CN113248973A - Water-based dye ink - Google Patents

Water-based dye ink Download PDF

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Publication number
CN113248973A
CN113248973A CN202110562718.XA CN202110562718A CN113248973A CN 113248973 A CN113248973 A CN 113248973A CN 202110562718 A CN202110562718 A CN 202110562718A CN 113248973 A CN113248973 A CN 113248973A
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direct
ether
dye ink
yellow
blue
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黄新红
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Zhuhai Ninestar Management Co Ltd
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Zhuhai Ninestar Management Co Ltd
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Priority to CN202110562718.XA priority Critical patent/CN113248973A/en
Publication of CN113248973A publication Critical patent/CN113248973A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The application relates to water-based dye ink which comprises the following components in percentage by weight: 5-15% of dye toner, 15-35% of moisturizing tackifier, 0.1-0.5% of polyester organic silicon flatting agent, 5-20% of organic solvent and the balance of deionized water, wherein the moisturizing tackifier comprises glycerol and ether compounds shown in formula I,

Description

Water-based dye ink
Technical Field
The invention relates to the technical field of printing, in particular to water-based dye ink.
Background
With the development of the packaging printing market from batch to personalized and diversified printing, the variety and specification of the product become more and more complex. The advantages of the digital ink jet printing technology in carton printing enterprises are gradually revealed, the characteristics of timely processing printing according to needs, variable information printing and the like can be realized, and the digital ink jet printing technology is complementary to the advantages of the printing mode, the working flow and the supply mode which are dominant in the current carton printing enterprises. The existing water-based pigment ink has poor leveling property effect of images and color blocks, poor ink fluency, easy blockage of a spray head in the printing process and the problem of orifice deletion.
Disclosure of Invention
In view of the above, the present application provides a water-based dye ink, which is not blocked by ink in a nozzle during use, and is beneficial to improving image printing effect and improving printing smoothness.
In a first aspect, an embodiment of the present application provides an aqueous dye ink, including the following components in percentage by weight: 5-15% of dye toner, 15-35% of moisturizing tackifier, 0.1-0.5% of polyester organic silicon flatting agent, 5-20% of organic solvent and the balance of deionized water, wherein the moisturizing tackifier comprises glycerol and ether compounds shown in formula I,
Figure BDA0003079623320000011
optionally, the dye toner includes any one of a direct dye or a reactive dye.
Optionally, the content of the dye toner is 7-12% of the total weight of the aqueous dye ink.
Optionally, the mass ratio of the ether compound to the glycerol is 1: (3-6).
Optionally, the organic solvent comprises at least one of a polyol and a lower alkyl ether of a polyol.
Optionally, the polyol comprises at least one of ethylene glycol, propylene glycol, 1, 2-hexanediol, 1, 2-glycerol, 1, 2-propanediol, diethylene glycol, triethylene glycol.
Optionally, the lower alkyl ether of the polyhydric alcohol comprises at least one of triethylene glycol monobutyl ether, ethylene glycol monopropyl ether, ethylene glycol isopropyl ether, ethylene glycol monobutyl ether, ethylene glycol isobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and dipropylene glycol monopropyl ether.
Optionally, the aqueous dye ink further comprises a surfactant, wherein the content of the surfactant is 0.5-3% of the total mass of the aqueous dye ink, and the content of the surfactant is acetylene glycol surfactant.
Optionally, the aqueous dye ink further comprises a preservative, and the content of the preservative is 0.1-1% of the total mass of the aqueous dye ink.
Optionally, the viscosity of the aqueous dye ink is 5cp to 12cp, and the surface tension of the aqueous dye ink is 25mN/m to 30 mN/m.
The invention has the beneficial effects that: the application provides a water-based dye ink, it shares through ether compound and glycerine, for the ink provides good moisturizing effect and tackification effect, polyester organosilicon flatting agent can reduce liquid surface tension and have excellent substrate wetting and levelling effect, make the water-based dye ink of preparation cheap, the smoothness is good, it is bright-colored to print on the corrugated paper, have good moisturizing nature, the printing shower nozzle is started up after standby for 7 days and is printed, the ink can be printed in succession and not block up the shower nozzle.
