CN113290980A - 一种隔热保温夹层玻璃及其制备方法 - Google Patents

一种隔热保温夹层玻璃及其制备方法 Download PDF

Info

Publication number
CN113290980A
CN113290980A CN202110494821.5A CN202110494821A CN113290980A CN 113290980 A CN113290980 A CN 113290980A CN 202110494821 A CN202110494821 A CN 202110494821A CN 113290980 A CN113290980 A CN 113290980A
Authority
CN
China
Prior art keywords
layer
parts
laminated glass
heat
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110494821.5A
Other languages
English (en)
Inventor
黄元旦
苏丹
魏晓勇
张德华
周志英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Xiangbang Technology Co ltd
Original Assignee
Zhejiang Xiangbang Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Xiangbang Technology Co ltd filed Critical Zhejiang Xiangbang Technology Co ltd
Priority to CN202110494821.5A priority Critical patent/CN113290980A/zh
Publication of CN113290980A publication Critical patent/CN113290980A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J1/00—Windows; Windscreens; Accessories therefor
    • B60J1/001—Double glazing for vehicles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/54—Slab-like translucent elements
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552—Fatigue strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

本发明涉及一种隔热保温夹层玻璃，尤其涉及一种隔热保温夹层玻璃及其制备方法。夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。运用高效的红外紫外阻隔助剂，流延成膜，用于夹层玻璃中间膜。多种材料层压，多层或单层结构制备获得隔热保温夹层玻璃。所制备的夹层玻璃，VLT+IRR≥165％，URR≥99％，雾度≤5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。工艺流程简便，无高压条件，明显优于PVB中间膜。

