pore rate can reach over 90 percent by regulating and controlling the type and the content of the foam stabilizer. The closed cell rate is reduced due to the low content of the foam stabilizer, and the effect of further improving the closed cell rate is not achieved due to the high content of the foam stabilizer, and other performances can be influenced.
(5) In the polyurethane microporous elastic base plate, the BDMAE catalyst is used for catalyzing-NCO and H2Foaming reaction between O, which reaction releases CO2A gas; the T-12 catalyst is used to catalyze the gel reaction between-NCO and-OH, the reaction product being the bulk of the polyurethane elastomer matrix formed. The foaming and gel reaction rates must be matched to prepare the polyurethane microporous elastic backing plate with proper gas pressure in micropores, proper closed porosity and no defect in appearance. If the gel reaction rate is too high, the average molecular weight of the polyurethane elastomer matrix is increased rapidly, the swelling binding force on the micropores is increased, the growth size of the micropores is affected, the occupied volume of the micropores is reduced, the swelling volume is insufficient, the appearance quality of the product is affected, and the density, elasticity and rigidity of the product are increased. If it isThe foaming reaction rate is relatively high, and CO is generated in unit time2The gas is increased, the strength of the polyurethane elastomer matrix is not enough to restrain the volume expansion of the gas in the micropores, so that the walls of the micropores are cracked, and the closed porosity is reduced; in addition, too much gas forms larger bubbles, which affects the uniformity of the size distribution of the micropores and may even cause a cosmetic defect of dimpling on the upper surface of the product.
Drawings
FIG. 1 is a Scanning Electron Microscope (SEM) image of a high static stiffness polyurethane microporous elastic backing plate prepared in example 1.
Fig. 2 is a scanning electron microscope image of the microporous elastic polyurethane backing prepared in comparative example 2.
Detailed Description
The present invention is further illustrated by the following detailed description, wherein the processes are conventional unless otherwise specified, and the starting materials are commercially available from a public source without further specification.
Example 1
(1) 15 parts of PTMEG1000 (polytetrahydrofuran ether glycol with functionality of 2 and molecular weight of 1000), 51 parts of PTMEG2000 (polytetrahydrofuran ether glycol with functionality of 2 and molecular weight of 2000), 24.4 parts of EP330 (polyoxypropylene triol with functionality of 3 and molecular weight of 5000), 8.3 parts of BDO (1, 4-butanediol), 0.2 part of H2O, 0.951 part of AK7703, 0.13 part of BDMAE (bis (dimethylaminoethyl) ether) and 0.019 part of T-12 (dibutyltin dilaurate) are uniformly mixed to obtain a component A;
mixing 50 parts of MDI (diphenylmethane diisocyanate), 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with an-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine and then are cast into a lockable mould (the mould can be locked, the volume in the mould cavity cannot be influenced by material expansion) preheated to 65 ℃, and the volume of the inner cavity is 868cm3Has a total mass of 607.6g of mixture, placing the mould injected with the mixture at 65 ℃ for curing for 10 minutes, filling the mould after the mixture is expanded and formed, and forming the cold-resistant polyurethane microporous elastic cushion plate with high static rigidity in the mould.
The microstructure of the elastic base plate prepared in the embodiment is characterized, and as can be seen from the SEM photograph in fig. 1, the distribution range of the sizes of the micropores in the prepared elastic base plate is narrow, and the sizes of the micropores are uniform.
Example 2
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.4 parts of EP330, 8.3 parts of BDO and 0.23 part of H2Mixing O, 0.91 part of AK7703, 0.14 part of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine, and then are cast into a lockable mold preheated to 65 ℃, wherein the volume of an inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is filled with the mixture after expansion molding, and the cold-resistant polyurethane microporous elastic cushion plate with high static stiffness is molded in the mold.
Comparative example 1
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.5 parts of EP330, 8.3 parts of BDO and 0.17 part of H2Mixing O, 0.89 part of AK7703, 0.12 part of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine and then are cast into a lockable mould preheated to 65 DEG CIn the instrument, the volume of the inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is filled with the mixture after expansion molding, and the polyurethane microporous elastic cushion plate is molded in the mold.
