CN113275376A - Device and method for repairing polluted soft clay - Google Patents

Device and method for repairing polluted soft clay Download PDF

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Publication number
CN113275376A
CN113275376A CN202110702180.8A CN202110702180A CN113275376A CN 113275376 A CN113275376 A CN 113275376A CN 202110702180 A CN202110702180 A CN 202110702180A CN 113275376 A CN113275376 A CN 113275376A
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China
Prior art keywords
electrode chamber
electrode
soft clay
electrodes
hose
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Pending
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CN202110702180.8A
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Chinese (zh)
Inventor
孙召花
侯昀
吴添玥
谈皖霞
路雷
徐益康
刘永亮
秦昊
赵鑫
陈昶昊
孙万青
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Nantong University
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Nantong University
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Priority to CN202110702180.8A priority Critical patent/CN113275376A/en
Priority to LU500806A priority patent/LU500806B1/en
Priority to PCT/CN2021/104107 priority patent/WO2022110808A1/en
Publication of CN113275376A publication Critical patent/CN113275376A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • B09C1/085Reclamation of contaminated soil chemically electrochemically, e.g. by electrokinetics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a device for repairing polluted soft clay, which comprises an electrode chamber, a conductive system and a pollutant extraction system, wherein the electrode chamber is provided with a plurality of electrodes; the electrode chamber is arranged into a single cylinder or formed by nesting a plurality of cylinders, wherein one end of the outermost cylinder in the electrode chamber formed by nesting the plurality of cylinders is provided with a bracket cover, and the bracket cover is provided with an electrode hole; the conductive system comprises a plurality of electrodes and a direct-current power supply, the electrodes are connected to two ends of the direct-current power supply through leads, the electrodes are vertically arranged and penetrate through electrode holes of the support cover to extend into electrolyte of the electrode chamber, and the electrodes are not in direct contact with soil body; the pollutant extraction system comprises a liquid storage bottle, a peristaltic pump and a pollutant purifier; the device disclosed by the invention is simple in structure and convenient to operate, can automatically perform timing shutdown, starting and timing and quantitative adjustment on the volume of the electrolyte, improves the working efficiency and is more intelligent.

Description

Device and method for repairing polluted soft clay
Technical Field
The invention belongs to the technical field of environmental protection, and particularly relates to a device and a method for repairing polluted soft clay.
Background
In areas with developed economy, dense population and frequent industrial and agricultural production activities, wastes produced in industrial production permeate into soil layers due to unorganized discharge or failure of discharge systems, so that physical, mechanical and chemical properties of the soil are changed, engineering activities are directly influenced, or the wastes are harmful to human health, animal reproduction and plant growth. The polluted soil inevitably meets soft clay and is polluted by different types, such as nitrogen and phosphorus nutrient salt pollution, heavy metal pollution, organic matter pollution, compound pollution and the like. The polluted soft clay has the characteristics of high water content, low permeability, fine particles, large specific surface area and the like, and pollutants such as heavy metals have great influence on the engineering performance of the soil body through ion exchange, the thickness change of an electric double layer and the dissolution and corrosion of cementing materials among particles, so that the compactness and the strength of the soil body are further reduced, the cementing force among soil particles is reduced, and the loss of beneficial minerals is accelerated.
The pollution soft clay is subjected to harmless treatment and then is recycled, so that the environment can be protected, the resources can be saved, and the method is one of the hot subjects of the current domestic and foreign researches. The existing treatment technology of the polluted soft clay comprises a solidification method, a heat drying method, an incineration method, a biological method, an electric remediation method and the like, wherein the solidification method is the most common stable technology, but when the external environment changes, pollutants are still released and the environment pollution is possibly caused, the heat drying method and the incineration method have large damage to the soil body property, the investment cost is high, and the composting and bioremediation method consumes long time. The electric restoration technology can enable pollutants to migrate under the action of a direct current electric field to achieve the purpose of removal, reduce the environmental risk caused by post-treatment of the polluted soft clay, and meet the requirement of resource utilization of the polluted soft clay. However, the conventional electric remediation technology for contaminated soil is usually developed in an indoor model test, wherein electrolyte chambers are arranged at two ends of a soil body, and electrodes are put into electrolyte and connected with a direct current power supply through a lead, so that the purpose of conducting ions through the electrolyte is achieved. However, this indoor implementation of electro-kinetic remediation techniques is difficult to apply to actual projects in the field. Therefore, the electric repairing technology needs to be innovative to realize the on-site in-situ repairing of the polluted soft clay.
Disclosure of Invention
The present invention provides a device for repairing contaminated soft clay and a repairing method thereof, so as to solve the defects or problems in the background art.
In order to achieve the above object, an embodiment of the present invention provides an apparatus for repairing contaminated soft clay, which is characterized in that the apparatus comprises an electrode chamber, a conductive system and a contaminant extraction system;
the electrode chamber is arranged into a single cylinder or formed by nesting a plurality of cylinders, wherein one end of the outermost cylinder in the electrode chamber formed by nesting the plurality of cylinders is provided with a bracket cover, and the bracket cover is provided with an electrode hole;
the conductive system comprises a plurality of electrodes and a direct-current power supply, the electrodes are vertically arranged and extend into electrolyte of the electrode chamber after penetrating through electrode holes of the support cover, and the electrodes are not in direct contact with soil body;
the pollutant extraction system comprises a liquid storage bottle, a peristaltic pump and a pollutant purifier; the liquid storage bottle is connected with a peristaltic pump or a pollutant purifier through a hose, and the peristaltic pump or the pollutant purifier is connected with an electrode chamber through a hose.
In a further embodiment of the present invention, the holder cover is provided with a hose hole, one end of the hose enters the electrode chamber through the hose hole on the holder cover, and the other end of the hose is connected with the peristaltic pump, the pollutant purifier or the liquid storage bottle.
In a further embodiment of the invention, one side of the electrode chamber of a single cylinder is provided with an upper nozzle, one end of the hose is connected with the electrode chamber through the upper nozzle, and the other end of the hose is connected with a peristaltic pump, a pollutant purifier or a liquid storage bottle.
In a further embodiment of the invention, the electrode chamber at least comprises an innermost barrel and an outermost barrel, wherein the height of the innermost barrel is 1.2-1.5 times of that of the other barrels, the electrode chamber can be used for sequentially unfolding the nested barrels through lifting, and the two adjacent unfolded barrels are fixedly connected through a buckle at the end part.
In a further embodiment of the invention, the support cover is provided with internal threads which can be connected with external threads of the port of the cylinder at the outermost layer of the electrode chamber, and the electrode holes on the support cover are supported by 4 skeletons.
In a further embodiment of the invention, said electrodes are fixed in the electrode compartment by means of a holder cover, and said electrodes in the field may be arranged in the form of a rectangle, a ring or a quincunx.
In a further embodiment of the invention, a water level sensor is arranged in the electrode chamber, the water level sensor is used for monitoring the water level of the electrode chamber and sending a water level signal to the controller, and the water level sensor and the controller are matched for controlling the peristaltic pump and the pollution purifier to automatically operate.
The embodiment of the invention also provides a method for repairing polluted soft clay by adopting the device for repairing polluted soft clay, which is characterized by comprising the following steps:
s1, vertically pressing the innermost barrel of the electrode chamber exceeding the length parts of other barrels into the polluted soft clay according to the design requirement, and putting the cleaned sand into the bottom of the electrode chamber to be 3-5 cm thick;
s2, screwing the bracket cover with the port of the barrel body on the outermost layer of the electrode chamber, feeding the electrode into the electrode chamber through the electrode hole of the bracket cover, wherein the electrode is not contacted with the soil body in the electrode chamber, fixing the electrode on the central axis of the electrode chamber by adjusting the framework of the bracket cover, and connecting the electrode with a direct current power supply through a lead as required;
s3, one end of the hose is sent to a preset position of the electrode chamber through a hose hole of the support cover, electrolyte is injected into the electrode chamber to a required scale according to design requirements, a direct-current power supply is started to be electrified, and the polluted soft clay is repaired; if the water level in the electrode chamber monitored by the water level sensor is higher than the set value, connecting the hose of the electrode chamber with a peristaltic pump or a pollutant purifier according to the type of pollutants, controlling the operation of the peristaltic pump or the pollutant purifier, and recovering electrolyte in the electrode chamber through the pollutant purifier when the content of the pollutants in the pollutant purifier is low;
s4, lifting the second layer of the nested cylinder from inside to outside upwards to enable the bottom of the second layer of the nested cylinder to be fixedly connected with the upper port of the innermost layer of the nested cylinder through a buckle, and manually or mechanically pressing down an electrode chamber to repair the deeper layer of the polluted soft clay by adopting the method;
and S5, repeating the polluted soft clay repairing treatment steps to finally realize the treatment of the polluted soft clay.
Further, in the step S2, the electrodes of different arrays are connected by wires according to the arrangement of the electrodes, and then alternately connected to the positive electrode or the negative electrode of the dc power supply, so as to realize the circular progressive energization.
Further, the electrolyte used in step S3 is a chemical reagent for assisting in the precipitation of the contaminants, and the chemical reagent includes a small molecule organic acid, a surfactant and a complexing agent
The technical scheme of the invention has the following beneficial effects: the core of the device for repairing the polluted soft clay is an electrode chamber, the electrode chamber is internally provided with electrolyte containing chemical reagents which are beneficial to separating out pollutants, and the electrode chamber is electrified by the conductive system for repairing through a plurality of nested cylinders or a single cylinder, a support cover, the conductive system and a pollutant extraction system, so that the repairing and treatment of the polluted soft clay are realized, the problem that the existing polluted soil electric repairing technology stays in an indoor experimental study and is difficult to apply to an actual field project is solved, and the basic research results are promoted to be applied. According to the invention, the electrode chamber formed by the nested cylinders is adopted, and the depth is continuously added into the polluted soft clay by the electrode arranged above the ground surface, so that the remediation efficiency of the polluted soft clay is improved. In addition, the invention has simple structure and convenient operation, can automatically and regularly stop, start and regularly and quantitatively adjust the volume of the electrolyte, improves the working efficiency and is more intelligent.
Drawings
Fig. 1 is a schematic view of repairing contaminated soft clay according to embodiment 1 of the present invention.
FIG. 2 is a schematic view showing an initial structure of an electrode chamber in example 1 of the present invention.
Fig. 3 is a schematic structural view of the electrode chamber after being pulled up in example 1 of the present invention.
Fig. 4 is a schematic top view of the electrode chamber in example 1 of the present invention.
Fig. 5 is a schematic structural view of a holder cover in embodiment 1 of the present invention.
Fig. 6 is a schematic view of the single barrel electrode chamber for repairing contaminated soft clay in example 2 of the present invention.
Fig. 7 is a schematic structural view of a single barrel electrode chamber in embodiment 2 of the present invention.
FIG. 8 is a schematic diagram of a method for repairing contaminated soft clay in a cyclic progression manner according to the present invention.
Fig. 9 is a top view of the present invention adopting a cyclic progressive remediation method of contaminated soft clay.
Description of reference numerals: 1. a direct current power supply; 2. polluting the soft clay; 3. an electrode chamber; 4. a wire; 5. cleaning sand; 6. an electrolyte; 7. an unpowered electrode; 8. electrifying the anode; 9. an energized cathode; 10. a power-on mode; 11. a peristaltic pump; 12. a liquid storage bottle; 13. a hose; 14. a pollutant purifier; 15. a bracket cover; 16. an electrode hole; 17. a hose hole; 18. scale lines; 19. an upper nozzle; 20. an innermost cylinder; 21. and an outermost layer cylinder body.
Detailed Description
In order to make the technical problems, technical solutions and advantages of the present invention more apparent, the following detailed description is given with reference to the accompanying drawings and specific embodiments.
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", "front", "rear", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example 1
As shown in fig. 1 to 5, a device for repairing contaminated soft clay comprises an electrode chamber 3 formed by nesting a plurality of barrels, wherein one end of the outermost barrel 21 is screwed with a support cover 15, the support cover 15 is provided with an electrode hole 16 and a hose hole 17, so that the unenergized electrode 7, the energized anode 8, the energized cathode 9 and the hose 13 are conveniently conveyed into the electrode chamber 3, the electrode is fixed by a telescopic framework, the electrode is connected with a direct current power supply 1 through a lead 4, electrolyte 6 is injected into or sucked out of the electrode chamber 3 through a peristaltic pump 11, a contaminant purifier 14, the hose 13, a liquid storage bottle 12 and a water level sensor, and the electrode is placed in the electrolyte 6 of the electrode chamber 3 and is not in direct contact with the contaminated soft clay 2.
The height of the barrel 20 at the innermost layer of the electrode chamber 3 is 1.2-1.5 times of the height of other barrels, the barrels can be unfolded in sequence by lifting, and after the barrels are unfolded, the two adjacent barrels are fixedly connected through a buckle at the end part. The electrode compartments 3 may be arranged in the form of rectangles, rings, rosettes, etc.
In a further embodiment, the electrode chamber 3 is made of PVC, which is very heat resistant even in hot summer, has stability of the main tube, is not easily corroded by sulfur and alkali, and is easy to process, reducing the number of finished products. The hose 13 is a PU pipe with good elasticity and strong toughness.
In a further embodiment, the inner diameter of the innermost cylinder is 100-200 mm, and the wall thickness is 0.2-2 mm; the inner diameter of the hose 13 is 10-40 mm, and the wall thickness is 0.1-2 mm.
Example 2
As shown in fig. 6 and 7, the difference between the embodiment 2 and the embodiment 1 is that when the electrode chamber 3 is a single cylinder, an upper nozzle 19 can be arranged at one end of the cylinder, and the electrode chamber 3 is connected with the peristaltic pump 11 and the pollutant purifier 14 through the upper nozzle 19 and the hose 13.
The device for repairing the polluted soft clay provided by the embodiment 1 of the invention is used for repairing the polluted soft clay, and comprises the following steps:
(1) and vertically pressing the innermost barrel 20 of the electrode chamber 3 exceeding the length parts of other barrels into the polluted soft clay 2 according to the design requirement, and putting the cleaning sand 5 into the bottom of the electrode chamber 3 for 3-5 cm in thickness.
(2) The support cover 15 is screwed with the port of the barrel 21 at the outermost layer of the electrode chamber 3, the electrode is sent into the electrode chamber 3 through the electrode hole 16 of the support cover 15, the electrode is not contacted with the soil body in the electrode chamber 3, the electrode is fixed on the central axis of the electrode chamber 3 by adjusting the framework of the support cover 15, and the electrode is connected with the direct current power supply 1 through the lead 4 according to requirements.
(3) One end of a hose 13 is conveyed into a preset position of an electrode chamber 3 through a hose hole 17 of a support cover 15, electrolyte 6 is injected into the electrode chamber 3 to a certain scale mark 18 according to design requirements, a direct current power supply 1 is started to be electrified, and polluted soft clay is repaired; if the water level in the electrode chamber 3 monitored by the water level sensor is higher than the set value, the hose 13 of the electrode chamber 3 is connected with the peristaltic pump 11 or the pollutant purifier 14 according to the type of the pollutant, and the peristaltic pump 11 or the pollutant purifier 14 is controlled by the controller to operate, when the pollutant content in the pollutant purifier 14 is low, the electrolyte 6 in the electrode chamber 3 is recovered through the pollutant purifier 14, and if the pollutant content is higher than the bearing capacity of the purifier, the electrolyte can be discharged into a specific collection processing device, which is not taken as the protection range of the invention and is not described herein again.
(4) Lifting the second layer of the cylinder body of the nested cylinder body from inside to outside upwards to ensure that the bottom of the second layer of the cylinder body is fixedly connected with the upper port of the innermost layer of the cylinder body through a buckle, and manually or mechanically pressing down an electrode chamber to repair the deeper layer of the polluted soft clay by adopting the method; in this embodiment, the electrode compartment comprises at least an innermost cylinder, a second cylinder and an outermost cylinder.
(5) And repeating the steps of repairing and treating the polluted soft clay, and finally realizing the treatment of the polluted soft clay.
The electrolyte adopted in the step (3) is a chemical reagent which is beneficial to the precipitation of pollutants, such as small molecular organic acid, a surfactant, a complexing agent and the like. When the water level of the electrode chamber 3 corresponding to the anode electrode is lowered to a certain position, the water level sensor transmits a signal to the controller, the controller controls the peristaltic pump 11 to work, so that the electrolyte 6 is added into the electrode chamber 3 through the liquid storage bottle 12, when the electrolyte of the electrode chamber 3 corresponding to the cathode exceeds a certain position, the water level sensor transmits a signal to the controller, the controller controls the pollutant purifier 14 to work, so that the pollutant purifier sucks out and purifies the liquid in the electrode chamber 3 through the hose 13 and then discharges the liquid into the liquid storage bottle 12, and in the embodiment, the pollutant purifier 14 has the function of a pump and can pump the liquid in the electrode chamber 3 into the liquid storage bottle 12.
In the step (2), as shown in fig. 8 and 9, the electrodes and the electrode chambers 3 are annularly arranged, when the number of the electrode rings is 3, the leads of the connecting middle ring and the inner ring are respectively connected with the positive electrode and the negative electrode of the direct current power supply 1, and after the preset electrifying time is reached, the power supply is cut off; then the outer ring and the middle ring electrodes are respectively connected with the anode and the cathode of the direct current power supply 1, and the power supply is cut off after the preset electrifying time is reached; the above two steps are repeated, and the power is circulated in such a way that the power-on mode 10 is as shown by the arrow direction in the figure. When the number of the electrode rings is 4, each ring electrode is connected to a direct current power supply from the inside to the outside to perform cyclic energization in the same manner as the above method. When the number of the electrode rings is 5, the electrodes are similarly circularly electrified, wherein the electrodes at the innermost two rings and the electrodes at the outermost two rings can be electrified simultaneously.
Through the embodiment, the electrode chamber formed by the nested cylinders is adopted, the electrode arranged above the ground surface is continuously added with the depth into the polluted soft clay, the remediation efficiency of the polluted soft clay is improved, the problem that the existing polluted soil electric remediation technology stays in indoor experimental research and is difficult to apply to on-site actual engineering is solved, and the basic research achievement is promoted to be applied.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (10)

1. The device for repairing the polluted soft clay is characterized by comprising an electrode chamber, a conductive system and a pollutant extraction system;
the electrode chamber is arranged into a single cylinder or formed by nesting a plurality of cylinders, wherein one end of the outermost cylinder in the electrode chamber formed by nesting the plurality of cylinders is provided with a bracket cover, and the bracket cover is provided with an electrode hole;
the conductive system comprises a plurality of electrodes and a direct-current power supply, the electrodes are vertically arranged and extend into electrolyte of the electrode chamber after penetrating through electrode holes of the support cover, and the electrodes are not in direct contact with soil body;
the pollutant extraction system comprises a liquid storage bottle, a peristaltic pump and a pollutant purifier; the liquid storage bottle is connected with a peristaltic pump or a pollutant purifier through a hose, and the peristaltic pump or the pollutant purifier is connected with an electrode chamber through a hose.
2. The device for remediating contaminated soft clay as recited in claim 1, wherein the holder cover is provided with a hose hole, one end of the hose enters the electrode chamber through the hose hole on the holder cover, and the other end of the hose is connected with a peristaltic pump, a contaminant purifier or a liquid storage bottle.
3. The device for remediating contaminated soft clay as recited in claim 1, wherein an upper nozzle is disposed at one side of the electrode chamber of a single cylinder, one end of the hose is connected to the electrode chamber through the upper nozzle, and the other end is connected to a peristaltic pump, a contaminant purifier or a liquid storage bottle.
4. The device for remediating contaminated soft clay as claimed in claim 1, wherein the electrode chamber comprises at least an innermost barrel and an outermost barrel, wherein the height of the innermost barrel is 1.2-1.5 times of the height of the other barrels, the electrode chamber can be sequentially unfolded by pulling, and the two adjacent unfolded barrels are fixedly connected by a buckle at the end.
5. The device for remediating contaminated soft clay as recited in claim 1, wherein the rack cover has internal threads for connecting with external threads of the end port of the barrel at the outermost layer of the electrode chamber, and the electrode holes of the rack cover are supported by 4 frames.
6. The device for remediating contaminated soft clay as recited in claim 1, wherein: the electrodes are fixed in the electrode chamber through the support cover, and the electrodes in the field can be arranged in a rectangular, annular or quincunx form.
7. The device for remediating contaminated soft clay as recited in claim 1, wherein: and a water level sensor is arranged in the electrode chamber and used for monitoring the water level of the electrode chamber and sending a water level signal to the controller, and the water level sensor and the controller are matched to control the peristaltic pump and the pollution purifier to automatically operate.
8. Method for repairing contaminated soft clay, using the device according to any one of claims 1 to 7, characterized in that it comprises the following steps:
s1, vertically pressing the innermost barrel of the electrode chamber exceeding the length parts of other barrels into the polluted soft clay according to the design requirement, and putting the cleaned sand into the bottom of the electrode chamber to be 3-5 cm thick;
s2, screwing the bracket cover with the port of the barrel body on the outermost layer of the electrode chamber, feeding the electrode into the electrode chamber through the electrode hole of the bracket cover, wherein the electrode is not contacted with the soil body in the electrode chamber, fixing the electrode on the central axis of the electrode chamber by adjusting the framework of the bracket cover, and connecting the electrode with a direct current power supply through a lead as required;
s3, one end of the hose is sent to a preset position of the electrode chamber through a hose hole of the support cover, electrolyte is injected into the electrode chamber to a required scale according to design requirements, a direct-current power supply is started to be electrified, and the polluted soft clay is repaired; if the water level in the electrode chamber monitored by the water level sensor is higher than the set value, connecting the hose of the electrode chamber with a peristaltic pump or a pollutant purifier according to the type of pollutants, controlling the operation of the peristaltic pump or the pollutant purifier, and recovering electrolyte in the electrode chamber through the pollutant purifier when the content of the pollutants in the pollutant purifier is low;
s4, lifting the second layer of the nested cylinder from inside to outside upwards to enable the bottom of the second layer of the nested cylinder to be fixedly connected with the upper port of the innermost layer of the nested cylinder through a buckle, and manually or mechanically pressing down an electrode chamber to repair the deeper layer of the polluted soft clay by adopting the method;
and S5, repeating the polluted soft clay repairing treatment steps to finally realize the treatment of the polluted soft clay.
9. The method for remediating contaminated soft clay as recited in claim 8, wherein the electrodes of step S2 are connected to the dc power source in a manner that different arrays of electrodes are connected by wires according to the arrangement of the electrodes, and are alternately connected to the positive electrode or the negative electrode of the dc power source to achieve cyclic progressive energization.
10. The method for remediating contaminated soft clay as recited in claim 8, wherein the electrolyte used in the step S3 is a chemical agent for assisting in the precipitation of contaminants, and the chemical agent comprises a small-molecule organic acid, a surfactant and a complexing agent.
CN202110702180.8A 2021-06-24 2021-06-24 Device and method for repairing polluted soft clay Pending CN113275376A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202110702180.8A CN113275376A (en) 2021-06-24 2021-06-24 Device and method for repairing polluted soft clay
LU500806A LU500806B1 (en) 2021-06-24 2021-07-01 Device and method for remedying polluted soft clay
PCT/CN2021/104107 WO2022110808A1 (en) 2021-06-24 2021-07-01 Apparatus for remediation of contaminated soft clay and remediation method for same

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Application Number Priority Date Filing Date Title
CN202110702180.8A CN113275376A (en) 2021-06-24 2021-06-24 Device and method for repairing polluted soft clay

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WO (1) WO2022110808A1 (en)

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CN108213070A (en) * 2018-01-10 2018-06-29 清华大学 A kind of original position is electronic-device and method of electrochemistry collaboration repairing polluted soil and underground water
CN108380660A (en) * 2018-01-30 2018-08-10 上海岩土工程勘察设计研究院有限公司 Multi-level injection method in situ for contaminated site
CN109108066A (en) * 2018-10-19 2019-01-01 中冶京诚工程技术有限公司 A kind of electronic-chemical combined repair system and method for organic material contaminated soil
CN110293125A (en) * 2019-04-28 2019-10-01 南通大学 It is a kind of original position electro reclamation and reinforce ultra-soft Polluted Soil device and method

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Application publication date: 20210820