CN112978871A - Device based on electrooxidation coupling electrocoagulation handles rubbish leachate membrane concentrate - Google Patents
Device based on electrooxidation coupling electrocoagulation handles rubbish leachate membrane concentrate Download PDFInfo
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- CN112978871A CN112978871A CN202110211649.8A CN202110211649A CN112978871A CN 112978871 A CN112978871 A CN 112978871A CN 202110211649 A CN202110211649 A CN 202110211649A CN 112978871 A CN112978871 A CN 112978871A
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- 238000006056 electrooxidation reaction Methods 0.000 title claims abstract description 27
- 239000012528 membrane Substances 0.000 title claims abstract description 21
- 230000008878 coupling Effects 0.000 title claims abstract description 18
- 238000010168 coupling process Methods 0.000 title claims abstract description 18
- 238000005859 coupling reaction Methods 0.000 title claims abstract description 18
- 238000009297 electrocoagulation Methods 0.000 title claims description 15
- 239000012141 concentrate Substances 0.000 title claims description 12
- 238000005188 flotation Methods 0.000 claims abstract description 22
- 238000005189 flocculation Methods 0.000 claims abstract description 19
- 239000010802 sludge Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000000149 chemical water pollutant Substances 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 238000005691 oxidative coupling reaction Methods 0.000 claims 3
- 239000002699 waste material Substances 0.000 claims 1
- 230000016615 flocculation Effects 0.000 abstract description 9
- 230000007547 defect Effects 0.000 abstract description 4
- 230000005684 electric field Effects 0.000 abstract description 4
- 239000012295 chemical reaction liquid Substances 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000006479 redox reaction Methods 0.000 abstract 1
- 239000002893 slag Substances 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 description 17
- 231100000719 pollutant Toxicity 0.000 description 17
- 238000000034 method Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 10
- 239000008394 flocculating agent Substances 0.000 description 6
- 238000011065 in-situ storage Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 229940095100 fulvic acid Drugs 0.000 description 1
- 239000002509 fulvic acid Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/06—Contaminated groundwater or leachate
Abstract
The invention discloses a device for treating garbage leachate membrane concentrated solution based on electrooxidation coupling electroflocculation, which comprises a reactor, two anode plates, two cathode plates, a plurality of bipolar plates, a direct current power supply, an external circulation device and the like, wherein the two anode plates are arranged on the reactor; a sludge settling chamber and a sludge discharge pipe are connected below the reactor; two anode plates and two cathode plates are symmetrically arranged in the reactor in an inclined 45-degree manner, the upper end and the lower end of the reactor form a driving electric field, a plurality of bipolar plates are arranged in the middle of the reactor and respectively generate electric flocculation and oxidation reduction reactions under the action of the driving electric field, and an external circulation device drives reaction liquid to circulate in the reactor for multiple times and scour the surfaces of the plates. The invention solves the defects that the air flotation slag is accumulated in the reactor in the electric flocculation process and the polar plates required by the electric flocculation are large and high in energy consumption, and can allow any number of sacrificial electrodes to simultaneously and efficiently perform electric flocculation and electrooxidation pollution removal work under very simple arrangement.
Description
Technical Field
The invention relates to a device for treating landfill leachate membrane concentrated solution, in particular to a device for treating landfill leachate membrane concentrated solution based on electrooxidation coupling electrocoagulation.
Background
At present, the electric flocculation device generally has the defects that a large reaction polar plate is needed in the using process, or the reaction time is long, and air floatation pollutants can enter a solution again, organic pollutants cannot be completely removed by single electric flocculation, a combined process is needed for treatment, however, the total mass transfer efficiency between serially connected combined process reactors is low, the occupied area is increased, the energy consumption is increased, the connection between a corrosion electrode and an external power supply and the connection between electrodes are generally connected by using a lead, contact corrosion can be generated at the connection part in the system operation process, further, the corrosion of a working electrode in the electric flocculation device is accelerated, the problems that the contact at the electrode connection part is poor and the like are easily caused, and the normal operation of a circuit is influenced. These problems increase the complexity of the production operation and maintenance of the electroflocculation plant and the operational stability of the system.
The single electrooxidation process is adopted to treat the high-concentration organic wastewater, and although the removal of low-valence ions and the mineralization of refractory organic matters (such as humic acid and fulvic acid) can be realized, the problems of low electrooxidation efficiency and large energy consumption exist. Even with the coupled electrocoagulation reactor, the traditional vertical polar plates are perpendicular to the direction of an electric field, so the reactor structure needs large reaction polar plates and high current density, and the flocculant generated in situ is often insufficient to treat large-flow industrial wastewater.
Aiming at the current ubiquitous practical bottleneck problem, more 'flocculating agents' need to be generated in situ, generated air-flotation pollutants are timely removed in a simple mode, the treatment effect is enhanced through process coupling, and a lead is not adopted to connect a polar plate. Although patents report a method of enhancing the in-situ generation of more "flocculants" by electrocoagulation and a bipolar generation method of electrocoagulation such as (patent CN107459113A — a radio flocculation water treatment device based on bipolar electrochemical principle), the horizontally disposed bipolar electrocoagulation electrode is easy to accumulate flocculated sediments, so that the amount of flocculants generated in situ in the electric field is greatly reduced, and the device has no way to mix and adsorb the generated flocculants with the pollutants in the solution in time to effectively generate flocs. Although the flocculation process of coupling electrooxidation is reported in documents or patents, the process needs to be controlled by additional drugs and more processes, which consumes manpower and material resources and increases the cost.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides a device for treating the garbage percolate membrane concentrated solution based on electrooxidation coupling electroflocculation.
The invention is realized by adopting the following technical scheme:
a device for treating garbage leachate membrane concentrated solution based on electrooxidation coupling electroflocculation comprises a reactor, two anode plates, two cathode plates, a plurality of bipolar plates, a direct current power supply and an external circulation device; wherein the content of the first and second substances,
a sludge settling chamber is communicated below the reactor, and a sludge discharge pipe is communicated below the sludge settling chamber; two anode plates are symmetrically arranged above the reactor, two cathode plates are symmetrically arranged below the reactor, a plurality of bipolar plates are arranged in the middle of the reactor, and the anode and the cathode of a direct current power supply are respectively connected with the anode plates and the cathode plates;
the outer wall of the reactor is provided with a water inlet at a position close to the upper part of the anode plate and communicated with a water inlet pipe, and is provided with a water outlet at a position close to the upper part of the cathode plate and communicated with a water outlet pipe; the external circulation device is communicated with the outer wall close to the bipolar plate reactor.
The invention is further improved in that a plurality of groups of electro-oxidation and electro-flocculation reactions can be realized in the reactor, wherein the electro-flocculation reactions are generated at the upper ends of a plurality of bipolar electrodes, and the electro-oxidation reactions are generated at the lower ends of the bipolar electrodes.
The further improvement of the invention is that the upper part of the reactor is communicated with an air flotation chamber, an air flotation groove which is arranged downwards is arranged in the air flotation chamber, and the lowest end of the air flotation groove is communicated with a scum discharge pipe.
The invention is further improved in that the inclination angle of the air flotation groove is 45 degrees.
A further improvement of the invention is that the anode plate is any one of dimensionally stable titanium-based oxide electrodes.
The invention has the further improvement that the shape of the bipolar plate is parallel to the cathode and the anode, and the inside of the bipolar plate is used as the bipolar electrode by a rectangular plate which is provided with vertical positive and negative plates.
A further improvement of the invention is that the bipolar plates are placed perpendicular to the anode and cathode plates.
The invention is further improved in that the bipolar plate is an iron net or an iron plate.
The invention is further improved in that the bipolar plate is arranged in the middle of the reactor through a bipolar plate fixing device, and the bipolar plate fixing device is in a clamping groove form.
The invention is further improved in that the external circulating device comprises a circulating pipeline communicated with the outer wall close to the bipolar plate reactor, and a gate valve and a circulating pump are arranged on the circulating pipeline.
Compared with the prior art, the invention has at least the following beneficial technical effects:
on the basis of the conventional series combination process, the electrooxidation and electroflocculation technology is embedded into one reactor, so that the reactor units are more compact, and the synergistic mass transfer effect and efficiency among the units are improved; a plurality of groups of bipolar polar plates (iron nets or iron plates) vertical to the positive and negative polar plates are arranged, so that a large amount of flocculating agents and various free radicals with strong oxidizing capability are generated in situ more effectively and rapidly, and the synergistic pollution removal effect of electric flocculation and electric oxidation is exerted; the external circulation device is arranged, flocs accumulated on the surface of the polar plate are automatically removed through circulation of the reaction liquid, the working efficiency of the polar plate is improved, and the pollutant removal effect is enhanced through multiple circulating reactions of the reaction liquid in the reactor; the rotary overflow air flotation tank is arranged, the sludge collecting tank is arranged, air flotation pollutants generated in the working process are discharged out of the reactor in time, and the pollutant removing effect and the working efficiency of the reactor are improved.
The invention realizes multiple synergistic removal effects of multiple groups of electro-oxidation and electro-flocculation, electro-Fenton-like and the like on organic matters and enhanced pollution removal effect generated by adding external circulation, so that the mass transfer is more uniform and efficient, the treatment effect is better, the timely removal of air-floating pollutants is realized, and the application bottleneck problem of poor independent treatment effect of the electro-flocculation and the electro-oxidation is economically and effectively solved. Multiple reaction characteristics are realized in one reactor, the problem of large occupied area of the traditional series device is solved, the single reactor is simple to operate, and the efficiency of removing pollutants cooperatively is higher; the air flotation tank with the rotary gradient is designed, the problem that air flotation pollutants enter a solution again is creatively solved, the electro-oxidation and electro-flocculation technology is embedded into one reactor, the removal process only consumes once electric quantity, a flocculating agent is not required to be added, the current utilization efficiency is high, the pollutant removal efficiency is high, and the defects of large polar plates and long reaction time are overcome by multiple groups of bipolar polar plates. The coupling device has a wide practical application prospect in the deep treatment process of the landfill leachate.
Drawings
FIG. 1 is a schematic diagram of the structure of the apparatus of the present invention.
Description of reference numerals:
1. the device comprises an air flotation chamber, 2. an air flotation tank, 3. a scum discharge pipe, 4. an anode plate, 5. a plate fixing device, 6. a bipolar plate fixing device, 7. a bipolar electrode, 8. a cathode plate, 9. a sludge settling chamber, 10. a sludge discharge pipe, 11. a device support frame, 12. a circulation pipeline, 13. a gate valve, 14. a circulation pump, 15. a water inlet pipe, 16. a water outlet pipe, 17. a direct current power supply and 18. a flange plate.
Detailed Description
The invention is further described below with reference to the following figures and examples.
As shown in fig. 1, the device for treating the landfill leachate membrane concentrated solution based on electrooxidation coupling electroflocculation provided by the invention comprises a reactor, two anode plates 4, two cathode plates 8, a plurality of bipolar plates 7, a direct current power supply 17 and an external circulation device; wherein, the upper part of the reactor is communicated with an air flotation chamber 1, an air flotation groove 2 which is arranged in a downward inclination way is arranged in the air flotation chamber 1, the lowest end of the air flotation groove 2 is communicated with a scum discharge pipe 3, the lower part of the reactor is communicated with a sludge settling chamber 9 through a flange plate 18, the lower part of the sludge settling chamber 9 is communicated with a sludge discharge pipe 10, and a device support frame 11 is arranged below the sludge settling chamber 9; two anode plates 4 are symmetrically arranged at the upper part in the reactor, two cathode plates 8 are symmetrically arranged at the lower part in the reactor, a plurality of bipolar plates 7 are arranged at the middle part in the reactor, and the anode and the cathode of a direct current power supply 17 are respectively connected with the anode plates 4 and the cathode plates 8; the outer wall of the reactor is provided with a water inlet close to the position above the anode plate 4 and communicated with a water inlet pipe 15, and is provided with a water outlet close to the position above the cathode plate 8 and communicated with a water outlet pipe 16; the external circulation device is communicated with the outer wall of the reactor close to the bipolar plate 7, the external circulation device comprises a circulation pipeline 12 communicated with the outer wall of the reactor close to the bipolar plate 7, and a gate valve 13 and a circulation pump 14 are arranged on the circulation pipeline 12.
The landfill leachate membrane concentrate that will handle gets into the reactor by inlet tube 15 to being full of the reactor, wherein there is the air supporting groove 2 to be the rotation type slope to dross discharge pipe 3, in order to present good air supporting from landing to dross discharge pipe 3, its inclination is 45, the air supporting pollutant flows to the scum pipe through the slope automatically and discharges, prevent that the pollutant from getting into solution again, then open DC power supply 17, open circulating pump 14 switch simultaneously, the water sample of handling back in the flocculation coagulation bundle reactor flows out by outlet pipe 16 after the reaction finishes. Wherein anode plate 4 is the rectangle, and is fixed through the draw-in groove, and it is 45 to place the angle, in order to let the mud of sediment can the landing to the lower part, also lets the quick arrival top of air supporting pollutant overflow to air supporting groove 2 simultaneously. Wherein the bipolar electrode is vertical to the upper and lower polar plates and fixed by a special clamping groove. Wherein the air-float pollutants enter air-float scum through overflow and are collected, and the collecting tank is obliquely screwed to a scum output pipe.
Preferably, the electrocatalytic anode plate 4 is two dimensionally stable rectangular anode plates of titanium-based oxide type; two anode plates 4 and two cathode plates 8 are respectively arranged on the side wall of the reactor through a plate fixing device 5.
Preferably, the electrocatalytic cathode plates 8 are two graphite type rectangular cathode plates;
preferably, the bipolar electrode is a plurality of rectangular iron plates or iron nets with the same size;
preferably, the fixing device for the cathode and anode plates is in a self-made inclined socket type;
preferably, the bipolar plate 7 is arranged in the middle inside the reactor by means of a bipolar plate fixing device 6, and the bipolar plate fixing device 6 is in the form of a clamping groove.
The invention provides a device for treating landfill leachate membrane concentrated solution based on electrooxidation coupling electrocoagulation, which is applied to the treatment of industrial wastewater of the landfill leachate membrane concentrated solution, and comprises the following steps:
(1) under the action of the water inlet pump, the concentrated solution wastewater enters the reactor through the water inlet pipe 14 and the water inlet;
(2) meanwhile, a direct current power supply 17 is switched on, the voltage is controlled to be 1.5-4V, and electrolysis is carried out for 1.5-2.0 h;
(3) meanwhile, the circulating pump 14 is started to ensure that the liquid has uniform mass transfer, bubbles are generated at the cathode and the anode in the reaction process, the bubbles adhere to pollutants and rise to the top, the pollutants enter the overflow tank in an overflow mode, and the pollutants are discharged from the overflow tank through a scum pipe through gradient descent;
(4) opening a water outlet valve, and allowing the treated water in the reactor to automatically flow out;
(5) after the reaction is finished, flocculating for half an hour, and opening a sludge valve to discharge settled sludge in the sludge collecting tank.
Claims (10)
1. A device for treating garbage leachate membrane concentrated solution based on electrooxidation coupling electroflocculation is characterized by comprising a reactor, two anode plates (4), two cathode plates (8), a plurality of bipolar plates (7), a direct current power supply (17) and an external circulation device; wherein the content of the first and second substances,
a sludge settling chamber (9) is communicated below the reactor, and a sludge discharge pipe (10) is communicated below the sludge settling chamber (9); two anode plates (4) are symmetrically arranged at the upper part in the reactor, two cathode plates (8) are symmetrically arranged at the lower part in the reactor, a plurality of bipolar plates (7) are arranged at the middle part in the reactor, and the anode and the cathode of a direct current power supply (17) are respectively connected with the anode plates (4) and the cathode plates (8);
the outer wall of the reactor is provided with a water inlet close to the upper part of the anode plate (4) and communicated with a water inlet pipe (15), and is provided with a water outlet close to the upper part of the cathode plate (8) and communicated with a water outlet pipe (16); the external circulation device is communicated with the outer wall of the reactor close to the bipolar plate (7).
2. The device for treating the garbage leachate membrane concentrate based on electrooxidation coupling electrocoagulation according to claim 1, wherein a plurality of groups of electrooxidation and electrocoagulation reactions are realized in the reactor, wherein the upper ends of a plurality of bipolar electrodes are subjected to the electrocoagulation reaction, and the lower ends of the bipolar electrodes are subjected to the electrooxidation reaction.
3. The device for treating the refuse leachate membrane concentrate based on electrooxidation coupling and electroflocculation according to claim 1, wherein an air flotation chamber (1) is communicated with the upper part of the reactor, an air flotation tank (2) which is obliquely arranged downwards is arranged in the air flotation chamber (1), and the lowest end of the air flotation tank (2) is communicated with a scum discharge pipe (3).
4. An apparatus for the treatment of landfill leachate membrane concentrate based on electro-oxidative coupling electro-flocculation as claimed in claim 3, wherein the inclination angle of the air flotation tank (2) is 45 °.
5. An apparatus for the treatment of leachate membrane concentrate of refuse based on electro-oxidative coupling electro-flocculation according to claim 1, wherein the anode plate (4) is any one of the titanium-based oxide electrodes with stable dimensions.
6. The device for treating the refuse leachate membrane concentrate based on electrooxidation coupling electrocoagulation according to claim 1, wherein the bipolar plate (7) is parallel to the cathode and the anode in shape, and the inside of the bipolar plate (7) is used as a bipolar electrode by a rectangular plate with vertical positive and negative plates.
7. An apparatus for the treatment of leachate membrane concentrate of waste based on electro-oxidative coupling electro-flocculation as claimed in claim 1, wherein the bipolar plate (7) is placed perpendicular to the anode plate (4) and the cathode plate (8).
8. The device for treating the landfill leachate membrane concentrate based on electrooxidation coupling electrocoagulation as claimed in claim 1, wherein the bipolar plate (7) is an iron net or an iron plate.
9. The device for treating the landfill leachate membrane concentrate based on electrooxidation coupling electrocoagulation as recited in claim 1, wherein the bipolar plate (7) is arranged in the middle of the reactor through a bipolar plate fixing device (6), and the bipolar plate fixing device (6) is in the form of a clamping groove.
10. The device for treating the landfill leachate membrane concentrate based on electrooxidation coupling electrocoagulation according to claim 1, wherein the external circulation device comprises a circulation pipeline (12) communicated with the outer wall of the reactor close to the bipolar plate (7), and the circulation pipeline (12) is provided with a gate valve (13) and a circulation pump (14).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110211649.8A CN112978871A (en) | 2021-02-25 | 2021-02-25 | Device based on electrooxidation coupling electrocoagulation handles rubbish leachate membrane concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110211649.8A CN112978871A (en) | 2021-02-25 | 2021-02-25 | Device based on electrooxidation coupling electrocoagulation handles rubbish leachate membrane concentrate |
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| CN112978871A true CN112978871A (en) | 2021-06-18 |
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| CN202110211649.8A Pending CN112978871A (en) | 2021-02-25 | 2021-02-25 | Device based on electrooxidation coupling electrocoagulation handles rubbish leachate membrane concentrate |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120031852A1 (en) * | 2009-04-06 | 2012-02-09 | Sa Envitech S.R.L. | Graphene based electrodes for electrochemical reactions, and electrooxidation process for the removal of contaminants from liquids using said electrodes |
| CN203360450U (en) * | 2013-06-21 | 2013-12-25 | 广州甘蔗糖业研究所 | Air floatation clarifier |
| CN107459113A (en) * | 2017-09-19 | 2017-12-12 | 云智前沿科技发展（深圳）有限公司 | A kind of radio flocculation water treatment facilities based on bi-polar electrochemical principle |
| CN110980891A (en) * | 2019-12-17 | 2020-04-10 | 昆明理工大学 | Tower type electric flocculation water treatment device |
| CN212151715U (en) * | 2020-03-04 | 2020-12-15 | 桂润环境科技股份有限公司 | Electrochemical device for treating lead-zinc industrial mineral processing wastewater |
-
2021
- 2021-02-25 CN CN202110211649.8A patent/CN112978871A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120031852A1 (en) * | 2009-04-06 | 2012-02-09 | Sa Envitech S.R.L. | Graphene based electrodes for electrochemical reactions, and electrooxidation process for the removal of contaminants from liquids using said electrodes |
| CN203360450U (en) * | 2013-06-21 | 2013-12-25 | 广州甘蔗糖业研究所 | Air floatation clarifier |
| CN107459113A (en) * | 2017-09-19 | 2017-12-12 | 云智前沿科技发展（深圳）有限公司 | A kind of radio flocculation water treatment facilities based on bi-polar electrochemical principle |
| CN110980891A (en) * | 2019-12-17 | 2020-04-10 | 昆明理工大学 | Tower type electric flocculation water treatment device |
| CN212151715U (en) * | 2020-03-04 | 2020-12-15 | 桂润环境科技股份有限公司 | Electrochemical device for treating lead-zinc industrial mineral processing wastewater |
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Application publication date: 20210618 |