CN113272370A - 工业规模生产对苯二甲酸的方法 - Google Patents

工业规模生产对苯二甲酸的方法 Download PDF

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Publication number
CN113272370A
CN113272370A CN201980086616.6A CN201980086616A CN113272370A CN 113272370 A CN113272370 A CN 113272370A CN 201980086616 A CN201980086616 A CN 201980086616A CN 113272370 A CN113272370 A CN 113272370A
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CN
China
Prior art keywords
polyester
reactor
reaction medium
interest
terephthalic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201980086616.6A
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English (en)
Chinese (zh)
Inventor
M·沙托
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Carbios SA
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Carbios SA
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Filing date
Publication date
Application filed by Carbios SA filed Critical Carbios SA
Publication of CN113272370A publication Critical patent/CN113272370A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/105—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with enzymes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/14—Hydrolases (3)
    • C12N9/16—Hydrolases (3) acting on ester bonds (3.1)
    • C12N9/18—Carboxylic ester hydrolases (3.1.1)
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12Y—ENZYMES
    • C12Y301/00—Hydrolases acting on ester bonds (3.1)
    • C12Y301/01—Carboxylic ester hydrolases (3.1.1)
    • C12Y301/01074—Cutinase (3.1.1.74)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Polymers & Plastics (AREA)
  • Sustainable Development (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201980086616.6A 2018-11-06 2019-11-05 工业规模生产对苯二甲酸的方法 Pending CN113272370A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1860220 2018-11-06
FR1860220A FR3088069B1 (fr) 2018-11-06 2018-11-06 Procede de production d'acide terephtalique a l'echelle industrielle
PCT/EP2019/080277 WO2020094661A1 (fr) 2018-11-06 2019-11-05 Procede de production d'acide terephtalique a l'echelle industrielle

Publications (1)

Publication Number Publication Date
CN113272370A true CN113272370A (zh) 2021-08-17

Family

ID=65685672

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980086616.6A Pending CN113272370A (zh) 2018-11-06 2019-11-05 工业规模生产对苯二甲酸的方法

Country Status (9)

Country Link
US (1) US20220002516A1 (https=)
EP (1) EP3877458B1 (https=)
JP (2) JP7573523B2 (https=)
KR (1) KR20210091202A (https=)
CN (1) CN113272370A (https=)
CA (1) CA3117273A1 (https=)
FR (1) FR3088069B1 (https=)
MX (1) MX2021005249A (https=)
WO (1) WO2020094661A1 (https=)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891767A (zh) * 2022-05-19 2022-08-12 华南理工大学 角质酶-酯酶融合蛋白及其应用
CN115927411A (zh) * 2022-12-21 2023-04-07 天津大学 一种酯酶突变体基因及该基因表达的蛋白与应用
CN116606873A (zh) * 2023-05-06 2023-08-18 天津大学 分解聚酯的酯酶突变体基因及该基因表达的蛋白与应用
CN118222540A (zh) * 2024-05-23 2024-06-21 湘湖实验室(农业浙江省实验室) 一种耐热塑料水解酶AtPETase突变体及其应用
WO2024227372A1 (zh) * 2023-09-28 2024-11-07 北京酶好生物科技有限公司 IsPETase-8×Chimera重组酶及其编码基因、重组质粒、工程菌和应用
CN119517153A (zh) * 2024-11-19 2025-02-25 上海交通大学 基于深度学习算法设计的新型pet水解酶及其制备方法
CN120464599A (zh) * 2025-07-11 2025-08-12 南京工业大学 Pet水解酶突变体及其应用

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107709457B (zh) 2015-06-12 2021-05-25 卡比奥斯公司 可生物降解聚酯组合物及其用途
CN116199935A (zh) 2016-05-19 2023-06-02 卡比奥斯公司 一种降解塑料产品的方法
EP4650442A3 (en) 2016-07-12 2026-03-11 Carbios Novel esterases and uses thereof
BR112019012258A2 (pt) 2016-12-16 2020-10-20 Carbios proteases de degradação de plástico aprimoradas
US11384218B2 (en) 2017-08-31 2022-07-12 Carbios Liquid composition comprising biological entities and uses thereof
JP7519987B2 (ja) 2018-07-27 2024-07-22 キャルビオス 新規なエステラーゼ及びその使用
FR3088070B1 (fr) 2018-11-06 2021-11-26 Carbios Procede de degradation enzymatique de polyethylene terephtalate
CN113614295B (zh) 2019-03-28 2024-04-30 卡比奥斯公司 多组分热塑性制品
US12344714B2 (en) 2019-07-11 2025-07-01 Carbios Esterases and uses thereof
CN114096664B (zh) 2019-07-11 2025-03-07 卡比奥斯公司 新型酯酶及其用途
KR20230093468A (ko) 2020-10-27 2023-06-27 까르비오 신규한 에스테라아제 및 그 용도
US20240301160A1 (en) * 2020-12-24 2024-09-12 Societe Des Produits N Éstlé S.A. Enzymatic recycling of recycled polyethylene terephthalate by cutinases
CA3218310A1 (en) 2021-05-20 2022-11-24 Carbios Process for degrading a plastic product comprising at least one polyester
US20240228732A1 (en) 2021-05-20 2024-07-11 Carbios Process for degrading a plastic product comprising at least one polyester
CN118369423A (zh) 2021-11-16 2024-07-19 卡比奥斯公司 酯酶的用途
EP4433582A2 (en) 2021-11-16 2024-09-25 Carbios Esterases and uses thereof
CA3237152A1 (en) 2021-11-16 2023-05-25 Alain Marty Esterases and uses thereof
KR20250023516A (ko) 2022-06-13 2025-02-18 까르비오 모노에틸렌 글리콜의 정제 방법
WO2024191601A2 (en) * 2023-03-01 2024-09-19 Battelle Memorial Institute Reduced crystallinity polymers for biodegradation
CN121175416A (zh) 2023-05-15 2025-12-19 卡比奥斯公司 酯酶变体及其在聚酯降解中的用途
KR20260011167A (ko) 2023-05-15 2026-01-22 까르비오 신규 에스테라제 및 이의 용도
WO2025012254A2 (en) * 2023-07-10 2025-01-16 Carbios Process for the pre-treatment of textile waste
FR3157400A1 (fr) * 2023-12-21 2025-06-27 Universite Claude Bernard Lyon 1 Procede de reaction a solide consommable et dispositif pour la mise en œuvre d’un tel procede
KR20250115684A (ko) * 2024-01-24 2025-07-31 씨제이제일제당 (주) 폴리에스테르 효소 분해 공정에서 TPA(terephthalic acid)를 효율적으로 회수하는 공정
WO2025235478A1 (en) * 2024-05-06 2025-11-13 Alliance For Sustainable Energy, Llc Ethylene glycol and terephthalic acid recovery from polyethylene terephthalate deconstruction processes
WO2026079421A1 (ja) * 2024-10-10 2026-04-16 東洋紡株式会社 エステルオリゴマーの製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050261465A1 (en) * 2004-05-24 2005-11-24 Vasantha Nagarajan Method to accelerate biodegradation of aliphatic-aromatic co-polyesters by enzymatic treatment
CN101456809A (zh) * 2009-01-08 2009-06-17 中国科学院嘉兴材料与化工技术工程中心 一种解聚废旧pet的方法
US20150290840A1 (en) * 2012-11-20 2015-10-15 Carbios Method for recycling plastic products
CN106459471A (zh) * 2014-05-16 2017-02-22 卡比欧斯公司 混合pet塑料制品的再循环方法
WO2017198786A1 (en) * 2016-05-19 2017-11-23 Carbios A process for degrading plastic products

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4355175A (en) * 1981-04-06 1982-10-19 Pusztaszeri Stephen F Method for recovery of terephthalic acid from polyester scrap
JP2004290130A (ja) * 2003-03-28 2004-10-21 Mitsubishi Chemicals Corp ポリエステル構成成分モノマーの回収方法
WO2012099018A1 (ja) * 2011-01-19 2012-07-26 天野エンザイム株式会社 枝葉コンポスト由来新規エステラーゼ
WO2015097104A1 (en) 2013-12-23 2015-07-02 Carbios Method for recycling plastic products
CN108554342A (zh) * 2018-04-13 2018-09-21 日照旭日复合材料有限公司 磨浆反应装置及其应用

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050261465A1 (en) * 2004-05-24 2005-11-24 Vasantha Nagarajan Method to accelerate biodegradation of aliphatic-aromatic co-polyesters by enzymatic treatment
CN101456809A (zh) * 2009-01-08 2009-06-17 中国科学院嘉兴材料与化工技术工程中心 一种解聚废旧pet的方法
US20150290840A1 (en) * 2012-11-20 2015-10-15 Carbios Method for recycling plastic products
CN106459471A (zh) * 2014-05-16 2017-02-22 卡比欧斯公司 混合pet塑料制品的再循环方法
WO2017198786A1 (en) * 2016-05-19 2017-11-23 Carbios A process for degrading plastic products

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891767A (zh) * 2022-05-19 2022-08-12 华南理工大学 角质酶-酯酶融合蛋白及其应用
CN114891767B (zh) * 2022-05-19 2023-04-28 华南理工大学 角质酶-酯酶融合蛋白及其应用
CN115927411A (zh) * 2022-12-21 2023-04-07 天津大学 一种酯酶突变体基因及该基因表达的蛋白与应用
CN116606873A (zh) * 2023-05-06 2023-08-18 天津大学 分解聚酯的酯酶突变体基因及该基因表达的蛋白与应用
CN116606873B (zh) * 2023-05-06 2024-03-01 天津大学 分解聚酯的酯酶突变体基因及该基因表达的蛋白与应用
WO2024227372A1 (zh) * 2023-09-28 2024-11-07 北京酶好生物科技有限公司 IsPETase-8×Chimera重组酶及其编码基因、重组质粒、工程菌和应用
CN118222540A (zh) * 2024-05-23 2024-06-21 湘湖实验室(农业浙江省实验室) 一种耐热塑料水解酶AtPETase突变体及其应用
CN119517153A (zh) * 2024-11-19 2025-02-25 上海交通大学 基于深度学习算法设计的新型pet水解酶及其制备方法
CN120464599A (zh) * 2025-07-11 2025-08-12 南京工业大学 Pet水解酶突变体及其应用
CN120464599B (zh) * 2025-07-11 2025-09-12 南京工业大学 Pet水解酶突变体及其应用

Also Published As

Publication number Publication date
EP3877458A1 (fr) 2021-09-15
EP3877458B1 (fr) 2025-12-31
JP2022512861A (ja) 2022-02-07
EP3877458C0 (fr) 2025-12-31
JP7573523B2 (ja) 2024-10-25
MX2021005249A (es) 2021-06-18
WO2020094661A1 (fr) 2020-05-14
KR20210091202A (ko) 2021-07-21
CA3117273A1 (fr) 2020-05-14
US20220002516A1 (en) 2022-01-06
JP2024156716A (ja) 2024-11-06
FR3088069B1 (fr) 2021-11-26
FR3088069A1 (fr) 2020-05-08

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