Comparative example 2
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.4 parts of EP330, 8.3 parts of BDO and 0.26 part of H2Mixing O, 0.87 part of AK7703, 0.15 part of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine, and then are cast into a lockable mold preheated to 65 ℃, wherein the volume of an inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is filled with the mixture after expansion molding, and the polyurethane microporous elastic cushion plate is molded in the mold.
The microstructure of the elastic cushion plate prepared by the comparative example is represented, and as can be seen from the SEM picture in FIG. 2, the size distribution range of the micropores in the prepared elastic cushion plate is wider, the sizes of the micropores are not uniform, and the number of the micropores is obviously more than that of the micropores in the embodiment 1.
Comparative example 3
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.7 parts of EP330, 8.3 parts of BDO and 0.23 part of H2Mixing O, 0.61 part of AK7703, 0.14 part of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are subjected to reactionThe mixture is poured into a lockable mould preheated to 65 ℃ after being uniformly mixed by a double-component polyurethane pouring machine, and the volume of an inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is filled with the mixture after expansion molding, and the polyurethane microporous elastic cushion plate is molded in the mold.
Comparative example 4
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24 parts of EP330, 8.3 parts of BDO and 0.23 part of H2Mixing O, 1.31 parts of AK7703, 0.14 parts of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine, and then are cast into a lockable mold preheated to 65 ℃, wherein the volume of an inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is filled with the mixture after expansion molding, and the polyurethane microporous elastic cushion plate is molded in the mold.
Comparative example 5
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.4 parts of EP330, 8.3 parts of BDO and 0.23 part of H2Mixing O, 0.85 part of AK7703, 0.2 part of BDMAE and 0.02 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine, and then are cast into a lockable mold preheated to 65 ℃, wherein the volume of an inner cavity is 868cm3The mold in (2) was filled with a total mass of 564.2g of the mixture, and the mold filled with the mixture was placed inCuring for 10 minutes at 65 ℃, filling the mold after the mixture is expanded and molded, and molding the polyurethane microporous elastic cushion plate in the mold.
Comparative example 6
(1) 15 parts of PTMEG1000, 51 parts of PTMEG2000, 24.4 parts of EP330, 8.3 parts of BDO and 0.23 part of H2Mixing O, 0.9 part of AK7703, 0.14 part of BDMAE and 0.03 part of T-12 uniformly to obtain a component A;
mixing 50 parts of MDI, 30 parts of PTMEG1000 and 20 parts of PTMEG2000, and stirring and reacting for 4 hours at 85 ℃ under the nitrogen protection atmosphere to obtain a component B with the-NCO value of 13.39;
(2) according to the mol ratio of active-H in the component A to-NCO group in the component B of 1:1, the component A preheated to 35 ℃ and the component B preheated to 45 ℃ are uniformly mixed by a two-component polyurethane casting machine, and then are cast into a lockable mold preheated to 65 ℃, wherein the volume of an inner cavity is 868cm3The mold is filled with the mixture with the total mass of 564.2g, the mold filled with the mixture is placed at 65 ℃ for curing for 10 minutes, the mold is not filled with the mixture after expansion molding, and the polyurethane microporous elastic cushion plate is molded in the mold.
Various performance tests are respectively carried out on the polyurethane microporous elastic base plate prepared in the embodiment and the comparative example according to corresponding standards, and the test results are detailed in table 1; the test method comprises the following steps of density test reference standard GB/T1033.1-2008, tensile strength and elongation at break test reference standard GB/T1040.3-2006, static stiffness test reference standard TB/T3395.1, compression set rate test reference standard GB/T10653 (70 ℃, 22h and 30% compression), load 300 ten thousand times fatigue test reference standard TB/T3395.1 appendix C (23 +/-2 ℃ for 24h, cyclic load 1 kN-35 kN, loading frequency 4Hz +/-1 Hz, and load cycle 3 multiplied by 106Second), the cold resistance test is referred to the standard TB/T3395.1 (-35 ℃, 16h static rigidity change rate), and the closed cell rate test is referred to the standard GB T10799-2008. From the test results in table 1, it can be seen that the high static stiffness polyurethane microporous elastic base plate prepared in examples 1-2 meets various performance index requirements for use in urban rail passenger lines, has good cold resistance, can improve the vibration reduction effect at low temperature, and meets the requirements for use at low temperature.
