CN113290951A - Oil-proof anti-fouling flame-retardant composite fiber fabric - Google Patents

Oil-proof anti-fouling flame-retardant composite fiber fabric Download PDF

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Publication number
CN113290951A
CN113290951A CN202110323779.0A CN202110323779A CN113290951A CN 113290951 A CN113290951 A CN 113290951A CN 202110323779 A CN202110323779 A CN 202110323779A CN 113290951 A CN113290951 A CN 113290951A
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CN
China
Prior art keywords
fabric
flame
retardant
parts
fouling
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Pending
Application number
CN202110323779.0A
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Chinese (zh)
Inventor
陈辉
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Simmons Bedding & Furniture Suzhou Co ltd
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Simmons Bedding & Furniture Suzhou Co ltd
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Application filed by Simmons Bedding & Furniture Suzhou Co ltd filed Critical Simmons Bedding & Furniture Suzhou Co ltd
Priority to CN202110323779.0A priority Critical patent/CN113290951A/en
Publication of CN113290951A publication Critical patent/CN113290951A/en
Pending legal-status Critical Current

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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D—TEXTILES; PAPER
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an oil-proof anti-fouling flame-retardant composite fiber fabric which comprises a base fabric, wherein flame-retardant layers are arranged on the upper surface and the lower surface of the base fabric, waterproof and anti-fouling layers are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers, and a non-woven fabric is arranged below the base fabric; the fabric is soaked in clear water added with a mildew inhibitor and an antistatic agent, so that the fabric has mildew-proof and antistatic effects, the flame retardant, the fluorine-free waterproof finishing agent and the fluorine-free anti-splashing agent are added, and the fabric is bonded with the non-woven fabric, so that the outer layer of the fabric is smooth and has excellent oil-repellent dirt performance, as the oil-repellent dirt and the water-repellent dirt cannot penetrate into fibers, dust and dirt can be easily shaken off or brushed off, the fabric is kept clean for a long time, the washing frequency is reduced, small water beads can be formed when water drops on the surface of the fabric, or the water drops can directly fall off from the surface of the fabric, so that the fabric is prevented from absorbing water, and the fabric has waterproofness.

Description

Oil-proof anti-fouling flame-retardant composite fiber fabric
Technical Field
The invention relates to the technical field of composite fiber fabrics, in particular to an oil-proof, anti-fouling and flame-retardant composite fiber fabric.
Background
The mattress is an article between a human body and a bed, which is used for ensuring that consumers obtain healthy and comfortable sleep, the mattress is made of various materials, the mattresses made of different materials can bring different sleep effects to people, a composite body formed by quilting a textile fabric on the surface of the mattress and foamed plastic, fiber for batting, non-woven fabric and other materials is positioned on the outermost layer of the mattress and directly contacted with the human body to play a role in protection and beauty, the composite body can also disperse and bear the force generated by the weight of the body, the integrity of the mattress is increased, and the excessive pressure on any part of the body is effectively prevented, when the surface fabric of the mattress is prepared, the fabric has the functions of moisture absorption and sweat conduction by adding special fluorine-containing epoxy compound and polyvinyl alcohol into a skin layer spinning solution, adding glycidyl methacrylate into a core layer spinning solution and adding dimethyl sulfoxide and triethylene diamine into a coagulation bath, however, the following problems still remain:
the existing fabric is used for a long time and is dry in weather, static electricity can be generated on the surface of the fabric, dust can be adsorbed on the surface of the fabric, a large amount of dirt and dust can be adsorbed on the surface of the fabric easily, the washing times of a user are increased, sweat of a human body is absorbed in the fabric by the existing fabric, the fabric is easily wet and moldy, and therefore the oil-proof anti-fouling flame-retardant composite fiber fabric is provided.
Disclosure of Invention
The invention aims to provide an oil-proof anti-fouling flame-retardant composite fiber fabric to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: an oil-proof anti-fouling flame-retardant composite fiber fabric comprises a base fabric, wherein flame-retardant layers are arranged on the upper surface and the lower surface of the base fabric, waterproof and anti-fouling layers are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers, a non-woven fabric is arranged below the base fabric, the upper surface of the non-woven fabric is bonded to the lower surface of the waterproof and anti-fouling layer at the bottom of the flame-retardant layer, and a back fabric is bonded to the bottom of the non-woven fabric;
the oil-proof anti-fouling flame-retardant composite fiber fabric is prepared from the following materials: the material comprises the following components in parts by weight: 10-20 parts of base fabric, 10-20 parts of flame-retardant layer, 10-20 parts of waterproof and antifouling layer, 2-4 parts of non-woven fabric, 10-20 parts of back fabric, 2-4 parts of mildew inhibitor and 2-4 parts of antistatic agent;
the preparation process of the mildew preventive, the antistatic agent and the base fabric comprises the following steps:
completely diluting the mildew preventive and the antistatic agent in clear water, soaking the base fabric, soaking for 10 minutes, rolling the soaked base fabric with 70% of water, and drying at the temperature of below 180 ℃ to obtain the base fabric mixed with the mildew preventive and the antistatic agent.
Preferably: the flame-retardant layer consists of 20-30 parts of clear water and 2-4 parts of flame retardant;
the preparation process of the flame-retardant layer comprises the following steps:
completely diluting a flame retardant in clear water to obtain a mixture a, soaking the base fabric in the mixture a for 20 minutes, controlling the temperature of the mixture a not to exceed 80 ℃, rolling the soaked base fabric with 70% of water under the condition of being lower than 80 ℃, and drying at the temperature of below 180 ℃ to obtain the base fabric mixed with the flame retardant layer.
Preferably: the waterproof and antifouling layer consists of 1-2 parts of acetic acid, 20-30 parts of clear water, 5-10 parts of a fluorine-free waterproof finishing agent, 5-10 parts of a fluorine-free anti-splashing agent and 4-8 parts of a penetrating agent;
the preparation process of the waterproof antifouling layer comprises the following steps:
completely diluting 0.5ml/l of 60% acetic acid in clear water to obtain a mixture b, adding 10-20g/l of penetrating agent into the mixture b, adding 30-60 g/l of fluorine-free waterproof finishing agent and 15-30 g/l of fluorine-free anti-splashing agent into the mixture b, stirring to obtain a mixture c, soaking the base fabric mixed with the flame-retardant layer in the mixture c for 15 minutes, controlling the temperature of the mixture c to be not more than 40 ℃, rolling the soaked flame-retardant layer with 20-40% of water, and drying the base fabric mixed with the flame-retardant layer in a setting machine at the temperature of 150 ℃ and the speed of 22m/min to obtain the base fabric mixed with the flame-retardant layer and the waterproof and anti-fouling layer.
Preferably: the compounding process of the oil-proof anti-fouling flame-retardant composite fiber fabric comprises the following steps:
adding glue into the back surface of the base fabric mixed with the flame-retardant layer and the waterproof and antifouling layer through a glue groove by a cloth guide device, attaching the glue to 30g/m2 non-woven fabric on the cloth guide device, bonding the back surface material to the bottom of the non-woven fabric, heating the back surface material by a big roller at the temperature of 140 ℃ and at the rotating speed of 15-20m/min, and thus obtaining the oil-proof, antifouling and flame-retardant composite fiber fabric.
Preferably: the flame retardant is one or more of antimony trioxide, magnesium hydroxide and aluminum hydroxide.
Preferably: the mildew preventive is any one of organic mercury salt, organic copper salt, organic tin salt, inorganic salt copper sulfate, mercuric chloride and sodium fluoride.
Preferably: the antistatic agent is one or more of amine salt, quaternary ammonium salt and alkyl amino acid salt.
Preferably: the non-woven fabric is made of any one of terylene, polypropylene fiber, chinlon, spandex and acrylon.
Compared with the prior art, the invention has the beneficial effects that: the fabric is soaked in clear water added with a mildew inhibitor and an antistatic agent, so that the fabric has mildew-proof and antistatic effects, the flame retardant, the fluorine-free waterproof finishing agent and the fluorine-free anti-splashing agent are added, and the fabric is bonded with the non-woven fabric, so that the outer layer of the fabric is smooth and has excellent oil-repellent dirt performance, as the oil-repellent dirt and the water-repellent dirt cannot penetrate into fibers, dust and dirt can be easily shaken off or brushed off, the fabric is kept clean for a long time, the washing frequency is reduced, small water beads can be formed when water drops on the surface of the fabric, or the water drops can directly fall off from the surface of the fabric, so that the fabric is prevented from absorbing water, and the fabric has waterproofness.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
In the figure: 1. a base fabric; 2. a flame retardant layer; 3. a waterproof antifouling layer; 4. non-woven fabrics; 5. and (4) backing the fabric.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
Referring to fig. 1, the present invention provides a technical solution: an oil-proof anti-fouling flame-retardant composite fiber fabric comprises a base fabric 1, wherein flame-retardant layers 2 are arranged on the upper surface and the lower surface of the base fabric 1, waterproof and anti-fouling layers 3 are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers 2, a non-woven fabric 4 is arranged below the base fabric 1, the upper surface of the non-woven fabric 4 is bonded to the lower surface of the waterproof and anti-fouling layer 3 at the bottom of the flame-retardant layer 2, and a back fabric 5 is bonded to the bottom of the non-woven fabric 4;
the oil-proof anti-fouling flame-retardant composite fiber fabric is prepared from the following materials: the material comprises the following components in parts by weight: 10 parts of base fabric 1, 10 parts of flame-retardant layer 2, 10 parts of waterproof and antifouling layer 3, 2 parts of non-woven fabric 4, 10 parts of back fabric 5, 2 parts of mildew preventive and 2 parts of antistatic agent;
the preparation process of the mixture of the mildew inhibitor, the antistatic agent and the base fabric 1 is as follows:
completely diluting the mildew preventive and the antistatic agent in clear water, soaking the base fabric 1, soaking for 10 minutes, rolling the soaked base fabric 1 with 70% of water, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the mildew preventive and the antistatic agent.
In this embodiment, specifically: the flame-retardant layer 2 consists of 20 parts of clear water and 2 parts of flame retardant;
the preparation process of the flame-retardant layer 2 is as follows:
completely diluting a flame retardant in clear water to obtain a mixture a, soaking the base fabric 1 in the mixture a for 20 minutes, controlling the temperature of the mixture a not to exceed 80 ℃, rolling the soaked base fabric 1 with 70% of water under the condition of being lower than 80 ℃, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the flame-retardant layer 2.
In this embodiment, specifically: the waterproof and antifouling layer 3 consists of 1 part of acetic acid, 20 parts of clear water, 5 parts of fluorine-free waterproof finishing agent, 5 parts of fluorine-free anti-splashing agent and 4 parts of penetrating agent;
the preparation process of the waterproof and antifouling layer 3 is as follows:
completely diluting 0.5ml/l of 60% acetic acid in clear water to obtain a mixture b, adding 10g/l of penetrating agent into the mixture b, adding 30g/l of fluorine-free waterproof finishing agent and 15g/l of fluorine-free water repellent agent into the mixture b, stirring to obtain a mixture c, soaking the base fabric 1 mixed with the flame-retardant layer 2 in the mixture c for 15 minutes, controlling the temperature of the mixture c to be not more than 40 ℃, rolling the soaked flame-retardant layer 2 with 20% of water, and drying the base fabric 1 mixed with the flame-retardant layer 2 in a setting machine with the temperature of 150 ℃ and the speed of 22m/min, thereby obtaining the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3.
In this embodiment, specifically: the compounding process of the oil-proof anti-fouling flame-retardant composite fiber fabric comprises the following steps:
adding glue into the back surface of the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3 through a glue groove by a fabric guide device, attaching the glue to 30g/m2 non-woven fabric 4 on the fabric guide device, bonding the back fabric 5 to the bottom of the non-woven fabric 4, heating the back fabric by a big roller at the temperature of 140 ℃ and at the rotating speed of 15m/min, and thus obtaining the oil-proof and antifouling flame-retardant composite fiber fabric.
In this embodiment, specifically: the flame retardant is antimony trioxide and magnesium hydroxide.
In this embodiment, specifically: the mildew inhibitor is any one of organic mercury salt, organic copper salt, organic tin salt, inorganic salt copper sulfate, mercuric chloride and sodium fluoride, and organic copper salt is preferred.
In this embodiment, specifically: the antistatic agent is amine salt or quaternary ammonium salt.
In this embodiment, specifically: the material of the non-woven fabric 4 is any one of terylene, polypropylene fiber, chinlon, spandex and acrylon, preferably terylene.
Example two
Referring to fig. 1, the present invention provides a technical solution: an oil-proof anti-fouling flame-retardant composite fiber fabric comprises a base fabric 1, wherein flame-retardant layers 2 are arranged on the upper surface and the lower surface of the base fabric 1, waterproof and anti-fouling layers 3 are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers 2, a non-woven fabric 4 is arranged below the base fabric 1, the upper surface of the non-woven fabric 4 is bonded to the lower surface of the waterproof and anti-fouling layer 3 at the bottom of the flame-retardant layer 2, and a back fabric 5 is bonded to the bottom of the non-woven fabric 4;
the oil-proof anti-fouling flame-retardant composite fiber fabric is prepared from the following materials: the material comprises the following components in parts by weight: 15 parts of base fabric 1, 15 parts of flame-retardant layer 2, 15 parts of waterproof and antifouling layer 3, 3 parts of non-woven fabric 4, 15 parts of back fabric 5, 3 parts of mildew preventive and 3 parts of antistatic agent;
the preparation process of the mixture of the mildew inhibitor, the antistatic agent and the base fabric 1 is as follows:
completely diluting the mildew preventive and the antistatic agent in clear water, soaking the base fabric 1, soaking for 10 minutes, rolling the soaked base fabric 1 with 70% of water, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the mildew preventive and the antistatic agent.
In this embodiment, specifically: the flame-retardant layer 2 consists of 25 parts of clear water and 3 parts of flame retardant;
the preparation process of the flame-retardant layer 2 is as follows:
completely diluting a flame retardant in clear water to obtain a mixture a, soaking the base fabric 1 in the mixture a for 20 minutes, controlling the temperature of the mixture a not to exceed 80 ℃, rolling the soaked base fabric 1 with 70% of water under the condition of being lower than 80 ℃, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the flame-retardant layer 2.
In this embodiment, specifically: the waterproof and antifouling layer 3 consists of 1.5 parts of acetic acid, 25 parts of clear water, 8 parts of fluorine-free waterproof finishing agent, 8 parts of fluorine-free anti-splashing agent and 6 parts of penetrating agent;
the preparation process of the waterproof and antifouling layer 3 is as follows:
completely diluting 0.5ml/l of 60% acetic acid in clean water to obtain a mixture b, adding 15g/l of penetrating agent into the mixture b, adding 40g/l of fluorine-free waterproof finishing agent and 25g/l of fluorine-free water repellent agent into the mixture b, stirring to obtain a mixture c, soaking the base fabric 1 mixed with the flame-retardant layer 2 in the mixture c for 15 minutes, controlling the temperature of the mixture c to be not more than 40 ℃, rolling the soaked flame-retardant layer 2 with 30% of water, and drying the base fabric 1 mixed with the flame-retardant layer 2 in a setting machine with the temperature of 150 ℃ and the speed of 22m/min, thereby obtaining the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3.
In this embodiment, specifically: the compounding process of the oil-proof anti-fouling flame-retardant composite fiber fabric comprises the following steps:
adding glue into the back surface of the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3 through a glue groove by a fabric guide device, attaching the glue to 30g/m2 non-woven fabric 4 on the fabric guide device, bonding the back fabric 5 to the bottom of the non-woven fabric 4, heating the back fabric by a big roller at the temperature of 140 ℃ and at the rotating speed of 18m/min, and thus obtaining the oil-proof and antifouling flame-retardant composite fiber fabric.
In this embodiment, specifically: the flame retardant is magnesium hydroxide and aluminum hydroxide.
In this embodiment, specifically: the mildew inhibitor is any one of organic mercury salt, organic copper salt, organic tin salt, inorganic salt copper sulfate, mercuric chloride and sodium fluoride, and organic tin salt is preferred.
In this embodiment, specifically: the antistatic agent is alkyl amino acid salt.
In this embodiment, specifically: the material of the non-woven fabric 4 is any one of terylene, polypropylene fiber, chinlon, spandex and acrylon, preferably chinlon.
EXAMPLE III
Referring to fig. 1, the present invention provides a technical solution: an oil-proof anti-fouling flame-retardant composite fiber fabric comprises a base fabric 1, wherein flame-retardant layers 2 are arranged on the upper surface and the lower surface of the base fabric 1, waterproof and anti-fouling layers 3 are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers 2, a non-woven fabric 4 is arranged below the base fabric 1, the upper surface of the non-woven fabric 4 is bonded to the lower surface of the waterproof and anti-fouling layer 3 at the bottom of the flame-retardant layer 2, and a back fabric 5 is bonded to the bottom of the non-woven fabric 4;
the oil-proof anti-fouling flame-retardant composite fiber fabric is prepared from the following materials: the material comprises the following components in parts by weight: 20 parts of base fabric 1, 20 parts of flame-retardant layer 2, 20 parts of waterproof and antifouling layer 3, 4 parts of non-woven fabric 4, 20 parts of back fabric 5, 4 parts of mildew preventive and 4 parts of antistatic agent;
the preparation process of the mixture of the mildew inhibitor, the antistatic agent and the base fabric 1 is as follows:
completely diluting the mildew preventive and the antistatic agent in clear water, soaking the base fabric 1, soaking for 10 minutes, rolling the soaked base fabric 1 with 70% of water, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the mildew preventive and the antistatic agent.
In this embodiment, specifically: the flame-retardant layer 2 consists of 30 parts of clear water and 4 parts of flame retardant;
the preparation process of the flame-retardant layer 2 is as follows:
completely diluting a flame retardant in clear water to obtain a mixture a, soaking the base fabric 1 in the mixture a for 20 minutes, controlling the temperature of the mixture a not to exceed 80 ℃, rolling the soaked base fabric 1 with 70% of water under the condition of being lower than 80 ℃, and drying at the temperature of below 180 ℃ to obtain the base fabric 1 mixed with the flame-retardant layer 2.
In this embodiment, specifically: the waterproof and antifouling layer 3 consists of 2 parts of acetic acid, 30 parts of clear water, 10 parts of fluorine-free waterproof finishing agent, 10 parts of fluorine-free anti-splashing agent and 8 parts of penetrating agent;
the preparation process of the waterproof and antifouling layer 3 is as follows:
completely diluting 0.5ml/l of 60% acetic acid in clean water to obtain a mixture b, adding 20g/l of penetrating agent into the mixture b, adding 60g/l of fluorine-free waterproof finishing agent and 30g/l of fluorine-free water repellent agent into the mixture b, stirring to obtain a mixture c, soaking the base fabric 1 mixed with the flame-retardant layer 2 in the mixture c for 15 minutes, controlling the temperature of the mixture c to be not more than 40 ℃, rolling the soaked flame-retardant layer 2 with 40% of water, and drying the base fabric 1 mixed with the flame-retardant layer 2 in a setting machine with the temperature of 150 ℃ and the speed of 22m/min, thereby obtaining the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3.
In this embodiment, specifically: the compounding process of the oil-proof anti-fouling flame-retardant composite fiber fabric comprises the following steps:
adding glue into the back surface of the base fabric 1 mixed with the flame-retardant layer 2 and the waterproof and antifouling layer 3 through a glue groove by a fabric guide device, attaching the glue to 30g/m2 non-woven fabric 4 on the fabric guide device, bonding the back fabric 5 to the bottom of the non-woven fabric 4, heating the back fabric by a big roller at the temperature of 140 ℃ and at the rotating speed of 20m/min, and thus obtaining the oil-proof and antifouling flame-retardant composite fiber fabric.
In this embodiment, specifically: the flame retardant is antimony trioxide.
In this embodiment, specifically: the mildew inhibitor is any one of organic mercury salt, organic copper salt, organic tin salt, inorganic salt copper sulfate, mercuric chloride and sodium fluoride, and preferably inorganic salt copper sulfate.
In this embodiment, specifically: the antistatic agent is amine salt.
In this embodiment, specifically: the material of the non-woven fabric 4 is any one of polyester, polypropylene, chinlon, spandex and acrylon, and preferably spandex.
Working principle or structural principle, when in use, a worker cleans the base fabric 1 to ensure the neatness of the base fabric 1, adds the mildew preventive and the antistatic agent into a dilution container, continuously stirs the mixture at room temperature until the solution reaches the final appropriate concentration based on the weight of the fabric to be treated, puts the cleaned base fabric 1 into an absorption and immersion device for absorption and immersion for 20 minutes, controls the temperature of the absorption and immersion solution to be not more than 50 ℃, takes out the base fabric 1 after the absorption and immersion is finished, adds clear water with the water amount required by the absorption and immersion device into an independent dilution container, slowly adds the flame retardant into the water, continuously stirs the mixture at room temperature until the solution reaches the final appropriate concentration based on the weight of the fabric to be treated, continuously adds the clear water and stirs the mixture until the volume of the solution reaches 100% of the working solution, adds the diluted flame retardant solution into a main absorption and immersion device for absorption and immersion for 20 minutes, heating the soaking solution to be not more than 80 ℃, under the condition of being lower than 80 ℃, observing effective soaking by workers, taking out the fabric, rolling water, drying at the temperature of 180 ℃, cleaning the flame-retardant layer 2 by clear water to ensure that no surface active substances remain, adding clear water with the water amount required by soaking equipment into a separate dilution container, adding acetic acid in advance to adjust the pH value of the solution, adding a penetrating agent into the solution to ensure good penetration and uniform rolling of the solution, adding a fluorine-free waterproof finishing agent and a fluorine-free splashing preventive agent into the solution, stirring at a low speed by a stirring rod to disperse the fluorine-free waterproof finishing agent and the fluorine-free splashing preventive agent into water, continuously adding clear water and stirring at a low speed until the volume of the solution reaches 100% of the volume of the working solution, adding the diluted waterproof and dirt-resistant finishing solution into main soaking equipment to continuously soak for 15 minutes, heating the soaking solution to a temperature not more than 40 ℃, wherein the working personnel observe effective soaking, taking out the fabric, rolling the fabric to remove water, placing the fabric at a temperature of 150 ℃, and drying and shaping the fabric by a shaping machine with a speed of 22m/min to obtain the flame-retardant, waterproof and anti-fouling fabric, placing the flame-retardant, waterproof and anti-fouling fabric on a non-woven fabric 4 with a density of 30g/m2, gluing the back surface of the flame-retardant, waterproof and anti-fouling fabric by a fabric guide device through a glue tank, adjusting the mesh number of patterned rods to ensure the gluing amount of the fabric and ensure uniform gluing, attaching the back surface of the glued fabric to a non-woven fabric 4 with a density of 30g/m2 on an inner layer fabric guide device, heating the two materials together by a large roller with a temperature of 140 ℃ and a rotating speed of 20m/min, attaching a back surface fabric 5 to the back surface of the non-woven fabric 4, placing the compounded finished fabric for a certain time, and (3) completely drying the glue, and increasing the composite fastness to obtain the fabric.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The oil-proof anti-fouling flame-retardant composite fiber fabric comprises a base fabric (1), and is characterized in that flame-retardant layers (2) are arranged on the upper surface and the lower surface of the base fabric (1), waterproof and anti-fouling layers (3) are respectively arranged on the sides, repellent to each other, of the two flame-retardant layers (2), a non-woven fabric (4) is arranged below the base fabric (1), the upper surface of the non-woven fabric (4) is bonded to the lower surface of the waterproof and anti-fouling layer (3) at the bottom of the flame-retardant layer (2), and a back fabric (5) is bonded to the bottom of the non-woven fabric (4);
the oil-proof anti-fouling flame-retardant composite fiber fabric is prepared from the following materials: the material comprises the following components in parts by weight: 10-20 parts of base fabric (1), 10-20 parts of flame retardant layer (2), 10-20 parts of waterproof and antifouling layer (3), 2-4 parts of non-woven fabric (4), 10-20 parts of back fabric (5), 2-4 parts of mildew preventive and 2-4 parts of antistatic agent;
the mixing preparation process of the mildew preventive, the antistatic agent and the base fabric (1) is as follows:
completely diluting the mildew preventive and the antistatic agent in clean water, soaking the base fabric (1) for 10 minutes, rolling the soaked base fabric (1) with 70% of water, and drying at the temperature of below 180 ℃ to obtain the base fabric (1) mixed with the mildew preventive and the antistatic agent.
2. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the flame-retardant layer (2) consists of 20-30 parts of clear water and 2-4 parts of flame retardant;
the preparation process of the flame-retardant layer (2) is as follows:
completely diluting a flame retardant in clear water to obtain a mixture a, soaking the base fabric (1) in the mixture a for 20 minutes, controlling the temperature of the mixture a not to exceed 80 ℃, rolling the soaked base fabric (1) with 70% of water at the temperature lower than 80 ℃, and drying at the temperature below 180 ℃ to obtain the base fabric (1) mixed with the flame retardant layer (2).
3. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the waterproof and antifouling layer (3) consists of 1-2 parts of acetic acid, 20-30 parts of clear water, 5-10 parts of fluorine-free waterproof finishing agent, 5-10 parts of fluorine-free water splashing preventive agent and 4-8 parts of penetrating agent;
the preparation process of the waterproof and antifouling layer (3) is as follows:
completely diluting 0.5ml/l of 60% acetic acid in clean water to obtain a mixture b, adding 10-20g/l of penetrating agent into the mixture b, adding 30-60 g/l of fluorine-free waterproof finishing agent and 15-30 g/l of fluorine-free anti-splashing agent into the mixture b, stirring to obtain a mixture c, soaking the base fabric (1) mixed with the flame-retardant layer (2) in the mixture c for 15 minutes, controlling the temperature of the mixture c to be not more than 40 ℃, rolling the soaked flame-retardant layer (2) for 20-40% of moisture, and drying the base fabric (1) mixed with the flame-retardant layer (2) in a setting machine with the temperature of 150 ℃ and the speed of 22m/min to obtain the base fabric (1) mixed with the flame-retardant layer (2) and the waterproof and anti-staining layer (3).
4. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the compounding process of the oil-proof anti-fouling flame-retardant composite fiber fabric comprises the following steps:
adding glue into the back surface of the base fabric (1) mixed with the flame-retardant layer (2) and the waterproof and antifouling layer (3) through a glue groove by a cloth guide device, attaching the glue to 30g/m2 non-woven fabric (4) on the cloth guide device, bonding the back fabric (5) to the bottom of the non-woven fabric (4), heating the back fabric by a large roller at the temperature of 140 ℃ and at the rotating speed of 15-20m/min, and thus obtaining the oil-proof, antifouling and flame-retardant composite fiber fabric.
5. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the flame retardant is one or more of antimony trioxide, magnesium hydroxide and aluminum hydroxide.
6. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the mildew preventive is any one of organic mercury salt, organic copper salt, organic tin salt, inorganic salt copper sulfate, mercuric chloride and sodium fluoride.
7. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the antistatic agent is one or more of amine salt, quaternary ammonium salt and alkyl amino acid salt.
8. The oil-resistant anti-fouling flame-retardant composite fiber fabric according to claim 1, characterized in that: the non-woven fabric (4) is made of any one of terylene, polypropylene fiber, chinlon, spandex and acrylon.
CN202110323779.0A 2021-03-26 2021-03-26 Oil-proof anti-fouling flame-retardant composite fiber fabric Pending CN113290951A (en)

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Application publication date: 20210824

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