Detailed Description
While the following is a preferred embodiment of the present invention, it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the embodiment of the present invention, and these modifications and decorations should also be regarded as the protection scope of the embodiment of the present invention.
The terminology used in the embodiments of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used in the examples of the present invention and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise.
The application provides water-based dye ink, which comprises the following components in percentage by weight: 5-15% of dye toner, 15-35% of moisturizing tackifier, 0.1-0.5% of polyester organic silicon flatting agent, 5-20% of organic solvent and the balance of deionized water, wherein the moisturizing tackifier comprises glycerol and ether compounds shown in formula I,
Figure BDA0003079623320000021
according to the water-based dye ink provided by the application, the glycerol, the ether compound shown as the formula I and the polyester organic silicon leveling agent are added into the ink formula, so that the ink has good fluency when printed on corrugated paper and excellent moisture retention property.
As an alternative embodiment of the present application, the dye toner includes any one of a direct dye or a reactive dye. Specifically, the direct dyes include direct yellow 8, direct yellow 9, direct yellow 11, direct yellow 12, direct yellow 27, direct yellow 28, direct yellow 29, direct yellow 33, direct yellow 35, direct yellow 39, direct yellow 41, direct yellow 44, direct yellow 50, direct yellow 53, direct yellow 58, direct yellow 59, direct yellow 68, direct yellow 86, direct yellow 87, direct yellow 93, direct yellow 95, direct yellow 96, direct yellow 98, direct yellow 100, direct yellow 106, direct yellow 108, direct yellow 109, direct yellow 110, direct yellow 130, direct yellow 132, direct yellow 142, direct yellow 144, direct yellow 161, direct yellow 163, direct blue 1, direct blue 10, direct blue 15, direct blue 22, direct blue 25, direct blue 41, direct blue 55, direct blue 67, direct blue 68, direct blue 71, direct blue 76, direct blue 77, direct blue 78, direct blue 80, direct blue 84, direct blue 86, Direct blue 87, direct blue 90, direct blue 98, direct blue 106, direct blue 108, direct blue 109, direct blue 120, direct blue 151, direct blue 156, direct blue 158, direct blue 159, direct blue 160, direct blue 153, direct blue 168, direct blue 189, direct blue 192, direct blue 193, direct blue 194, direct blue 199, direct blue 200, direct blue 201, direct blue 202, direct blue 203, direct blue 207, direct blue 211, direct blue 213, direct blue 214, direct blue 218, direct blue 225, direct blue 226, direct blue 229, direct blue 236, direct blue 237, direct blue 244, direct blue 248, direct blue 249, direct blue 251, direct blue 252, direct blue 264, direct blue 270, direct blue 280, direct blue 288, direct blue 291, direct violet 7, direct violet 9, direct violet 47, direct violet 48, direct violet 51, direct violet 66, direct violet 90, direct violet 93, direct blue 291, direct blue 168, direct blue 189, direct blue 291, direct blue 192, direct blue 291, direct blue 7, direct violet 9, direct violet 47, direct violet, Direct violet 94, direct violet 95, direct violet 98, direct violet 100, direct violet 101, direct yellow 8, direct yellow 9, direct yellow 11, direct yellow 12, direct yellow 27, direct yellow 28, direct yellow 29, direct yellow 33, direct yellow 35, direct yellow 39, direct yellow 41, direct yellow 44, direct yellow 50, direct yellow 53, direct yellow 58, direct yellow 59, direct yellow 68, direct yellow 86, direct yellow 87, direct yellow 93, direct yellow 95, direct yellow 96, direct yellow 98, direct yellow 100, direct yellow 106, direct yellow 108, direct yellow 109, direct yellow 110, direct yellow 130, direct yellow 132, direct yellow 142, direct yellow 144, direct yellow 161, direct yellow 163, direct black 9, direct black 17, direct black 19, direct black 22, direct black 32, direct black 51, direct black 56, direct black 62, direct black 69, direct black 77, direct black 80, direct black 91, direct black 94, direct yellow 28, direct yellow 96, direct yellow 98, direct yellow 80, direct yellow 108, direct yellow 60, direct yellow 80, direct yellow 26, direct yellow 80, direct yellow 80, direct yellow 48, direct yellow 80, direct yellow 48, direct yellow 80, direct yellow 7, direct yellow 48, direct yellow 80, direct yellow 48, direct yellow 80, direct yellow 7, direct yellow 7, direct yellow 7, direct yellow, direct, Direct black 97, direct black 108, direct black 112, direct black 113, direct black 114, direct black 117, direct black 118, direct black 121, direct black 122, direct black 125, direct black 132, direct black 146, direct black 154, direct black 166, direct black 168, direct black 173, direct black 195, and direct black 199. Reactive dyes include reactive red 2, reactive red 3, reactive red 4, reactive red 5, reactive red 8, reactive red 11, reactive red 21, reactive red 22, reactive red 23, reactive red 24, reactive red 28, reactive red 29, reactive red 31, reactive red 33, reactive red 35, reactive red 43, reactive red 45, reactive red 49, reactive red 55, reactive red 56, reactive red 58, reactive red 65, reactive red 66, reactive red 78, reactive red 83, reactive red 84, reactive red 106, reactive red 111, reactive red 112, reactive red 113, reactive red 114, reactive red 116, reactive red 120, reactive red 123, reactive red 124, reactive red 128, reactive red 130, reactive red 136, reactive red 141, reactive red 147, reactive red 158, reactive red 159, reactive red 171, reactive red 174, reactive red 180, reactive red 183, reactive red 187, reactive red 190, reactive red 193, reactive red 190, reactive red 193, reactive red 28, reactive red x 65, reactive red x, reactive, Reactive red 194, reactive red 195, reactive red 198, reactive red 220, reactive red 222, reactive red 223, reactive red 226, reactive red 228, reactive red 235, reactive yellow 1, reactive yellow 2, reactive yellow 3, reactive yellow 5, reactive yellow 11, reactive yellow 13, reactive yellow 14, reactive yellow 15, reactive yellow 17, reactive yellow 18, reactive yellow 20, reactive yellow 22, reactive yellow 23, reactive yellow 24, reactive yellow 25, reactive yellow 26, reactive yellow 27, reactive yellow 29, reactive yellow 35, reactive yellow 37, reactive yellow 40, reactive yellow 41, reactive yellow 42, reactive yellow 47, reactive yellow 51, reactive yellow 55, reactive yellow 65, reactive yellow 67, reactive yellow 81, reactive yellow 95, reactive yellow 116, reactive yellow 142, reactive yellow 161, reactive blue 1, reactive blue 2, reactive blue 3, reactive blue 5, reactive blue 7, reactive blue 8, reactive blue 10, reactive blue 13, Any one of active blue 14, active blue 15, active blue 17, active blue 18, active blue 19, active blue 21, active blue 23, active blue 25, active blue 26, active blue 27, active blue 28, active blue 29, active blue 32, active blue 35, active blue 38, active blue 41, active blue 49, active blue 63, active blue 72, active blue 75, active blue 80, active blue 95, active blue 190, active black 1, active black 3, active black 4, active black 5, active black 7, active black 8, active black 11, active black 12, active black 14, active black 17, active black 21, active black 23, active black 26, active black 31, active black 32, active black 34, and active black 39.
Alternatively, the weight ratio of the dye toner in the aqueous dye ink may be specifically 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, preferably 7% to 12%, but is not limited to the recited values, and other values not recited in the numerical value range are also applicable.
As an alternative technical scheme of the application, the mass ratio of the ether compound shown as the formula I to the glycerol is 1:
(3-6), the mass ratio of the ether compound shown in the formula I to the glycerol can be 1:3, 1:4, 1:5, 1:6 and the like, and the dye ink prepared in the ratio range has high moisture retention and good fluency and is suitable for a printer nozzle; if the mass ratio of the ether compound shown in the formula I to the glycerol is less than 1:6, the ether compound is low in mass, and the printing nozzle can drop ink due to low viscosity, so that the printing quality is influenced; if the mass ratio of the ether compound shown in the formula I to the glycerol is more than 1: and 3, the ether compound has high mass and high viscosity, so that ink supply to the printing head is not smooth, and the printing smoothness is poor. The ether compound shown in the formula I is used as a tackifier and a humectant in water-based dye ink, and is matched with glycerin for use.
As an alternative embodiment of the present application, the organic solvent includes at least one of a polyhydric alcohol and a lower alkyl ether of a polyhydric alcohol, and the organic solvent can improve dispersion stability of the dye in the ink.
Optionally, the polyol comprises at least one of ethylene glycol, propylene glycol, 1, 2-hexanediol, 1, 2-glycerol, 1, 2-propanediol, diethylene glycol, triethylene glycol.
Optionally, the lower alkyl ether of the polyol comprises at least one of triethylene glycol monobutyl ether, ethylene glycol monopropyl ether, ethylene glycol isopropyl ether, ethylene glycol monobutyl ether, ethylene glycol isobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and dipropylene glycol monopropyl ether.
The organic solvents mentioned above may be used alone or in combination of two or more, and preferably two or more.
Preferably, the weight ratio of the organic solvent in the aqueous dye ink may be specifically 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, but is not limited to the enumerated values, and other unrecited values within the numerical range are also applicable. Experiments show that the weight ratio of the organic solvent in the water-based dye ink is controlled within the range of 5-20%, so that the water can be fully preserved and the quick drying property of the pigment ink is not reduced.
As an alternative embodiment of the present application, the aqueous dye ink further comprises a surfactant, and the surfactant may be contained in an amount of 0.5% to 3% by mass of the total mass of the aqueous dye ink, specifically, in an amount of 0.5%, 0.7%, 0.9%, 1.2%, 1.5%, 2%, 2.5%, 3% by mass of the total mass of the aqueous dye ink, but the present invention is not limited to the above-mentioned values, and other values not listed in the above-mentioned value range are also applicable. The surfactant is an acetylene glycol surfactant which can act as a surface tension modifier to help provide an effective printing effect, and optionally, the acetylene glycol surfactant includes any one of 2,4,7, 9-tetramethyl-5-decyne-4, 7-diol, 3, 6-dimethyl-4-octyne-3, 6-diol, and 3, 5-dimethyl-1-hexyne-3-ol, more specifically, Surfynol 104, 82, 465, 485 from Air Products, ltd, usa can be used, and Surfynol 104, 465 is particularly preferably used.
Preferably, the weight ratio of the polyester silicone leveling agent in the aqueous dye ink can be specifically 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, but is not limited to the recited values, and other values not recited in the numerical range are also applicable. The polyester organic silicon leveling agent can reduce the surface tension of liquid and has excellent substrate wetting and leveling effects.
As an alternative embodiment of the present application, the viscosity of the aqueous dye ink is 5cp to 12cp, specifically 5cp, 6cp, 7cp, 8cp, 9cp, 10cp, 11cp, and 12cp, but the present invention is not limited to the above-mentioned values, and other values not listed in the above-mentioned value range are also applicable. The viscosity of the ink is 5-12 cp, so that the ink is suitable for a printer nozzle, ink can not be dripped, ink supply is not smooth, and the ink printing smoothness is ensured to be excellent.
As an alternative embodiment of the present application, the surface tension of the aqueous dye ink is 25mN/m to 30mN/m, specifically 25mN/m, 26mN/m, 27mN/m, 28mN/m, 29mN/m, 30mN/m, but the present invention is not limited to the recited values, and other values not recited in the numerical range are also applicable. The smoothness of the dye ink can be improved by controlling the surface tension of the dye ink within the above range.
As an alternative technical scheme, the water-based dye ink comprises the following components in percentage by weight: 5-15% of toner, 15-35% of moisturizing tackifier, 0.1-0.5% of polyester organic silicon flatting agent, 0.5-3% of surfactant, 0.1-1% of preservative, 5-20% of organic solvent and the balance of deionized water.
Organic substances and the like contained in the ink raw materials are easy to rot and mildew under a humid environment, and a preservative is usually added to prevent the decomposition, the preservative added in the present application is PROXEL GXL, and the addition amount is 0.1 to 1 percent, specifically 0.1, 0.3, 0.5, 0.7, 0.9 and 1 percent of the total mass of the aqueous dye ink, but the present invention is not limited to the recited numerical values, and other numerical values not recited in the numerical value range are also applicable.
The utility model provides a water-based dye ink low price, bright-colored printing on the corrugated paper has good moisturizing, prints the shower nozzle and prints 7 days after the start, and ink can not block up the shower nozzle by the continuity printing, and the smoothness nature of this ink is good simultaneously.
The present application will be further described with reference to specific examples and comparative examples, but the present application is not limited to these specific examples. The percentages of the components mentioned above and below in the present application are percentages by weight, and are percentages of the components based on the total weight of the pigment ink, except where specifically indicated.
1. Preparation of aqueous dye ink
Examples 1 to 4: blue (C), red (M), yellow (Y) and Black (BK) water-based dye inks prepared according to the weight percentage compositions shown in the following table 1 are respectively examples 1-4.
TABLE 1
Figure BDA0003079623320000061
2. Preparation of common dye ink
Comparative examples 1 to 4: blue (C), red (M), yellow (Y) and Black (BK) dye inks prepared without glycerol and glycerol ether or glycerol polyoxyethylene ether are prepared according to the weight percentage shown in the following table 2, and are respectively comparative examples 1-4.
Table 2:
Figure BDA0003079623320000062
Figure BDA0003079623320000071
viscosity tests show that the viscosity of the water-based dye ink prepared in the comparative examples 1-4 is less than 5 cp.
3. Aqueous formulation of non-polyaddition polyester organosilicon leveling agents
Comparative examples 5 to 8: blue (C), red (M), yellow (Y) and Black (BK) dye inks prepared by the non-polyester-polymerized organic silicon leveling agent are prepared according to the weight percentage composition shown in the following table 3, and are respectively comparative examples 5-8.
Table 3:
Figure BDA0003079623320000072
the surface tension test shows that: the surface tension of the dye ink prepared in the comparative examples 5 to 8 is between 30 and 35 mN/m.
4. Performance testing
The dye inks prepared in tables 1,2 and 3 were subjected to image effect test, smoothness test and standby test, respectively, and the results are shown in table 4 below:
table 4:
Figure BDA0003079623320000081
according to the data of the tables 1-4, the following data are found:
the dye ink prepared in the comparative examples 1-4 is not added with glycerol and ether compounds shown in the formula I, the moisture retention performance of the dye ink is poor, and a spray head is blocked in 7 days when a printer is in a standby state; the smoothness of the ink is poor, the phenomenon of missing of the jet holes exists, and compared with examples 1-4, the moisture retention performance of the dye ink is obviously reduced.
The dye ink prepared in the comparative examples 5-8 is not added with a polyester organic silicon leveling agent, has no leveling effect and large surface tension, and has poor leveling property and obviously reduced smoothness of printed images compared with the dye ink prepared in the examples 1-4.
In summary, the present application controls the weight ratio of glycerol to the ether compound represented by formula I to be 1: (3-6), the ink prepared in the proportion range has excellent moisture retention, is suitable for a printer nozzle, and has good ink fluency; if the mass ratio of the ether compound shown in the formula I to the glycerol is less than 1:6, the ether compound is low in mass, and the printing nozzle can drop ink due to low viscosity, so that the printing quality is influenced; if the mass ratio of the ether compound shown in the formula I to the glycerol is more than 1: and 3, the ether compound has high mass and high viscosity, so that ink supply to the printing head is not smooth, and the printing smoothness is poor. The polyester organic silicon flatting agent is added to reduce the surface tension of the liquid and has excellent substrate wetting and flatting effects, so that the prepared water-based dye ink has excellent leveling property and fluency.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions, improvements, etc. made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (10)

1. The water-based dye ink is characterized by comprising the following components in percentage by weight: 5-15% of dye toner, 15-35% of moisturizing tackifier, 0.1-0.5% of polyester organic silicon flatting agent, 5-20% of organic solvent and the balance of deionized water, wherein the moisturizing tackifier comprises glycerol and ether compounds shown in formula I,
Figure FDA0003079623310000011
2. the aqueous dye ink of claim 1, wherein the dye toner comprises any one of a direct dye or a reactive dye.
3. The aqueous dye ink according to claim 1 or 2, wherein the dye toner content is 7% to 12% of the total weight of the aqueous dye ink.
4. The aqueous dye ink according to claim 1, wherein the mass ratio of the ether compound to the glycerin is 1: (3-6).
5. The aqueous dye ink of claim 1, wherein the organic solvent comprises at least one of a polyol and a lower alkyl ether of a polyol.
6. The aqueous dye ink of claim 5, wherein the polyol comprises at least one of ethylene glycol, propylene glycol, 1, 2-hexanediol, 1, 2-glycerol, 1, 2-propanediol, diethylene glycol, and triethylene glycol.
7. The aqueous dye ink according to claim 5, wherein the lower alkyl ether of the polyhydric alcohol includes at least one of triethylene glycol monobutyl ether, ethylene glycol monopropyl ether, ethylene glycol isopropyl ether, ethylene glycol monobutyl ether, ethylene glycol isobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and dipropylene glycol monopropyl ether.
8. The aqueous dye ink according to claim 1, further comprising a surfactant, wherein the surfactant is contained in an amount of 0.5 to 3% by mass of the total mass of the aqueous dye ink, and the surfactant is an acetylene glycol-based surfactant.
9. The aqueous dye ink according to claim 1, further comprising a preservative in an amount of 0.1 to 1% by mass of the total mass of the aqueous dye ink.
10. The aqueous dye ink according to claim 1, wherein the aqueous dye ink has a viscosity of 5 to 12cp and a surface tension of 25 to 30 mN/m.
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Citations (5)

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Publication number Priority date Publication date Assignee Title
JPH01118583A (en) * 1988-09-30 1989-05-11 Seiko Epson Corp Ink for ink jet recording
CN108824026A (en) * 2018-06-20 2018-11-16 深圳市墨库图文技术有限公司 Reactive dye ink suitable for single-pass digital decorating machine
CN109575688A (en) * 2018-12-10 2019-04-05 郑州鸿盛数码科技股份有限公司 A kind of aqueous UV ink-jet ink and preparation method thereof and curing method
CN110373064A (en) * 2019-08-02 2019-10-25 珠海经济特区高宝化工厂有限公司 Corrugated paper water-based jet ink and its preparation method and application
JP2020062767A (en) * 2018-10-15 2020-04-23 Dic株式会社 Manufacturing method of printed matter

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01118583A (en) * 1988-09-30 1989-05-11 Seiko Epson Corp Ink for ink jet recording
CN108824026A (en) * 2018-06-20 2018-11-16 深圳市墨库图文技术有限公司 Reactive dye ink suitable for single-pass digital decorating machine
JP2020062767A (en) * 2018-10-15 2020-04-23 Dic株式会社 Manufacturing method of printed matter
CN109575688A (en) * 2018-12-10 2019-04-05 郑州鸿盛数码科技股份有限公司 A kind of aqueous UV ink-jet ink and preparation method thereof and curing method
CN110373064A (en) * 2019-08-02 2019-10-25 珠海经济特区高宝化工厂有限公司 Corrugated paper water-based jet ink and its preparation method and application

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Title
冯年平等: "《中药经皮给药与功效性化妆品》", 中国医药科技出版社, pages: 277 *

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