TABLE 1
In summary, the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (7)
1. A cold-resistant high static rigidity polyurethane micropore elastic backing plate is characterized in that: the elastic cushion plate is obtained by curing and molding the component A and the component B, and the density of the elastic cushion plate is 650kg/m3～700kg/m3And loading a polyurethane microporous elastic cushion plate with static rigidity of (23 +/-2.3) kN/mm under 1 kN-35 kN;
the component A is composed of PTMEG1000, PTMEG2000, EP330, BDO, H2O, AK7703, BDMAE and T12; wherein, the total mass of the raw materials for preparing the component A is 100 parts, and the raw materials for preparing the component A and the mass contents of the components are as follows:
the component B is a prepolymer with an NCO value of 12-15 formed by stirring and reacting a compound containing-NCO groups and polytetrahydrofuran ether polyol at the temperature of 80-100 ℃ for 4-6 h;
the molar ratio of active-H contained in the component A to-NCO contained in the component B is 1.00: (0.98-1.03).
2. The cold-resistant high static stiffness polyurethane microporous elastic backing plate according to claim 1, wherein: the molar ratio of active-H contained in the component A to-NCO contained in the component B is 1.00: (0.99 to 1.01).
3. The cold-resistant high static stiffness polyurethane microporous elastic backing plate according to claim 1, wherein: taking the total mass of the raw materials for preparing the component A as 100 parts, the raw materials for preparing the component A and the mass contents of the components are as follows:
4. the cold-resistant high static stiffness polyurethane microporous elastic backing plate according to claim 1, wherein: in the preparation of the component B, MDI is selected as the compound containing-NCO groups; the polytetrahydrofuran ether polyol is a mixture of PTMEG1000 and PTMEG 2000.
5. The cold-resistant high static stiffness polyurethane microporous elastic backing plate according to claim 4, wherein: when the compound containing-NCO groups is MDI and the polytetrahydrofuran ether polyol is a mixture of PTMEG1000 and PTMEG2000, the raw material components for preparing the component B and the mass contents of the components are as follows, wherein the total mass of the raw materials for preparing the component B is 100 parts:
PTMEG 100025-40 parts
PTMEG 200015-25 parts
40-60 parts of MDI.
6. A cold-resistant high static stiffness polyurethane cellular elastic mat according to claim 4 or 5, characterized in that: when the polytetrahydrofuran ether polyol is a mixture of PTMEG1000 and PTMEG2000, the mass ratio of the PTMEG1000 to the PTMEG2000 is (1.3-1.7): 1.
7. A cold-resistant high static stiffness polyurethane cellular elastic mat according to any one of claims 1 to 5, wherein: preheating the component A to 35 +/-2) DEG C and the component B to 45 +/-2℃, uniformly mixing the preheated component A and the preheated component B, pouring the mixture into a mold preheated to 65 +/-5℃, placing the mold at 65 +/-5℃, curing for 10-15 min, and forming the cold-resistant polyurethane microporous elastic cushion plate with high static stiffness in the mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110814037.8A CN113307930B (en) | 2021-07-19 | 2021-07-19 | Cold-resistant high-static-stiffness polyurethane microporous elastic base plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110814037.8A CN113307930B (en) | 2021-07-19 | 2021-07-19 | Cold-resistant high-static-stiffness polyurethane microporous elastic base plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113307930A true CN113307930A (en) | 2021-08-27 |
| CN113307930B CN113307930B (en) | 2022-02-11 |
Family
ID=77382310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110814037.8A Active CN113307930B (en) | 2021-07-19 | 2021-07-19 | Cold-resistant high-static-stiffness polyurethane microporous elastic base plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113307930B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113831503A (en) * | 2021-10-20 | 2021-12-24 | 洛阳科博思新材料科技有限公司 | Elastomer for vibration damping mattress and preparation method thereof |
| CN114276515A (en) * | 2021-12-08 | 2022-04-05 | 山东奥卓新材料有限公司 | Polyurethane microporous elastic base plate with ultrahigh strength and low dynamic-static stiffness ratio and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110194828A (en) * | 2019-06-28 | 2019-09-03 | 北京理工大学 | A kind of preparation method of phase transformation energy-absorbing polyurethane elastomer anti-explosion tank outer protective cover |
| CN110305292A (en) * | 2019-07-09 | 2019-10-08 | 北京理工大学 | A kind of preparation method of low springrate ratio microporous polyurethane resilient sleeper-bearing |
| US20200071448A1 (en) * | 2017-03-03 | 2020-03-05 | Dow Global Technologies Llc | Low density polyurethane elastomer foam with high ball rebound |
-
2021
- 2021-07-19 CN CN202110814037.8A patent/CN113307930B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20200071448A1 (en) * | 2017-03-03 | 2020-03-05 | Dow Global Technologies Llc | Low density polyurethane elastomer foam with high ball rebound |
| CN110194828A (en) * | 2019-06-28 | 2019-09-03 | 北京理工大学 | A kind of preparation method of phase transformation energy-absorbing polyurethane elastomer anti-explosion tank outer protective cover |
| CN110305292A (en) * | 2019-07-09 | 2019-10-08 | 北京理工大学 | A kind of preparation method of low springrate ratio microporous polyurethane resilient sleeper-bearing |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113831503A (en) * | 2021-10-20 | 2021-12-24 | 洛阳科博思新材料科技有限公司 | Elastomer for vibration damping mattress and preparation method thereof |
| CN114276515A (en) * | 2021-12-08 | 2022-04-05 | 山东奥卓新材料有限公司 | Polyurethane microporous elastic base plate with ultrahigh strength and low dynamic-static stiffness ratio and preparation method thereof |
| CN114276515B (en) * | 2021-12-08 | 2023-04-21 | 山东奥卓新材料有限公司 | Polyurethane microporous elastic backing plate with ultrahigh strength and low dynamic and static stiffness ratio and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113307930B (en) | 2022-02-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113461900B (en) | Low-static-rigidity polyurethane microporous elastic base plate with low-temperature static rigidity change rate | |
| CN110305292B (en) | Preparation method of polyurethane microporous elastic base plate with low dynamic-static stiffness ratio | |
| CN107602817B (en) | High-cold-resistance polyurethane shock pad and preparation method thereof | |
| CN113307930B (en) | Cold-resistant high-static-stiffness polyurethane microporous elastic base plate | |
| CN113307940B (en) | Low-temperature-resistant middle-static-stiffness polyurethane microporous elastic base plate | |
| JP4708251B2 (en) | Foamed polyurethane elastomer, method for producing the same and railroad pad | |
| TW517065B (en) | Process for making microcellular polyurethane elastomers | |
| CN113563563B (en) | Low-density fatigue-resistant microporous polyurethane elastic damping pad and preparation method thereof | |
| CN115124693B (en) | Foaming polyurethane elastomer and preparation method and application thereof | |
| CN105732946B (en) | The preparation method of microporous polyurethane elastomer | |
| CN113549193B (en) | WJ-8A type high-speed rail elastic base plate with low static rigidity change rate at low temperature | |
| CN105732935B (en) | A kind of preparation method of microporous polyurethane elastomer | |
| CN114276515B (en) | Polyurethane microporous elastic backing plate with ultrahigh strength and low dynamic and static stiffness ratio and preparation method thereof | |
| CN106674480A (en) | Preparation method of NDI (Naphthalene Diisocyanate) modified MDI (Diphenyl Methane Diisocyanate)-based polyurethane microporous elastomer | |
| JP2007023123A (en) | Polyurethane foam shaped body and method for producing the same | |
| CN114989389A (en) | High-closed-pore-rate low-density polyurethane vibration isolation pad and preparation method thereof | |
| CN1065884C (en) | Urethane foam for shoe soles | |
| KR20130025161A (en) | Microcellular polyurethane elastomer and manufacturing methods thereof | |
| JPH0680107B2 (en) | Method for producing polyurethane urea type elastomer | |
| CN106957407B (en) | CHDI is modified MDI base polyurethane micropore method for producing elastomers | |
| JP3780522B2 (en) | Method for producing flexible polyurethane foam for automobile seat cushion | |
| JP5571905B2 (en) | Polyurethane foam molding | |
| CN114316205B (en) | High-strength low-dynamic-static-stiffness-ratio polyurethane microporous elastic base plate and preparation method thereof | |
| JP5082829B2 (en) | Polyurethane foam molding and method for producing the same | |
| JP4217895B2 (en) | Method for producing polyurethane foam molding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |