CN103005613A - Sheet with characteristics of environmental protection, mildew resistance and fresh keeping - Google Patents

Sheet with characteristics of environmental protection, mildew resistance and fresh keeping Download PDF

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Publication number
CN103005613A
CN103005613A CN2011102810141A CN201110281014A CN103005613A CN 103005613 A CN103005613 A CN 103005613A CN 2011102810141 A CN2011102810141 A CN 2011102810141A CN 201110281014 A CN201110281014 A CN 201110281014A CN 103005613 A CN103005613 A CN 103005613A
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mildew
layer
resistant
sheet
lamellar body
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CN103005613B (en
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张维尹
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Abstract

The present invention relates to a sheet with characteristics of environmental protection, mildew resistance and fresh keeping. According to the present invention, a substrate is subjected to printing; a graphic layer is formed on the substrate, an optical adhesive film polyester layer is adhered on the graphic layer through a processing machine so as to form the sheet; the sheet is placed in a fumigation device having a nature raw material with characteristics of mildew resistance, fresh keeping and anti-oxidation; a sealing chamber fumigation penetration process is performed, such that the sheet absorbs the nature raw material component; a PE lamination film of the substrate is arranged to cover pores of glassine paper, wherein an aqueous adhesive on the PE lamination film is subjected to sealing chamber fumigation penetration gasification to maintain a certain dose so as to reduce viscosity, such that the bottom paper is easy to tear off, presence amounts of the mildew resistance components can be identified, and the fresh keeping sheet capable of identifying the mildew resistance component amount can be formed; and the main components of the nature raw material with characteristics of mildew resistance, fresh keeping and anti-oxidation comprise allyl isothiocyanate and cineole. The sheet has characteristics of environmental protection, food material freshness prolonging, and food material oxidation and yellowing avoiding.