Description

一种隔热保温夹层玻璃及其制备方法
技术领域
本发明涉及一种隔热保温夹层玻璃，尤其涉及一种隔热保温夹层玻璃及其制备方法。
背景技术
现有技术中应用隔热保温的夹层玻璃，基本都是应用PVB作为封装胶膜，工艺制程较为苛刻，需要高压条件，制程涉及到高压反应釜，成本高等缺陷。夹层玻璃大多使用PVB材质封装，工艺复杂、成本高等问题。现有技术中功能性夹层玻璃较少，阻隔性能较差。夹层玻璃粘结层层次不一，制备工艺需要高压，很难大规模生产，生产成本居高。
发明内容
本发明主要是解决现有技术中存在的不足，提供一种该夹层玻璃具有隔热保温的功能，增强玻璃的隔热能力，阻隔紫外线灼伤人的皮肤的一种隔热保温夹层玻璃及其制备方法。
本发明的上述技术问题主要是通过下述技术方案得以解决的：
一种隔热保温夹层玻璃，夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。
作为优选，所述表面层为玻璃或高分子树脂层，所述玻璃或高分子树脂层的表面与空气表面接触，所述表面层的厚度大于2mm，所述高分子树脂层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，所述玻璃为压花玻璃、钢化玻璃和半钢化玻璃的一种。
作为优选，所述粘结剂层为EVA胶膜、POE胶膜、TPU胶膜任意一种或多种，所述粘结剂层厚度0.1～30mm。
作为优选，所述夹层玻璃具有红外紫外阻隔性能，VLT+IRR≥165％，URR≥99％。
作为优选，所述夹层玻璃雾度不大于5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。
作为优选，粘结剂层中的胶膜，按以下质量份进行配比：
原料组成1：EVA树脂86～95份，耐老化助剂1～5份，偶联剂0.5～3份，交联剂1～3份，填料0.1～3份；
原料组成2：POE树脂86～95份，耐老化助剂1～5份，偶联剂0.5～3份，交联剂1～3份，填料0.1～3份；
原料组成3：TPU料93～98份，耐老化助剂1～5份；
作为优选，所述的耐老化助剂，按照重量份组成为抗氧剂0～1份、紫外光吸收剂0.2～2份与光稳定剂0.3～2份组成：
所述的紫外光吸收剂为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类一种或多种。
所述的光稳定剂为受阻胺类光稳定剂，优选抗氧剂为芳香胺类抗氧剂、硫代酯类和亚磷酸酯类一种或多种。
作为优选，偶联剂为硅烷偶联剂，所述交联剂为过氧化物类化合物。
作为优选，填料成分为无机填料和有机填料，包括ATO、GTO，固含量为20～40％，粒径10～40nm；分散剂为乙酸乙酯、甲苯、二甲苯、乙腈和二氯甲烷一种或多种。
一种隔热保温夹层玻璃制备方法，按以下步骤进行：从内往外依次放置好各层物料，置于层压机中，层压温度125～150℃，层压时间10～20min，获得建筑用夹层玻璃。特别适用于建筑内饰、阳光房和汽车等领域。
本发明中夹层玻璃所用胶膜具有优异隔热保温、抗老化和抗冲击性能，能够有效保护动植物阻隔紫外和红外线，保护动植物皮肤不被灼伤。
本发明中所用制程工艺简便，无需高温高压，普通的设备即可生产，显著降低成本。
本发明中高分子层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，具有广泛性。
创新点与效果：运用高效的红外紫外阻隔助剂，流延成膜，用于夹层玻璃中间膜。多种材料层压，多层或单层结构制备获得隔热保温夹层玻璃。所制备的夹层玻璃，VLT+IRR≥165％，URR≥99％，雾度≤5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。工艺流程简便，无高压条件，明显优于PVB中间膜。
具体实施方式
下面通过实施例，对本发明的技术方案作进一步具体的说明。
实施例1：一种隔热保温夹层玻璃，夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。
所述表面层为玻璃或高分子树脂层，所述玻璃或高分子树脂层的表面与空气表面接触，所述表面层的厚度大于2mm，所述高分子树脂层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，所述玻璃为压花玻璃、钢化玻璃和半钢化玻璃的一种。
所述粘结剂层为EVA胶膜、POE胶膜、TPU胶膜任意一种或多种，所述粘结剂层厚度0.1mm。
所述夹层玻璃具有红外紫外阻隔性能，VLT+IRR≥165％，URR≥99％。
所述夹层玻璃雾度不大于5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。
粘结剂层中的胶膜，按以下质量份进行配比：
原料组成1：EVA树脂86份，耐老化助剂1份，偶联剂0.5份，交联剂1份，填料0.1份；
原料组成2：POE树脂86份，耐老化助剂1份，偶联剂0.5份，交联剂1份，填料0.1份；
原料组成3：TPU料93～98份，耐老化助剂1份；
所述的耐老化助剂，按照重量份组成为抗氧剂0份、紫外光吸收剂0.2份与光稳定剂0.3份组成：
所述的紫外光吸收剂为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类一种或多种。
所述的光稳定剂为受阻胺类光稳定剂，优选抗氧剂为芳香胺类抗氧剂、硫代酯类和亚磷酸酯类一种或多种。
偶联剂为硅烷偶联剂，所述交联剂为过氧化物类化合物。
填料成分为无机填料和有机填料，包括ATO、GTO，固含量为20～40％，粒径10nm；分散剂为乙酸乙酯、甲苯、二甲苯、乙腈和二氯甲烷一种或多种。
按以下步骤进行：从内往外依次放置好各层物料，置于层压机中，层压温度125℃，层压时间10min，获得建筑用夹层玻璃。
实施例2：一种隔热保温夹层玻璃，夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。
所述表面层为玻璃或高分子树脂层，所述玻璃或高分子树脂层的表面与空气表面接触，所述表面层的厚度大于2mm，所述高分子树脂层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，所述玻璃为压花玻璃、钢化玻璃和半钢化玻璃的一种。
所述粘结剂层为EVA胶膜、POE胶膜、TPU胶膜任意一种或多种，所述粘结剂层厚度15mm。
所述夹层玻璃具有红外紫外阻隔性能，VLT+IRR≥165％，URR≥99％。
所述夹层玻璃雾度不大于5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。
粘结剂层中的胶膜，按以下质量份进行配比：
原料组成1：EVA树脂90份，耐老化助剂3份，偶联剂2.5份，交联剂1.5份，填料2份；
原料组成2：POE树脂90份，耐老化助剂3份，偶联剂2份，交联剂1.5份，填料1.3份；
原料组成3：TPU料95份，耐老化助剂3份；
所述的耐老化助剂，按照重量份组成为抗氧剂0.5份、紫外光吸收剂1.5份与光稳定剂1份组成：
所述的紫外光吸收剂为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类一种或多种。
所述的光稳定剂为受阻胺类光稳定剂，优选抗氧剂为芳香胺类抗氧剂、硫代酯类和亚磷酸酯类一种或多种。
偶联剂为硅烷偶联剂，所述交联剂为过氧化物类化合物。
填料成分为无机填料和有机填料，包括ATO、GTO，固含量为30％，粒径20nm；分散剂为乙酸乙酯、甲苯、二甲苯、乙腈和二氯甲烷一种或多种。
一种隔热保温夹层玻璃制备方法，按以下步骤进行：从内往外依次放置好各层物料，置于层压机中，层压温度135℃，层压时间15min，获得建筑用夹层玻璃。
实施例3：一种隔热保温夹层玻璃，夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。
所述表面层为玻璃或高分子树脂层，所述玻璃或高分子树脂层的表面与空气表面接触，所述表面层的厚度大于2mm，所述高分子树脂层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，所述玻璃为压花玻璃、钢化玻璃和半钢化玻璃的一种。
所述粘结剂层为EVA胶膜、POE胶膜、TPU胶膜任意一种或多种，所述粘结剂层厚度30mm。
所述夹层玻璃具有红外紫外阻隔性能，VLT+IRR≥165％，URR≥99％。
所述夹层玻璃雾度不大于5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。
粘结剂层中的胶膜，按以下质量份进行配比：
原料组成1：EVA树脂95份，耐老化助剂5份，偶联剂3份，交联剂3份，填料3份；
原料组成2：POE树脂95份，耐老化助剂5份，偶联剂3份，交联剂3份，填料3份；
原料组成3：TPU料98份，耐老化助剂5份；
所述的耐老化助剂，按照重量份组成为抗氧剂1份、紫外光吸收剂2份与光稳定剂2份组成：
所述的紫外光吸收剂为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类一种或多种。
所述的光稳定剂为受阻胺类光稳定剂，优选抗氧剂为芳香胺类抗氧剂、硫代酯类和亚磷酸酯类一种或多种。
偶联剂为硅烷偶联剂，所述交联剂为过氧化物类化合物。
填料成分为无机填料和有机填料，包括ATO、GTO，固含量为40％，粒径40nm；分散剂为乙酸乙酯、甲苯、二甲苯、乙腈和二氯甲烷一种或多种。
一种隔热保温夹层玻璃制备方法，按以下步骤进行：从内往外依次放置好各层物料，置于层压机中，层压温度150℃，层压时间20min，获得建筑用夹层玻璃。

Claims (10)

1.一种隔热保温夹层玻璃，其特征在于：夹层玻璃包括表面层、粘结剂层和内层，所述粘结剂层位于所述表面层与内层之间，所述表面层、粘结剂层以及所述内层的厚度总和大于等于6mm。
2.如权利要求1所述的一种隔热保温夹层玻璃，其特征在于：所述表面层为玻璃或高分子树脂层，所述玻璃或高分子树脂层的表面与空气表面接触，所述表面层的厚度大于2mm，所述高分子树脂层为PC层、PBT/PET层、PA膜层、PVDF层、聚烯烃层的任意一种或多种，所述玻璃为压花玻璃、钢化玻璃和半钢化玻璃的一种。
3.如权利要求1所述的一种隔热保温夹层玻璃，其特征在于：所述粘结剂层为EVA胶膜、POE胶膜、TPU胶膜任意一种或多种，所述粘结剂层厚度0.1～30mm。
4.如权利要求1所述的一种隔热保温夹层玻璃，其特征在于：所述夹层玻璃具有红外紫外阻隔性能，VLT+IRR≥165％，URR≥99％。
5.如权利要求1所述的一种隔热保温夹层玻璃，其特征在于：所述夹层玻璃雾度不大于5，敲击强度≥8，剥离强度≥60N/cm，霰弹袋冲击高度≥300mm。
6.如权利要求3所述的一种隔热保温夹层玻璃，其特征在于：粘结剂层中的胶膜，按以下质量份进行配比：
原料组成1：EVA树脂86～95份，耐老化助剂1～5份，偶联剂0.5～3份，交联剂1～3份，填料0.1～3份；
原料组成2：POE树脂86～95份，耐老化助剂1～5份，偶联剂0.5～3份，交联剂1～3份，填料0.1～3份；
原料组成3：TPU料93～98份，耐老化助剂1～5份。
7.如权利要求6所述的一种隔热保温夹层玻璃，其特征在于：所述的耐老化助剂，按照重量份组成为抗氧剂0～1份、紫外光吸收剂0.2～2份与光稳定剂0.3～2份组成：
所述的紫外光吸收剂为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类一种或多种。
所述的光稳定剂为受阻胺类光稳定剂，优选抗氧剂为芳香胺类抗氧剂、硫代酯类和亚磷酸酯类一种或多种。
8.如权利要求6所述的一种隔热保温夹层玻璃，其特征在于：偶联剂为硅烷偶联剂，所述交联剂为过氧化物类化合物。
9.如权利要求6所述的一种隔热保温夹层玻璃，其特征在于：填料成分为无机填料和有机填料，包括ATO、GTO，固含量为20～40％，粒径10～40nm；分散剂为乙酸乙酯、甲苯、二甲苯、乙腈和二氯甲烷一种或多种。
10.如权利要求1所述的一种隔热保温夹层玻璃制备方法，其特征在于按以下步骤进行：从内往外依次放置好各层物料，置于层压机中，层压温度125～150℃，层压时间10～20min，获得建筑用夹层玻璃。
CN202110494821.5A 2021-05-07 2021-05-07 一种隔热保温夹层玻璃及其制备方法 Pending CN113290980A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110494821.5A CN113290980A (zh) 2021-05-07 2021-05-07 一种隔热保温夹层玻璃及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110494821.5A CN113290980A (zh) 2021-05-07 2021-05-07 一种隔热保温夹层玻璃及其制备方法

