CN113273660B - Green preparation system and method for moisture-resistant food deoxidizer - Google Patents

Green preparation system and method for moisture-resistant food deoxidizer Download PDF

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Publication number
CN113273660B
CN113273660B CN202110307780.4A CN202110307780A CN113273660B CN 113273660 B CN113273660 B CN 113273660B CN 202110307780 A CN202110307780 A CN 202110307780A CN 113273660 B CN113273660 B CN 113273660B
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China
Prior art keywords
pressing
base cloth
deoxidizing
cloth layer
deoxidizer
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CN113273660A (en
Inventor
薛从福
卢灯荣
沈文辉
何承政
戴文智
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Fujian Jixian Biotechnology Co ltd
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Fujian Jixian Biotechnology Co ltd
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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23L3/3418Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • A23L3/3427Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
    • A23L3/3436Oxygen absorbent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0004Cutting, tearing or severing, e.g. bursting; Cutter details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • B32B2037/1215Hot-melt adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • B32B2262/0284Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a green preparation system and method of a moisture-resistant food deoxidizer, which belong to the technical field of food preservation and sequentially comprise a deoxidizing carrier forming device, a deoxidizing carrier impregnating device, a deoxidizing carrier adhering device, a dicing device and a packaging device, wherein the deoxidizing carrier forming device sequentially comprises an opener, a net forming machine and a needling machine, and the deoxidizing carrier adhering device is an ultrasonic composite device capable of realizing ultrasonic hot-pressing welding of three sheets. The beneficial effects of the invention are as follows: through ultrasonic hot-pressing welding, the composite cost can be reduced, and the space structures inside the first base cloth layer and the second base cloth layer can be kept from being damaged to the greatest extent.

Description

Green preparation system and method for moisture-resistant food deoxidizer
Technical Field
The invention relates to the technical field of food preservation, in particular to a green preparation system and method of a moisture-resistant food deoxidizer.
Background
Spoilage of foods is the most prominent of the quality and safety problems of foods, and brings about a huge economic loss worldwide every year. The key factor causing food spoilage is the growth and metabolism of microorganisms, and the essential factor is that the nutrients such as protein, carbohydrate and fat in the food are decomposed by degrading enzymes secreted by the microorganisms, for example, protein decomposition products include substances such as amines, hydrogen sulfide, mercaptan, indole and skatole which are aversive after being smelled; fatty rancidity produces aldehydes, ketones, etc., and further breaks down to develop a particular rancidity taste. In addition, tissue ulceration, mucus filth and the like of the appearance of the food seriously affect the sensory and hygienic quality of the food, and reduce or lose the use value. The food spoilage not only reduces the nutritive value of the food and causes people to feel aversion, but also can generate various toxic and harmful substances to cause people to suffer acute poisoning or to suffer chronic poisoning, and in order to achieve the purposes of preserving and preserving the food and prolonging the shelf life and the shelf life of the food, various preservation technologies such as refrigeration, irradiation and the like are adopted, but more convenient and economic technologies are a method for preserving the food by adopting deoxidizing agents or preservation cards, for example, chinese patent CN103653185A discloses a moisture-proof deoxidizing agent for the food, which consists of 90-110 parts of iron powder, 5-15 parts of calcium chloride, 5-15 parts of active carbon and 20-40 parts of auxiliary materials; wherein the auxiliary materials are attapulgite and montmorillonite with a mass ratio of 4-6:4-6. Although the moisture-resistant deoxidizer can maintain deoxidizing performance under high humidity condition and is not easy to turn back water, when the packaging bag of the deoxidizer breaks, food is easy to pollute and can not be eaten, and the deoxidizer is hard particles, so that the deoxidizer is easy to collide with food in the transportation process to damage the appearance of the food.
As another example, chinese patent CN107215044a discloses a fresh-keeping card for alcohol flake food and a manufacturing method thereof, comprising a card body made into flake, wherein the card body comprises a first film layer, a substrate layer and a second film layer, the substrate layer is made of a cloth-based material with alcohol, the first film layer is fixedly connected to the bottom surface of the substrate layer by an adhesive, and the second film layer is fixedly connected to the top surface of the substrate layer by an adhesive. Although the anti-mildew agent has good anti-mildew effect, cannot pollute food, can effectively avoid damage to the appearance of the food caused by collision with the food in the transportation process, and has the problems of reduced fresh-keeping effect under the humidity condition and the like.
Disclosure of Invention
The invention discloses a green preparation system and method of a moisture-resistant food deoxidizer, aiming at the problems that the fresh-keeping effect cannot be well processed at the same time in the prior art and foods are easy to be polluted by fresh-keeping materials, and the like.
Through ultrasonic hot-pressing welding, the composite cost can be reduced, and the space structures inside the first base cloth layer and the second base cloth layer can be kept from being damaged to the greatest extent.
Preferably, the deoxidizing carrier adhering device comprises a feeding roller set, a press-attaching workbench and a pressing component, wherein the feeding roller set comprises a first feeding roller set for conveying an upper second base cloth layer, a second feeding roller set for conveying a middle first base cloth layer and a third feeding roller set for conveying a lower second base cloth layer, the feeding roller set is arranged at the inlet position of the press-attaching workbench, and the pressing component is positioned right above the press-attaching workbench.
Preferably, the pressing assembly comprises a pressing plate, a pressing support rod, a pressing driving assembly and an ultrasonic generator, wherein the pressing driving assembly is used for controlling the pressing of the pressing support rod, the pressing support rod is installed on the pressing driving assembly, the pressing plate is fixedly installed at the lower end part of the pressing support rod, and the ultrasonic generator is installed on the pressing support rod. The outer surface of the pressing support rod is also provided with a sliding rail for guiding the pressing support rod to slide up and down.
Preferably, the pushing driving assembly comprises a driving motor, a driven wheel and a cam, wherein the driving motor drives the driven wheel to rotate, a central shaft of the driven wheel is coaxial with a rotating shaft of the cam, and the cam abuts against the upper end of the pushing supporting rod.
Preferably, a driving wheel is installed on the rotating shaft of the driving motor, and the driving wheel and the driven wheel are in transmission through a belt.
Preferably, the lower surface of the lower pressure plate is distributed with a lamination pattern fusion joint for ultrasonic lamination.
Preferably, the laminated pattern melt joint is a matrix sequence, and each pattern unit in the matrix sequence is one of a circle, a rectangle or an ellipse.
Preferably, a limiting plate assembly for limiting the thickness of the adhered composite sheet is arranged behind the pressing assembly.
Preferably, a limiting wheel set for controlling the distance between the composite front base fabrics is arranged in front of the pressing component.
Preferably, a rolling assembly for secondarily compacting the composite sheet is installed at the rear of the limiting plate assembly.
The invention also provides a green preparation method of the moisture-resistant food deoxidizer, which comprises the following steps:
Step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 30-40wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 30-40wt%;
adhering low-melting-point particles on the upper surface and the lower surface of the first base cloth layer, and then enabling the first base cloth layer and the second base cloth layer to be adhered on the upper surface and the lower surface of the first base cloth layer through an adhesion device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
Step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
Preferably, in the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, and the distance L1 between the lower surface of the limiting plate and the press-attaching workbench in the limiting plate assembly is larger than the thickness W of the three layers of base cloth, and is preferably 0< L1-W <0.3mm.
The low-melting-point particles on the surfaces of the first base cloth layer and the second base cloth layer are fused and bonded under the action of ultrasonic vibration, the pressure is released rapidly, then the bonding structure formed by the low-melting-point particles in the process of continuously moving forward of the base cloth layer is still in a semi-fused state and is pulled into a filament bundle shape by the restoring force between the two base cloth layers, the fineness of the filament bundle shape and the filaments are kept relatively stable and are further cooled due to the limitation of the limiting plate component, and then the base cloth layers are compressed again under the action of the rolling component, so that the purpose of adhesion is achieved.
Preferably, in the third step, the distance l2=w between the two limiting wheels on the limiting wheel set.
Preferably, the distance L3 between the two pressing rollers on the pressing assembly in the third step meets 0<W-L3< W/2mm.
Preferably, in the third step, the low-melting point particles are low-melting point polypropylene particles or low-melting point polyester particles, and the melting point is 160-180 ℃.
Preferably, the first deoxidizing solution comprises the following components in percentage by weight:
the water absorption formula system with anhydrous calcium chloride as a main body and the deoxidizing formula system with activated iron powder as a main body are matched to form a film which is adhered to the surface of the fiber inside the first base cloth layer, so that the double-layer effect of water absorption and deoxidization is achieved.
Preferably, the first deoxidizing solution comprises the following components in percentage by weight:
preferably, the second deoxidizing solution comprises the following components in percentage by weight:
preferably, the second deoxidizing solution comprises the following components in percentage by weight:
the deoxidizing formula system with activated iron powder, diatomite and active carbon as main components is adopted, the activated iron powder is used as a base, the diatomite, the active carbon and sodium chloride are used as auxiliary materials, and the deoxidizing formula system is uniformly dispersed in the solution through the combined action of the dispersing agent, the crosslinked starch and the adhesive to form a film which is adhered to the surface of the fiber and keeps stable adhesive force with the surface of the fiber.
The carrier for containing the deoxidizing component is formed by compounding three layers of non-woven fabrics, and when the carrier is in a three-dimensional netlike space structure formed by fiber construction, the deoxidizing solution forms a uniform film on the surface of the fiber during dipping the deoxidizing solution, so that the contact area between the deoxidizing component and the space is greatly increased, and the deoxidizing effect of the deoxidizing agent and the utilization rate of the deoxidizing agent are improved.
The first base cloth layer positioned on the inner layer adopts fibers with finer specification and higher density, has good unidirectional moisture guiding performance, ensures that moisture absorbed from the outer layer can be quickly conducted to the inner layer and absorbed by the drying agent attached to the inner layer fibers, so as to keep the outer layer dry, and the surface of the cross hollow polyester fiber in the inner layer can be attached with more drying agents, and can improve the moisture conducting capacity of the inner layer fibers and the integral deoxidizing effect of the deoxidizer.
The beneficial effects are that:
the technical scheme of the invention has the following beneficial effects:
(1) Through ultrasonic hot-pressing welding, the composite cost can be reduced, and the space structures inside the first base cloth layer and the second base cloth layer can be kept from being damaged to the greatest extent.
(2) The low-melting-point particles on the surfaces of the first base cloth layer and the second base cloth layer are fused and bonded under the action of ultrasonic vibration, the pressure is released rapidly, then the bonding structure formed by the low-melting-point particles in the process of continuously moving forward of the base cloth layer is still in a semi-fused state and is pulled into a filament bundle shape by the restoring force between the two base cloth layers, the fineness of the filament bundle shape and the filaments are kept relatively stable and are further cooled due to the limitation of the limiting plate component, and then the base cloth layers are compressed again under the action of the rolling component, so that the purpose of adhesion is achieved.
(3) The water absorption formula system with anhydrous calcium chloride as a main body and the deoxidizing formula system with activated iron powder as a main body are matched to form a film which is adhered to the surface of the fiber inside the first base cloth layer, so that the double-layer effect of water absorption and deoxidization is achieved.
(4) The deoxidizing formula system with activated iron powder, diatomite and active carbon as main components is adopted, the activated iron powder is used as a base, the diatomite, the active carbon and sodium chloride are used as auxiliary materials, and the deoxidizing formula system is uniformly dispersed in the solution through the combined action of the dispersing agent, the crosslinked starch and the adhesive to form a film which is adhered to the surface of the fiber and keeps stable adhesive force with the surface of the fiber.
(5) The carrier for containing the deoxidizing component is formed by compounding three layers of non-woven fabrics, and when the carrier is in a three-dimensional netlike space structure formed by fiber construction, the deoxidizing solution forms a uniform film on the surface of the fiber during dipping the deoxidizing solution, so that the contact area between the deoxidizing component and the space is greatly increased, and the deoxidizing effect of the deoxidizing agent and the utilization rate of the deoxidizing agent are improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are needed in the embodiments will be briefly described below, it being understood that the following drawings only illustrate some examples of the present invention and therefore should not be considered as limiting the scope, and other related drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a diagram showing the control relationship of a green preparation system for a moisture-resistant food deoxidizer in accordance with the present invention;
FIG. 2 is a schematic view of a preferred deoxidizing carrier adhesive apparatus of the present invention;
FIG. 3 is a partial view of a preferred embodiment of the present invention.
In the figure:
1-deoxidizing carrier adhering means; 2-a feeding roller set; 21-a first feeding roller set;
22-a second feeding roller set; 23-a third feeding roller group; 3-pressing and attaching a workbench; 4-pressing down the assembly;
41-pressing down the laminate; 42-pressing down the support rod; 43-push down drive assembly; 431-driving the motor;
432-driven wheel; 433-cam; 44-an ultrasonic generator; 5-sliding rails; 6, a driving wheel; 7-a belt;
8-laminating a pattern melt joint; 9-a limiting plate assembly; 10-limiting wheel sets; 11-a roll-in assembly;
12-deoxidizing carrier molding device; 121-opener; 122-a web former; 123-needling machine;
13-a deoxidizing support impregnating device; 14-a dicing device; 15-packaging device.
Detailed Description
For the purpose of making the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is apparent that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, based on the embodiments of the invention, which are apparent to those of ordinary skill in the art without inventive faculty, are intended to be within the scope of the invention. Thus, the following detailed description of the embodiments of the invention, as presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, based on the embodiments of the invention, which are apparent to those of ordinary skill in the art without inventive faculty, are intended to be within the scope of the invention.
As shown in fig. 1, the green preparation system of the moisture-resistant food deoxidizer sequentially comprises a deoxidizing carrier forming device 12, a deoxidizing carrier impregnating device 13, a deoxidizing carrier adhering device 1, a dicing device 14 and a packaging device 15, wherein the deoxidizing carrier forming device 12 sequentially comprises an opener 121, a net-forming machine 122 and a needle machine 123, and the deoxidizing carrier adhering device 1 is an ultrasonic composite device capable of realizing ultrasonic hot-pressing welding of three sheets.
Through ultrasonic hot-pressing welding, the composite cost can be reduced, and the space structures inside the first base cloth layer and the second base cloth layer can be kept from being damaged to the greatest extent.
As shown in fig. 2, the deoxidizing carrier adhering device 1 includes a feeding roller set 2, a press-attaching table 3 and a pressing assembly 4, wherein the feeding roller set 2 includes a first feeding roller set 21 for conveying an upper second base cloth layer, a second feeding roller set 22 for conveying a middle first base cloth layer and a third feeding roller set 23 for conveying a lower second base cloth layer, the feeding roller set 2 is disposed at an inlet position of the press-attaching table 3, and the pressing assembly 4 is located directly above the press-attaching table 3.
As shown in fig. 3, the pressing assembly 4 includes a pressing plate 41, a pressing support bar 42, a pressing driving assembly 43 for controlling the pressing of the pressing support bar 42, and an ultrasonic generator 44, the pressing support bar 42 being mounted on the pressing driving assembly 43, the pressing plate 41 being fixedly mounted on a lower end portion of the pressing support bar 42, and the ultrasonic generator 44 being mounted on the pressing support bar 42. The outer surface of the pressing support rod 42 is also provided with a sliding rail 5 for guiding the pressing support rod 42 to slide up and down.
As a preferred embodiment, the pressing driving assembly 43 includes a driving motor 431, a driven wheel 432, and a cam 433, where the driving motor 431 drives the driven wheel 432 to rotate, a central axis of the driven wheel 432 is coaxial with a rotation axis of the cam 433, and the cam 433 abuts against an upper end of the pressing support rod 42.
As a preferred embodiment, the driving motor 431 is rotatably mounted with a driving wheel 6, and the driving wheel 6 and the driven wheel 432 are driven by a belt 7.
As a preferred embodiment, the lower surface of the lower laminate 41 is provided with a laminate pattern fusion splice 8 for ultrasonic lamination.
As a preferred embodiment, the laminated pattern fusion splice 8 is a matrix sequence, and each pattern element within the matrix sequence is one of circular, rectangular or elliptical.
As a preferred embodiment, a limiting plate assembly 9 for limiting the thickness of the adhered composite sheet is mounted behind the pressing assembly 4.
As a preferred embodiment, a limiting wheel set 10 for controlling the distance between the composite front base fabrics is installed in front of the pressing component 4.
As a preferred embodiment, a rolling assembly 11 for secondarily compacting the composite sheet is installed behind the limiting plate assembly 9.
The embodiment also provides a green preparation method of the moisture-resistant food deoxidizer, which comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 30-40wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 30-40wt%;
adhering low-melting-point particles on the upper surface and the lower surface of the first base cloth layer, and then enabling the first base cloth layer and the second base cloth layer to be adhered on the upper surface and the lower surface of the first base cloth layer through an adhesion device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
As a preferred embodiment, in the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, and the distance L1 between the lower surface of the limiting plate and the pressing table 3 in the limiting plate assembly 9 is greater than the thickness W of the three layers of base cloth, preferably 0< L1-W <0.3mm.
The low-melting-point particles on the surfaces of the first base cloth layer and the second base cloth layer are fused and bonded under the action of ultrasonic vibration, the pressure is released rapidly, then the bonding structure formed by the low-melting-point particles in the process of continuously moving forward of the base cloth layer is still in a semi-fused state and is pulled into a filament bundle shape by the restoring force between the two base cloth layers, the fineness of the filament bundle shape and the filaments are kept relatively stable and are further cooled due to the limitation of the limiting plate assembly 9, and then the base cloth layers are compressed again under the action of the rolling assembly 11, so that the purpose of adhesion is achieved.
As a preferred embodiment, in the third step, the distance l2=w between two limiting wheels on the limiting wheel set 10.
As a preferred embodiment, the distance L3 between the two pressing rolls on the pressing assembly 11 in the third step satisfies 0<W-L3< W/2mm.
In a preferred embodiment, in the third step, the low-melting point particles are low-melting point polypropylene particles or low-melting point polyester particles, and the melting point is 160-180 ℃.
As a preferred embodiment, the first deoxidizing solution comprises the following components in percentage by weight:
the water absorption formula system with anhydrous calcium chloride as a main body and the deoxidizing formula system with activated iron powder as a main body are matched to form a film which is adhered to the surface of the fiber inside the first base cloth layer, so that the double-layer effect of water absorption and deoxidization is achieved.
As a preferred embodiment, the first deoxidizing solution comprises the following components in percentage by weight:
as a preferred embodiment, the second deoxidizing solution comprises the following components in percentage by weight:
as a preferred embodiment, the second deoxidizing solution comprises the following components in percentage by weight:
the deoxidizing formula system with activated iron powder, diatomite and active carbon as main components is adopted, the activated iron powder is used as a base, the diatomite, the active carbon and sodium chloride are used as auxiliary materials, and the deoxidizing formula system is uniformly dispersed in the solution through the combined action of the dispersing agent, the crosslinked starch and the adhesive to form a film which is adhered to the surface of the fiber and keeps stable adhesive force with the surface of the fiber.
The carrier for containing the deoxidizing component is formed by compounding three layers of non-woven fabrics, and when the carrier is in a three-dimensional netlike space structure formed by fiber construction, the deoxidizing solution forms a uniform film on the surface of the fiber during dipping the deoxidizing solution, so that the contact area between the deoxidizing component and the space is greatly increased, and the deoxidizing effect of the deoxidizing agent and the utilization rate of the deoxidizing agent are improved.
The first base cloth layer positioned on the inner layer adopts fibers with finer specification and higher density, has good unidirectional moisture guiding performance, ensures that moisture absorbed from the outer layer can be quickly conducted to the inner layer and absorbed by the drying agent attached to the inner layer fibers, so as to keep the outer layer dry, and the surface of the cross hollow polyester fiber in the inner layer can be attached with more drying agents, and can improve the moisture conducting capacity of the inner layer fibers and the integral deoxidizing effect of the deoxidizer.
The beneficial effects of the deoxidizer obtained by the technical solution of this embodiment will be further described below by way of several groups of examples and comparative examples, wherein the first deoxidizing solution used in the examples and comparative examples is 35 parts by weight of anhydrous calcium chloride; 24 parts of activated iron powder; 8 parts of cross-linked starch; 5 parts of adhesive; 5 parts of dispersing agent; 100 parts of water; 30 parts of activated iron powder in percentage by weight of a second deoxidizing solution; 25 parts of diatomite; 24 parts of active carbon; 3 parts of sodium chloride; 5 parts of cross-linked starch; 5 parts of dispersing agent; 8 parts of adhesive; 100 parts of water.
Embodiment one:
the preparation method of the deoxidizer in the embodiment comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Embodiment two:
the preparation method of the deoxidizer in the embodiment comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-12N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 30wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 10-12N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 30wt%;
adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-25N, and the amplitude is controlled to be 15-20um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
And fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.4-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Embodiment III:
the preparation method of the deoxidizer in the embodiment comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 13-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 40wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 13-15N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 40wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 25-30N, and the amplitude is controlled to be 20-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.3s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Embodiment four:
the preparation method of the deoxidizer in the embodiment comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
attaching low-melting-point polyester particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then enabling the first base cloth layer and the second base cloth layer to be adhered on the upper and lower surfaces of the first base cloth layer through an adhesion device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
And fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example one:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is 1-5% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is 1-5% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example two:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller in the impregnation process to be 6-9N, so that the content of the first deoxidizer in the first base cloth layer is 25wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 6-9N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 25wt%;
adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
And fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example three:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 10-15N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 15-20KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example four:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 35-40N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 45-50KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
And fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example five:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with specification of 2-3D.51mm and 60-70wt% of polyester fiber with specification of 3-6D.51mm to obtain cloth II, wherein the thickness of cloth is 0.8-1.2mm, and the weight of cloth II is 60-70wt% of the total weight of the cloth IIThe weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 2.0mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example six:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with specification of 2-3D.51mm and 60-70wt% of polyester fiber with specification of 3-6D.51mm to obtain cloth II, wherein the cloth is thickThe degree is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
And fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 1.5mm, and the distance L3 between two press rollers on the rolling assembly is 2.0mm.
Comparative example seven:
the preparation method of the deoxidizer in the comparative example comprises the following steps:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the The chitin fiber with the specification of 2-3D-51 mm accounting for 30-40wt% and the polyester fiber with the specification of 3-6D-51 mm accounting for 60-70wt% are subjected to needling reinforcement to obtain clothSecondly, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of a press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 35wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the pressing roller to be 10-15N in the soaking process, so that the content of the second deoxidizer in the second base cloth layer is 35wt%;
Adhering low-melting-point polypropylene particles with melting points of 160-180 ℃ on the upper and lower surfaces of the first base cloth layer, and then adhering the first base cloth layer and the second base cloth layer on the upper and lower surfaces of the first base cloth layer through an adhering device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
In the third step, the ultrasonic hot pressing time is controlled to be 0.2-0.5s, the distance L1 between the lower surface of the limiting plate in the limiting plate assembly and the press-attaching workbench is 3.2mm, the thickness W of the three-layer base cloth is 3.0mm, the distance L2 between two limiting wheels on the limiting wheel set is 3.0mm, and the distance L3 between two press rollers on the rolling assembly is 1.0mm.
The deoxidizer prepared by the four groups of examples and the seven groups of comparative examples is used for taking the same cake and simultaneously testing the fresh-keeping effect at room temperature. The specific data are as follows:
table 1 test data for deoxidizers prepared for each set of examples and comparative examples
Project Time/d
Example 1 No change after 60 days
Example two No change after 60 days
Example III No change after 60 days
Example IV No change after 60 days
Comparative example one Mildew after 52 days
Comparative example two Mildew after 50 days
Comparative example three Mildew after 46
Comparative example four Mildew after 50
Comparative example five Mildew after 55
Comparative example six Mildew after 53
Comparative example seven Mildew after 52
No deoxidizer is used Mildew after 6 days
As can be seen from Table 1, the deoxidizer prepared in the examples has a better fresh-keeping effect than the comparative examples and no deoxidizer, and the deoxidizer prepared by the production method in the examples can preserve cakes for more than two months without mildew, which shows that the deoxidizer prepared in the examples has a good fresh-keeping effect under the humidity condition, and in addition, the deoxidizer can effectively avoid damage to the appearance of food caused by collision with the food during transportation, and has the characteristics of safety, sanitation, economy, practicability and the like.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, and various modifications and variations may be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. The green preparation method of the moisture-resistant food deoxidizer is characterized by comprising the following steps of:
step one, carrying out needling reinforcement on 30-40wt% of terylene fiber with the specification of 1.5-51 mm and 60-70wt% of cross hollow terylene fiber with the specification of 1.5-2D-51 mm to obtain a cloth I, wherein the thickness of the cloth I is 0.8-1.2mm, and the gram weight is 80-120g/cm 2 The method comprises the steps of carrying out a first treatment on the surface of the Needling 30-40wt% of chitin fiber with the specification of 2-3D-51 mm and 60-70wt% of polyester fiber with the specification of 3-6D-51 mm to obtain cloth II, wherein the thickness of the cloth is 0.8-1.2mm, and the gram weight is 100-150g/cm 2
Step two, putting the cloth I into a first deoxidizing solution for dipping treatment, and drying the cloth I through a drying oven to ensure that the moisture content of the cloth I is below 1% to obtain a first base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the first deoxidizer in the first base cloth layer is 30-40wt%; putting the second cloth into a second deoxidizing solution for dipping treatment, and drying the second cloth in an oven to ensure that the moisture content of the second cloth is below 1% to obtain a second base cloth layer; controlling the pressure of the press roller to be 10-15N in the impregnation process, so that the content of the second deoxidizer in the second base cloth layer is 30-40wt%; the first deoxidizing solution is prepared from 30-40 parts of anhydrous calcium chloride, 20-30 parts of activated iron powder, 5-10 parts of crosslinked starch, 3-8 parts of adhesive, 3-8 parts of dispersing agent and 100 parts of water; the second deoxidizing solution is prepared from 25-40 parts of activated iron powder, 20-30 parts of diatomite, 20-30 parts of activated carbon, 2-5 parts of sodium chloride, 3-8 parts of crosslinked starch, 3-8 parts of dispersing agent, 5-10 parts of adhesive and 100 parts of water;
Adhering low-melting-point particles on the upper surface and the lower surface of the first base cloth layer, and then enabling the first base cloth layer and the second base cloth layer to be adhered on the upper surface and the lower surface of the first base cloth layer through an adhesion device, wherein the ultrasonic hot-pressing pressure is 20-30N, and the amplitude is controlled to be 15-25um during welding; controlling the vibration frequency at 20-40KHz to obtain a composite sheet;
step four, cutting the composite sheet into blocks to obtain a required fresh-keeping card;
and fifthly, placing the fresh-keeping card into a packaging bag and sewing the fresh-keeping card to obtain the deoxidizer.
2. The method for green preparation of a moisture resistant food deoxidizer as claimed in claim 1, comprising a moisture resistant food deoxidizer green preparation apparatus; the green preparation equipment of the moisture-resistant food deoxidizer sequentially comprises a deoxidizing carrier forming device, a deoxidizing carrier impregnating device, a deoxidizing carrier adhering device, a dicing device and a packaging device; the deoxidizing carrier forming device sequentially comprises an opener, a net forming machine and a needling machine, and the deoxidizing carrier adhering device is an ultrasonic composite device capable of realizing ultrasonic hot-pressing welding of three sheets.
3. The method for preparing the wet-resistant food deoxidizer according to claim 2, wherein the deoxidizing carrier adhering device comprises a feeding roller set, a pressing table and a pressing assembly, the feeding roller set comprises a first feeding roller set for conveying an upper second base cloth layer, a second feeding roller set for conveying a middle first base cloth layer and a third feeding roller set for conveying a lower second base cloth layer, the feeding roller set is arranged at an inlet position of the pressing table, and the pressing assembly is located right above the pressing table.
4. The green preparation method of the moisture-resistant food deoxidizer according to claim 3, wherein the pressing component comprises a pressing plate, a pressing support rod, a pressing driving component for controlling the pressing of the pressing support rod and an ultrasonic generator, the pressing support rod is mounted on the pressing driving component, the pressing plate is fixedly mounted on the lower end part of the pressing support rod, and the ultrasonic generator is mounted on the pressing support rod.
5. The green preparation method of the moisture-resistant food deoxidizer according to claim 4, wherein the pressing driving assembly comprises a driving motor, a driven wheel and a cam, the driving motor drives the driven wheel to rotate, the central shaft of the driven wheel is coaxial with the rotating shaft of the cam, and the cam abuts against the upper end of the pressing supporting rod.
6. The green preparation method of the moisture-resistant food deoxidizer according to claim 5, wherein a driving wheel is installed on a rotating shaft of the driving motor, and the driving wheel and the driven wheel are driven by a belt.
7. The method for green preparing a moisture resistant food deoxidizer as recited in claim 4, wherein the lower surface of the lower laminate has a laminate pattern melt joint for ultrasonic lamination.
8. The method of claim 7, wherein the laminated pattern melt joint is a matrix sequence and each pattern element in the matrix sequence is one of circular, rectangular or oval.
9. A green method of preparing a moisture resistant food deoxidizer as in claim 3, wherein a limiting plate assembly for limiting the thickness of the adhered composite sheet is installed behind the hold-down assembly.
10. The green preparation method of the moisture-resistant food deoxidizer according to claim 9, wherein a limiting wheel set for controlling the distance between the composite front base fabrics is installed in front of the pressing component.
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Citations (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0286758A (en) * 1988-09-22 1990-03-27 Mitsubishi Gas Chem Co Inc Sheet-like deoxidizing agent
JPH04190773A (en) * 1990-10-23 1992-07-09 Kohjin Co Ltd Freshness keeping tool produced by using new air-permeable and heat-sealable laminated sheet
JPH0716976A (en) * 1993-06-30 1995-01-20 Dainippon Printing Co Ltd Freshness maintaining sheet and preservation vessel using same
GB9718510D0 (en) * 1997-09-01 1997-11-05 Akio Usai Viscous Liquid Deoxidizer, Deoxidizing Sheet Made Thereof and Manufacturing Method for Deoxidizing Sheet
CN2302011Y (en) * 1997-07-11 1998-12-30 吴踪萍 Energy fresh-keeping card
CN1214216A (en) * 1997-09-24 1999-04-21 臼井昭男 Viscous liquid deoxidizer, deoxidizing sheet made thereof and manufacturing method for deoxidizing sheet
FR2770224A1 (en) * 1997-10-03 1999-04-30 Akio Usui Viscous liquid deoxidant compositions containing metal powder, adhesive and water, used for preventing oxidation of stored materials, e.g. foodstuffs
JP2000142644A (en) * 1998-09-04 2000-05-23 Mitsubishi Gas Chem Co Inc Food packaging equipment and food packaging method
JP2000169596A (en) * 1998-12-11 2000-06-20 Sumitomo Chem Co Ltd Film for deoxygenating packaging bag and deoxygenating packing bag
CN1279022A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Long-acting antistaling tablet for grapes
CN1302567A (en) * 1999-10-29 2001-07-11 陆文琴 Immersion-type antistaling disinfectant
JP2002095453A (en) * 2000-09-21 2002-04-02 Unitika Ltd Freshness-retaining agent
CN101073403A (en) * 2006-05-17 2007-11-21 科伍德有限公司 Packaging products, film and method for improving and keeping meat color desired for person
JP2008079569A (en) * 2006-09-29 2008-04-10 Oji Nepia Kk Freshness-keeping sheet for vegetables, and method for producing the same
CN101195290A (en) * 2007-12-14 2008-06-11 朱春生 Process for producing superpower abrasion-proof resin fire-proof board
CN103003065A (en) * 2010-03-08 2013-03-27 多种吸附技术公司 Laminated and thermoformed articles containing oxygen scavenger
CN103005613A (en) * 2011-09-21 2013-04-03 张维尹 Sheet with characteristics of environmental protection, mildew resistance and fresh keeping
CN103653178A (en) * 2013-12-16 2014-03-26 苏州安特实业有限公司 Plant source compound sterilizing fresh-keeping agent and preparation method thereof
CN104382185A (en) * 2014-12-09 2015-03-04 广东广益科技实业有限公司 Preparation method of deoxidization preservative agent
CN105076389A (en) * 2015-07-23 2015-11-25 小嵩保鲜技术(常熟)有限公司 Deoxidizer and making method thereof
CN105767840A (en) * 2016-04-13 2016-07-20 浙江中医药大学 Room-temperature food preservation sheet and preparing method thereof
CN106744636A (en) * 2016-11-30 2017-05-31 宁波雄狮机械制造有限公司 A kind of fabric delivery and set composite
WO2018103172A1 (en) * 2016-12-07 2018-06-14 国家农产品保鲜工程技术研究中心(天津) Dual-effect antistaling sticker, and application thereof in preservation of garlic scapes
CN108338308A (en) * 2018-01-03 2018-07-31 广东广益科技实业有限公司 A kind of antistaling agent and preparation method thereof with double suction function
CN109699685A (en) * 2019-01-15 2019-05-03 深圳市淳睿贸易有限公司 Antibiotic slice, antibacterial agent and its application
CN110326661A (en) * 2019-08-14 2019-10-15 河南科技学院 A kind of method of acetic acid fresh-keeping card combination controlled atmospheric packing Ginger Juice Preservation of F resh Pork
CN111134265A (en) * 2020-02-19 2020-05-12 厦门市阿利阿多生物科技有限公司 Bacteriostatic and mildewproof preservative and preservation medium containing same
CN210879833U (en) * 2019-10-30 2020-06-30 福建吉鲜生物科技有限公司 Cutting device of fresh-keeping card production usefulness
CN210880945U (en) * 2019-10-14 2020-06-30 安庆市恒昌机械制造有限责任公司 Novel raw and other materials compound device
CN211073886U (en) * 2019-10-30 2020-07-24 福建吉鲜生物科技有限公司 Production equipment of fresh-keeping card
CN212422374U (en) * 2020-05-07 2021-01-29 山东泰鹏环保材料股份有限公司 Substrate layer of food fresh-keeping card
CN112515085A (en) * 2020-11-30 2021-03-19 四川农业大学 Novel preservation card and preparation method thereof
CN113276424A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Environment-friendly food preservation card forming system and preparation method
CN113273661A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Preparation method and preparation system of environment-friendly food deoxidizer
CN113632908A (en) * 2021-08-06 2021-11-12 广东广益科技实业有限公司 Alcohol preservation card with deoxidation function and preparation method thereof

Patent Citations (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0286758A (en) * 1988-09-22 1990-03-27 Mitsubishi Gas Chem Co Inc Sheet-like deoxidizing agent
EP0366254A1 (en) * 1988-09-22 1990-05-02 Mitsubishi Gas Chemical Company, Inc. Deoxidizer sheet
US5143769A (en) * 1988-09-22 1992-09-01 Mitsubishi Gas Chemical Company, Inc. Deoxidizer sheet
JPH04190773A (en) * 1990-10-23 1992-07-09 Kohjin Co Ltd Freshness keeping tool produced by using new air-permeable and heat-sealable laminated sheet
JPH0716976A (en) * 1993-06-30 1995-01-20 Dainippon Printing Co Ltd Freshness maintaining sheet and preservation vessel using same
CN2302011Y (en) * 1997-07-11 1998-12-30 吴踪萍 Energy fresh-keeping card
GB9718510D0 (en) * 1997-09-01 1997-11-05 Akio Usai Viscous Liquid Deoxidizer, Deoxidizing Sheet Made Thereof and Manufacturing Method for Deoxidizing Sheet
CN1214216A (en) * 1997-09-24 1999-04-21 臼井昭男 Viscous liquid deoxidizer, deoxidizing sheet made thereof and manufacturing method for deoxidizing sheet
FR2770224A1 (en) * 1997-10-03 1999-04-30 Akio Usui Viscous liquid deoxidant compositions containing metal powder, adhesive and water, used for preventing oxidation of stored materials, e.g. foodstuffs
JP2000142644A (en) * 1998-09-04 2000-05-23 Mitsubishi Gas Chem Co Inc Food packaging equipment and food packaging method
JP2000169596A (en) * 1998-12-11 2000-06-20 Sumitomo Chem Co Ltd Film for deoxygenating packaging bag and deoxygenating packing bag
CN1279022A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Long-acting antistaling tablet for grapes
CN1302567A (en) * 1999-10-29 2001-07-11 陆文琴 Immersion-type antistaling disinfectant
JP2002095453A (en) * 2000-09-21 2002-04-02 Unitika Ltd Freshness-retaining agent
CN101073403A (en) * 2006-05-17 2007-11-21 科伍德有限公司 Packaging products, film and method for improving and keeping meat color desired for person
JP2008079569A (en) * 2006-09-29 2008-04-10 Oji Nepia Kk Freshness-keeping sheet for vegetables, and method for producing the same
CN101195290A (en) * 2007-12-14 2008-06-11 朱春生 Process for producing superpower abrasion-proof resin fire-proof board
CN103003065A (en) * 2010-03-08 2013-03-27 多种吸附技术公司 Laminated and thermoformed articles containing oxygen scavenger
CN103005613A (en) * 2011-09-21 2013-04-03 张维尹 Sheet with characteristics of environmental protection, mildew resistance and fresh keeping
CN103653178A (en) * 2013-12-16 2014-03-26 苏州安特实业有限公司 Plant source compound sterilizing fresh-keeping agent and preparation method thereof
CN104382185A (en) * 2014-12-09 2015-03-04 广东广益科技实业有限公司 Preparation method of deoxidization preservative agent
CN105076389A (en) * 2015-07-23 2015-11-25 小嵩保鲜技术(常熟)有限公司 Deoxidizer and making method thereof
CN105767840A (en) * 2016-04-13 2016-07-20 浙江中医药大学 Room-temperature food preservation sheet and preparing method thereof
CN106744636A (en) * 2016-11-30 2017-05-31 宁波雄狮机械制造有限公司 A kind of fabric delivery and set composite
WO2018103172A1 (en) * 2016-12-07 2018-06-14 国家农产品保鲜工程技术研究中心(天津) Dual-effect antistaling sticker, and application thereof in preservation of garlic scapes
CN108338308A (en) * 2018-01-03 2018-07-31 广东广益科技实业有限公司 A kind of antistaling agent and preparation method thereof with double suction function
CN109699685A (en) * 2019-01-15 2019-05-03 深圳市淳睿贸易有限公司 Antibiotic slice, antibacterial agent and its application
CN110326661A (en) * 2019-08-14 2019-10-15 河南科技学院 A kind of method of acetic acid fresh-keeping card combination controlled atmospheric packing Ginger Juice Preservation of F resh Pork
CN210880945U (en) * 2019-10-14 2020-06-30 安庆市恒昌机械制造有限责任公司 Novel raw and other materials compound device
CN210879833U (en) * 2019-10-30 2020-06-30 福建吉鲜生物科技有限公司 Cutting device of fresh-keeping card production usefulness
CN211073886U (en) * 2019-10-30 2020-07-24 福建吉鲜生物科技有限公司 Production equipment of fresh-keeping card
CN111134265A (en) * 2020-02-19 2020-05-12 厦门市阿利阿多生物科技有限公司 Bacteriostatic and mildewproof preservative and preservation medium containing same
CN212422374U (en) * 2020-05-07 2021-01-29 山东泰鹏环保材料股份有限公司 Substrate layer of food fresh-keeping card
CN112515085A (en) * 2020-11-30 2021-03-19 四川农业大学 Novel preservation card and preparation method thereof
CN113276424A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Environment-friendly food preservation card forming system and preparation method
CN113273661A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Preparation method and preparation system of environment-friendly food deoxidizer
CN113632908A (en) * 2021-08-06 2021-11-12 广东广益科技实业有限公司 Alcohol preservation card with deoxidation function and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
热熔黏聚酯合成技术的发展及应用;王鸣义;;纺织导报(第04期);第48-54页 *
纸基复合材料包装封口超声波焊接技术;刘胜友, 曾乐予;食品与机械(第02期);第35-36页 *
脱氧剂及其脱氧包装技术的开发与应用;汪秋安, 张春香;包装工程(第04期);第7-10页 *

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