Description

The environment friendly mildew resistant antistaling tablet
Technical field
The present invention relates to a kind of antistaling tablet, particularly relate to a kind of environmental protection and can prolong the food materials freshness, prevent the mould-proof refreshing piece of food materials oxidation, xanthochromia.
Background technology
In order to allow food or article keep its freshness and to avoid damp and mouldy, most likely place the chemicals such as dry bag or deoxidation bag, reach the effect that suppresses mildew-resistant, how much all very unhealthy to human body right aforesaid chemistry goods commonly used are, therefore industry is researched and developed a kind of mildew-resistant paster that utilizes gasification mode to make, be 94215658 such as the TaiWan, China number of patent application, name is called: the patent application of mildew-resistant paster, it consists predominantly of a release liners and a paster consists of, this paster contains the volatilizable mildew-resistant composition that disengages, can fit in the container after tearing off by paster and release liners, to reach effect easy to use; Right its mildew-resistant composition still can't break away from chemicals, so do not have environmental protection and identification mildew-resistant composition effect, so this case creator develops TaiWan, China and applies for a patent application number and be 98108754 and be called: the patent application of environmental-protection bacteriostatic mildew-proof freshness keeping sheet, take a kind of natural material as anti-fungus material, though but right its fresh-keeping effect can reach Expected Results, but can't delay the food materials flavescence, it is easily flavescence after the food materials oxidation, and cause food not attractive in appearance, so the inventor more meets people's demand for pursuing, and how to imitate and reach outside the fresh-keeping effect, can delay food materials flavescence (anti-oxidant), above-mentioned shortcoming is for mainly improving part person.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of antistaling tablet that has environmental protection and antimildew function concurrently, the amount of all right identification mildew-resistant composition of this antistaling tablet.
Environment friendly mildew resistant antistaling tablet of the present invention, direct printing figure message layer on base material, the top of this picture and text layer is then through processing machine and the upper optical cement film polyester layer of fitting, so consist of a lamellar body, after lamellar body is fumigated the infiltration program via secret room, make lamellar body draw natural anti-mildew fresh-keeping antioxidant material composition, the setting of its PE leaching membrane layer of this base material, cover the pore of Ge Laxin paper, its top water-based viscose keeps certain dosage that stickiness is reduced via the stifling infiltration gasification of secret room is rear, via can easily tearing off lower base stock, can distinguish that mildew-resistant becomes deal to have number, the Main Ingredients and Appearance of this natural anti-mildew fresh-keeping antioxidant material is: propenyl mustard oil (A lly isothiocyanate) and cineol (cineole, Chinese juniper wood polyphenol powde namely are the essential oil by Chinese juniper wood distillation extraction) are consisted of, wherein, the mass ratio that propenyl mustard oil and cineol add is 1: 1, has mildew-resistant composition and anti-oxidation efficacy, efficiently solves the shortcoming that exists in the prior art.
Main purpose of the present invention, be to be to provide a kind of natural fresh-keeping anti-oxidant mildew-resistant composition, pass through propenyl mustard oil, be strong volatility high concentration molecule, and the anti-oxidant anti-xanthochromia effect of natural fresh-keeping of cineol (Chinese juniper wood polyphenol powde), it is synthetic to greatly reduce chemical analysis, and utilize the cineol (Chinese juniper wood polyphenol powde) after the purified extraction of distillation, and the composition hydrolysed ferment (enzymolysis) that utilizes natural crucifer extracts outside the natural mildew-resistant composition of the propenyl mustard oil that produces ultrahigh concentration, has antibacterium by cineol (Chinese juniper wood polyphenol powde) again, virus, mould and the function such as anti-oxidant, and can improve the time that prolongs anti-mildew fresh-keeping, and have oxidation resistant function by it, and can effectively delay the food materials flavescence.
Environment friendly mildew resistant antistaling tablet of the present invention, its preparation method may further comprise the steps:
Base material is for upper base stock below is consisted of by water-based adhesive-layer and lower base stock, and this time base stock is that Ge Laxin paper top is provided with one deck PE leaching membrane layer;
Printing figure message layer: be the figure layer of printing literal or pattern in base material;
Upper optical cement film polyester layer: be to utilize processing machine with fit upper optical cement film polyester layer and form lamellar body of base material, optical cement film polyester layer is to be provided with glazing layer by plasticity viscose glue not on this;
Secret room is fumigated the infiltration program: described lamellar body is put in the steam box on the stifling groove of secret room, should stifling groove be the good material of tool heat-conducting effect, which is provided with the top cover that to raise, and be provided with a dividing plate in the inner nearly middle position of stifling groove, this dividing plate is provided with some open-works, and steam box is inserted in the open-work top, and the bottom is provided with a shim, make stifling trench bottom form two groove chambers, to supply respectively the propenyl mustard oil of this natural anti-mildew fresh-keeping antioxidant material, cineol (Chinese juniper wood polyphenol powde) injects, in between dividing plate and groove chamber, form again a mixed zone, this secret room is provided with a radiator valve, to make this secret room temperature maintain 40 ℃-50 ℃, so stifling groove then is heated and makes the indoor natural anti-mildew fresh-keeping antioxidant material of groove be heated and produce gas, its propenyl mustard oil, the mixing remittance reached after the gas of cineol (the wooden polyphenol powde of Chinese juniper) rose to the mixed zone, and made lamellar body via rear its natural anti-mildew fresh-keeping antioxidant material composition of saturated absorption of 50 to 70 hours fumigate;
The mildew-resistant finished product: but have identification mildew-resistant composition and have the lamellar body finished product of the environment friendly mildew resistant antistaling tablet of mold-proof oxidation-resistant effectiveness, and get final product.
Environment friendly mildew resistant antistaling tablet of the present invention, wherein said lower base stock also can be high-density paper.
Environment friendly mildew resistant antistaling tablet of the present invention mainly by base material via the printing after square thereon one-tenth picture and text layer, the top of this picture and text layer is then through processing machine and the upper optical cement film polyester layer of fitting, so consist of lamellar body, this lamellar body is put in the stifling groove with natural anti-mildew fresh-keeping antioxidant material again, after the stifling infiltration program of secret room, make lamellar body draw natural anti-mildew fresh-keeping antioxidant material composition, and the setting of its PE leaching membrane layer of this base material, cover the pore of Ge Laxin paper, its top water-based viscose keeps certain dosage that stickiness is reduced via the stifling infiltration gasification of secret room is rear, via can easily tearing off lower base stock, it is saturated that can distinguish that mildew-resistant becomes deal to exist for this moment, only after sealing off the use mildew resistant slice, mildew resistant slice naturally volatilize mould inhibitor when reaching one section of mildew-resistant effect in the future, water-based viscose recovery this moment stickiness is difficult for tearing off lower base stock, can distinguish that then mildew-resistant dosage volatilizees totally fully, can distinguish that mildew-resistant becomes deal to have number, have again oxidation resistant environment friendly mildew resistant antistaling tablet but form identification mildew-resistant composition, wherein: the main component of this natural anti-mildew fresh-keeping antioxidant material by: propenyl mustard oil (A lly isothiocyanate) and cineol (Chinese juniper wood polyphenol powde) are consisted of.
Description of drawings
Fig. 1 is making schematic flow sheet of the present invention;
Fig. 2 is STRUCTURE DECOMPOSITION schematic diagram of the present invention;
Fig. 3 is the cutaway view of structure of the present invention;
Fig. 4 is the cutaway view of another embodiment of the present invention.
Description of reference numerals: 10,10 '-lamellar body; The 20-base material; The upper base stock of 21-; 22-water-based viscose glue; Base stock under the 23-; The 231-PE leaching membrane layer; 232-lattice Racine paper; The 24-high-density paper; 30-picture and text layer; The upper optical cement film polyester of 40-layer; 41-is the plasticity viscose not; The 42-glazing layer; (A) base material; (B) printing figure message layer; (C) upper optical cement film polyester layer; (D) secret room fumigation infiltration program; (E) mildew-resistant finished product; The 50-secret room; 51-fumigates groove; The 511-top cover; The 512-dividing plate; The 513-open-work; The 514-shim; 52-groove chamber; The 53-mixed zone; The 54-steam box; The 55-radiator valve; 60-propenyl mustard oil (A lly isothiocyanate); 61-cineol (Chinese juniper wood polyphenol powde).
The specific embodiment
Below in conjunction with accompanying drawing, embodiment and test data, be described in more detail with other technical characterictic and advantage the present invention is above-mentioned.
As Figure 1-3, the structure of environment friendly mildew resistant antistaling tablet of the present invention and preparation method mainly comprise:
(A) base material 20, and it is consisted of by water-based adhesive-layer 22 and lower base stock 23 for upper base stock 21 belows, and this time base stock 23 is provided with one deck PE leaching membrane layer 231 for Ge Laxin paper 232 tops;
(B) the printing figure message layer 30: for print the picture and text layer 30 of literal or pattern in base material 20;
(C) upper optical cement film polyester layer 40: it is to utilize processing machine with the upper optical cement film polyester layer 40 of base material applying, should upper optical cement film polyester layer 40 be to be provided with glazing layer 42 by plasticity viscose 41 tops not, glazing layer is o-phenyl phenol (O-phenylphenol, OPP); Form lamellar body 10 by base material 20, printing figure message layer 30 and upper optical cement film polyester layer 40;
(D) the stifling infiltration program of secret room: lamellar body 10 is put in the steam box 54 on the secret room 50 stifling grooves 51, should stifling groove 51 be to have the good material of heat-conducting effect, which is provided with the top cover 511 that to raise, and be provided with a dividing plate 512 in stifling groove 51 inner nearly middle positions, this dividing plate is provided with some open-works 513, and steam box 54 is inserted in open-work 513 tops, and the bottom is provided with a shim 514, make stifling trench bottom form two groove chambers 52, with the propenyl mustard oil 60 (A lly isothiocyanate) that supplies respectively this natural anti-mildew fresh-keeping antioxidant material, cineol (Chinese juniper wood polyphenol powde) 61 injects, form a mixed zone 53 in dividing plate 512 and 52 of groove chambers again, this secret room 50 is provided with a radiator valve 55, keep between 40 ℃-50 ℃ to make this secret room 50, so stifling 51 of grooves are heated and make the indoor natural anti-mildew fresh-keeping antioxidant material of groove be heated and produce gas, its propenyl mustard oil (A lly isothiocyanate) 60, the gas of cineol (Chinese juniper wood polyphenol powde) 61 rise to that mixed zone 53 rear mixing converge and, and make lamellar body 10 via its natural anti-mildew fresh-keeping antioxidant material composition of saturated absorption behind stifling after 50 to 70 hours; This propenyl mustard oil 60 (A lly isothiocyanate) is composition such as the sulphur glucoside (Thioglycosides) that utilizes in the natural crucifer, contain high-load activity chemistry composition isothiocyanate (isothiocyanates), and the purified extraction of hydrolysed ferment (enzymolysis) produces the propenyl mustard oil (A lly isothiocyanate) of ultrahigh concentration afterwards, has the mildew-resistant effect, its special macromolecular structure produces high penetration, the cell membrane that can penetrate rapidly microorganism directly destroys DNA, and decomposing protein makes bacterium, mould can't survive and reach biocidal efficacies; And cineol (Chinese juniper wood polyphenol powde) 61 compositions via the distillation purifying extraction after, produce have anti-oxidant anti-xanthochromia can be to functions such as antibacterium, virus, moulds.
(E) mildew-resistant finished product: but lamellar body 10 forms the lamellar body 10 ' finished product of the environment friendly mildew resistant antistaling tablet with identification mildew-resistant composition and tool mold-proof oxidation-resistant effectiveness after the stifling infiltration program of secret room.
Structure person in this way, the present invention is except being that composition enzymolysis by natural crucifer extracts its natural mildew-resistant composition by propenyl mustard oil 60 (A lly isothiocyanate), has antibacterium by cineol (Chinese juniper wood polyphenol powde) 61 again, virus, mould and the function such as anti-oxidant (since the growth of Chinese juniper wood system through in more than thousand, and also really find the essential oil that refines that extracts on the Chinese juniper wood body via research, having can be to antibacterium, virus, mould and the function such as anti-oxidant), utilize again the mode of the stifling infiltration program (D) of secret room, make the anti-oxidant composition of its anti-mildew fresh-keeping of lamellar body 10 saturable absorption, and then can improve the timeliness that prolongs anti-mildew fresh-keeping, reach the setting by these base material 20 its PE leaching membrane layers 231, cover the pore of Ge Laxin paper 232, its top water-based viscose 22 keeps certain dosage that stickiness is reduced via stifling infiltration program (D) gasification of secret room is rear, via can easily tearing off lower base stock 23, can distinguish that mildew-resistant becomes deal to have number, but the function of its lamellar body 10 ' real tool identification mildew-resistant composition and mold-proof oxidation-resistant, and can effectively delay the food materials flavescence.
Again, the present invention can also replace Ge Laxin paper (Glassine paper) 232 and PE leaching membrane layer 231 by high-density paper 24 in lower base stock 23, as shown in Figure 4.Described high-density paper is the paper wood without pore, PE for example, PET, PP (polyester film);
Test example:
Given the test agent is: flour
This test is divided into three groups, is respectively control group 1: hermetically sealed can does not have without any drier and anticorrisive agent; Control group 2: be placed with the drier of buying on the bag market in the hermetically sealed can; Test group: hermetically sealed can is placed with environment friendly mildew resistant antistaling tablet of the present invention.
After one week, observe the situation of change of sample in the hermetically sealed can, the color sample in control group 1 hermetically sealed can changes, the flavescence of sample surfaces part or brown; Sample part in control group 2 hermetically sealed cans becomes black; Sample in the test group hermetically sealed can is unchanged.
After one month, observe the situation of change of sample in the hermetically sealed can, obvious xanthochromia or brown stain occur in the sample in control group 1 hermetically sealed can; A large amount of globules is arranged at control group 2 hermetically sealed can tops, mouldy, the most of blackening of sample; Sample in the test group hermetically sealed can is without significant change.
To sum up institute is old, and environment friendly mildew resistant antistaling tablet of the present invention has the advantages such as environmental protection, natural, antioxygen, anti-xanthochromia, identification mildew-resistant composition, and can effectively prolong freshness.
Above-described embodiment is described preferred embodiment of the present invention; be not that scope of the present invention is limited; design under the prerequisite of spirit not breaking away from the present invention; various distortion and improvement that those of ordinary skills make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.

Claims (3)

1. environment friendly mildew resistant antistaling tablet, mainly be that this base material forms the picture and text layer via printing is rear in the base material top, the top of this picture and text layer is then through processing machine and the upper optical cement film polyester layer of fitting, so consist of lamellar body, again this lamellar body is put in the stifling groove with natural anti-mildew fresh-keeping antioxidant material, after the stifling infiltration program of secret room, makes lamellar body draw natural anti-mildew fresh-keeping antioxidant material composition, form the environment friendly mildew resistant antistaling tablet, wherein:
The main component of this natural anti-mildew fresh-keeping antioxidant material by: propenyl mustard oil and cineol (Chinese juniper wood polyphenol powde) are consisted of.
2. environment friendly mildew resistant antistaling tablet as claimed in claim 1, its preparation method comprises:
Base material is for upper base stock below is consisted of by water-based adhesive-layer and lower base stock, and this time base stock is that Ge Laxin paper top is provided with one deck PE leaching membrane layer;
Printing figure message layer: be the figure layer of printing literal or pattern in base material;
Upper optical cement film polyester layer: be to utilize processing machine with fit upper optical cement film polyester layer and form lamellar body of base material, optical cement film polyester layer is to be provided with glazing layer by plasticity viscose glue not on this;
Secret room is fumigated the infiltration program: described lamellar body is put in the steam box on the stifling groove of secret room, should stifling groove be the good material of tool heat-conducting effect, which is provided with the top cover that to raise, and be provided with a dividing plate in the inner nearly middle position of stifling groove, this dividing plate is provided with some open-works, and steam box is inserted in the open-work top, and the bottom is provided with a shim, make stifling trench bottom form two groove chambers, to supply respectively the propenyl mustard oil of this natural anti-mildew fresh-keeping antioxidant material, cineol (Chinese juniper wood polyphenol powde) injects, in between dividing plate and groove chamber, form again a mixed zone, this secret room is provided with a radiator valve, to make this secret room temperature maintain 40 ℃-50 ℃, so stifling groove then is heated and makes the indoor natural anti-mildew fresh-keeping antioxidant material of groove be heated and produce gas, its propenyl mustard oil, the mixing remittance reached after the gas of cineol (the wooden polyphenol powde of Chinese juniper) rose to the mixed zone, and made lamellar body via rear its natural anti-mildew fresh-keeping antioxidant material composition of saturated absorption of 50 to 70 hours fumigate;
The mildew-resistant finished product: but have identification mildew-resistant composition and have the lamellar body finished product of the environment friendly mildew resistant antistaling tablet of mold-proof oxidation-resistant effectiveness.
3. environment friendly mildew resistant antistaling tablet as claimed in claim 1 or 2, wherein said lower base stock is high-density paper.
CN 201110281014 2011-09-21 2011-09-21 Sheet with characteristics of environmental protection, mildew resistance and fresh keeping Expired - Fee Related CN103005613B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105795305A (en) * 2014-12-29 2016-07-27 张维尹 Bacteriostasis mildew-resistant fresh-keeping sheet
CN106508957A (en) * 2016-11-28 2017-03-22 武亦然 Mildew-resistant card device used in clothes, making method thereof, and mildew-resistant composition
CN112120318A (en) * 2020-10-14 2020-12-25 山东侨邦纸业科技有限公司 Antiviral gauze mask of wood juice
CN112425711A (en) * 2020-11-23 2021-03-02 东北林业大学 Acorn shell extract coating preservative and preparation method thereof
CN113273660A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Green preparation system and method for moisture-proof food deoxidizer

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CN201518705U (en) * 2009-05-08 2010-07-07 张维尹 Mould-proof refreshing piece

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CN2335382Y (en) * 1998-07-09 1999-09-01 杨文渊 Oxygen absorbing freshness retaining piece
CN201518705U (en) * 2009-05-08 2010-07-07 张维尹 Mould-proof refreshing piece

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105795305A (en) * 2014-12-29 2016-07-27 张维尹 Bacteriostasis mildew-resistant fresh-keeping sheet
CN106508957A (en) * 2016-11-28 2017-03-22 武亦然 Mildew-resistant card device used in clothes, making method thereof, and mildew-resistant composition
CN106508957B (en) * 2016-11-28 2019-02-22 武亦然 For the mould proof card device and preparation method, mould proof composition in clothes
CN112120318A (en) * 2020-10-14 2020-12-25 山东侨邦纸业科技有限公司 Antiviral gauze mask of wood juice
CN112425711A (en) * 2020-11-23 2021-03-02 东北林业大学 Acorn shell extract coating preservative and preparation method thereof
CN112425711B (en) * 2020-11-23 2023-01-24 东北林业大学 Acorn shell extract coating preservative and preparation method thereof
CN113273660A (en) * 2021-03-23 2021-08-20 福建吉鲜生物科技有限公司 Green preparation system and method for moisture-proof food deoxidizer
CN113273660B (en) * 2021-03-23 2024-02-27 福建吉鲜生物科技有限公司 Green preparation system and method for moisture-resistant food deoxidizer

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