Publications (1)

Publication Number Publication Date
CN113290980A true CN113290980A (zh) 2021-08-24

Family

ID=77320983

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110494821.5A Pending CN113290980A (zh) 2021-05-07 2021-05-07 一种隔热保温夹层玻璃及其制备方法

Country Status (1)

Country Link
CN (1) CN113290980A (zh)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892906A (zh) * 2018-06-20 2018-11-27 天台县百赞塑胶有限公司 一种红外阻隔的pvb中间膜及制备方法
CN109796907A (zh) * 2019-01-25 2019-05-24 南京谷尚新材料科技有限公司 一种高透光耐老化夹层玻璃用eva中间膜及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892906A (zh) * 2018-06-20 2018-11-27 天台县百赞塑胶有限公司 一种红外阻隔的pvb中间膜及制备方法
CN109796907A (zh) * 2019-01-25 2019-05-24 南京谷尚新材料科技有限公司 一种高透光耐老化夹层玻璃用eva中间膜及其制备方法

Similar Documents

Publication Publication Date Title
US8663773B2 (en) Vacuum insulation panel and method for manufacturing the same
CN110792879B (zh) 一种不惧表面破损真空绝热板材的加工工艺
CN110328932B (zh) 一种隔热包装袋及其制备方法和应用
EP1018166A1 (de) Fotovoltaischer modul sowie ein verfahren zu dessen herstellung
CA2716191A1 (en) High performance anti-spall laminate article
CN103022192A (zh) 一种高反射率太阳能电池背板膜及其制备方法及一种太阳能电池
CN113290980A (zh) 一种隔热保温夹层玻璃及其制备方法
CN109473498B (zh) 一种封装一体化背板及其制备方法
CN201721767U (zh) 真空隔热板包装薄膜
CN201931665U (zh) 一种功能夹层玻璃
CN201523013U (zh) 太阳能光伏电池背板的复合薄膜
CN107933054A (zh) 一种夹层玻璃的加工方法
CN114750496B (zh) 一种太阳能防火复合背板及其制备方法
CN202917522U (zh) 一种高反射率太阳能电池背板膜及一种太阳能电池
KR101525297B1 (ko) 유리섬유를 포함하는 진공단열재용 심재, 그 제조방법 및 이를 이용한 진공단열재
CN101776421A (zh) 一种多级腔型防爆炸玻璃及其制造方法
CN106144215A (zh) 一种阻燃、保温包装材料
CN201680767U (zh) 一种多级腔型防爆炸玻璃
CN114077081A (zh) 一种调光玻璃及其制备方法
CN218838888U (zh) 一种远红外保温复合聚酯薄膜
WO2013107099A1 (zh) 用于真空绝热板的高阻隔复合膜及其制造方法
CN111253868A (zh) 一种太阳能膜片
AU2012291917B2 (en) Process for manufacturing a glazing unit having a decorative effect
CN114872405B (zh) 一种耐候、抗老化的po光伏背板及其制备方法
RU2610774C1 (ru) Способ получения абразивостойкого электрообогреваемого полимерного слоистого материала

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination